JP2015126194A - Substrate processing method and substrate processing device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a technique capable of efficiently processing a substrate having a recess on the surface thereof.SOLUTION: A substrate processing method for processing a substrate 9 having a recess on the surface thereof comprises the steps of: a) forming a liquid film of the process liquid covering a surface of the substrate 9 held in a horizontal posture and rotated in a horizontal plane by supplying the process liquid to the surface of the substrate; and b) switching the rotation speed of the substrate 9 twice or more between a first rotation speed and a second rotation speed while keeping the liquid film of the process liquid covering the surface of the substrate 9. However, the step a) and the step b) are performed in parallel.

Description

  The present invention relates to a technique for processing a substrate having a concave portion on the surface. Examples of substrates to be processed include semiconductor wafers, liquid crystal display substrates, plasma display substrates, FED (Field Emission Display) substrates, optical disk substrates, magnetic disk substrates, magneto-optical disk substrates, and photomasks. Substrate, ceramic substrate, solar cell substrate, and the like.

  In the manufacturing process of a semiconductor device, a liquid crystal display device, etc., a cleaning process is performed to remove foreign substances from a substrate such as a semiconductor wafer or a glass substrate for a liquid crystal display device. For example, in a back-end process (BEOL: Back End of the Line) in which multilayer wiring is formed on the surface of a semiconductor wafer on which devices such as transistors and capacitors are built, a polymer that removes polymer residues generated by dry etching or ashing A removal step is performed. For example, Patent Documents 1 and 2 disclose a technique for removing a polymer residue on a substrate by supplying a polymer removing solution to the rotated substrate.

JP 2007-81419 A JP2013-123001A

  By the way, if a processing liquid such as a polymer removing solution is supplied to a substrate (a substrate having a concave portion such as a wiring groove or a via hole formed on the surface), the surface of the substrate is covered with a liquid film of the processing solution. In this state, the recess is filled with the processing liquid. As a result, the polymer residue in the recess is melted out by the treatment liquid and peeled off. Further, the processing liquid filling the recess is discharged from the recess together with the polymer residue, and the polymer residue is removed from the substrate by successively replacing the recess with fresh processing liquid.

  However, it is not easy to discharge the processing liquid filling the recess from the recess. Conventionally, for example, the substrate is rotated in a predetermined direction at a constant rotation speed, and a centrifugal force is applied to the treatment liquid in the recess to discharge the treatment liquid from the recess. However, in this embodiment, since the treatment liquid in the recess only has a force biased in one direction, the fluidity of the treatment liquid in the recess is not sufficiently increased, and most of the treatment liquid in the recess is discharged. Without being retained in the recess. That is, the processing liquid in the recess is not sufficiently replaced with fresh processing liquid. If it becomes like this, a polymer residue may not be fully removed from the inside of a recessed part, and there exists a possibility that a polymer residue may remain in a recessed part. Residue of the polymer residue may cause a decrease in the electrical characteristics of the device, a decrease in yield, and the like.

  To increase the removal rate of polymer residues, for example, extending the processing time or increasing the amount of processing solution used can be considered, but extending the processing time leads to a decrease in throughput and increasing the amount of processing solution increases costs. It will be connected.

  This invention is made | formed in view of the said subject, and it aims at providing the technique which can process efficiently the board | substrate with a recessed part in the surface.

  A first aspect is a substrate processing method for processing a substrate having a concave portion on a surface thereof, wherein a) a processing liquid is supplied to the surface of the substrate held in a horizontal posture and rotated in a horizontal plane, A step of forming a liquid film of the processing liquid covering the surface; b) in parallel with the step a), while maintaining the liquid film of the processing liquid covering the surface, And a step of switching at least twice between the first rotational speed and the second rotational speed.

  A 2nd aspect is a substrate processing method which concerns on a 1st aspect, Comprising: In the said a) process, the said process liquid is supplied to the said surface, moving the landing position of the said process liquid.

  A 3rd aspect is a substrate processing method which concerns on a 2nd aspect, Comprising: The said liquid landing position is moved within the area | region which includes the rotation center of the said board | substrate and does not contain the peripheral part of the said board | substrate.

  A 4th aspect is a substrate processing method which concerns on a 3rd aspect, Comprising: The position of the outer periphery of the said area | region is prescribed | regulated based on the speed of the said process liquid in the said recessed part in each position in the said surface. .

  A fifth aspect is a substrate processing method according to the first aspect, wherein in the step a), the landing position of the processing liquid is fixed to the rotation center of the substrate, and the processing liquid is applied to the surface. Supply.

  A sixth aspect is a substrate processing method according to any one of the first to fifth aspects, wherein the substrate is rotated at the first rotational speed and rotated at the second rotational speed. The rotation direction of the substrate is the same direction.

  A seventh aspect is a substrate processing method according to any one of the first to sixth aspects, wherein switching between the first rotation speed and the second rotation speed is performed intermittently.

  An eighth aspect is a substrate processing method according to any one of the first to seventh aspects, wherein the treatment liquid removes the polymer on the surface and the thin film formed on the surface. It is a chemical solution.

  A ninth aspect is the substrate processing method according to any one of the first to seventh aspects, wherein the processing liquid is a rinsing liquid for rinsing a chemical liquid.

  A tenth aspect is a substrate processing apparatus for processing a substrate having a concave portion on a surface thereof, the rotation holding unit rotating the substrate around a vertical rotation axis while holding the substrate in a horizontal posture, A discharge unit that supplies a treatment liquid to the surface of the substrate held by the rotation holding unit, and a liquid film of the treatment liquid that covers the surface is formed by causing the discharge unit to supply the treatment liquid to the surface. In parallel with this, while maintaining the liquid film of the processing liquid covering the surface, the rotation holding portion is rotated twice between the first rotation speed and the second rotation speed on the rotation holding unit. A control unit for switching the above.

  According to the first and tenth aspects, the rotation speed of the substrate is switched twice or more between the first rotation speed and the second rotation speed while supplying the processing liquid to the substrate. According to this configuration, the processing liquid on the substrate is greatly shaken. Thereby, the fluidity of the processing liquid on the surface of the substrate is increased, and the substrate can be processed efficiently.

  According to the second aspect, the processing liquid is supplied to the surface of the substrate while moving the landing position of the processing liquid. In the region where the processing liquid is supplied while moving the position where the processing liquid is deposited on the surface of the substrate, the processing liquid arrives from directly above each concave portion, so that the fluidity of the processing liquid in the concave portion is increased, The treatment liquid is particularly difficult to stay in the recess. That is, the fluidity of the processing liquid on the surface of the substrate can be particularly improved by supplying the processing liquid to the surface of the substrate while moving the landing position of the processing liquid.

  According to the third and fourth aspects, the liquid landing position is moved within a region that includes the rotation center of the substrate and does not include the peripheral portion of the substrate. That is, here, in the region near the center of rotation of the substrate, where the fluidity of the processing liquid tends to be low because the centrifugal force is relatively small, in addition to switching the rotation speed of the substrate, the movement of the landing position also The fluidity of the processing liquid is improved. According to this configuration, the fluidity of the processing liquid can be sufficiently increased over the entire surface of the substrate. Further, according to this configuration, the processing liquid that has landed near the rotation center of the substrate spreads to the peripheral edge of the substrate due to centrifugal force, and effectively acts on a wide region within the surface of the substrate. As a result, the amount of processing liquid used can be reduced, and the uniformity of processing over the entire surface of the substrate can be improved.

  According to the fifth aspect, the processing liquid is supplied to the surface of the substrate with the processing liquid landing position fixed at the rotation center of the substrate. According to this configuration, the processing liquid that has landed on the rotation center of the substrate spreads over the entire substrate by centrifugal force, and effectively acts on the entire surface of the substrate. As a result, the amount of processing liquid used can be reduced, and the uniformity of processing over the entire surface of the substrate can be improved.

  According to the sixth aspect, the rotation direction of the substrate rotated at the first rotation speed and the rotation direction of the substrate rotated at the second rotation speed are the same direction. According to this configuration, the moment when the rotation speed of the substrate becomes zero does not occur. Accordingly, a centrifugal force in a direction away from the rotation center of the substrate always acts on the processing liquid on the substrate, and excess processing liquid on the substrate is shaken off vigorously from the peripheral edge of the substrate. For this reason, it is difficult to cause a situation in which excess processing liquid on the substrate drops from the peripheral edge of the substrate and is not recovered.

  According to the seventh aspect, switching between the first rotation speed and the second rotation speed is performed intermittently. According to this configuration, a time zone in which the substrate is rotated at a constant speed occurs, and in this time zone, the liquid film of the processing liquid covering the surface of the substrate is smoothly replaced with fresh processing liquid.

It is a typical side view of a substrate processing apparatus. It is a block diagram which shows the electric constitution of a substrate processing apparatus. It is a sectional side view which shows typically the mode of the surface layer vicinity of the board | substrate used as a process target. It is a figure for demonstrating an example of the process performed in a substrate processing apparatus. It is a figure for demonstrating a scanning outer periphery. It is a figure which shows an example of the switching aspect of the rotational speed of a board | substrate. It is a figure for demonstrating the direction of the force which the process liquid on a board | substrate receives. It is a figure which shows an example of the switching aspect of the rotational speed of a board | substrate. It is a figure which shows an example of the switching aspect of the rotational speed of a board | substrate. It is a figure which shows an example of the switching aspect of the rotational speed of a board | substrate. It is a typical side view of the substrate processing apparatus which concerns on another embodiment.

  Hereinafter, embodiments will be described with reference to the drawings. The following embodiment is an example embodying the present invention, and is not an example of limiting the technical scope of the present invention. In each of the drawings referred to below, the size and number of each part may be exaggerated or simplified for easy understanding.

<1. Configuration of Substrate Processing Apparatus 100>
The substrate processing apparatus 100 is a single-wafer type substrate processing apparatus that processes a disk-shaped substrate 9 such as a semiconductor wafer one by one. The configuration of the substrate processing apparatus 100 will be described with reference to FIGS. FIG. 1 is a schematic side view of the substrate processing apparatus 100. FIG. 2 is a block diagram showing an electrical configuration of the substrate processing apparatus 100.

  The substrate processing apparatus 100 includes a spin chuck 1, a splash prevention unit 2, a first processing liquid supply unit 3, a second processing liquid supply unit 4, and a control unit 5.

<Spin chuck 1>
The spin chuck 1 is a rotation holding unit that rotates the substrate 9 around a vertical rotation axis passing through the center of the main surface while holding the substrate 9 in a substantially horizontal posture.

  The spin chuck 1 includes a spin base 11 that is a disk-shaped member that is slightly larger than the substrate 9. A rotation shaft portion 12 is connected to the central portion of the lower surface of the spin base 11. The rotating shaft portion 12 is arranged in such a posture that its axis is along the vertical direction. Further, the rotary shaft portion 12 is connected to a rotation drive portion (for example, a motor) 13 that rotates the shaft around the axis. The rotating shaft portion 12 and the rotation driving portion 13 are accommodated in a cylindrical casing 14. In addition, a plurality of (for example, six) holding members 15 are provided in the vicinity of the peripheral edge of the upper surface of the spin base 11 at an appropriate interval. The holding member 15 contacts the end surface of the substrate 9 to position the substrate 9 in the horizontal direction, and at a position slightly higher than the upper surface of the spin base 11 (that is, with a predetermined interval from the upper surface of the spin base 11). The substrate 9 is held in a substantially horizontal posture.

  In this configuration, when the rotation drive unit 13 rotates the rotation shaft unit 12 with the holding member 15 holding the substrate 9 above the spin base 11, the spin base 11 is rotated around the axis along the vertical direction. As a result, the substrate 9 held on the spin base 11 is rotated around a vertical rotation axis passing through the center in the plane.

  The rotation drive unit 13 and the holding member 15 are electrically connected to the control unit 5 and operate under the control of the control unit 5 (see FIG. 2). That is, the timing of holding the substrate 9 on the spin base 11, the timing of releasing the held substrate 9, and the rotation mode of the spin base 11 (that is, the rotation mode of the substrate 9) (specifically, the rotation start timing) , Rotation end timing, rotation speed (ie, rotation speed), etc.) are controlled by the control unit 5.

<Spattering prevention part 2>
The anti-scattering unit 2 receives a processing liquid and the like that are scattered from the substrate 9 held and rotated by the spin base 11.

  The scattering prevention unit 2 includes a cup 21. The cup 21 is a cylindrical member having an open upper end and is provided so as to surround the spin chuck 1. The cup 21 includes, for example, an inner member 211, an intermediate member 212, and an outer member 213.

  The inner member 211 is a cylindrical member having an open upper end, an annular bottom member 211a, a cylindrical inner wall member 211b extending upward from the inner edge of the bottom member 211a, and an outer edge of the bottom member 211a. A cylindrical outer wall member 211c extending upward from the portion, and a cylindrical guide wall 211d erected between the inner wall member 211b and the outer wall member 211c. The guide wall 211d extends upward from the bottom member 211a, and its upper end portion is curved inwardly upward. At least the vicinity of the tip of the inner wall member 211b is accommodated in the inner space of the bowl-shaped member 141 provided in the casing 14 of the spin chuck 1.

  The bottom member 211a is formed with a drainage groove (not shown) communicating with the space between the inner wall member 211b and the guide wall 211d. The drainage groove is connected to a factory drainage line. The drainage groove is connected to an exhaust fluid mechanism that forcibly exhausts the groove and places the space between the inner wall member 211b and the guide wall 211d in a negative pressure state. The space between the inner wall member 211b and the guide wall 211d is a space for collecting and draining the processing liquid used for processing the substrate 9, and the processing liquid collected in this space is discharged from the drain groove. Drained.

  The bottom member 211a is formed with a first recovery groove (not shown) that communicates with the space between the guide wall 211d and the outer wall member 211c. The first collection groove is connected to the first collection tank. The first recovery groove is connected to an exhaust liquid mechanism that forcibly exhausts the groove and places the space between the guide wall 211d and the outer wall member 211c in a negative pressure state. The space between the guide wall 211d and the outer wall member 211c is a space for collecting and recovering the processing liquid used for processing the substrate 9, and the processing liquid collected in this space is the first recovery groove. Through the first recovery tank.

  The middle member 212 is a cylindrical member having an open upper end, and is provided outside the guide wall 211 d of the inner member 211. The upper part of the middle member 212 is curved inward and upward, and the upper edge of the middle member 212 is bent along the upper edge of the guide wall 211d.

  An inner peripheral wall member 212a extending downward along the inner peripheral surface and an outer peripheral wall member 212b extending downward along the outer peripheral surface are formed at the lower portion of the middle member 212. The inner peripheral wall member 212a is accommodated between the guide wall 211d and the outer wall member 211c of the inner member 211 in a state where the inner member 211 and the middle member 212 are close to each other (the state shown in FIG. 1). The lower end of the outer peripheral wall member 212b is attached to the inner edge of the annular bottom member 212c. A cylindrical outer wall member 212d extending upward is erected from the outer edge portion of the bottom member 212c.

  The bottom member 212c is formed with a second recovery groove (not shown) communicating with the space between the outer peripheral wall member 212b and the outer wall member 212d. The second collection groove is connected to the second collection tank. The second recovery groove is connected to an exhaust fluid mechanism that forcibly exhausts the inside of the groove and places the space between the outer peripheral wall member 212b and the outer wall member 212d in a negative pressure state. The space between the outer peripheral wall member 212b and the outer wall member 212d is a space for collecting and collecting the processing liquid used for the processing of the substrate 9, and the processing liquid collected in this space is the second recovery liquid. It is recovered in the second recovery tank via the groove.

  The external member 213 is a cylindrical member having an open upper end, and is provided outside the intermediate member 212. The upper part of the outer member 213 is curved inward and upward, and its upper edge 201 is bent slightly inward and downward from the upper edge of the middle member 212 and the upper edge of the inner member 211. Yes. In a state where the inner member 211, the middle member 212, and the outer member 213 are close to each other (the state shown in FIG. 1), the upper edge of the middle member 212 and the upper edge of the inner member 211 are bent of the outer member 213. Covered by the done part.

  An inner peripheral wall member 213a is formed below the outer member 213 so as to extend downward along the inner peripheral surface. The inner peripheral wall member 213a is accommodated between the outer peripheral wall member 212b and the outer wall member 212d of the intermediate member 212 in a state where the intermediate member 212 and the outer member 213 are close to each other (the state shown in FIG. 1).

  The cup 21 is provided with a cup drive mechanism 22 that moves the cup 21 up and down. The cup drive mechanism 22 is configured by a stepping motor, for example. The cup drive mechanism 22 raises and lowers the three members 211, 212, and 213 included in the cup 21 independently.

  Each of the inner member 211, the middle member 212, and the outer member 213 receives the drive of the cup drive mechanism 22 and is moved between the upper position and the lower position. Here, the upper positions of the members 211, 212, and 213 are positions at which the upper end edges of the members 211, 212, and 213 are disposed on the sides of the substrate 9 held on the spin base 11. On the other hand, the lower positions of the members 211, 212, and 213 are positions where the upper edge portions of the members 211, 212, and 213 are disposed below the upper surface of the spin base 11. However, the cup drive mechanism 22 is electrically connected to the control unit 5 and operates under the control of the control unit 5 (see FIG. 2). That is, the position of the cup 21 (specifically, the position of each of the inner member 211, the middle member 212, and the outer member 213) is controlled by the control unit 5.

  Pointing to the state in which the external member 213 is disposed at the lower position (that is, the state where all of the inner member 211, the middle member 212, and the outer member 213 are disposed at the lower position), "It is in a retreat position." While the substrate 9 is being carried in and out of the spin base 11, the cup 21 is disposed at the retracted position.

  On the other hand, the state in which the outer member 213 is disposed at the upper position is referred to as “the cup 21 is at the processing position”. However, the state of “the cup 21 is in the processing position” includes the following three states. The first state is a state in which all of the inner member 211, the middle member 212, and the outer member 213 are arranged at the upper position (the state shown in FIG. 1). In this state, the processing liquid splashed from the substrate 9 held by the spin chuck 1 is collected in the space between the inner wall member 211b of the inner member 211 and the guide wall 211d and drained from the drainage groove. . The second state is a state in which the inner member 211 is disposed at the lower position and the middle member 212 and the outer member 213 are disposed at the upper position. In this state, the processing liquid splashed from the substrate 9 held by the spin chuck 1 is collected in the space between the guide wall 211d of the inner member 211 and the outer wall member 211c, and is collected in the first collection tank. The The third state is a state in which the inner member 211 and the middle member 212 are disposed at the lower position and the outer member 213 is disposed at the upper position. In this state, the processing liquid splashed from the substrate 9 held by the spin chuck 1 is collected in the space between the outer peripheral wall member 212b and the outer wall member 212d of the intermediate member 212 and recovered in the second recovery tank. Is done.

<First treatment liquid supply unit 3>
The first processing liquid supply unit 3 supplies the processing liquid to the substrate 9 held on the spin chuck 1. The first processing liquid supply unit 3 includes a first nozzle (scan nozzle) 31 that discharges the processing liquid, and a first processing liquid supply system 32 that is a piping system that supplies the processing liquid thereto.

  Specifically, the first processing liquid supply system 32 includes, for example, a first processing liquid supply source 321, a pipe 322, and a first valve 323, and the first processing liquid supply source 321 includes the first valve 323. It is configured to be connected to the scan nozzle 31 via an inserted pipe 322. However, the first processing liquid supply source 321 is a supply source that supplies the first processing liquid. The first treatment liquid is, for example, a chemical liquid (here, a chemical liquid that removes the polymer on the surface of the substrate 9 and removes the hard mask 908 formed on the surface of the substrate 9. A polymer removing solution containing an organic solvent).

  In this configuration, when the first valve 323 is opened, the first processing liquid supplied from the first processing liquid supply source 321 is discharged from the scan nozzle 31. However, the first valve 323 is electrically connected to the control unit 5 and is opened and closed under the control of the control unit 5 (see FIG. 2). That is, the discharge mode of the processing liquid from the scan nozzle 31 (specifically, the discharge start timing, the discharge end timing, the discharge flow rate, etc.) is controlled by the control unit 5.

  The scan nozzle 31 is attached to the tip of an arm 33 that extends horizontally. The base end portion of the arm 33 is connected to the upper end of the elevating shaft 34 that is arranged in such a posture that the axis is along the vertical direction. The lifting shaft 34 is disposed on the nozzle base 35.

  The nozzle base 35 is provided with a nozzle driving unit 36 for driving the scan nozzle 31. The nozzle drive unit 36 includes, for example, a rotation drive unit (for example, a servo motor) that rotates the lift shaft 34 around its axis, and a lift drive unit (for example, a stepping motor) that expands and contracts the lift shaft 34 along the axis. , Including. When the nozzle drive unit 36 rotates the lift shaft 34, the scan nozzle 31 moves along an arc orbit in the horizontal plane, and when the nozzle drive unit 36 expands and contracts the lift shaft 34, the scan nozzle 31 moves the spin chuck. It moves in the direction of approaching and separating from the upper surface of the substrate 9 held by 1.

  However, the nozzle drive unit 36 is electrically connected to the control unit 5 and operates under the control of the control unit 5. That is, the position of the scan nozzle 31 is controlled by the control unit 5. Note that the control unit 5 arranges the scan nozzle 31 at a position that does not interfere with the transport path of the substrate 9 (a retreat position) while the processing liquid is not discharged from the scan nozzle 31.

<Second treatment liquid supply unit 4>
The second processing liquid supply unit 4 supplies the processing liquid to the substrate 9 held on the spin chuck 1. The second processing liquid supply unit 4 includes a second nozzle (fixed nozzle) 41 that discharges the processing liquid, and a second processing liquid supply system 42 that is a piping system that supplies the processing liquid thereto.

  Specifically, the second processing liquid supply system 42 includes, for example, a second processing liquid supply source 421, a pipe 422, and a second valve 423, and the second processing liquid supply source 421 includes a second valve 423. It is configured to be connected to the fixed nozzle 41 via the inserted pipe 422. However, the second processing liquid supply source 421 is a supply source that supplies the second processing liquid. The second treatment liquid is, for example, a rinse liquid (specifically, for example, pure water) that rinses the chemical liquid.

  In this configuration, when the second valve 423 is opened, the second processing liquid supplied from the second processing liquid supply source 421 is discharged from the fixed nozzle 41. However, the second valve 423 is electrically connected to the control unit 5 and is opened and closed under the control of the control unit 5 (see FIG. 2). That is, the discharge mode of the processing liquid from the fixed nozzle 41 (specifically, the discharge start timing, the discharge end timing, the discharge flow rate, etc.) is controlled by the control unit 5.

  The fixed nozzle 41 is disposed on the nozzle base 44 via a support shaft 43. The fixed nozzle 41 is at a predetermined position (specifically, on the upper surface of the substrate 9 on which the processing liquid discharged from the fixed nozzle 41 is held by the spin chuck 1 while the processing liquid is being discharged from now on. It is fixedly supported at a position where the liquid is deposited at the center (rotation center). However, the fixed nozzle 41 may be provided with a drive unit for moving the fixed nozzle 41 between the above-defined position and a position that does not interfere with the transport path of the substrate 9 (a retreat position). .

<Control unit 5>
The control unit 5 is a device that controls the operation of each unit in the substrate processing apparatus 100. The configuration of the control unit 5 as hardware can be the same as that of a general computer. That is, the control unit 5 stores, for example, a CPU that performs various arithmetic processes, a ROM that is a read-only memory that stores basic programs, a RAM that is a readable and writable memory that stores various information, control software, data, and the like. It has a magnetic disk to keep. In the control unit 5, various functional units that control each unit of the substrate processing apparatus 100 are realized by the CPU as the main control unit performing arithmetic processing according to the procedure described in the program. However, some or all of the functional units implemented in the control unit 5 may be implemented by hardware using a dedicated logic circuit or the like. The memory or hard disk of the control unit 5 stores a processing recipe that defines the content of processing to be executed by the substrate processing apparatus 100.

  As shown in FIG. 2, the control unit 5 is electrically connected to the rotation drive unit 13, the holding member 15, the cup drive mechanism 22, the first valve 323, the second valve 423, the nozzle drive unit 36, and the like. Yes. The control unit 5 operates each of these units according to the processing recipe, so that a series of processes for the substrate 9 proceeds.

<2. Substrate 9>
Next, a state near the surface layer of the substrate 9 to be processed by the substrate processing apparatus 100 will be described with reference to FIG. FIG. 3 is a side sectional view schematically showing a state near the surface layer of the substrate 9.

  The substrate 9 to be processed by the substrate processing apparatus 100 is, for example, a semiconductor wafer from which a metal pattern is exposed. The metal pattern may be a single film of copper, tungsten, or other metal, or may be a multilayer film in which a plurality of metal films are stacked. The multilayer film may be, for example, a laminated film including a copper film and a CoWP (cobalt-tungsten-phosphorus) film laminated on the copper film. The CoWP film is an example of a cap film for preventing diffusion.

  For example, an interlayer insulating film 901 is formed on the surface of the substrate 9. A lower wiring trench 902 is formed in the interlayer insulating film 901 by digging from the upper surface. A copper wiring 903 is embedded in the lower wiring groove 902. On the interlayer insulating film 901, a low dielectric constant insulating film 905 is stacked as an example of a film to be processed via an etch stopper film 904. An upper wiring trench 906 is formed in the low dielectric constant insulating film 905 by digging from the upper surface. Further, a via hole 907 reaching the surface of the copper wiring 903 from the bottom surface of the upper wiring groove 906 is formed in the low dielectric constant insulating film 905. Copper is buried in the upper wiring groove 906 and the via hole 907 in a lump.

  The upper wiring groove 906 and the via hole 907 are subjected to dry etching after a hard mask 908 is formed on the low dielectric constant insulating film 905, and a portion exposed from the hard mask 908 in the low dielectric constant insulating film 905 is exposed. It is formed by removing. By forming the upper wiring groove 906, the via hole 907, and the like, a recessed portion (recessed portion 90) is formed on the surface of the substrate 9.

  By the way, at the time of dry etching, a reaction product (polymer residue) 900 containing components of the low dielectric constant insulating film 905 adheres to the surface of the hard mask 908, the inner surface of the upper wiring groove 906, and the via hole 907. That is, there is a high possibility that the polymer residue 900 is attached to the surface of the substrate 9 after dry etching (particularly, in the recess 90).

  The substrate processing apparatus 100 performs, for example, a process in which removal of the hard mask 908 and removal of the polymer residue 900 are simultaneously performed on the substrate 9 with the substrate 9 after such dry etching as a processing target, for example. . Specifically, the hard mask 908 is peeled off from the substrate 9 by wet etching, and polymer residues (reaction products generated during dry etching (reaction products including components of the low dielectric constant insulating film 905), And the process which removes the reaction product (reaction product containing the component of the hard mask 908) which arises at the time of wet etching can be given.

<3. Operation of Substrate Processing Apparatus 100>
An example of the flow of processing performed in the substrate processing apparatus 100 will be described with reference to FIGS. 1 and 4. FIG. 4 is a diagram illustrating an example of the flow of processing performed in the substrate processing apparatus 100. In the substrate processing apparatus 100, a series of processes described below are executed under the control of the control unit 5.

  First, in a state where the cup 21 and the scan nozzle 31 are disposed at the respective retreat positions, a transfer robot (not shown) carries the substrate 9 into the substrate processing apparatus 100, and the substrate 9 is moved to the surface (upper wiring). The main surface on the side where the groove 906 and the via hole 907 are formed is disposed on the spin base 11 in a posture (step S1). The substrate 9 disposed on the spin base 11 is held by a group of holding members 15. As a result, the substrate 9 is held in a substantially horizontal position on the spin base 11.

  When the substrate 9 is held on the spin base 11, the rotation of the spin base 11 is started after the cup 21 is disposed at the processing position. As a result, the substrate 9 held in a horizontal position on the spin base 11 starts to rotate in a horizontal plane (that is, around a vertical rotation axis) (step S2).

  Subsequently, chemical treatment is performed (step S3). In the chemical treatment, the first valve 323 is opened and directed from the scan nozzle 31 toward the surface of the substrate 9 to be rotated (the main surface facing upward and the surface on which the concave portion 90 is formed). Then, the chemical solution is discharged. However, here, in parallel with the discharge of the chemical solution, the nozzle drive unit 36 moves the scan nozzle 31 from the central portion of the substrate 9 in a horizontal plane adjacent to the surface of the substrate 9 on the spin base 11 in a non-contact state. The first position (that is, the position at which the chemical liquid discharged from the scan nozzle 31 lands on the surface center portion P1 of the substrate 9) and the circumference of a virtual circle defined on the surface of the substrate 9 (however, The virtual circle is concentric with the center of rotation of the substrate 9 and has a diameter smaller than the diameter of the substrate 9, and the circumference of the virtual circle is hereinafter also referred to as “scan outer peripheral edge E”). It is reciprocated along an arc orbit connecting the second position (that is, the position at which the chemical discharged from the scan nozzle 31 is deposited at the position P2 on the scan outer periphery E) (see FIG. 5).

  Here, the outer scanning edge E will be specifically described with reference to FIG. FIG. 5 is a diagram for explaining the outer scanning edge E. FIG.

  When the processing liquid is supplied to the substrate 9 to be rotated, the magnitude of the speed component in the horizontal direction of the processing liquid at each position within the surface of the substrate 9 is the force acting on the processing liquid (the rotational speed of the substrate 9). The magnitude of the force acting on the processing liquid increases from the center of the substrate 9 toward the peripheral portion. . That is, the magnitude of the velocity component in the horizontal direction increases as it approaches the peripheral edge from the center of the substrate 9.

  Incidentally, as described above, the concave portion 90 exists on the surface of the substrate 9 to be processed in the substrate processing apparatus 100. The size of the upward speed component of the processing liquid in the recess 90 (that is, the speed component that contributes to the discharge of the processing liquid from the recess 90, hereinafter simply referred to as “upward speed component”) is as follows. The larger the velocity component in the horizontal direction of the treatment liquid flowing on the upper surface of the film, the larger the value. That is, the magnitude of the upward velocity component also increases as it approaches the peripheral edge from the center of the substrate 9. Theoretically, this upward velocity component is known to increase in a quadratic function that is convex upward as it approaches the peripheral edge from the center of the substrate 9, as shown in FIG.

  The position of the scanning outer peripheral edge E is defined based on, for example, the speed of the processing liquid in the recess 90 at each position in the surface of the substrate 9 (specifically, for example, the magnitude of the upward speed component). Specifically, for example, the upward velocity component of the processing liquid in the recess 90 at the peripheral edge of the substrate 9 is “Ve”, and the upward velocity component of the processing liquid in the recess 90 is half of “Ve” (ie, The position where the upward speed component is “Ve / 2”) is the outer scanning edge E. In the case of the substrate 9 having a diameter of 300 mm, the separation distance between the center of the substrate 9 and the scanning outer peripheral edge E is, for example, 50 mm. The region surrounded by the scan outer peripheral edge E is a region that includes the rotation center of the substrate 9 and does not include the peripheral portion of the substrate 9. Hereinafter, this region is also referred to as a “central region C”.

  When the nozzle drive unit 36 moves the scan nozzle 31 back and forth between the first position and the second position while the substrate 9 is rotating, the liquid deposition position of the chemical liquid discharged from the scan nozzle 31 is the center. The region moves within the region C (scanning), and the chemical solution reaches all positions in the central region C. The chemical solution supplied to the central region C spreads toward the periphery of the substrate 9 due to the centrifugal force generated by the rotation of the substrate 9. As a result, the chemical solution spreads over the entire surface of the substrate 9 and a liquid film of the chemical solution covering the entire surface of the substrate 9 is formed. As a matter of course, the recess 90 is also filled with the chemical solution. By forming a liquid film of a chemical solution covering the surface of the substrate 9, the hard mask 908 formed on the surface of the substrate 9 reacts with the chemical solution and is etched, and the surface of the substrate 9 (flat portion and The polymer residue in the recess 90 is removed by reacting with the chemical solution. However, since fresh chemical solutions are successively supplied to the substrate 9, the chemical solution film covering the entire surface of the substrate 9 is successively replaced with fresh chemical solution films. The old chemical liquid swept away by the newly supplied chemical liquid is shaken off from the periphery of the substrate 9 by the centrifugal force caused by the rotation of the substrate 9. The chemical liquid scattered from the substrate 9 is received by the cup 21 and collected.

  While the chemical solution is supplied to the substrate 9 (that is, in parallel with the supply of the chemical solution to the substrate 9), the rotation speed of the spin base 11 is maintained while maintaining the chemical film covering the entire surface of the substrate 9. (That is, the rotation speed of the substrate 9) is switched between the first rotation speed V1 and the second rotation speed V2 at least twice (see FIG. 6). This point will be described in detail later. As will be apparent later, by switching the rotation speed of the substrate 9, the fluidity of the chemical solution on the substrate 9 (particularly, the chemical solution in the recess 90) is enhanced. As a result, the polymer residue is sufficiently removed from the recess 90.

  However, in order to optimally process the surface of the substrate 9, the rotational speed (the magnitude of the rotational speed) of the substrate 9 is defined by the processing conditions (the amount of processing liquid supplied, the type of processing liquid) and the like. What is necessary is just to control so that an upper / lower limit allowable speed may not be exceeded. For example, when the supply amount of the processing liquid to the substrate 9 is 1.0 L / min, the chemical liquid can be recovered in the recovery cup 21 unless the rotation speed of the substrate 9 is less than 250 rpm. If the rotation speed does not exceed 1000 rpm, it is possible to suppress the generation of foreign matter generated by rebounding from the recovery cup 21 without lowering the liquid temperature at the outer peripheral portion of the surface of the substrate 9. That is, in this case, in order to optimally treat the surface of the substrate 9, the rotational speed corresponding to the first rotational speed V1 should be 250 rpm or higher, and the rotational speed corresponding to the second rotational speed V2 should be 1000 rpm or lower. That's fine. As a result, the generation of foreign matter on the pattern formed on the substrate 9 is avoided.

  When a predetermined time elapses after the first valve 323 is opened, the first valve 323 is closed, the discharge of the chemical solution from the scan nozzle 31 is stopped, and the scan nozzle 31 is moved to the retracted position. . This is the end of the chemical treatment.

  Subsequently, a rinsing process is performed (step S4). In the rinsing process, the second valve 423 is opened, and the rinsing liquid is discharged from the fixed nozzle 41 toward the center of the rotated substrate 9. That is, in the rinsing process, the rinsing liquid is supplied to the surface of the substrate 9 in a state in which the rinsing liquid landing position is fixed to the central portion (rotation center) of the substrate 9. The rinse liquid discharged from the fixed nozzle 41 lands on the center of the substrate 9 and then spreads toward the periphery of the substrate 9 due to the centrifugal force generated by the rotation of the substrate 9. As a result, the rinsing liquid spreads over the entire surface of the substrate 9 and a liquid film of the rinsing liquid covering the entire surface of the substrate 9 is formed. By forming a liquid film of the rinsing liquid covering the surface of the substrate 9, the chemical liquid containing the polymer residue remaining on the substrate 9 is rinsed away. However, since the fresh rinsing liquid is supplied to the substrate 9 one after another, the liquid film of the rinsing liquid covering the entire surface of the substrate 9 is successively replaced with the liquid film of the fresh rinsing liquid. The old rinse liquid swept away by the newly supplied rinse liquid is shaken off from the periphery of the substrate 9 together with the chemical liquid containing the polymer residue by the centrifugal force generated by the rotation of the substrate 9. The rinse liquid splashed from the substrate 9 is received by the cup 21 and collected.

  While the rinse liquid is supplied to the substrate 9 (that is, in parallel with the supply of the rinse liquid to the substrate 9), the spin base 11 is maintained while maintaining the liquid film of the rinse liquid covering the entire surface of the substrate 9. (Ie, the rotation speed of the substrate 9) is switched between the first rotation speed V1 and the second rotation speed V2 at least twice (see FIG. 6). This point will be described in detail later. As will be apparent later, the fluidity of the rinsing liquid on the substrate 9 (particularly, the rinsing liquid in the recess 90) is increased by switching the rotation speed of the substrate 9. As a result, the polymer residue is sufficiently removed from the recess 90.

  When a predetermined time elapses after the second valve 423 is opened, the second valve 423 is closed and the discharge of the rinsing liquid from the fixed nozzle 41 is stopped.

  Subsequently, a drying process is performed (step S5). Specifically, in a state where the discharge of the processing liquid toward the substrate 9 is stopped, the rotation speed of the spin base 11 is higher than the high rotation speed (for example, the first rotation speed V1 and the second rotation speed V2). High rotational speed). Thereby, the processing liquid remaining on the substrate 9 on the spin base 11 is shaken off and removed from the substrate 9, and the substrate 9 is dried (so-called spin dry).

  When a predetermined time elapses after the spin base 11 starts to rotate at a high rotational speed, the rotation of the spin base 11 is stopped.

  Subsequently, the cup 21 is moved to the retracted position, the holding member 15 opens the substrate 9, and a transfer robot (not shown) carries the substrate 9 out of the substrate processing apparatus 100 (step S6). Thus, a series of processes for the substrate 9 is completed.

<4. Switching mode of rotation speed of substrate 9>
As described above, the process of covering the entire surface of the substrate 9 while the chemical process (step S3) and the rinse process (step S4) are performed (that is, while the processing liquid is supplied to the substrate 9). While maintaining the liquid film of the liquid (chemical liquid or rinsing liquid), the rotation speed of the spin base 11 (that is, the rotation speed of the substrate 9) is between the first rotation speed V1 and the second rotation speed V2. Can be switched more than once. However, the first rotation speed V1 and the second rotation speed V2 are different rotation speeds.

  Switching of the rotation speed of the substrate 9 will be described with reference to FIGS. FIG. 6 is a diagram illustrating an example of a manner of switching the rotation speed of the substrate 9. FIG. 7 is a diagram for explaining the direction of the force received by the processing liquid Q in the recess 90 in each time zone when the rotation speed of the substrate 9 is switched in the manner illustrated in FIG. However, in the following description, for convenience, it is assumed that the counterclockwise rotation direction in FIG. 7 is a positive direction, and the first rotation speed V1 is higher than the second rotation speed V2. In FIG. 7, only one concave portion 90 is shown for easy understanding of the drawing, but in general, a plurality of concave portions 90 exist on the substrate 9.

  While the substrate 9 is rotating (that is, a time zone in which the rotation speed of the substrate 9 is not zero (“0”)), the treatment liquid Q in the recess 90 has a force in a direction away from the rotation center 910 of the substrate 9. (Centrifugal force) is applied. This centrifugal force increases as the rotation speed of the substrate 9 increases. Further, while the rotation speed of the substrate 9 is changing (that is, while the acceleration (angular acceleration) in the rotation direction of the substrate 9 is not zero), in addition to the centrifugal force, A force (inertial force) in the rotation direction of the substrate 9 is applied. This inertial force is in the opposite direction to the angular acceleration of the substrate 9 and increases as the absolute value of the angular acceleration increases.

  A time zone in which the substrate 9 is rotated at a relatively high first rotation speed V1 (that is, a time zone in which the substrate 9 is being rotated at a high speed at a constant speed, hereinafter also referred to as a “first constant speed time zone”). ) Since the inertial force applied to the processing liquid Q in the recess 90 is zero in T1, only a relatively large centrifugal force F1 is applied to the processing liquid Q in the recess 90. Therefore, in the first constant velocity time zone T1, the processing liquid Q in the recess 90 flows in the direction of the centrifugal force F1 (3 o'clock direction in FIG. 7).

  The time zone in which the rotation speed of the substrate 9 is switched from the first rotation speed V1 to the second rotation speed V2 (that is, the time zone in which the rotation speed of the substrate 9 is decelerated, hereinafter referred to as “deceleration time zone”) T2) The inertial force K1 in the positive rotation direction is applied to the processing liquid Q in the recess 90, while the magnitude of the centrifugal force applied to the processing liquid Q decreases with time. That is, in the deceleration time zone T2, as the time passes, the direction of the force received by the processing liquid Q rotates in the positive rotation direction (F2 (1), F2 (2),..., F2 (n )). Therefore, in this time zone T2, the direction in which the processing liquid Q in the recess 90 flows changes with time between the 3 o'clock direction and the 12 o'clock direction in FIG.

  A time zone in which the substrate 9 is rotated at a relatively low second rotation speed V2 (that is, a time zone in which the substrate 9 is rotated at a low speed at a constant speed, and is hereinafter also referred to as a “second constant speed time zone”). ) Since T3 has no inertial force applied to the processing liquid Q in the recess 90, only a relatively small centrifugal force F3 is applied to the processing liquid Q in the recess 90. Accordingly, in the second constant velocity time zone T3, the processing liquid Q in the recess 90 flows in the direction of the centrifugal force F3 (3 o'clock direction in FIG. 7).

  The time zone in which the rotation speed of the substrate 9 is switched from the second rotation speed V2 to the first rotation speed V1 (that is, the time zone in which the rotation speed of the substrate 9 is accelerated, hereinafter referred to as “acceleration time zone”) In T4, the inertial force K2 in the negative rotation direction is applied to the processing liquid Q in the recess 90, while the centrifugal force applied to the processing liquid Q increases with time. That is, in the acceleration time zone T4, the direction of the force received by the processing liquid Q rotates in the positive rotation direction as time passes (F4 (1), F4 (2),..., F4 (n )). Therefore, in this time zone T4, the direction in which the processing liquid Q in the recess 90 flows changes with time between the 6 o'clock direction and the 3 o'clock direction in FIG.

  As described above, when the rotation speed of the spin base 11 is switched twice or more between the first rotation speed V1 and the second rotation speed V2, the direction in which the processing liquid Q flows in the recess 90 changes with time. It changes greatly and the processing liquid Q in the recessed part 90 is shaken greatly. However, “two or more times” means that acceleration and deceleration are performed once. That is, the fluidity of the processing liquid Q in the recess 90 is increased. As a result, the processing liquid Q is less likely to stay in the recess, and the processing liquid Q is sufficiently discharged from the recess. As described above, the liquid film of the processing liquid covering the surface of the substrate 9 is successively replaced with fresh processing liquid. For this reason, even in the recess, the old processing liquid is discharged from the recess together with the polymer residue, while the fresh processing liquid flows into the recess and the inside of the recess is successively replaced with the fresh processing liquid. Thereby, the polymer residue in the recess is sufficiently scraped out from the recess, and the polymer residue is sufficiently removed from the recess.

  For example, when the rotation speed of the substrate 9 is changed in the manner illustrated in FIG. 6, as an example, the rotation speed corresponding to the first rotation speed V1 is set to 1000 rpm, and the rotation speed corresponding to the second rotation speed V2 is set to 400 rpm. The first constant speed time zone T1 may be 5 seconds, the deceleration time zone T2 may be 1 second, the second constant speed time zone T3 may be 5 seconds, and the acceleration time zone T4 may be 1 second. In this case, switching between the first rotation speed V1 and the second rotation speed V2 is performed 10 times per minute.

  However, the mode of switching the rotation speed of the substrate 9 is not limited to that illustrated in FIG. In each of FIGS. 8 to 10, another example of a switching mode of the rotation speed of the substrate 9 is shown.

  For example, a first constant speed time zone T1 in which the substrate 9 is rotated at a constant speed at a first rotation speed V1 and a second constant speed time zone T3 in which the substrate 9 is rotated at a constant speed at a second rotation speed V2 are illustrated in FIG. 6 may be the same length, and as shown in FIG. 8, one of the first constant speed time zone T1 and the second constant speed time zone T3 is the other time zone. It may be longer than the time zone.

  Further, for example, the switching between the first rotation speed V1 and the second rotation speed V2 may be performed intermittently as shown in FIG. 6, or continuously as shown in FIG. It may be done. However, intermittently switching means that the rotation speed of the substrate 9 is reduced after a predetermined time has elapsed after the rotation speed of the substrate 9 reaches the first rotation speed V1. This means that, after a predetermined time has elapsed after the rotation speed of the substrate 9 reaches the second rotation speed V2, acceleration of the rotation speed is started. In addition, the continuous switching means that, specifically, when the rotation speed of the substrate 9 reaches the first rotation speed V1, the rotation speed of the substrate 9 starts to be reduced. This means that the acceleration of the rotational speed is started when the second rotational speed V2 is reached.

  When switching is performed intermittently, there are constant speed time periods T1, T3 in which the substrate 9 is rotated at a constant speed. The constant velocity time zones T1 and T3 in which the substrate 9 is rotated at a constant velocity are the time zones in which the processing liquid supplied to the substrate 9 spreads rapidly toward the periphery of the substrate 9 (that is, depending on the newly supplied chemical solution). The surface of the substrate 9 is secured by securing at least one of the first constant velocity time zone T1 and the second constant velocity time zone T3. An advantage is obtained in that the liquid film of the processing liquid covering the entire area is smoothly (rapidly) replaced with fresh processing liquid. On the other hand, when switching is performed continuously, the constant velocity time zones T1 and T3 do not exist. According to this aspect, since the number of rotation speed switching can be increased, the fluidity of the processing liquid in the recess can be particularly improved. For example, the second constant speed time zone T3 rotated at a constant speed at a relatively low rotational speed is set to zero, and the first constant speed time zone T1 rotated at a constant speed at a relatively high rotational speed is set larger than zero. Also good. In this case, it is possible to obtain the effect of improving the fluidity of the processing liquid in the recesses by increasing the number of times of switching while promoting the replacement of the liquid film of the processing liquid covering the entire surface of the substrate 9.

  Further, for example, the rotation direction of the substrate 9 rotated at the first rotation speed V1 and the rotation direction of the substrate 9 rotated at the second rotation speed V2 may be the same direction as shown in FIG. (That is, the first rotation speed V1 and the second rotation speed V2 may have the same sign), or may be in opposite directions as shown in FIG. 10 (that is, the first rotation speed). V1 and the second rotation speed V2 may be opposite signs).

  However, if the rotation direction of the substrate 9 rotated at the first rotation speed V1 is the same as the rotation direction of the substrate 9 rotated at the second rotation speed V2, the moment when the rotation speed of the substrate 9 becomes zero. (That is, the moment when the centrifugal force acting on the processing liquid on the substrate 9 becomes zero) does not occur. Therefore, the excessive processing liquid on the substrate 9 is always shaken off vigorously from the peripheral edge of the substrate 9, so that the shaken processing liquid is reliably received by the inner wall of the cup 21. That is, if the rotation direction of the substrate 9 rotated at the first rotation speed V1 and the rotation direction of the substrate 9 rotated at the second rotation speed V2 are the same direction, excess processing liquid on the substrate 9 is transferred to the substrate. It is possible to avoid the occurrence of a situation such as dripping from the peripheral edge of 9 and failing to be recovered.

  In order to reliably receive the processing liquid shaken off from the peripheral edge of the substrate 9 by the inner wall of the cup 21, the rotational speed (the magnitude of the rotational speed) of the substrate 9 may not fall below a predetermined lower limit allowable speed. Particularly preferably, in order to prevent the processing liquid shaken off from the peripheral edge of the substrate 9 from bouncing off the inner wall of the cup 21 and reattaching to the substrate 9, the rotational speed of the substrate 9 exceeds a predetermined upper limit allowable speed. Preferably not. Specific values of the lower limit allowable speed and the upper limit allowable speed are defined by the distance between the peripheral edge of the substrate 9 on the spin base 11 and the cup 21, the type of processing liquid, and the like. As an example, the rotation speed corresponding to the lower limit allowable speed is 300 rpm, and the rotation speed corresponding to the upper limit allowable speed is 1000 rpm.

  In any of the rotation modes illustrated in FIGS. 6 and 8 to 10, the fluidity of the processing liquid on the substrate 9 increases as the difference ΔV between the first rotation speed V1 and the second rotation speed V2 increases. Therefore, the difference ΔV is preferably sufficiently large (for example, 100 rpm or more). In addition, the fluidity of the processing liquid on the substrate 9 increases as the acceleration magnitude at the time of switching between the first rotation speed V1 and the second rotation speed V2 increases. Therefore, the magnitude of this acceleration is preferably sufficiently large (for example, 250 (rpm / s) or more).

<5. Effect>
According to the above embodiment, while supplying the processing liquid to the substrate 9, the rotation speed of the substrate 9 is switched between the first rotation speed V1 and the second rotation speed V2 two or more times. According to this configuration, the processing liquid on the substrate 9 (particularly, the processing liquid Q in the recess 90) is greatly shaken. Thereby, the fluidity of the processing liquid on the surface of the substrate 9 (particularly, the fluidity of the processing liquid Q in the recess 90) is increased, and the substrate 9 can be processed efficiently.

  Further, according to the above-described embodiment, in the chemical processing, the processing liquid is supplied to the surface of the substrate 9 while moving the landing position of the processing liquid. On the surface of the substrate 9, a region where the processing liquid is supplied while the processing liquid landing position is moved (that is, a region where the processing liquid discharged from the moved scan nozzle 31 is deposited, hereinafter referred to as a “scanning region”. In other words, since the processing liquid arrives from directly above each recess 90, the upward velocity component of the processing liquid Q in the recess 90 increases. Thereby, the fluidity of the processing liquid Q in the recess 90 is increased, and the processing liquid is particularly difficult to stay in the recess 90. That is, the fluidity of the processing liquid on the surface of the substrate 9 can be particularly enhanced by supplying the processing liquid to the surface of the substrate 9 while moving the landing position of the processing liquid.

  Further, according to the above embodiment, the liquid landing position is moved in the central region C (that is, the central region C that includes the rotation center of the substrate 9 and does not include the peripheral portion of the substrate 9). . That is, here, the central region C in which the fluidity of the processing liquid tends to be low due to the relatively small centrifugal force is set as the scan region. In this central region C, the rotation speed of the substrate 9 is switched. In addition, the fluidity of the treatment liquid can be enhanced by the movement of the landing liquid position. According to this configuration, the fluidity of the processing liquid can be sufficiently increased over the entire surface of the substrate 9.

  Further, according to the configuration in which the liquid landing position is moved in the central region C that does not include the peripheral portion of the substrate 9, that is, the scan region is limited to the region that does not include the peripheral portion of the substrate 9, The processing liquid deposited near the rotation center of the liquid spreads to the peripheral edge of the substrate 9 due to centrifugal force and effectively acts on a wide area within the surface of the substrate 9. As a result, the amount of processing liquid used can be reduced, and the uniformity of processing over the entire surface of the substrate 9 can be improved. For example, when a process (etching process) for removing the hard mask 908 by a chemical process is performed, the uniformity of the etching amount over the entire surface of the substrate 9 can be improved.

  If the entire area of the surface of the substrate 9 is set as a scan region, the processing liquid deposited near the peripheral edge of the substrate 9 is immediately shaken off from the substrate 9 as it is subjected to centrifugal force. That is, the processing liquid that has landed near the peripheral edge of the substrate 9 is shaken off from the substrate 9 while acting only on a very narrow region within the surface of the substrate 9. As described above, if the entire surface of the substrate 9 is set as a scan region, a time zone in which the processing liquid cannot be used effectively occurs, and the total amount of processing liquid used increases. Further, during the time zone when the processing liquid is deposited near the peripheral edge of the substrate 9, the processing near the center is difficult to proceed because the fresh processing liquid does not rotate near the center of the substrate 9. As a result, processing non-uniformity is likely to occur between the vicinity of the center portion and the periphery of the substrate 9. For example, when the hard mask 908 is peeled off, if the entire surface of the substrate 9 is a scan region, the etching amount near the center of the substrate 9 is smaller than the etching amount near the periphery of the substrate 9. Tend. As described above, if the entire surface of the substrate 9 is set as the scan region, there is a possibility that the amount of processing liquid used increases and the processing uniformity decreases. On the other hand, in the above embodiment, the scan region is limited to the central region C that does not include the peripheral portion of the substrate 9, so that an increase in the amount of processing liquid used can be suppressed, and the surface of the substrate 9 can be suppressed. The uniformity of processing over the entire area can be improved.

  Further, according to the above embodiment, in the rinsing process, the position where the processing liquid is deposited is fixed to the rotation center of the substrate 9 and the processing liquid is supplied to the surface of the substrate 9. According to this configuration, the processing liquid deposited on the rotation center of the substrate 9 spreads over the entire substrate 9 due to centrifugal force and effectively acts on the entire surface of the substrate 9. As a result, the amount of processing liquid used can be reduced, and the uniformity of processing over the entire surface of the substrate 9 can be improved.

  In the above embodiment, if the rotation direction of the substrate 9 rotated at the first rotation speed V1 is the same as the rotation direction of the substrate 9 rotated at the second rotation speed V2 (FIG. 6). 8 and FIG. 9), the moment when the rotation speed of the substrate 9 becomes zero does not occur. Therefore, a centrifugal force in a direction away from the rotation center of the substrate 9 always acts on the processing liquid on the substrate 9, and excess processing liquid on the substrate 9 is shaken off from the peripheral edge of the substrate 9. For this reason, it is difficult to cause a situation in which excess processing liquid on the substrate 9 drops from the peripheral edge of the substrate 9 and is not recovered.

  Further, in the above embodiment, if the switching between the first rotation speed V1 and the second rotation speed V2 is performed intermittently (see FIGS. 6, 8, and 10), the angular acceleration of the substrate 9 will be described. Are generated in the time zone in which the substrate 9 is zero (that is, the constant speed time zone in which the substrate 9 is rotated at a constant speed), and in this time zone T1, T3, the liquid film of the processing liquid covering the surface of the substrate 9 is fresh. It is smoothly (rapidly) replaced with a new treatment solution.

<6. Another embodiment>
<6-1. Configuration of Substrate Processing Apparatus 100a>
A substrate processing apparatus 100a according to another embodiment will be described with reference to FIG. FIG. 11 is a diagram showing the configuration of the substrate processing apparatus 100a.

  Similar to the substrate processing apparatus 100 according to the above-described embodiment, the substrate processing apparatus 100a is a single-wafer type apparatus that processes the substrates 9 one by one, and includes a chamber 71, a holding rotation mechanism 72, and a first processing. A liquid supply system 73, a second processing liquid supply system 74, a pressure adjustment unit 75, and a control unit 76 are provided.

  The chamber 71 includes a substantially disc-shaped chamber bottom 711, a substantially cylindrical chamber side wall 712 fixed to the outer periphery of the chamber bottom 711, and a substantially disc-shaped chamber lid that closes the upper opening of the chamber side wall 712. Unit 713. The chamber lid portion 713 is biased to the upper portion of the chamber side wall portion 712, whereby the internal space 70 of the chamber 71 is set as a sealed space. The chamber lid 713 is movable in the vertical direction, and the substrate 9 is carried into and out of the chamber 71 in a state where the chamber lid 713 moves upward and is separated from the chamber side wall 712.

  In the central portion of the chamber lid portion 713, pipes (processing liquid discharge pipe 701 and gas discharge pipe 702) penetrating therethrough are provided. For example, the gas discharge pipe 702 has an annular cross section and is disposed so as to surround the periphery of the processing liquid discharge pipe 701. In addition, a plurality of pipes (suction pipes 703) penetrating the chamber bottom 711 are provided on the outer periphery of the chamber bottom 711 at, for example, an equal pitch in the circumferential direction.

  The holding and rotating mechanism 72 is a rotation holding unit that rotates the substrate 9 around a vertical rotation axis passing through the center of the main surface while holding the substrate 9 in a substantially horizontal posture in the chamber 71. Specifically, the holding and rotating mechanism 72 is, for example, a stator 721 disposed in the circumferential direction inside the chamber side wall 712 and a substantially annular shape disposed inside the stator 721 in the internal space 70 of the chamber 71. A rotor 722, and a holding member 723 provided on the inner peripheral surface of the rotor 722. The rotor 722 is supported by the magnetic force acting on the stator 721 without contacting the stator 721 and the chamber side wall 712, and rotates about the central axis along the vertical direction. The holding member 723 is a substantially annular plate-like member, is fixed to the inner peripheral surface of the rotor 722, and is accommodated in the internal space 70 of the chamber 71 together with the rotor 722. The substrate 9 is held on the holding member 723 by being placed on the holding member 723 in a substantially horizontal posture.

  In this configuration, when the rotor 722 is rotated with the holding member 723 holding the substrate 9, the substrate 9 held by the holding member 723 is moved around a vertical rotation axis passing through the center in the plane. It is rotated. The rotor 722 and the stator 721 are electrically connected to the control unit 76 and operate under the control of the control unit 76. That is, the rotation mode of the substrate 9 (specifically, the rotation start timing, the rotation end timing, the rotation speed (that is, the rotation speed), etc.) is controlled by the control unit 76.

  The first processing liquid supply system 73 includes, for example, a first processing liquid supply source 731 that supplies a first processing liquid (for example, a chemical liquid, specifically, for example, a polymer removal liquid containing an organic solvent). A configuration is provided in which a processing liquid discharge pipe 701 is connected via a pipe 732 in which a single valve 733 is inserted.

  The second processing liquid supply system 74 includes, for example, a second processing liquid supply source 741 that supplies a second processing liquid (for example, a rinsing liquid, specifically, for example, pure water), and a second valve 743. A configuration is provided in which the processing liquid discharge pipe 701 is connected via an inserted pipe 742.

  In this configuration, when the first valve 733 is opened, the first processing liquid supplied from the first processing liquid supply source 731 is discharged from the processing liquid discharge pipe 701. When the second valve 743 is opened, the second processing liquid supplied from the second processing liquid supply source 741 is discharged from the processing liquid discharge pipe 701. However, the first valve 733 and the second valve 743 are electrically connected to the control unit 76 and are opened and closed under the control of the control unit 76. That is, the discharge mode of the processing liquid from the processing liquid discharge pipe 701 (specifically, the type of processing liquid to be discharged, the discharge start timing, the discharge end timing, the discharge flow rate, etc.) is controlled by the control unit 76. .

  The pressure adjustment unit 75 includes a gas supply system 751 and a suction system 752. The gas supply system 751 has a configuration in which, for example, a gas supply source 7511 for supplying gas (for example, nitrogen gas) is connected to a gas discharge pipe 702 via a pipe 7512 in which a gas valve 7513 is inserted. The suction system 752 has a configuration in which, for example, a suction unit 7521 that sucks (exhausts) gas or the like is connected to a suction pipe 703 via a pipe 7522 in which a suction valve 7523 is inserted.

  In this configuration, when the gas valve 7513 is opened, gas is discharged from the gas discharge pipe 702 and the internal space 70 of the chamber 71 is pressurized. On the other hand, when the suction valve 7523 is opened, the gas in the internal space 70 is sucked through the suction pipe 703 and the internal space 70 of the chamber 71 is decompressed. When the suction valve 7523 is opened, the processing liquid in the internal space 70 is sucked through the suction pipe 703 and discharged outside the chamber 71. However, the gas valve 7513 and the suction valve 7523 are electrically connected to the control unit 76 and are opened and closed under the control of the control unit 76. That is, the pressure in the internal space 70 is controlled by the control unit 76.

  The control unit 76 is a device that controls the operation of each unit in the substrate processing apparatus 100a. The hardware configuration of the control unit 76 can be the same as that of a general computer. The control unit 76 is electrically connected to the rotor 722, the stator 721, the first valve 733, the second valve 743, the gas valve 7513, the suction valve 7523, and the like. The control unit 76 operates each of these units according to the processing recipe, so that a series of processes for the substrate 9 proceeds.

<6-2. Process flow>
A flow of processing performed in the substrate processing apparatus 100a will be described. Since the flow of processing performed in the substrate processing apparatus 100a is substantially the same as the flow of processing performed in the substrate processing apparatus 100, it will be described here with reference to FIG. In the substrate processing apparatus 100a, a series of processes described below is executed under the control of the control unit 76.

  First, in a state where the chamber lid portion 713 is disposed above, a transfer robot (not shown) carries the substrate 9 into the chamber 71, and the substrate 9 is placed on the surface (the upper wiring groove 906 and the via hole 907 are arranged). It arrange | positions on the holding member 723 with the attitude | position in which the formed main surface) faces upwards (step S1). As a result, the substrate 9 is held on the holding member 723 in a substantially horizontal posture. When the substrate 9 is loaded, the chamber lid 713 is lowered and the upper opening of the chamber side wall 712 is closed by the chamber lid 713. That is, the internal space 70 of the chamber 71 is a sealed space. Note that the pressure adjusting unit 75 may appropriately adjust the pressure in the internal space 70 at an arbitrary timing while a series of processes described below is performed after the internal space 70 is set as a sealed space.

  When the chamber 71 is sealed, the rotation of the rotor 722 is started. As a result, the substrate 9 held in a horizontal posture on the holding member 723 is started to rotate within a horizontal plane (that is, around a vertical rotation axis) (step S2).

  Subsequently, chemical treatment is performed (step S3). In the chemical processing, the first valve 733 is opened. Then, the chemical liquid is discharged from the processing liquid discharge pipe 701 toward the surface of the rotated substrate 9. The chemical liquid discharged from the processing liquid discharge pipe 701 spreads toward the periphery of the substrate 9 by the centrifugal force generated by the rotation of the substrate 9 after landing on the central portion of the substrate 9. As a result, the chemical solution spreads over the entire surface of the substrate 9 and a liquid film of the chemical solution covering the entire surface of the substrate 9 is formed. By forming a liquid film of a chemical solution covering the surface of the substrate 9, the hard mask 908 formed on the surface of the substrate 9 reacts with the chemical solution and is etched, and the surface of the substrate 9 (flat portion and The polymer residue in the recess 90 is removed by reacting with the chemical solution. However, since fresh chemical solutions are successively supplied to the substrate 9, the chemical solution film covering the entire surface of the substrate 9 is successively replaced with fresh chemical solution films. The old chemical liquid swept away by the newly supplied chemical liquid is shaken off from the periphery of the substrate 9 by the centrifugal force caused by the rotation of the substrate 9. The chemical liquid scattered from the substrate 9 receives the suction force of the suction portion 7521 and is discharged out of the chamber 71.

  While the chemical solution is supplied to the substrate 9 (that is, in parallel with the supply of the chemical solution to the substrate 9), the rotational speed of the substrate 9 is maintained while maintaining the chemical film covering the entire surface of the substrate 9. The switching between the first rotation speed V1 and the second rotation speed V2 is performed twice or more (for example, see FIG. 6). As described above, by switching the rotation speed of the substrate 9, the fluidity of the chemical solution on the substrate 9 (particularly, the chemical solution in the recess 90) is enhanced. As a result, the polymer residue is sufficiently removed from the recess 90.

  When a predetermined time elapses after the first valve 733 is opened, the first valve 733 is closed and the discharge of the chemical liquid from the processing liquid discharge pipe 701 is stopped. This is the end of the chemical treatment. However, the supply of the rinsing liquid starts immediately after the supply of the chemical liquid is stopped so that the surface of the substrate 9 does not dry between the end of the chemical liquid processing and the start of the rinsing process described later. Is done.

  Subsequently, a rinsing process is performed (step S4). In the rinsing process, the second valve 743 is opened. Then, the rinsing liquid is discharged from the processing liquid discharge pipe 701 toward the surface of the rotated substrate 9. The rinse liquid discharged from the processing liquid discharge pipe 701 spreads toward the periphery of the substrate 9 by the centrifugal force generated by the rotation of the substrate 9 after landing on the center of the substrate 9. As a result, the rinsing liquid spreads over the entire surface of the substrate 9 and a liquid film of the rinsing liquid covering the entire surface of the substrate 9 is formed. By forming a liquid film of the rinsing liquid covering the surface of the substrate 9, the chemical liquid containing the polymer residue remaining on the substrate 9 is rinsed away. However, since the fresh rinsing liquid is supplied to the substrate 9 one after another, the liquid film of the rinsing liquid covering the entire surface of the substrate 9 is successively replaced with the liquid film of the fresh rinsing liquid. The old rinse liquid swept away by the newly supplied rinse liquid is shaken off from the periphery of the substrate 9 together with the chemical liquid containing the polymer residue by the centrifugal force generated by the rotation of the substrate 9. The rinse liquid scattered from the substrate 9 receives the suction force of the suction part 7521 and is discharged out of the chamber 71.

  While the rinsing liquid is supplied to the substrate 9 (that is, in parallel with the supply of the rinsing liquid to the substrate 9), while maintaining the liquid film of the rinsing liquid covering the entire surface of the substrate 9, The rotation speed is switched between the first rotation speed V1 and the second rotation speed V2 at least twice (see, for example, FIG. 6). As described above, by switching the rotation speed of the substrate 9, the fluidity of the rinsing liquid on the substrate 9 (particularly, the rinsing liquid in the recess 90) is increased. As a result, the polymer residue is sufficiently removed from the recess 90.

  When a predetermined time elapses after the second valve 743 is opened, the second valve 743 is closed and the discharge of the rinsing liquid from the processing liquid discharge pipe 701 is stopped.

  Subsequently, a drying process is performed (step S5). Specifically, in a state where the discharge of the processing liquid toward the substrate 9 is stopped, the rotation speed of the substrate 9 is higher than the high rotation speed (for example, higher than the first rotation speed V1 and the second rotation speed V2). Rotational speed). As a result, the processing liquid remaining on the substrate 9 is shaken off and removed from the substrate 9, and the substrate 9 is dried.

  When a predetermined time elapses after the substrate 9 starts to rotate at a high rotation speed, the rotation of the substrate 9 is stopped.

  Subsequently, the chamber lid 713 is raised, the upper opening of the chamber side wall 712 is opened, and the transfer robot (not shown) carries the substrate 9 out of the chamber 71 (step S6). Thus, a series of processes for the substrate 9 is completed.

<6-3. Effect>
Also in this embodiment, the same effect as the embodiment described above can be obtained. In particular, according to this embodiment, since the process for the substrate 9 proceeds in the sealed chamber 71, at least one of the chemical process and the rinse process, the moment when the rotation speed of the substrate 9 becomes zero (or the lower limit allowable). Even if excess processing liquid on the substrate 9 drops from the peripheral edge of the substrate 9 due to a moment when the speed falls below the speed, the dropped processing liquid can be recovered without any problem. That is, when the substrate processing apparatus 100a according to this embodiment is employed, for example, the rotation direction of the substrate 9 rotated at the first rotation speed V1 and the rotation direction of the substrate 9 rotated at the second rotation speed V2. There is no problem even if they are in the opposite direction (see FIG. 10).

<7. Other Embodiments>
In the substrate processing apparatuses 100 and 100a according to each of the above embodiments, the peeling of the hard mask 908 and the removal of the polymer residue are simultaneously performed on the substrate 9 after dry etching. 100a, for example, with respect to the substrate 9 with the substrate 9 after the hard mask 908 is peeled off (for example, the substrate 9 subjected to ashing for removing the hard mask 908 after dry etching) as a processing target, Polymer residue (reaction product generated during dry etching (reaction product including components of low dielectric constant insulating film 905) and reaction product generated during ashing (reaction product including components of hard mask 908)) You may perform the process to remove. In addition, the substrate processing apparatuses 100 and 100a may perform a process of removing a resist pattern on a hard mask, for example.

  In the above embodiment, the central region C is the scan region, but the entire surface of the substrate 9 may be the scan region. For example, when the substrate 9 after the hard mask 908 is peeled off is used as a processing target and the processing for removing the polymer residue is performed on the substrate 9, it is not necessary to consider the uniformity of the etching amount. Therefore, for example, in such a case, the entire surface of the substrate 9 may be set as a scan region.

  Further, in the above-described embodiment, in the chemical processing, the chemical nozzle is ejected toward the substrate 9 while the scan nozzle 31 moves, and the chemical liquid landing position scans, for example, the central region C. However, the position where the chemical solution is deposited may be fixed to the rotation center of the substrate 9 in the chemical treatment. Specifically, in the chemical treatment, the chemical solution may be discharged from the fixed nozzle 41 toward the rotation center of the substrate 9.

  In the above embodiment, in the rinsing process, the fixed nozzle 41 discharges the rinsing liquid toward the center of the substrate 9, and the liquid landing position of the rinsing liquid is fixed to the rotation center of the substrate 9. However, in the rinsing process, for example, the central position C (or the entire area of the substrate 9) may be scanned for the rinsing liquid landing position. Specifically, in the rinsing process, the scan nozzle 31 may discharge the rinsing liquid toward the substrate 9 while moving.

  In the above embodiment, the rotation speed of the substrate 9 is switched between the first rotation speed V1 and the second rotation speed V2 at least twice in both the chemical solution treatment and the rinse treatment. In one process (for example, rinse process), the substrate 9 may be rotated at a constant rotation speed. Further, in at least one of the chemical treatment and the rinse treatment, the rotation speed of the substrate 9 may be switched two or more times between three or more rotation speeds.

  In the above embodiment, at least one of the scan nozzle 31 and the fixed nozzle 41 is a two-fluid nozzle (that is, a treatment liquid and a gas are mixed to generate a treatment liquid droplet, and the treatment liquid is generated. May be configured by a two-fluid nozzle that ejects the liquid droplets toward the substrate 9.

  In the above embodiment, the spin chuck 1 is a clamping chuck that sandwiches the substrate 9 in the horizontal direction. However, the spin chuck is a vacuum chuck that sucks the lower surface of the substrate 9. Also good.

  In the above embodiment, the substrate 9 is a semiconductor wafer. However, the substrate 9 is a glass substrate for a liquid crystal display device, a glass substrate for a plasma display, a substrate for an optical disk, a substrate for a magnetic disk, a magneto-optical disk. For example, a glass substrate for a photomask, a substrate for a solar cell, and the like.

  As described above, the present invention has been shown and described in detail, but the above description is illustrative in all aspects and not limiting. Therefore, embodiments of the present invention can be modified or omitted as appropriate within the scope of the invention.

DESCRIPTION OF SYMBOLS 100,100a Substrate processing apparatus 1 Spin chuck 11 Spin base 13 Rotation drive part 2 Splash prevention part 21 Cup 3 1st process liquid supply part 31 Scan nozzle 4 2nd process liquid supply part 41 Fixed nozzle 5,76 Control part 71 Chamber 72 Holding and rotating mechanism 73 First processing liquid supply system 74 Second processing liquid supply system 75 Pressure adjusting unit 701 Processing liquid discharge pipe 9 Substrate 90 Recess

Claims (10)

A substrate processing method for processing a substrate having a recess on a surface,
a) supplying a treatment liquid to the surface of the substrate held in a horizontal posture and rotated in a horizontal plane to form a liquid film of the treatment liquid covering the surface;
b) In parallel with the step a), the substrate is rotated at least twice between the first rotation speed and the second rotation speed while maintaining the liquid film of the processing liquid covering the surface. Switching process,
A substrate processing method comprising: The substrate processing method according to claim 1,
In the step a),
Supplying the treatment liquid to the surface while moving the landing position of the treatment liquid;
Substrate processing method. The substrate processing method according to claim 2,
Moving the liquid deposition position within a region that includes the center of rotation of the substrate and does not include the peripheral edge of the substrate;
Substrate processing method. The substrate processing method according to claim 3,
The position of the outer peripheral edge of the region is defined based on the speed of the treatment liquid in the recess at each position in the surface;
Substrate processing method. The substrate processing method according to claim 1,
In the step a),
Fixing the liquid deposition position of the processing liquid to the rotation center of the substrate and supplying the processing liquid to the surface;
Substrate processing method. A substrate processing method according to any one of claims 1 to 5,
The rotation direction of the substrate rotated at the first rotation speed and the rotation direction of the substrate rotated at the second rotation speed are the same direction.
Substrate processing method. A substrate processing method according to any one of claims 1 to 6,
Switching between the first rotation speed and the second rotation speed is performed intermittently,
Substrate processing method. A substrate processing method according to any one of claims 1 to 7,
The treatment liquid is a chemical liquid for removing the polymer on the surface and removing a thin film formed on the surface.
Substrate processing method. A substrate processing method according to any one of claims 1 to 7,
The treatment liquid is a rinsing liquid for rinsing a chemical liquid.
Substrate processing method. A substrate processing apparatus for processing a substrate having a recess on a surface,
A rotation holding unit that rotates the substrate around a vertical rotation axis while holding the substrate in a horizontal posture;
A discharge unit for supplying a treatment liquid to the surface of the substrate held by the rotation holding unit;
While supplying the processing liquid to the surface to the discharge unit and forming a liquid film of the processing liquid covering the surface, in parallel with this, maintaining the liquid film of the processing liquid covering the surface A control unit that causes the rotation holding unit to switch the rotation speed of the substrate at least twice between a first rotation speed and a second rotation speed;
A substrate processing apparatus comprising:

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