JP2015003504A - Molding and production method thereof - Google Patents

Molding and production method thereof Download PDF

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JP2015003504A
JP2015003504A JP2013131709A JP2013131709A JP2015003504A JP 2015003504 A JP2015003504 A JP 2015003504A JP 2013131709 A JP2013131709 A JP 2013131709A JP 2013131709 A JP2013131709 A JP 2013131709A JP 2015003504 A JP2015003504 A JP 2015003504A
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thermoplastic resin
fiber
resin layer
reinforced thermoplastic
molded
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JP6229197B2 (en
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章亘 佐々木
Akinobu Sasaki
章亘 佐々木
理 奥中
Osamu Okunaka
理 奥中
英一郎 宇野
Eiichiro Uno
英一郎 宇野
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Mitsubishi Rayon Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a molding which has a protrusion part formed on a fiber-reinforced thermoplastic resin layer and having high strength and is easy to produce and its production method.SOLUTION: A molding 1 includes a substrate part 12 composed of a thermoplastic resin, fiber-reinforced thermoplastic resin layers 14 and 16 arranged on both surfaces of the substrate part 12 and a protrusion part 18 formed on the fiber-reinforced thermoplastic resin layer 14, and the protrusion part 18 is formed by causing a part of the thermoplastic resin which is arranged on the side of the substrate part 12 of the fiber-reinforced thermoplastic resin layer 14 and constitutes the substrate part 12 and the protrusion part 18 to flow to the front side of the fiber-reinforced thermoplastic resin layer 14.

Description

本発明は、成型品およびその製造方法に関する。   The present invention relates to a molded article and a manufacturing method thereof.

航空機や自動車等の様々な分野において、強化繊維と熱可塑性樹脂からなる繊維強化熱可塑性樹脂を用いた成型品が広く用いられている。例えば、以下に示す成型品が挙げられる。
(i)炭素繊維に熱硬化性樹脂および熱可塑性樹脂を含浸したプリプレグを加熱加圧して得られる炭素繊維複合材料板の表面に、熱可塑性樹脂を射出成型して結合一体化した成型品(特許文献1)。
(ii)熱可塑性樹脂層の両面に繊維強化熱可塑性樹脂層が配置されたシート状の成型材料を、型によって表面形状が使用者の足裏の形状に一致するように加熱成型した中敷き(特許文献2)。
In various fields such as aircraft and automobiles, molded products using fiber reinforced thermoplastic resins made of reinforced fibers and thermoplastic resins are widely used. For example, the molded product shown below is mentioned.
(I) Molded product in which a thermoplastic resin is injection-molded and bonded and integrated onto the surface of a carbon fiber composite material plate obtained by heating and pressing a prepreg impregnated with a thermosetting resin and a thermoplastic resin in carbon fiber (patented) Reference 1).
(Ii) An insole (patented) in which a sheet-shaped molding material in which fiber-reinforced thermoplastic resin layers are arranged on both sides of a thermoplastic resin layer is heat-molded so that the surface shape matches the shape of the user's sole with a mold Reference 2).

ところで、航空機や自動車等に用いられる、表層の繊維強化熱可塑性樹脂層を有するシート状の成型品等では、強度を高める等の目的で、繊維強化熱可塑性樹脂層の表面に熱可塑性樹脂からなるリブやボス等の突起部が形成されることが多い。
このような突起部を有する成型品の製造方法としては、例えば、成型品(i)の製造のように、表層に繊維強化熱可塑性樹脂層を有する成型体の表面に熱可塑性樹脂を射出成型してリブやボス等の突起部を形成する方法が挙げられる。しかし、該方法は、繊維強化熱可塑性樹脂層を有する成型体の成型と、突起部の射出成型とを別々に行う必要があるため製造が煩雑である。また、該方法では、得られた成型品において突起部の強度が充分に得られ難いことがある。
また、成型品(ii)の製造方法は、シート状の成型材料の表面形状が所望の形状になるようにプレス成型するだけであるため、表面にリブやボス等の突起部を有する成型品は得られない。
By the way, in the case of a sheet-like molded article having a surface fiber reinforced thermoplastic resin layer used for an aircraft or an automobile, the surface of the fiber reinforced thermoplastic resin layer is made of a thermoplastic resin for the purpose of increasing the strength. Projections such as ribs and bosses are often formed.
As a method for producing a molded product having such a protrusion, for example, a thermoplastic resin is injection-molded on the surface of a molded product having a fiber-reinforced thermoplastic resin layer on the surface layer, as in the production of a molded product (i). And a method of forming protrusions such as ribs and bosses. However, this method is complicated to manufacture because it is necessary to separately perform molding of the molded body having the fiber-reinforced thermoplastic resin layer and injection molding of the protrusions. In addition, in this method, it may be difficult to obtain sufficient strength of the protrusions in the obtained molded product.
Moreover, since the manufacturing method of a molded product (ii) is only press-molded so that the surface shape of the sheet-shaped molding material becomes a desired shape, a molded product having protrusions such as ribs and bosses on the surface I can't get it.

特許第3098478号公報Japanese Patent No. 3098478 米国特許第4778717号明細書US Pat. No. 4,778,717

本発明は、繊維強化熱可塑性樹脂層上に突起部を形成した成型品であって、製造が簡便で、かつ突起部の強度が高い成型品、および該成型品の製造方法を提供する。   The present invention provides a molded product in which a protrusion is formed on a fiber-reinforced thermoplastic resin layer, which is easy to manufacture and has a high strength of the protrusion, and a method for manufacturing the molded product.

本発明の成型品は、基体部および該基体部から突出する突起部を有する熱可塑性樹脂成型体と、前記基体部における少なくとも一部の表面に配置された繊維強化熱可塑性樹脂層と、を有し、前記突起部が前記繊維強化熱可塑性樹脂層を貫通して突き出ていることを特徴とする。   The molded article of the present invention has a thermoplastic resin molded body having a base portion and a protruding portion protruding from the base portion, and a fiber-reinforced thermoplastic resin layer disposed on at least a part of the surface of the base portion. The protruding portion protrudes through the fiber reinforced thermoplastic resin layer.

本発明の成型品では、前記基体部がシート状であり、前記繊維強化熱可塑性樹脂層が前記基体部の両面にそれぞれ配置されていることが好ましい。
また、本発明の成型品では、前記繊維強化熱可塑性樹脂層を形成する強化繊維は長繊維であることが好ましい。
In the molded article of the present invention, it is preferable that the base portion is in a sheet form, and the fiber reinforced thermoplastic resin layers are respectively disposed on both sides of the base portion.
In the molded article of the present invention, it is preferable that the reinforcing fiber forming the fiber-reinforced thermoplastic resin layer is a long fiber.

本発明の成型品の製造方法は、前記熱可塑性樹脂成型体の形成に用いる熱可塑性樹脂体の少なくとも一部の表面に繊維強化熱可塑性樹脂層が配置された成型材料を、型によって成型し、前記熱可塑性樹脂体の一部を前記繊維強化熱可塑性樹脂層の表面側へ流動させて前記突起部を形成する成型工程を有する方法である。   In the method for producing a molded article of the present invention, a molding material in which a fiber reinforced thermoplastic resin layer is disposed on at least a part of the surface of the thermoplastic resin body used for forming the thermoplastic resin molded body is molded by a mold. In this method, a part of the thermoplastic resin body is caused to flow toward the surface side of the fiber reinforced thermoplastic resin layer to form the protrusions.

本発明の成型品の製造方法では、前記成型材料が、シート状の熱可塑性樹脂体の両面に繊維強化熱可塑性樹脂層が配置された成型材料であることが好ましい。
また、本発明の成型品の製造方法では、前記繊維強化熱可塑性樹脂層を形成する強化繊維が長繊維であることが好ましい。
In the method for producing a molded article according to the present invention, the molding material is preferably a molding material in which fiber-reinforced thermoplastic resin layers are disposed on both sides of a sheet-like thermoplastic resin body.
Moreover, in the manufacturing method of the molded article of this invention, it is preferable that the reinforced fiber which forms the said fiber reinforced thermoplastic resin layer is a long fiber.

本発明の成型品は、繊維強化熱可塑性樹脂層上に突起部を形成した成型品であって、製造が簡便で、かつ突起部の強度が高い。
本発明の成型品の製造方法によれば、簡便に、突起部の強度が高い成型品が得られる。
The molded product of the present invention is a molded product in which a protruding portion is formed on a fiber reinforced thermoplastic resin layer, is easy to manufacture, and has a high strength of the protruding portion.
According to the method for producing a molded product of the present invention, a molded product with a high strength of the protrusion can be obtained easily.

本発明の成型品の一例を示した斜視図である。It is the perspective view which showed an example of the molded article of this invention. 図1の成型品のA−A断面図である。It is AA sectional drawing of the molded article of FIG. 図1の成型品の製造に用いる成型材料を示した断面図である。It is sectional drawing which showed the molding material used for manufacture of the molded article of FIG. 本発明の成型品の製造に用いる金型の一例を示した断面図である。It is sectional drawing which showed an example of the metal mold | die used for manufacture of the molded article of this invention. 図1の成型品の製造方法における成型工程を示した断面図である。It is sectional drawing which showed the shaping | molding process in the manufacturing method of the molded article of FIG. 図1の成型品の製造方法における成型工程を示した断面図である。It is sectional drawing which showed the shaping | molding process in the manufacturing method of the molded article of FIG.

<成型品>
以下、本発明の成型品の一例を示して詳細に説明する。
本実施形態の成型品1は、図1および図2に示すように、シート状の基体部12および基体部12から突出する突起部14を有する熱可塑性樹脂成型体10と、基体部12の両方の表面にそれぞれ配置された繊維強化熱可塑性樹脂層16,18と、を有する。
<Molded product>
Hereinafter, an example of the molded product of the present invention will be shown and described in detail.
As shown in FIGS. 1 and 2, the molded product 1 according to the present embodiment includes both a thermoplastic resin molded body 10 having a sheet-like base portion 12 and a protruding portion 14 protruding from the base portion 12, and the base portion 12. Fiber reinforced thermoplastic resin layers 16 and 18 respectively disposed on the surface of the fiber.

熱可塑性樹脂成型体10は、熱可塑性樹脂で形成された成型体であり、シート状の基体部12における繊維強化熱可塑性樹脂層16が配置された側の面に4つの突起部14が形成されている。
突起部14は、基体部12の表面に配置された繊維強化熱可塑性樹脂層16を貫通して突き出るように形成されている。突起部14の基端部側の繊維強化熱可塑性樹脂層16に埋もれている部分においては、突起部14を形成する熱可塑性樹脂と、繊維強化熱可塑性樹脂層16を形成する強化繊維および熱可塑性樹脂が混在している。
The thermoplastic resin molded body 10 is a molded body formed of a thermoplastic resin, and four protrusions 14 are formed on the surface of the sheet-like base portion 12 on the side where the fiber reinforced thermoplastic resin layer 16 is disposed. ing.
The protruding portion 14 is formed so as to protrude through the fiber reinforced thermoplastic resin layer 16 disposed on the surface of the base portion 12. In a portion buried in the fiber reinforced thermoplastic resin layer 16 on the base end side of the protrusion 14, the thermoplastic resin forming the protrusion 14, the reinforcing fiber forming the fiber reinforced thermoplastic resin layer 16, and the thermoplastic resin. Resin is mixed.

成型品1においては、このように熱可塑性樹脂成型体10の突起部14が繊維強化熱可塑性樹脂層16を貫通するように突き出して形成されているため、後述するように製造が簡便である。また、基体部12と突起部14が一体の熱可塑性樹脂成型体10となっているため、繊維強化熱可塑性樹脂層上に射出成型によって突起部を形成する場合等、突起部を独立して形成するに比べて、突起部14の強度が高い。   In the molded product 1, the protrusions 14 of the thermoplastic resin molded body 10 are formed so as to protrude through the fiber reinforced thermoplastic resin layer 16, so that the manufacturing is simple as will be described later. In addition, since the base portion 12 and the projection portion 14 are an integrated thermoplastic resin molded body 10, the projection portion is formed independently, such as when the projection portion is formed by injection molding on the fiber reinforced thermoplastic resin layer. Compared to this, the strength of the protrusion 14 is high.

基体部12の形状は、この例では矩形であるが、矩形には限定されない。
基体部12の厚みは、特に限定されず、0.3〜10.0mmが好ましく、0.5〜3.5mmがより好ましい。基体部12の厚みが下限値以上であれば、高い強度が得られやすい。基体部12の厚みが上限値以下であれば、曲げ比強度に優れた成型体が得られやすい。
Although the shape of the base | substrate part 12 is a rectangle in this example, it is not limited to a rectangle.
The thickness of the base portion 12 is not particularly limited, but is preferably 0.3 to 10.0 mm, and more preferably 0.5 to 3.5 mm. If the thickness of the base portion 12 is equal to or greater than the lower limit value, high strength is easily obtained. If the thickness of the base portion 12 is equal to or less than the upper limit value, a molded body excellent in bending specific strength can be easily obtained.

突起部14としては、例えば、リブ、ボス等が挙げられる。
突起部14の形状は、この例では略円錐状であるが、特に限定されない。突起部14の形状は、円柱状、四角註状断面矩形状、断面三角形状等であってもよく、突起部14の用途に応じて適宜決定すればよい。また、突起部14の高さも特に限定されず、突起部14の用途に応じて適宜決定すればよい。
また、突起部14の数は、この例では4つであるが、3つ以下でもよく、5つ以上でもよい。
Examples of the protrusion 14 include a rib and a boss.
The shape of the protrusion 14 is substantially conical in this example, but is not particularly limited. The shape of the protruding portion 14 may be a columnar shape, a quadrangular rectangular cross section, a triangular shape, or the like, and may be determined as appropriate according to the use of the protruding portion 14. Further, the height of the protrusion 14 is not particularly limited, and may be determined as appropriate according to the use of the protrusion 14.
Moreover, although the number of the protrusion parts 14 is four in this example, three or less may be sufficient and five or more may be sufficient.

熱可塑性樹脂成型体10を形成する熱可塑性樹脂としては、特に限定されず、例えば、ポリオレフィン(ポリエチレン、ポリプロピレン等。)、ポリエステル(ポリエチレンテレフタレート、ポリブチレンテレフタレート等。)、ポリスチレン、ABS樹脂、アクリル樹脂、塩化ビニル、ポリアミド(ポリアミド6等。)、ポリカーボネート、ポリフェニレンエーテル、ポリエーテルスルフォン、ポリサルフォン、ポリエーテルイミド、ポリケトン、ポリエーテルケトン、ポリエーテルエーテルケトン等が挙げられる。熱可塑性樹脂としては、これら各樹脂の変性体を用いてもよい。
熱可塑性樹脂成型体10を形成する熱可塑性樹脂としては、ポリオレフィン、ポリアミド、ポリカーボネートが好ましく、ポリプロピレン、ポリアミド6がより好ましい。
The thermoplastic resin forming the thermoplastic resin molding 10 is not particularly limited, and examples thereof include polyolefin (polyethylene, polypropylene, etc.), polyester (polyethylene terephthalate, polybutylene terephthalate, etc.), polystyrene, ABS resin, acrylic resin. , Vinyl chloride, polyamide (polyamide 6 etc.), polycarbonate, polyphenylene ether, polyether sulfone, polysulfone, polyetherimide, polyketone, polyether ketone, polyether ether ketone and the like. As the thermoplastic resin, modified products of these resins may be used.
As a thermoplastic resin which forms the thermoplastic resin molding 10, polyolefin, polyamide, and polycarbonate are preferable, and polypropylene and polyamide 6 are more preferable.

熱可塑性樹脂成型体10を形成する熱可塑性樹脂は、1種でもよく、2種以上でもよい。
また、熱可塑性樹脂成型体10を形成する熱可塑性樹脂には、各種添加剤、フィラー、着色剤等が配合されてもよい。
The thermoplastic resin forming the thermoplastic resin molded body 10 may be one type or two or more types.
In addition, various additives, fillers, colorants, and the like may be blended in the thermoplastic resin forming the thermoplastic resin molded body 10.

繊維強化熱可塑性樹脂層16は、強化繊維に熱可塑性樹脂を含浸した繊維強化熱可塑性樹脂により形成された層である。この例では、繊維強化熱可塑性樹脂層16は、基体部12の一方の表面全体を覆うように配置されている。
なお、本発明では、繊維強化熱可塑性樹脂層は、本発明の効果を損なわない範囲であれば、基体部における表面に部分的に配置されていてもよい。
The fiber reinforced thermoplastic resin layer 16 is a layer formed of a fiber reinforced thermoplastic resin in which a reinforced fiber is impregnated with a thermoplastic resin. In this example, the fiber-reinforced thermoplastic resin layer 16 is disposed so as to cover the entire one surface of the base portion 12.
In the present invention, the fiber reinforced thermoplastic resin layer may be partially disposed on the surface of the base portion as long as the effects of the present invention are not impaired.

繊維強化熱可塑性樹脂層16を形成する熱可塑性樹脂としては、例えば、熱可塑性樹脂成型体10を形成する熱可塑性樹脂として挙げたものと同じものが挙げられる。
繊維強化熱可塑性樹脂層16を形成する熱可塑性樹脂としては、ポリオレフィン、ポリアミド、ポリカーボネートが好ましく、酸変性ポリプロピレン、ポリアミド6がより好ましい。好ましい熱可塑性樹脂を用いることで、強化繊維として炭素繊維を用いた場合に、熱可塑性樹脂と繊維の間の界面強度をより高くすることが可能であり、成型体の強度がより高くなる。
As a thermoplastic resin which forms the fiber reinforced thermoplastic resin layer 16, the same thing as what was mentioned as a thermoplastic resin which forms the thermoplastic resin molding 10 is mentioned, for example.
As a thermoplastic resin which forms the fiber reinforced thermoplastic resin layer 16, polyolefin, polyamide, and polycarbonate are preferable, and acid-modified polypropylene and polyamide 6 are more preferable. By using a preferable thermoplastic resin, when carbon fiber is used as the reinforcing fiber, the interface strength between the thermoplastic resin and the fiber can be further increased, and the strength of the molded body is further increased.

繊維強化熱可塑性樹脂層16を形成する熱可塑性樹脂は、1種でもよく、2種以上でもよい。
また、繊維強化熱可塑性樹脂層16を形成する熱可塑性樹脂には、各種添加剤、フィラー、着色剤等が配合されてもよい。
また、繊維強化熱可塑性樹脂層16を形成する熱可塑性樹脂は、熱可塑性樹脂成型体10を形成する熱可塑性樹脂と同じでもよく、異なっていてもよい。
The thermoplastic resin that forms the fiber reinforced thermoplastic resin layer 16 may be one type or two or more types.
Various additives, fillers, colorants, and the like may be blended in the thermoplastic resin that forms the fiber-reinforced thermoplastic resin layer 16.
Further, the thermoplastic resin that forms the fiber-reinforced thermoplastic resin layer 16 may be the same as or different from the thermoplastic resin that forms the thermoplastic resin molded body 10.

繊維強化熱可塑性樹脂層16を形成する強化繊維としては、例えば、ガラス繊維、炭素繊維、アラミド繊維等が挙げられる。   Examples of the reinforcing fibers that form the fiber-reinforced thermoplastic resin layer 16 include glass fibers, carbon fibers, and aramid fibers.

繊維強化熱可塑性樹脂層16を形成する強化繊維は、長繊維が好ましい。特に、強化繊維は、繊維強化熱可塑性樹脂層16内において途切れのない連続した長繊維であることが好ましい。強化繊維が長繊維であれば、より高強度な成型品が得られやすい。
強化繊維が長繊維である繊維強化熱可塑性樹脂層16としては、例えば、一方向に引き揃えられた長繊維に熱可塑性樹脂が含浸されたシート、該シートを2枚以上積層した積層体等が挙げられる。前記シートを2枚以上積層する場合、それぞれのシートの長繊維の方向が交差するようにしてもよく、並行するようにしてもよい。
The reinforcing fibers forming the fiber reinforced thermoplastic resin layer 16 are preferably long fibers. In particular, it is preferable that the reinforcing fibers are continuous long fibers that are not interrupted in the fiber-reinforced thermoplastic resin layer 16. If the reinforcing fiber is a long fiber, a molded product with higher strength can be easily obtained.
Examples of the fiber reinforced thermoplastic resin layer 16 in which the reinforcing fibers are long fibers include a sheet in which a long fiber aligned in one direction is impregnated with a thermoplastic resin, and a laminate in which two or more sheets are laminated. Can be mentioned. When two or more sheets are laminated, the directions of the long fibers of each sheet may intersect or may be parallel.

なお、繊維強化熱可塑性樹脂層16は、長繊維を一方向に引き揃えて熱可塑性樹脂を含浸したテープ状材料を製織してなるクロス材、強化繊維の織物に熱可塑性樹脂を含浸させたクロス材等により形成してもよい。
前記クロス材の織り方としては、例えば、平織、綾織、朱子織、三軸織等が挙げられる。
The fiber reinforced thermoplastic resin layer 16 is a cloth material obtained by weaving a tape-like material in which long fibers are aligned in one direction and impregnated with a thermoplastic resin, and a cloth in which a reinforced fiber fabric is impregnated with a thermoplastic resin. You may form with a material etc.
Examples of the weave of the cloth material include plain weave, twill weave, satin weave, and triaxial weave.

また、繊維強化熱可塑性樹脂層16に用いる強化繊維は、チョップされた短繊維であってもよい。例えば、熱可塑性樹脂に、短繊維が一本一本開繊された状態あるいは束の状態で分散されたシートにより繊維強化熱可塑性樹脂層16を形成してもよい。
また、短繊維が一本一本開繊された状態あるいは束の状態で分散された熱可塑性樹脂を長繊維に含浸させたシートにより繊維強化熱可塑性樹脂層16を形成してもよい。
Further, the reinforced fibers used for the fiber reinforced thermoplastic resin layer 16 may be chopped short fibers. For example, the fiber reinforced thermoplastic resin layer 16 may be formed of a sheet in which short fibers are opened one by one or dispersed in a bundle in a thermoplastic resin.
Alternatively, the fiber reinforced thermoplastic resin layer 16 may be formed of a sheet in which a long fiber is impregnated with a thermoplastic resin in which short fibers are opened individually or in a bundle.

繊維強化熱可塑性樹脂層16における強化繊維の体積含有率は、20〜60%が好ましく、30〜50%がより好ましい。前記強化繊維の体積含有率が下限値以上であれば、強度の高い成型品が得られやすい。前記強化繊維の体積含有率が上限値以下であれば、後述する成型の際に熱可塑性樹脂が繊維強化熱可塑性樹脂層16内を通過しやすくなり、安定して突起部14を形成しやすくなる。   20-60% is preferable and, as for the volume content rate of the reinforced fiber in the fiber reinforced thermoplastic resin layer 16, 30-50% is more preferable. If the volume content of the reinforcing fiber is equal to or higher than the lower limit value, a molded product having high strength is easily obtained. If the volume content of the reinforcing fiber is equal to or less than the upper limit value, the thermoplastic resin easily passes through the fiber-reinforced thermoplastic resin layer 16 during molding, which will be described later, and the protrusions 14 are easily formed stably. .

繊維強化熱可塑性樹脂層16の厚さは、0.1〜1.0mmが好ましく、0.2〜0.6mmがより好ましい。繊維強化熱可塑性樹脂層16の厚さが下限値以上であれば、強度の高い成型品が得られやすい。繊維強化熱可塑性樹脂層16の厚さが上限値以下であれば、後述する成型の際に熱可塑性樹脂が繊維強化熱可塑性樹脂層16内を通過しやすくなり、安定して突起部14を形成しやすくなる。   The thickness of the fiber reinforced thermoplastic resin layer 16 is preferably 0.1 to 1.0 mm, and more preferably 0.2 to 0.6 mm. If the thickness of the fiber reinforced thermoplastic resin layer 16 is equal to or greater than the lower limit value, a molded product having high strength is easily obtained. If the thickness of the fiber reinforced thermoplastic resin layer 16 is equal to or less than the upper limit value, the thermoplastic resin easily passes through the fiber reinforced thermoplastic resin layer 16 during molding, which will be described later, and the protrusions 14 are stably formed. It becomes easy to do.

繊維強化熱可塑性樹脂層18を形成する熱可塑性樹脂としては、例えば、熱可塑性樹脂成型体10で挙げたものと同じものが挙げられ、好ましい態様は繊維強化熱可塑性樹脂層16の場合と同じである。繊維強化熱可塑性樹脂層18を形成する強化繊維としては、例えば、繊維強化熱可塑性樹脂層16で挙げたものと同じものが挙げられ、好ましい態様も同じである。
繊維強化熱可塑性樹脂層18における熱可塑性樹脂は、繊維強化熱可塑性樹脂層16における熱可塑性樹脂と同じであってもよく、異なっていてもよい。
繊維強化熱可塑性樹脂層18における強化繊維は、繊維強化熱可塑性樹脂層16における強化繊維と同じであってもよく、異なっていてもよい。
Examples of the thermoplastic resin that forms the fiber-reinforced thermoplastic resin layer 18 include the same ones as those described for the thermoplastic resin molded body 10, and the preferred embodiment is the same as that for the fiber-reinforced thermoplastic resin layer 16. is there. Examples of the reinforcing fibers that form the fiber-reinforced thermoplastic resin layer 18 include the same fibers as those mentioned for the fiber-reinforced thermoplastic resin layer 16, and the preferred embodiments are also the same.
The thermoplastic resin in the fiber reinforced thermoplastic resin layer 18 may be the same as or different from the thermoplastic resin in the fiber reinforced thermoplastic resin layer 16.
The reinforcing fibers in the fiber reinforced thermoplastic resin layer 18 may be the same as or different from the reinforcing fibers in the fiber reinforced thermoplastic resin layer 16.

繊維強化熱可塑性樹脂層18における強化繊維の体積含有率は、20〜60%が好ましく、30〜50%がより好ましい。前記強化繊維の体積含有率が下限値以上であれば、強度の高い成型品が得られやすい。前記強化繊維の体積含有率が上限値以下であれば、曲げ比強度に優れた成型体が得られやすい。   20-60% is preferable and, as for the volume content rate of the reinforced fiber in the fiber reinforced thermoplastic resin layer 18, 30-50% is more preferable. If the volume content of the reinforcing fiber is equal to or higher than the lower limit value, a molded product having high strength is easily obtained. If the volume content of the reinforcing fibers is equal to or less than the upper limit value, a molded body excellent in bending specific strength can be easily obtained.

繊維強化熱可塑性樹脂層18の厚さは、0.1〜1.0mmが好ましく、0.2〜0.6mmがより好ましい。繊維強化熱可塑性樹脂層18の厚さが下限値以上であれば、強度の高い成型品が得られやすい。繊維強化熱可塑性樹脂層18の厚さが上限値以下であれば、曲げ比強度に優れた成型体が得られやすい。   The thickness of the fiber reinforced thermoplastic resin layer 18 is preferably 0.1 to 1.0 mm, and more preferably 0.2 to 0.6 mm. If the thickness of the fiber reinforced thermoplastic resin layer 18 is equal to or greater than the lower limit value, a molded product having high strength is easily obtained. If the thickness of the fiber reinforced thermoplastic resin layer 18 is equal to or less than the upper limit value, a molded body excellent in bending specific strength is easily obtained.

以上説明した本発明の成型品においては、熱可塑性樹脂成型体における基体部と突起部が一体となっており、突起部が繊維強化熱可塑性樹脂層を貫通して突き出るように形成されているため、製造が簡便で、かつ突起部の強度が高い。   In the molded product of the present invention described above, the base portion and the projection portion in the thermoplastic resin molded body are integrated, and the projection portion is formed so as to protrude through the fiber reinforced thermoplastic resin layer. The manufacture is simple and the strength of the protrusion is high.

なお、本発明の成型品は前記した成型品1には限定されない。例えば、繊維強化熱可塑性樹脂層がシート状の基体部の片面のみに設けられた成型品であってもよい。
本発明の成型品としては、シート状の基体部とする場合、成型品が反り難く、またより高い強度が得られやすい点から、該基体部の両面にそれぞれ繊維強化熱可塑性樹脂層が設けられていることが好ましい。また、繊維強化熱可塑性樹脂層がシート状の基体部の両面に設けられる場合は、両面に突起部が形成された成型品であってもよい。
また、本発明の成型品は、シート状以外の形状を有する基体部を有するものであってもよい。
The molded product of the present invention is not limited to the molded product 1 described above. For example, it may be a molded product in which the fiber reinforced thermoplastic resin layer is provided only on one side of the sheet-like base portion.
As the molded product of the present invention, when a sheet-like substrate portion is used, the molded product is not easily warped, and a fiber-reinforced thermoplastic resin layer is provided on each side of the substrate portion because higher strength is easily obtained. It is preferable. Moreover, when a fiber reinforced thermoplastic resin layer is provided on both surfaces of a sheet-like base | substrate part, the molded article in which the projection part was formed in both surfaces may be sufficient.
The molded product of the present invention may have a base portion having a shape other than a sheet shape.

<成型品の製造方法>
以下、本発明の成型品の製造方法の一例として、成型品1の製造方法について説明する。成型品1の製造方法としては、例えば、下記の予熱工程および成型工程を有する方法が挙げられる。
予熱工程:図3に例示した、熱可塑性樹脂成型体10を形成するシート状の熱可塑性樹脂体10Aの両方の表面に、それぞれ繊維強化熱可塑性樹脂層16,18が配置された成型材料1Aを予熱する工程。
成型工程:予熱した成型材料1Aを、該成型材料1Aの予熱温度よりも低い温度に調温した金型100(図4)によって成型し、熱可塑性樹脂体10Aの一部を繊維強化熱可塑性樹脂層16の表面側へ流動させて突起部14を形成させる工程。
<Method of manufacturing molded product>
Hereinafter, the manufacturing method of the molded product 1 will be described as an example of the manufacturing method of the molded product of the present invention. As a manufacturing method of the molded article 1, for example, a method having the following preheating step and molding step can be mentioned.
Preheating step: The molding material 1A in which the fiber reinforced thermoplastic resin layers 16 and 18 are respectively disposed on both surfaces of the sheet-like thermoplastic resin body 10A forming the thermoplastic resin molded body 10 illustrated in FIG. Preheating process.
Molding step: A preheated molding material 1A is molded by a mold 100 (FIG. 4) adjusted to a temperature lower than the preheating temperature of the molding material 1A, and a part of the thermoplastic resin body 10A is a fiber reinforced thermoplastic resin. A step of forming the protrusion 14 by flowing toward the surface side of the layer 16.

(予熱工程)
成型材料1Aにおける熱可塑性樹脂体10Aは、成型品1における熱可塑性樹脂成型体10を形成するものである。熱可塑性樹脂体10Aは、シート状であり、目的の成型品1の基体部12よりも厚みが厚くなっている。
成型材料1Aにおける繊維強化熱可塑性樹脂層16を形成する強化繊維は、強度の点から、長繊維が好ましい。繊維強化熱可塑性樹脂層18を形成する強化繊維についても同様である。
(Preheating process)
The thermoplastic resin body 10 </ b> A in the molding material 1 </ b> A forms the thermoplastic resin molded body 10 in the molded product 1. The thermoplastic resin body 10 </ b> A has a sheet shape and is thicker than the base portion 12 of the target molded product 1.
The reinforcing fibers forming the fiber-reinforced thermoplastic resin layer 16 in the molding material 1A are preferably long fibers from the viewpoint of strength. The same applies to the reinforcing fibers forming the fiber-reinforced thermoplastic resin layer 18.

繊維強化熱可塑性樹脂層18上に、熱可塑性樹脂体10Aおよび繊維強化熱可塑性樹脂層16をこの順に積層して成型材料1Aとし、加熱装置により成型材料1Aを予熱する。
加熱装置としては、成型材料1Aを所望の温度に予熱できるものであればよく、例えば、赤外線加熱炉、電気オーブン、ホットプレート等が挙げられる。なかでも、加熱装置としては、赤外線加熱炉が好ましい。このように、予熱工程において成型材料1Aを赤外線加熱する方法は、成型材料1Aを内部まで均一に加熱しやすい点で有利である。
A thermoplastic resin body 10A and a fiber reinforced thermoplastic resin layer 16 are laminated in this order on the fiber reinforced thermoplastic resin layer 18 to form a molding material 1A, and the molding material 1A is preheated by a heating device.
Any heating device may be used as long as it can preheat the molding material 1A to a desired temperature, and examples thereof include an infrared heating furnace, an electric oven, and a hot plate. Of these, an infrared heating furnace is preferable as the heating device. Thus, the method of heating the molding material 1A by infrared rays in the preheating step is advantageous in that the molding material 1A can be easily heated to the inside.

予熱温度は、用いる熱可塑性樹脂の種類によっても異なるが、150〜450℃が好ましく、210〜250℃がより好ましい。
予熱時間は、成型材料1Aの厚み等によって適宜決定すればよい。
The preheating temperature varies depending on the type of thermoplastic resin used, but is preferably 150 to 450 ° C, and more preferably 210 to 250 ° C.
The preheating time may be appropriately determined depending on the thickness of the molding material 1A.

(成型工程)
成型工程に用いる金型100は、図4に示すように、下型110と上型112とを有する。金型100においては、下型110と上型112を型締めすることで、内部にキャビティ114が形成される。キャビティ114の形状は、成型品1の形状と相補的な形状になっている。
図5に示すように、下型110上に予熱した成型材料1Aを設置し、上型112を降下させて金型100を閉じて成型材料1Aをプレス成型する。成型工程は、予熱された成型材料1Aにおける熱可塑性樹脂体10Aが流動可能な温度を維持している状態で行う。
(Molding process)
As shown in FIG. 4, the mold 100 used in the molding process has a lower mold 110 and an upper mold 112. In the mold 100, a cavity 114 is formed inside by clamping the lower mold 110 and the upper mold 112. The shape of the cavity 114 is complementary to the shape of the molded product 1.
As shown in FIG. 5, the preheated molding material 1A is placed on the lower mold 110, the upper mold 112 is lowered, the mold 100 is closed, and the molding material 1A is press-molded. The molding process is performed in a state where the temperature at which the thermoplastic resin body 10A in the preheated molding material 1A can flow is maintained.

成型工程では、下型110と上型112によって、成型材料1Aの厚みが目的とする成型品1の基体部12の厚みとなるまでプレスされる。このとき、図6に示すように、熱可塑性樹脂体10Aの厚みが薄くされて基体部12が形成されると共に、熱可塑性樹脂体10Aの一部が繊維強化熱可塑性樹脂層16内の強化繊維間を流動して上型112側へと飛び出し、キャビティ114の形状に沿うように成型される。これにより、基体部12と、基体部12から繊維強化熱可塑性樹脂層16を貫通するように突き出た突起部14とを有する熱可塑性樹脂成型体10が形成される。   In the molding process, the lower mold 110 and the upper mold 112 are pressed until the thickness of the molding material 1A reaches the thickness of the base portion 12 of the target molded product 1. At this time, as shown in FIG. 6, the thickness of the thermoplastic resin body 10 </ b> A is reduced to form the base portion 12, and part of the thermoplastic resin body 10 </ b> A is reinforced fiber in the fiber reinforced thermoplastic resin layer 16. It flows between them, jumps out to the upper mold 112 side, and is molded so as to follow the shape of the cavity 114. Thereby, the thermoplastic resin molded body 10 having the base portion 12 and the protruding portion 14 protruding from the base portion 12 so as to penetrate the fiber reinforced thermoplastic resin layer 16 is formed.

成型工程における金型100の温度は、前記予熱温度よりも低い温度であり、成型材料1Aがキャビティ114の形状に成型された状態で固化する温度に調温する。
金型100の温度は、用いる熱可塑性樹脂の種類によっても異なるが、60〜180℃が好ましく、100〜130℃がより好ましい。
The temperature of the mold 100 in the molding step is lower than the preheating temperature, and the temperature is adjusted to a temperature at which the molding material 1A is solidified in the state of being molded into the shape of the cavity 114.
The temperature of the mold 100 varies depending on the type of thermoplastic resin used, but is preferably 60 to 180 ° C, more preferably 100 to 130 ° C.

成型工程における成型圧力、すなわち金型100の下型110と上型112によって成型材料1Aに加える圧力は、0.2〜50MPaが好ましく、3〜30MPaがより好ましい。
成型時間は、0.2〜10分間が好ましく、0.5〜3分間がより好ましい。
金型100内で成型材料1Aが固化した後に金型100を開き、成型品1を取り出す。
The molding pressure in the molding process, that is, the pressure applied to the molding material 1A by the lower mold 110 and the upper mold 112 of the mold 100 is preferably 0.2 to 50 MPa, and more preferably 3 to 30 MPa.
The molding time is preferably 0.2 to 10 minutes, and more preferably 0.5 to 3 minutes.
After the molding material 1A is solidified in the mold 100, the mold 100 is opened and the molded product 1 is taken out.

以上説明した本発明の成型品の製造方法は、基体部の表面に繊維強化熱可塑性樹脂層を設けたシート状成型体を成型した後に、該シート状成型体の表面に射出成型によって突起部を形成する場合に比べて、成型回数が少なくて済むため、成型品の製造が容易である。
また、本発明では、前記したように熱可塑性樹脂体の一部が繊維強化熱可塑性樹脂層の内部を流動して突起部が形成されるため、繊維強化熱可塑性樹脂層内の熱可塑性樹脂と共に強化繊維の一部が突起部に混入しやすい。このように、突起部に強化繊維が混入することで、突起部の強度がさらに高くなる。
In the method for producing a molded article of the present invention described above, after a sheet-like molded body having a fiber reinforced thermoplastic resin layer provided on the surface of the base portion is molded, a protrusion is formed on the surface of the sheet-like molded body by injection molding. Compared with the case of forming, the number of times of molding can be reduced, so that it is easy to manufacture a molded product.
Further, in the present invention, as described above, a part of the thermoplastic resin body flows inside the fiber reinforced thermoplastic resin layer to form a protrusion, so that together with the thermoplastic resin in the fiber reinforced thermoplastic resin layer, Part of the reinforcing fiber is likely to be mixed into the protrusion. Thus, the strength of the protrusions is further increased by mixing the reinforcing fibers into the protrusions.

なお、本発明の成型品の製造方法は、前記した成型品1の製造方法には限定されない。例えば、本発明の成型品の製造方法は、シート状の熱可塑性樹脂体の片面のみに繊維強化熱可塑性樹脂層を設けた成型材料を用いて、シート状の基体部の片面のみに繊維強化熱可塑性樹脂層が設けられた成型品を製造する方法であってもよい。
本発明の成型品の製造方法により、シート状の基体部を有する成型品を製造する場合は、得られる成型品が反り難く、またより高い強度の成型品が得られやすい点から、シート状の熱可塑性樹脂体の両面に繊維強化熱可塑性樹脂層が配置された成型材料を用いる方法が好ましい。
また、本発明の成型品の製造方法は、シート状以外の形状を有する基体部を有する成型品を製造する方法であってもよい。
In addition, the manufacturing method of the molded product of the present invention is not limited to the manufacturing method of the molded product 1 described above. For example, the method for producing a molded product according to the present invention uses a molding material in which a fiber-reinforced thermoplastic resin layer is provided only on one side of a sheet-like thermoplastic resin body, and fiber-reinforced heat is applied only on one side of a sheet-like base portion. It may be a method for producing a molded article provided with a plastic resin layer.
When a molded product having a sheet-like base portion is produced by the method for producing a molded product of the present invention, the molded product obtained is less likely to warp, and a molded product having a higher strength is easily obtained. A method of using a molding material in which a fiber reinforced thermoplastic resin layer is disposed on both surfaces of a thermoplastic resin body is preferable.
The method for producing a molded product of the present invention may be a method for producing a molded product having a base portion having a shape other than a sheet shape.

また、本発明の成型品の製造方法では、成型材料を形成する熱可塑性樹脂体や繊維強化熱可塑性樹脂層をそれぞれ別々に加熱した後、成型工程に用いる型においてそれらを積層して成型材料を形成してもよい。
また、本発明の成型品の製造方法は、予熱工程を行わずに、成型工程において熱可塑性樹脂体を流動可能な温度まで加熱できる温度に調温された金型によってプレス成型し、該金型を冷却して成型材料を固化させた後に金型を開いて成型品を取り出す方法であってもよい。ただし、生産性の点から、本発明の成型品の製造方法は、前記した予熱工程および成型工程を有する方法が好ましい。
In the method for producing a molded article of the present invention, the thermoplastic resin body and the fiber reinforced thermoplastic resin layer forming the molding material are separately heated, and then laminated in a mold used in the molding process to obtain the molding material. It may be formed.
In addition, the method for producing a molded product of the present invention includes press molding with a mold adjusted to a temperature at which the thermoplastic resin body can be heated to a flowable temperature in the molding process without performing the preheating process. The mold may be opened after the mold is cooled to solidify the molding material, and the molded product may be taken out. However, from the viewpoint of productivity, the method for producing a molded product of the present invention is preferably a method having the above-described preheating step and molding step.

以下、実施例によって本発明を詳細に説明するが、本発明は以下の記載によっては限定されない。
[突起部の強度評価]
突起部をペンチで把持し、これを捻ることで突起部の根元を破壊し、これに要する力の度合いで突起部の強度を評価した。
EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited by the following description.
[Evaluation of protrusion strength]
The protrusion was gripped with pliers and twisted to break the root of the protrusion, and the strength of the protrusion was evaluated based on the degree of force required for this.

[実施例1]
図3に例示した成型材料1Aの熱可塑性樹脂体10Aとして、ポリプロピレン(商品名「ノバテックPP FY4」、日本ポリプロ社製)からなる170mm×120mm×2.0mmのシート状の熱可塑性樹脂体を作成した。また、繊維強化熱可塑性樹脂層16,18として、炭素繊維(商品名「パイロフィル TR50S」、三菱レイヨン社製)からなる長繊維を一方向に引き揃えた強化繊維に酸変性ポリプロピレン(商品名「モディック P958V」、三菱化学社製)を含浸させ、これを直交積層することで、強化繊維の体積含有率が33%、170mm×120mm×0.25mmのシート状の繊維強化熱可塑性樹脂層を作成した。
[Example 1]
As the thermoplastic resin body 10A of the molding material 1A illustrated in FIG. 3, a sheet-shaped thermoplastic resin body of 170 mm × 120 mm × 2.0 mm made of polypropylene (trade name “NOVATEC PP FY4”, manufactured by Nippon Polypro Co., Ltd.) is prepared. did. In addition, as the fiber reinforced thermoplastic resin layers 16 and 18, acid-modified polypropylene (trade name “MODIC” is used as a reinforced fiber in which long fibers made of carbon fiber (trade name “Pyrofil TR50S”, manufactured by Mitsubishi Rayon Co., Ltd.) are aligned in one direction. P958V "(manufactured by Mitsubishi Chemical Corporation) was impregnated and orthogonally laminated to create a sheet-like fiber-reinforced thermoplastic resin layer having a volume content of reinforcing fibers of 33% and 170 mm x 120 mm x 0.25 mm .

次いで、得られた繊維強化熱可塑性樹脂層18、熱可塑性樹脂体10Aおよび繊維強化熱可塑性樹脂層16をこの順に積層して成型材料1Aとし、該成型材料1Aを赤外線加熱炉によって240℃に予熱した。その後、予熱した成型材料1Aを図4に例示した金型100の下型110上に移し、上型112を降下させて金型100を閉じてプレス成型し、成型品1を得た。該プレス成型における金型100の温度は130℃、成型圧力は22MPa、成型時間は2分とした。基体部12の厚みは1.0mm、突起部14の高さは5mmであった。
得られた成型品1は、突起部14の強度が高かった。
Subsequently, the obtained fiber reinforced thermoplastic resin layer 18, the thermoplastic resin body 10A, and the fiber reinforced thermoplastic resin layer 16 are laminated in this order to form a molding material 1A, and the molding material 1A is preheated to 240 ° C. by an infrared heating furnace. did. Thereafter, the preheated molding material 1A was transferred onto the lower mold 110 of the mold 100 illustrated in FIG. 4, the upper mold 112 was lowered, the mold 100 was closed, and press molding was performed to obtain the molded product 1. The temperature of the mold 100 in the press molding was 130 ° C., the molding pressure was 22 MPa, and the molding time was 2 minutes. The base portion 12 had a thickness of 1.0 mm, and the protrusion 14 had a height of 5 mm.
The obtained molded product 1 had a high strength of the protrusion 14.

[比較例1]
熱可塑性樹脂体10Aの厚みを1.0mmとした以外は実施例1と同様の成型材料を作成し、金型により温度130℃、圧力22MPaの条件で加熱加圧して、170mm×120mm×1.5mmのシート状の成型体を得た。次いで、射出成型金型に前記成型体を設置し、シリンダー温度200℃、金型温度80℃の条件でポリプロピレン(商品名「ノバテックPP FY4」、日本ポリプロ社製)を射出成型し、前記成型体の繊維強化熱可塑性樹脂層上に突起部を形成し、成型品1と同様の形状の成型品を得た。
得られた成型品の突起部は、実施例1の成型品1の突起部14に比べて根元を破壊するのに要する力が小さくて済み、強度が劣っていた。
[Comparative Example 1]
A molding material similar to that of Example 1 was prepared except that the thickness of the thermoplastic resin body 10A was 1.0 mm, and heated and pressurized by a mold under the conditions of a temperature of 130 ° C. and a pressure of 22 MPa, and 170 mm × 120 mm × 1. A 5 mm sheet-like molded body was obtained. Next, the molded body is placed in an injection mold, and polypropylene (trade name “Novatech PP FY4”, manufactured by Nippon Polypro Co., Ltd.) is injection molded under the conditions of a cylinder temperature of 200 ° C. and a mold temperature of 80 ° C. A protrusion was formed on the fiber reinforced thermoplastic resin layer to obtain a molded product having the same shape as the molded product 1.
The projecting portion of the obtained molded product required less force to break the root than the projecting portion 14 of the molded product 1 of Example 1, and was inferior in strength.

1 成型品
10 熱可塑性樹脂成型体
12 基体部
14 突起部
16,18 繊維強化熱可塑性樹脂層
DESCRIPTION OF SYMBOLS 1 Molded article 10 Thermoplastic resin molding 12 Base part 14 Protrusion part 16, 18 Fiber reinforced thermoplastic resin layer

Claims (6)

基体部および該基体部から突出する突起部を有する熱可塑性樹脂成型体と、前記基体部における少なくとも一部の表面に配置された繊維強化熱可塑性樹脂層と、を有し、
前記突起部が前記繊維強化熱可塑性樹脂層を貫通して突き出ている、成型品。
A thermoplastic resin molded body having a base portion and a protruding portion protruding from the base portion, and a fiber-reinforced thermoplastic resin layer disposed on at least a part of the surface of the base portion,
A molded product in which the protrusion protrudes through the fiber-reinforced thermoplastic resin layer.
前記基体部がシート状であり、前記繊維強化熱可塑性樹脂層が前記基体部の両面にそれぞれ配置されている、請求項1に記載の成型品。   The molded article according to claim 1, wherein the base portion is in a sheet form, and the fiber reinforced thermoplastic resin layers are respectively disposed on both sides of the base portion. 前記繊維強化熱可塑性樹脂層を形成する強化繊維が長繊維である、請求項1または2に記載の成型品。   The molded article according to claim 1 or 2, wherein the reinforcing fibers forming the fiber-reinforced thermoplastic resin layer are long fibers. 請求項1に記載された成型品の製造方法であって、
前記熱可塑性樹脂成型体の形成に用いる熱可塑性樹脂体の少なくとも一部の表面に繊維強化熱可塑性樹脂層が配置された成型材料を、型によって成型し、前記熱可塑性樹脂体の一部を前記繊維強化熱可塑性樹脂層の表面側へ流動させて前記突起部を形成する成型工程を有する、成型品の製造方法。
A method for producing a molded product according to claim 1,
A molding material in which a fiber reinforced thermoplastic resin layer is disposed on at least a part of the surface of the thermoplastic resin body used for forming the thermoplastic resin molded body is molded by a mold, and a part of the thermoplastic resin body is The manufacturing method of a molded article which has a shaping | molding process which is made to flow to the surface side of a fiber reinforced thermoplastic resin layer, and forms the said projection part.
前記成型材料が、シート状の前記熱可塑性樹脂体の両面に繊維強化熱可塑性樹脂層が配置された成型材料である、請求項4に記載の成型品の製造方法。   The manufacturing method of the molded article of Claim 4 whose said molding material is a molding material by which the fiber reinforced thermoplastic resin layer is arrange | positioned on both surfaces of the said sheet-like thermoplastic resin body. 前記繊維強化熱可塑性樹脂層を形成する強化繊維が長繊維である、請求項4または5に記載の成型品の製造方法。   The manufacturing method of the molded article of Claim 4 or 5 whose reinforced fiber which forms the said fiber reinforced thermoplastic resin layer is a long fiber.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015083707A1 (en) * 2013-12-03 2015-06-11 三菱レイヨン株式会社 Fiber-reinforced resin laminate
JP2016221885A (en) * 2015-06-01 2016-12-28 富士重工業株式会社 Fiber-reinforced resin structure and manufacturing process thereof
KR102324587B1 (en) * 2021-02-01 2021-11-10 주식회사 아이에프엘 First row seatback covers for automobiles using fibrous composite materials and their manufacturing methods

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JPS62216710A (en) * 1986-03-19 1987-09-24 Meiwa Sangyo Kk Manufacture of composite molded product
JP2006327465A (en) * 2005-05-27 2006-12-07 Fts:Kk Fuel tank for automobile its manufacturing method

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Publication number Priority date Publication date Assignee Title
JPS62216710A (en) * 1986-03-19 1987-09-24 Meiwa Sangyo Kk Manufacture of composite molded product
JP2006327465A (en) * 2005-05-27 2006-12-07 Fts:Kk Fuel tank for automobile its manufacturing method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015083707A1 (en) * 2013-12-03 2015-06-11 三菱レイヨン株式会社 Fiber-reinforced resin laminate
JP2016221885A (en) * 2015-06-01 2016-12-28 富士重工業株式会社 Fiber-reinforced resin structure and manufacturing process thereof
KR102324587B1 (en) * 2021-02-01 2021-11-10 주식회사 아이에프엘 First row seatback covers for automobiles using fibrous composite materials and their manufacturing methods

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