JP2015183357A - Paint material surface finishing method - Google Patents
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Abstract
Description
本発明は、漆喰調塗材に光輝性を付与して高い意匠性を発現する塗材表面仕上げ方法に関するものである。 The present invention relates to a coating material surface finishing method that imparts glitter to a stucco-like coating material and exhibits high designability.
従来、漆喰調塗材として、消石灰、ポリマー成分及び水を含有する塗料組成物であって、塗液又はその乾燥塗膜の(1)容器の中での状態、(2)塗装作業性、(3)低温安定性、(4)塗膜の外観、(5)耐アルカリ性、(6)耐洗浄性、(7)隠ぺい率が、JIS K5663−1995に規定される少なくとも2種のペイントの性質を満たすものである塗料組成物及び該塗料組成物を塗布してなる塗装物が提案されている(特許文献1)。 Conventionally, it is a coating composition containing slaked lime, a polymer component and water as a plaster coating material, and (1) the state of the coating liquid or its dried coating film in a container, (2) painting workability, ( 3) Low temperature stability, (4) Appearance of coating film, (5) Alkali resistance, (6) Washing resistance, (7) Concealment rate is the property of at least two kinds of paints specified in JIS K5663-1995. A coating composition that satisfies the requirements and a coated product obtained by applying the coating composition have been proposed (Patent Document 1).
また、磨き漆喰にほとんど遜色のない風合いで、しかも強度等に優れ、かつひび割れ等の発生しにくい磨き漆喰風の壁材が得られる磨き漆喰風壁材組成物として、消石灰100重量部に対して、珪砂30〜70重量部、合成樹脂エマルジョン又はパウダー樹脂3〜10重量部、すさ0.5〜6重量部、クレイ成分0.5〜5重量部、分散剤0.5〜5重量部、セルロース系増粘剤0.2〜3重量部、消泡剤0.1〜2重量部を含有することを特徴とする磨き漆喰風壁材組成物が提案されている(特許文献2)。 Moreover, as a polished plaster-like wall material composition that gives a polished plaster-like wall material that has a texture that is almost inferior to polished plaster, is excellent in strength, etc., and is difficult to generate cracks, etc., for 100 parts by weight of slaked lime , 30 to 70 parts by weight of silica sand, 3 to 10 parts by weight of synthetic resin emulsion or powder resin, 0.5 to 6 parts by weight of soil, 0.5 to 5 parts by weight of clay component, 0.5 to 5 parts by weight of dispersant, cellulose A polished plaster-like wall material composition characterized by containing 0.2 to 3 parts by weight of a system thickener and 0.1 to 2 parts by weight of an antifoaming agent has been proposed (Patent Document 2).
また、塗装模様形成方法として、炭酸カルシウム及びバインダー樹脂を含有し、水と混練してなり、炭酸カルシウムの累積量90%に相当する粒子直径が3〜20μmの範囲内であることが好ましい塗料組成物を、被塗装面の一部又は全部に、1回又は複数回塗りつける工程と、塗りつけられた前記塗料組成物の表面を乾燥させる工程と、塗りつけられた塗料組成物表面をコテ塗りする工程と、を含むもので、簡便、安全且つ低コストで所望の濃淡模様等の塗装模様を現出する方法が提案されている(特許文献3)。 Further, as a method for forming a coating pattern, a coating composition containing calcium carbonate and a binder resin, kneaded with water, and preferably having a particle diameter corresponding to 90% of the cumulative amount of calcium carbonate in the range of 3 to 20 μm. A step of applying an object to a part or all of a surface to be coated one or more times, a step of drying the surface of the applied coating composition, and a step of applying a trowel to the surface of the applied coating composition , And a method for displaying a desired paint pattern such as a shade pattern in a simple, safe and low cost has been proposed (Patent Document 3).
しかしながら、これらの塗料組成物及び該塗料組成物を塗布してなる塗装物や磨き漆喰風壁材組成物及び塗装模様形成方法は、どちらかというと従来の仕上げに近いものであって、最近の店舗等に求められる、派手すぎなく且つ高級感のあるデザインに対応するものでは無いという課題がある。 However, these coating compositions, and coatings and polished plaster-like wall material compositions and coating pattern forming methods obtained by applying the coating compositions are somewhat close to conventional finishes. There is a problem that it is not too flashy and does not correspond to a high-class design required for stores and the like.
本発明が解決しようとする課題は、大理石調の光沢を有しながら、光輝性が点状に存在し、派手すぎなく高級感のある塗材表面仕上げ方法を提供することにある。 The problem to be solved by the present invention is to provide a coating material surface finishing method that has a marble-like luster, has brilliancy in a dotted shape, and is high-quality without being too flashy.
請求項1記載の発明は、消石灰若しくは炭酸カルシウムのいずれか又は消石灰と炭酸カルシウムの混合物を40〜80重量%含有し、合成樹脂エマルションが樹脂成分として10重量%以下3重量%以上である漆喰調塗材100重量部と透明性金属光沢顔料を3〜5重量部とを均一に混合した塗材を、下地に0.5〜0.7kg/m2塗布し、乾燥後、さらに0.6〜1.0kg/m2塗布し、乾燥後に金属性鏝のエッジにて塗材表面を擦り押さえて塗材表面に光沢と光輝点を付与することを特徴とする塗材表面仕上げ方法を提供する。 The invention according to claim 1 contains 40-80% by weight of either slaked lime or calcium carbonate or a mixture of slaked lime and calcium carbonate, and the synthetic resin emulsion is 10% by weight or less and 3% by weight or more as a resin component. A coating material in which 100 parts by weight of the coating material and 3 to 5 parts by weight of a transparent metallic luster pigment are uniformly mixed is applied to the base at 0.5 to 0.7 kg / m 2 , dried, and further 0.6 to Provided is a coating material surface finishing method characterized by applying 1.0 kg / m 2 and drying and rubbing the surface of the coating material with an edge of a metallic wrinkle to give gloss and a bright spot to the coating material surface.
また、請求項2記載の発明は、透明性金属光沢顔料は、ガラス片を芯物質とし、該芯物質の表面を金属酸化物で被覆したフレーク状顔料であることを特徴とする請求項1記載の塗材表面仕上げ方法を提供する。 The invention described in claim 2 is characterized in that the transparent metallic luster pigment is a flake pigment in which a glass piece is used as a core material and the surface of the core material is coated with a metal oxide. Provide a surface finish method for coating materials.
また、請求項3記載の発明は、透明性金属光沢顔料の平均粒径は20〜200μmであることを特徴とする請求項1又は請求項2に記載の塗材表面仕上げ方法を提供する。 The invention according to claim 3 provides the coating material surface finishing method according to claim 1 or 2, wherein the transparent metallic luster pigment has an average particle diameter of 20 to 200 μm.
本発明の塗材表面仕上げ方法は、透明性金属光沢顔料を適正量含み、下地に所定量塗布した後さらに所定量塗布し、さらに金属製鏝により塗材表面を擦る押さえることにより、塗材表面に光沢を付与すると共に光輝点を付与することが出来る効果がある。このため、大理石調の光沢を有しながら、光輝性が点状に存在し、派手すぎなく高級感のある塗材表面となる効果がある。 The coating material surface finishing method of the present invention includes an appropriate amount of a transparent metallic luster pigment, and after applying a predetermined amount to a base, further applying a predetermined amount, and further pressing the surface of the coating material with a metal flaw, There is an effect that it is possible to impart gloss to the surface as well as a bright spot. For this reason, there is an effect that the surface of the coating material has high-quality feeling without being too flashy, having glossiness in the form of dots while having a marble-like luster.
以下、本発明の塗材表面仕上げ方法を実施するための形態について説明する。 Hereinafter, the form for implementing the coating material surface finishing method of this invention is demonstrated.
本発明に使用する塗材は漆喰調塗材100重量部と透明性金属光沢顔料を3〜5重量部が均一の混合された塗材であるが、漆喰調塗材は、消石灰若しくは炭酸カルシウムのいずれか又は消石灰と炭酸カルシウムの混合物を40〜80重量%含有し、合成樹脂エマルションが樹脂成分として10重量%以下3重量%以上である。合成樹脂エマルションは乾燥後の塗膜に耐水性を付与し、また乾燥によるひび割れを防止するために配合される。樹脂成分3重量%未満では乾燥後の塗膜の耐水性が不十分となり、また乾燥時にひび割れを生じる。樹脂成分が10重量%超では乾燥後の塗膜の水蒸気透過性が不十分となる場合があり、この場合下地の水分により付着性が不十分となり、場合によっては膨れが生じる。 The coating material used in the present invention is a coating material in which 100 parts by weight of a stucco coating material and 3 to 5 parts by weight of a transparent metallic luster pigment are uniformly mixed, but the plaster coating material is made of slaked lime or calcium carbonate. One or a mixture of slaked lime and calcium carbonate is contained in an amount of 40 to 80% by weight, and the synthetic resin emulsion is 10% by weight or less and 3% by weight or more as a resin component. The synthetic resin emulsion is blended to impart water resistance to the dried coating film and to prevent cracking due to drying. If the resin component is less than 3% by weight, the water resistance of the coating film after drying becomes insufficient, and cracks occur during drying. If the resin component exceeds 10% by weight, the water vapor permeability of the coating film after drying may be insufficient. In this case, the adhesiveness becomes insufficient due to the moisture of the base, and in some cases swelling occurs.
また漆喰調塗材は充填材として、消石灰若しくは炭酸カルシウムのいずれかまたは消石灰と炭酸カルシウムの混合物が意匠性や塗布作業性を良好とするために、40〜80重量%配合され、着色剤として、顔料が3〜6重量%が配合される。この他に、分散剤、増粘剤、消泡剤等が2〜4重量%配合される。 In addition, the stucco-like coating material is blended as a filler, and either slaked lime or calcium carbonate or a mixture of slaked lime and calcium carbonate is blended in an amount of 40 to 80% by weight in order to improve designability and application workability, and as a colorant, 3 to 6% by weight of pigment is blended. In addition, a dispersing agent, a thickener, an antifoaming agent, etc. are mix | blended 2 to 4 weight%.
漆喰調塗材に配合される合成樹脂エマルションは、アクリル樹脂系エマルション、エチレン酢酸ビニル樹脂系エマルション、ウレタン樹脂系エマルション、アクリルシリコン樹脂系エマルション、シリコン樹脂系エマルション等を使用することができる。 As the synthetic resin emulsion blended in the plaster coating material, an acrylic resin emulsion, an ethylene vinyl acetate resin emulsion, a urethane resin emulsion, an acrylic silicone resin emulsion, a silicone resin emulsion, or the like can be used.
本願発明に適用できる漆喰調塗材の市販品としては、ジョリパットイタリアートII JP−70、JP−65、JM−65(商品名、アイカ工業社製)、フィオレンティーノ(商品名、株式会社フッコー社製)、ベネチアート(商品名、株式会社スタッコ社製)等がある。 Examples of commercially available plaster coating materials that can be applied to the present invention include Jolipat Italian II JP-70, JP-65, JM-65 (trade name, manufactured by Aika Kogyo Co., Ltd.), Fiorentino (trade name, Fukko Co., Ltd.) And Venechi Art (trade name, manufactured by Stucco Co., Ltd.).
本発明で使用される透明性金属光沢顔料は、合成雲母、ガラス、アルミナを芯物質とし、その表面をチタン、ジルコニウム、クロム、バナジウム、鉄等の金属酸化物で被覆したものを用いることができ、特にはガラス片の表面を二酸化ケイ素で被覆し、更に二酸化チタンで被覆したフレーク状顔料であることが光輝性を発現する上で好ましい。仮に芯物質が例えば天然雲母であると光輝性が不十分となる。 As the transparent metallic luster pigment used in the present invention, synthetic mica, glass, alumina as a core substance, and the surface thereof coated with a metal oxide such as titanium, zirconium, chromium, vanadium, iron can be used. In particular, a flake pigment in which the surface of a glass piece is coated with silicon dioxide and further coated with titanium dioxide is preferable in terms of expressing glitter. If the core material is natural mica, for example, the glitter is insufficient.
また透明性金属光沢顔料が、上記ガラス片の表面を二酸化ケイ素で被覆し、更に二酸化チタンで被覆した二層被覆型のフレーク状顔料であれば、二酸化ケイ素がガラスよりも硬度が高いため、芯とするガラス片の厚みを薄くすることができ、ガラス片の厚みが薄いと光透過性がより高くなる。その結果、本願発明の漆喰調塗材に特に配合することによって、金属性鏝のエッジにて塗材表面を擦り押さえることで発現する塗膜全面の光沢と、よりコントラストが強くでて、光輝性がシャープになる。なお係る効果は本願発明者によって初めて発見された効果である。 In addition, if the transparent metallic luster pigment is a two-layer coating type flaky pigment in which the surface of the glass piece is coated with silicon dioxide and further coated with titanium dioxide, silicon dioxide has a higher hardness than glass. The thickness of the glass piece can be reduced. If the thickness of the glass piece is thin, the light transmittance becomes higher. As a result, especially by blending with the plaster-like coating material of the present invention, the gloss of the entire surface of the coating film, which is manifested by rubbing the surface of the coating material with the edge of the metallic wrinkles, has a stronger contrast, and is brilliant. Becomes sharper. This effect is an effect discovered for the first time by the present inventors.
また透明性金属光沢顔料の平均粒径は、20〜200μmが好ましく、20μm未満では光輝性が目立たなくなり、200μm超では、金属性鏝のエッジにて塗材表面を擦り押さえる際に小さく破損して、意匠性が不十分となる。ここでいう平均粒径とは、累積重量が50%となる粒径のことを言う。 The average particle size of the transparent metallic luster pigment is preferably 20 to 200 μm. If the average particle size is less than 20 μm, the glossiness becomes inconspicuous. , The design property becomes insufficient. The average particle diameter here means a particle diameter at which the cumulative weight is 50%.
このような透明性金属光沢顔料の市販品としては、Miraval 5411 Magic White、同 5420 Magic Gold、同 5422 Magic Red、同 5424 Magic Blue(商品名、メルク社製)等がある。 Commercial products of such transparent metallic luster pigments include Miraval 5411 Magic White, 5420 Magic Gold, 5422 Magic Red, 5424 Magic Blue (trade name, manufactured by Merck & Co., Inc.).
本発明に使用する塗材は、漆喰調塗材と透明性金属光沢顔料が、漆喰調塗材100重量部に対して透明性金属光沢顔料3〜5重量部が均一に混合されたものを使用するが、透明性金属光沢顔料が3重量%未満では光輝性が不十分となり、5重量部超では塗布作業性が不良となる。 As the coating material used in the present invention, a plaster-tone coating material and a transparent metallic luster pigment are used in which 3 to 5 parts by weight of a transparent metallic luster pigment are uniformly mixed with 100 parts by weight of the plaster-tone coating material. However, if the transparent metallic luster pigment is less than 3% by weight, the glitter is insufficient, and if it exceeds 5 parts by weight, the coating workability is poor.
また本発明に使用する塗材は、まず下塗りとして0.5〜0.7kg/m2を金鏝等にて塗布する。0.5kg/m2未満では下地の隠ぺい力が不十分となり、0.7kg/m2超では凹凸が生じて平滑性が不十分となる。 Moreover, the coating material used for this invention apply | coats 0.5-0.7 kg / m < 2 > with a metal hammer etc. first as undercoat. If it is less than 0.5 kg / m 2 , the hiding power of the base becomes insufficient, and if it exceeds 0.7 kg / m 2 , unevenness occurs and the smoothness becomes insufficient.
下塗りが乾燥後、同じ塗材を上塗りとして0.6〜1.0kg/m2塗布し乾燥させる。塗布量が0.6kg/m2未満では混合された透明性金属光沢顔料が脱落しやすい状態となり、1.0kg/m2超では凹凸が生じて平滑性が不十分となる。 After the undercoat has dried, 0.6 to 1.0 kg / m 2 is applied as the top coat and dried. When the coating amount is less than 0.6 kg / m 2 , the mixed transparent metallic luster pigment is in a state where it easily falls off, and when it exceeds 1.0 kg / m 2 , unevenness is generated and the smoothness becomes insufficient.
上塗りが乾燥後には、金属製の鏝のエッジを立てるようにして、該エッジにて塗材表面を擦り押さえる。これにより塗材表面に光沢と光輝点が現れる。 After the top coat is dried, the edge of the metal ridge is raised and the surface of the coating material is rubbed and pressed with the edge. As a result, gloss and bright spots appear on the surface of the coating material.
以下、実施例及び比較例にて具体的に説明する。 Hereinafter, it demonstrates concretely in an Example and a comparative example.
実施例及び比較例の塗材表面の作成
実施例として、石膏ボード(12mm厚、JISA6901相当品)にジョリパットシーラーJS−300(アイカ工業株式会社製、アクリル系樹脂エマルション、アクリル系樹脂固形分70%、下塗材、商品名)を150g/m2で刷毛塗りし、乾燥後、ジョリパット イタリアートII JP−70C72(商品名、アイカ工業株式会社製、漆喰調塗材、白色、炭酸カルシウム25重量%、消石灰35重量%、エチレン酢酸ビニル樹脂エマルション5重量%)100重量部にMiraval 5411 Magic White(平均粒径20〜200μm、商品名、メルク社製)3.8重量部を均一に混合した塗材を、下塗りとして0.6kg/m2塗布し、乾燥後、同塗材をさらに0.8kg/m2塗布した。乾燥後、金鏝のエッジにて塗材表面を擦り押さえることにより作成した塗材表面を実施例の塗材表面とした。
Preparation of coating material surfaces of examples and comparative examples
As an example, a gypsum board (12 mm thick, JISA6901 equivalent) and Jolipat Sealer JS-300 (manufactured by Aika Kogyo Co., Ltd., acrylic resin emulsion, acrylic resin solid content 70%, primer, trade name) 150 g / m 2 after brushing and drying, Jollipat Italian II JP-70C72 (trade name, manufactured by Aika Kogyo Co., Ltd., white plaster coating material, white, calcium carbonate 25% by weight, slaked lime 35% by weight, ethylene vinyl acetate resin emulsion 5 The coating material in which 3.8 parts by weight of Miraval 5411 Magic White (average particle size 20 to 200 μm, trade name, manufactured by Merck & Co., Ltd.) is uniformly mixed with 100 parts by weight of 0.6 kg / m 2 is applied as an undercoat. After drying, the same coating material was further applied at 0.8 kg / m 2 . After drying, the surface of the coating material prepared by rubbing the surface of the coating material with the edge of a hammer was used as the coating material surface of the example.
比較例として、塗材の塗布乾燥までは上記実施例と同様にし、金鏝のエッジにて塗材表面を擦り押さえる工程を行なわなかった塗材表面を比較例の塗材表面とした。 As a comparative example, the same procedure as in the above example was applied until the coating material was applied and dried, and the coating material surface that was not subjected to the step of rubbing the coating material surface with the edge of a hammer was used as the coating material surface of the comparative example.
塗材表面の評価
塗材表面をマイクロスコープVH−Z20UR/W(商品名、キーエンス社製)で100倍に拡大し、光輝性と塗材表面の光沢性の有無を目視にて判定した。実施例の塗材表面を図1に比較例の塗材表面を図2に示す。
Evaluation of coating material surface The coating material surface was magnified 100 times with a microscope VH-Z20UR / W (trade name, manufactured by Keyence Corporation), and the presence or absence of glossiness and glossiness of the coating material surface was visually determined. The coating material surface of the example is shown in FIG. 1, and the coating material surface of the comparative example is shown in FIG.
評価結果
実施例の塗材表面は、塗材表面が明瞭で全体として光沢があり、また透明性金属光沢顔料が鮮明に目視でき、光輝点が明瞭であるのに対して、比較例の塗材表面は、塗材表面がくすんで明瞭でなく、配合しているはずの透明性金属光沢顔料を視認することが出来なかった。
Evaluation results The coating material surface of the example is clear and glossy as a whole, and the transparent metallic luster pigment is clearly visible and the bright point is clear, whereas the coating material of the comparative example The surface of the coating material was dull and dull, and the transparent metallic luster pigment that should have been blended could not be seen.
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JP2018171617A (en) * | 2017-03-31 | 2018-11-08 | ベック株式会社 | Coated film formation method |
JP2021010879A (en) * | 2019-07-08 | 2021-02-04 | 株式会社クリスタルプロセス | Metallic mirror surface forming coating method |
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JP2001192255A (en) * | 2000-01-06 | 2001-07-17 | Futsukoo:Kk | Polished plaster type wall material composition |
US20020020328A1 (en) * | 2000-03-24 | 2002-02-21 | Krenz Kristen Amanda | Composition and method for wall treatment |
JP2004211035A (en) * | 2003-01-08 | 2004-07-29 | Osaka Gas Chem Kk | Coating composition and method for forming coated pattern |
JP2006152231A (en) * | 2004-02-26 | 2006-06-15 | Sk Kaken Co Ltd | Decorative coating material and decorative building material |
JP2010194429A (en) * | 2009-02-24 | 2010-09-09 | Nippon Paint Co Ltd | Laminated coating film and method of forming the same |
JP2013129831A (en) * | 2011-12-21 | 2013-07-04 | Merck Patent Gmbh | Effect pigment |
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JP2018171617A (en) * | 2017-03-31 | 2018-11-08 | ベック株式会社 | Coated film formation method |
JP7075799B2 (en) | 2017-03-31 | 2022-05-26 | ベック株式会社 | Film formation method |
JP2021010879A (en) * | 2019-07-08 | 2021-02-04 | 株式会社クリスタルプロセス | Metallic mirror surface forming coating method |
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