JP2015002690A - Method of manufacturing noodle, and noodle - Google Patents

Method of manufacturing noodle, and noodle Download PDF

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JP2015002690A
JP2015002690A JP2013128835A JP2013128835A JP2015002690A JP 2015002690 A JP2015002690 A JP 2015002690A JP 2013128835 A JP2013128835 A JP 2013128835A JP 2013128835 A JP2013128835 A JP 2013128835A JP 2015002690 A JP2015002690 A JP 2015002690A
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starch
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noodle
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JP5431607B1 (en
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茜 奥田
Akane Okuda
茜 奥田
岳史 藤村
Takeshi Fujimura
岳史 藤村
竜一 安東
Ryuichi Ando
竜一 安東
俊久 田口
Toshihisa Taguchi
俊久 田口
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Japan Maize Products Co Ltd
Nihon Shokuhin Kako Co Ltd
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Nihon Shokuhin Kako Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a method of manufacturing a noodle capable of imparting a food texture which is equal to or better than the case of using high price hydroxypropyl starch even when using acetylated starch low in a production cost for a noodle using a brine such as a Chinese noodle, and a noodle manufactured by the method.SOLUTION: The noodle is manufactured by blending 100 pts.mass of a total amount of a cereal flour and starch containing in a noodle raw material, and 1.8-3.0 pts.mass of a brine using the noodle raw material containing acetylated starch. A raw material starch of the acetylated starch is preferably tapioca starch.

Description

本発明は、アセチル化澱粉を含有する麺原料に、かんすいを添加する麺の製造方法および該方法で得られる麺に関する。   The present invention relates to a method for producing noodles in which kansui is added to a raw material for noodles containing acetylated starch, and noodles obtained by the method.

従来、麺類を製造する際に製麺性の向上、保存性の向上、食味の向上、収量の向上、変色防止および色相の向上等の目的で、澱粉、増粘剤、グルテン、乳化剤等の添加物が用いられている。また、中華麺においては、かんすいを加えることで、独特の滑らかさとつやがあり、適度な粘弾性と歯応えのある食感を与えることができる。   Conventionally, when producing noodles, starch, thickener, gluten, emulsifier, etc. are added for the purpose of improving noodle-making properties, improving storage stability, improving taste, improving yield, preventing discoloration and improving hue. Things are used. In addition, Chinese noodles have a unique smoothness and luster by adding kansui, and can provide a texture with moderate viscoelasticity and crunchiness.

麺類の品質向上のため、様々な麺の製造方法が開示されている。例えば、下記特許文献1には、麺類の熱湯復元性や食感の改良目的のために、ヒドロキシプロピル化澱粉やアセチル化澱粉などの化工澱粉を配合して麺類を製造する方法が開示されている。また、下記特許文献2には、タピオカ澱粉にヒドロキシプロピル化またはアセチル化の化工を施すと共に、微量の次亜塩素酸ナトリウムにより処理することによって得られた化工澱粉を配合することで、弾力、モチモチ感に優れた麺類を製造する方法が開示されている。また、下記特許文献3には、ヒドロキシプロピル化リン酸架澱粉やアセチル化リン酸架橋澱粉などのリン酸架橋化工澱粉を配合すると共に、熱凝固性蛋白質素材を配合することで、長期保存による品質の劣化がほとんど見られない麺類を製造する方法が開示されている。   Various methods for producing noodles have been disclosed for improving the quality of noodles. For example, Patent Document 1 below discloses a method for producing noodles by blending a modified starch such as hydroxypropylated starch or acetylated starch for the purpose of improving the hot water restoration property and texture of the noodles. . Further, in Patent Document 2, the tapioca starch is subjected to hydroxypropylation or acetylation, and by blending a modified starch obtained by treating with a small amount of sodium hypochlorite, elasticity, A method for producing noodles excellent in feeling is disclosed. In addition, in Patent Document 3 below, by blending a phosphate cross-linked starch such as hydroxypropylated phosphoric acid crosslinked starch or acetylated phosphoric acid cross-linked starch, and by blending a thermocoagulable protein material, quality by long-term storage Has disclosed a method for producing noodles in which the deterioration of the material is hardly observed.

更に、下記特許文献4には、小麦粉60〜95重量部に、サゴ澱粉、馬鈴薯澱粉および/または緑豆澱粉のエーテル化および/またはエステル化誘導体40〜5重量部を混合し、これにかんすいを加えて混練することを特徴とする生中華麺の製造方法の発明が開示されている。これにより、保存性に優れ、かつ食感の良好な生中華麺が得られることが記載されている。また、かんすいは、ボーメ2〜5度のものであれば、小麦粉と澱粉誘導体の合計量を100重量部としたとき、27〜35重量部(固形分に換算すると0.65重量部〜1.4重量部に相当)添加するのが望ましいことが記載されている(特許文献4の段落0009参照)。   Further, in Patent Document 4 below, 60 to 95 parts by weight of wheat flour is mixed with 40 to 5 parts by weight of an etherified and / or esterified derivative of sago starch, potato starch and / or mung bean starch, and then added with kansui. An invention of a method for producing raw Chinese noodles characterized by kneading and kneading is disclosed. Thus, it is described that raw Chinese noodles having excellent storability and good texture can be obtained. Moreover, if the pan is 2-5 degrees of Baume, when the total amount of wheat flour and starch derivative is 100 parts by weight, it is 27 to 35 parts by weight (0.65 parts by weight to 1. (It corresponds to 4 parts by weight) and it is described that it is desirable to add (see paragraph 0009 of Patent Document 4).

なお、かんすいの添加量に関しては、下記非特許文献1に記載されているように、生中華麺のかんすい濃度は小麦粉に対して粉末かんすいで1〜1.2%、皮類のワンタン皮で0.5〜1.2%とするのが一般的である。また、かんすいを必要以上に多く添加すると収斂味やえぐ味が生じ、麺として好ましくないことが知られている。   In addition, as described in Non-Patent Document 1 below, the amount of kansui added is 1 to 1.2% for the powdered rinse of wheat noodles and 0 for the wonton rind of the skin. It is common to set it as 0.5 to 1.2%. Further, it is known that adding too much kansui produces an astringent taste and a savory taste, which is not preferable as noodles.

特公昭62−62137号公報Japanese Patent Publication No.62-62137 特開2005−27643号公報JP 2005-27643 A 特開平10-215803号公報Japanese Patent Laid-Open No. 10-215803 特開平5−316978号公報JP-A-5-316978

新島 繁・柴田 茂久 監修 「▲麺▼類百科事典」第246ページ 発行所 株式会社 食品出版社 昭和59年1月26日 初版発行Supervised by Shigehisa Niijima and Shigehisa Shibata “Noodles ▼ Encyclopedia of Encyclopedia”, page 246 Publication Office Food Publishing Co., Ltd. Published January 26, 1984

中華麺(特にチルド)等の食感の改良のため、ヒドロキシプロピル化澱粉などが用いられるが、ヒドロキシプロピル澱粉は化工反応試薬であるプロピレンオキサイドが非常に高価で、且つ反応効率が悪いことから製造コストが嵩むという問題があった。一方、コストダウンを重視した麺には、比較的製造コストが低いアセチル化澱粉を用いることも多い。しかしながら、アセチル化澱粉では、ヒドロキシプロピル澱粉のようなソフトでしなやかな食感を付与することが困難であった。   Hydroxypropyl starch is used to improve the texture of Chinese noodles (especially chilled). Hydroxypropyl starch is manufactured because propylene oxide, a chemical reaction reagent, is very expensive and has poor reaction efficiency. There was a problem that the cost increased. On the other hand, for noodles where cost reduction is important, acetylated starch with a relatively low production cost is often used. However, with acetylated starch, it has been difficult to impart a soft and supple texture like hydroxypropyl starch.

そこで、本発明の目的は、中華麺のようにかんすいを用いた麺に、製造コストの低いアセチル化澱粉を用いた場合でも、高価なヒドロキシプロピル澱粉を用いた場合と同等以上の食感を付与することができる、麺の製造方法を提供することにある。また、その方法で製造された麺を提供することにある。   Therefore, the object of the present invention is to impart a texture equal to or higher than that when using expensive hydroxypropyl starch, even when using low-cost acetylated starch to noodles using candy like Chinese noodles. An object of the present invention is to provide a method for producing noodles. Moreover, it is providing the noodle manufactured by the method.

本発明者らは、上記課題を解決するために、鋭意検討を重ねた結果、アセチル化澱粉を配合する際、かんすいを通常用いない程多量に添加することで、極めて食感の良好な麺を製造できることを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the present inventors have added noodles with a very good texture by adding so much that citrus is not normally used when blending acetylated starch. The inventors have found that it can be manufactured, and have completed the present invention.

すなわち、本発明の麺の製造方法は、アセチル化澱粉を含有する麺原料を用い、麺原料中に含まれる穀物粉および澱粉の合計量を100質量部としたとき、かんすいを1.8〜3.0質量部配合することを特徴とする。   That is, the method for producing noodles of the present invention uses noodle raw materials containing acetylated starch, and when the total amount of cereal flour and starch contained in the noodle raw materials is 100 parts by mass, It is characterized by containing 0.0 part by mass.

本発明の麺の製造方法においては、前記穀物粉および澱粉の合計量中の前記アセチル化澱粉の含量が5〜45質量%であることが好ましい。   In the manufacturing method of the noodles of this invention, it is preferable that the content of the said acetylated starch in the total amount of the said grain flour and starch is 5-45 mass%.

また、前記アセチル化澱粉のアセチル基含量が1.2〜2.5%であることが好ましい。   The acetyl group content of the acetylated starch is preferably 1.2 to 2.5%.

また、前記アセチル化澱粉は、原料澱粉にアセチル化剤として無水酢酸を処理して得られたものであることが好ましい。   The acetylated starch is preferably obtained by treating raw material starch with acetic anhydride as an acetylating agent.

また、前記アセチル化澱粉の原料澱粉がタピオカ澱粉であることが好ましい。   Moreover, it is preferable that the raw material starch of the acetylated starch is tapioca starch.

一方、本発明のもう1つは、上記の麺の製造方法によって製造された麺を提供するものである。   On the other hand, another aspect of the present invention provides noodles produced by the above-described noodle production method.

本発明の麺の製造方法によれば、製造コストの低いアセチル化澱粉を用いた場合でも、高価なヒドロキシプロピル澱粉を用いた場合と同等以上の食感を麺に付与することができる。より具体的には、麺類のしなやかさやつるみの付与といった食感を改良することができる。更に、本発明の麺の製造方法によって製造された麺は、保存中に麺同士が接着し難いといった利点もある。   According to the method for producing noodles of the present invention, even when acetylated starch having a low production cost is used, the noodles can be given a texture equivalent to or higher than that when expensive hydroxypropyl starch is used. More specifically, it is possible to improve the texture of the noodles, such as the suppleness and the stuffiness. Furthermore, the noodles produced by the method for producing noodles of the present invention also have an advantage that the noodles are difficult to adhere to each other during storage.

本発明の麺の製造方法は、アセチル化澱粉を含有する麺原料を用いて、かんすいを通常用いない程多量に配合することを特徴としている。   The method for producing noodles of the present invention is characterized by using a raw material for noodles containing acetylated starch and blending it in such a large amount that kansui is not usually used.

穀物粉としては、麺の製造に通常使用できるものを用いればよく、例えば、小麦粉(強力粉、準強力粉、中力粉、薄力粉、デュラム小麦)、大麦粉、ライ麦粉、米粉等があげられる。澱粉としては、麺の製造に通常使用できるものを用いればよいが、本発明においては、その一部または全部を下記に説明するアセチル化澱粉が占める必要がある。穀物粉や澱粉は2種以上を併用してもよい。   Grain flour that can be used in the production of noodles may be used, and examples thereof include wheat flour (strong flour, semi-strong flour, medium flour, thin flour, durum wheat), barley flour, rye flour, and rice flour. As starch, what can be normally used for manufacture of noodles may be used, but in the present invention, part or all of the starch must be occupied by acetylated starch described below. Two or more kinds of cereal flour and starch may be used in combination.

かんすいとは、食品衛生法で定義される「かんすい」、すなわち、中華麺類の製造に用いられるアルカリ剤で、炭酸カリウム、炭酸ナトリウム、炭酸水素ナトリウム、リン酸類のカリウム又はナトリウム塩を言い、本発明においてもこれらのものが使用できる。また、本発明に用いられるかんすいには、植物などを燃やした後に生じる灰を水に溶かした上澄み液である「灰汁」も含まれる。ただし、通常市販されているかんすいは、炭酸ナトリウムまたは炭酸カリウム、あるいはこれらの混合物を主剤とする製剤形態ものが一般的で、本発明に用いるかんすいにもこのようなものが好ましく用いられる。また、本明細書においてかんすいの配合量は、一般的に「かんすい」として市販されている物質や製剤の配合量を意味するものとする。かんすいの添加方法としては、原料粉と共に粉体で添加しても、水に溶解、懸濁して練り水として加えてもよい。   “Kansui” is “Kansui” as defined by the Food Sanitation Law, that is, an alkaline agent used in the production of Chinese noodles, which means potassium carbonate, sodium carbonate, sodium bicarbonate, potassium or sodium salt of phosphoric acid, and the present invention. These can also be used in In addition, the rinse used in the present invention also includes “ash juice” which is a supernatant obtained by dissolving ash generated after burning a plant or the like in water. However, generally commercially available cans are generally in the form of a preparation mainly composed of sodium carbonate or potassium carbonate, or a mixture thereof, and such are preferably used for the cans used in the present invention. In addition, in the present specification, the compounding amount of Kansui shall mean the compounding amount of substances and preparations generally marketed as “Kansui”. As a method for adding kansui, powder may be added together with the raw material powder, or it may be dissolved and suspended in water and added as kneaded water.

本発明の麺の製造方法においては、穀物粉および澱粉(アセチル化澱粉を含有)の合計量100質量部に対して、かんすいを1.8〜3.0質量部配合することが必要であり、2.0〜2.8質量部配合することがより好ましい。穀物粉および澱粉の合計量100質量部に対するかんすいの配合量が1.8質量部を下回るとしなやかさが低下し食感劣化に繋がるため好ましくなく、3.0質量部を上回るとかんすい由来の収斂味やえぐ味が発生するため好ましくない。なお、本発明におけるかんすいの配合量は、かんすいの固形分換算での配合量を意味している。   In the method for producing noodles of the present invention, it is necessary to blend 1.8 to 3.0 parts by mass of Kansui with respect to 100 parts by mass of the total amount of cereal flour and starch (containing acetylated starch), It is more preferable to add 2.0 to 2.8 parts by mass. If the blending amount of the cereal with respect to 100 parts by mass of the total amount of cereal flour and starch is less than 1.8 parts by mass, the suppleness is lowered and the texture is deteriorated. This is not preferable because a taste and savory taste occur. In addition, the compounding quantity of the pan in this invention means the compounding quantity in conversion of solid content of the pan.

本発明に用いるアセチル化澱粉は、通常知られたアセチル化剤を用いる方法で調製することが可能である。例えば、アセチル化剤として無水酢酸、酢酸ビニルモノマー、塩化アセチル等を用いてアセチル化澱粉を調製することができる。これらの中でもアセチル化剤として無水酢酸が好ましい。無水酢酸を用いて調製したアセチル化澱粉を用いることで、よりソフトでしなやかな食感を付与することができる。   The acetylated starch used in the present invention can be prepared by a method using a generally known acetylating agent. For example, acetylated starch can be prepared using acetic anhydride, vinyl acetate monomer, acetyl chloride or the like as an acetylating agent. Among these, acetic anhydride is preferable as the acetylating agent. By using acetylated starch prepared with acetic anhydride, a softer and more supple texture can be imparted.

アセチル化澱粉の原料澱粉としては、一般に入手可能な澱粉であればよく、特段限定されるものではない。具体的には、トウモロコシ、コムギ、オオムギ、ライムギ、コメ、サツマイモ(甘藷澱粉)、ジャガイモ(馬鈴薯澱粉)、エンドウ、緑豆、キャッサバ(タピオカ澱粉)、サゴ等の植物から得られる澱粉があげられる。原料澱粉は、1種類を単独で用いてもよいし、2種類以上を併用してもよい。これらの中でもキャッサバの根茎から採取される澱粉(タピオカ澱粉)が好ましい。また、いずれの澱粉においても通常の澱粉に加え、ウルチ種、ワキシー種、ハイアミロース種のように、育種学的手法もしくは遺伝子工学的手法において改良されたものを用いてもよい。   The raw material starch of the acetylated starch is not particularly limited as long as it is a generally available starch. Specific examples include starch obtained from plants such as corn, wheat, barley, rye, rice, sweet potato (sweet potato starch), potato (potato starch), pea, mung bean, cassava (tapioca starch), and sago. Raw material starch may be used individually by 1 type, and may use 2 or more types together. Among these, starch (tapioca starch) collected from cassava rhizome is preferable. Further, in any starch, in addition to ordinary starch, those modified in breeding techniques or genetic engineering techniques such as urch seeds, waxy seeds, and high amylose seeds may be used.

さらに、本発明に用いるアセチル化澱粉は、本発明の効果を損なわない範囲で、上記原料澱粉に、アセチル化以外の加工処理(酸化処理、エーテル化処理、架橋処理といった化学修飾処理や、α化処理、造粒処理、湿熱処理、油脂加工処理、ボールミル処理、微粉砕処理、加熱処理、温水処理、漂白処理、殺菌処理、酸処理、アルカリ処理、酵素処理といった加工処理、あるいはそれらの2種以上の加工処理)を施したものであってもよい。   Furthermore, the acetylated starch used in the present invention is a process other than acetylation (chemical modification treatment such as oxidation treatment, etherification treatment, cross-linking treatment, α-formation, etc.) to the above raw material starch within the range that does not impair the effects of the present invention. Treatment, granulation treatment, wet heat treatment, fat and oil treatment treatment, ball mill treatment, fine pulverization treatment, heating treatment, hot water treatment, bleaching treatment, sterilization treatment, acid treatment, alkali treatment, enzyme treatment, or two or more of them May have been processed).

本発明に用いるアセチル化澱粉のアセチル基含量は、1.2〜2.5%であることが好ましく、1.8〜2.5%であることがより好ましい。アセチル化澱粉のアセチル基含量を1.2%以上とすることにより、後述の実施例から明らかなように、麺のしなやかさ・つるみといった食感を改良することができ、また冷蔵保存による老化を防ぐことができる。更には、保存中に麺同士が接着し難いといった利点もある。なお、アセチル化剤によるアセチル化反応の効率や、食品衛生法の食品、添加物等の規格基準を考慮すれば、アセチル化澱粉のアセチル基含量は2.5%以下とすることが好ましい。   The acetyl group content of the acetylated starch used in the present invention is preferably 1.2 to 2.5%, and more preferably 1.8 to 2.5%. By making the acetyl group content of the acetylated starch 1.2% or more, the texture such as suppleness and sushi of noodles can be improved, as will be apparent from the examples described later, and aging due to refrigerated storage can be achieved. Can be prevented. Furthermore, there is an advantage that the noodles are difficult to adhere to each other during storage. In view of the efficiency of the acetylation reaction by the acetylating agent and the standards of food, additives, etc. of the Food Sanitation Law, the acetyl group content of the acetylated starch is preferably 2.5% or less.

アセチル化澱粉のアセチル基含量はアセチル化剤の添加量、反応温度、反応pH、反応時間等を常法により適宜調整することで調整可能であり、その調製方法に特に制限は無いが、アセチル基含量が1.2〜2.5%のアセチル化澱粉は、例えば、以下の方法で得ることができる。   The acetyl group content of the acetylated starch can be adjusted by appropriately adjusting the addition amount of the acetylating agent, the reaction temperature, the reaction pH, the reaction time, etc. by a conventional method, and the preparation method is not particularly limited. An acetylated starch having a content of 1.2 to 2.5% can be obtained, for example, by the following method.

原料となる澱粉に水を添加して20〜45質量%、好ましくは36〜43質量%の濃度となるスラリー状に調製した後、例えば水酸化ナトリウム、水酸化カルシウム、炭酸ナトリウムなどのアルカリ剤を澱粉スラリーに添加して、pH8〜11、好ましくはpH8.5〜10.5に調整する。次いで、澱粉に対して無水酢酸を3〜9質量%添加した後、澱粉スラリーの温度を10〜45℃、好ましくは20〜40℃、更により好ましくは25〜35℃に保ち、10〜200分間、好ましくは30〜180分間の反応を行う。その後、例えば塩酸などの酸を添加して、澱粉スラリーをpH7.5未満、好ましくはpH3〜7.3、より好ましくはpH5〜7に中和する。以上の処理を行った澱粉スラリーを水で洗浄し、脱水した後、乾燥・篩いがけ・包装する。さらに、前記中和から包装にかけての工程において、pH調整剤を添加することで澱粉を所望のpHに再調整してもよい。   After adding water to starch as a raw material to prepare a slurry having a concentration of 20 to 45% by mass, preferably 36 to 43% by mass, an alkaline agent such as sodium hydroxide, calcium hydroxide, sodium carbonate or the like is added. Add to starch slurry and adjust to pH 8-11, preferably pH 8.5-10.5. Subsequently, after adding 3-9 mass% of acetic anhydride to the starch, the temperature of the starch slurry is kept at 10 to 45 ° C, preferably 20 to 40 ° C, more preferably 25 to 35 ° C, and 10 to 200 minutes. The reaction is preferably performed for 30 to 180 minutes. Then, for example, an acid such as hydrochloric acid is added to neutralize the starch slurry to a pH of less than 7.5, preferably a pH of 3 to 7.3, more preferably a pH of 5 to 7. The starch slurry subjected to the above treatment is washed with water, dehydrated, dried, sieved and packaged. Furthermore, in the process from the neutralization to packaging, the starch may be readjusted to a desired pH by adding a pH adjuster.

アセチル基含量は以下の方法で求めることができる。   The acetyl group content can be determined by the following method.

澱粉試料5.0gを精密に量り、水50mLに懸濁し、フェノールフタレイン試液数滴を加え、液が微紅色を呈するまで0.1mol/L水酸化ナトリウム溶液を滴下後、0.45mol/L水酸化ナトリウム溶液25mLを正確に加え、温度が30℃以上にならないように注意しながら栓をして30分間激しく振り混ぜる。0.2mol/L塩酸で過量の水酸化ナトリウムを滴定する。終点は液の微紅色が消えるときとする。別に空試験を行い補正する。下記式(1)により遊離アセチル基含量を求め、更に乾燥物換算を行う。   A starch sample (5.0 g) is accurately weighed and suspended in 50 mL of water, a few drops of phenolphthalein test solution is added, and 0.1 mol / L sodium hydroxide solution is added dropwise until the solution turns slightly red, then 0.45 mol / L Add exactly 25 mL of sodium hydroxide solution, cap, and shake vigorously for 30 minutes, being careful not to let the temperature rise above 30 ° C. Titrate excess sodium hydroxide with 0.2 mol / L hydrochloric acid. The end point is when the slight red color of the liquid disappears. Separately, perform a blank test to correct. A free acetyl group content is calculated | required by following formula (1), and also dry matter conversion is performed.

アセチル基含量(%)=(e−f)×n×0.043×100/w…(1)
上記式(1)中、e:空試験滴定量(mL)、f:試料滴定量(mL)、n:0.2mol/L塩酸の力価、w:試料乾燥物重量(g)を意味する。
Acetyl group content (%) = (ef) × n × 0.043 × 100 / w (1)
In the above formula (1), e: blank test titration (mL), f: sample titration (mL), n: titer of 0.2 mol / L hydrochloric acid, w: dry sample weight (g) .

本発明の麺の製造方法において、穀物粉および澱粉の合計量中のアセチル化澱粉の含量は5〜45質量%であることが好ましく、15〜40質量%であることがより好ましい。これにより、後述の実施例から明らかなように、麺のしなやかさ・つるみといった食感をより効果的に改良することができ、また冷蔵保存による老化をより効果的に防ぐことができる。更には、保存中に麺同士が接着し難いといった利点も得られる。   In the noodle manufacturing method of the present invention, the content of acetylated starch in the total amount of cereal flour and starch is preferably 5 to 45% by mass, and more preferably 15 to 40% by mass. Thereby, as will be apparent from examples described later, the texture of noodles can be improved more effectively, and aging caused by refrigeration can be more effectively prevented. Furthermore, there is an advantage that the noodles are difficult to adhere to each other during storage.

本発明の麺の製造方法においては、上記に説明したように、アセチル化澱粉を含有する麺原料を用いて、かんすいを上記で特定した量で配合すること以外は、その他の原料を配合すること等に制限は無い。例えば、上記アセチル化澱粉以外の澱粉、グルテン、蛋白類、油脂類、食塩等の無機塩、糖類、色素、保存料、多糖類等を配合することができる。そして、従来公知の製麺方法に準じて、例えば、麺原料に水を添加して混練し、シート状に圧延して切断する等の方法により、麺を製造することができる。   In the method for producing noodles of the present invention, as described above, other raw materials are blended except that the noodle raw materials containing acetylated starch are blended in the amounts specified above. There is no restriction on the etc. For example, starches other than the acetylated starch, gluten, proteins, fats and oils, inorganic salts such as salt, saccharides, pigments, preservatives, polysaccharides and the like can be blended. And according to a conventionally known noodle making method, for example, noodles can be produced by a method such as adding water to a noodle raw material, kneading, rolling into a sheet and cutting.

本発明の麺の製造方法の適用範囲は、特に限定されるものではなく、ラーメン、冷やし中華、即席ラーメン、やきそば、ちゃんぽん、沖縄そば等に用いられる中華麺やワンタンなど様々な麺に適用可能である。その形態にも特に制限は無く、生麺、茹で麺、蒸し麺、チルド麺、レトルト麺、LL麺、即席麺、乾麺、冷凍麺等のいずれであってもよい。   The scope of application of the method for producing noodles of the present invention is not particularly limited, and can be applied to various noodles such as Chinese noodles and wontons used in ramen, chilled Chinese, instant ramen, yakisoba, champon, Okinawa soba, etc. . There is no particular limitation on the form, and any of raw noodles, boiled noodles, steamed noodles, chilled noodles, retort noodles, LL noodles, instant noodles, dry noodles, frozen noodles and the like may be used.

なお、上記麺類には従来かんすいを添加することが行なわれていたが、その目的は、麺をアルカリ性にすることで中華麺独特の風味を出すこと、麺の粘弾性を強化させること、淡黄色に発色させることなどであった。また、小麦粉のグルテンの水和性が増すため、粘性、伸展性が大きくなり、細い強固な麺をつくり易くするという利点も知られていた。しかしながら、アセチル化澱粉による麺の改良を補助する目的で、かんすいを通常用いない程多量に配合するという発想はなかった。   In addition, it has been conventionally performed to add noodles to the above-mentioned noodles, the purpose of which is to make the noodles alkaline so as to give the Chinese noodles a unique flavor, to enhance the viscoelasticity of the noodles, It was to make it color. Further, since the hydration property of wheat gluten is increased, the viscosity and extensibility are increased, and the advantage of facilitating the production of thin and strong noodles has also been known. However, for the purpose of assisting the improvement of noodles with acetylated starch, there was no idea of blending so much that kansui is not usually used.

本発明のメカニズムの詳細は不明であるが、アセチル化澱粉による麺の食感改良および老化耐性付与に加え、かんすいの効果が損なわれない範囲に茹で麺のpHを保持することにあると考えられる。すなわち、強アルカリ性下では、アセチル化澱粉からアセチル基が遊離し、遊離したアセチル基は酢酸となって茹で麺のpHを低下させる為、アセチル化澱粉を用いると、かんすいの効果が発現し難かったが、かんすい添加量を増加させ、かんすいの効果が得られ易い範囲に茹で麺のpHを保持することで、アセチル化澱粉を使用した場合でも、かんすいの効果が十分に得られ、麺の食感向上等に寄与したと考えられる。尚、本発明での具体的な茹で麺のpHの範囲は8.6〜9.8であるが、これに限らない。   The details of the mechanism of the present invention are unknown, but in addition to improving the texture of noodles and imparting aging resistance with acetylated starch, it is believed to be in maintaining the pH of boiled noodles to the extent that the effect of rinsing is not impaired. . That is, under strong alkalinity, the acetyl group is released from the acetylated starch, and the released acetyl group becomes acetic acid to lower the pH of the boiled noodles. However, by increasing the amount of rinsing and maintaining the pH of the boiled noodles in a range where the rinsing effect is easily obtained, even when acetylated starch is used, the rinsing effect is sufficiently obtained and the noodle texture It is thought that it contributed to improvement. In addition, although the range of the pH of the concrete boiled noodles in this invention is 8.6-9.8, it is not restricted to this.

以下に実施例を挙げて本発明を説明するが、本発明は以下の実施例に限定されるものではない。   EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to the following examples.

[アセチル化澱粉の調製]
(調製方法1)
未加工のタピオカ澱粉300g(乾燥物重量)に水を加えて40質量%濃度の澱粉懸濁液を調製し、3%濃度の水酸化ナトリウムを添加してpH9に調整した。これに、澱粉の乾燥物重量に対して無水酢酸26g(澱粉試料1)、21g(澱粉試料2)、14g(澱粉試料3)、12g(澱粉試料4)、6g(澱粉試料5)をそれぞれ180分間かけて添加しつつ、3%濃度の水酸化ナトリウムを添加することでpH8〜9を維持して攪拌し、アセチル化反応を行った。次いで、9%濃度の塩酸を加えてpH5に調整することで、アセチル化反応を終了して、2Lの水を加えて脱水し、乾燥して下記表1に示す試料1〜5のアセチル化タピオカ澱粉を得た。
[Preparation of acetylated starch]
(Preparation method 1)
Water was added to 300 g (dry matter weight) of raw tapioca starch to prepare a 40 mass% starch suspension, and pH was adjusted to 9 by adding 3% sodium hydroxide. To this, 180 g of acetic anhydride 26 g (starch sample 1), 21 g (starch sample 2), 14 g (starch sample 3), 12 g (starch sample 4), and 6 g (starch sample 5) are each added to the dry weight of starch. While adding over a period of time, 3% concentration of sodium hydroxide was added to maintain pH 8-9, and stirring was carried out to carry out an acetylation reaction. Next, 9% concentration hydrochloric acid was added to adjust the pH to 5 to complete the acetylation reaction, 2 L of water was added for dehydration, drying, and acetylated tapioca of samples 1 to 5 shown in Table 1 below. Starch was obtained.

(調製方法2)
未加工のタピオカ澱粉300g(乾燥物重量)に水を加えて40質量%濃度の澱粉懸濁液を調製し、炭酸ナトリウムを添加してpH10に調整した。これに、澱粉の乾燥物重量に対して酢酸ビニルモノマー6g(澱粉試料6)、5g(澱粉試料7)、4.5g(澱粉試料8)をそれぞれ添加し、30分間攪拌を維持した。次いで、9%塩酸を加えてpH5に調整することでアセチル化反応を終了して、2Lの水を加えて脱水し、乾燥して下記表1に示す試料6〜8のアセチル化タピオカ澱粉を得た。
(Preparation method 2)
Water was added to 300 g (dry matter weight) of raw tapioca starch to prepare a starch suspension having a concentration of 40% by mass, and sodium carbonate was added to adjust the pH to 10. The vinyl acetate monomer 6g (starch sample 6), 5g (starch sample 7), and 4.5g (starch sample 8) were added to this with respect to the dry substance weight of starch, respectively, and stirring was maintained for 30 minutes. Next, 9% hydrochloric acid was added to adjust the pH to 5 to complete the acetylation reaction, 2 L of water was added to dehydrate, and dried to obtain samples 6 to 8 of acetylated tapioca starch shown in Table 1 below. It was.

調製方法1および調製方法2で調製した澱粉試料1〜8のアセチル化澱粉に関し、そのアセチル基含量を測定した結果を表1に纏めた。   Table 1 summarizes the results of measuring the acetyl group content of the acetylated starches of the starch samples 1 to 8 prepared by Preparation Method 1 and Preparation Method 2.

[試験例1]
上記澱粉試料1を用い、表2に示す配合の中華麺を調製した(試験区1〜13)。すなわち、A群の原材料に予め混合・溶解したB群の原材料を添加して、混練し、麺帯を形成させ、1時間熟成した後に圧延(1.4mm厚)し、切り歯(#20)にて切り出した。切り出し後の麺線100gをそれぞれ2Lの熱湯中で、歩留まり180%まで茹でた。なお、かんすいとしては、オリエンタル酵母製「かんすいCS」(商品名)を用いた。
[Test Example 1]
Chinese starch noodles with the composition shown in Table 2 were prepared using the starch sample 1 (test groups 1 to 13). That is, Group B raw materials mixed and dissolved in advance are added to Group A raw materials, kneaded to form a noodle band, aged for 1 hour, rolled (1.4 mm thick), and incisors (# 20) Cut out at 100 g of the cut noodle strings were each boiled in 2 L of hot water to a yield of 180%. In addition, "kansui CS" (trade name) manufactured by Oriental Yeast was used as the Kansui.

茹でた中華麺について流水でぬめりを取った後に氷水で冷やし、ほぐれ剤(理研ビタミン製「エマテックW−700」)を2%添加し、5℃にて1日間および2日間保存した後にそれぞれ評価した。評価はソフトさ、しなやかさ、味の総合評価について5名のパネラーによる平均値を算出し、1〜10の10段階で行なった。硬くごわつきのある、味の良好でないもの程1に近い評価、ソフトでしなやかで味の良好なもの程10に近い評価とした。結果を表2に示す。   Boiled Chinese noodles were rinsed with running water, then cooled with ice water, 2% of a loosening agent ("Ematech W-700" manufactured by Riken Vitamin) was added, and the samples were evaluated after storage at 5 ° C for 1 day and 2 days, respectively. . The evaluation was performed in 10 steps from 1 to 10 by calculating an average value by five panelists for the overall evaluation of softness, suppleness, and taste. Hard and stiff, unfavorable taste was evaluated as close to 1, and soft, supple and good taste was evaluated as close to 10. The results are shown in Table 2.

また、氷水で冷やした茹で中華麺について、pH測定を実施した。pH測定は、麺5gに蒸留水45gを加えてホモジナイズし、得られた懸濁液のpHを測定することにより行なった。結果を表2に示す。   Moreover, pH measurement was performed about the boiled Chinese noodles boiled with ice water. The pH was measured by adding 45 g of distilled water to 5 g of noodle and homogenizing, and measuring the pH of the resulting suspension. The results are shown in Table 2.

表2に示されるように、アセチル化澱粉と準強力粉の合計量100質量部に対してかんすいを1.8〜3.0質量部配合した試験区2,3,4,7,9,10,12および13に関しては、麺同士がほぐれやすく、ソフトでしなやかな、好ましい食感を示した。特に試験区7および9はしなやかでつるみのある、良好な食感を示し、非常に好ましかった。一方で、アセチル化澱粉と準強力粉の合計量100質量部に対するかんすいの配合量が1.8質量部未満であった試験区6および11は硬くごわつきがあり、麺として良好でない食感であった。また、アセチル化澱粉と準強力粉の合計量100質量部に対するかんすいの配合量が3.0質量部を上回った試験区5および8は、えぐ味および収斂味が強く、食品として適さない食感であった。   As shown in Table 2, test groups 2, 3, 4, 7, 9, 10, in which 1.8 to 3.0 parts by weight of potassium were blended with respect to 100 parts by weight of the total amount of acetylated starch and semi-strong powder. Regarding Nos. 12 and 13, the noodles were easily loosened, and a soft and supple texture was exhibited. In particular, the test plots 7 and 9 were very preferable because they showed a good texture with a supple and slick texture. On the other hand, the test sections 6 and 11 in which the blending amount of citrus with respect to 100 parts by mass of the total amount of acetylated starch and semi-strong powder was less than 1.8 parts by mass were hard and stiff and had a poor texture as noodles. . Moreover, the test areas 5 and 8 in which the blending amount of Kansai with respect to 100 parts by mass of the total amount of acetylated starch and semi-strong powder exceeds 3.0 parts by mass has a strong taste and astringent taste, and has a texture that is not suitable as a food. there were.

[試験例2]
上記澱粉試料1〜8、市販のヒドロキシプロピル化(HP化と略称することもある)タピオカ澱粉及びヒドロキシプロピル化リン酸架橋タピオカ澱粉を用い、表3に示す配合の中華麺を調製した(試験区14〜25)。すなわち、A群の原材料に予め混合・溶解したB群の原材料を添加して、混練し、麺帯を形成させ、1時間熟成した後に圧延(1.4mm厚)し、切り歯(#20)にて切り出した。切り出し後の麺線100gをそれぞれ2Lの熱湯中で、歩留まり180%まで茹でた。なお、かんすいとしては、オリエンタル酵母製「かんすいCS」(商品名)を用いた。
[Test Example 2]
Using the starch samples 1 to 8, commercially available hydroxypropylated (sometimes abbreviated as HP) tapioca starch and hydroxypropylated phosphate-crosslinked tapioca starch, Chinese noodles having the composition shown in Table 3 were prepared (test group). 14-25). That is, Group B raw materials mixed and dissolved in advance are added to Group A raw materials, kneaded to form a noodle band, aged for 1 hour, rolled (1.4 mm thick), and incisors (# 20) Cut out at 100 g of the cut noodle strings were each boiled in 2 L of hot water to a yield of 180%. In addition, "kansui CS" (trade name) manufactured by Oriental Yeast was used as the Kansui.

茹でた中華麺について流水でぬめりを取った後に氷水で冷やし、ほぐれ剤(理研ビタミン製「エマテックW−700」)を2%添加し、5℃にて1日間および2日間保存した後にそれぞれ評価した。評価はソフトさ、しなやかさ、味の総合評価について5名のパネラーによる平均値を算出し、1〜10の10段階で行なった。硬くごわつきのある、味の良好でないもの程1に近い評価、ソフトでしなやかで味の良好なもの程10に近い評価とした。結果を表3に示す。   Boiled Chinese noodles were rinsed with running water, then cooled with ice water, 2% of a loosening agent ("Ematech W-700" manufactured by Riken Vitamin) was added, and the samples were evaluated after storage at 5 ° C for 1 day and 2 days, respectively. . The evaluation was performed in 10 steps from 1 to 10 by calculating an average value by five panelists for the overall evaluation of softness, suppleness, and taste. Hard and stiff, unfavorable taste was evaluated as close to 1, and soft, supple and good taste was evaluated as close to 10. The results are shown in Table 3.

また、氷水で冷やした茹で中華麺について、pH測定を実施した。pH測定は、麺5gに蒸留水45gを加えてホモジナイズし、得られた懸濁液のpHを測定することにより行なった。結果を表3に示す。   Moreover, pH measurement was performed about the boiled Chinese noodles boiled with ice water. The pH was measured by adding 45 g of distilled water to 5 g of noodle and homogenizing, and measuring the pH of the resulting suspension. The results are shown in Table 3.

表3に示されるように、上記澱粉試料1〜8のアセチル化澱粉を用い、かんすいをアセチル化澱粉と準強力粉の合計量100質量部に対して2.5質量部配合した試験区18〜25に関しては、麺同士がほぐれやすく、ソフトでしなやかな、好ましい食感を示した。特に、アセチル基含量が1.2〜2.5%のアセチル化澱粉を用いた試験区18〜20および試験区23〜25はしなやかでつるみのある、良好な食感を示し、アセチル化剤として無水酢酸を使用したアセチル化澱粉を用いた試験区18〜20が最も好ましい食感を示した。一方で、アセチル化澱粉を配合しないか、澱粉としてヒドロキシプロピル化澱粉またはヒドロキシプロピル化リン酸架橋タピオカ澱粉を用いて、これに配合するかんすいの配合割合を、上記試験区18〜25と同様とした試験区14,15および17では、えぐ味および収斂味が強く、食品として適さない食感であった。   As shown in Table 3, using the acetylated starch of the above starch samples 1 to 8, test sections 18 to 25 in which 2.5 parts by mass of Kansai was added to 100 parts by mass of the total amount of acetylated starch and semi-strong powder. In regard to, the noodles were easily loosened and showed a soft and supple texture. In particular, the test sections 18 to 20 and the test sections 23 to 25 using acetylated starch having an acetyl group content of 1.2 to 2.5% show a supple and slick, good texture, and are used as acetylating agents. Test groups 18-20 using acetylated starch using acetic anhydride showed the most preferable texture. On the other hand, acetylated starch is not blended, or hydroxypropylated starch or hydroxypropylated phosphoric acid cross-linked tapioca starch is used as starch, and the blending ratio of the pan to be blended therein is the same as that in the above test sections 18-25. In the test plots 14, 15 and 17, the savory taste and astringent taste were strong, and the texture was not suitable for food.

Claims (6)

アセチル化澱粉を含有する麺原料を用い、麺原料中に含まれる穀物粉および澱粉の合計量を100質量部としたとき、かんすいを1.8〜3.0質量部配合することを特徴とする麺の製造方法。   The noodle raw material containing acetylated starch is used, and the total amount of cereal flour and starch contained in the noodle raw material is 100 parts by mass. A method for producing noodles. 前記穀物粉および澱粉の合計量中の前記アセチル化澱粉の含量が5〜45質量%である請求項1記載の麺の製造方法。   The method for producing noodles according to claim 1, wherein the content of the acetylated starch in the total amount of the cereal flour and starch is 5 to 45 mass%. 前記アセチル化澱粉のアセチル基含量が1.2〜2.5%である請求項1又は2に記載の麺の製造方法。   The method for producing noodles according to claim 1 or 2, wherein the acetylated starch has an acetyl group content of 1.2 to 2.5%. 前記アセチル化澱粉は、原料澱粉にアセチル化剤がとして無水酢酸を処理して得られたものである請求項1〜3に記載の麺の製造方法。   The method for producing noodles according to claim 1, wherein the acetylated starch is obtained by treating raw material starch with acetic anhydride as an acetylating agent. 前記アセチル化澱粉の原料澱粉がタピオカ澱粉である請求項1〜4に記載の麺の製造方法。   The method for producing noodles according to claim 1, wherein the raw starch of the acetylated starch is tapioca starch. 請求項1〜5のいずれか1つに記載の麺の製造方法によって製造された麺。   Noodles produced by the method for producing noodles according to any one of claims 1 to 5.
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