JP2015136327A - coating fat composition - Google Patents
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- JP2015136327A JP2015136327A JP2014009845A JP2014009845A JP2015136327A JP 2015136327 A JP2015136327 A JP 2015136327A JP 2014009845 A JP2014009845 A JP 2014009845A JP 2014009845 A JP2014009845 A JP 2014009845A JP 2015136327 A JP2015136327 A JP 2015136327A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 57
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- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
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- VMPHSYLJUKZBJJ-UHFFFAOYSA-N lauric acid triglyceride Natural products CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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Landscapes
- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Description
本発明は、米菓、スナック菓子、ビスケット菓子等の食品に塗布されるコーティング用油脂組成物に関する。 The present invention relates to a coating oil composition applied to foods such as rice confectionery, snack confectionery, biscuit confectionery and the like.
米菓、スナック菓子、ビスケット菓子等の食品は、表面の艶出しや、色調、風味、サクさ等の改良、保存安定性の向上、調味料の固着等を目的として、焼成した生地に油脂をコーティングすることが行われている。 For foods such as rice confectionery, snack confectionery, biscuits confectionery, etc., the baked dough is coated with fats and oils for the purpose of surface glazing, color tone, flavor, crispness improvement, storage stability improvement, sticking of seasonings, etc. To be done.
このコーティング用油脂は、塗布後に速やかに固化しベタツキがなくなることが、油脂の液ダレや包装材料への付着等を短時間で抑制できる点から求められる。 The coating fats and oils are required to be solidified immediately after application and to be free of stickiness from the point of being able to suppress dripping of fats and oils and adhesion to packaging materials in a short time.
また、塗布直後のベタツキはない場合でも、塗布した食品を保存中に、2不飽和トリグリセリド及び3不飽和トリグリセリド等の低融点トリグリセリドである液状油が染みだすこと等に起因して、経時的にベタツキが生じることがあり、この経時的なベタツキを抑制することも求められる。 Moreover, even when there is no stickiness immediately after application, during storage of the applied food, liquid oil which is a low melting point triglyceride such as diunsaturated triglyceride and triunsaturated triglyceride oozes out over time. Stickiness may occur, and it is also required to suppress this stickiness over time.
そして食品として消費者に供される際には、口に入れた際に表面を被覆したコーティングが速やかに溶ける口溶け感が、食品の美味しさを出すために重要である。 And when it is provided to consumers as food, the sense of melting in the mouth, in which the coating covering the surface quickly dissolves when put in the mouth, is important in order to bring out the deliciousness of the food.
そして食品へのコーティングは主にスプレー等で生地に噴霧することによって行われているが、コーティングの作業時に3飽和トリグリセリドが多い油脂や結晶化が速過ぎる油脂の結晶析出によってノズルの目詰まりが生じる場合がある。ノズルの目詰まりが生じると噴霧状態が変化し適切なコーティングに支障を生じたり、コーティングが困難になったりする。したがってコーティングの作業性の向上にはノズルの目詰まりが生じにくいことが必須になる。 The food is coated mainly by spraying on the dough with a spray or the like, but during the coating operation, clogging of the nozzle occurs due to the crystallization of fats and oils that are rich in trisaturated triglycerides or oils that are crystallized too quickly. There is a case. When the nozzle is clogged, the spraying state is changed, which causes an obstacle to proper coating or makes coating difficult. Therefore, in order to improve the workability of the coating, it is essential that the nozzles are not clogged.
従来、このコーティング用油脂には液状油や高融点油脂が使用されている。しかし、液状油を使用した場合、包装袋や手に油脂が付着したり、食感が油っぽく、また酸化安定性が低いため、長期保存する米菓、スナック菓子、ビスケット菓子等の食品の風味を損ねる。一方水添した油脂やパーム等の高融点油脂を使用した場合、酸化安定性は向上し、コーティングした食品の風味は良いが、表面の艶がなく、口溶けが悪くなる場合がある。 Conventionally, liquid oil and high melting point oil have been used for the oil for coating. However, when liquid oil is used, oil and fat adhere to packaging bags and hands, the texture is oily, and the oxidation stability is low, so the flavor of foods such as rice confectionery, snack confectionery, biscuits confectionery etc. stored for a long time Damage. On the other hand, when high melting point oils such as hydrogenated oils and palms are used, the oxidation stability is improved and the taste of the coated food is good, but the surface is not glossy and the mouth melt may be poor.
上記を改善するために食品のコーティングに使用される油脂組成物として、次のような技術が提案されている。 In order to improve the above, the following techniques have been proposed as an oil and fat composition used for food coating.
特許文献1には液状油に対して極度硬化油を配合した流動状のコーティング用油脂組成物が提案されている。流動状であるとスプレーによる噴霧時の作業性は良いものの、コーティングした食品を保存中に経時的に液状油が染みだし、ベタツキを生じ易くなる。 Patent Document 1 proposes a fluid oil composition for coating in which extremely hardened oil is blended with liquid oil. Although it is good in workability at the time of spraying when it is in a fluid state, liquid oil oozes out over time while the coated food is stored, and stickiness tends to occur.
特許文献2〜5には、エステル交換油脂を使用し、油脂組成物のSFC(固体脂含量)や3飽和トリグリセリドの割合等を特定範囲にする技術が提案されている。 Patent Documents 2 to 5 propose a technique in which transesterified fats and oils are used, and the SFC (solid fat content) of the fat and oil composition, the ratio of trisaturated triglycerides, and the like are in a specific range.
しかしながら、エステル交換油脂を使用したこれらの従来技術は、主にパーム系油脂やこれと他の油脂を組み合わせたものが使用されているが、エステル交換油脂の全構成脂肪酸中の炭素数14以下の飽和脂肪酸量が多く、エステル交換油脂と他の油脂との相溶性が悪い。そのためスプレーで噴霧してコーティングする際にエステル交換油脂のみで固化し、目詰まりを生じて作業性が悪くなり、相溶性の悪さは、経時での液状油の染みだしによるベタツキを引き起こし得る。またエステル交換油脂の組成やヨウ素価、及び添加量が適切ではないと、スプレーで噴霧してコーティングする際にエステル交換油脂のみで固化し、目詰まりを生じて作業性が更に悪くなる。 However, these conventional technologies using transesterified fats and oils mainly use palm-based fats and oils in combination with other fats and oils, but have 14 or less carbon atoms in the total constituent fatty acids of the transesterified fats and oils. The amount of saturated fatty acid is large, and the compatibility between the transesterified oil and fat and other fats and oils is poor. Therefore, when coating is performed by spraying with a spray, it is solidified only by the transesterified oil and fat, resulting in clogging, resulting in poor workability, and poor compatibility can cause stickiness due to oozing out of liquid oil over time. Further, if the composition, iodine value, and addition amount of the transesterified oil / fat are not appropriate, solidification occurs only with the transesterified oil / fat when sprayed and coated by spraying, resulting in clogging and further worsening workability.
例えば、特許文献2、3ではパーム系油脂に液状油を組み合わせたエステル交換油脂や、全構成脂肪酸中の炭素数14以下の飽和脂肪酸量が高いエステル交換油脂を使用しているが、エステル交換油脂と他の油脂との相溶性が悪く、また特許文献4では油脂組成物のSFCが高く、特許文献5ではエステル交換油脂のヨウ素価が低いが、このような場合にはスプレーで噴霧する際にエステル交換油脂のみで固化し、目詰まりを生じて作業性が悪くなりやすい。 For example, Patent Documents 2 and 3 use transesterified fats and oils in which liquid oil is combined with palm-based fats and oils, and transesterified fats and oils having a high amount of saturated fatty acids having 14 or less carbon atoms in all fatty acids. Is poor in compatibility with other oils and fats, and in Patent Document 4, the SFC of the oil / fat composition is high, and in Patent Document 5 the iodine value of the transesterified oil / fat is low. Solidified only with transesterified oils and fats, causing clogging, and workability tends to deteriorate.
本発明は、以上の通りの事情に鑑みてなされたものであり、コーティングした食品の固化性が良く速やかにベタツキが抑制され、食品保存時等に経時でのベタツキが生じることも抑制され、口溶けが良好で、更にスプレー等で噴霧する際に目詰まり等が生じにくく作業性にも優れたコーティング用油脂組成物を提供することを課題としている。 The present invention has been made in view of the circumstances as described above, and the solidification of the coated food is good and the stickiness is quickly suppressed, and the occurrence of stickiness with time during food storage and the like is also suppressed. It is an object of the present invention to provide an oil and fat composition for coating which is excellent in workability, and is less likely to be clogged when sprayed with a spray or the like and is excellent in workability.
前記の課題を解決するために、本発明のコーティング用油脂組成物は、ラウリン系油脂とパーム系油脂とのエステル交換油脂を含有し、エステル交換油脂は全構成脂肪酸中の炭素数14以下の飽和脂肪酸量が20質量%未満であり、エステル交換油脂の含有量が組成物全量に対して5質量%以上45質量%未満であることを特徴としている。 In order to solve the above-mentioned problems, the oil composition for coating of the present invention contains a transesterified oil and fat of lauric oil and palm oil and the transesterified oil and fat is saturated with 14 or less carbon atoms in the total constituent fatty acids. The amount of fatty acid is less than 20% by mass, and the content of the transesterified oil / fat is 5% by mass or more and less than 45% by mass with respect to the total amount of the composition.
このコーティング用油脂組成物は、構成脂肪酸として飽和脂肪酸(S)を2個、不飽和脂肪酸(U)を1個含む2飽和トリグリセリドのうち、対称型トリグリセリド(SUS)と非対称型トリグリセリド(SSU)との質量比(SUS/SSU)が0.1〜5.0であることが好ましい。 This oil composition for coating comprises a symmetric triglyceride (SUS) and an asymmetric triglyceride (SSU) among di-saturated triglycerides containing two saturated fatty acids (S) and one unsaturated fatty acid (U) as constituent fatty acids. It is preferable that mass ratio (SUS / SSU) of this is 0.1-5.0.
このコーティング用油脂組成物は、構成脂肪酸として飽和脂肪酸(S)を2個、不飽和脂肪酸(U)を1個含む2飽和トリグリセリドと、構成脂肪酸として飽和脂肪酸(S)を3個含む3飽和トリグリセリドとの合計割合が40〜85質量%であることが好ましい。 This oil composition for coating comprises two saturated triglycerides containing two saturated fatty acids (S) as constituent fatty acids and one unsaturated fatty acid (U), and three saturated triglycerides containing three saturated fatty acids (S) as constituent fatty acids. It is preferable that the sum total ratio is 40-85 mass%.
このコーティング用油脂組成物は、エステル交換油脂は、ヨウ素価が20超45以下であることが好ましい。 In the oil composition for coating, the transesterified oil or fat preferably has an iodine value of more than 20 and 45 or less.
このコーティング用油脂組成物は、ノズルからの噴霧による食品のコーティングに使用されることが好ましい。 This oil composition for coating is preferably used for coating food by spraying from a nozzle.
本発明によれば、コーティングした食品の固化性が良く速やかにベタツキが抑制され、食品保存時等に経時でのベタツキが生じることも抑制され、口溶けが良好で、更にスプレー等で噴霧する際には目詰まり等が生じにくく作業性にも優れている。 According to the present invention, the solidification of the coated food is good and the stickiness is quickly suppressed, the stickiness over time is also suppressed during food storage, etc., the mouth melt is good, and further when sprayed with a spray etc. Is less clogged and has excellent workability.
以下に、本発明を詳細に説明する。 The present invention is described in detail below.
本発明のコーティング用油脂組成物は、ラウリン系油脂とパーム系油脂とのエステル交換油脂を含有することを特徴としている。 The coating oil / fat composition of the present invention is characterized by containing a transesterified oil / fat of lauric oil / fat and palm oil / fat.
このエステル交換油脂は、全構成脂肪酸中の炭素数14以下の飽和脂肪酸量が20質量%未満であり、好ましくは18質量%以下、より好ましくは2〜18質量%、更に好ましくは10〜18質量%である。また全構成脂肪酸中の炭素数12と炭素数14の飽和脂肪酸量が好ましくは15質量%以下、より好ましくは2〜15質量%、更に好ましくは8〜15質量%である。 In this transesterified oil and fat, the amount of saturated fatty acid having 14 or less carbon atoms in all the constituent fatty acids is less than 20% by mass, preferably 18% by mass or less, more preferably 2 to 18% by mass, and still more preferably 10 to 18% by mass. %. The amount of saturated fatty acids having 12 and 14 carbon atoms in all the constituent fatty acids is preferably 15% by mass or less, more preferably 2 to 15% by mass, and still more preferably 8 to 15% by mass.
本発明のコーティング用油脂組成物は、このエステル交換油脂を特定量含有し、他の油脂と組み合わせ、特にSUS/SSUや2飽和トリグリセリドと3飽和トリグリセリドとの合計割合を前記のような範囲に調整することによって、コーティングした食品の固化性が良く速やかにベタツキが抑制され、食品保存時等に経時でのベタツキが生じることも抑制され、食品を口に入れた際にコーティング用油脂組成物が速やかに溶けて良好な口溶けが得られ、更にスプレー等で噴霧する際には目詰まり等が生じにくく作業性にも優れている。 The oil composition for coating of the present invention contains a specific amount of this transesterified oil and oil, and is combined with other oils and fats, and in particular, the total ratio of SUS / SSU and 2-saturated triglyceride and 3-saturated triglyceride is adjusted to the above range. By doing so, the solidification of the coated food is good and the stickiness is quickly suppressed, and the stickiness over time is also suppressed when the food is stored, etc., and when the food is put in the mouth, the coating fat composition is quickly When melted with a spray or the like, clogging or the like hardly occurs and the workability is excellent.
すなわち、このエステル交換油脂は、他の油脂との相溶性が良く、例えば硬い油脂だけで固まることが抑制され、経時による液状油の染みだしを抑制できる。そのため食品保存時等に液状油が固液分離して経時でのベタツキが生じることが抑制され、更にスプレー等で噴霧する際には油脂結晶析出による目詰まりが生じにくい。そして他の油脂に対して核となりやすく、核発生を誘発し、その結果として固化が遅れることを抑制することができるため、コーティングした食品の固化性が良く速やかにベタツキが抑制される。 That is, this transesterified oil and fat has good compatibility with other fats and oils, for example, it is suppressed from hardening only with hard fats and oils, and oozing of liquid oil over time can be suppressed. Therefore, liquid oil is separated into solid and liquid during food storage and the like is prevented from becoming sticky over time. Further, when spraying with a spray or the like, clogging due to oil crystal precipitation is less likely to occur. And since it is easy to become a nucleus with respect to other fats and oils, the generation of the nucleus can be suppressed, and as a result, the delay in solidification can be suppressed, so that the solidification of the coated food is good and the stickiness is quickly suppressed.
そしてエステル交換油脂は、ヨウ素価が好ましくは20超45以下、より好ましくは22〜45、更に好ましくは25〜40である。ヨウ素価がこの範囲内であると、前記のように他の油脂との相溶性が良く、そして他の油脂に対して核となりやすく、核発生を誘発し、その結果として固化が遅れることを抑制することができるため、前記したような各種の特性が更に改善される。ヨウ素価が20超であると、他の油脂との相溶性が良く、例えば硬い油脂だけで固まることが抑制され、経時による液状油の染みだしを抑制できるため、食品保存時等に液状油が固液分離して経時でのベタツキが生じることが抑制され、更にスプレー等で噴霧する際には固形分による目詰まりが生じにくい。ヨウ素価が45以下であると、他の油脂に対して核となりやすく、核発生を誘発し、その結果として固化が遅れることを抑制することができるため、コーティングした食品の固化性が良く速やかにベタツキが抑制される。 The transesterified oil / fat preferably has an iodine value of more than 20 and 45 or less, more preferably 22 to 45, and still more preferably 25 to 40. If the iodine value is within this range, the compatibility with other fats and oils is good as described above, and it is easy to become a nucleus with respect to other fats and oils. Therefore, various characteristics as described above are further improved. If the iodine value is more than 20, the compatibility with other fats and oils is good, for example, it is possible to suppress solidification only with hard fats and oils, and to prevent the liquid oil from oozing over time. Occurrence of stickiness over time due to solid-liquid separation is suppressed, and clogging due to solid content is less likely to occur when spraying with a spray or the like. If the iodine value is 45 or less, it is easy to become a nucleus for other fats and oils, and it is possible to induce the generation of nuclei, and as a result, it is possible to suppress delay in solidification. Stickiness is suppressed.
エステル交換油脂の原料であるラウリン系油脂は、全構成脂肪酸中のラウリン酸含有量が30質量%以上、好ましくは40〜55質量%、より好ましくは45〜50質量%である。このようなラウリン系油脂としては、パーム核油、ヤシ油、これらの分別油、硬化油等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。これらのうち、ヤシ油に比べて融点が高く、高融点のエステル交換油脂を容易に得ることができる点を考慮すると、パーム核油及びその分別油や硬化油が好ましい。硬化油としては、部分硬化油、低温硬化油、又は完全水素添加した極度硬化油を用いることができるが、極度硬化油を用いるとトランス酸量を低減することができる。 As for the lauric fats and oils which are raw materials of transesterified fats and oils, lauric acid content in all the constituent fatty acids is 30 mass% or more, preferably 40 to 55 mass%, more preferably 45 to 50 mass%. Examples of such lauric fats and oils include palm kernel oil, coconut oil, fractionated oils thereof, hardened oils, and the like. These may be used alone or in combination of two or more. Among these, palm kernel oil and its fractionated oil and hardened oil are preferred in view of the fact that the melting point is higher than that of coconut oil and a high melting point transesterified oil and fat can be easily obtained. As the hardened oil, a partially hardened oil, a low temperature hardened oil, or an extremely hardened oil that has been completely hydrogenated can be used. However, using an extremely hardened oil can reduce the amount of trans acid.
ラウリン系油脂は、ヨウ素価が2以下であることが好ましい。ヨウ素価が2以下のラウリン系油脂を用いると、他の油脂に対して核となりやすく、核発生を誘発するため固化が遅れるのを抑制できる。ヨウ素価が2以下のラウリン系油脂としては、極度硬化油を用いることができる。 The lauric oil / fat preferably has an iodine value of 2 or less. When a lauric oil having an iodine value of 2 or less is used, it tends to be a nucleus with respect to other oils and fats, and it is possible to suppress delay in solidification because it induces nucleation. As the lauric oil having an iodine value of 2 or less, extremely hardened oil can be used.
エステル交換油脂の原料であるパーム系油脂は、全構成脂肪酸中の炭素数16以上の脂肪酸含有量が35質量%以上である。パーム系油脂としては、パーム油、パーム分別油、これらの硬化油、エステル交換油脂等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部(パームステアリン等)、軟質部(パームオレイン、パームダブルオレイン等)、中融点部(PMF等)等を用いることができる。パーム系油脂として硬化油を使用する場合、部分硬化油、低温硬化油、極度硬化油等を用いることができるが、中でも極度硬化油が好ましい。 Palm-based fats and oils that are raw materials for transesterified fats and oils have a fatty acid content of 16 or more carbon atoms in all the constituent fatty acids of 35% by mass or more. Examples of palm oils and fats include palm oil, palm fractionated oil, hardened oils thereof, transesterified oils and fats, and the like. These may be used alone or in combination of two or more. As palm fractionated oil, a hard part (palm stearin etc.), a soft part (palm olein, palm double olein etc.), a medium melting point part (PMF etc.), etc. can be used. When using hardened oil as palm oil and fat, partially hardened oil, low temperature hardened oil, extremely hardened oil, etc. can be used, but extremely hardened oil is particularly preferable.
パーム系油脂は、極度硬化油をパーム系油脂の合計量に対して5〜45質量%の範囲内で含有することが好ましく、20〜40質量%の範囲内で含有することがより好ましい。極度硬化油をこの範囲内で含有すると、経時による液状油の染みだしが抑制されベタツキが生じることを抑制できる。 The palm oil / fat preferably contains extremely hardened oil within a range of 5 to 45% by mass, and more preferably within a range of 20 to 40% by mass with respect to the total amount of palm oil / fat. When the extremely hardened oil is contained within this range, it is possible to prevent the liquid oil from leaking over time and to prevent stickiness.
そしてエステル交換油脂は、ラウリン系油脂5質量%以上30質量%未満と、パーム系油脂70質量%超95質量%以下とをエステル交換して得られたものであることが好ましい。ラウリン系油脂とパーム系油脂をこの質量範囲で使用すると、エステル交換油脂の全構成脂肪酸中の炭素数14以下の飽和脂肪酸量を20質量%未満とすることが容易である。 And it is preferable that transesterified fats and oils are obtained by transesterifying lauric fats and oils 5 mass% or more and less than 30 mass%, and palm fats and oils more than 70 mass% and 95 mass% or less. When lauric fats and palm fats and oils are used in this mass range, it is easy to make the amount of saturated fatty acids having 14 or less carbon atoms in all the constituent fatty acids of the transesterified fats and oils less than 20% by weight.
ラウリン系油脂とパーム系油脂とのエステル交換反応には、エステル交換触媒として化学触媒や酵素触媒が用いられる。化学触媒としてはナトリウムメチラートや水酸化ナトリウム等が用いられ、酵素触媒としてはリパーゼ等が用いられる。リパーゼとしてはアスペルギルス属、アルカリゲネス属等のリパーゼが挙げられ、イオン交換樹脂、ケイ藻土、セラミック等の担体上に固定し固定化したものを用いても、粉末の形態として用いても良い。また位置選択性のあるリパーゼ、位置選択性のないリパーゼのいずれも用いることができるが、位置選択性のないリパーゼを用いることが好ましい。エステル交換触媒として化学触媒や位置選択性のない酵素触媒を用いた場合、ラウリン系油脂とパーム系油脂とのエステル交換反応が完了すると、構成脂肪酸として飽和脂肪酸(S)を2個、不飽和脂肪酸(U)を1個含む2飽和トリグリセリドのうち、対称型トリグリセリド(SUS)と非対称型トリグリセリド(SSU)とのエステル交換油脂中における質量比(SUS/SSU)が0.45〜0.55となる。 A chemical catalyst or an enzyme catalyst is used as a transesterification catalyst in the transesterification reaction between lauric fat and palm fat. Sodium methylate, sodium hydroxide or the like is used as the chemical catalyst, and lipase or the like is used as the enzyme catalyst. Examples of the lipase include lipases of the genus Aspergillus, Alkagenes, etc., which may be fixed and immobilized on a carrier such as an ion exchange resin, diatomaceous earth, or ceramic, or may be used in the form of a powder. Either lipase with regioselectivity or lipase without regioselectivity can be used, but it is preferable to use a lipase without regioselectivity. When a chemical catalyst or an enzyme catalyst without regioselectivity is used as the transesterification catalyst, when the transesterification reaction between the lauric fat and the palm fat is completed, two saturated fatty acids (S) as constituent fatty acids and unsaturated fatty acids Among di-saturated triglycerides containing one (U), the mass ratio (SUS / SSU) in the transesterified oil / fat of symmetric triglyceride (SUS) and asymmetric triglyceride (SSU) is 0.45 to 0.55. .
エステル交換に化学触媒を用いる場合、触媒を油脂質量の0.05〜0.15質量%添加し、減圧下で80〜120℃に加熱し、0.5〜1.0時間攪拌することでラウリン系油脂とパーム系油脂とのエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。また酵素触媒を用いる場合、リパーゼ等の酵素触媒を油脂質量の0.01〜10質量%添加し、40〜80℃でエステル交換反応を行うことによりエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。エステル交換反応はカラムによる連続反応、バッチ反応のいずれの方法で行うこともできる。エステル交換反応後、必要に応じて脱色、脱臭等の精製を行うことができる。 When a chemical catalyst is used for transesterification, 0.05 to 0.15% by mass of the oil lipid amount is added to the catalyst, heated to 80 to 120 ° C. under reduced pressure, and stirred for 0.5 to 1.0 hour. The transesterification reaction between the base oil and fat and the palm oil and fat is completed in an equilibrium state, and the transesterification oil and fat can be obtained. When an enzyme catalyst is used, an enzyme catalyst such as lipase is added in an amount of 0.01 to 10% by mass of the oil lipid amount, and the ester exchange reaction is completed in an equilibrium state by performing an ester exchange reaction at 40 to 80 ° C. Transesterified fats and oils can be obtained. The transesterification reaction can be carried out by either a continuous reaction using a column or a batch reaction. After the transesterification reaction, purification such as decolorization and deodorization can be performed as necessary.
ラウリン系油脂における全構成脂肪酸中のラウリン酸の割合、パーム系油脂における全構成脂肪酸中の炭素数16以上の脂肪酸含有量、エステル交換反応の終了は、ガスクロマトグラフ法により確認することができる。 The ratio of lauric acid in all constituent fatty acids in lauric fats and oils, the content of fatty acids having 16 or more carbon atoms in all constituent fatty acids in palm fats and oils, and the end of transesterification can be confirmed by gas chromatography.
本発明のコーティング用油脂組成物におけるエステル交換油脂の含有量は、組成物全量に対して5〜45質量%未満、好ましくは7〜43質量%、より好ましくは10〜40質量%である。この範囲内であると、コーティングした食品の固化性が良く速やかにベタツキが抑制され、食品保存時等に経時でのベタツキが生じることも抑制され、口溶けが良好で、更にスプレー等で噴霧する際には目詰まり等が生じにくく作業性にも優れている。この含有量が5質量%以上であると、固化性が良く、経時でのベタツキも抑制され、この含有量が45質量%未満であると、口溶けが良好で、スプレー等で噴霧する際に目詰まりが生じにくく作業性に優れる。 The content of the transesterified fat / oil in the coating fat / oil composition of the present invention is less than 5 to 45% by mass, preferably 7 to 43% by mass, and more preferably 10 to 40% by mass with respect to the total amount of the composition. Within this range, the solidification of the coated food is good and the stickiness is quickly suppressed, the stickiness over time is also suppressed during food storage, etc., the mouth melts well, and further when sprayed with a spray etc. Is not clogged and has excellent workability. When the content is 5% by mass or more, the solidification property is good, and the stickiness with time is suppressed, and when the content is less than 45% by mass, the mouth melts well, and when spraying with a spray or the like, Clogging hardly occurs and workability is excellent.
特に、エステル交換油脂の含有量をこのような範囲とし、他の油脂を組み合わせることによって、コーティング用油脂組成物のトリグリセリドを次のような範囲にすることが好ましい。 In particular, it is preferable to set the triglyceride of the coating oil composition to the following range by combining the content of the transesterified oil and fat in such a range and combining other oils and fats.
本発明のコーティング用油脂組成物は、2飽和トリグリセリドのうち、対称型トリグリセリド(SUS)と非対称型トリグリセリド(SSU)との質量比(SUS/SSU)が0.1〜5.0であることが好ましい。この範囲内であると、固化性、経時でのベタツキ抑制、口溶け、スプレー等で噴霧する際の作業性が特に優れている。固化性が特に良好であること等を考慮すると0.1〜3.0がより好ましい。 The oil / fat composition for coating of the present invention has a mass ratio (SUS / SSU) of symmetric triglyceride (SUS) to asymmetric triglyceride (SSU) of disaturated triglycerides of 0.1 to 5.0. preferable. Within this range, solidification properties, suppression of stickiness over time, melting in the mouth, workability when spraying with a spray, etc. are particularly excellent. Considering that the solidification property is particularly good, 0.1 to 3.0 is more preferable.
このコーティング用油脂組成物は、構成脂肪酸として飽和脂肪酸(S)を2個、不飽和脂肪酸(U)を1個含む2飽和トリグリセリドと、構成脂肪酸として飽和脂肪酸(S)を3個含む3飽和トリグリセリドとの合計割合が油脂全体の質量に対して40〜85質量%であることが好ましい。この範囲内であると、固化性、経時でのベタツキ抑制、口溶け、スプレー等で噴霧する際の作業性が特に優れている。この合計割合が40質量%以上であると経時でのベタツキが抑制される。更に、経時でのベタツキが特に少ない点を考慮すると、この合計割合は50質量%以上が好ましく、口溶けが特に良好になる点を考慮すると、この合計割合は60質量%以下が好ましい。 This oil composition for coating comprises two saturated triglycerides containing two saturated fatty acids (S) as constituent fatty acids and one unsaturated fatty acid (U), and three saturated triglycerides containing three saturated fatty acids (S) as constituent fatty acids. It is preferable that the sum total ratio is 40-85 mass% with respect to the mass of the whole fats and oils. Within this range, solidification properties, suppression of stickiness over time, melting in the mouth, workability when spraying with a spray, etc. are particularly excellent. If this total ratio is 40% by mass or more, stickiness over time is suppressed. Furthermore, considering that the stickiness with time is particularly small, the total ratio is preferably 50% by mass or more, and considering the point that the mouth melting is particularly good, the total ratio is preferably 60% by mass or less.
本発明のコーティング用油脂組成物は、第1の油脂成分としてのエステル交換油脂に加えて次の第2の油脂成分を配合することが好ましい。 The oil composition for coating of the present invention preferably contains the following second oil / fat component in addition to the transesterified oil / fat as the first oil / fat component.
第2の油脂成分は、構成脂肪酸の総炭素数が46であるトリグリセリドと構成脂肪酸の総炭素数が48であるトリグリセリドとの合計割合が1〜25質量%の範囲内である油脂であり、パーム系油脂や、ラード、乳脂、ヤシ油、パーム核油、及びこれらの分別油や部分硬化油、菜種部分硬化油等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。 The second fat and oil component is a fat and oil in which the total ratio of the triglyceride having 46 total fatty acids and the triglyceride having 48 total fatty acids is in the range of 1 to 25 mass%, and palm Oils, lard, milk fat, coconut oil, palm kernel oil, fractionated oils, partially hardened oils, rapeseed partially hardened oils, and the like. These may be used alone or in combination of two or more. May be.
この第2の油脂成分は、本発明のコーティング用油脂組成物のSUS/SSUや2飽和トリグリセリドと3飽和トリグリセリドとの合計割合を調整し、本発明の効果を高めることができる。 This 2nd oil-fat component can adjust the sum total ratio of SUS / SSU of the oil-fat composition for coating of this invention, 2 saturated triglyceride, and 3 saturated triglyceride, and can heighten the effect of this invention.
これらの中でも、パーム系油脂及びヤシ油から選ばれる少なくとも1種が好ましい。 Among these, at least 1 sort (s) chosen from palm oil fat and palm oil is preferable.
ここでパーム系油脂としては、パーム油、パーム分別油、及びこれらの硬化油、エステル交換油脂等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部(パームステアリン等)、軟質部(パームオレイン、パームスーパーオレイン等)、中融点部(PMF等)等を用いることができる。 Here, examples of the palm-based fats and oils include palm oil, palm fractionated oil, and these hardened oils and transesterified fats and oils. These may be used alone or in combination of two or more. As palm fractionated oil, a hard part (palm stearin etc.), a soft part (palm olein, palm super olein etc.), a middle melting point part (PMF etc.), etc. can be used.
この第2の油脂成分のパーム系油脂は、相溶性等の点から、ヨウ素価45〜65のパーム系油脂を使用することが好ましく、このようなパーム系油脂としては、パーム油、パーム分別軟質油、パーム分別中融点油、及びこれらのエステル交換油脂等が挙げられる。 The palm oil / fat of the second oil / fat component is preferably a palm oil / fat having an iodine value of 45 to 65 from the viewpoint of compatibility and the like. Oil, palm fractionation middle melting point oil, and these transesterified oils and the like.
本発明のコーティング用油脂組成物における第2の油脂成分の含有量は、組成物全量に対して40〜92質量%が好ましく、50〜90質量%がより好ましい。 40-92 mass% is preferable with respect to the composition whole quantity, and, as for content of the 2nd oil-fat component in the oil-fat composition for coating of this invention, 50-90 mass% is more preferable.
本発明のコーティング用油脂組成物は、以上の第1及び第2の油脂成分に加えて、第3の油脂成分として液状油を配合することができる。ここで液状油は5℃で流動状を呈する油脂であり、菜種油、大豆油、コーン油、米油、綿実油、ひまわり油、ゴマ油、オリーブ油等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。 The oil composition for coating of the present invention can contain liquid oil as the third oil component in addition to the first and second oil components described above. Here, the liquid oil is oil and fat that exhibits a fluid state at 5 ° C., and examples thereof include rapeseed oil, soybean oil, corn oil, rice oil, cottonseed oil, sunflower oil, sesame oil, olive oil, and the like. You may use 2 or more types together.
本発明のコーティング用油脂組成物における第3の油脂成分の含有量は、組成物全量に対して40質量%以下が好ましく、5〜30質量%がより好ましい。 40 mass% or less is preferable with respect to the composition whole quantity, and, as for content of the 3rd oil-fat component in the oil-fat composition for coating of this invention, 5-30 mass% is more preferable.
本発明のコーティング用油脂組成物は、以上の油脂成分の他に、その他の油脂成分、例えば、植物油脂の極度硬化油等を適宜の量で配合することができる。植物油脂の極度硬化油としては、ヤシ極度硬化油、パーム極度硬化油、パーム核極度硬化油、菜種極度硬化油等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。 The oil composition for coating of the present invention can contain other oil components, for example, extremely hardened oils of vegetable oils and the like in an appropriate amount in addition to the above oil components. Examples of extremely hardened oils of vegetable oils include palm extremely hardened oil, palm extremely hardened oil, palm kernel extremely hardened oil, rapeseed extremely hardened oil, and the like. These may be used alone or in combination of two or more. May be.
本発明のコーティング用油脂組成物は、本発明の効果を損なわない範囲内において、保存安定性、酸化安定性、熱安定性、低温化での結晶抑制等を目的とした通常用いられる乳化剤、酸化防止剤、消泡剤、フレーバー等を配合することができる。 The oil composition for coating according to the present invention is an emulsifier usually used for the purpose of storage stability, oxidation stability, thermal stability, crystallization suppression at low temperature, etc. within the range not impairing the effects of the present invention. An inhibitor, an antifoaming agent, a flavor, etc. can be mix | blended.
本発明のコーティング用油脂組成物は、前記の各成分を配合し常法により均一に混合することによって製造することができる。混合は各成分が均一に溶解するように加熱下で攪拌することによって行うことができ、その後冷却することにより本発明のコーティング用油脂組成物を調製することができる。 The oil composition for coating of the present invention can be produced by blending the above-mentioned components and uniformly mixing them by a conventional method. Mixing can be performed by stirring under heating so that each component is uniformly dissolved, and then the oil composition for coating of the present invention can be prepared by cooling.
本発明のコーティング用油脂組成物を使用する食品は、特に制限はないが、米菓、スナック菓子、ビスケット菓子等のような、焼成又は油ちょうした食品が好適である。 The food using the oil composition for coating of the present invention is not particularly limited, but a baked or oily food such as rice confectionery, snack confectionery, biscuits confectionery and the like is suitable.
米菓としては、煎餅、おかき、あられ等の米を原料とする菓子類が挙げられる。 Examples of rice confectionery include confectionery made from rice such as rice crackers, rice crackers, and hail.
スナック菓子としては、パフ、コーンフレーク、ポップコーン、ポテトチップス等のトウモロコシ、米粉、いも類、豆類、澱粉類等を原料とする菓子類が挙げられる。 Examples of snacks include confections made from corn such as puff, corn flakes, popcorn, potato chips, rice flour, potatoes, beans, and starches.
ビスケット菓子としては、ハードビスケット、クッキー、クラッカー、プレッツェル等が挙げられる。 Examples of the biscuits confectionery include hard biscuits, cookies, crackers, and pretzel.
本発明のコーティング用油脂組成物を上記の食品に塗布する方法は特に限定されず、スプレー等による噴霧や、浸漬、刷毛などによる塗布等を適用することができるが、中でも噴霧による方法が好ましい。噴霧には従来よりこの分野で使用されているスプレー等が使用できる。 The method for applying the coating oil composition of the present invention to the above food is not particularly limited, and spraying or the like, application by dipping, brushing, or the like can be applied. Among these, the spraying method is preferable. The spray etc. which are conventionally used in this field can be used for spraying.
本発明のコーティング用油脂組成物を上記の食品に塗布する際には、表面の艶出しや、色調、風味、サクさ等の改良、保存安定性の向上、調味料の固着等を目的として、食品の種類等に応じて適宜の量を塗布することができる。またコーティング用油脂組成物と予め混合して、又はコーティング用油脂組成物とは別個に、調味料を食品表面に塗布してもよい。 When applying the oil composition for coating of the present invention to the above food, for the purpose of surface gloss, improvement of color tone, flavor, crispness, improvement of storage stability, fixing of seasoning, etc. An appropriate amount can be applied according to the type of food. Moreover, you may apply | coat a seasoning to the foodstuff surface previously mixed with the oil-fat composition for coating, or separately from the oil-fat composition for coating.
本発明のコーティング用油脂組成物を上記食品に対し1〜40質量%塗布することが好ましく、5〜40質量%であることがより好ましい。 It is preferable to apply 1 to 40% by mass, and more preferably 5 to 40% by mass, of the oil / fat composition for coating of the present invention to the food.
以下に、実施例により本発明を更に詳しく説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、表1〜表3における各成分の配合量は質量部を示す。
(1)測定方法
各油脂のヨウ素価は基準油脂分析試験法(社団法人日本油化学会)の「2.3.4.1−1996 ヨウ素価(ウィイス−シクロヘキサン法)」で測定した。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. In addition, the compounding quantity of each component in Table 1-Table 3 shows a mass part.
(1) Measuring method The iodine value of each fat / oil was measured by “2.3.4.1-1996 Iodine number (Wiis-cyclohexane method)” of the standard fat analysis method (Japan Oil Chemical Society).
油脂組成物における全構成脂肪酸中の炭素数14以下の飽和脂肪酸量、全構成脂肪酸中の炭素数12と炭素数14の飽和脂肪酸量は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「2.4.2.2−1996 脂肪酸組成(FID昇温ガスクロマトグラフ法)で測定した。 The amount of saturated fatty acids having 14 or less carbon atoms in all constituent fatty acids in the fat and oil composition, and the amount of saturated fatty acids having 12 and 14 carbon atoms in all constituent fatty acids are determined by gas chromatography (standard oil analysis test method (Japan Oil) Chemical Society) "2.4.2.2-1996 Fatty acid composition (FID temperature rising gas chromatograph method).
油脂組成物における対称型トリグリセリド(SUS)と非対称型トリグリセリド(SSU)との質量比(SUS/SSU)は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「2.4.2.2−1996 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「暫7-2003 2位脂肪酸組成」)により求めたSUS型トリグリセリドとSSU型トリグリセリドの質量より算出した。 The mass ratio (SUS / SSU) of symmetric triglyceride (SUS) to asymmetric triglyceride (SSU) in the oil / fat composition was determined by the gas chromatographic method (standard oil analysis test method (Japan Oil Chemists' Society) 2.4). It was calculated from the masses of the SUS triglyceride and the SSU triglyceride obtained by “2.2-1996 fatty acid composition (FID temperature rising gas chromatograph method)” and “temporary 7-2003 2-position fatty acid composition”).
油脂組成物における2飽和トリグリセリドと3飽和トリグリセリドとの合計割合は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「2.4.2.2−1996 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「暫7-2003 2位脂肪酸組成」)で測定し、それぞれ脂肪酸量を用いて計算にて求めた。 The total ratio of di-saturated triglyceride and tri-saturated triglyceride in the oil / fat composition is determined according to “2.4.2.2-1996 Fatty Acid Composition (FID Ascent) of Gas Chromatography Method (Standard Oil Analysis Test Method (Japan Oil Chemists' Society)). Warm gas chromatographic method) ”and“ temporary 7-2003 2-position fatty acid composition ”), and each was calculated by using the amount of fatty acid.
(2)油脂組成物の調製
(エステル交換油脂1〜6)
エステル交換油脂1〜6は次の方法で調製した。表1に示す割合でラウリン系油脂とパーム系油脂とを混合して110℃に加熱し、十分に脱水させた後、化学触媒としてナトリウムメチラートを油脂量の0.08質量%添加し、減圧下、100℃で0.5時間攪拌しながらエステル交換反応を行った。エステル交換反応後、水洗して触媒を除去し、活性白土を用いて脱色し、更に脱臭を行ってエステル交換油脂を得た。
(2) Preparation of oil composition (transesterified oil 1-6)
Transesterified fats and oils 1 to 6 were prepared by the following method. After mixing lauric fat and palm fat and oil at a ratio shown in Table 1 and heating to 110 ° C. and sufficiently dehydrating, sodium methylate as a chemical catalyst was added in an amount of 0.08% by mass of the fat and oil. The transesterification was carried out with stirring at 100 ° C. for 0.5 hour. After the transesterification reaction, the catalyst was removed by washing with water, decolorized using activated clay, and further deodorized to obtain a transesterified oil and fat.
エステル交換に用いたラウリン系油脂、パーム系油脂を以下に示す。
ラウリン系油脂
パーム核極度硬化油:ラウリン酸含有量45.7質量%(ヨウ素価2)
パーム核油:ラウリン酸含有量45.7質量%(ヨウ素価18)
パーム系油脂
パーム油:C16以上の脂肪酸含有量97.9質量%(ヨウ素価53)
パーム極度硬化油:C16以上の脂肪酸含有量97.9質量%(ヨウ素価2)
パーム分別軟質油:C16以上の脂肪酸含有量97.7質量%(ヨウ素価56)
The lauric oil and palm oil used for the transesterification are shown below.
Laurin oil and fat Palm core extremely hardened oil: lauric acid content 45.7% by mass (iodine value 2)
Palm kernel oil: lauric acid content 45.7% by mass (iodine value 18)
Palm oil / fat Palm oil: C16 or higher fatty acid content 97.9% by mass (iodine value 53)
Palm extremely hardened oil: C7.9 or higher fatty acid content 97.9% by mass (iodine value 2)
Palm fractionated soft oil: C16 or higher fatty acid content 97.7% by mass (iodine value 56)
得られたエステル交換油脂1〜6の分析結果を表1に示す。 The analysis results of the obtained transesterified fats and oils 1 to 6 are shown in Table 1.
(油脂組成物)
表2と表3に示す配合比にて各油脂を配合し、70℃で溶解後、均一に撹拌しコーティング用油脂組成物を得た。
(Oil composition)
Each fat / oil was blended at the blending ratio shown in Table 2 and Table 3, dissolved at 70 ° C., and stirred uniformly to obtain an oil / fat composition for coating.
(3)評価
実施例及び比較例の各試料について次の評価を行った。
(クラッカーの作製)
以下の配合でクラッカーを作製した。あらかじめ水に炭酸アンモニウム、重曹を別々に溶かして、その後全材料を合わせ低速1分、中高速8分ミキシングし、40℃のホイロで約2時間おき、生地を得た。その後生地を9層折りし、2mm厚で型抜きし、220℃で焼成し、クラッカーを得た。
(3) Evaluation The following evaluation was performed about each sample of an Example and a comparative example.
(Production of crackers)
A cracker was prepared with the following composition. Ammonium carbonate and baking soda were separately dissolved in water in advance, and then all the ingredients were combined and mixed at a low speed of 1 minute and at a medium high speed of 8 minutes. Thereafter, the dough was folded into 9 layers, punched out at a thickness of 2 mm, and fired at 220 ° C. to obtain a cracker.
上記焼成したクラッカーにコーティング用油脂組成物をスプレーで噴霧することによって、上記焼成したクラッカーの質量に対してコーティング用油脂組成物が12〜14質量%となるようにコーティング用油脂組成物を塗布した。
〈クラッカーの配合〉
薄力粉 100質量部
グラニュー糖 8質量部
ショートニング※1 20質量部
脱脂粉乳 2質量部
食塩 1質量部
炭酸アンモニウム 3質量部
重曹 1質量部
パパイン 0.025質量部
温水 30質量部
※1 ショートニング:ミヨシ油脂製「ミヨシショートニングZ」
The coating oil composition was applied to the fired cracker by spraying the coating oil composition with a spray so that the coating oil composition was 12 to 14% by mass relative to the mass of the fired cracker. .
<Combination of crackers>
Soft flour 100 parts by weight Granulated sugar 8 parts by weight Shortening * 1 20 parts by weight Nonfat dry milk 2 parts by weight Salt 1 part by weight Ammonium carbonate 3 parts by weight Baking soda 1 part by weight Papain 0.025 parts by weight Hot water 30 parts by weight * 1 Shortening: made by Miyoshi Oil & Fats "Miyoshi Shortening Z"
[作業性]
コーティング用油脂組成物をスプレーで噴霧する際の作業性(ノズルの目詰まり)を以下の基準で評価した。
評価基準
◎:目詰まりなく噴霧できる。
○:ほとんど目詰まりなく噴霧できる。
△:時々目詰まりを生じる。
×:目詰まりが多い。
[Workability]
Workability (nozzle clogging) when spraying the oil composition for coating with a spray was evaluated according to the following criteria.
Evaluation Criteria A : Can be sprayed without clogging.
○: Can be sprayed with almost no clogging.
Δ: Clogging occurs occasionally.
X: There is much clogging.
[固化性]
クラッカーにコーティング用油脂組成物を噴霧した後、20℃で10分保管し、その後の表面のベタツキ状態により固化性を以下の基準で評価した。
評価基準
◎:全くベタツキがない
○:ほとんどベタツキがない。
△:若干ベタツキがある。
×:ベタツキがある。
[Solidification]
After spraying the coating oil or fat composition on the cracker, it was stored at 20 ° C. for 10 minutes, and the solidification property was evaluated according to the following criteria based on the subsequent sticky state of the surface.
Evaluation standard ◎: No stickiness
○: Almost no stickiness.
Δ: Slightly sticky
X: There is stickiness.
[経時によるベタツキ]
クラッカーにコーティング用油脂組成物を噴霧した後、20℃で1週間保管し、その後のベタツキを以下の基準で評価した。
評価基準
◎:全くベタツキがない。
○:ほとんどベタツキがない。
△:若干ベタツキがある。
×:ベタツキがある。
[Stickness over time]
After spraying the oil composition for coating on the cracker, it was stored at 20 ° C. for 1 week, and the subsequent stickiness was evaluated according to the following criteria.
Evaluation standard (double-circle): There is no stickiness at all.
○: Almost no stickiness.
Δ: Slightly sticky
X: There is stickiness.
[口溶け]
コーティング用油脂組成物を塗布して得たクラッカーの口溶けをパネル20名により以下の基準で評価した。
評価基準
◎:20名中16名以上が良好と評価した。
○:20名中10名〜15名が良好と評価した。
△:20名中6名〜9名が良好と評価した。
×:20名中5名以下が良好と評価した。
[Melting mouth]
The cracking of the cracker obtained by applying the oil composition for coating was evaluated by the following 20 standards based on the following criteria.
Evaluation criteria A : 16 or more out of 20 evaluated as good.
○: 10 to 15 out of 20 evaluated as good.
(Triangle | delta): Six to nine persons evaluated that 20 persons were favorable.
X: 5 or less out of 20 evaluated as good.
以上の評価の結果を表4と表5に示す。また油脂組成物の分析値も表4と表5に併せて示した。 The results of the above evaluation are shown in Tables 4 and 5. The analytical values of the oil and fat composition are also shown in Tables 4 and 5.
Claims (5)
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017099351A (en) * | 2015-12-03 | 2017-06-08 | ミヨシ油脂株式会社 | Oil and fat composition for coating |
JP2018093842A (en) * | 2016-12-16 | 2018-06-21 | 日清オイリオグループ株式会社 | Wash-free rice and method for producing the same |
JP2020162512A (en) * | 2019-03-29 | 2020-10-08 | 不二製油株式会社 | Fat composition for covering |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09285255A (en) * | 1996-04-24 | 1997-11-04 | Fuji Oil Co Ltd | Additive composition for hard butter and production of hard butter |
JP2010144158A (en) * | 2008-12-22 | 2010-07-01 | Nisshin Oillio Group Ltd | Fat, and method for production of fat |
JP2012152113A (en) * | 2011-01-24 | 2012-08-16 | Adeka Corp | Oil and fat composition for coating |
WO2013051388A1 (en) * | 2011-10-05 | 2013-04-11 | 日清オイリオグループ株式会社 | Oil or fat composition, bakery food using oil or fat composition, and composite food using bakery food |
-
2014
- 2014-01-22 JP JP2014009845A patent/JP6466062B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09285255A (en) * | 1996-04-24 | 1997-11-04 | Fuji Oil Co Ltd | Additive composition for hard butter and production of hard butter |
JP2010144158A (en) * | 2008-12-22 | 2010-07-01 | Nisshin Oillio Group Ltd | Fat, and method for production of fat |
JP2012152113A (en) * | 2011-01-24 | 2012-08-16 | Adeka Corp | Oil and fat composition for coating |
WO2013051388A1 (en) * | 2011-10-05 | 2013-04-11 | 日清オイリオグループ株式会社 | Oil or fat composition, bakery food using oil or fat composition, and composite food using bakery food |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017099351A (en) * | 2015-12-03 | 2017-06-08 | ミヨシ油脂株式会社 | Oil and fat composition for coating |
JP2018093842A (en) * | 2016-12-16 | 2018-06-21 | 日清オイリオグループ株式会社 | Wash-free rice and method for producing the same |
JP2020162512A (en) * | 2019-03-29 | 2020-10-08 | 不二製油株式会社 | Fat composition for covering |
JP7346875B2 (en) | 2019-03-29 | 2023-09-20 | 不二製油株式会社 | Coating oil and fat composition |
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