JP2002053857A - Fading inhibitor of carotenoid pigment and method for preventing fading - Google Patents

Fading inhibitor of carotenoid pigment and method for preventing fading

Info

Publication number
JP2002053857A
JP2002053857A JP2000240923A JP2000240923A JP2002053857A JP 2002053857 A JP2002053857 A JP 2002053857A JP 2000240923 A JP2000240923 A JP 2000240923A JP 2000240923 A JP2000240923 A JP 2000240923A JP 2002053857 A JP2002053857 A JP 2002053857A
Authority
JP
Japan
Prior art keywords
fading
carotenoid
pigment
composition
fading agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000240923A
Other languages
Japanese (ja)
Inventor
Kazuyo Iwami
佳寿代 岩見
Masaharu Nagao
正春 長尾
Izumi Kawada
泉 川田
Hiroshi Ishii
潯 石井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago International Corp
Takasago Perfumery Industry Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp, Takasago Perfumery Industry Co filed Critical Takasago International Corp
Priority to JP2000240923A priority Critical patent/JP2002053857A/en
Publication of JP2002053857A publication Critical patent/JP2002053857A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain an excellent fading inhibitor for articles such as a carote noid pigment-containing beverage, food, feed, medicine, quasi-medicine, sanitation supplies, cosmetic, etc., without deteriorating qualities which these articles essentially have, and to provide a method for preventing fading using the fading inhibitor. SOLUTION: This fading inhibitor of a carotenoid pigment comprises an extract of pecan nuts or the extract and vitamin E as active ingredients. This carotenoid pigment composition is characterized by mixing a carotenoid pigment with the fading inhibitor. This fading preventing method of carotenoid pigment is characterized by mixing a carotenoid pigment-containing food, beverage, medicine, quasi-medicine, sanitation article or cosmetic with the fading inhibitor.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、カロチノイド系色
素の褪色防止剤及び褪色防止方法に関し、詳しくは飲食
品、飼料、医薬品、医薬部外品、保健衛生用品及び香粧
品などに添加して、これらの物品に固有の好ましい色調
等を安定に保持し、これらの物品に含まれているカロチ
ノイド系色素の褪色(退色)を効果的に防止することの
できる褪色防止剤並びにこの褪色防止剤を用いるカロチ
ノイド系色素含有物品の褪色防止方法に関する。更に詳
しくは、ペカンナッツ抽出物又はこれに抗酸化剤として
知られるビタミンEを添加してなるものを有効成分とす
る褪色防止剤並びに該褪色防止剤を用いるカロチノイド
系色素含有物品の褪色防止方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anti-fading agent and a method for preventing fading of carotenoid pigments, and more particularly to a food and drink, feed, pharmaceuticals, quasi-drugs, health and hygiene products, and cosmetics. Use of an anti-fading agent which stably retains a preferable color tone and the like inherent to these articles and which can effectively prevent fading (fading) of a carotenoid-based pigment contained in these articles, and using the anti-fading agent The present invention relates to a method for preventing discoloration of a carotenoid-based article. More specifically, the present invention relates to an anti-fading agent containing a pecan nut extract or a vitamin E known as an antioxidant added thereto as an active ingredient, and a method for preventing discoloration of a carotenoid pigment-containing article using the anti-fading agent.

【0002】[0002]

【従来の技術】天然物由来のカロチノイド系などの色素
は、熱、光又は酸素などによって酸化され、褪色又は変
色することは良く知られている。このような不安定な色
素類の変色、褪色防止方法に関して既に多くの提案がな
されている。例えばパプリカ色素の褪色防止剤として、
ルチン及び/又はケルセチン(特公昭54−10568
号公報)、ハマメリスの水又は含水エタノール抽出物を
有効成分とする退色防止剤(特開平6−207172号
公報)、ヒマワリ種子抽出物及び茶抽出物を有効成分と
して含有するカロチノイド系色素用褪変色防止剤及び方
法(特開平10−94381号公報)などの他、アスコ
ルビン酸類やトコフェロール類等の添加が知られてい
る。これらの褪色防止剤は、いずれも相応の効果を示す
が、対象とする食品によってはなお、満足し得る効果が
得られない場合があった。また、アスコルビン酸類を用
いる場合は、黄ばみが出る等の欠点があり、更に取扱上
の容易さ、香りや味への影響等にも問題があり、必ずし
も満足できる効果が得られなかった。
2. Description of the Related Art It is well known that pigments such as carotenoids derived from natural products are oxidized by heat, light, oxygen or the like, and fade or discolor. Many proposals have been made on methods for preventing discoloration and fading of such unstable dyes. For example, as an anti-fading agent for paprika dyes,
Rutin and / or quercetin (Japanese Patent Publication No. 54-10568)
Japanese Patent Application Laid-Open No. 6-207172), a fading inhibitor for carotenoid pigments containing sunflower seed extract and tea extract as active ingredients. In addition to inhibitors and methods (JP-A-10-94381), addition of ascorbic acids and tocopherols is known. Each of these anti-fading agents shows a corresponding effect, but depending on the target food, a satisfactory effect may not be obtained in some cases. Further, when ascorbic acids are used, they have drawbacks such as yellowing, and also have problems in ease of handling, influence on aroma and taste, etc., so that satisfactory effects were not always obtained.

【0003】[0003]

【発明が解決しようとする課題】本発明の目的は、カロ
チン色素、パプリカ色素及びアナトー色素等のカロチノ
イド系色素を含む飲料や食品、飼料、医薬品、医薬部外
品、保健衛生用品及び香粧品などが本来的に有する品質
等に影響を与えずに、これらの物品の褪色を防止するこ
とができる、優れた褪色防止剤並びに該褪色防止剤を用
いた褪色防止方法を提供することである。
SUMMARY OF THE INVENTION An object of the present invention is to provide beverages, foods, feeds, pharmaceuticals, quasi-drugs, health and hygiene products and cosmetics containing carotenoid pigments such as carotene pigments, paprika pigments and annatto pigments. An object of the present invention is to provide an excellent anti-fading agent and a method for preventing fading using the anti-fading agent, which can prevent the fading of these articles without affecting the quality or the like inherently possessed by the anti-fading agent.

【0004】[0004]

【課題を解決するための手段】このような事情を考慮し
て、本発明者らは、カロチノイド系色素の褪色防止につ
いて種々検討した結果、ペカンナッツ抽出物やこれとビ
タミンEを併用したものが優れた褪色防止効果を有して
いることを見出し、本発明を完成した。
In view of such circumstances, the present inventors have conducted various studies on the prevention of fading of carotenoid pigments. As a result, it was found that a pecan nut extract or a combination of vitamin E and pecan nut extract is excellent. The present inventors have found that they have a discoloration preventing effect, and have completed the present invention.

【0005】請求項1記載の本発明は、ペカンナッツ抽
出物を有効成分として含有するカロチノイド系色素の褪
色防止剤である。請求項2記載の本発明は、ペカンナッ
ツ抽出物とビタミンEを有効成分として含有するカロチ
ノイド系色素の褪色防止剤である。請求項3記載の本発
明は、ペカンナッツ抽出物1重量部に対しビタミンEを
0.01〜2.0重量部の割合で配合することを特徴と
する請求項2記載のカロチノイド系色素の褪色防止剤で
ある。請求項4記載の本発明は、カロチノイド系色素
に、請求項1、2及び3のいずれかに記載の褪色防止剤
を配合することを特徴とする褪色防止性が改善されたカ
ロチノイド系色素組成物である。請求項5記載の本発明
は、カロチノイド系色素を含有する飲食品、飼料、医薬
品、医薬部外品、保健衛生用品又は香粧品に、請求項
1、2及び3のいずれかに記載の褪色防止剤を配合する
ことを特徴とするカロチノイド系色素の褪色防止方法で
ある。請求項6記載の本発明は、飲食品、飼料、医薬
品、医薬部外品、保健衛生用品又は香粧品の製造にあた
り、着色料として請求項4記載のカロチノイド系色素組
成物を配合することを特徴とするカロチノイド系色素の
褪色防止方法である。
[0005] The present invention described in claim 1 is an anti-fading agent for carotenoid pigments containing a pecan nut extract as an active ingredient. The present invention according to claim 2 is an anti-fading agent for carotenoid pigments containing a pecan nut extract and vitamin E as active ingredients. The present invention according to claim 3 is characterized in that vitamin E is blended at a ratio of 0.01 to 2.0 parts by weight with respect to 1 part by weight of the pecan nut extract, and the carotenoid-based pigment according to claim 2 is prevented from fading. Agent. According to a fourth aspect of the present invention, there is provided a carotenoid-based pigment composition having improved anti-fading properties, comprising mixing the carotenoid-based pigment with the anti-fading agent according to any one of the first, second and third aspects. It is. The present invention according to claim 5 is a food or drink, feed, pharmaceutical, quasi-drug, health or hygiene product or cosmetic containing a carotenoid pigment, and the anti-fading method according to any one of claims 1, 2 and 3 A method for preventing discoloration of carotenoid pigments, which comprises adding an agent. The present invention according to claim 6 is characterized in that the carotenoid pigment composition according to claim 4 is blended as a coloring agent in the production of foods and drinks, feeds, pharmaceuticals, quasi-drugs, health and hygiene products, and cosmetics. This is a method for preventing discoloration of carotenoid pigments.

【0006】[0006]

【発明の実施の形態】以下において、本発明を詳細に説
明する。本発明の褪色防止剤の有効成分であるペカンナ
ッツ抽出物は、クルミ科ペカン属の植物の種子もしくは
種子殻を抽出して得られる抽出物であり、詳しくはクル
ミ科ペカン属に属する植物の種子または種子殻を水、ア
ルコール等の有機溶媒又は有機溶媒の含水物で抽出する
ことにより得られる抽出物である。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. The pecan nut extract which is an active ingredient of the anti-fading agent of the present invention is an extract obtained by extracting a seed or a seed shell of a plant belonging to the genus Pecan of the family Walnuts. It is an extract obtained by extracting a seed hull with an organic solvent such as water or alcohol or a hydrate of an organic solvent.

【0007】本発明で使用するクルミ科ペカン属の植物
は、主として北米から中米に分布しており、その種子の
胚部は古来より食用とされ、種子全体はペカンナッツも
しくはピーカンナッツと呼称されている。本発明に用い
るペカンナッツ抽出物の抽出方法は、特に限定されるも
のではなく、常法に従って行えばよい。以下に、好まし
い抽出方法について説明する。抽出溶媒としては、水、
加熱された水の他に、メタノール、エタノール、n−プ
ロパノール、iso−プロパノール、アセトン等の有機
溶媒が挙げられ、これらの単独又はこれら水や有機溶媒
の混合溶媒が好ましい。混合溶媒においては、上記有機
溶媒の含水物がより好ましい。
[0007] The plants of the genus Pecan of the family Walnuts used in the present invention are mainly distributed from North America to Central America, and the embryos of the seeds have been edible since ancient times, and the whole seeds are called pecan nuts or pecan nuts. I have. The method for extracting the pecan nut extract used in the present invention is not particularly limited, and may be performed according to a conventional method. Hereinafter, a preferred extraction method will be described. As an extraction solvent, water,
In addition to heated water, organic solvents such as methanol, ethanol, n-propanol, iso-propanol, and acetone can be mentioned, and these alone or a mixed solvent of water and an organic solvent are preferable. In the mixed solvent, a hydrate of the above organic solvent is more preferable.

【0008】抽出溶媒の使用量は特に限定されるもので
はなく、通常は使用するペカンナッツもしくはその殻の
重量の5〜100倍量とすればよい。抽出温度について
は、水もしくは熱水を抽出溶媒とする場合には、約20
℃〜120℃で行えばよい。有機溶媒もしくは含水有機
溶媒を抽出溶媒とする場合には、特に限定されるもので
はないが、好ましくは室温下、特に好ましくは20℃〜
30℃の温度下で抽出する。また、抽出時間について
は、水もしくは熱水抽出の場合は、5〜60分程度でよ
いが、有機溶媒もしくは含水有機溶媒による抽出の場合
には、24〜96時間が適当である。抽出を行った後、
濾紙や脱脂綿等を用いた自然濾過、減圧濾過等の手段に
よって各抽出溶媒可溶部を得、次いで減圧濾過等の手段
により溶媒を留去し、さらに必要に応じて凍結乾燥や噴
霧乾燥を行うことにより本発明に係る褪色防止剤の有効
成分であるペカンナッツ抽出物を得る。
[0008] The amount of the extraction solvent is not particularly limited, and may be usually 5 to 100 times the weight of the pecan nut or its shell used. The extraction temperature is about 20 when water or hot water is used as the extraction solvent.
C. to 120.degree. When an organic solvent or a water-containing organic solvent is used as the extraction solvent, the extraction solvent is not particularly limited, but is preferably at room temperature, particularly preferably 20 ° C to
Extract at a temperature of 30 ° C. The extraction time may be about 5 to 60 minutes in the case of extraction with water or hot water, but 24 to 96 hours is appropriate in the case of extraction with an organic solvent or a water-containing organic solvent. After performing the extraction,
Natural filtration using filter paper or cotton wool, etc., to obtain a portion soluble in each extraction solvent by means of filtration under reduced pressure, etc., then distill off the solvent by means such as filtration under reduced pressure, and further freeze-dry or spray-dry as necessary. Thereby, a pecan nut extract which is an active ingredient of the anti-fading agent according to the present invention is obtained.

【0009】こうして得られるペカンナッツ抽出物は、
極めて高いカロチノイド系色素褪色防止の効果を有し、
ビタミンEを併用することにより更に強力な効果を発揮
することができる。
[0009] The pecan nut extract thus obtained is
It has an extremely high effect of preventing carotenoid pigment discoloration,
A more powerful effect can be exhibited by using vitamin E in combination.

【0010】本発明に用いるペカンナッツ抽出物及びビ
タミンEは安全性が高く、且つ加熱等の加工手段を加え
ても、その効果は失われることなく安定である。そのた
め、これらの物質を退色防止剤として使用することによ
り、カロチノイド系色素の退色防止に優れた効果を奏す
ることができる。
The pecan nut extract and vitamin E used in the present invention are highly safe, and their effects are stable without losing their effects even when processing means such as heating are added. Therefore, by using these substances as an anti-fading agent, an excellent effect of preventing the fading of the carotenoid pigment can be obtained.

【0011】本発明の褪色防止剤の対象となる色素は、
カロチノイド系色素である。具体的には、α−カロチ
ン、β−カロチン、γ−カロチン、ルティン、クリプト
キサンチン、ゼアキサンチン、クロセチン、パプリカ色
素、アナトー、クチナシ黄色色素、リコピン色素等が挙
げられる。これら色素は飲食物などの物品に単独で、も
しくは2種類以上が混合して含まれていてもよい。
The dyes which are the object of the anti-fading agent of the present invention include:
It is a carotenoid pigment. Specific examples include α-carotene, β-carotene, γ-carotene, rutin, cryptoxanthin, zeaxanthin, crocetin, paprika dye, anato, gardenia yellow dye, and lycopene dye. These pigments may be contained alone or in a mixture of two or more in articles such as food and drink.

【0012】更に、本発明の褪色防止剤において併用す
るビタミンEとしては、合成あるいは天然のα−トコフ
ェロール、β−トコフェロール、γ−トコフェロール、
δ−トコフェロール、ε−トコフェロール、ζ−トコフ
ェロール、η−トコフェロールなどの他、これらと酢
酸、コハク酸又はニコチン酸等とのエステル類があり、
単独で、もしくは2種類以上を混合して使用することが
できる。
The vitamin E used in combination with the anti-fading agent of the present invention includes synthetic or natural α-tocopherol, β-tocopherol, γ-tocopherol,
Other than δ-tocopherol, ε-tocopherol, ζ-tocopherol, η-tocopherol, and the like, there are esters thereof with acetic acid, succinic acid, nicotinic acid, and the like,
They can be used alone or as a mixture of two or more.

【0013】請求項1〜3記載の本発明の褪色防止剤、
すなわちペカンナッツ抽出物またはペカンナッツ抽出物
とビタミンEを組み合わせたものの使用量は、カロチノ
イド系色素1重量部あたり0.02〜3.0重量部、好
ましくは0.3〜1.0重量部である。カロチノイド系
色素に対して、褪色防止剤の配合割合が下限値よりも少
ない場合は、期待する退色防止効果が得られない。一
方、褪色防止剤の配合割合が上限値よりも多い場合は、
官能上好ましくない状態となることがある。また、褪色
防止剤としてペカンナッツ抽出物とビタミンEを併用す
る場合は、ペカンナッツ抽出物1重量部に対してビタミ
ンEを0.01〜2.0重量部配合することが好まし
い。ビタミンEの配合割合が下限値より少ない場合、期
待する褪色防止効果が得られず、上限値より多い場合
は、官能上好ましくない状態になることがある。
The anti-fading agent of the present invention according to claims 1 to 3,
That is, the used amount of the pecan nut extract or the combination of the pecan nut extract and vitamin E is 0.02 to 3.0 parts by weight, preferably 0.3 to 1.0 part by weight, per part by weight of the carotenoid pigment. If the mixing ratio of the anti-fading agent to the carotenoid-based pigment is less than the lower limit, the expected anti-fading effect cannot be obtained. On the other hand, when the compounding ratio of the anti-fading agent is larger than the upper limit,
It may be in a state that is not functionally preferable. When the pecan nut extract and vitamin E are used in combination as an anti-fading agent, it is preferable to add 0.01 to 2.0 parts by weight of vitamin E to 1 part by weight of the pecan nut extract. If the blending ratio of vitamin E is less than the lower limit, the expected effect of preventing fading cannot be obtained, and if it is greater than the upper limit, a functionally unfavorable state may result.

【0014】次に、請求項4記載の本発明について述べ
る。請求項4記載の本発明は、カロチノイド系色素に上
記の褪色防止剤を配合してなる組成物である。この組成
物は、アラビアガム等の乳化剤を用いて乳化処理を行っ
てカロチノイド系色素乳化組成物の形態とすることもで
きる。本発明に係る組成物がカロチノイド系色素乳化組
成物である場合は、乳化剤、比重調整剤、油脂、多価ア
ルコール類を配合することが好ましい。カロチノイド系
色素を乳化組成物とする場合は、通常カロチノイド系色
素を色素乳化組成物に対して0. 1〜5. 0重量%配合
する。また、カロチノイド系色素乳化組成物中における
褪色防止剤の配合量は、該組成物に含まれるカロチノイ
ド系色素に基づいて決定すればよく、カロチノイド系色
素1重量部に対して褪色防止剤0. 02〜3. 0重量
部、好ましくは0. 3〜1. 0重量部が適当である。カ
ロチノイド系色素に対して、褪色防止剤の配合量が下限
値よりも少ない場合は、期待する褪色防止効果が得られ
ない。一方、褪色防止剤を上限値を越えて必要以上に多
く配合すると、官能上好ましくないものとなることがあ
る。
Next, a fourth aspect of the present invention will be described. The present invention according to claim 4 is a composition comprising a carotenoid-based pigment and the above-mentioned anti-fading agent. The composition may be emulsified using an emulsifier such as gum arabic to form a carotenoid-based pigment emulsified composition. When the composition according to the present invention is a carotenoid-based pigment emulsified composition, it is preferable to incorporate an emulsifier, a specific gravity adjuster, a fat or oil, and a polyhydric alcohol. When a carotenoid pigment is used as an emulsified composition, the carotenoid pigment is usually added in an amount of 0.1 to 5.0% by weight based on the pigment emulsified composition. The amount of the anti-fading agent in the carotenoid-based pigment emulsified composition may be determined based on the carotenoid-based pigment contained in the composition. The amount is suitably from 3.0 to 3.0 parts by weight, preferably from 0.3 to 1.0 parts by weight. If the amount of the anti-fading agent is less than the lower limit of the carotenoid pigment, the expected anti-fading effect cannot be obtained. On the other hand, if the discoloration inhibitor exceeds the upper limit and is added in an unnecessarily large amount, it may be undesirably functional.

【0015】また、本発明品がカロチノイド系色素乳化
組成物である場合、使用できる好適な乳化剤としてアラ
ビアガムが挙げられる。アラビアガムは、夾雑物を除い
た水溶液として用いられる。本発明には、アラビアガム
のような天然物以外にも、合成の乳化剤を使用すること
ができる。例えば、ポリグリセリン脂肪酸エステル、シ
ョ糖脂肪酸エステルなどが挙げられる。
When the product of the present invention is a carotenoid pigment emulsified composition, gum arabic is mentioned as a suitable emulsifier that can be used. Gum arabic is used as an aqueous solution from which impurities are removed. In the present invention, besides natural products such as gum arabic, synthetic emulsifiers can be used. For example, polyglycerin fatty acid ester, sucrose fatty acid ester and the like can be mentioned.

【0016】本発明品がアラビアガム等の乳化剤を用い
たカロチノイド系色素乳化組成物である場合、通常は比
重調整剤を配合する。比重調整剤として使用できるもの
にショ糖酢酸イソ酪酸エステル(Sucrose acetate iso-
butyrate、以下SAIBとする)がある。SAIBは、
ショ糖の水酸基2個が酢酸基、また6個がイソ酪酸基で
エステル化されており、更に8個の水酸基全部は脂肪酸
で置換されている。そのため、油脂類に良く溶け、比重
調整剤として広く使用されているものである。また、本
発明に使用できる油脂については、カロチノイド系色素
製剤の用途に応じて選択すればよく、飲食品、飼料等に
使用する場合には、可食性の油脂であれば良い。具体的
には、大豆油、サフラワー油、綿実油、ゴマ油、コーン
油、ヒマワリ油、オリーブ油、菜種油、落花生油、ヤシ
油、パーム油、コメ油、牛脂、豚脂、魚油などの動植物
油脂又は炭素数6〜12の中鎖飽和脂肪酸トリグリセラ
イド等の可食性油性材料並びにこれらの任意な混合物等
が挙げられる。
When the product of the present invention is a carotenoid pigment emulsified composition using an emulsifier such as gum arabic, a specific gravity adjuster is usually added. Sucrose acetate iso-butyrate (Sucrose acetate iso-
butyrate, hereinafter referred to as SAIB). SAIB,
Two hydroxyl groups of sucrose are esterified with an acetic acid group and six are isobutyric acid groups, and all eight hydroxyl groups are substituted with fatty acids. Therefore, it is well soluble in fats and oils and is widely used as a specific gravity adjuster. The fats and oils that can be used in the present invention may be selected according to the use of the carotenoid-based pigment preparation. When used in foods and drinks, feeds, and the like, any edible fats and oils may be used. Specifically, animal and vegetable oils or carbon such as soybean oil, safflower oil, cottonseed oil, sesame oil, corn oil, sunflower oil, olive oil, rapeseed oil, peanut oil, coconut oil, palm oil, rice oil, tallow, lard, fish oil, etc. An edible oily material such as triglyceride of a medium-chain saturated fatty acid of Formulas 6 to 12 and an arbitrary mixture thereof are included.

【0017】更に、本発明に使用できる多価アルコール
類としては、グリセリン、プロピレングリコール、ソル
ビトール、マルチトールなどや、これらの任意な混合物
等が挙げられる。
Furthermore, examples of the polyhydric alcohol that can be used in the present invention include glycerin, propylene glycol, sorbitol, maltitol and the like, and arbitrary mixtures thereof.

【0018】カロチノイド系色素乳化組成物における上
記各成分の配合割合は、通常カロチノイド系色素乳化組
成物が添加される各種飲食品、飼料、医薬品、医薬部外
品、保健衛生品及び香粧品等により適宜決められる。乳
化の方法は、特に限定されるものではなく、以下に好ま
しい乳化の方法について説明する。
The mixing ratio of each of the above components in the carotenoid-based pigment emulsified composition depends on various foods and drinks, feeds, pharmaceuticals, quasi-drugs, health and hygiene products, cosmetics, etc. to which the carotenoid-based pigment emulsified composition is usually added. It is determined as appropriate. The emulsification method is not particularly limited, and a preferred emulsification method will be described below.

【0019】カロチノイド系色素、ヤシ油等の可食性油
性材料、SAIBを混合後、約100〜150℃に加熱
溶解して均一な混合油にする。次に、ペカンナッツ抽出
物、アラビアガム水溶液、プロピレングリコールを混合
し、約80℃で30分ほど加熱殺菌する。ここに、先の
均一混合油を加え、5000〜10000rpmで5〜
30分間攪拌し予備乳化を行い、高圧ホモジナイザーに
より200〜250Kg/cm2 、5〜10分間高圧均
質化処理し、カロチノイド系色素乳化組成物を得る。ま
た、褪色防止剤として、ペカンナッツ抽出物とビタミン
Eを併用する場合には、カロチノイド系色素、ヤシ油等
の可食性油性材料、SAIBを混合する際にビタミンE
も更に添加し、約100〜150℃で加熱溶解して均一
混合油を調製する。これ以降の処理方法は、前述の方法
と同様にして目的とする色素乳化組成物を得る。その
他、公知の方法により乳化組成物としてもよい。
After mixing a carotenoid pigment, an edible oil-based material such as coconut oil, and SAIB, the mixture is heated and dissolved at about 100 to 150 ° C. to form a uniform mixed oil. Next, the pecan nut extract, the aqueous solution of gum arabic, and propylene glycol are mixed and sterilized by heating at about 80 ° C. for about 30 minutes. Here, the above-mentioned homogeneous mixed oil is added, and it is 5 to 10,000 rpm.
Preliminary emulsification is carried out by stirring for 30 minutes, and high-pressure homogenization treatment is carried out with a high-pressure homogenizer at 200 to 250 Kg / cm 2 for 5 to 10 minutes to obtain a carotenoid pigment emulsion composition. When a pecan nut extract and vitamin E are used in combination as an anti-fading agent, when carotenoid pigments, edible oily materials such as coconut oil, and SAIB are mixed, vitamin E
And further heat-dissolve at about 100 to 150 ° C. to prepare a homogeneous mixed oil. Subsequent treatment methods are the same as those described above to obtain the desired dye emulsion composition. In addition, an emulsion composition may be prepared by a known method.

【0020】本発明の褪色防止剤及びカロチノイド系色
素乳化組成物は、各種飲料や食品、飼料、医薬品、医薬
部外品、保健衛生用品及び香粧品等の物品に用いること
ができる。ここで、これら物品には本来的にカロチノイ
ド系色素を含有するものや、カロチノイド系色素を添加
することによって着色されたものがある。前者の場合
は、基本的には本発明の褪色防止剤が用いられ、後者の
場合は、褪色防止剤を含有するカロチノイド系色素乳化
組成物が用いられる。
The anti-fading agent and the carotenoid pigment emulsified composition of the present invention can be used for articles such as various drinks, foods, feeds, pharmaceuticals, quasi-drugs, health and hygiene products, and cosmetics. Here, some of these articles inherently contain a carotenoid pigment, and some are colored by adding a carotenoid pigment. In the former case, the anti-fading agent of the present invention is basically used, and in the latter case, a carotenoid-based pigment emulsion composition containing the anti-fading agent is used.

【0021】飲食品の例としては、清涼飲料、果汁飲
料、アルコール飲料等液体飲料;アイスクリーム、シャ
ーベット、氷菓、ゼリー等冷菓・デザート類;キャンデ
ィー、チューインガム、錠菓、クッキー、パン、ジャ
ム、センタークリーム、ケーキ、和菓子等製菓ベーカリ
ー製品;チーズ、バター、発酵乳等乳製品;マーガリ
ン、マヨネーズ、ドレッシング等油脂加工食品;ハム、
かまぼこ等畜肉・水産製品;生中華麺、しゅうまい・餃
子の皮、即席麺等の小麦粉・澱粉の加工食品、健康食品
等を挙げることができる。
Examples of foods and drinks include liquid drinks such as soft drinks, fruit drinks, and alcoholic drinks; cold desserts and desserts such as ice cream, sorbet, frozen desserts, and jelly; candies, chewing gum, tablet confectionery, cookies, bread, jam, and centers. Confectionery bakery products such as cream, cake, Japanese confectionery; dairy products such as cheese, butter, and fermented milk; processed oil and fat products such as margarine, mayonnaise, and dressing;
Livestock meat and marine products such as kamaboko; raw Chinese noodles, sweet potato, dumpling skin, instant noodles and the like, processed foods of flour and starch, health foods, and the like.

【0022】これら飲食品には、使用目的に応じた任意
の成分を用いることができ、また本発明品を添加する場
合は、その飲食品の形態により適宜使用すればよい。一
般的には、上記の物品に対して本発明の褪色防止剤を
0.0000002〜0.45重量%、好ましくは0.
000001〜0.3重量%、さらに好ましくは0.0
00015〜0.1重量%配合すればよく、また本発明
のカロチノイド系色素組成物を用いる場合は、上記の物
品に対して0.01〜3.0重量%、好ましくは0.0
5〜2.0重量%の範囲で配合するのがよい。
These foods and drinks can use any components according to the purpose of use, and when the product of the present invention is added, it may be used appropriately depending on the form of the food or drink. Generally, the anti-fading agent of the present invention is used in an amount of 0.0000002 to 0.45% by weight, preferably 0.1% by weight, based on the above article.
00000-0.3% by weight, more preferably 0.0
The carotenoid pigment composition of the present invention may be used in an amount of 0.01 to 3.0% by weight, preferably 0.01 to 3.0% by weight.
It is preferable to mix in the range of 5 to 2.0% by weight.

【0023】更に、本発明品を各種飼料に配合すること
もできる。飼料の形態としては、牛育成用、採卵鶏飼
料、養魚用飼料等が挙げられる。これら飼料に対して、
本発明品を必要に応じて適宜添加すればよい。本発明の
褪色防止剤の添加量は、0.0000002〜0.45
重量%、好ましくは0.000001〜0.3重量%、
さらに好ましくは0.000015〜0.1重量%であ
り、カロチノイド系色素組成物の添加量は、0.01〜
3. 0重量%、好ましくは0.05〜2.0重量%の範
囲とするのがよい。
Further, the product of the present invention can be blended in various feeds. Examples of the form of the feed include feed for raising cattle, feed for laying hens, feed for fish farming, and the like. For these feeds,
The product of the present invention may be appropriately added as needed. The amount of the anti-fading agent of the present invention is 0.0000002 to 0.45.
% By weight, preferably 0.000001 to 0.3% by weight,
More preferably, the amount is 0.000015 to 0.1% by weight, and the amount of the carotenoid pigment composition is 0.01 to 0.1% by weight.
3.0 wt%, preferably in the range of 0.05 to 2.0 wt%.

【0024】本発明に係る褪色防止剤やカロチノイド系
色素組成物は、上記物品の他、各種医薬品、医薬部外
品、保健衛生用品、香粧品などにも使用することがで
き、例えば錠剤、カプセル剤、液状経口薬、ドリンク
剤、栄養ドリンク、トローチ、うがい薬、歯磨き、口中
清涼剤、口臭防止剤、スキンローション、乳液、クリー
ム類、口紅、その他に含まれる原料由来のカロチノイド
系色素または添加されたカロチノイド系色素を含有する
組成物又は製品等に使用できる。
The anti-fading agent and the carotenoid pigment composition according to the present invention can be used in various pharmaceuticals, quasi-drugs, health and hygiene products, cosmetics, and the like in addition to the above-mentioned articles. Agents, liquid oral medicines, drinks, nutritional drinks, troches, mouthwashes, toothpastes, mouth fresheners, anti-odor agents, skin lotions, emulsions, creams, lipsticks, and other carotenoid pigments derived from raw materials contained in or added It can be used in compositions or products containing carotenoid pigments.

【0025】本発明の褪色防止剤及びカロチノイド系色
素組成物には、所望により、他の褪色防止剤や抗酸化剤
を併用することもできる。
The anti-fading agent and the carotenoid-based dye composition of the present invention may optionally contain other anti-fading agents and antioxidants.

【0026】[0026]

【実施例】次に、本発明を実施例などにより詳しく説明
するが、本発明はこれらによって制限されるものではな
い。
EXAMPLES Next, the present invention will be described in more detail with reference to examples and the like, but the present invention is not limited thereto.

【0027】製造例1(ペカンナッツ抽出物の製造) ペカンナッツの食用部を除去して得た種子殻を粉砕し、
その粉砕物100gに蒸留水500mLを加えて110
℃下で10分間加熱抽出を行った。室温まで冷却後、水
可溶部の濾紙濾過を行い、50℃下で減圧濃縮して水を
留去し、さらに凍結乾燥し、目的とする有効成分(淡褐
色の粉体6.5g、収率6.5%)を得た。
Production Example 1 (Production of Pecan Nut Extract) The seed shell obtained by removing the edible part of pecan nut was pulverized,
Add 500 mL of distilled water to 100 g of the pulverized product and add 110 g
Heat extraction was performed at 10 ° C. for 10 minutes. After cooling to room temperature, the water-soluble portion was filtered through a filter paper, concentrated under reduced pressure at 50 ° C. to distill off water, and further freeze-dried to obtain the desired active ingredient (6.5 g of light brown powder, yield). 6.5%).

【0028】上記の方法により得られた有効成分の赤外
吸収スペクトルは以下の通りであった。なお、本スペク
トル測定装置は、日本分光(株)製のIR−810型、
試料の調製法は、KBr法により行った。 有効成分の吸収ピーク(cm-1):3400〜3300
(broad)、1615、1450、1350、12
00、1040、830
The infrared absorption spectrum of the active ingredient obtained by the above method was as follows. In addition, this spectrum measuring device is IR-810 type manufactured by JASCO Corporation,
The sample was prepared by the KBr method. Active ingredient absorption peak (cm -1 ): 3400-3300
(Broad), 1615, 1450, 1350, 12
00, 1040, 830

【0029】実施例1(色素組成物の製造、パプリカ色
素組成物) パプリカ色素(スタンゲ社製)4.0g、SAIB1
8.0g、ヤシ油16.0gの混合物を150℃に加熱
して、均一な油溶性混合物とした。次に、水54.0g
にペカンナッツ抽出物1.2gを溶解し、更にアラビア
ガム(固形分30%)266.8g、プロピレングリコ
ール40.0gを加えて得た混合物を80℃で30分間
加熱殺菌を行った。ここに、先の均一な油溶性混合物を
加え、5000〜10000rpm、5〜30分間の条
件でTKミキサー(特殊機化工業社製)にて攪拌し予備
乳化を行った。次いで、高圧ホモジナイザー(ゴーリン
社製)により200〜250Kg/cm2、5〜10分
間の条件で高圧均質化処理し、カロチノイド系色素乳化
組成物を得た。
Example 1 (Production of Dye Composition, Paprika Dye Composition) 4.0 g of paprika dye (manufactured by Stange), SAIB1
A mixture of 8.0 g and coconut oil 16.0 g was heated to 150 ° C. to obtain a uniform oil-soluble mixture. Next, 54.0 g of water
Then, a mixture obtained by dissolving 1.2 g of the pecan nut extract and adding 266.8 g of gum arabic (solid content: 30%) and 40.0 g of propylene glycol were heat-sterilized at 80 ° C. for 30 minutes. The above uniform oil-soluble mixture was added thereto, and the mixture was stirred with a TK mixer (manufactured by Tokushu Kika Kogyo Co., Ltd.) under conditions of 5000 to 10000 rpm for 5 to 30 minutes to perform preliminary emulsification. Next, high-pressure homogenization was performed with a high-pressure homogenizer (manufactured by Gorin) at 200 to 250 kg / cm 2 for 5 to 10 minutes to obtain a carotenoid-based pigment emulsion composition.

【0030】実施例2(色素組成物の製造、パプリカ色
素組成物) ペカンナッツ抽出物の添加量を変化させたことを除き、
実施例1と同様の方法で色素組成物を得た。
Example 2 (Preparation of pigment composition, paprika pigment composition) Except that the amount of pecan nut extract added was changed,
A dye composition was obtained in the same manner as in Example 1.

【0031】実施例3(色素組成物の製造、パプリカ色
素組成物) パプリカ色素(スタンゲ社製)4.0g、SAIB1
8.0g、ヤシ油16.0g、ビタミンE(エーザイ社
製)0.2gの混合物を150℃に加熱して、均一な油
溶性混合物とした。次に、水53.8gにペカンナッツ
抽出物1.2gを溶解し、更にアラビアガム(固形分3
0%)266.8g、プロピレングリコール40.0g
を加えて得た混合物を80℃で30分間加熱殺菌を行っ
た。ここに、先の均一な油溶性混合物を加え、5000
〜10000rpm、5〜30分間の条件でTKミキサ
ー(特殊機化工業社製)にて攪拌し予備乳化を行った。
次いで、高圧ホモジナイザー(ゴーリン社製)により2
00〜250Kg/cm2、5〜10分間の条件で高圧
均質化処理し、カロチノイド系色素乳化組成物を得た。
Example 3 (Production of Dye Composition, Paprika Dye Composition) 4.0 g of paprika dye (manufactured by Stange), SAIB1
A mixture of 8.0 g, 16.0 g of coconut oil, and 0.2 g of vitamin E (manufactured by Eisai) was heated to 150 ° C. to obtain a uniform oil-soluble mixture. Next, 1.2 g of the pecan nut extract was dissolved in 53.8 g of water, and gum arabic (solid content: 3 g) was added.
(0%) 266.8 g, propylene glycol 40.0 g
The mixture obtained by adding was sterilized by heating at 80 ° C. for 30 minutes. Here, the above uniform oil-soluble mixture was added, and 5000
Preliminary emulsification was performed by stirring with a TK mixer (manufactured by Tokushu Kika Kogyo Co., Ltd.) under the conditions of 1 to 10,000 rpm and 5 to 30 minutes.
Then, a high pressure homogenizer (Gaulin Co., Ltd.)
High-pressure homogenization treatment was performed under the conditions of 00 to 250 Kg / cm 2 for 5 to 10 minutes to obtain a carotenoid-based pigment emulsion composition.

【0032】実施例4〜11(色素組成物の製造、パプ
リカ色素組成物) ペカンナッツ抽出物とビタミンE(エーザイ社製)の添
加量を変化させたことを除き、実施例3と同様の方法で
色素組成物を得た。
Examples 4 to 11 (Production of pigment composition, paprika pigment composition) Except that the amounts of the pecan nut extract and vitamin E (manufactured by Eisai Co., Ltd.) were changed, the same method as in Example 3 was used. A dye composition was obtained.

【0033】実施例12(色素組成物の製造、β−カロ
チン色素組成物) パプリカ色素に代えてβ−カロチン(ロッシュビタミン
ジャパン社製)を用いたこと及びSAIB、ヤシ油の
添加量を変えたことを除き、実施例3と同様の方法で色
素組成物を得た。
Example 12 (Production of pigment composition, β-carotene pigment composition) β-carotene (manufactured by Roche Vitamin Japan) was used instead of paprika pigment, and the amounts of added SAIB and coconut oil were changed. Except for this, a dye composition was obtained in the same manner as in Example 3.

【0034】実施例1〜12の各色素組成物の組成を表
1に示す。
Table 1 shows the composition of each of the dye compositions of Examples 1 to 12.

【0035】[0035]

【表1】表1(その1) [Table 1] Table 1 (Part 1)

【0036】[0036]

【表2】表1(その2) [Table 2] Table 1 (Part 2)

【0037】比較例1〜5(色素組成物の製造) 色素及び褪色防止剤の種類や添加量を変化させたことを
除き、実施例1や実施例3と同様の方法で色素組成物を
得た。
Comparative Examples 1 to 5 (Preparation of Dye Composition) A dye composition was obtained in the same manner as in Examples 1 and 3, except that the types and amounts of the dye and the anti-fading agent were changed. Was.

【0038】比較例1〜5の各色素組成物の組成を表2
に示す。
Table 2 shows the composition of each dye composition of Comparative Examples 1 to 5.
Shown in

【0039】[0039]

【表3】表2 クロロゲン酸:東京化成工業社製 ビタミンC:武田薬品工業社製 ビタミンE:エーザイ社製[Table 3] Table 2 Chlorogenic acid: manufactured by Tokyo Chemical Industry Co., Ltd. Vitamin C: manufactured by Takeda Pharmaceutical Co., Ltd. Vitamin E: manufactured by Eisai

【0040】試験例1(着色飲料の製造) 精製水にグラニュー糖を混合し、ブリックス(可溶性固
形分濃度)10%のシロップを調製した。飲料用透明ガ
ラス瓶に、調製したシロップを100mlずつ充填し、
次に実施例1〜12及び比較例1〜5のカロチノイド系
色素乳化組成物をそれぞれ0.1重量%ずつ添加し、80
℃、20分間の条件で殺菌を行い、着色飲料1〜12
(実施例1〜12の色素組成物を含む着色飲料)並びに
着色飲料13〜17(比較例1〜5の色素組成物を含む
着色飲料)を製造した(着色飲料No. は表1および表2
に示した)。
Test Example 1 (Production of Colored Beverage) Granulated sugar was mixed with purified water to prepare a syrup having a brix (soluble solid content concentration) of 10%. Fill 100 ml of the prepared syrup into a transparent glass bottle for beverages,
Next, the carotenoid pigment emulsified compositions of Examples 1 to 12 and Comparative Examples 1 to 5 were each added in an amount of 0.1% by weight, and
Sterilized at 20 ° C. for 20 minutes, and colored beverages 1 to 12
(Colored beverages containing the pigment compositions of Examples 1 to 12) and Colored beverages 13 to 17 (colored beverages containing the pigment compositions of Comparative Examples 1 to 5) were produced (the colored beverage Nos. Are shown in Tables 1 and 2).
Pointing out toungue).

【0041】試験例2(ペカンナッツ抽出物の褪色防止
効果) ペカンナッツ抽出物によるカロチノイド系色素の褪色防
止効果の評価を行った。すなわち、上記で製造した着色
飲料1、2、13、14について、蛍光灯付き恒温恒湿
槽(LH3014M、ナガノ科学製作所社製)を用い、
25℃、蛍光照射9000ルクス(lx)下で保存し
た。それぞれの着色飲料について、蛍光照射6時間後と
17時間後のλmaxの波長(480nm)における吸
光度を分光光度計(UV−1200、島津製作所社製)
で測定し、以下の式で色素残存率(%)を求めた。結果
を表3に示す。
Test Example 2 (Effect of Preventing Pecan Nut Extract from Discoloration) The effect of pecan nut extract on the anti-fading of carotenoid pigments was evaluated. That is, for the colored beverages 1, 2, 13, and 14 produced above, using a constant temperature / humidity chamber with a fluorescent lamp (LH3014M, manufactured by Nagano Science Co., Ltd.)
It was stored at 25 ° C. under 9,000 lux (lx) of fluorescence irradiation. For each of the colored beverages, the absorbance at a wavelength of λmax (480 nm) after 6 hours and 17 hours of fluorescence irradiation was measured using a spectrophotometer (UV-1200, manufactured by Shimadzu Corporation).
And the residual ratio (%) of the dye was determined by the following equation. Table 3 shows the results.

【0042】[0042]

【数1】 (Equation 1)

【0043】[0043]

【表4】表3 ペカンナッツ抽出物の褪色防止効果 [Table 4] Table 3 Anti-fading effect of pecan nut extract

【0044】表3に示したとおり、ペカンナッツ抽出物
は、他の水溶性褪色防止剤であるビタミンCやクロロゲ
ン酸と比較すると、褪色防止効果が優れている。
As shown in Table 3, the pecan nut extract has an excellent anti-fading effect as compared with other water-soluble anti-fading agents such as vitamin C and chlorogenic acid.

【0045】上記表中の対照品は、褪色防止剤を添加し
ないことを除き、実施例1と同様の方法で色素組成物を
得た後に、同様に着色飲料を製造した。褪色防止剤の添
加量は、製造した色素組成物中の褪色防止成分の重量%
である。
The control products in the above table were prepared in the same manner as in Example 1 except that no anti-fading agent was added, and then a colored beverage was produced in the same manner. The amount of the anti-fading agent is based on the weight% of the anti-fading component in the produced dye composition.
It is.

【0046】試験例3(ペカンナッツ抽出物とビタミン
Eを併用したときの褪色防止効果)ペカンナッツ抽出物
とビタミンEを併用した場合のカロチノイド系色素の褪
色防止効果の評価を行った。着色飲料3、4、5、6、
7、8、15、16について、試験例2と同様な方法
で、蛍光照射24時間後、56時間後、78時間後の色
素残存率を求めた。結果を表4に示す。
Test Example 3 (Discoloration preventing effect when pecan nut extract and vitamin E are used in combination) The discoloration preventing effect of carotenoid pigments when pecan nut extract and vitamin E were used in combination was evaluated. Colored beverages 3, 4, 5, 6,
With respect to 7, 8, 15, and 16, the dye remaining rates after 24 hours, 56 hours, and 78 hours after fluorescence irradiation were determined in the same manner as in Test Example 2. Table 4 shows the results.

【0047】表4から明らかなように、ペカンナッツ抽
出物とビタミンEを併用すると、ペカンナッツ抽出物以
外の水溶性の褪色防止剤として従来使用されているビタ
ミンCやクロロゲン酸とビタミンEを併用した場合より
も持続性のある優れた褪色防止効果が得られた。
As is evident from Table 4, when the pecan nut extract and vitamin E are used in combination, when vitamin E or chlorogenic acid, which is conventionally used as a water-soluble anti-fading agent other than the pecan nut extract, is used in combination with vitamin E. An excellent anti-fading effect with more sustainability was obtained.

【0048】[0048]

【表5】表4 ペカンナッツ抽出物とビタミンEを併用
したときの褪色防止効果
[Table 5] Table 4 Anti-fading effect when pecan nut extract and vitamin E are used in combination

【0049】上記表中の対照品は、褪色防止剤を添加し
ないこと以外は、実施例2と同様の方法で色素組成物を
得た後に、同様に着色飲料を製造した。なお、褪色防止
剤の添加量は、製造した色素組成物中の褪色防止成分の
重量%である。
The control products in the above table were prepared in the same manner as in Example 2, except that no anti-fading agent was added, and then a colored beverage was produced in the same manner. The amount of the anti-fading agent is the weight% of the anti-fading component in the produced dye composition.

【0050】実施例13(オレンジジュースの製造) 下記処方の成分を用いて常法によりオレンジジュース1
000gを製造した。 成 分 配合割合(重量%) オレンジ果汁 2.0 果糖ブドウ糖液糖 1.4 クエン酸 0.02 実施例1で製造した色素組成物 0.1 オレンジ香料 0.1 水 残部
Example 13 (Manufacture of orange juice) Orange juice 1 was prepared by a conventional method using the following components.
000 g were produced. Ingredients Compounding ratio (% by weight) Orange juice 2.0 Fructose-glucose liquid sugar 1.4 Citric acid 0.02 Pigment composition produced in Example 1 0.1 Orange flavor 0.1 Water Remainder

【0051】実施例14(オレンジゼリーの製造) 下記処方の成分を用いて常法によりオレンジゼリー10
0gを製造した。 成 分 配合割合(重量%) オレンジ果汁 30.0 グラニュー糖 0.8 寒天 15.0 クエン酸 0.2 実施例12で製造した色素組成物 0.1 オレンジ香料 0.1 水 残部
Example 14 (Production of orange jelly) Orange jelly 10 was prepared in a conventional manner using the following ingredients.
0 g was produced. Ingredients Mixing ratio (% by weight) Orange juice 30.0 Granulated sugar 0.8 Agar 15.0 Citric acid 0.2 Pigment composition produced in Example 12 0.1 Orange flavor 0.1 Water Remainder

【0052】実施例15(牛育成用飼料の製造) 下記処方の成分を用いて常法により牛育成用飼料100
0gを製造した。 成 分 配合割合(重量%) 脱脂粉乳 72.0 動物性油脂 20.0 魚エキスパウダー 5.0 ミネラル類混合物 1.5 実施例3で製造した色素組成物 1.5
Example 15 (Manufacture of feed for cattle breeding) Feed for cattle breeding 100 was prepared by a conventional method using the following components.
0 g was produced. Ingredients Mixing ratio (% by weight) Skim milk powder 72.0 Animal fats and oils 20.0 Fish extract powder 5.0 Mineral mixture 1.5 Pigment composition produced in Example 3 1.5

【0053】[0053]

【発明の効果】本発明のカロチノイド系色素褪色防止剤
は、ペカンナッツ抽出物を有効成分とし、更にペカンナ
ッツ抽出物にビタミンEを併用したものを有効成分と
し、カロチノイド系色素の褪色防止に優れた効果を有し
ている。そのため、飲食品、飼料、医薬品、医薬部外
品、保健衛生用品及び香粧品などに添加することによ
り、これらの製品に含まれたカロチノイド系色素の褪色
防止を図ることに極めて有用である。
The carotenoid pigment anti-fading agent of the present invention comprises a pecan nut extract as an active ingredient, a pecan nut extract combined with vitamin E as an active ingredient, and has an excellent effect of preventing the carotenoid pigment from fading. have. Therefore, when added to foods and drinks, feeds, pharmaceuticals, quasi-drugs, health and hygiene products, cosmetics, and the like, it is extremely useful for preventing discoloration of carotenoid-based pigments contained in these products.

【0054】更に、本発明のカロチノイド系色素組成物
は、カロチノイド系色素に上記の褪色防止剤を配合した
ものであり、このものを飲食品等の物品に着色料として
添加して調製した製品は、長期間にわたりカロチノイド
系色素の褪色を防止することができる。
Further, the carotenoid-based pigment composition of the present invention is obtained by adding the above-mentioned anti-fading agent to a carotenoid-based pigment. The discoloration of the carotenoid pigment can be prevented for a long period of time.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C09K 15/08 C09K 15/08 (72)発明者 川田 泉 神奈川県平塚市西八幡1丁目4番11号 高 砂香料工業株式会社総合研究所内 (72)発明者 石井 潯 神奈川県平塚市西八幡1丁目4番11号 高 砂香料工業株式会社総合研究所内 Fターム(参考) 2B150 AA02 AA05 AA08 AB02 AB05 AB08 AB20 DD31 DD57 DE15 4B018 MA01 MB05 MC04 MF01 4H025 AA83 BA01 BA04 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C09K 15/08 C09K 15/08 (72) Inventor Izumi Kawada 1-4-11 Nishi-Hachiman, Hiratsuka-shi, Kanagawa Takasago International Co., Ltd. (72) Inventor Shun Ishii 1-4-11 Nishi-Hachiman, Hiratsuka-shi, Kanagawa Prefecture Takasago International Co., Ltd. F-term (reference) 2B150 AA02 AA05 AA08 AB02 AB05 AB08 AB20 DD31 DD57 DE15 4B018 MA01 MB05 MC04 MF01 4H025 AA83 BA01 BA04

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 ペカンナッツ抽出物を有効成分として含
有するカロチノイド系色素の褪色防止剤。
1. An anti-fading agent for carotenoid pigments containing a pecan nut extract as an active ingredient.
【請求項2】 ペカンナッツ抽出物とビタミンEを有効
成分として含有するカロチノイド系色素の褪色防止剤。
2. An anti-fading agent for carotenoid pigments comprising a pecan nut extract and vitamin E as active ingredients.
【請求項3】 ペカンナッツ抽出物1重量部に対しビタ
ミンEを0.01〜2.0重量部の割合で配合すること
を特徴とする請求項2記載のカロチノイド系色素の褪色
防止剤。
3. The anti-fading agent for carotenoid pigments according to claim 2, wherein vitamin E is mixed in an amount of 0.01 to 2.0 parts by weight per 1 part by weight of the pecan nut extract.
【請求項4】 カロチノイド系色素に、請求項1、2及
び3のいずれかに記載の褪色防止剤を配合することを特
徴とする褪色防止性が改善されたカロチノイド系色素組
成物。
4. A carotenoid-based dye composition having improved anti-fading properties, characterized in that the anti-fading agent according to any one of claims 1, 2 and 3 is added to a carotenoid-based dye.
【請求項5】 カロチノイド系色素を含有する飲食品、
飼料、医薬品、医薬部外品、保健衛生用品又は香粧品
に、請求項1、2及び3のいずれかに記載の褪色防止剤
を配合することを特徴とするカロチノイド系色素の褪色
防止方法。
5. A food or drink containing a carotenoid pigment,
A method for preventing discoloration of carotenoid pigments, comprising incorporating the anti-fading agent according to any one of claims 1, 2 and 3 into feed, pharmaceuticals, quasi-drugs, health and hygiene products or cosmetics.
【請求項6】 飲食品、飼料、医薬品、医薬部外品、保
健衛生用品又は香粧品の製造にあたり、着色料として請
求項4記載のカロチノイド系色素組成物を配合すること
を特徴とするカロチノイド系色素の褪色防止方法。
6. A carotenoid based composition comprising the carotenoid pigment composition according to claim 4 as a coloring agent in the production of foods and drinks, feeds, pharmaceuticals, quasi-drugs, health and hygiene products and cosmetics. A method for preventing color fading.
JP2000240923A 2000-08-09 2000-08-09 Fading inhibitor of carotenoid pigment and method for preventing fading Pending JP2002053857A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004107314A (en) * 2002-07-23 2004-04-08 Orbis Inc Oral administration formulation for antioxidation
JP2005060534A (en) * 2003-08-12 2005-03-10 Sanei Gen Ffi Inc Fading inhibitor
JP2010195925A (en) * 2009-02-25 2010-09-09 T Hasegawa Co Ltd Antioxidant composition
JP2012075340A (en) * 2010-09-30 2012-04-19 Riken Vitamin Co Ltd Anthocyanin pigment discoloration-preventing agent
CN108142488A (en) * 2018-02-08 2018-06-12 宁波海通食品科技有限公司 A kind of method that white control is returned in ice cream moon cakes cake shell stored frozen phase colour fading
JPWO2017171091A1 (en) * 2016-04-01 2019-02-14 三栄源エフ・エフ・アイ株式会社 Method for stabilizing solid dyes
CN113801493A (en) * 2021-10-14 2021-12-17 锦柯草木染(上海)纺织科技有限公司 Method for extracting natural dye from outer skin of pecan

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004107314A (en) * 2002-07-23 2004-04-08 Orbis Inc Oral administration formulation for antioxidation
JP4527938B2 (en) * 2002-07-23 2010-08-18 オルビス株式会社 Orally administered composition for antioxidant
JP2005060534A (en) * 2003-08-12 2005-03-10 Sanei Gen Ffi Inc Fading inhibitor
JP4510412B2 (en) * 2003-08-12 2010-07-21 三栄源エフ・エフ・アイ株式会社 Fading inhibitor
JP2010195925A (en) * 2009-02-25 2010-09-09 T Hasegawa Co Ltd Antioxidant composition
JP2012075340A (en) * 2010-09-30 2012-04-19 Riken Vitamin Co Ltd Anthocyanin pigment discoloration-preventing agent
JPWO2017171091A1 (en) * 2016-04-01 2019-02-14 三栄源エフ・エフ・アイ株式会社 Method for stabilizing solid dyes
JP7128739B2 (en) 2016-04-01 2022-08-31 三栄源エフ・エフ・アイ株式会社 Method for stabilizing solid dyes
CN108142488A (en) * 2018-02-08 2018-06-12 宁波海通食品科技有限公司 A kind of method that white control is returned in ice cream moon cakes cake shell stored frozen phase colour fading
CN113801493A (en) * 2021-10-14 2021-12-17 锦柯草木染(上海)纺织科技有限公司 Method for extracting natural dye from outer skin of pecan

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