JP2015064273A - Gas sensor - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a gas sensor having excellent airtightness.SOLUTION: Provided is a gas sensor GS1 comprising a gas sensor element 1, a housing 2, and sealing means including a powder filled part 30 composed mainly of talc and a cylindrical insulator 31 for pressing the powder filled part 30, the sealing means sealing between an outer circumference 10 of the gas sensor element 1 and an inner circumference 20 of the housing 2, wherein, pertaining to the relationship between a screened particle diameter Dof filled powder particles constituting the powder filled part 30, an element-side gap GP1 between an inner circumference 310 of the cylindrical insulator 31 and the outer circumference 10 of the gas sensor element 1, and a housing-side gap GP2 between an outer circumference 311 of the cylindrical insulator 31 and the inner circumference 20 of the housing 2, the element-side gap GP1 and the housing-side gap GP2 are set to twice the screened particle diameter Dof the filled powder particles or less.

Description

  The present invention relates to a gas sensor that detects the concentration of a specific gas component in a gas to be measured, and particularly contributes to an improvement in airtightness between a gas sensor element and a housing.

  Conventionally, a gas sensor for detecting the concentration of a specific gas component such as oxygen contained in combustion exhaust gas has been provided in a combustion exhaust passage of an internal combustion engine such as an automobile engine, and the air-fuel ratio is determined by the detected concentration of the specific gas component. Control and temperature control of exhaust treatment catalyst are performed.

As such a gas sensor, an oxygen concentration detection element is provided in which a measurement electrode layer in contact with a gas to be measured and a reference electrode layer in contact with the atmosphere introduced as a reference gas are provided on the surface of an oxygen ion conductive solid electrolyte such as zirconia. An oxygen sensor that detects the potential difference between the two electrodes based on the difference between the oxygen concentration in the gas to be measured and the oxygen concentration in the reference gas to measure the oxygen concentration in the gas to be measured, An air-fuel ratio sensor that detects the air-fuel ratio of the air-fuel mixture introduced into the internal combustion engine from the concentration of the gas component, an ammonia sensor that detects the ammonia concentration in the gas to be measured using a hydrogen ion conductive solid electrolyte body, etc. are widely used It has been.
Further, in such a gas sensor, it is necessary to ensure airtightness with a housing holding the gas sensor element in order to prevent a decrease in detection accuracy due to leakage of the gas to be measured.

  Patent Document 1 discloses a detection structure including a detection element for detecting a component to be detected in a gas to be measured, which has a rod-like or cylindrical shape in which a detection portion is formed at a tip portion, and the detection structure. A metal shell mainly disposed on the outside of the body, and a talc main body, and a seal filler layer that fills and seals the gap between the inner surface of the metal shell and the outer surface of the detection structure, A gas sensor is disclosed in which the seal filler layer contains water glass in the range of 2 to 7% by weight.

JP 2000-314715 A

However, as in Patent Document 1, when water glass is added to the seal filling layer to improve the airtightness, water glass is added to the powder filler or the molded body of the filling powder is heated. The man-hour for adjusting the moisture increases, which may increase the manufacturing cost.
In addition, since the sealing property of water glass changes depending on the moisture content, in the gas sensor used in a high temperature environment, the moisture content of the filling portion varies depending on the use situation, and it is impossible to expect stable airtightness. There is also a fear.

On the other hand, gas sensors that detect specific gas components in the combustion exhaust gas of internal combustion engines used for air-fuel ratio control of automobiles and motorcycles are used in harsh environments that are subject to large external vibrations and exposed to a cold cycle. The
For this reason, when fine talc particles having a sieving particle size D _{SV of 2} to 30 μm are used in the powder filling portion, there is a possibility that airtightness may be reduced due to the degranulation from the powder filling portion, and this is prevented. For. It was necessary to provide a seal packing made of metal or vermiculite, mica, mica molding, etc. between the cylindrical insulator and the powder filling part, resulting in an increase in manufacturing man-hours and material costs. .

  Therefore, in view of such circumstances, the present invention is less likely to occur from the powder filling portion even if the seal packing for preventing the filling powder leakage is abolished, and the airtightness of the powder filling portion is reduced while reducing the manufacturing cost. An object of the present invention is to provide a highly reliable gas sensor that is unlikely to deteriorate.

The present invention is a gas sensor for detecting a specific component in a gas to be measured, the gas sensor element (1), a cylindrical housing (2) for housing and fixing the gas sensor element (1), and the gas sensor element (1). ) Between the outer peripheral surface (10) and the inner peripheral surface (20) of the housing (2), and the powder filling portion (30) containing talc as a main component and the powder filling portion (30) are pressed. In a gas sensor (GS1, GS2, GS3) formed by sealing means (3) including a cylindrical insulator (31) and sealed, filled powder particles (300) constituting the powder filling portion (30) and sieving particle diameter _{D SV} of an element side gap GP1 between the outer peripheral surface (10) of the inner peripheral surface of the cylindrical insulator (31) (310) and the gas sensor element (1), the tubular insulator The outer peripheral surface (311) of (31) and the inner peripheral surface of the housing (2) (20) and the housing-side gap GP2 are characterized in that the element-side gap GP1 and the housing-side GP2 are not more than twice the sieving particle size D _SV of the filling powder (300). And

The sieving particle diameter D _SV and the element-side gap GP1, and by optimizing the relationship between the housing side gap GP2, between the powder filling portion (30) and the tubular insulator (31) Even if it is not provided with a seal packing, even if it is exposed to a cooling cycle and external vibration, the powder filling portion (30) does not fall out of the powder filling portion (30), and the powder filling portion ( The internal pressure of 30) is maintained in a constant state, and airtightness is not lowered.
Moreover, since it is not necessary to provide a metal seal for preventing the pulverization of the filled powder particles (300), it is possible to reduce the number of parts and the number of assembling steps.

The principal part sectional drawing which shows the outline | summary of the sealing structure of the gas sensor which concerns on this invention. The flowchart which shows the sealing method of the gas sensor concerning this invention later on in order of a process Schematic diagram showing the crystal structure of the characteristic properties of talc used in the present invention Schematic showing changes when pressure acts on large particle size filled powder The main part enlarged view which shows the state which has arrange | positioned the powder filler primary molded object 30MLD in order to demonstrate the effect of this invention Continuing to FIG. 4A, a main part enlarged view showing a state in which the powder filler primary molded body 30MLD is compressed to form the powder filler 30 As Comparative Example 1, an enlarged view of the main part showing the problems when 2-30 μm filled powder is used As Comparative Example 2, the main part enlarged view showing the case where the seal 34 is added to FIG. 5A. Characteristics chart showing effects of the present invention Sectional drawing which shows the whole outline | summary of gas sensor GS1 in the 1st Embodiment of this invention. Sectional drawing which shows the whole outline | summary of gas sensor GS2 in the 2nd Embodiment of this invention. Sectional drawing which shows the principal part of gas sensor GS3 in the 3rd Embodiment of this invention.

The present invention is a gas sensor that detects a specific component in a gas to be measured, and includes a gas sensor element 1, a cylindrical housing 2 that houses and fixes the gas sensor element 1, an outer peripheral surface 10 of the gas sensor element 1, and a housing 2. The present invention relates to a gas sensor that is sealed by a sealing means 3 including a powder filling portion 30 mainly composed of talc and a cylindrical insulator 31 that presses the powder filling portion 30 between the inner peripheral surface 20 and the inner peripheral surface 20. is there.
The gas sensor of the present invention is not particularly limited in application, and can be applied to any of early activation gas sensor GS1, simple gas sensor GS2, and stacked gas sensor GS3, which will be described later.

  With reference to FIG. 1, the structure and structure of the powder filling part 30 which is the principal part of this invention are demonstrated. The configuration shown in FIG. 1 is common to all the embodiments described later. In the following description, in order to facilitate understanding of the present invention, as the gas sensor element 1, a so-called cup-type gas sensor in which a pair of electrodes are formed on the inner side and the outer side of a solid electrolyte body formed in a low and low cylinder shape. Will be described as an example.

A part of the outer periphery of the sensor element 1 is formed with an enlarged diameter portion 11 protruding so as to increase in diameter toward the outside.
A cylindrical powder filling portion 30 is formed on the proximal end side of the enlarged diameter portion 11 so as to cover the outer peripheral surface 10 of the gas sensor element 1.
The distal end side of the enlarged diameter portion 11 is in contact with a locking portion 21 whose diameter is reduced so that a part of the inner peripheral surface of the housing 2 is reduced in diameter via a metal seal ring 33.

The powder filling unit 30 is pressed by a cylindrical insulator 31 formed in a cylindrical shape.
A known ceramic material such as alumina is used for the cylindrical insulator 31.
In the powder filling unit 30, talc powder having a sieving particle size D _SV of 210 μm or more and 710 μm or less is used as the filling powder particles 300.
Sieve particle size D _{SV of} filled powder particles 300 constituting powder filling unit 30, element side gap GP1 between inner peripheral surface 310 of cylindrical insulator 31 and outer peripheral surface 10 of gas sensor element 1, and cylindrical insulator In the relationship between the outer peripheral surface 311 of the housing 31 and the housing-side gap GP2 between the inner peripheral surface 20 of the housing 2, the element-side gap GP1 and the housing-side gap GP2 both have a sieving particle size D _{SV of the} filling powder 300. It is formed to be 2 times or less.
The element side gap GP1 and the housing side gap GP2 are set to 0.1 mm or more.

Furthermore, the element side gap GP1 and the housing side welcome GP2 are both formed to be 0.1 mm or more, and the assembly of the gas sensor element 1 and the powder filling unit 30 into the housing 2 is facilitated.
The powder filling unit 30 is formed by a manufacturing method described later, and the filling powder particle 300 is uniaxially pressed to form a filling powder molded body 30MLD formed into a cylindrical shape, and is further partitioned between the gas sensor element 1 and the housing 2. The powder filling portion 30 is formed by pressing through the cylindrical insulator 31 in the space to increase the airtightness.

The housing 2 is provided with a wrap crimping portion 22 that elastically presses the cylindrical insulator 31 in the axial direction, and can transmit the axial force of the housing 2 to the cylindrical insulator 31 efficiently. A shrunk portion 23 formed by heat caulking is provided on the front end side of the enveloping caulking portion 22.
The shrump portion 23 is buckled in the axial direction by heat caulking, and applies an axial force in a direction in which the cylindrical insulator 31 is pressed against the powder filling portion 30 via the encapsulating caulking portion 22.
The axial force that presses the powder filling portion 30 forms a repulsive force that acts in all directions within the powder filling portion 30, and the outer peripheral surface 10 of the gas sensor element 1, the proximal end surface of the enlarged diameter portion 11, and the housing 2. The inner peripheral surface 20, the bottom surface of the cylindrical insulator 31, and the powder filling portion 30 are in close contact with each other.

In the powder filling part 30 of the present invention, the flaky talc particles 300 having a large particle size are oriented in layers, and the airtightness is maintained.
Further, a metal seal ring 32 may be interposed between the cylindrical insulator 31 and the wrapping and crimping portion 22.
Furthermore, the distal end side of the enlarged diameter portion 33 provided in the gas sensor element 1 is engaged with an element engagement portion 21 whose diameter is reduced at a part of the inner periphery of the housing 2 via a metal seal ring 33.
For the housing 2, a known metal material such as carbon steel, stainless steel, iron, nickel, or an alloy thereof is selected and used according to the use environment.

With reference to FIG. 2, the manufacturing method of the powder filling part 30 which is the principal part of the gas sensor of this invention is demonstrated.
In the powder pretreatment process P1, talc powder used as a filling powder material is pretreated. Specifically, it is adjusted to a predetermined particle size range (210 μm or more and 710 μm or less) by sieving, and flammable impurities are removed by heat treatment.
For example, starting from talc powder having a fine particle size of 100 μm or less, an organic binder such as methylcellulose or an inorganic binder such as primary aluminum phosphate is added, and a predetermined particle size range (210 μm or more, 710 μm or less) A granulated product may be used.

In the powder molding step P2, a predetermined amount of talc powder is filled in a mold, and a predetermined molding load (for example, 235 N / mm ² or less) is applied to form a cylindrical filled powder molded body 30MLD.
At this time, if the molding pressure is increased, the molding density can be increased, but there is a risk of cracking when taking out from the mold due to the orientation and cleavage of the talc particles.
Further, since it is compressed again after being mounted in the housing 2, it is not necessary to increase the molding load in particular, and it is only necessary to maintain a certain shape so that a predetermined amount of talc can be accurately assembled in the housing 2.
By making the talc molding load smaller than the load when the talc molded body 30MLD is assembled and compressed to form the powder filling portion 30, the packing density of the powder filling portion 30 can be finally increased.

Next, in the powder compact assembly / compression process P3, the seal ring 33, the gas sensor element 1, and the powder compact 30MLD are sequentially mounted in the housing 2 and powdered using the cylindrical insulator 31 or the pressing jig. The compact 30MLD is compressed to form the powder filling part 30.
At this time, since large talc particles having a sieving particle size D _SV of 210 μm or more are used as the packed powder particles 300, rearrangement of the flaky particles occurs due to slipping and cleaving of the lump particles, resulting in an increase in orientation. By reducing the voids, the porosity of the powder filling portion 30 can be reduced and stabilized.

Furthermore, in this process. (Specifically, for example, 235N / mm ² or more 705N / mm ² or less) load of a predetermined range by load, while achieving a reduction in sufficient porosity, achieve prevention of cracking of the gas sensor element 30 be able to.

Next, in the insulator / seal ring assembly step P4, the cylindrical insulator 31 and the seal ring 32 are assembled.
As a matter of course, when the powder compact 30MLD is compressed through the cylindrical insulator 31, only the seal ring 32 is assembled.
Further, the seal ring 32 is not essential, and the seal ring 32 can be omitted, and in the next step, the wrapping and crimping portion 22 can be directly brought into contact with the upper surface of the cylindrical insulator 31.

Next, in the cooling step P5, the pressure in the axial direction is applied by the caulking dies M1 and M2 to perform cold caulking, and the wrapping and crimping portion 22 of the housing 2 is tilted toward the cylindrical insulator 31 so that the shaft The shape is such that the force can be efficiently transmitted to the cylindrical insulator 31.
Next, in the heat caulking step P6, the shrump part 23 is buckled and formed by applying an alternating current to the housing 2 while applying a load to the wrapping and crimping part 22.
By forming the shrump portion 23, it is possible to prevent the axial force from being lost even if it is exposed to a cooling cycle.
In the heat caulking step P6, not only the shrump part 23 is locally heated, but also the entire housing 2 is heated to provide a temperature difference between the housing 2 and the powder filling part 30, thereby increasing the axial force and airtightness. It is also possible to further suppress the decrease in sex.

Here, with reference to FIG. 3A and FIG. 3B, the talc used as a powder filler in this invention is demonstrated.
Talc is a natural mineral composed of magnesium hydroxide and silicate having a composition of (Mg ₃ Si ₄ O ₁₀ (OH) ₂ ) and contains magnesite, dolomite, etc. as impurities, as shown in FIG. 3A. It has a monoclinic / triclinic crystal structure and exhibits complete cleavage only in certain directions.
As shown in FIG. 3B, the large-diameter talc particles 300 used in the present invention are aggregated particles formed by aggregating flaky particles in a plurality of layers, and when a load in a certain direction is applied, Sliding and cleaving of the particles occur, and the flaky particles are oriented in a certain direction.

The effects of the present invention will be described with reference to FIGS. 4A and 4B.
As shown in FIG. 4A, the filler powder compact 30 is formed with some pores remaining as described above, and the direction of the filler powder particles (talc particles) 300 is not aligned.
When this is pressed in the housing 2 via the cylindrical insulator 31 as shown in FIG. 4B, the talc particles 300 are rearranged while sliding, increasing the orientation and reducing the gaps between the particles.
At this time, the talc particles 300 in contact with the inner peripheral surface 20 of the housing 2 tend to be oriented in the axial direction due to friction with the inner peripheral surface, and in the central portion of the powder filling portion 30, parallel to a plane perpendicular to the axis. The tendency to orient in the direction becomes stronger.

In addition, since a predetermined housing side gap GP2 exists between the outer peripheral surface of the cylindrical insulator 31 and the inner peripheral surface 20 of the housing 2, the talc particles 300 at a position exposed to the housing side gap GP2 The axial pressing force from the cylindrical insulator 31 does not act directly, but is indirectly pressed through the talc particles 300 in contact with the bottom surface of the cylindrical insulator 31.
As a result, the talc particles 300 in contact with the cylindrical insulator 31 are covered with the adjacent talc particles 300, or a plurality of talc particles 300 are arranged in the housing-side gap GP2, as indicated by a portion A surrounded by a dotted line in FIG. 4B. At this time, since it bites into the inner peripheral surface 20 of the housing 2, the talc particles 300 play a role as a lid at the position exposed to the housing side gap GP2 to prevent the particles from falling into the housing side gap GP2. It is assumed that there is.

In particular, in the present invention, talc particles having a large particle size with a sieved particle size D _SV of 210 to 710 μm are used as the packed powder particles 300, and the housing side gap GP2 has a sieved particle size D _SV of Since it is set to be twice or less, a part of the talc particles 300 that are directly pressed against the bottom surface of the cylindrical insulator 31 is in contact with the talc particles 300 exposed in the housing-side gap GP2, Axial force is transmitted.
Note that, on the element side GP1 as well, the filled powder particles 300 do not fall out of the powder filling portion 30 and the airtightness can be stably maintained based on the same principle.
In addition, it is possible that the filled powder particles 300 (talc particles) constituting the powder filling portion 30 are completely oriented by forming the filled powder compact 30MLD in advance and storing it in the housing 2 and then compressing it again. Since the orientation direction varies moderately, the difference in thermal expansion coefficient between the axial direction and the orthogonal direction of the gas sensor GS1 does not become extremely large.

Here, with reference to FIG. 5A and FIG. 5B, in the same configuration as the gas sensor GS1 of the present invention, a problem when a fine talc powder having a sieving particle size D _{SV of 2} to 30 μm is used as the filling powder 300z. The point will be described.
As Comparative Example 1, when a talc powder having an average particle size of about 10 μm and a sieving particle size D _{SV in} the range of 2 to 30 μm is used as the packed powder particles 300z as in the gas sensor GSz shown in FIG. 5A. Accordingly, the specific surface area increases, the internal pressure of the powder filling portion 30z is dispersed, and the force for pressing each particle becomes relatively small.

Further, in the portion B covered by the dotted line in FIG. 5A, even if the pressing force from the cylindrical insulator 31 is not transmitted at all or is transmitted through a plurality of adjacent talc particles 300z, each talc particle 300z is The pressing force is reduced.
When the axial force transmitted to the powder filling portion 30z via the cylindrical insulator 31z is weakened due to the thermal expansion of the housing 2, if the external vibration is applied, the filling powder particles 300z are likely to fall apart.
There is a possibility that the filled powder particles 300z may be separated from the powder filling portion 30z and leak out of the housing side gap GP2 between the inner diameter of the sealing member housing portion 20 and the outer diameter of the cylindrical insulator 31.

Once the pulverization of the filled powder particles 300z occurs, the internal pressure of the powder filling portion 30z decreases, causing further pulverization of the filled powder particles 300z, and the airtightness of the powder filling portion 30z decreases.
For this reason, as in the gas sensor GSy shown in FIG. 5B, in order to suppress the shedding of the filled powder particles 300z, a metal or vermiculite, mica, between the cylindrical insulator 31 and the upper surface of the powder filling portion 30z, It is necessary to provide a seal packing 34 made of a mica molded product or the like, resulting in an increase in manufacturing steps and material costs.

With reference to FIG. 6, the test result performed about the relationship between the sieving particle diameter DSV _{, the} pressing load (kN), and the porosity (%) of the packed particles 300 will be described.
As shown in this figure, when talc particles having different particle sizes were used and the load for pressing the cylindrical insulator 31 was changed and the porosity was measured, 10 kN (to 235 N / mm ² at any particle size). in equivalent) or more, the porosity is stabilized at 30 kN (equivalent to 705N / ^{mm 2)} or more, can lead to cracking of the gas sensor element 1, sieving particle diameter _{D SV} most the porosity when 210~710μm It turned out that it can be lowered.

It should be noted that the porosity can be lowered even when the sieved particle size D _SV is 210 to 1000 μm, but since there is almost no change from the state of the molded body, after assembling the filled powder molded body 30MLD in the housing 2, Even if pressed through the cylindrical insulator 31, the filled powder particles 300 do not bite into the element side gap GP <b> 1 and the housing side gap GP <b> 2.
In addition, if the orientation of the filled powder particles 300 is too strong, the difference in thermal expansion coefficient between the axial direction and the meter direction of the gas sensor increases, and the axial force from the housing 2 may be weakened.
Therefore, it has been found that the sieving particle size D _SV is desirably in the range of 210 to 710 μm, which causes moderate variation in orientation.

Here, the effects of the present invention will be described with reference to Table 1.
The inventors changed the talc particle size DSV and the talc pressing part gap (element side gap GP1, housing side gap GP2), created a plurality of gas sensors, and conducted a durability test corresponding to 240,000 km running, The high temperature airtightness after the durability test was investigated, and the results are shown in Table 1.
As an endurance condition, the housing 2 was heated to 400 ° C. and then immersed in water to apply a thermal stress, and this was repeated 400 times.
Moreover, the evaluation of the high temperature airtightness is that when air is injected from the front end side of the housing 2 under a high temperature environment of 550 ° C. (air pressure 0.4 MPa) and the flow rate is 10 cc / min or less, the airtightness is good. Judgment was made and a round mark was given. When it exceeded 10 cc / min, it was judged that the airtightness was poor, and an x mark was given.
As a result, when the talc pressing portion gap (element-side gap GP1, housing-side gap GP2) is narrower than 0.1 mm, it is difficult to assemble the cylindrical insulator 31 to the housing 2; When the talc presser gap (element-side gap GP1, housing-side gap GP2) exceeds twice the talc sieve particle size D _SV , high-temperature airtightness is deteriorated, and talc sieve It was found that good high temperature airtightness can be maintained when the particle size is less than twice the _SV .

With reference to FIG. 7A, the gas sensor GS1 in the first embodiment of the present invention will be described.
The gas sensor GS1 is a so-called cup-type gas sensor, and is an early activation type gas sensor in which a heater 18 is incorporated to achieve early activation.
In the present embodiment, an oxygen sensor that is a typical example of a cup-type sensor will be described as an example. However, in the present invention, the detection target is not limited, and an oxygen sensor, an A / F sensor, a NOx sensor, ammonia The present invention can be applied to any of sensors, hydrogen sensors, and the like.
The gas sensor GS <b> 1 is provided in the measured gas flow path 6, and the detection unit 12 provided at the tip is exposed to the measured gas G.

The gas sensor element 1 is provided with a reference electrode 121 on the inner surface of a solid electrolyte body 120 formed into a bottomed cylindrical shape using a known solid electrolyte material such as zirconia having oxygen ion conductivity, and a measurement electrode 122 on the outer surface. The detecting section 12 is provided, and the diameter-enlarged section 11 is provided on the base end side of the detecting section 12 so that the diameter of the detecting section 12 is increased.
Inside the solid electrolyte body, air is introduced as a reference gas and is in contact with the reference electrode 122.
A plus signal line 14S + is connected to the reference electrode 122 via a plus terminal fitting 131S +.

A measurement electrode 122 that is exposed to the gas G to be measured is formed outside the detection unit 12, and the measurement electrode 122 is connected to the negative terminal fitting 131 </ b> S− at the base end portion 100 of the solid electrolyte body. The terminal fitting 131S- is connected to the minus signal line 14S-.
The positive terminal fitting 13S + includes a crimping portion 130S + connected to one center line 140S of the pair of signal lines 14S, and a reference electrode 122 that exerts a pressing force toward the outer peripheral side and is formed on the inner peripheral surface of the solid electrolyte body. It is composed of 131S + that is elastically connected and a heater gripper 133 that exerts a pressing force toward the center and grips the heater 18.
The minus terminal fitting 13S- has a crimping part 130S- connected to the other center line 140S of the pair of signal lines 14S, and a measurement reference electrode formed on the outer peripheral surface of the solid electrolyte body that exerts a pressing force toward the center. 123, and a connecting portion 131S- elastically connected. Inside the gas sensor element 1, a heater 18 containing a heating element that generates heat when energized is housed at the tip.

The heater 18 incorporates a known heating element such as W or molybdenum silicite in an insulator such as alumina.
A pair of energizing electrodes 181 for energizing a built-in heating element (not shown) is provided on the proximal end side of the heater 18.
The pair of through electrodes 181 are connected to the pair of energization wires 14H through the pair of energization terminal fittings 13H.

  The energizing terminal fitting 13H is electrically connected to the energizing electrode 181 by elastically contacting the energizing electrode 181 by exerting a pressing force toward the center on the crimping portion 130H connected to the center line 140H of the energizing wire 14H on the proximal end side. And a connecting portion 131H for achieving the above.

The housing 2 is formed in a cylindrical shape using a known metal material such as stainless steel, iron, nickel, alloys thereof, carbon steel, or the like according to the installation environment, and accommodates and fixes the gas sensor element 1 on the inner side. .
Between the inner peripheral surface 20 of the housing 2 and the outer peripheral surface 10 of the gas sensor element 1, a powder filling portion 30 and a cylindrical insulator 31 which are the main parts of the present invention are disposed.
A part of the inner peripheral surface of the housing 2 is reduced in diameter so that the diameter decreases toward the tip, and a locking part 21 that locks the diameter-enlarged part 11 of the gas sensor element 1 is formed.
On the proximal end side of the housing 2, a crimping portion 22 and a shrump portion 23 are formed to generate an axial force that presses the cylindrical insulator 31 in the distal axial direction.

A cylindrical casing 40 is fixed to the boss portion 24 of the housing 2 so as to cover the base end side of the housing and to draw out and fix the signal line and the conductive line.
A screw portion 25 is formed on the outer periphery on the front end side of the housing 2 and is screwed to the gas flow path 6 to be measured.
A hexagonal portion 26 for tightening the screw portion 25 is formed on the outer periphery of the base end side of the housing 2.
A caulking portion 27 for fixing the cover bodies 50 and 51 is formed at the tip of the housing 2.

In the present embodiment, the sealing means 3 includes a powder filling unit 30, a cylindrical insulator 31, and metal seal rings 32 and 33.
Sealing means 3 is provided between the gas sensor element GS1, the cylindrical housing 2 that accommodates and fixes the gas sensor element GS1, the outer peripheral surface 10 of the gas sensor element GS1, and the inner peripheral surface 20 of the housing 2.

Sieve particle size D _{SV of} filled powder particles 300 constituting powder filling unit 30, element side gap GP1 between inner peripheral surface 310 of cylindrical insulator 31 and outer peripheral surface 10 of gas sensor element 1, and cylindrical insulator 31, the element-side gap GP1 and the housing-side GP2 are not more than twice the sieving particle size D _SV of the filling powder 300 in the relationship between the housing-side gap GP2 between the outer peripheral surface 311 of 31 and the inner peripheral surface 20 of the housing 2. Is set to

The detection unit 12 provided on the distal end side of the gas sensor element 1 is covered with cover bodies 50 and 51.
The cover bodies 50 and 51 are caulked and fixed by a caulking portion 27 provided at the front end of the housing 2.
The cover bodies 50 and 51 are appropriately provided with through holes for introducing the gas to be measured G into the cover bodies 50 and 51 and leading it to the outside.
On the base end side of the hexagonal portion 27, a boss portion 24 for fixing the casing 4 is formed.

The casing 4 is made of a metal such as stainless steel, and has a cylindrical portion 40 formed in a stepped cylindrical shape, a vent hole 41 for introducing the atmosphere, a crimping portion 42 for sealing the proximal end side of the casing 2, and the insulator 15. The holding means 43 is used.
The casing 4 holds a pair of signal wires 14S + and 14S, a pair of signal terminal fittings 13S + and 13S−, a pair of energization wires 14H, and a pair of energization terminal fittings 13H while covering the proximal end side of the housing 2.
The pair of signal terminal fittings 13S + and 13S- and the pair of energizing terminal fittings 14H are accommodated in an insulator 15 made of an insulating material such as alumina so as to be electrically insulated from each other.

The insulator 15 is elastically held by the holding means 43.
The casing 4 is provided with a known water-repellent filter 16 that prevents air from entering while the atmosphere is introduced from the vent hole 41.
A sealing member 17 is provided on the base end side of the casing 4 and is made of a heat-resistant elastic member such as silicone rubber or fluororubber, and pulls out the pair of signal lines 14S +/− and the conductive line 14H while ensuring airtightness. .
In the present invention, inside the casing 4, the pair of signal lines 14 </ b> S (+/−) and the pair of conductive lines 14 </ b> H are connected to the sensor element 1 in the same manner inside the casing 4. Thus, the atmosphere as the reference gas is taken in, or the shape of the insulator 15 can be changed as appropriate, and is not limited to the embodiment.

With reference to FIG. 7B, gas sensor GS2 in the 2nd Embodiment of this invention is demonstrated.
In addition, about the same structure as previous embodiment, the same code | symbol is attached | subjected, About the different part, since the branch code | symbol of the alphabet was attached to the corresponding code | symbol, the description about a common part is abbreviate | omitted, Description will be made centering on characteristic portions in the present embodiment.
The gas sensor GS2 is a simple gas sensor that has a simple configuration by eliminating the heater from the gas sensor GS1, and is used in an internal combustion engine such as a motorcycle.
Also in this embodiment, as shown in FIG. 1, the powder filling part 30 and the cylindrical insulator 31 are provided between the gas sensor element 1 and the housing 2, and the gaps GP1 and GP2 in the pressing part are provided. By setting the predetermined range, airtightness is ensured.

In the embodiment, the heater element 14 that generates heat by energization is provided in order to activate the sensor element 1 at an early stage. However, in the present embodiment, the activation of the gas sensor element 1A is the heat of the gas G to be measured itself. The heater for activation is not provided.
Further, in the embodiment, the reference electrode 121 of the detection unit 12 is connected to the plus signal line 14S + via the plus terminal fitting 131S +, and the measurement electrode 122 is connected to the minus signal line 14S− via the minus terminal fitting 131S−. However, in the present embodiment, the measurement electrode 122 provided in the detection unit 12 by eliminating the minus-side signal wiring 14S- is connected to the measured gas flow path 6 via the metal seal ring 33 and the housing 2. Only the plus signal line 14 that is grounded and connected to the reference electrode 121 via the plus terminal fitting 13A is drawn out.
The positive terminal fitting 13A includes a crimping portion 130A connected to the center line 140 of the signal line 14, a reference electrode 122 formed on the inner peripheral surface of the solid electrolyte body, and 131A elastically connected to the inner peripheral surface of the solid electrolyte body. The contact portion 132A is configured to elastically contact the inclined portion and suppress axial vibration.
In this embodiment as well as in this embodiment, a powder filling portion 30 and a cylindrical insulator 31 are provided between the gas sensor element 1A and the housing 2 in the same manner as shown in FIG. Airtightness is ensured by setting the gaps GP1 and GP2 within a predetermined range.

With reference to FIG. 7C, a gas sensor GS3 according to a third embodiment of the present invention will be described.
In the above embodiment, a so-called cup-type gas sensor has been shown. However, the present invention can also be applied to a so-called laminated gas sensor, and this embodiment is an example.

  In the embodiment, the powder filling portion 30 and the cylindrical insulation are provided between the enlarged diameter portions 11 and 11A obtained by enlarging a part of the solid electrolyte body constituting the gas sensor elements 1 and 1A and the inner peripheral surface 20 of the housing 2. Although the sealing means 3 including the body 31 and the seal rings 32 and 33 are interposed, the shaft 2 is sandwiched between the reduced diameter portion 21 of the housing 2, the wrap crimping portion 22 and the shrump portion 23, and an axial force is applied. In the gas sensor GS3 in the present embodiment, as shown in FIG. 7C, the cylindrical housing 2, the gas sensor element 1B disposed in the housing 2, and the insulator constituting the sensor element 1B with the inner surface 20 of the housing 2 are provided. A sealing means 3 including a powder filling portion 30, a cylindrical insulator 31, and seal rings 32 and 33 is interposed between the outer side surface 10B, and the wrapping and crimping portion 22 of the housing 2, the shrump portion 23, and the shrinkage portion. The part 21, the enlarged diameter portion 11B which is enlarged a portion of the insulator of the sensor element 1B sandwiching retain the airtightness by applying an axial force.

The detection part 12 in this embodiment is comprised by what is called a laminated | stacked type gas sensor element, and is formed in the flat rod shape which laminates | stacks several ceramic sheets.
The detection unit 12 is inserted into a cylindrical insulator made of alumina or the like, and is held by a sealing portion 35 made of glass or the like.

Also in the present embodiment, as shown in FIG. 1, the powder filling portion 30 and the cylindrical insulator 31 are provided between the gas sensor element 1B and the housing 2, and the gaps GP1 and GP2 in the pressing portion are set to be predetermined. By ensuring that the airtightness is within the range, airtightness is ensured.
The specific configuration of the gas sensor element 1B is not particularly limited, and the detection unit 12B is formed with a detection cell, a heat generation unit, and the like according to a required detection function.
In addition, the detection target of the gas sensor in the present embodiment is not limited to the gas component, but may be PM, moisture, or the like.

DESCRIPTION OF SYMBOLS 1 Gas sensor element 2 Housing 3 Sealing means 10 Element outer peripheral surface 20 Housing inner peripheral surface 30 Powder filling part 300 Filling powder particle (talc particle)
31 Tubular insulator 310 Tubular insulator outer peripheral surface 311 Tubular insulator outer peripheral surface GS1, GS2, GS3 Gas sensor D _SV sieving particle size GP1 Element side gap GP2 Housing side gap

Claims (6)

A gas sensor for detecting a specific component in a gas to be measured, the gas sensor element (1), a cylindrical housing (2) for housing and fixing the gas sensor element (1), and an outer peripheral surface of the gas sensor element (1) (10) and the inner peripheral surface (20) of the housing (2), a powder filling part (30) mainly composed of talc, and a cylindrical insulator for pressing the powder filling part (30) (31) In the gas sensor (GS1, GS2, GS3) formed by providing the sealing means (3) including the sealing,
Sieving particle size D _{SV of} filled powder particles (300) constituting the powder filling portion (30);
An element side gap GP1 between the inner peripheral surface (310) of the cylindrical insulator (31) and the outer peripheral surface (10) of the gas sensor element (1);
In the relationship between the outer peripheral surface (311) of the cylindrical insulator (31) and the housing side gap GP2 between the inner peripheral surface (20) of the housing (2),
The element side gap GP1 and the housing side gap GP2 are
Gas sensor (GS1, GS2, GS3) characterized in that it is not more than twice the sieving particle size D _SV of the filling powder (300) The gas sensor (GS1, GS2, GS3) according to claim 1, wherein the sieving particle size D _SV is 210 µm or more and 710 µm or less.   The gas sensor (GS1, GS2, GS3) according to claim 1 or 2, wherein the element side gap GP1 and the housing side gap GP2 are 0.1 mm or more.   In the space defined between the gas sensor element (1) and the housing (2), the filled powder particles (300) are uniaxially pressed to form a filled powder molded body (30MOLD) formed into a cylindrical shape. The gas sensor according to any one of claims 1 to 3, wherein the powder filling portion (30) is formed by pressing through the cylindrical insulator (31) to increase airtightness.   The gas sensor according to any one of claims 1 to 4, wherein the housing (2) includes a wrap and crimp part (22) that elastically presses the cylindrical insulator (31) in an axial direction.   The gas sensor according to any one of claims 1 to 4, wherein the housing (2) includes a shrump portion (23) for elastically pressing the cylindrical insulator (31) in the axial direction.

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