JP2015067497A - Method for treating cement kiln extraction gas, and chlorine bypass system - Google Patents
Method for treating cement kiln extraction gas, and chlorine bypass system Download PDFInfo
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- JP2015067497A JP2015067497A JP2013203429A JP2013203429A JP2015067497A JP 2015067497 A JP2015067497 A JP 2015067497A JP 2013203429 A JP2013203429 A JP 2013203429A JP 2013203429 A JP2013203429 A JP 2013203429A JP 2015067497 A JP2015067497 A JP 2015067497A
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- 238000000605 extraction Methods 0.000 title claims abstract description 44
- 239000004568 cement Substances 0.000 title claims abstract description 42
- 239000000460 chlorine Substances 0.000 title claims abstract description 36
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 36
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims description 8
- 239000007789 gas Substances 0.000 claims abstract description 100
- 238000001816 cooling Methods 0.000 claims abstract description 35
- 239000007788 liquid Substances 0.000 claims abstract description 30
- 239000000428 dust Substances 0.000 claims abstract description 15
- 239000000567 combustion gas Substances 0.000 claims abstract description 9
- 239000002826 coolant Substances 0.000 claims abstract description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 13
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 13
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 13
- 239000000920 calcium hydroxide Substances 0.000 claims description 13
- 239000002699 waste material Substances 0.000 claims description 8
- 239000000523 sample Substances 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 239000011593 sulfur Substances 0.000 abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 abstract description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003595 mist Substances 0.000 abstract description 9
- 238000010304 firing Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 239000011575 calcium Substances 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000001804 chlorine Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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Abstract
Description
本発明は、塩素の除去を目的として、セメントキルンの窯尻から最下段サイクロンに至るまでのキルン排ガス流路より抽気した燃焼ガスを処理する方法及び塩素バイパスシステムに関する。 The present invention relates to a method and a chlorine bypass system for treating a combustion gas extracted from a kiln exhaust gas passage from a kiln bottom of a cement kiln to a lowermost cyclone for the purpose of removing chlorine.
近年、廃棄物のセメント原料化及び燃料化が推進されているが、廃棄物の処理量が増加するのに伴い、セメントキルンに持ち込まれる塩素等の揮発成分の量も増加している。そのため、セメント製造設備におけるプレヒータの閉塞等の問題を引き起こす原因になると共に、製品の品質に影響を与える塩素分を除去する塩素バイパスシステムが不可欠となっている。 In recent years, the use of waste as a raw material for cement and fuel has been promoted, but as the amount of waste processed increases, the amount of volatile components such as chlorine brought into the cement kiln also increases. For this reason, a chlorine bypass system that removes the chlorine component that causes problems such as blockage of the preheater in the cement manufacturing facility and affects the quality of the product is indispensable.
この塩素バイパスシステムは、図２に示すように、セメントキルン２２の窯尻から最下段サイクロン（不図示）に至るまでのキルン排ガス流路より燃焼ガスの一部Ｇ２１をプローブ２３で抽気すると同時に、冷却ファン２４からの冷風で抽気ガスＧ２１を急冷し、サイクロン２５で粗粉Ｄ２１を分離した後の抽気ガスＧ２３に含まれる、塩素が濃縮した微粉Ｄ２２をバグフィルタ２８で微粉Ｄ２４として回収する。この微粉Ｄ２４と、冷却器２６から回収された微粉Ｄ２３とを塩素バイパスダストＤ２５として系外に排出し、効率よく塩素を除去する一方、バグフィルタ２８の排ガスＧ２４を排気ファン３０によってセメントキルン２２の排ガス系に戻す（特許文献１、２）。
As shown in FIG. 2, this chlorine bypass system bleeds part G21 of the combustion gas from the kiln exhaust gas flow path from the kiln bottom of the
上述のように、塩素バイパスシステムの排ガス（以下「塩素バイパス排ガス」という。）は、セメントキルンの排ガス系に戻されるが、塩素バイパス排ガスに含まれる硫黄分を除去するため、プレヒータの８００℃以上の高温部に１５０℃程度の塩素バイパス排ガスを戻すとセメント焼成装置での熱損失が増大する。一方、塩素バイパス排ガスをプレヒータの出口側に戻した場合は、排ガス中の硫黄分が増加して環境汚染を引き起こす虞がある。 As described above, the exhaust gas of the chlorine bypass system (hereinafter referred to as “chlorine bypass exhaust gas”) is returned to the cement kiln exhaust gas system, but in order to remove sulfur contained in the chlorine bypass exhaust gas, the preheater has a temperature of 800 ° C. or higher. When the chlorine bypass exhaust gas of about 150 ° C. is returned to the high temperature part, the heat loss in the cement baking apparatus increases. On the other hand, when the chlorine bypass exhaust gas is returned to the outlet side of the preheater, the sulfur content in the exhaust gas may increase and cause environmental pollution.
また、セメントキルン２２に持ち込まれる塩素等の揮発成分の量が増加するのに伴い、抽気プローブや後段の設備が大型化する傾向にあった。そのため、設備の設置場所に制約が生じたり、メンテナンスのための作業量が増加するといった問題点が生じていた。
In addition, as the amount of volatile components such as chlorine brought into the
そこで、本発明は、上記従来の技術における問題点に鑑みてなされたものであって、セメント焼成装置での熱損失の増大を招くことなく塩素バイパス排ガス中の硫黄分を除去すると共に、抽気プローブや後段の設備の大型化を回避することを目的とする。 Therefore, the present invention has been made in view of the above-described problems in the prior art, and removes the sulfur content in the chlorine bypass exhaust gas without causing an increase in heat loss in the cement baking apparatus, and the extraction probe. The purpose is to avoid the enlargement of the equipment in the latter stage.
上記目的を達成するため、本発明は、セメントキルン抽気ガスの処理方法であって、セメントキルンの窯尻から最下段サイクロンに至るまでのキルン排ガス流路より燃焼ガスの一部を抽気し、該抽気ガスの冷却媒体として空気及び液体を用いて該抽気ガスを６００℃以下に冷却し、該冷却後の抽気ガス中のダストを回収して前記セメントキルンの系外へ排出することを特徴とする。 In order to achieve the above object, the present invention is a method for treating a cement kiln extraction gas, wherein a part of the combustion gas is extracted from a kiln exhaust gas passage from the bottom of the cement kiln to the bottom cyclone, The extraction gas is cooled to 600 ° C. or lower using air and liquid as a cooling medium for the extraction gas, and dust in the extracted extraction gas is recovered and discharged out of the cement kiln system. .
本発明によれば、抽気ガスの冷却媒体として空気に加えて液体を用いて抽気ガス中の水分を増加させることで、抽気ガス中のダストに含まれるカルシウム分と水とで生ずる消石灰の量を増加させることができる。これによって、セメント焼成装置での熱損失の増大を招くことなく、塩素バイパス排ガスの脱硫を行うことができる。 According to the present invention, the amount of slaked lime generated by the calcium and water contained in the dust in the extraction gas is increased by increasing the moisture in the extraction gas using a liquid in addition to air as a cooling medium for the extraction gas. Can be increased. Thereby, desulfurization of the chlorine bypass exhaust gas can be performed without increasing the heat loss in the cement baking apparatus.
また、空気のみで冷却する場合に比較して、冷却に用いられる液体の蒸発潜熱の分だけ抽気ガスを冷却した後のガス量が低下するため、抽気プローブや後段の設備の大型化を回避することもできる。 Also, compared to cooling with air alone, the amount of gas after cooling the extracted gas by the amount of latent heat of vaporization of the liquid used for cooling is reduced, so the size of the extraction probe and subsequent equipment is avoided. You can also.
前記抽気ガスを冷却する空気に液体を噴霧し、該冷却空気を前記抽気ガス中に導入することができる。これにより、簡易な装置を用いて冷却媒体としての液体を抽気ガス中に導入することができる。 Liquid can be sprayed onto the air that cools the extraction gas, and the cooling air can be introduced into the extraction gas. Thereby, the liquid as a cooling medium can be introduce | transduced in extraction gas using a simple apparatus.
前記冷却後の抽気ガス中の水分を２％以上３０％以下に調整することができ、塩素バイパス排ガスの脱硫に必要な消石灰を該排ガス中に生じさせることができる。 The moisture in the extracted gas after cooling can be adjusted to 2% or more and 30% or less, and slaked lime necessary for desulfurization of the chlorine bypass exhaust gas can be generated in the exhaust gas.
前記抽気ガス中に噴霧する液体として廃液を用いることができ、廃液を処理しながらセメントキルン抽気ガスを処理することができる。 Waste liquid can be used as the liquid sprayed into the extraction gas, and the cement kiln extraction gas can be processed while processing the waste liquid.
前記冷却後の抽気ガスに消石灰を添加することができ、冷却媒体として用いた液体によって生じた消石灰の量が不足している場合に、これを補うことができる。 Slaked lime can be added to the extracted gas after cooling, and this can be compensated for when the amount of slaked lime generated by the liquid used as the cooling medium is insufficient.
また、本発明は、塩素バイパスシステムであって、セメントキルンの窯尻から最下段サイクロンに至るまでのキルン排ガス流路より燃焼ガスの一部を抽気し、該抽気ガスの冷却媒体として空気及び液体を用いて該抽気ガスを冷却する抽気装置と、該抽気装置で抽気及び冷却したガス中のダストを回収する集塵装置とを備えることを特徴とする。本発明によれば、セメント焼成装置での熱損失の増大を招くことなく、塩素バイパス排ガスの脱硫を行うことができると共に、抽気プローブや後段の設備の大型化を回避することができる。 Further, the present invention is a chlorine bypass system, in which a part of combustion gas is extracted from a kiln exhaust gas passage from a kiln bottom of a cement kiln to a lowermost cyclone, and air and liquid are used as a cooling medium for the extracted gas. And a dust collector for collecting dust in the gas extracted and cooled by the extraction device. According to the present invention, it is possible to desulfurize the chlorine bypass exhaust gas without causing an increase in heat loss in the cement baking apparatus, and it is possible to avoid an increase in the size of the extraction probe and the subsequent equipment.
以上のように、本発明によれば、セメント焼成装置での熱損失の増大を招くことなく塩素バイパス排ガス中の硫黄分を除去すると共に、抽気プローブや後段の設備の大型化を回避することができる。 As described above, according to the present invention, it is possible to remove the sulfur content in the chlorine bypass exhaust gas without causing an increase in heat loss in the cement baking apparatus, and to avoid an increase in the size of the extraction probe and the subsequent equipment. it can.
図１は、本発明に係る塩素バイパスシステムの一実施形態を示し、この塩素バイパスシステム１は、セメントキルン２の窯尻から最下段サイクロンに至るまでのキルン排ガス流路より燃焼ガスの一部Ｇ１を冷却しながら抽気する抽気装置としてのプローブ３と、プローブ３から排出された抽気ガスＧ２から粗粉Ｄ１を分離するための分級機としてのサイクロン６と、サイクロン６から排出された微粉Ｄ２を含む抽気ガスＧ３を冷却する冷却器７と、冷却器７から排出された排ガスＧ４から微粉を回収するバグフィルタ８と、バグフィルタ８の排ガスＧ５を系外に排出する排気ファン９等で構成される。
FIG. 1 shows an embodiment of a chlorine bypass system according to the present invention. This
プローブ３は、セメントキルン２の窯尻からセメントキルン２の排ガス流路の一部として上方へ向かう立上り部に突設され、抽気ガスＧ１を冷却するため１次冷却ファン４と２次冷却ファン５とが付設される。また、１次冷却ファン４からプローブ３に冷却媒体として供給する冷却空気Ａ１がプローブ３に導入される前の配管に、液体・水ミストＭを噴霧するための噴霧装置（不図示）が設けられる。２次冷却ファン５からの冷却空気にも、プローブ３に導入する前に液体・水ミストを噴霧してもよい。 The probe 3 protrudes upward from the kiln bottom of the cement kiln 2 as a part of the exhaust gas flow path of the cement kiln 2 and rises upward, and cools the extracted gas G1 with the primary cooling fan 4 and the secondary cooling fan 5. And are attached. Further, a spraying device (not shown) for spraying the liquid / water mist M is provided in the pipe before the cooling air A1 supplied as a cooling medium from the primary cooling fan 4 to the probe 3 is introduced into the probe 3. . Liquid / water mist may also be sprayed onto the cooling air from the secondary cooling fan 5 before being introduced into the probe 3.
サイクロン６、冷却器７、バグフィルタ８、排気ファン９は、図２に示した従来の塩素バイパスシステム２１のサイクロン２５、冷却器２６、バグフィルタ２８、排気ファン３０と同様の構造を有する。
The cyclone 6, the cooler 7, the bag filter 8, and the exhaust fan 9 have the same structure as the
次に、上記構成を有する塩素バイパスシステム１の動作について、図１を参照しながら説明する。
Next, operation | movement of the
セメントキルン２の窯尻から最下段サイクロンに至るまでのキルン排ガス流路より燃焼ガスの一部Ｇ１をプローブ３で抽気すると同時に、８００〜１１００℃程度の抽気ガスＧ１を１次冷却ファン４からの冷却空気Ａ１及び液体・水ミストＭ、及び２次冷却ファン５からの冷却空気Ａ２でＫＣｌ等の塩素化合物の融点である６００℃以下、好ましくは４００℃以下にまで冷却する。これによって、抽気ガスＧ１中のＫＣｌ等の塩素化合物が析出して抽気ガスＧ２中の微粉の表面等に付着する。 A part of the combustion gas G1 is extracted by the probe 3 from the kiln exhaust gas flow path from the kiln bottom of the cement kiln 2 to the lowest cyclone, and at the same time, the extraction gas G1 of about 800 to 1100 ° C. is extracted from the primary cooling fan 4. The cooling air A1, the liquid / water mist M, and the cooling air A2 from the secondary cooling fan 5 are cooled to 600 ° C. or lower, preferably 400 ° C. or lower, which is the melting point of a chlorine compound such as KCl. As a result, a chlorine compound such as KCl in the extraction gas G1 is deposited and adheres to the surface of the fine powder in the extraction gas G2.
また、液体・水ミストＭの添加により、以下に示すように、抽気ガスＧ１等のダストに含まれるカルシウム分と水とで消石灰が生成され、消石灰と抽気ガスＧ１等に含まれるＳＯ2とが反応して石膏が生成され、抽気ガスＧ１等の脱硫が行われる。 Further, by adding the liquid / water mist M, as shown below, slaked lime is generated by the calcium content and water contained in the dust such as the extracted gas G1, and the SO 2 contained in the slaked lime and the extracted gas G1 and the like. Reacting produces gypsum and desulfurization of the extracted gas G1 and the like is performed.
ＳＯ2＋Ｃａ（ＯＨ）2→ＣａＳＯ3・１／２Ｈ2Ｏ＋１／２Ｈ2Ｏ
ＣａＳＯ3・１／２Ｈ2Ｏ＋１／２Ｏ2＋３／２Ｈ2Ｏ→ＣａＳＯ4・２Ｈ2Ｏ
次に、抽気ガスＧ２をサイクロン６に導入し、粗粉Ｄ１と、微粉Ｄ２を含む抽気ガスＧ３とに分離し、粗粉Ｄ１をセメントキルン２系に戻すと共に、上記反応式で示した反応の効率を考慮し、抽気ガスＧ３を冷却器７で１００〜２００℃、好ましくは１４０〜１７０℃、また抽気ガスＧ３の水分が２〜３０％、好ましくは１０〜１５％となるように冷却する。
SO 2 + Ca (OH) 2 → CaSO 3 .1 / 2H 2 O + 1 / 2H 2 O
CaSO 3 · 1 / 2H 2 O + 1 / 2O 2 + 3 / 2H 2 O → CaSO 4 · 2H 2 O
Next, the extraction gas G2 is introduced into the cyclone 6 and separated into the coarse powder D1 and the extraction gas G3 containing the fine powder D2. The coarse powder D1 is returned to the cement kiln 2 system, and the reaction shown in the above reaction formula is performed. In consideration of efficiency, the extraction gas G3 is cooled by the cooler 7 so that the moisture of the extraction gas G3 is 2 to 30%, preferably 10 to 15%.
上記サイクロン６で分離された粗粉Ｄ１には、上記反応式によって生じた硫黄分も含まれているが、この硫黄分は粗粉Ｄ１と共にセメントキルン２に戻され、プレーヒータ等で脱硫されたり、セメントキルン２とサイクロン６との間を循環する。 The coarse powder D1 separated by the cyclone 6 also contains the sulfur content generated by the above reaction formula. This sulfur content is returned to the cement kiln 2 together with the coarse powder D1 and desulfurized by a preheater or the like. Circulate between the cement kiln 2 and the cyclone 6.
次に、冷却器７の排ガスＧ４をバグフィルタ８に導入して微粉Ｄ４を回収し、冷却器７から回収した微粉Ｄ３と共に塩素バイパスダストＤ５とする。バグフィルタ８の排ガスＧ５は、排気ファン９によって排ガスＧ６としてセメントキルン２の排ガス系に戻す。 Next, the exhaust gas G4 of the cooler 7 is introduced into the bag filter 8 to collect the fine powder D4, and together with the fine powder D3 collected from the cooler 7, the chlorine bypass dust D5 is obtained. The exhaust gas G5 of the bag filter 8 is returned to the exhaust gas system of the cement kiln 2 as exhaust gas G6 by the exhaust fan 9.
上記塩素バイパスダストＤ５には、析出した塩素化合物に加え、硫黄分（ＣａＳＯ4・２Ｈ2Ｏ）が濃縮しているため、塩素バイパスダストＤ５をセメント粉砕工程でセメントクリンカと共に粉砕することで硫黄分を系外に除去することができる。また、塩素バイパスダストＤ５を水洗して塩素を除去した後、セメント原料等として利用した場合には、硫黄分を系外に除去することはできないが、排気ファン９の排ガスＧ６をプレヒータの高温部に戻す必要がなく、セメント焼成装置での熱損失の増大を回避することができる。 In the chlorine bypass dust D5, the sulfur content (CaSO 4 · 2H 2 O) is concentrated in addition to the precipitated chlorine compound. Can be removed out of the system. Further, when chlorine bypass dust D5 is washed with water to remove chlorine and then used as a cement raw material or the like, the sulfur content cannot be removed out of the system, but the exhaust gas G6 of the exhaust fan 9 is removed from the high temperature portion of the preheater. Therefore, it is possible to avoid an increase in heat loss in the cement baking apparatus.
また、１次冷却ファン４からの冷却空気Ａ１に液体・水ミストＭを添加して抽気ガスＧ１を冷却しているため、従来のように空気のみで冷却する場合に比較して、冷却に用いられる水の蒸発潜熱の分だけ抽気ガスＧ１を冷却した後のガス量が低下するため、抽気プローブ３や後段のサイクロン６等の設備の大型化を回避することもできる。 Further, since the extraction gas G1 is cooled by adding the liquid / water mist M to the cooling air A1 from the primary cooling fan 4, it is used for cooling as compared with the case where cooling is performed only with air as in the prior art. Since the amount of gas after cooling the extraction gas G1 is reduced by the amount of latent heat of vaporization of the generated water, it is possible to avoid an increase in the size of the extraction probe 3, the subsequent cyclone 6 and the like.
上記液体・水ミストＭの添加により生じる消石灰に加え、排気ファン９の排ガスＧ６に補助的に消石灰粉末を噴霧してもよい。上記反応式で示した脱硫反応は、ガス中の相対湿度が高い方が効率よく行われるため、ガスの低温側に消石灰を添加することが効率的である。そこで、１５０℃程度の排ガスＧ６に消石灰粉末を噴霧し、上記反応により硫黄分が濃縮したダストを集塵して系外に除去することができる。また、上述のように排ガスＧ６をセメントキルン２の排気系に戻してもよい。尚、既に高温側で液体・水ミストＭを添加して排ガスＧ６の相対湿度を高めているため、効率よく脱硫を行うことができる。 In addition to the slaked lime generated by the addition of the liquid / water mist M, the slaked lime powder may be sprayed auxiliary to the exhaust gas G6 of the exhaust fan 9. Since the desulfurization reaction shown in the above reaction formula is performed efficiently when the relative humidity in the gas is high, it is efficient to add slaked lime to the low temperature side of the gas. Therefore, slaked lime powder can be sprayed on the exhaust gas G6 at about 150 ° C., and the dust enriched in sulfur by the above reaction can be collected and removed out of the system. Further, the exhaust gas G6 may be returned to the exhaust system of the cement kiln 2 as described above. In addition, since the relative humidity of the exhaust gas G6 is already increased by adding the liquid / water mist M on the high temperature side, desulfurization can be performed efficiently.
尚、上述の理由により、また、塩素バイパスダストＤ５の回収量の増加を伴わないため、排気ファン９の排ガスＧ６に消石灰粉末を噴霧することが好ましいが、さらに上流側の排ガスＧ２、Ｇ３には消石灰スラリーを噴霧してもよい。 In addition, for the above-mentioned reasons, and because there is no increase in the recovery amount of the chlorine bypass dust D5, it is preferable to spray slaked lime powder on the exhaust gas G6 of the exhaust fan 9, but further upstream exhaust gases G2 and G3 Slaked lime slurry may be sprayed.
また、１次冷却ファン４からの冷却空気Ａ１に噴霧する液体・水ミストＭには、工業用水の他、石油精製における脱硫、植物油の生成によって排出される工場廃液や、有機物含有廃液、含油廃液等を用いてもよい。 The liquid / water mist M sprayed on the cooling air A1 from the primary cooling fan 4 includes industrial water, factory waste liquid discharged by petroleum refining, production of vegetable oil, organic substance-containing waste liquid, and oil-containing waste liquid. Etc. may be used.
１ 塩素バイパスシステム
２ セメントキルン
３ プローブ
４ １次冷却ファン
５ ２次冷却ファン
６ サイクロン
７ 冷却器
８ バグフィルタ
９ 排気ファン
1 Chlorine bypass system 2 Cement kiln 3 Probe 4 Primary cooling fan 5 Secondary cooling fan 6 Cyclone 7 Cooler 8 Bag filter 9 Exhaust fan
Claims (6)
該抽気装置で抽気及び冷却したガス中のダストを回収する集塵装置とを備えることを特徴とする塩素バイパスシステム。 A bleeder for extracting a part of the combustion gas from the kiln exhaust gas flow path from the bottom of the kiln of the cement kiln to the lowermost cyclone, and cooling the bleed gas using air and liquid as a cooling medium for the bleed gas;
A chlorine bypass system comprising: a dust collecting device that collects dust in gas extracted and cooled by the extraction device.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017031033A (en) * | 2015-08-06 | 2017-02-09 | 太平洋セメント株式会社 | Chlorine bypass exhaust gas treatment method and chlorine bypass system |
| JP2017119587A (en) * | 2015-12-28 | 2017-07-06 | 宇部興産株式会社 | Extraction device and extraction method |
| JP2020023439A (en) * | 2015-12-28 | 2020-02-13 | 宇部興産株式会社 | Extraction device and extraction method |
| JP2020023416A (en) * | 2018-08-08 | 2020-02-13 | 宇部興産株式会社 | Manufacturing method of cement composition, and manufacturing system of cement composition |
| JP2020176057A (en) * | 2018-08-08 | 2020-10-29 | 宇部興産株式会社 | Manufacturing method of cement composition, and manufacturing system of cement composition |
| JPWO2021019754A1 (en) * | 2019-08-01 | 2021-02-04 | ||
| JP2021127287A (en) * | 2019-10-24 | 2021-09-02 | 宇部興産株式会社 | Extraction device and extraction method |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS499471A (en) * | 1972-05-24 | 1974-01-28 | ||
| JPS5851924A (en) * | 1981-09-24 | 1983-03-26 | Sumitomo Cement Co Ltd | Method for desulfurizing and cooling exhaust gas |
| JPS61287419A (en) * | 1985-04-24 | 1986-12-17 | オサケ イフテイオ タンペラ ア−ベ− | Removal of gaseous sulfur compound from flue gas of furnace |
| JPH09175847A (en) * | 1995-10-24 | 1997-07-08 | Ube Ind Ltd | Method for treating bled exhaust gas of cement kiln and its treating device |
| US5704780A (en) * | 1994-10-15 | 1998-01-06 | Deutz Ag | Apparatus for thermal processing of raw materials in dust form |
| US5951279A (en) * | 1997-04-30 | 1999-09-14 | Khd Humboldt Wedag Ag | Method and apparatus for reducing pollutant circulations in the manufacture of cement clinker from raw meal |
| JP2007031188A (en) * | 2005-07-25 | 2007-02-08 | Sumitomo Osaka Cement Co Ltd | Method and apparatus for treating waste gas in cement firing equipment |
| JP2012140313A (en) * | 2011-01-06 | 2012-07-26 | Taiheiyo Cement Corp | Chlorine bypass system, and method for treatment of chlorine bypass extracted gas |
| JP2013180941A (en) * | 2012-03-05 | 2013-09-12 | Taiheiyo Cement Corp | Apparatus and method for treating chlorine bypass exhaust gas |
| JP2013202476A (en) * | 2012-03-28 | 2013-10-07 | Taiheiyo Cement Corp | Apparatus and method for treating cement kiln combustion exhaust gas |
| JP2014014730A (en) * | 2012-07-05 | 2014-01-30 | Ube Ind Ltd | Cooling device for high temperature exhaust gas |
| JP2014108907A (en) * | 2012-12-03 | 2014-06-12 | Taiheiyo Cement Corp | Treatment device for cement kiln combustion exhaust gas and treatment method therefor |
-
2013
- 2013-09-30 JP JP2013203429A patent/JP6153258B2/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS499471A (en) * | 1972-05-24 | 1974-01-28 | ||
| JPS5851924A (en) * | 1981-09-24 | 1983-03-26 | Sumitomo Cement Co Ltd | Method for desulfurizing and cooling exhaust gas |
| JPS61287419A (en) * | 1985-04-24 | 1986-12-17 | オサケ イフテイオ タンペラ ア−ベ− | Removal of gaseous sulfur compound from flue gas of furnace |
| US5704780A (en) * | 1994-10-15 | 1998-01-06 | Deutz Ag | Apparatus for thermal processing of raw materials in dust form |
| JPH09175847A (en) * | 1995-10-24 | 1997-07-08 | Ube Ind Ltd | Method for treating bled exhaust gas of cement kiln and its treating device |
| US5951279A (en) * | 1997-04-30 | 1999-09-14 | Khd Humboldt Wedag Ag | Method and apparatus for reducing pollutant circulations in the manufacture of cement clinker from raw meal |
| JP2007031188A (en) * | 2005-07-25 | 2007-02-08 | Sumitomo Osaka Cement Co Ltd | Method and apparatus for treating waste gas in cement firing equipment |
| JP2012140313A (en) * | 2011-01-06 | 2012-07-26 | Taiheiyo Cement Corp | Chlorine bypass system, and method for treatment of chlorine bypass extracted gas |
| JP2013180941A (en) * | 2012-03-05 | 2013-09-12 | Taiheiyo Cement Corp | Apparatus and method for treating chlorine bypass exhaust gas |
| JP2013202476A (en) * | 2012-03-28 | 2013-10-07 | Taiheiyo Cement Corp | Apparatus and method for treating cement kiln combustion exhaust gas |
| JP2014014730A (en) * | 2012-07-05 | 2014-01-30 | Ube Ind Ltd | Cooling device for high temperature exhaust gas |
| JP2014108907A (en) * | 2012-12-03 | 2014-06-12 | Taiheiyo Cement Corp | Treatment device for cement kiln combustion exhaust gas and treatment method therefor |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017031033A (en) * | 2015-08-06 | 2017-02-09 | 太平洋セメント株式会社 | Chlorine bypass exhaust gas treatment method and chlorine bypass system |
| JP2017119587A (en) * | 2015-12-28 | 2017-07-06 | 宇部興産株式会社 | Extraction device and extraction method |
| JP2020023439A (en) * | 2015-12-28 | 2020-02-13 | 宇部興産株式会社 | Extraction device and extraction method |
| JP2020023416A (en) * | 2018-08-08 | 2020-02-13 | 宇部興産株式会社 | Manufacturing method of cement composition, and manufacturing system of cement composition |
| JP2020176057A (en) * | 2018-08-08 | 2020-10-29 | 宇部興産株式会社 | Manufacturing method of cement composition, and manufacturing system of cement composition |
| JPWO2021019754A1 (en) * | 2019-08-01 | 2021-02-04 | ||
| WO2021019754A1 (en) * | 2019-08-01 | 2021-02-04 | 太平洋エンジニアリング株式会社 | Method and apparatus for producing desulfurizing agent, and method for removing sulfur dioxide from cement kiln exhaust gas |
| JP7326448B2 (en) | 2019-08-01 | 2023-08-15 | 太平洋エンジニアリング株式会社 | Method for producing desulfurizing agent and method for desulfurizing exhaust gas from cement kiln |
| JP2021127287A (en) * | 2019-10-24 | 2021-09-02 | 宇部興産株式会社 | Extraction device and extraction method |
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