JP2015129260A - Material for soil - Google Patents

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JP2015129260A
JP2015129260A JP2014236139A JP2014236139A JP2015129260A JP 2015129260 A JP2015129260 A JP 2015129260A JP 2014236139 A JP2014236139 A JP 2014236139A JP 2014236139 A JP2014236139 A JP 2014236139A JP 2015129260 A JP2015129260 A JP 2015129260A
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soil
waste
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sludge
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JP5800259B2 (en
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真輝 川谷
Masaki Kawatani
真輝 川谷
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TOWA SPORTS SHISETSU KK
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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Abstract

PROBLEM TO BE SOLVED: To provide an inexpensive material for soil utilizing waste and being superior in water permeability, water holding and safety.SOLUTION: A material for soil is provided that contains porous inorganic scraps of which particle size is not more than 30 mm and which consists of at least one of crushed waste roof tiles, crushed waste ceramics and crushed waste bricks, and a compaction material of which particle size is not more than 30 mm. The compaction material can contain at least one of waterworks sludge, paper sludge, polymer and bamboo scraps, or at least one of ground waste roof tiles, ground waste bricks, gypsum scraps, crushed stone (sand) powder and screenings of which particle size is not more than 0.075 mm. Besides, a soil improvement method is provided that blends the material for soil with existing soil.

Description

本発明は、廃棄物を利用した土壌用資材に関する。   The present invention relates to a soil material using waste.

一般廃棄物や産業廃棄物の量は年々増加しており、これら廃棄物の処分場や埋め立て地の不足が大きな問題となっている。このような問題を解決するため、従来より廃棄物を有効に活用する方法が考えられており、その一つに廃棄物を利用した土壌用資材の開発がある。土壌用資材は、運動場、競技場、競馬場、公園等の土壌(グラウンド用土壌)や、野菜や果樹、園芸植物の栽培用土壌(植栽用土壌)として、既存の土壌に混ぜ込んで、あるいは単独で使用される。そのため、土壌用資材にはそれ自身が保水性や透水性、保肥性といった土壌特性を有することはもちろん、既存の土壌が有する土壌特性を改良する機能が要求される。   The amount of general waste and industrial waste is increasing year by year, and the shortage of disposal sites and landfills for these wastes is a major problem. In order to solve such a problem, a method of effectively using waste has been conventionally considered, and one of them is development of a material for soil using waste. Soil materials are mixed with existing soil as soil (ground soil) for athletic fields, stadiums, racetracks, parks, etc., or as soil for cultivating vegetables, fruit trees and garden plants (planting soil) Or it is used alone. For this reason, the soil material is required not only to have soil properties such as water retention, water permeability and fertilizer, but also to have a function of improving the soil properties of existing soil.

例えば特許文献1には、一般廃棄物・産業廃棄物の溶融スラグ、浄水スラッジ(浄水汚泥)、紙・プラスチックの焼却灰や家畜糞尿の燃焼灰等、様々な廃棄物を利用した土壌用資材(緑化資材)が開示されている。同文献では、原料となる廃棄物を適宜の大きさに破砕して粒度調整したり、バインダー成分を添加したりすることにより土壌用資材の保水性や透水性を高めている。また、配合する廃棄物の種類や割合を調整したり肥料成分を添加したりすることにより、土壌用資材に保肥性を付加している。   For example, Patent Document 1 discloses soil materials that use various wastes such as molten slag of general waste and industrial waste, purified water sludge, incinerated ash of paper and plastic, and combustion ash of livestock manure ( Greening materials) are disclosed. In this document, the water retention and water permeability of the soil material are enhanced by crushing the waste as a raw material to an appropriate size and adjusting the particle size, or by adding a binder component. Moreover, the fertilizer is added to the soil material by adjusting the type and ratio of the waste to be blended or adding a fertilizer component.

さらに、特許文献1では、土壌用資材の安全性を高めるため、水や酸性液を用いて廃棄物を洗浄するようにしている。廃棄物によっては、毒性の強い成分を含むものや強アルカリ性を示すものがあるため、洗浄処理を施すことにより、廃棄物の毒性を緩和したりpH値を調整したりしている。   Furthermore, in patent document 1, in order to improve the safety | security of the material for soil, it wash | cleans waste materials using water or an acidic liquid. Since some wastes contain highly toxic components and others show strong alkalinity, the toxicity of the waste is reduced or the pH value is adjusted by performing a cleaning treatment.

特開2007-306844号公報JP 2007-306844

農林水産省ホームページ,"土壌の物理性の測定",[online],[平成26年11月12日検索],インターネット<URL:http://www.maff.go.jp/j/seisan/kankyo/hozen_type/h_sehi_kizyun/pdf/gum23.pdf>Ministry of Agriculture, Forestry and Fisheries homepage, "Measurement of soil physical properties", [online], [Search on November 12, 2014], Internet <URL: http://www.maff.go.jp/j/seisan/kankyo /hozen_type/h_sehi_kizyun/pdf/gum23.pdf>

このような洗浄処理を行うためには、多くの洗浄水が必要になる他、洗浄用の設備が必要になる。また、手間や時間が掛かる。このため、せっかく廃棄物を利用しているにもかかわらず、その製造コストを抑えることができないという問題があった。
本発明が解決しようとする課題は、透水性、保水性及び安全性に優れ、且つ、安価な、廃棄物を利用した土壌用資材を提供することである。
In order to perform such a cleaning process, not only a large amount of cleaning water is required, but also a cleaning facility is required. Also, it takes time and effort. For this reason, there was a problem that the manufacturing cost could not be suppressed despite the fact that waste was used.
The problem to be solved by the present invention is to provide a soil material using waste, which is excellent in water permeability, water retention and safety, and inexpensive.

上記課題を解決するために成された本発明の第1態様に係る土壌用資材は、
a) 廃瓦破砕材、廃陶磁器破砕材、及び廃レンガ破砕材のうちの少なくとも一種類からなる、粒度が30mm以下の多孔質無機廃材と、
b) 粒度が30mm以下の締め固め材と
を含むことを特徴とする。
The material for soil which concerns on the 1st aspect of this invention made in order to solve the said subject,
a) a porous inorganic waste material having a particle size of 30 mm or less, comprising at least one of waste tile crushing material, waste ceramic crushing material, and waste brick crushing material;
b) It is characterized by including a compacting material having a particle size of 30 mm or less.

多孔質無機廃材である廃瓦破砕材、廃陶磁器破砕材、廃レンガ破砕材は、いずれも保水性を有するため、これら多孔質無機廃材を含むことにより本発明の土壌用資材は保水性に優れる。また、多孔質無機廃材の粒度を適宜調整することにより、土壌用資材の保水機能や透水機能を調整することができる。   Since all of the porous inorganic waste materials, such as waste tile crushing material, waste ceramic crushing material and waste brick crushing material, have water retention, the soil material of the present invention is excellent in water retention by including these porous inorganic waste materials. . Moreover, the water retention function and water permeability function of the soil material can be adjusted by appropriately adjusting the particle size of the porous inorganic waste material.

上記廃瓦破砕材には、粘土を混練、成形、焼成した粘土瓦の廃材を用いることが好ましく、粘土瓦であれば釉薬瓦、いぶし瓦、無釉瓦のいずれでも良い。また、瓦チップとして一般に市販されている瓦廃材の破砕材を用いると良い。前記瓦チップは、0.01〜3mm、0.01〜5mm、5〜13mm、10〜30mmの粒度に予め調整されており、適宜の粒度のものを用いることができる。
廃陶磁器破砕材には、比較的孔隙径が大きい陶器又は磁器を用いることが好ましく、釉薬の有無は問わない。
廃レンガ破砕材には、粘土や頁岩、泥等の材料を成形し窯で焼き固めたもの、あるいは材料を圧縮成形したもの、いずれのタイプのレンガを用いても良い。
As the waste tile crushing material, it is preferable to use a clay tile waste material obtained by kneading, molding, and firing clay. As long as the clay tile is used, any of glaze tile, smoldering tile, and non-glazed tile may be used. Moreover, it is good to use the crushing material of the tile waste material generally marketed as a tile chip | tip. The tile chips are preliminarily adjusted to particle sizes of 0.01 to 3 mm, 0.01 to 5 mm, 5 to 13 mm, and 10 to 30 mm, and those having an appropriate particle size can be used.
It is preferable to use pottery or porcelain having a relatively large pore diameter as waste ceramic crushing material, regardless of whether glaze is present.
As the waste brick crushing material, any type of brick, such as clay, shale, mud, etc., molded and baked in a kiln, or compression molded material is used.

上記締め固め材は、例えば、浄水スラッジ、ペーパースラッジ、高分子ポリマー、及び竹廃材のうちの少なくとも一種類を含むものとすることができる。   The compaction material may include, for example, at least one of water purification sludge, paper sludge, polymer polymer, and bamboo waste material.

浄水スラッジは、浄水場において汚濁水に凝集剤を投入して汚濁成分の一つであるリンを吸着させた結果得られる沈澱物であり、肥料の三大要素の一つであるリンを含む。また、保水性に優れる。浄水スラッジは非常に小さい粒度のものから30mm程度のものまで種々の粒度のものを用いることができる。
ペーパースラッジは、製紙工程において発生する廃棄物であり、浄水スラッジ同様に保水性に優れ、種々の粒度のものを用いることができる。
高分子ポリマーは、例えば、ポリビニルアルコール、ポリエチレングリコール、ポリアクリル酸ナトリウム等の水溶性樹脂を架橋した親水性架橋高分子であり、特に、ポリアクリル酸ナトリウムを架橋した水溶性アクリル酸重合体を好適に用いることができる。これらは従来から土壌用保水剤や紙おむつ、ペットシートなどに利用されており、水分を吸収すると数十倍に膨張する性質を有する。膨張後の大きさを考慮すると吸水性高分子ポリマー粒の大きさは1mm程度か、あるいはそれ以下であることが好ましい。また、高分子ポリマーとして、無機凝集材である硫酸アルミニウム(硫酸バンド)やポリ塩化アルミニウム(PAC)を用いることもできる。これらは上水道用水、下水道排水、あるいは工業排水の処理に用いられる凝集材であり、被処理懸濁液中の微粒子や浮遊物が付着して沈降するという機能性を有するため、土壌の団粒化を促進する効果も得ることができる。
竹廃材は、竹林の伐採によって大量に発生する廃材である。竹廃材には、土壌を締め固める効果に加え、雑草の生育を抑える効果もある。従って、竹廃材を用いると防草効果も得ることができ、例えば土グラウンド用土壌や芝生グラウンド用土壌用の資材、歩道用の資材として好適に用いることができる。
本発明では、多孔質無機廃材に加えて上記の締め固め材を含むため、保水性や保肥性に優れた土壌用資材を得ることができる。
The purified water sludge is a precipitate obtained as a result of adsorbing phosphorus, which is one of the pollutant components, by adding a flocculant into the contaminated water at the water purification plant, and contains phosphorus, which is one of the three major elements of fertilizer. Moreover, it is excellent in water retention. The purified water sludge having various particle sizes from very small to 30 mm can be used.
Paper sludge is a waste generated in the papermaking process, and has excellent water retention like purified water sludge and can be of various particle sizes.
The high molecular polymer is, for example, a hydrophilic cross-linked polymer obtained by cross-linking a water-soluble resin such as polyvinyl alcohol, polyethylene glycol or sodium polyacrylate, and a water-soluble acrylic acid polymer obtained by cross-linking sodium polyacrylate is particularly preferable. Can be used. These are conventionally used for soil water retention agents, disposable diapers, pet sheets, and the like, and have the property of expanding several tens of times when they absorb moisture. Considering the size after expansion, the size of the water-absorbing polymer particles is preferably about 1 mm or less. Further, as the polymer, inorganic aggregates such as aluminum sulfate (sulfate band) and polyaluminum chloride (PAC) can be used. These are agglomerates used for the treatment of water for sewage water, sewage effluents, or industrial effluents, and have the functionality that fine particles and suspended solids in the suspension to be treated adhere and settle, so that the soil is agglomerated. The effect which promotes can also be acquired.
Bamboo waste is a waste material generated in large quantities by logging a bamboo forest. In addition to the effect of compacting soil, bamboo waste has the effect of suppressing the growth of weeds. Therefore, when bamboo waste material is used, a herbicidal effect can also be obtained. For example, it can be suitably used as materials for soil for soil ground, soil for lawn ground, and materials for sidewalks.
In the present invention, since the compaction material is included in addition to the porous inorganic waste material, a soil material having excellent water retention and fertilization properties can be obtained.

また、上記締め固め材は、例えば、粒度が0.075mm以下の廃瓦磨砕材、廃レンガ磨砕材、砕石粉(砂粉)、及びスクリーニングスのうちの少なくとも一種類を含むものとすることもできる。   In addition, the compacting material may include, for example, at least one of waste tile grinding material having a particle size of 0.075 mm or less, waste brick grinding material, crushed stone powder (sand powder), and screenings. .

廃瓦や廃レンガを破砕すると様々な粒径の資材が得られる。その中でも、磨砕材と呼ばれる0.075mm以下の微粒子(シルト・粘土分)は上記多孔質無機廃材の隙間に入り込むため、締め固め材として好適に用いることができる。
石こう廃材は、建造物の新築や解体時に廃棄される石こうボードを破砕・粉砕した後、紙を分離したものである。石こう廃材は硫酸カルシウムを主たる成分とする石こうの廃棄物であるため、カルシウムを多く含む土壌用資材が得られる。土壌に対するカルシウムの吸着特性はナトリウムの吸着特性よりも高いため、ナトリウムを多く含むアルカリ性の土壌に適用すれば、土壌中からナトリウムを排出して中性あるいは弱アルカリ性土壌に改質することができる。
砕石(砂)粉は、採石場、砕石場、製砂場等で砕石を洗浄するなどの湿式処理時に発生する廃材で、粒径が極めて細かい砂質系の微粒子である。スクリーニングスは、破砕した岩石やスラグなどをふるいにかけて粒径が整えられたものである。石こう廃材、砕石粉、及びスクリーニングスはいずれも低コストのシルト原料であり、土壌用資材に締め固め機能を付与することができる。
By crushing waste tiles and waste bricks, materials with various particle sizes can be obtained. Among them, fine particles (silt / clay) of 0.075 mm or less called grinding material enter the gaps in the porous inorganic waste material, and can be suitably used as a compacting material.
The gypsum waste material is obtained by crushing and crushing gypsum board that is discarded when building is newly constructed or demolished, and then separating the paper. Since the gypsum waste material is a gypsum waste mainly composed of calcium sulfate, a soil material containing a large amount of calcium can be obtained. Since the adsorption property of calcium to soil is higher than the adsorption property of sodium, when applied to alkaline soil containing a large amount of sodium, sodium can be discharged from the soil and modified to neutral or weakly alkaline soil.
Crushed stone (sand) powder is a waste material generated during wet processing such as washing crushed stone in a quarry, a quarry, a sand mill, etc., and is a fine sandy particle having a very small particle size. The screenings are prepared by sieving crushed rocks or slags to adjust the particle size. Gypsum waste, crushed stone powder, and screenings are all low-cost silt raw materials and can impart a compacting function to soil materials.

本発明の土壌用資材には、防霜材として塩材を含めることができる。これにより、寒冷地での使用に適した土壌用資材とすることができる。   The soil material of the present invention can contain a salt material as a defrosting material. Thereby, it can be set as the soil material suitable for use in a cold region.

本発明の土壌用資材には、間伐材、浄水スラッジ、及びペーパースラッジのうちの少なくとも一種類からなる肥料材が含まれていることが好ましい。このような肥料材を含む土壌用資材は、特に植栽用土壌のための資材として好適に用いることができる。   It is preferable that the soil material of the present invention contains a fertilizer material consisting of at least one of thinned wood, purified water sludge, and paper sludge. Soil materials containing such fertilizer materials can be suitably used as materials for planting soils in particular.

本発明の土壌用資材には、間伐材、蛎殻、ホタテ殻、及び軽石のうちの少なくとも一種類を破砕・粉砕したものからなる保水材が含まれていることが好ましい。これらの保水材はいずれも土壌の保水性や調湿性を高める機能性を有する。特に、蛎殻やホタテ殻を配合すれば、路盤材の凍結を防止し、雑草の生育を抑制することもできる。また、軽石は内部に多くの気孔を有しており、保水性や調湿性に加え、保肥性や排水性を高めることもできる。軽石には、例えばカガライト(製品名。カガライト工業株式会社)を用いることができる。   The soil material of the present invention preferably contains a water retention material made of crushed and pulverized at least one of thinned wood, rice husk, scallop shell, and pumice. All of these water retention materials have the functionality of enhancing the water retention and humidity control properties of the soil. In particular, if rice husk or scallop husk is blended, the roadbed material can be prevented from freezing and weed growth can be suppressed. Moreover, pumice has many pores inside, and in addition to water retention and humidity control, it can also enhance fertilizer and drainage. As the pumice, for example, kagalite (product name: Kagalite Kogyo Co., Ltd.) can be used.

本発明の土壌用資材には、平均粒径が0.01〜10mmの真砂土、赤土(関東ローム層)、及び黒土のうちの少なくとも一種類を含めることができる。これにより、資材全体の粒度等を調整し、保水性や透水性、硬度等を適宜に設定することができる。   The soil material of the present invention can include at least one of pure sand soil having an average particle diameter of 0.01 to 10 mm, red soil (Kanto loam layer), and black soil. Thereby, the particle size etc. of the whole material can be adjusted and water retention, water permeability, hardness, etc. can be set suitably.

また、既存土に上述した土壌用資材を配合することにより土壌を改良することができる。本発明の土壌改良方法を用いることにより、現地土や天然土といった既存土を有効利用しつつ土壌を改良することができる。   Moreover, soil can be improved by mix | blending the material for soil mentioned above with the existing soil. By using the soil improvement method of the present invention, it is possible to improve the soil while effectively using existing soil such as local soil and natural soil.

本発明に係る土壌用資材は廃棄物を主たる材料とする。そのうち、廃瓦破砕材、廃陶磁器破砕材、廃レンガ破砕材は、多孔質無機廃材であり保水性を有する。これらの多孔質無機廃材は適宜の粒度を調整することにより、土壌用資材の保水機能及び透水機能を調整することができる。また、上記の多孔質無機廃材は一般廃棄物や産業廃棄物と異なり安全性に優れ、pH値を調整したり毒性を緩和したりするための処理が不要であるため、製造コストを低く抑えることができる。   The soil material according to the present invention is mainly waste. Among them, waste tile crushing material, waste ceramic crushing material, and waste brick crushing material are porous inorganic waste materials and have water retention. These porous inorganic waste materials can adjust the water retention function and water permeability function of the soil material by adjusting the appropriate particle size. In addition, unlike the general waste and industrial waste, the above porous inorganic waste materials are excellent in safety and do not require treatment for adjusting the pH value or mitigating toxicity. Can do.

本発明の土壌用資材を用いた芝のハウス栽培における生育量の実験結果を示すグラフ。The graph which shows the experimental result of the growth amount in the house cultivation of the turf using the soil material of this invention. 本発明の土壌用資材を用いた芝の露地栽培における生育量の実験結果を示すグラフ。The graph which shows the experimental result of the growth amount in the open field cultivation of the turf using the soil material of this invention. 本発明の土壌用資材の硬度試験結果を示すグラフ。The graph which shows the hardness test result of the material for soils of this invention. 本発明の土壌用資材の防草効果試験における区画の配置と使用土壌の配合を示す図。The figure which shows the arrangement | positioning of the division in the herbicidal effect test of the soil material of this invention, and the mixing | blending of use soil. 本発明の土壌用資材を用いた土壌改良方法の工程を説明する図。The figure explaining the process of the soil improvement method using the soil material of this invention.

本発明に係る土壌用資材は、廃瓦破砕材、廃陶磁器破砕材、廃レンガ破砕材のうちの少なくとも一種類からなる粒度が30mm以下の多孔質無機廃材と、粒度が30mm以下の締め固め材を含む。
本発明に係る土壌用資材は、多孔質無機廃材である廃瓦破砕材、廃陶磁器破砕材、廃レンガ破砕材のいずれかを含み、かつその粒度が30mm以下に調整されているため保水性、透水性に優れる。上記の多孔質性無機廃材は、一般廃棄物及び産業廃棄物の溶融スラグ等その他の廃棄物に比べると毒性が低く、また、その溶出液のpH値も植物の生育に悪影響を及ぼすような値ではないため、安全性にも優れた土壌用資材となる。
The soil material according to the present invention includes a porous inorganic waste material having a particle size of 30 mm or less and a compacting material having a particle size of 30 mm or less, consisting of at least one of waste tile crush material, waste ceramic crush material, and waste brick crush material. including.
The material for soil according to the present invention includes any one of waste tile crushing material, waste ceramic crushing material, waste brick crushing material, which is a porous inorganic waste material, and its particle size is adjusted to 30 mm or less, so that water retention is achieved. Excellent water permeability. The porous inorganic waste material is less toxic than other wastes such as general waste and industrial waste molten slag, and the pH value of the eluate is also a value that adversely affects the growth of plants. Therefore, it is a soil material with excellent safety.

また、本発明に係る土壌用資材に用いる締め固め材は、浄水スラッジ、ペーパースラッジ、高分子ポリマー、及び竹廃材のうちの少なくとも一種類を含むものとすることができる。あるいは、締め固め材を、粒度が0.075mm以下の廃瓦磨砕材、廃レンガ磨砕材、石こう廃材、砕石粉、及びスクリーニングスのうちの少なくとも一種類を含むものとしてもよい。廃瓦や廃レンガの磨砕材は、これらを破砕したときに同時に得られる資材であり、粒子同士が擦れあって生じるシルト分である。また、石こう廃材、砕石粉、スクリーニングスも同様に廃材の破砕時に発生するシルト分である。   Moreover, the compacting material used for the soil material according to the present invention may include at least one of purified water sludge, paper sludge, polymer polymer, and bamboo waste material. Alternatively, the compacting material may include at least one of waste tile grinding material having a particle size of 0.075 mm or less, waste brick grinding material, gypsum waste material, crushed stone powder, and screenings. Waste tiles and waste brick grinding materials are materials obtained at the same time when they are crushed, and are silt parts produced by rubbing particles. Similarly, gypsum waste, crushed stone powder, and screenings are silt components that are generated when the waste is crushed.

本発明に係る土壌用資材は、グラウンド用土壌、植栽用土壌、舗装用の路盤材、歩道用資材等、様々な土壌に適用することができ、適用対象に応じた適宜の材料を多孔質無機廃材に付加することができる。
例えば、土や芝生のグラウンド用土壌、舗装用の路盤材、あるいは歩道用資材として用いる場合は、上述した締め固め材の組み合わせや配合量によって、資材の硬度を適宜に調整することができる。
グラウンド用土壌に適用される土壌用資材には、過度な踏圧に対する土壌構造(団粒構造や土壌粒子間の間隙)の劣化を改良する機能が求められる。浄水スラッジ、ペーパースラッジ、及び高分子ポリマー粒はいずれも団粒化し易いため、これらを締め固め材に含めれば過度な踏圧に対する土壌構造の劣化改良機能を有する土壌用資材が得られる。
ここで、団粒化、あるいは団粒構造とは、土壌粒子が陽イオンや粘土鉱物、有機物(腐植)などのはたらきによって結合し、小粒の集合体(団粒)となった状態をいう。団粒構造が発達した土は、団粒の内部に微細な団粒内間隙が、団粒の外部に団粒間間隙(非毛管孔隙)ができるため、透水性、弾力性、保水性に優れる。従って、浄水スラッジ又は高分子ポリマー粒を含む土壌用資材は透水性、弾力性、保水性にも優れる。
また、本発明の土壌用資材をグラウンド用土壌や歩道用資材として用いる場合には、締め固め材に竹廃材を含めることにより、防草性を有する土壌用資材を得ることができる。
The soil material according to the present invention can be applied to various soils such as ground soil, planting soil, pavement roadbed material, sidewalk material, etc., and an appropriate material according to the application target is porous. It can be added to inorganic waste materials.
For example, when used as soil for ground of soil or lawn, roadbed material for pavement, or material for sidewalks, the hardness of the material can be appropriately adjusted depending on the combination and blending amount of the above-described compacting materials.
The soil material applied to the ground soil is required to have a function of improving the deterioration of the soil structure (aggregate structure or gap between soil particles) against excessive treading pressure. Since all of the purified water sludge, the paper sludge, and the polymer polymer particles are easily aggregated, if they are included in the compacting material, a soil material having a function of improving the deterioration of the soil structure against excessive treading pressure can be obtained.
Here, agglomeration, or agglomeration structure, refers to a state in which soil particles are combined by the action of a cation, clay mineral, organic matter (humus), or the like to form an aggregate (aggregate) of small particles. Soil with a developed aggregate structure is excellent in water permeability, elasticity, and water retention because a fine intergranular gap is formed inside the aggregate and an inter-aggregate gap (non-capillary pore) is formed outside the aggregate. . Therefore, the soil material containing purified water sludge or polymer polymer particles is excellent in water permeability, elasticity, and water retention.
Moreover, when using the soil material of this invention as a soil for grounds or a material for sidewalks, the soil material which has a herbicidal property can be obtained by including bamboo waste material in the compacting material.

本発明の土壌用資材を植栽用土壌として用いる場合にも、上述した団粒構造を有するように、締め固め材に浄水スラッジ、ペーパースラッジ、及び高分子ポリマー粒のいずれかを含めておくことが好ましい。これにより、土壌内部の団粒間に大きな孔げきを、団粒内部に小さな孔げきを形成して土壌微生物や土壌小生物の活動を活性化し、植物等の生育に必要な栄養素が多く生成されるように環境を整えることができる。これらの中でも、特に高分子ポリマー粒の一種である無機凝集材である硫酸アルミニウム(硫酸バンド)やポリ塩化アルミニウム(PAC)を用いることにより土壌をより多く団粒化させることができる。
また、締め固め材に浄水スラッジを含めておくと、植物の生育に必要な肥料成分の一つであるリンを含む土壌用資材を得ることができる。さらに、多孔質無機廃材や締め固め材とは別に森林の間伐により発生する間伐材を適宜の粒度に調整したものを含めることによっても、肥料成分を含む土壌用資材を得ることができる。
Even when the soil material of the present invention is used as planting soil, the compacted material should contain either purified water sludge, paper sludge, or polymer polymer particles so as to have the aggregate structure described above. Is preferred. As a result, large pores are formed between the aggregates inside the soil, and small pores are formed inside the aggregates to activate the activities of soil microorganisms and soil small organisms, and many nutrients necessary for the growth of plants and the like are generated. The environment can be arranged as follows. Among these, more soil can be agglomerated by using aluminum sulfate (sulfate band) or polyaluminum chloride (PAC), which is an inorganic agglomerate which is a kind of polymer polymer particles.
In addition, when purified water sludge is included in the compacting material, a soil material containing phosphorus, which is one of the fertilizer components necessary for plant growth, can be obtained. Furthermore, the material for soil containing a fertilizer component can be obtained also by including what adjusted the thinning material produced | generated by the thinning of a forest to the appropriate particle size separately from a porous inorganic waste material and a compacting material.

浄水スラッジ、ペーパースラッジ、及び高分子ポリマー粒は保水性を有するため、これらを締め固め材に含めることでヒートアイランド抑制作用に優れた土壌用資材が得られ、植栽用土壌では、肥料効果も向上する。また、乾燥防止効果を有するため、散水量の低減、夏枯れ防止効果が得られる。
他にも、多孔質無機廃材や締め固め材とは別に塩材を含めておくことにより防霜性を持たせ、寒冷地での使用に適した土壌用資材を得ることができる。
また、間伐材、蛎殻、ホタテ殻、及び軽石のうちの少なくとも一種類を破砕・粉砕したものからなる保水材を含めることにより、さらに保水性を高めたり、調湿性を高めたりすることができる。特に、蛎殻やホタテ殻を配合すれば、路盤材の凍結を防止し、雑草の生育を抑制することもできる。また、軽石は内部に多くの気孔を有しており、保水性や調湿性に加え、保肥性や排水性を高めることもできる。軽石には、例えばカガライト(製品名。カガライト工業株式会社)を用いることができる。
Since water purification sludge, paper sludge, and high polymer particles have water retention properties, inclusion of these in the compaction material provides soil materials with excellent heat island control, and improves fertilizer effects in planting soils. To do. Moreover, since it has a dry prevention effect, it can reduce the amount of water spray and prevent summer withering.
In addition, by adding a salt material separately from the porous inorganic waste material and the compacting material, it is possible to obtain a frost-proof property and obtain a soil material suitable for use in a cold region.
In addition, by including a water retaining material made of crushed and crushed at least one of thinned wood, rice husk, scallop shell, and pumice, it is possible to further increase water retention and humidity control. . In particular, if rice husk or scallop husk is blended, the roadbed material can be prevented from freezing and weed growth can be suppressed. Moreover, pumice has many pores inside, and in addition to water retention and humidity control, it can also enhance fertilizer and drainage. As the pumice, for example, kagalite (product name: Kagalite Industry Co., Ltd.) can be used.

本発明に係る土壌用資材は、上記の他にも種々の材料を含めることにより、種々の機能を付加することができる。以下の表1及び表2に、グラウンド用土壌に利用可能な土壌用資材の配合成分の例及び配合パターンの例を示す。また、表1には一部の配合成分の好適な粒度範囲を示した。なお、粒度範囲に下限値を示していない(0mmが含まれる)が、これは、粒度が非常に小さくても良いことを示す。これらの成分は、個々の粒の粒度が非常に小さい場合でも複数の粒が塊状になって存在することにより保水性や通気性などの機能が得られることがあるためである。

Figure 2015129260
Figure 2015129260
The soil material according to the present invention can be added with various functions by including various materials in addition to the above. Tables 1 and 2 below show examples of blending components and blending patterns of soil materials that can be used for ground soil. Table 1 shows suitable particle size ranges for some of the blended components. In addition, although the lower limit is not shown in the particle size range (including 0 mm), this indicates that the particle size may be very small. This is because these components may have functions such as water retention and air permeability due to the presence of a plurality of grains in a lump even when the grain size of individual grains is very small.
Figure 2015129260
Figure 2015129260

また、植栽用土壌に利用可能な土壌用資材の配合成分を表3に、配合パターンの例を表4に示す。

Figure 2015129260
Figure 2015129260
Table 3 shows blending components of soil materials that can be used for planting soil, and Table 4 shows examples of blending patterns.
Figure 2015129260
Figure 2015129260

表1及び表3には、各成分の特性(効果)を併せて示す。表1及び表3の比較から明らかなように、グラウンド用土壌では、植栽用土壌に比べて締め固め機能、団粒化機能を有する材料が多く含まれる。また、廃瓦破砕材は保水性を有するため、本発明の土壌用資材を利用することにより、グラウンド用土壌は防塵性、ヒートアイランド抑制作用に優れる。植栽用土壌では、肥料効果が向上する。また、乾燥防止効果を有するため、散水量の低減、夏枯れ防止効果が得られる。また、廃瓦破砕材の粒度を調整することにより、グラウンド用土壌では透水性や締め固め度の調整が可能となる。
一方、廃瓦破砕材を用いることにより、植栽用土壌では、透水性、通気性が向上し、土壌の固化を防止できる。
Tables 1 and 3 also show the characteristics (effects) of each component. As is clear from the comparison of Tables 1 and 3, the ground soil contains a lot of materials having a compaction function and an aggregating function as compared with the soil for planting. Moreover, since the waste tile crushing material has water retention, by using the soil material of the present invention, the ground soil is excellent in dustproofness and heat island suppression action. In planting soil, the fertilizer effect is improved. Moreover, since it has a dry prevention effect, it can reduce the amount of water spray and prevent summer withering. Further, by adjusting the particle size of the waste tile crushing material, it is possible to adjust the water permeability and the degree of compaction in the ground soil.
On the other hand, by using waste tile crushing material, water permeability and air permeability are improved in the soil for planting, and solidification of the soil can be prevented.

次に、本発明に係る土壌用資材が植物の生育に及ぼす影響について調べる実験を行った。
この実験では、下記の表5に示す対照区、及びA〜C区に4種の芝生(ヒメコウライ、ティフトン、ベント、ケンタッキーブルーグラス)の種を蒔き、露地及びハウス内で所定期間栽培したときの生育量を調べた。対照区では、従来よりグラウンド用土壌や植栽用土壌として用いられている真砂土を用いた。
Next, an experiment was conducted to examine the influence of the soil material according to the present invention on the growth of plants.
In this experiment, when the seeds of four kinds of lawns (Himekourai, Tifton, Bent, Kentucky Bluegrass) were sown in the control plots shown in Table 5 and A to C plots, they were cultivated for a predetermined period in the open ground and house. The amount of growth was examined. In the control plot, sand sand soil which has been conventionally used as soil for ground and soil for planting was used.

Figure 2015129260
Figure 2015129260

生育量は、栽培終了後に各区内の芝を刈り取り、その重量(新鮮重)(g/m2)で表した。その結果を表6及び表7、並びに図1及び図2に示す。表6は3品種の芝のハウス栽培における生育量を示す表、図1は4品種の芝のうち「ベント」のハウス栽培における生育量を示すグラフである。一方、表7は4品種の芝の露地栽培における生育量を示す表、図2は「ベント」の露地栽培における生育量を示すグラフである。 The amount of growth was expressed in terms of weight (fresh weight) (g / m 2 ) after cutting the grass in each ward after cultivation. The results are shown in Tables 6 and 7, and FIGS. Table 6 is a table showing the amount of growth in house cultivation of three varieties of turf, and FIG. 1 is a graph showing the amount of growth in house cultivation of “Vent” among four varieties of turf. On the other hand, Table 7 is a table showing the amount of growth in open field cultivation of four varieties of turf, and FIG. 2 is a graph showing the amount of growth in open field cultivation of “Bent”.

Figure 2015129260
Figure 2015129260
Figure 2015129260
Figure 2015129260

表6、表7及び図1、図2に示すように、ハウス栽培では、ティフトン及びベントの生育量はA区で最も優れ、次にC区が良かった。また、ヒメコウライはA区及びC区の生育量は同じであった。一方、露地栽培では、ベントの生育量はA区で最も優れ、C区が次に優れていたが、それ以外の3品種はC区の生育量がもっとも優れ、A区の生育量が次に優れていた。さらに、ハウス栽培、露地栽培のいずれにおいても、対照区の生育量が最も悪かった。   As shown in Tables 6 and 7 and FIGS. 1 and 2, in house cultivation, the growth of Tifton and bent was the best in the A zone, and the C zone was the next best. Moreover, Himekourai had the same amount of growth in the A and C sections. On the other hand, in open-air cultivation, the bent growth was the best in the A ward, and the C ward was the next best, but the other three varieties had the highest growth in the C ward, and the A It was excellent. Furthermore, the growth of the control plot was the worst in both house cultivation and outdoor cultivation.

対照区とC区の土壌の透水係数を測定したところ、対照区の透水係数は0.049cm/s、C区の透水係数は0.652cm/sとなった。透水係数とは、土の中を水が移動する速度を数値化したものである。透水係数の測定結果から、本実施例の土壌用資材では、従来の土壌用資材に比べて10倍以上の透水性を有しており、根腐れを抑制する効果が高いといえる。   When the hydraulic conductivity of the soil in the control plot and C plot was measured, the hydraulic conductivity in the control plot was 0.049 cm / s, and the hydraulic conductivity in the plot C was 0.652 cm / s. The hydraulic conductivity is a numerical value of the speed at which water moves through the soil. From the measurement results of the hydraulic conductivity, it can be said that the soil material of the present example has a water permeability of 10 times or more compared with the conventional soil material, and the effect of suppressing root rot is high.

対照区とC区の土壌の三相分布を測定した結果を表8に示す。三相分布とは、土壌を構成する固相、液相、及び気相の割合を数値化したものである。

Figure 2015129260
対照区では固相が半分以上を占めているのに対し、C区では固相が27.6%にとどまっており、気相が42.0%を占めている。これにより、土壌内部の間隙が多く通気性が高いことが分かる。また、液相の割合もC区の方が高く、本実施例の土壌が保水性にも優れていることが分かる。 Table 8 shows the results of measuring the three-phase distribution of the soil in the control and C zones. The three-phase distribution is a numerical value of the ratio of the solid phase, liquid phase, and gas phase constituting the soil.
Figure 2015129260
In the control zone, the solid phase accounts for more than half, whereas in the C zone, the solid phase is only 27.6% and the gas phase accounts for 42.0%. Thereby, it turns out that there are many gaps inside soil and air permeability is high. Moreover, the ratio of the liquid phase is higher in the C section, and it can be seen that the soil of this example is excellent in water retention.

次に、配合材料及び配合比率を変えた種々の土壌用資材を作製し、これら土壌用資材の透水性及び保水性を調べる実験を行った。実験は、サンプルを、底面に20個程度の小さな通水孔を有する容器に該底面にろ紙を敷いた状態で入れ、上から水を注入したときの該水の通過時間、及び、注入した水量と通過した水量との差(ml)を測定し、それぞれを透水性及び保水性の指標とした。
まずは、土壌用資材の配合材料である真砂土、砂、廃瓦2種の透水性及び保水性を調べた。その結果を表9に示す。
Next, various soil materials with different blending materials and blending ratios were prepared, and experiments were conducted to examine the water permeability and water retention of these soil materials. In the experiment, the sample was placed in a container having about 20 small water passage holes on the bottom surface with filter paper on the bottom surface, and the water passage time when water was injected from above, and the amount of water injected The difference (ml) between the amount of water and the amount of water passed was measured, and each was used as an index of water permeability and water retention.
First, the water permeability and water retention of two kinds of pure sand, sand, and waste tiles, which are blended materials for soil, were examined. The results are shown in Table 9.

Figure 2015129260
Figure 2015129260

表9から分かるように、4種の中では廃瓦1(粒が細かいもの)の透水性が最も優れ、廃瓦2(粒が粗いもの)の保水性が最も優れていた。
次に、エコクレイ、エコクレイに廃瓦2を配合した土壌用資材(以下「エコクレイ瓦」という。)、エコクレイにカガライト(天然小粒軽石(流紋岩系天然硝子)の破砕物、カガライト工業株式会社)を配合した土壌用資材(以下「エコクレイTS」という。)を作製し、それらの透水性、保水性を調べた。その結果を表10に示す。なお、エコクレイは、東和スポーツ施設株式会社の商品名であり、真砂土、浄水スラッジを適宜の比率で配合した土壌用資材、又は真砂土、浄水スラッジ、砂等を適宜の比率で配合した土壌用資材である。表10に、各土壌用資材の配合材料及びその比率を示す。
As can be seen from Table 9, the water permeability of the waste tile 1 (having fine grains) was the best among the four types, and the water retention of the waste tile 2 (having coarse grains) was the best.
Next, Ecoclay, a material for soil containing waste clay 2 in Ecoclay (hereinafter referred to as “ecoclay tile”), kagarite in ecoclay (natural crushed pumice stone (Rhyolite natural glass), Kagalite Industrial Co., Ltd.) The material for soil which mix | blended (henceforth "eco clay TS") was produced, and those water permeability and water retention were investigated. The results are shown in Table 10. Eco-clay is a trade name of Towa Sports Facility Co., Ltd., and it is used for soil materials containing pure sand soil and purified water sludge at an appropriate ratio, or for soil containing natural sand soil, purified water sludge, sand, etc. at an appropriate ratio. It is a material. In Table 10, the compounding material of each soil material and its ratio are shown.

Figure 2015129260
Figure 2015129260

表10に示した結果を考察するために、表11にエコクレイ瓦1〜4の結果だけを取り出して示す。また、表12に真砂土を70%配合した土壌用資材の結果だけを取り出して示し、表13に真砂土を80%配合した土壌用資材の結果だけを取り出して示す。表11〜表13では、透水性、保水性に優れた順に順位を付け、その順位を表す数字を足し合わせた数値を総合評価の欄に示した。従って、数値が小さい方が総合評価が高いことを示す。   In order to consider the results shown in Table 10, only the results of the eco clay tiles 1 to 4 are taken out and shown in Table 11. Table 12 shows only the results of soil materials containing 70% pure sand soil, and Table 13 shows only the results of soil materials containing 80% true sand soil. In Tables 11 to 13, rankings are given in the order of excellent water permeability and water retention, and numerical values obtained by adding numbers representing the rankings are shown in the column for comprehensive evaluation. Therefore, the smaller the numerical value, the higher the overall evaluation.

Figure 2015129260
Figure 2015129260
Figure 2015129260
Figure 2015129260
Figure 2015129260
Figure 2015129260

表11〜表13から、必ずしも廃瓦を用いた土壌用資材が透水性、保水性に優れる結果は得られなかったが、廃瓦以外の種々の材料を配合することにより、透水性、保水性を高めることができることが分かった。   From Tables 11 to 13, it was not always possible to obtain the result that the soil material using waste tiles was excellent in water permeability and water retention, but by blending various materials other than waste tiles, water permeability and water retention were obtained. It was found that can be increased.

本発明に係る土壌用資材が有する、グラウンド用土壌としての特性を調べるための試験を行った。試験に使用した3種類の土壌は、従来土(真砂土100%)、エコクレイTS1’(真砂土70%、廃瓦15%、スラッジ15%)、及びエコクレイTS2’ (真砂土80%、廃瓦10%、スラッジ10%)である。   The test for investigating the characteristics of the soil material according to the present invention as the ground soil was conducted. The three types of soil used in the test were conventional soil (100% pure sand), Ecoclay TS1 '(70% pure sand, 15% waste tile, 15% sludge), and Ecoclay TS2' (80% pure sand, waste tile) 10% and sludge 10%).

まず、3種類の土壌の透水試験を行った。透水試験は、所定量の水を所定厚さの土壌に投入し、該土壌内を浸透する速度を測定することにより行った。また、各土壌を製造してから2日後と4日後にそれぞれ測定を行った。表14に示す透水試験の結果から、エコクレイTS1’及びTS2’のいずれも、従来土に比べて透水時間が短く、透水性が良いことが確認できた。

Figure 2015129260
First, three types of soil permeability tests were conducted. The water permeability test was performed by putting a predetermined amount of water into a soil having a predetermined thickness and measuring the rate of penetration into the soil. In addition, the measurement was performed 2 days and 4 days after each soil was produced. From the results of the water permeability test shown in Table 14, it was confirmed that both Ecoclay TS1 ′ and TS2 ′ had a short water permeability time and good water permeability compared to conventional soil.
Figure 2015129260

次に、上記3種類の土壌の粘土分布試験を行った。粘土分布試験は、各土壌の細粒分(コロイド分、粘土分、及びシルト分)の量とそれらの浮遊状態を確認することにより行った。この試験では、細粒分が浮遊していない状態に至るまでの時間を計測した。表15に示す結果から、エコクレイTS1’及びTS2’のいずれも、従来土に比べて細粒分の沈降時間が短く、従来土に比べて泥濘化しにくく埃がたちにくい土壌であるといえる。

Figure 2015129260
Next, a clay distribution test of the above three types of soil was performed. The clay distribution test was performed by confirming the amount of fine particles (colloid, clay, and silt) in each soil and their floating state. In this test, the time until the fine particles were not suspended was measured. From the results shown in Table 15, it can be said that both Ecoclay TS1 ′ and TS2 ′ are soils that have a shorter settling time for fine particles than conventional soil, and are less susceptible to mudging and less dusty than conventional soil.
Figure 2015129260

また、上記3種類の土壌の水分特性試験を行った。水分特性試験は、土壌の固相率、及び乾燥状態における含水率を測定して土壌中の有効水分量を確認することにより行った。また、各土壌を製造してから2日後と4日後にそれぞれ測定を行った。表16に示す結果から、エコクレイTS1’及びTS2’のいずれも、従来土に比べて固相率が低く、土壌の内部により多くの間隙が形成されていることが分かる。また、従来土に比べて有効水分量が多いことも確認できた。これは、土壌の内部に多くの間隙を有するため、該間隙の内部に水分を保有できるためであると考えられる。さらに、多くの水分を保有できるため、土壌が乾燥しにくく、埃がたちにくい土壌であるといえる。

Figure 2015129260
Moreover, the moisture characteristic test of the three types of soil was conducted. The moisture characteristic test was performed by measuring the solid phase rate of the soil and the moisture content in the dry state to confirm the effective moisture content in the soil. In addition, the measurement was performed 2 days and 4 days after each soil was produced. From the results shown in Table 16, it can be seen that both Ecoclay TS1 ′ and TS2 ′ have a lower solid phase ratio than conventional soil, and more gaps are formed in the soil. It was also confirmed that the amount of effective moisture was larger than that of conventional soil. This is thought to be due to the fact that there are many gaps inside the soil, so that moisture can be retained inside the gaps. Furthermore, since it can hold a lot of moisture, it can be said that the soil is hard to dry and dust is hard to reach.
Figure 2015129260

さらに、上記3種類の土壌の硬度試験を行った。硬度試験は、プロクターニードルを用い、1インチ/秒の速度で押し込み硬度を測定することにより行った。また、硬度試験は各土壌の2箇所で行い、その平均値を得た。さらに、各土壌を製造してから2日後と4日後にそれぞれ測定を行った。グラウンド(校庭、学校運動場)には硬度40〜110の土壌が適しているとされている。表17に示す結果から、本実施例のエコクレイTS1’及びTS2’はいずれもグラウンド用土壌に適した硬度を有していることが分かる。

Figure 2015129260
Furthermore, the hardness test of the above three types of soil was performed. The hardness test was performed by measuring the indentation hardness using a proctor needle at a speed of 1 inch / second. Moreover, the hardness test was done in two places of each soil, and the average value was obtained. Furthermore, the measurement was performed 2 days and 4 days after each soil was produced. It is said that soil with a hardness of 40-110 is suitable for the ground (schoolyard, school playground). From the results shown in Table 17, it can be seen that the ecoclays TS1 ′ and TS2 ′ of this example both have a hardness suitable for the ground soil.
Figure 2015129260

次に、土壌に塩材を配合することによる、霜柱の生成を抑制する効果を確認する試験を行った。試験には表18に示す5種類の土壌(各150ml)を使用した。5種類の土壌のうち、エコクレイX及びエコクレイZには、それぞれ1m2あたり3kg(0.13〜0.14m3あたり3kgに相当)の塩を配合した。

Figure 2015129260
Next, the test which confirms the effect which suppresses the production | generation of a frost column by mix | blending a salt material with soil was done. In the test, five types of soils (150 ml each) shown in Table 18 were used. Of the five types of soil, each of Ecoclay X and Ecoclay Z was mixed with 3 kg of salt per 1 m 2 (equivalent to 3 kg per 0.13 to 0.14 m 3).
Figure 2015129260

この試験は、以下の手順で行った。
(1)コップ型のプラスチック製容器の底にティッシュペーパーを敷き詰め5mlのお湯を注入する。
(2)上記5種類の土壌をプラスチック製容器に投入し、手圧をかけながら表面を均す。
(3)霧吹きで表面を湿らせ、容器内側の水滴をふき取ったあと蓋をする。
(4)プラスチック製容器が収まる大きさの別の容器(大容器)に気泡緩衝材を敷きお湯を注入する。
(5)上記大容器にプラスチック製容器を収容する。
(6)蓋の上に、ビニール袋を入れた氷8個(塩を10g程度添加)を固定して冷凍庫内に載置する。
(7)1時間毎に土壌表面の状態を確認し、上記大容器にお湯を追加する。
This test was performed according to the following procedure.
(1) Spread tissue paper on the bottom of a cup-shaped plastic container and pour 5 ml of hot water.
(2) Put the above five types of soil into a plastic container and level the surface while applying manual pressure.
(3) Moisten the surface with a spray bottle, wipe off the water droplets inside the container, and then cover.
(4) Place a bubble cushioning material in another container (large container) of a size that can accommodate a plastic container, and pour hot water.
(5) A plastic container is accommodated in the large container.
(6) On the lid, fix 8 pieces of ice (adding about 10g of salt) in a plastic bag and place it in the freezer.
(7) Check the condition of the soil surface every hour and add hot water to the large container.

試験開始後、1時間が経過した時点で、従来土2(赤土)の表面に凍結が確認された。また、エコクレイY(塩添加なし)の表面に1本の氷柱が確認された。他の土壌には凍結や氷柱は確認されなかった。
試験開始後、2時間が経過した時点でも、従来土2(赤土)の表面に凍結が確認された。また、エコクレイYの表面には小さな氷柱が数本確認された。他の土壌には凍結や氷柱は確認されなかった。
その後、1時間毎に確認を続けた結果、7時間後には、従来土2に凍結と氷柱が確認され、エコクレイYには氷柱が確認された。
開始から23時間が経過した時点で試験を終了して各土壌の状態を確認した。従来土1(真砂土)では、凍結や氷柱は確認されないものの土壌の膨張が確認された。また、従来土2では凍結及び氷柱に加え土壌の大幅な膨張が確認された。エコクレイX、Y、及びZでは土壌の膨張が確認されなかった。
塩を添加したエコクレイX及びZでは、土壌の凍結や氷柱が確認されず、まだ土壌の膨張も見られなかったことから、塩が凍結や霜柱の発生を抑制する効果を有することを確認した。従って、塩を添加することにより、寒冷地での使用に適した土壌用資材を製造することができる。
Freezing was confirmed on the surface of the conventional soil 2 (red soil) when 1 hour passed after the start of the test. Moreover, one ice column was confirmed on the surface of Ecoclay Y (without salt addition). No freezing or icicles were observed in other soils.
Even when 2 hours passed after the start of the test, freezing was confirmed on the surface of the conventional soil 2 (red soil). Moreover, several small ice pillars were confirmed on the surface of Ecoclay Y. No freezing or icicles were observed in other soils.
After that, as a result of continuing confirmation every hour, freezing and icicles were confirmed in the conventional soil 2 and icicles were confirmed in Ecoclay Y after 7 hours.
When 23 hours passed from the start, the test was terminated and the state of each soil was confirmed. In the conventional soil 1 (masa sand soil), although the freezing and the icicle were not confirmed, the expansion of the soil was confirmed. Moreover, in the conventional soil 2, in addition to freezing and icicles, significant expansion of the soil was confirmed. In Ecoclay X, Y, and Z, soil expansion was not confirmed.
In Ecoclay X and Z to which salt was added, the soil was not frozen or icicles were confirmed, and the soil was still not expanded. Therefore, it was confirmed that the salt has an effect of suppressing freezing and generation of frost columns. Therefore, by adding salt, a soil material suitable for use in a cold region can be produced.

なお、上記試験は、塩を1kg添加した場合と2kg添加した場合についても同様に行った。その結果、塩を1kg添加するのみでは防霜効果が十分でなく、塩を2kg添加することで上記同様の結果が得られる(即ち十分な防止も効果が得られる)ことを確認した。   The above test was performed in the same manner when 1 kg of salt was added and when 2 kg of salt was added. As a result, it was confirmed that the addition of 1 kg of salt was not sufficient in the defrosting effect, and the addition of 2 kg of salt gave the same result as above (that is, sufficient prevention was also obtained).

塩を添加した土壌用資材について、上記実施例2と同様に透水性及び保水性の試験を行った。実施例5の試験で配合成分として用いた真砂土の透水性及び保水性試験の結果を表19に示す。また、この試験に使用した10種類の土壌(エコクレイ11〜20、うち8種類に塩を添加)の配合と透水性及び保水性試験の結果を表20に示す。

Figure 2015129260
Figure 2015129260
About the material for soil which added salt, the water permeability and water retention test were done like Example 2 above. Table 19 shows the results of water permeability and water retention tests of the sand sand used as a blending component in the test of Example 5. In addition, Table 20 shows the results of blending and water permeability and water retention tests of 10 types of soil (eco clay 11 to 20, 8 of which salt was added) used in this test.
Figure 2015129260
Figure 2015129260

表20に示す結果から、塩を添加すると透水性は若干低下するものの大きな差はなく、また、塩を添加しても保水性には大きな影響が無いことが確認できた。   From the results shown in Table 20, it was confirmed that when salt was added, the water permeability slightly decreased, but there was no significant difference, and even when salt was added, there was no significant effect on water retention.

石こうボード廃材(石こう廃材)の配合量によって土壌の硬度がどのように変化するかを確認する試験を行った。使用した土壌は、従来土(真砂土100%)、エコクレイA(真砂土95%、石こうボード廃材5%)、エコクレイB(真砂土90%、石こうボード廃材10%)、及びエコクレイC(真砂土80%、石こうボード廃材20%)である。   A test was conducted to confirm how the hardness of the soil changes depending on the amount of gypsum board waste (gypsum waste). The soil used was conventional soil (100% pure sand), Ecoclay A (95% pure sand, 5% gypsum board waste), Ecoclay B (90% pure sand, 10% gypsum board waste), and Ecoclay C (masa sand) 80%, gypsum board waste 20%).

上記4種類の土壌の乾燥密度を1.68g/cm3に統一して硬度を測定した結果を表21に示す。実施例6では山中式硬度計(非特許文献1等参照)を用いて土壌の硬度を測定した。

Figure 2015129260
Table 21 shows the results of measuring the hardness by unifying the dry density of the above four types of soil to 1.68 g / cm 3 . In Example 6, the hardness of the soil was measured using a Yamanaka hardness tester (see Non-Patent Document 1, etc.).
Figure 2015129260

上記の測定結果から、石こうボード廃材を5%又は10%配合した土壌では従来土に比べて硬度が上昇することが分かった。一方、石こうボード廃材を20%配合すると硬度が低下して全体が粘土質に近くなることが分かった。   From the above measurement results, it was found that the hardness increased in soil containing 5% or 10% of gypsum board waste compared to conventional soil. On the other hand, it was found that when 20% of gypsum board waste was mixed, the hardness decreased and the whole became close to clay.

また、上記土壌の乾燥密度を、1.68g/cm3、1.70g/cm3、1.73g/cm3、及び1.75g/cm3の4段階に変化させて硬度を測定した結果を図3に示す。この結果から、いずれの乾燥密度においても、石こうボード廃材の配合割合が5%又は10%である土壌の硬度が高く、配合割合が20%になると硬度が低下することが確認された。 Also shows the dry density of the soil, 1.68g / cm 3, 1.70g / cm 3, a 1.73 g / cm 3, and 1.75 g / cm 3 of varied in four stages result of measuring the hardness in FIG . From these results, it was confirmed that at any dry density, the hardness of the soil where the mixing ratio of gypsum board waste was 5% or 10% was high, and the hardness decreased when the mixing ratio was 20%.

配合成分が異なる8種類の土壌をそれぞれ60mm四方の区画に配置してバミューダグラスの種を散布し、約3ヶ月(98日間)経過を観察した。また、並行して各区画の硬度測定とpH測定を行った。各区画に配置した土壌の成分を図4に示す。なお、配合材料における0-10等の表記は粒度を表し、0-10は粒度10mm以下のものであることを意味する。   Eight kinds of soils with different blending components were placed in a 60mm square section and sprinkled with Bermudagrass seeds, and the progress was observed for about 3 months (98 days). Moreover, the hardness measurement and pH measurement of each division were performed in parallel. The components of the soil arranged in each section are shown in FIG. In addition, the notation such as 0-10 in the blended material indicates the particle size, and 0-10 means that the particle size is 10 mm or less.

表22に、試験終了時における各土壌の硬度とpH値の測定値、及び防草効果の有無をまとめて示す。表22に示す防草効果の×は防草効果が見られない(バミューダグラスが大きく生育した)、△は防草効果が低い、○及び◎は防草効果が確認できる(バミューダグラスの生育が抑えられており、特に◎ではほとんど生育が確認されない)ことを意味している。

Figure 2015129260
Table 22 summarizes the measured values of the hardness and pH value of each soil at the end of the test, and the presence or absence of the herbicidal effect. The herbicidal effect x shown in Table 22 shows no herbicidal effect (Bermuda grass grew greatly), △ shows low herbicidal effect, ○ and ◎ confirm the herbicidal effect (Bermuda grass growth is It means that the growth is suppressed, and in particular, growth is hardly confirmed with ◎.
Figure 2015129260

表22に示すように、竹チップを含む土壌を配置した区画6、7、及び8において良好な防草効果が認められた。従って、防草効果が求められる用途(グラウンドや歩道など)に使用する土壌には竹チップを含めることが好ましい。一方、スラッジと石こうボード廃材を含む区画2の土壌ではバミューダグラスが大きく生育しており、防草効果とは逆に肥料効果が認められた。従って、肥料効果が求められる用途(植栽用土壌など)ではスラッジや石こうボード廃材を含めることが好ましい。
各区画におけるpH値はいずれも中性近傍の値であった。
また、各区画における硬度の測定結果は、概ね表23に示すグラウンド用土壌に適した硬度値の範囲内の値であり、硬度の面ではいずれの土壌もグラウンド(土グラウンドあるいは芝生グラウンド)、テニスコート、遊歩道等において用いることができる。

Figure 2015129260
As shown in Table 22, a good herbicidal effect was observed in the sections 6, 7, and 8 in which the soil containing bamboo chips was placed. Therefore, it is preferable to include bamboo chips in the soil used for applications that require a herbicidal effect (ground, sidewalk, etc.). On the other hand, Bermudagrass grew greatly in the soil of section 2 containing sludge and gypsum board waste, and the fertilizer effect was recognized contrary to the herbicidal effect. Therefore, it is preferable to include sludge and gypsum board waste materials in applications where fertilizer effects are required (such as planting soil).
The pH values in each compartment were all near neutral.
Moreover, the measurement results of the hardness in each section are values within the range of hardness values suitable for the ground soil shown in Table 23. In terms of hardness, any soil is ground (soil ground or lawn ground), tennis It can be used on courts, promenades, and the like.
Figure 2015129260

上述した各種試験において使用し種々の効果が確認された土壌には真砂土や赤土を含むものがある。これらは天然土であり、既にグラウンド土壌や植栽土壌、あるいは歩道用土壌に含まれている。従って、本発明に係る土壌用資材は、単独で土壌として使用するのみならず、既存土の機能性を補うような配合で製造し、既存土と混合することによって用いることもできる。本発明に係る土壌用資材を既存土と混合して使用する場合の手順を図5に示す。図5(a)はグラウンド用土壌の場合、図5(b)は芝の床土(植栽用土壌)の場合の一例である。   Some soils that have been used in the various tests described above and have been confirmed to have various effects include pure sand and red soil. These are natural soils and are already contained in ground soil, planting soil, or sidewalk soil. Therefore, the soil material according to the present invention can be used not only as soil alone, but also by manufacturing with a composition that supplements the functionality of existing soil and mixing it with existing soil. FIG. 5 shows a procedure when the soil material according to the present invention is used by mixing with existing soil. FIG. 5 (a) is an example of ground soil, and FIG. 5 (b) is an example of turf floor soil (planting soil).

グラウンド用土壌の場合、まず、事前調査として、現地調査、室内試験及び配合設計を行う。現地調査では現地で既存土(現地土)をサンプリングする。室内試験では、既存土の土質試験を行う。配合設計では、既存土のうちリサイクル可能な割合を決定し、既存土を改善したり不足する機能を補ったりするように土壌用資材の配合を設計する。
事前調査が完了すると、配合設計に基づいて土壌用資材を製造する。
土壌用資材の製造が完了すると、施工を行う。施工は、既存土の鋤取及び集積(土工)、既存土の最大粒度調整(篩分)、粒度調整済みの既存土と土壌用資材の混合、整地転圧の順に行う。これにより、グラウンド用土壌が完成する。
In the case of soil for ground, first, as a preliminary survey, a field survey, a laboratory test, and a formulation design are performed. In the field survey, existing soil (local soil) is sampled locally. In the laboratory test, the soil quality of the existing soil is tested. In the mix design, the proportion of existing soil that can be recycled is determined, and the mix of soil materials is designed to improve the existing soil or to make up for the lack of functions.
When the preliminary survey is completed, the soil material is manufactured based on the formulation design.
When the production of soil materials is completed, construction is performed. The construction will be carried out in the order of scraping and accumulation of existing soil (earthwork), maximum particle size adjustment (sieving) of existing soil, mixing of existing soil and soil material after particle size adjustment, and leveling rolling. Thereby, the ground soil is completed.

芝の床土(植栽用土壌)の場合も、土壌用資材の製造までの各工程は上記同様であり、施工の工程が異なる。施工は、土壌用資材の搬入、土壌用資材の敷均し、土壌用資材と現地土の攪拌、整地転圧、張芝の順に行う。これにより芝の床土が完成する。   In the case of turf floor soil (planting soil), the steps up to the production of soil materials are the same as described above, and the construction steps are different. Construction will be carried out in the order of carrying in soil materials, leveling the soil materials, mixing the soil materials with the local soil, ground leveling and rolling. This completes the turf floor soil.

尚、本発明は上記した実施例に限定されるものではなく、適宜の変更が可能である。例えば、上記実施例では多孔質無機廃材として廃瓦破砕材を用いた例を示したが、廃陶磁器破砕材や廃レンガ破砕材を用いても良い。
上記した成分以外の成分を含めても良い。例えば土壌の酸性度、アルカリ性度の改良を目的とする土壌用資材の場合は溶融スラグを配合すると良い。
In addition, this invention is not limited to an above-described Example, A suitable change is possible. For example, although the example which used the waste tile crushing material as a porous inorganic waste material was shown in the said Example, you may use a waste ceramic crushing material and a waste brick crushing material.
Components other than those described above may be included. For example, in the case of a soil material for the purpose of improving the acidity and alkalinity of the soil, molten slag is preferably blended.

上記課題を解決するために成された本発明に係る土壌用資材は、
a) 廃瓦破砕材、廃陶磁器破砕材、及び廃レンガ破砕材のうちの少なくとも一種類からなる、粒度が30mm以下の多孔質無機廃材と、
b) 粒度が30mm以下の締め固め材と
を含むことを特徴とする。
Soil for materials according to the present onset Ming was made in order to solve the above-
a) a porous inorganic waste material having a particle size of 30 mm or less, comprising at least one of waste tile crushing material, waste ceramic crushing material, and waste brick crushing material;
b) It is characterized by including a compacting material having a particle size of 30 mm or less.

本発明に係る土壌用資材は、グラウンド用土壌、植栽用土壌、舗装用の路盤材、歩道用資材等、様々な土壌に適用することができ、適用対象に応じた適宜の材料を多孔質無機廃材に付加することができる。
例えば、土や芝生のグラウンド用土壌、舗装用の路盤材、あるいは歩道用資材として用いる場合は、上述した締め固め材の組み合わせや配合量によって、資材の硬度を適宜に調整することができる。
グラウンド用土壌に適用される土壌用資材には、過度な踏圧に対する土壌構造(団粒構造や土壌粒子間の間隙)の劣化を改良する機能が求められる。浄水スラッジ、ペーパースラッジ、及び高分子ポリマー粒はいずれも団粒化し易いため、これらを締め固め材に含めれば過度な踏圧に対する土壌構造の劣化改良機能を有する土壌用資材が得られる。
ここで、団粒化、あるいは団粒構造とは、土壌粒子が陽イオンや粘土鉱物、有機物(腐植)などのはたらきによって結合し、小粒の集合体(団粒)となった状態をいう。団粒構造が発達した土は、団粒の内部に微細な団粒内間隙が、団粒の外部に団粒間間隙(非毛管孔隙)ができるため、透水性、弾力性、保水性に優れる。従って、浄水スラッジ、ペーパースラッジ、又は高分子ポリマー粒を含む土壌用資材は透水性、弾力性、保水性にも優れる。
また、本発明の土壌用資材をグラウンド用土壌や歩道用資材として用いる場合には、締め固め材に竹廃材を含めることにより、防草性を有する土壌用資材を得ることができる。
The soil material according to the present invention can be applied to various soils such as ground soil, planting soil, pavement roadbed material, sidewalk material, etc., and an appropriate material according to the application target is porous. It can be added to inorganic waste materials.
For example, when used as soil for ground of soil or lawn, roadbed material for pavement, or material for sidewalks, the hardness of the material can be appropriately adjusted depending on the combination and blending amount of the above-described compacting materials.
The soil material applied to the ground soil is required to have a function of improving the deterioration of the soil structure (aggregate structure or gap between soil particles) against excessive treading pressure. Since all of the purified water sludge, the paper sludge, and the polymer polymer particles are easily aggregated, if they are included in the compacting material, a soil material having a function of improving the deterioration of the soil structure against excessive treading pressure can be obtained.
Here, agglomeration, or agglomeration structure, refers to a state in which soil particles are combined by the action of a cation, clay mineral, organic matter (humus), or the like to form an aggregate (aggregate) of small particles. Soil with a developed aggregate structure is excellent in water permeability, elasticity, and water retention because a fine intergranular gap is formed inside the aggregate and an inter-aggregate gap (non-capillary pore) is formed outside the aggregate. . Therefore, the soil material containing purified water sludge , paper sludge, or polymer polymer particles is excellent in water permeability, elasticity, and water retention.
Moreover, when using the soil material of this invention as a soil for grounds or a material for sidewalks, the soil material which has a herbicidal property can be obtained by including bamboo waste material in the compacting material.

Claims (8)

a) 廃瓦破砕材、廃陶磁器破砕材、及び廃レンガ破砕材のうちの少なくとも一種類からなる、粒度が30mm以下の多孔質無機廃材と、
b) 粒度が30mm以下の締め固め材と
を含む土壌用資材。
a) a porous inorganic waste material having a particle size of 30 mm or less, comprising at least one of waste tile crushing material, waste ceramic crushing material, and waste brick crushing material;
b) Soil material containing compaction material with a particle size of 30mm or less.
前記締め固め材が、浄水スラッジ、ペーパースラッジ、高分子ポリマー、及び竹廃材のうちの少なくとも一種類を含むことを特徴とする請求項1に記載の土壌用資材。   The soil material according to claim 1, wherein the compacting material includes at least one of water purification sludge, paper sludge, polymer polymer, and bamboo waste material. 前記締め固め材が、粒度が0.075mm以下の廃瓦磨砕材、廃レンガ磨砕材、石こう廃材、砕石(砂)粉、及びスクリーニングスのうちの少なくとも一種類を含むことを特徴とする請求項1又は2に記載の土壌用資材。   The compacting material includes at least one of waste tile grinding material having a particle size of 0.075 mm or less, waste brick grinding material, gypsum waste material, crushed stone (sand) powder, and screenings. Item 3. A soil material according to Item 1 or 2. 防霜材として塩材を含むことを特徴とする請求項1〜3のいずれかに記載の土壌用資材。   The soil material according to any one of claims 1 to 3, further comprising a salt material as a defrosting material. 間伐材、浄水スラッジ、及びペーパースラッジのうちの少なくとも一種類からなる肥料材を含むことを特徴とする請求項1〜4のいずれかに記載の土壌用資材。   5. The soil material according to claim 1, comprising a fertilizer material comprising at least one of thinned wood, purified water sludge, and paper sludge. 間伐材、蛎殻、ホタテ殻、及び軽石のうちの少なくとも一種類を破砕・粉砕したものからなる保水材を含むことを特徴とする請求項1〜5のいずれかに記載の土壌用資材。   The soil material according to any one of claims 1 to 5, further comprising a water retention material made of crushed and pulverized at least one of thinned wood, rice husk, scallop shell, and pumice. 平均粒径が0.01〜10mmの真砂土、赤土、及び黒土の少なくとも一種類をさらに含むことを特徴とする請求項1〜6のいずれかに記載の土壌用資材。   The soil material according to any one of claims 1 to 6, further comprising at least one kind of pure sand soil, red soil, and black soil having an average particle diameter of 0.01 to 10 mm. 既存土に請求項1〜7に記載の土壌用資材を配合することを特徴とする土壌改良方法。   The soil improvement method characterized by mix | blending the soil material of Claims 1-7 with the existing soil.
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KR20190082464A (en) 2018-01-02 2019-07-10 민덕규 Photograping application of cellular phone camera
CN108395340A (en) * 2018-06-04 2018-08-14 山西省农业科学院果树研究所 One planting fruit-trees special-purpose non-toxic fertilizer formula and its production method
IT202000011842A1 (en) * 2020-05-21 2021-11-21 Matteo Bianchi METHOD OF TREATMENT OF WASTE FOR THE PRODUCTION OF AGGREGATES FOR THE CONSTRUCTION OF ROAD SUBSTRATES AND FOUNDATION LAYERS OF SUPERSTRUCTURES AND AREAS SUBJECT TO TRAFFIC
JP2023037543A (en) * 2021-09-03 2023-03-15 光広 大友 Soil improvement material and mixed soil used in baseball ground and softball ground
JP7383857B2 (en) 2021-09-03 2023-11-21 光広 大友 Soil improvement materials and mixed soil used at baseball fields and softball fields

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