JP2015119647A - Pigment fading inhibitor - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a pigment fading inhibitor which suppresses the fading of a carotenoid-based pigment and further has excellent dispersibility and emulsion stability in foods without impairing the appearance and flavor of foods.SOLUTION: There is provided a carotenoid-based pigment fading inhibitor which contains (A) tocopherol having 40% or more α-tocopherol in a tocopherol composition and (B) a tea extract and is an oil-in-water and/or -polyhydric alcohol type emulsion containing a surfactant.

Description

  The present invention relates to a dye fading inhibiting agent that suppresses discoloration of carotenoid pigments and does not impair the appearance and flavor of foods and beverages, and is excellent in dispersibility and emulsion stability in foods.

  Conventionally, pigments have been used to increase the commercial value of many foods, drinks, cosmetics, and pharmaceuticals. However, these dyes are unstable to factors such as light, heat, and oxygen, and for example, they are discolored under the influence of food during processing, distribution, and storage, and cause deterioration in quality. In addition, they are easily affected by heat and oxygen in addition to light, such as being displayed in showcases at convenience stores and supermarkets, and hot selling of food and drink in plastic containers. In order to solve these problems, sterilization during the manufacturing process is processed at a low temperature, the confidentiality and light shielding properties of the packaging material are improved, and an antioxidant material such as vitamin C is added to the product. Measures have been taken, but each had some drawbacks.

  For example, as the addition of an antioxidant, synthetic products such as dibutylhydroxytoluene (BHT), butylhydroxyanisole (BHA), erythorbic acid and derivatives thereof have long been added. However, these synthetic antioxidants have been pointed out to have an unfavorable impact on health and are of concern for use.

  In addition, a method of using various natural antioxidants in place of these synthetic antioxidants alone or in combination is known. For example, an anti-fading agent for gardenia yellow pigments containing polyphenols (chlorogenic acids) such as chlorogenic acid, caffeic acid, and ferulic acid as active ingredients (see, for example, Patent Document 1), and a method for stabilizing pigments including genus genus plants ( For example, refer to Patent Document 2), and anthocyanin-based pigments and / or carotenoid-based pigment fading inhibitors (for example, refer to Patent Document 3), which have an extract of Nanten leaves as an active ingredient, have been proposed. However, many of these anti-fading agents have the disadvantage that the flavor of the anti-fading agent itself adversely affects food and drink.

JP-A-6-93199 (page 2-4) JP-A-6-234935 (page 2-4) Japanese Patent Laid-Open No. 8-222068 (page 2-3)

  An object of the present invention is to develop an anti-fading agent that suppresses discoloration of carotenoid pigments and does not impair the appearance and flavor of food and drink, and is excellent in dispersibility and emulsion stability in foods.

  As a result of intensive investigations to suppress the fading of carotenoid pigments, the inventors added tocopherol having an α-tocopherol content of 40% or more in the total tocopherol and an anti-fading agent containing a tea extract. As a result, it has been found that fading is remarkably suppressed as compared with conventional anti-fading agents, and the present invention has been completed. That is, the present invention is characterized in that a tocopherol containing 40% or more of α-tocopherol and an anti-fading agent containing a tea extract are added.

  According to the present invention, it is possible to provide a dye fading inhibiting agent that suppresses discoloration of carotenoid pigments, and does not impair the appearance and flavor of foods and beverages, and is excellent in dispersibility and emulsion stability in foods. .

Hereinafter, the present invention will be described in detail.
The carotenoid pigments that are the subject of the present invention are not particularly limited, but are generally compounds having an isoprene unit as a skeleton, and hydrocarbons such as α-carotene, β-carotene, lycopene, phytoene, etc. Astaxanthin, zeaxanthin, actinioerythrol, lutein, cryptoxanthine, tunaxanthin, salmoxanthine, parasiloxanetin, violaxanthin, anthaxanthin, cucurbitaxanthin, diato Xanthine, alloxanthin, pectinol, pectinolone, mactraxanthine, capsanthin, capsanthinol, fucoxanthin, fucoxanthinol, peridinin, halocinthiaxanthine, amaranthiaxanthine, canthaxane Examples include tin, echinenone, rhodoxanthin, bixin, norbixin, and norcarotenoids and apocarotenoids.
In addition to being extracted from natural products, these are obtained by synthesis and are put to practical use as single items or mixtures or crude extracts.

  The tocopherols used in the invention of the present application are natural and synthetic tocopherols and are not particularly limited. When extracted and refined from oils and fats derived from plant raw materials, it is not particularly limited, but representative examples include soybean oil, wheat germ oil, and palm oil. In addition, the component ratio of α, β, γ, and δ in the extracted tocopherol is influenced by the plant type, variety, production area, etc., but the component ratio of a specific homologous composition by a process such as molecular distillation industrially. Products with increased The content of each homologue in tocopherol can be measured by the measurement method (high performance liquid chromatographic method) described in the Food Additives Official Document.

  The tocopherol used in the present invention is not particularly limited in its purification method, but the total tocopherol contains 40% or more α-tocopherol, and preferably contains 60% or more α-tocopherol. More preferably, it is desirable to contain 75% or more of α-tocopherol. Among the tocopherol homologues, α-tocopherol has the highest anti-fading effect on carotenoid pigments, and the higher the proportion of α-tocopherol in the total tocopherol, the more effective. Therefore, if the content of α-tocopherol in the total tocopherol is less than 40%, a sufficient effect cannot be exhibited.

  The amount of tocopherol contained in the anti-fading agent of the present invention is not particularly limited, but it is preferably 0.5 to 25% by weight, more preferably 1.0 to 10% by weight. . If it is less than 0.1%, it is difficult to obtain the expected effect, and if it is added in a concentration exceeding 40% by weight, it becomes difficult to add it stably when it is an oil-in-water emulsion in water or a polyhydric alcohol.

  The raw material of the tea extract used in the present invention is not particularly limited, and botany is green tea, which is a non-fermented tea produced from leaves of Camellia sinensis, which is a plant of the camellia family, and oolong tea, which is a semi-fermented tea. And black tea that is fermented tea. Among them, it is preferable to use green tea which is preferably unfermented tea. Examples of the extract include tea leaves or a product obtained by pulverizing tea leaves with water, hot water, an alcohol such as glycerin or ethanol, an ethyl acetate soluble fraction, an acetone soluble fraction, or the like. More preferably, (+)-catechin, (−)-epicatechin, (+)-gallocatechin, (−)-epigallocatechin, (−)-catechin gallate, (−)-epicatechin gallate, (− One or more catechins selected from the group consisting of) -gallocatechin gallate and (-)-epigallocatechin gallate are included.

  The content of the catechins is not particularly limited, but is preferably 60% or more, more preferably 70% or more in the tea extract to be used. The total content of these catechins can be measured by a colorimetric method using iron tartrate, but in order to measure the composition of each catechin in detail, it is preferable to measure by high performance liquid chromatography. .

  The amount of tea extract contained in the anti-fading agent of the present invention is not particularly limited, but is preferably 0.01 to 5% by weight. More preferably, the content is 0.1 to 2.5% by weight. If it is less than 0.01%, the expected effect is difficult to obtain, and if it exceeds 5% by weight, the flavor of the food may be affected.

  The surfactant contained in the anti-fading agent of the present invention is not particularly limited, but is preferably a saturated or unsaturated fatty acid having 8 to 22 carbon atoms, and a polyglycerin fatty acid composed of a single or mixed constituent fatty acid. It is desirable to include one or more of an ester, a sucrose fatty acid ester, and a polysorbate, and more preferably a polyglycerin fatty acid ester. The degree of hydrophilicity and lipophilicity of the surfactant is represented by HLB (Hydrophile-Lipophile Balance). To obtain an oil-in-water emulsion in water and / or polyhydric alcohol in the present invention, HLB is used. It is 9 or more, preferably 11 or more. When HLB is smaller than 9, it becomes difficult to stably disperse tocopherol, which is an oil-soluble substance, in water.

  The method for obtaining the HLB is not particularly limited, and various existing methods can be used. For example, in the case of an ester type surfactant, it can be calculated from the saponification value and the acid value of the constituent fatty acid by the following formula. Moreover, the surfactant used for emulsification of the anti-fading agent may be used alone or in combination of two or more other surfactants. Examples of such surfactants include monoglycerin fatty acid esters, organic acid monoglycerides, monoglyceride derivatives, propylene glycol fatty acid esters, sorbitan fatty acid esters, enzymatically decomposed lecithins, and quilaya extracts.

HLB = 20 × (1-S / A)
S: Saponification value, A: Acid value of the constituent fatty acid A compound having only a polyoxyethylene chain as a hydrophilic group can be calculated by the following formula.
HLB = E / 5
E: Weight fraction of polyoxyethylene group

  In addition to these arithmetic methods, the HLB can also be obtained experimentally. In other words, a combination of a surfactant known to HLB and an unknown surfactant is used to emulsify fat and water known to HLB and a mixture having the best emulsification state is selected, and can be calculated from the following equation.

{(Wu × HLBu) + (Wa × HLBa)} / (Wu + Wa) = HLBo
Wu: weight fraction of HLB unknown surfactant Wa: weight fraction of HLB known surfactant HLBu: HLB of HLB unknown surfactant (HLB of the desired surfactant)
HLBa: HLB of HLB known surfactant
HLBo: Required HLB for fats and oils

  The polyhydric alcohol described in the present invention is a general term for compounds having two or more hydroxyl groups in one molecule, and the type of the polyhydric alcohol is not particularly limited. For example, glycerin, propylene glycol, sorbitol, maltitol, xylitol, erythritol, lactitol, sorbitan, xylose, arabinose, mannose, lactose, sugar, coupling sugar, glucose, enzyme starch syrup, acidified starch syrup, maltose starch syrup, maltose, isomerization Examples thereof include sugar, fructose, reduced maltose, reduced starch syrup, and honey. These can be used alone or in admixture of two or more. Further, for the purpose of facilitating the use, ethanol or the like may be mixed within a range that does not affect the emulsification.

  When preparing a dye fading inhibitor that is an oil-in-water emulsion in water and / or polyhydric alcohol in the present invention, after dissolving a surfactant in water and / or polyhydric alcohol, an oil phase containing tocopherol is added. It is obtained by adding and emulsifying using an emulsifying device. The emulsifying apparatus is not particularly limited, and specific examples include a homomixer, a colloid mill, a high-pressure homogenizer, and an ultrahigh-pressure homogenizer. The method of adding the tea extract is not particularly limited and may be any before or after emulsification, but it is preferably added before emulsification and dissolved well in water and / or polyhydric alcohol. In order to prevent the deterioration of the raw material and improve the stability of the preparation, preparation under an inert gas stream such as nitrogen and helium is desirable throughout all the steps.

  By making the average particle diameter of 1.0 μm or less, preferably 0.4 μm or less when the color fading inhibitor, which is an oil-in-water emulsion in water and / or polyhydric alcohol in the present invention, dispersed in water, it is oil-soluble. Since the tocopherol is not separated and the dispersibility is improved, the fading of the carotenoid pigment can be effectively suppressed without impairing the appearance of the final product. When the particle diameter exceeds 1.0 μm, separation and floating of the oil-soluble tocopherol are recognized, and the effect of preventing fading is not sufficiently exhibited, and the appearance of the final product may be impaired. By making the fine emulsification 0.4 μm or less, the emulsification stability is further improved. Further, the smaller the average particle size, the larger the surface area where the tocopherol and the carotenoid pigment are in contact with each other. Therefore, the effect of preventing fading is also increased, and the effect can be sufficiently exerted with a small amount of addition. The average particle size when the tocopherol in the present invention is dispersed in water can be easily measured using a particle size distribution measuring device (L-230) manufactured by Beckman Coulter.

  Carotenoid pigments are affected by light, heat, oxygen, etc., and fade at a very fast speed, so the most active α-tocopherol among the tocopherol homologues is the most effective against the fading of carotenoid pigments. Work effectively. The higher the blending ratio of α-tocopherol in the total tocopherol, the more effective, and it is expected to improve the suppression effect on fading caused by heat, oxygen, light, etc. by making it a fine and stable emulsion with surfactant. can do.

  In the present invention, a desired effect can be obtained by adding a tocopherol containing 40% or more of α-tocopherol in the total tocopherols, or a fading inhibitor containing a tea extract. If necessary, a known antioxidant can be used. You may use together. Examples include oil-soluble antioxidants (licorice oil extract, sesame oil unsaponifiable matter, γ-oryzanol, rapeseed oil extract), water-soluble antioxidants (L-ascorbic acid, L-ascorbic acid ester, sodium L-ascorbate) Erythorbic acid, sodium erythorbate, gallic acid, chlorogenic acid, enzyme-treated rutin, grape seed extract, rosemary extract, sunflower extract, quercetin, bayberry extract, edible canna extract, blueberry leaf extract, etc.) Antioxidants that are poorly soluble in water and oil (Dokudami extract, mallow flower extract, pimenta extract, etc.), sequestering agents (gluconic acid, kojic acid, phytic acid, polyphosphoric acid, chitin, chitosan, etc.) , Amino acids, organic acids such as citric acid or salts thereof, hesperidin, hesperetin and the like. Or two or more may be used in combination formulations.

  In addition, when the anti-fading agent of the present invention is mixed with an edible dye, the method is not particularly limited. However, in order to effectively suppress the fading of the dye, the oil-soluble dye is previously added before emulsification. It is better to mix with tocopherol, and it is better to mix the water-soluble pigment after emulsification.

  The mixing ratio of the anti-fading agent of the present invention and the food color is not particularly limited and varies depending on the type of food used and the like, but cannot be determined unconditionally, but in general, the color 99: 1 to 1 : It is preferable to mix in the range of 99.

  In the present invention, the food and drink is not particularly limited, and is effective for all food and drink where the pigment component fades due to the influence of light, heat, oxygen, etc. Beverages such as vegetable beverages, lactic acid bacteria beverages, carbonated beverages, alcoholic beverages, mineral-containing beverages, vitamin-containing beverages, beverages containing functional food materials, milk beverages, lactic acid bacteria beverages, fermented milk, yogurt, milk such as ice cream, and Examples include products made mainly of milk, dessert foods such as jelly, bavaroa and pudding, confectionery such as candy and snack foods, and supplements.

  The amount of the anti-fading agent of the present invention added to these foods and drinks is not particularly limited, and varies depending on the purity of the ingredients in the anti-fading agent used, the blending ratio, the type of food and drink to be added, etc. In general, it is preferably added in the range of 0.005 to 0.5% by weight of the food or drink. More preferably, the content is 0.01 to 0.1% by weight. If the amount is less than 0.005% by weight, the expected effect is hardly obtained, and if the concentration exceeds 0.5% by weight, the flavor of the anti-fading agent may affect the flavor of the food or drink.

  In the following, aspects of the invention will be further described and disclosed by means of examples. This example is merely illustrative of the invention and is not meant to be limiting in any way.

Example 1
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the antifading agent thus obtained was dispersed in water was 0.1 μm or less. The preparation thus obtained was added to the acid sugar solution by 0.05%. The acid sugar solution was prepared by adding 0.1 g of a commercially available β-carotene pigment preparation to an aqueous solution of 100 g of fructose glucose liquid sugar, 2.5 g of citric acid and 0.5 g of sodium citrate so that the absorbance at 470 nm was 1.0. In Bx. 7.5 and adjusted to pH 2.8. 1000 ml of this was prepared and filled into a colorless and transparent 200 ml glass bottle. The sample thus obtained was irradiated under conditions of 12 ° C. and 7500 Lx, and absorbance measurement and sensory evaluation were performed.

Example 2
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 70%) is used as an oil phase, which is added to a polyhydric alcohol, and emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) to fade. 100 g of inhibitor was obtained. The average particle size when the antifading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 3
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 45%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm, and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 4
As polyhydric alcohol, 83.7 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) as a polyglycerin fatty acid ester and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 0.8 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol and emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.). As a result, 100 g of an anti-fading agent was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 5
As polyhydric alcohol, 72.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14), which is a polyglycerin fatty acid ester, and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 12 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm, and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.4 μm. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 6
As polyhydric alcohol, 84.2 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchange water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14), which is a polyglycerin fatty acid ester, and tea extraction 0.5 g of a product (catechin content of 90% or more, manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved by heating at 65 ° C. 0.3 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, and emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm. As a result, 100 g of an anti-fading agent was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. The preparation thus obtained was added 0.2% to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 7
As polyhydric alcohol, 64.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water, 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 20 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm, and faded. 100 g of inhibitor was obtained. The average particle size when the antifading agent thus obtained was dispersed in water was 0.8 μm. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 8
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 62%, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 9
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 25%, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 10
As polyhydric alcohol, glycerin (manufactured by Nippon Oil & Fats Co., Ltd.) 82.95 g, ion-exchanged water 10 g, polyglycerin fatty acid ester decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.05g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 11
As polyhydric alcohol, 73 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water, 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extract (polyglycerin fatty acid ester) 10 g of a catechin content of 90% or more, manufactured by Taiyo Kagaku Co., Ltd. was added and dissolved by heating at 65 ° C. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 12
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchange water and 5 g of polyoxyethylene sorbitan monooleate which is a polyoxyethylene sorbitan fatty acid ester (manufactured by Kao Corporation, HLB value 15), 0.5 g of tea extract (catechin content: 90% or more, manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved by heating at 65 ° C. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 13
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion exchange water and 5 g of decaglycerin trimyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 10), which is a polyglycerin fatty acid ester, and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.5 μm. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 14
0.2% of the anti-fading agent obtained in the same manner as in Example 1 was added to the acid sugar solution, and the same evaluation as in Example 1 was performed.

Example 15
0.4% of the anti-fading agent obtained in the same manner as in Example 1 was added to the acid sugar solution, and the same evaluation as in Example 1 was performed.

Example 16
As polyhydric alcohol, 74.8 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchange water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14), which is a polyglycerin fatty acid ester, and tea extraction The product (catechin content 62%, Taiyo Kagaku Co., Ltd.) 0.2g was added, and it heated and melt | dissolved at 65 degreeC. 10 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm, and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.3 μm. The preparation thus obtained was added in an amount of 0.005% to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 17
1.0% of the anti-fading agent obtained in the same manner as in Example 1 was added to the acid sugar solution, and the same evaluation as in Example 1 was performed.

Example 18
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water, 5 g of sucrose stearate (HLB value 15) and tea extract (catechin content of 90% or more, Taiyo Kagaku Co., Ltd.) 0.5 g) was added and dissolved by heating to 65 ° C. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.5 μm. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 19
As polyhydric alcohol, 82.5 g of glycerin (manufactured by Nippon Oil & Fats Co., Ltd.), 10 g of ion-exchanged water and 5 g of decaglycerin pentamyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 8) which is a polyglycerin fatty acid ester and tea extraction The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. When the anti-fading agent thus obtained was dispersed in water, the average particle size was 1.3 μm. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Example 20
As polyhydric alcohol, 80 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (HLB value 14 manufactured by Taiyo Kagaku Co., Ltd.) and tea extract (polyglycerin fatty acid ester) 3 g of a catechin content of 90% or more (manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved by heating at 65 ° C. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 1
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 20%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 2
As polyhydric alcohol, 84.5 g of glycerin (manufactured by Nippon Oil & Fats Co., Ltd.), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction 0.5 g of a product (catechin content of 90% or more, manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved by heating at 65 ° C. to obtain 100 g of a fading inhibitor. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 3
As polyhydric alcohol, 82.5 g of glycerin (manufactured by NOF Corporation), 10 g of ion-exchanged water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) and tea extraction. The product (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) 0.5g was added, and it heated and melt | dissolved at 65 degreeC. 2 g of extracted tocopherol (d-α-tocopherol content 0%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.) at a rotational speed of 9000 rpm, and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 4
As polyhydric alcohol, add glycerin (manufactured by NOF Corporation) 83g, ion-exchanged water 10g and polyglycerin fatty acid ester decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14) to 65 ° C. Dissolved warm. 2 g of extracted tocopherol (d-α-tocopherol content 80%) is used as an oil phase, which is added to a polyhydric alcohol, emulsified at a rotation speed of 9000 rpm with a homomixer (made by Tokushu Kika Kogyo Co., Ltd.), and faded. 100 g of inhibitor was obtained. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 5
As polyhydric alcohol, 10 g of ion exchange water and 5 g of decaglycerin monomyristate (manufactured by Taiyo Kagaku Co., Ltd., HLB value 14), which is polyglycerin fatty acid ester, are added to 85 g of glycerin (manufactured by NOF Corporation), 65 100 g of an emulsified preparation was obtained by heating and dissolving at 0 ° C. The average particle size when the anti-fading agent thus obtained was dispersed in water was 0.1 μm or less. 0.05% of the thus obtained preparation was added to the acid sugar solution prepared in the same manner as in Example 1, and the same evaluation was performed.

Comparative Example 6
Add 0.001 g of extracted tocopherol (d-α-tocopherol content 20%) and 0.00025 g of tea extract (catechin content 90% or more, Taiyo Kagaku Co., Ltd.) to the acid sugar solution prepared in the same manner as in Example 1. And filled into a colorless and transparent 200 ml glass bottle. The samples obtained in this way were evaluated in the same manner as in Example 1.

Absorbance measurement and sensory evaluation In the absorbance measurement, turbidity at 470 nm was measured at room temperature using Hitachi U-3900 three days after the start of irradiation, and the unbleached rate of the dye was quantified from the turbidity before irradiation. . Moreover, the flavor check before and after irradiating light was carried out by sensory evaluation by 20 professional panelists, and the scores based on the following criteria were averaged. In addition, the overall evaluation is 4.0 or higher for the flavor before and after deterioration, ◯ for both the flavor before and after deterioration, ◯ for both the flavor before and after the deterioration, △ for both flavors before and after the deterioration, and × for the other flavors. .

Before deterioration 1: Strong odor is felt.
2: I feel a deteriorated odor.
3: Slightly deteriorated odor is felt.
4: Almost no deterioration odor.
5: I do not feel the deterioration odor.

After deterioration 1: Strong odor is felt.
2: I feel a deteriorated odor.
3: Slightly deteriorated odor is felt.
4: Almost no deterioration odor.
5: I do not feel the deterioration odor.

  As is apparent from Table 1, the carotenoid pigment anti-fading agent containing an extracted tocopherol containing 40% or more of α-tocopherol in the tocopherol composition and a tea extract is a conventional anti-fading agent. It is clear that it has an excellent anti-fading ability compared with.

  Suppresses fading of carotenoid pigments, and does not impair the appearance and flavor of foods and beverages, and can provide pigment fading inhibitors with excellent dispersibility and emulsification stability in foods. It ’s big.

Claims (6)

Hereinafter, a carotenoid-based dye fading inhibitor which is an oil-in-water emulsion containing water and / or polyhydric alcohol containing (A) and (B) and a surfactant.
(A) Tocopherol in which α-tocopherol in the tocopherol composition is 40% or more (B) Tea extract   The dye fading inhibitor according to claim 1, wherein (A) is 0.1 to 40% by weight and (B) is 0.01 to 5% by weight.   3. The dye fading preventive according to claim 1 or 2, wherein the average particle size when dispersed in water is 1.0 [mu] m or less.   The carotenoid pigment | dye containing the pigment | dye fading inhibitor in any one of Claims 1-3.   Food-drinks containing the pigment discoloration prevention agent in any one of Claims 1-3.   The method for preventing fading of foods and drinks, wherein the dye fading inhibitor according to any one of claims 1 to 3 is added.