JP2014213521A - Three-dimensional fiber-reinforced composite material - Google Patents

Three-dimensional fiber-reinforced composite material Download PDF

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JP2014213521A
JP2014213521A JP2013092472A JP2013092472A JP2014213521A JP 2014213521 A JP2014213521 A JP 2014213521A JP 2013092472 A JP2013092472 A JP 2013092472A JP 2013092472 A JP2013092472 A JP 2013092472A JP 2014213521 A JP2014213521 A JP 2014213521A
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thread
fiber
laminated
fastening thread
fastening
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俊 久野
Shun Kuno
俊 久野
堀 藤夫
Fujio Hori
藤夫 堀
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Toyota Industries Corp
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Toyota Industries Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/14Making preforms characterised by structure or composition
    • B29B11/16Making preforms characterised by structure or composition comprising fillers or reinforcement
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Moulding By Coating Moulds (AREA)
  • Woven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

PROBLEM TO BE SOLVED: To achieve reduction of a resin accumulation amount in a root part of a sewing thread folded in a loop form and improvement of the fiber volume content at the same time by using a fiber structure formed by binding an at least two-axis oriented laminate fiber layer with a sewing thread and a fastening thread.SOLUTION: A three-dimensional fiber structure 10 serving as a reinforcing base material for three-dimensional fiber-reinforced composite materials is formed by binding two-axis oriented laminate fiber layers 12 composed of in-plane thread layers 11 laminated by means of a sewing thread 13 and a fastening thread 14. The sewing thread 13 includes a folding insertion part 13a which is engaged with the fastening thread arranged on one outermost layer of the laminate fiber layers 12 so as to be folded in a loop form and inserted into the laminate fiber layers and an opposite fastening thread-side arrangement part 13b which is arranged outside the surface of the laminate fiber layers opposite to the surface where the fastening thread are arranged. In the root part 16 of the folded insertion part 13a, an inlet part 13c in the direction toward the fastening thread and an outlet part 13d in the direction of being engaged with the fastening thread and folded are bent in the same direction.

Description

本発明は、三次元繊維強化複合材に係り、詳しくは面内糸層が積層された少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材とする三次元繊維強化複合材に関する。   The present invention relates to a three-dimensional fiber reinforced composite material, and more specifically, a fiber structure formed by binding at least biaxially oriented laminated fiber layers in which in-plane yarn layers are laminated with sewing threads and fastening threads. The present invention relates to a three-dimensional fiber reinforced composite material.

繊維強化複合材は軽量の構造材料として広く使用されている。複合材用の強化基材として三次元織物(三次元繊維構造体)がある。この三次元織物を強化基材として、樹脂をマトリックスとした複合材は航空機、自動車、船舶あるいは一般産業機器の構造用部材として用いられている。三次元織物複合材(三次元繊維強化複合材)は、織布や不織布等の強化繊維に樹脂を含浸硬化して形成した繊維強化複合材と異なり、基準面内に配列された強化繊維(面内配向糸)と交差する方向に配列される厚さ方向糸(面外方向糸)を有する三次元織物を強化基材としている。そのため、面外方向糸を有さない繊維強化複合材に比較して、高い面外方向強度を持つ反面、厚さ方向糸(面外方向糸)の周辺でクラックが発生し易いという品質課題がある。   Fiber reinforced composites are widely used as lightweight structural materials. There is a three-dimensional fabric (three-dimensional fiber structure) as a reinforcing base material for composite materials. A composite material using this three-dimensional woven fabric as a reinforcing base and a resin as a matrix is used as a structural member for aircraft, automobiles, ships, or general industrial equipment. Three-dimensional woven composite materials (three-dimensional fiber reinforced composite materials) are different from fiber reinforced composite materials formed by impregnating and curing resin in reinforced fabrics such as woven fabrics and non-woven fabrics. A three-dimensional woven fabric having thickness direction yarns (out-of-plane direction yarns) arranged in a direction intersecting with the (inner oriented yarn) is used as the reinforcing base material. Therefore, compared to a fiber reinforced composite material that does not have an out-of-plane direction yarn, it has a high out-of-plane direction strength, but there is a quality problem that cracks are likely to occur around the thickness direction yarn (out-of-plane direction yarn). is there.

この課題に対応するため、積層された面内方向糸の複数の層が有機繊維からなる縫い糸により縫い合わされた三次元織物に樹脂を含浸硬化してなる三次元繊維強化樹脂複合材が提案されている。(特許文献1参照)。特許文献1の三次元繊維強化樹脂複合材は、図7に示すように、複数の経糸51と複数の緯糸52からなる面内方向糸53と、面内方向糸53の基準面に対して直交する複数の面外方向糸(縫い糸)54と、面外方向糸54を固定する耳糸(留め糸)55とから形成される平板状三次元織布56に樹脂を含浸し、加熱加圧処理して硬化することで形成される。面外方向糸54は1000デニール以下のものが使用される。   In order to cope with this problem, a three-dimensional fiber reinforced resin composite material is proposed in which a resin is impregnated and cured in a three-dimensional fabric in which a plurality of layers of laminated in-plane direction yarns are stitched together with sewing threads made of organic fibers. Yes. (See Patent Document 1). As shown in FIG. 7, the three-dimensional fiber reinforced resin composite material of Patent Document 1 is orthogonal to the reference plane of the in-plane direction yarn 53 composed of a plurality of warps 51 and a plurality of wefts 52 and the in-plane direction yarn 53. A plate-like three-dimensional woven fabric 56 formed of a plurality of out-of-plane direction threads (sewing threads) 54 and ear threads (fastening threads) 55 for fixing the out-of-plane direction threads 54 is impregnated with resin, and heated and pressurized. And then cured. As the out-of-plane direction yarn 54, one having 1000 denier or less is used.

特開2007−152672号公報JP 2007-152672 A

特許文献1の三次元繊維強化樹脂複合材は、面外方向糸54に有機繊維を使用することにより、無機繊維に比べてマトリックス樹脂と熱的性質が近く、クラックの原因となる内部ひずみが減少する。また、1000デニール以下の細い糸を使用することにより、図7に矢印A,Bで示す箇所、即ち面外方向糸54のループ内や面外方向糸54及び耳糸55の太さ分生じる治具と面内方向糸53の隙間における樹脂溜まりを減少させる方策として有効である。   The three-dimensional fiber reinforced resin composite material of Patent Document 1 uses an organic fiber for the out-of-plane direction yarn 54, so that it has a thermal property closer to that of the matrix resin than inorganic fibers, and reduces internal strain that causes cracks. To do. Further, by using a thin thread having a denier of 1000 denier or less, a treatment indicated by the thicknesses of the loops of the out-of-plane direction thread 54 and the thickness of the out-of-plane direction thread 54 and the ear thread 55 is shown by arrows A and B in FIG. This is effective as a measure for reducing the resin pool in the gap between the tool and the in-plane direction thread 53.

ところが、これらの対策では、図7において矢印Cで示す部分、即ち面外方向糸54の根元部の樹脂溜まりを減少させる方策としては、面外方向糸54の張力を上げられないという背反が伴い有効ではない。また、面外方向糸54の張力を上げることができないと、一般的な構造用CFRP(炭素繊維強化樹脂)材の繊維体積含有率(Vf55%程度)を実現できないという問題がある。   However, in these measures, as a measure for reducing the resin pool in the portion indicated by the arrow C in FIG. 7, that is, the root portion of the out-of-plane direction yarn 54, there is a contradiction that the tension of the out-of-plane direction yarn 54 cannot be increased. It is not valid. Further, if the tension of the out-of-plane direction thread 54 cannot be increased, there is a problem that the fiber volume content (about Vf 55%) of a general structural CFRP (carbon fiber reinforced resin) material cannot be realized.

また、面外方向糸54は、積層繊維層の各繊維層と直交する方向に延び、かつ耳糸55と係合してループ状に折り返して配列された部分と、積層繊維層の耳糸55の側と反対側の表層に沿って配列された部分とを有する。そのため、平板状三次元織布56の製造工程において面外方向糸54を引き締める際に、面外方向糸54の耳糸55と係合してループ状に折り返して配列された部分の根元部において、積層繊維層の耳糸55の側と反対側の表層に沿って配列される部分が、面外方向糸54の間隔を拡げるように作用する。その結果、平板状三次元織布56は、面外方向糸54の根元部の間隔が広がった状態となり、平板状三次元織布56を強化基材として繊維強化複合材(繊維強化樹脂)を形成すると、面外方向糸54の根元部の樹脂溜まり量が多くなり、樹脂溜まりの部分からクラックが発生し易くなる。   Further, the out-of-plane direction thread 54 extends in a direction orthogonal to each fiber layer of the laminated fiber layer, engages with the ear thread 55, and is looped back and arranged, and the ear thread 55 of the laminated fiber layer. And a portion arranged along the surface layer on the opposite side. Therefore, when the out-of-plane direction thread 54 is tightened in the manufacturing process of the flat plate-like three-dimensional woven fabric 56, it is engaged with the ear thread 55 of the out-of-plane direction thread 54 and folded at the root portion of the looped portion. The portion arranged along the surface layer opposite to the ear yarn 55 side of the laminated fiber layer acts so as to widen the spacing between the out-of-plane direction yarns 54. As a result, the flat plate-like three-dimensional woven fabric 56 is in a state in which the distance between the root portions of the out-of-plane direction yarns 54 is widened, and a fiber-reinforced composite material (fiber-reinforced resin) is formed using the flat plate-like three-dimensional woven fabric 56 as a reinforcing base material. When formed, the amount of the resin pool at the base portion of the out-of-plane direction thread 54 increases, and cracks are likely to occur from the resin pool portion.

本発明は、前記の問題に鑑みてなされたものであって、その目的は、少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材として使用し、ループ状に折り返す縫い糸の根元部の樹脂溜まり量の減少と繊維体積含有率の向上とを両立させることができる三次元繊維強化複合材を提供することにある。   The present invention has been made in view of the above problems, and its purpose is to use a fiber structure formed by binding a laminated fiber layer that is at least biaxially oriented with a sewing thread and a fastening thread as a reinforcing base material. It is an object of the present invention to provide a three-dimensional fiber reinforced composite material that can be used to achieve both a reduction in the amount of resin pool at the base of a sewing thread that is folded back into a loop and an improvement in the fiber volume content.

上記課題を解決する三次元繊維強化複合材は、面内糸層が積層された少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材とする三次元繊維強化複合材である。そして、前記繊維構造体は、前記留め糸が前記積層繊維層のいずれか一方の最外層上に配列されている。前記縫い糸は、前記留め糸と係合してループ状に折り返して前記積層繊維層に挿入された折り返し挿入部と、前記積層繊維層の前記留め糸が配列された側と反対側の面の外側に配列された反留め糸側配列部とを有し、前記折り返し挿入部の根元部において、前記留め糸に向かう方向の入側部と、前記留め糸に係合して折り返してくる方向の出側部とが同一方向に屈曲されている。   A three-dimensional fiber reinforced composite material that solves the above-described problem is a fiber structure formed by binding a laminated fiber layer having at least biaxial orientation in which in-plane yarn layers are laminated with a sewing thread and a fastening thread as a reinforcing base material. It is a three-dimensional fiber reinforced composite. And as for the said fiber structure, the said thread is arranged on the outermost layer of any one of the said laminated fiber layers. The sewing thread is engaged with the fastening thread, folded back in a loop shape and inserted into the laminated fiber layer, and the outer side of the surface of the laminated fiber layer opposite to the side where the fastening thread is arranged. And at the base part of the folded back insertion part, an entry side part in the direction toward the fastening thread and an output in the direction of folding back by engaging with the fastening thread. The side part is bent in the same direction.

この構成によれば、強化基材となる繊維構造体の製造工程において、積層繊維層を留め糸と協同して結束する縫い糸を引き締める際に、積層繊維層の留め糸の側と反対側の表層に沿って配列される縫い糸の反留め糸側配列部が、縫い糸の折り返し挿入部の根元部において、縫い糸の間隔を拡げるように作用しない。したがって、少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材として使用した三次元繊維強化複合材において、ループ状に折り返す縫い糸の根元部の樹脂溜まり量の減少と繊維体積含有率の向上とを両立させることができる。   According to this configuration, when tightening the sewing thread that binds the laminated fiber layer in cooperation with the fastening thread in the manufacturing process of the fiber structure that becomes the reinforcing base, the surface layer on the opposite side of the fastening thread side of the laminated fiber layer The anti-fastening thread side arrangement part of the sewing thread arranged along the line does not act so as to widen the interval of the sewing thread at the root part of the return insertion part of the sewing thread. Therefore, in a three-dimensional fiber reinforced composite material using a fiber structure formed by binding a laminated fiber layer that is at least biaxially oriented with a sewing thread and a fastening thread as a reinforcing base material, It is possible to achieve both a reduction in the amount of resin pool and an improvement in the fiber volume content.

前記縫い糸は、前記積層繊維層の幅方向の一方の端部から1ピッチより離れた位置で折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入され、以降の挿入位置が3ピッチ先の位置と、前記3ピッチ先の位置から1ピッチ戻る位置とを繰り返さすように挿入されていることが好ましい。この構成によれば、繊維構造体を製造する際、縫い糸の留め糸と係合してループ状に折り返して積層繊維層に挿入された部分が一定ピッチで存在するように縫い糸を積層繊維層に挿入する作業が他の挿入方法に比べて簡単になる。   The sewing thread is inserted in a folded shape at a position apart from one pitch from one end in the width direction of the laminated fiber layer, and then inserted in a folded shape at a position returning by one pitch. It is preferable that the insertion is repeated so as to repeat the previous position and the position returned by one pitch from the position three pitches ahead. According to this configuration, when the fiber structure is manufactured, the sewing thread is formed in the laminated fiber layer so that the portions inserted into the laminated fiber layer are engaged with the fastening thread of the sewing thread, folded back into a loop shape, and inserted into the laminated fiber layer. The insertion work is easier than other insertion methods.

本発明によれば、少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材として使用した三次元繊維強化複合材において、ループ状に折り返す縫い糸の根元部の樹脂溜まり量の減少と繊維体積含有率の向上とを両立させることができる。   According to the present invention, in a three-dimensional fiber reinforced composite material using a fiber structure formed by binding laminated fiber layers that are at least biaxially oriented with a sewing thread and a fastening thread as a reinforcing base material, a sewing thread that is folded back into a loop shape. It is possible to achieve both a reduction in the amount of resin pool at the base of the fiber and an improvement in the fiber volume content.

一実施形態の三次元繊維構造体の模式斜視図。The schematic perspective view of the three-dimensional fiber structure of one Embodiment. 三次元繊維構造体の模式断面図。The schematic cross section of a three-dimensional fiber structure. 縫い糸と留め糸の関係を示す模式図。The schematic diagram which shows the relationship between a sewing thread and a fastening thread. (a)は実施形態の三次元繊維構造体を用いた三次元織繊維強化複合材の模式断面図、(b)は(a)の部分拡大図。(A) is a schematic cross section of the three-dimensional woven fiber reinforced composite material using the three-dimensional fiber structure of the embodiment, and (b) is a partially enlarged view of (a). (a)は従来の三次元繊維構造体を用いた三次元織繊維強化複合材の模式断面図、(b)は(a)の部分拡大図。(A) is a schematic cross section of a three-dimensional woven fiber reinforced composite material using a conventional three-dimensional fiber structure, and (b) is a partially enlarged view of (a). (a),(b)はそれぞれ別の実施形態の縫い糸と留め糸の関係を示す模式図。(A), (b) is a schematic diagram which shows the relationship between the sewing thread | yarn of another embodiment, and a fastening thread, respectively. 従来技術の模式断面図。The schematic cross section of a prior art.

(第1の実施形態)
以下、第1の実施形態を図1〜図5にしたがって説明する。
図1及び図2に示すように、三次元繊維強化複合材の強化基材として使用される繊維構造体としての三次元繊維構造体10は、面内糸層11が積層された少なくとも2軸配向となる積層繊維層12が、縫い糸13と留め糸14とで結束されて構成されている。三次元繊維構造体10は、留め糸14が積層繊維層12のいずれか一方の最外層上に配列されている。
(First embodiment)
Hereinafter, the first embodiment will be described with reference to FIGS.
As shown in FIGS. 1 and 2, the three-dimensional fiber structure 10 as a fiber structure used as a reinforcing base material of a three-dimensional fiber-reinforced composite material has at least biaxial orientation in which in-plane thread layers 11 are laminated. The laminated fiber layer 12 is formed by binding the sewing thread 13 and the fastening thread 14 together. In the three-dimensional fiber structure 10, the fastening thread 14 is arranged on one of the outermost layers of the laminated fiber layer 12.

縫い糸13は、留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aと、積層繊維層12の留め糸14が配列された側と反対側の面の外側に配列された反留め糸側配列部13bとを有する。縫い糸13は、留め糸14と係合してループ状に折り返す折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが同一方向に屈曲されている。縫い糸13の配列面Pzは、留め糸14の配列方向と直交するようになっており、この実施形態では配列面Pzは、配向角0度の面内糸と平行になっている。   The sewing thread 13 engages with the fastening thread 14 and is folded back into a loop shape to be inserted into the laminated fiber layer 12, and on the surface opposite to the side on which the fastening thread 14 of the laminated fiber layer 12 is arranged. And an anti-fastening thread side array portion 13b arranged on the outside. The sewing thread 13 engages with the fastening thread 14 and the entry side 13c in the direction toward the fastening thread 14 at the base part 16 of the folding insertion part 13a that engages with the fastening thread 14 and folds in a loop. The direction exit side 13d is bent in the same direction. The arrangement surface Pz of the sewing thread 13 is orthogonal to the arrangement direction of the fastening thread 14. In this embodiment, the arrangement surface Pz is parallel to the in-plane thread having an orientation angle of 0 degrees.

図3に示すように、この実施形態では、縫い糸13は、積層繊維層12に対して基本的には3ピッチの間隔をおいて折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入されることの繰り返しで構成されている。但し、縫い糸13の積層繊維層12に対する挿入の最初の部分は、積層繊維層12に端部から1ピッチより離れた位置で折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入される。即ち、縫い糸13は、留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aが一定のピッチPで存在するように配列されている。1ピッチは、例えば、3mm程度である。   As shown in FIG. 3, in this embodiment, the sewing thread 13 is basically inserted into the laminated fiber layer 12 in a folded shape at an interval of 3 pitches, and then folded back at a position returning by 1 pitch. It consists of repeated insertions. However, the first part of the sewing thread 13 inserted into the laminated fiber layer 12 is inserted into the laminated fiber layer 12 in a folded shape at a position away from the end by one pitch, and then inserted in a folded shape at a position returning by one pitch. The In other words, the sewing thread 13 is arranged so that the folded insertion portions 13 a that are engaged with the fastening thread 14 and folded back into a loop shape and inserted into the laminated fiber layer 12 exist at a constant pitch P. One pitch is about 3 mm, for example.

図2に示すように、この実施形態では、積層繊維層12は、配向角0度の連続繊維から成る面内糸層11aと、配向角90度の連続繊維から成る面内糸層11bと、配向角45度の連続繊維から成る面内糸層11cと、配向角−45度の連続繊維から成る面内糸層11dとが、所定数積層されて疑似等方性に構成されている。そして、積層繊維層12の厚さ方向の両面にそれぞれ配向角45度の連続繊維から成る面内糸層11c又は配向角−45度の連続繊維から成る面内糸層11dが配列されている。連続繊維は、三次元繊維構造体10の厚さ方向(図2の上下方向)と直交する面内に配列される面内糸となる。   As shown in FIG. 2, in this embodiment, the laminated fiber layer 12 includes an in-plane thread layer 11a made of continuous fibers having an orientation angle of 0 degrees, an in-plane thread layer 11b made of continuous fibers having an orientation angle of 90 degrees, A predetermined number of in-plane thread layers 11c made of continuous fibers with an orientation angle of 45 degrees and in-plane thread layers 11d made of continuous fibers with an orientation angle of -45 degrees are laminated to form a quasi-isotropic property. The in-plane yarn layer 11c made of continuous fibers with an orientation angle of 45 degrees or the in-plane yarn layers 11d made of continuous fibers with an orientation angle of -45 degrees are arranged on both surfaces of the laminated fiber layer 12 in the thickness direction. The continuous fibers become in-plane yarns arranged in a plane orthogonal to the thickness direction of the three-dimensional fiber structure 10 (vertical direction in FIG. 2).

面内糸、縫い糸13及び留め糸14としては、例えば、炭素繊維が使用される。炭素繊維はフィラメント数が数百〜数万本程度であり、要求性能に適した本数の繊維束が選択される。縫い糸13及び留め糸14としては、基本的に同じ太さの繊維束が使用される。また、縫い糸13及び留め糸14は面内糸層11を構成する面内糸と同じ太さであってもよいが、面内糸より細い方が好ましい。   For example, carbon fiber is used as the in-plane thread, the sewing thread 13 and the fastening thread 14. Carbon fiber has a number of filaments of about several hundred to several tens of thousands, and the number of fiber bundles suitable for the required performance is selected. As the sewing thread 13 and the fastening thread 14, fiber bundles having basically the same thickness are used. Further, the sewing thread 13 and the fastening thread 14 may have the same thickness as the in-plane thread constituting the in-plane thread layer 11, but are preferably thinner than the in-plane thread.

次に前記のように構成された三次元繊維構造体10の製造方法の一例を説明する。三次元繊維構造体10は、積層繊維層12に公知の方法、例えば特開平8−218249号公報に開示されている厚さ方向糸(縫い糸)の挿入方法と同様に、先端に孔を有する複数本の挿入針を用いて縫い糸13を挿入する。即ち、積層繊維層12の厚さ方向に、先端に備えた孔に縫い糸13を掛止した複数本の挿入針を、各挿入針の孔が積層繊維層12を貫通するまで挿入した後、各挿入針をわずかに後退させて縫い糸13がループ状になった部分に留め糸14を挿入する。その状態で挿入針を引き戻し、留め糸14に張力を加えた状態で縫い糸13により留め糸14を締め付けて各面内糸層11を結合する。しかし、従来の挿入方法と異なり、挿入針は一定ピッチで順次積層繊維層12に挿入されるのではない。   Next, an example of a manufacturing method of the three-dimensional fiber structure 10 configured as described above will be described. The three-dimensional fiber structure 10 has a plurality of holes having holes at the tip, as in a known method for the laminated fiber layer 12, for example, a thickness direction thread (sewing thread) insertion method disclosed in JP-A-8-218249. The sewing thread 13 is inserted using a book insertion needle. That is, in the thickness direction of the laminated fiber layer 12, after inserting a plurality of insertion needles, each having a sewing thread 13 hooked into a hole provided at the tip, until each insertion needle hole penetrates the laminated fiber layer 12, The insertion needle is retracted slightly, and the retaining thread 14 is inserted into the looped portion of the sewing thread 13. In this state, the insertion needle is pulled back, and the tension thread 14 is tightened by the sewing thread 13 in a state where tension is applied to the retaining thread 14, and the in-plane thread layers 11 are coupled. However, unlike conventional insertion methods, the insertion needles are not sequentially inserted into the laminated fiber layer 12 at a constant pitch.

詳述すると、縫い糸13は、折り返し挿入部13aが先ず図3において、左から2番目のIで示す位置に留め糸14の配列側と反対側から折り返し状に挿入された後、その位置から1ピッチ戻った最も左側のIIで示す位置に挿入される。次にIIで示す位置から3ピッチ先のIII で示す位置に挿入された後、その位置から1ピッチ戻ったIVで示す位置に挿入される。以下、「3ピッチ先」、「1ピッチ戻し」を繰り返すように積層繊維層12に挿入される。なお、縫い糸13が積層繊維層12に対して最初に挿入される位置は、積層繊維層12の端から3ピッチの間隔をおいた位置ではなく、1ピッチ戻る余地のある端からほぼ1ピッチ間隔をおいた位置となる。   More specifically, the sewing thread 13 is inserted into the folded insertion portion 13a at the position indicated by the second I from the left in FIG. It is inserted at the position indicated by II on the leftmost side after returning to the pitch. Next, it is inserted at a position indicated by III, which is three pitches after the position indicated by II, and then inserted by a position indicated by IV which is one pitch back from that position. Thereafter, it is inserted into the laminated fiber layer 12 so as to repeat “3 pitches ahead” and “1 pitch return”. Note that the position at which the sewing thread 13 is first inserted into the laminated fiber layer 12 is not located at a pitch of 3 pitches from the end of the laminated fiber layer 12, but at approximately 1 pitch interval from an end where there is room to return by 1 pitch. It will be the position where you put it.

そして、縫い糸13は、留め糸14と係合してループ状に折り返す折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが同一方向に屈曲する状態で積層繊維層12に挿入された状態になる。   Then, the sewing thread 13 engages with the fastening thread 14 and engages with the fastening thread 14 at the base part 16 of the folding insertion part 13a that engages with the fastening thread 14 and folds in a loop. It will be in the state inserted in the lamination | stacking fiber layer 12 in the state bent to the exit side part 13d of the coming direction in the same direction.

そのため、挿入針を引き戻し、留め糸14に張力を加えた状態で縫い糸13により留め糸14を締め付ける場合、縫い糸13の留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aの根元部16には、図3に矢印Fで示す方向に張力が作用する状態となる。即ち、折り返し状に挿入された折り返し挿入部13aの根元部16の入側部13c及び出側部13dにはその間隔を拡げる方向に張力が作用しない。したがって、縫い糸13及び留め糸14の張力を高めて積層繊維層12に大きな圧縮力を加えた場合、根元部16の目開きを大きくせずに三次元繊維構造体10の繊維体積密度を高めることができる。その結果、三次元繊維構造体10は、縫い糸13の折り返し挿入部13aの根元部16と対応する箇所において、三次元繊維構造体10に樹脂を含浸させた際に樹脂溜まりとなる部分の占める体積が小さくなる。   Therefore, when the insertion needle is pulled back and the fastening thread 14 is tightened by the sewing thread 13 in a state where tension is applied to the fastening thread 14, it engages with the fastening thread 14 of the sewing thread 13 and is folded back into a loop to be inserted into the laminated fiber layer 12. A tension is applied to the root portion 16 of the folded-back insertion portion 13a in the direction indicated by the arrow F in FIG. That is, no tension acts on the entry side portion 13c and the exit side portion 13d of the root portion 16 of the folded insertion portion 13a inserted in a folded shape in the direction of widening the interval. Therefore, when the tension of the sewing thread 13 and the fastening thread 14 is increased and a large compressive force is applied to the laminated fiber layer 12, the fiber volume density of the three-dimensional fiber structure 10 is increased without increasing the opening of the root portion 16. Can do. As a result, in the three-dimensional fiber structure 10, the volume occupied by a portion that becomes a resin pool when the three-dimensional fiber structure 10 is impregnated with resin at a location corresponding to the root portion 16 of the folded insertion portion 13 a of the sewing thread 13. Becomes smaller.

一方、従来技術のように挿入針が一定ピッチで順次積層繊維層12に挿入される縫い糸の挿入方法では、縫い糸13及び留め糸14の張力を高めて積層繊維層12に大きな圧縮力を加える際、縫い糸13の折り返し挿入部13aの根元部16の入側部13c及び出側部13dにはその間隔を拡げる方向に張力が作用する。その結果、三次元繊維構造体10は、縫い糸13の折り返し挿入部13aの根元部16と対応する箇所において、三次元繊維構造体10に樹脂を含浸させた際に樹脂溜まりとなる部分の占める体積が大きくなる。   On the other hand, in the conventional method of inserting a sewing thread in which insertion needles are sequentially inserted into the laminated fiber layer 12 at a constant pitch, when the tension of the sewing thread 13 and the fastening thread 14 is increased to apply a large compressive force to the laminated fiber layer 12. The tension acts on the entry side portion 13c and the exit side portion 13d of the root portion 16 of the folded back insertion portion 13a of the sewing thread 13 in the direction of widening the interval. As a result, in the three-dimensional fiber structure 10, the volume occupied by a portion that becomes a resin pool when the three-dimensional fiber structure 10 is impregnated with resin at a location corresponding to the root portion 16 of the folded insertion portion 13 a of the sewing thread 13. Becomes larger.

三次元繊維構造体10は三次元繊維強化複合材としての三次元繊維強化樹脂の強化基材として使用される。三次元繊維強化樹脂は、三次元繊維構造体10に、例えば、エポキシ樹脂等の熱硬化性樹脂が含浸硬化されて構成される。図4(a),(b)に示すように、実施形態の三次元繊維強化樹脂では、縫い糸13は、留め糸14と係合してループ状に折り返す折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが同一方向に屈曲する状態で積層繊維層12に挿入された状態になる。そして、入側部13c及び出側部13dの目開きが防止された状態で樹脂が含浸硬化されているため、縫い糸13の折り返し挿入部13aの根元部16と対応する箇所における樹脂溜まり17となる部分の占める体積が小さくなる。そのため、樹脂溜まり17の部分からのクラックの発生が、抑制される。   The three-dimensional fiber structure 10 is used as a reinforced base material of a three-dimensional fiber reinforced resin as a three-dimensional fiber reinforced composite material. The three-dimensional fiber reinforced resin is configured by impregnating and curing a three-dimensional fiber structure 10 with, for example, a thermosetting resin such as an epoxy resin. As shown in FIGS. 4A and 4B, in the three-dimensional fiber reinforced resin of the embodiment, the sewing thread 13 is engaged with the fastening thread 14 and folded at the root portion 16 of the folded insertion portion 13a. The entering side portion 13c in the direction toward the clasp 14 and the exit side portion 13d in the direction of engaging and folding back with the clasp 14 are inserted into the laminated fiber layer 12 in a state of bending in the same direction. . Since the resin is impregnated and cured in a state in which the opening of the entry side portion 13c and the exit side portion 13d is prevented, the resin reservoir 17 is formed at a location corresponding to the root portion 16 of the folded insertion portion 13a of the sewing thread 13. The volume occupied by the portion is reduced. Therefore, the occurrence of cracks from the resin reservoir 17 is suppressed.

一方、図5(a),(b)に示すように、従来技術では、縫い糸13が、留め糸14と係合してループ状に折り返す折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが逆方向に屈曲する状態で積層繊維層12に挿入された状態になる。そのため、入側部13c及び出側部13dの目開きが大きくなり、その三次元繊維構造体を強化基材とした三次元繊維強化樹脂では、縫い糸13の折り返し挿入部13aの根元部16と対応する箇所における樹脂溜まり17が大きくなり、樹脂溜まり17の部分からクラックが発生し易くなる。   On the other hand, as shown in FIGS. 5 (a) and 5 (b), in the prior art, the sewing thread 13 is engaged with the fastening thread 14 and folded into a loop shape to be turned into the fastening thread 14 at the root portion 16 of the folded insertion portion 13a. The entering side portion 13c in the direction toward and the exit side portion 13d in the direction of being engaged with the clasp 14 and bent back are bent in the opposite direction and are inserted into the laminated fiber layer 12. Therefore, the opening of the entry side portion 13c and the exit side portion 13d is increased, and the three-dimensional fiber reinforced resin using the three-dimensional fiber structure as a reinforcing base corresponds to the root portion 16 of the folded insertion portion 13a of the sewing thread 13. The resin reservoir 17 at the place where the resin is accumulated becomes large, and cracks are easily generated from the resin reservoir 17 portion.

この実施形態によれば、以下に示す効果を得ることができる。
(1)三次元繊維強化複合材は、面内糸層11が積層された少なくとも2軸配向となる積層繊維層12を、縫い糸13と留め糸14とで結束してなる繊維構造体を強化基材とする三次元繊維強化複合材である。繊維構造体(三次元繊維構造体10)は、留め糸14が積層繊維層12のいずれか一方の最外層上に配列されている。縫い糸13は、留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aと、積層繊維層12の留め糸14が配列された側と反対側の面の外側に配列された反留め糸側配列部13bとを有する。折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが同一方向に屈曲されている。したがって、少なくとも2軸配向となる積層繊維層12を、縫い糸13と留め糸14とで結束してなる繊維構造体(三次元繊維構造体10)を強化基材として使用した三次元繊維強化複合材において、ループ状に折り返す縫い糸13の根元部16の樹脂溜まり量の減少と繊維体積含有率の向上とを両立させることができる。
According to this embodiment, the following effects can be obtained.
(1) A three-dimensional fiber reinforced composite material is a reinforcing structure of a fiber structure formed by binding a laminated fiber layer 12 having at least biaxial orientation in which in-plane yarn layers 11 are laminated with a sewing thread 13 and a fastening thread 14. It is a three-dimensional fiber reinforced composite material. In the fiber structure (three-dimensional fiber structure 10), the fastening thread 14 is arranged on one of the outermost layers of the laminated fiber layer 12. The sewing thread 13 engages with the fastening thread 14 and is folded back into a loop shape to be inserted into the laminated fiber layer 12, and on the surface opposite to the side on which the fastening thread 14 of the laminated fiber layer 12 is arranged. And an anti-fastening thread side array portion 13b arranged on the outside. In the root portion 16 of the folded back insertion portion 13a, the entry side portion 13c in the direction toward the retaining thread 14 and the exit side portion 13d in the direction of engaging with the retaining thread 14 and folded back are bent in the same direction. Therefore, a three-dimensional fiber reinforced composite material using a fiber structure (three-dimensional fiber structure 10) formed by binding the laminated fiber layer 12 having at least biaxial orientation with the sewing thread 13 and the fastening thread 14 as a reinforcing substrate. Thus, it is possible to achieve both a reduction in the amount of resin pool at the base portion 16 of the sewing thread 13 that is folded back into a loop and an improvement in the fiber volume content.

(2)縫い糸13は、積層繊維層12の幅方向の一方の端部から1ピッチより離れた位置で折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入され、以降の挿入位置が3ピッチ先の位置と、3ピッチ先の位置から1ピッチ戻る位置とを繰り返さすように挿入されている。したがって、繊維構造体(三次元繊維構造体10)を製造する際、縫い糸13の留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aが一定ピッチで存在するように縫い糸13を積層繊維層12に挿入する作業が他の挿入方法に比べて簡単になる。   (2) The sewing thread 13 is inserted in a folded shape at a position away from one pitch from one end in the width direction of the laminated fiber layer 12, and then inserted in a folded shape at a position returning by one pitch. Are inserted so as to repeat a position three pitches ahead and a position one pitch back from the position three pitches ahead. Therefore, when the fiber structure (three-dimensional fiber structure 10) is manufactured, the folded insertion portions 13a engaged with the fastening threads 14 of the sewing thread 13 and folded back into a loop shape and inserted into the laminated fiber layer 12 are formed at a constant pitch. The operation of inserting the sewing thread 13 into the laminated fiber layer 12 so as to exist is simpler than other insertion methods.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
○ 縫い糸13は、基本的に3ピッチの間隔をおいて折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入されたことの繰り返しで構成されているものに限らない。例えば、図6(a)に示すように、縫い糸13は、積層繊維層12の最外層の面内糸層11cに沿って配列された留め糸14と係合してループ状に折り返して積層繊維層12に挿入される折り返し挿入部13aの挿入位置が、積層繊維層12の幅方向(図6(a)の左右方向)の外側から内側に向かって変更されるように順次挿入されて形成されたものでもよい。
The embodiment is not limited to the above, and may be embodied as follows, for example.
The sewing thread 13 is not limited to being configured by repeatedly inserting the sewing thread 13 at a position returning by 1 pitch after being inserted in a folded shape at intervals of 3 pitches. For example, as shown in FIG. 6 (a), the sewing thread 13 engages with the retaining thread 14 arranged along the outermost in-plane thread layer 11c of the laminated fiber layer 12 and is folded back into a loop shape to form the laminated fiber. The insertion position of the folded insertion portion 13a to be inserted into the layer 12 is sequentially inserted so as to be changed from the outside to the inside in the width direction of the laminated fiber layer 12 (left and right direction in FIG. 6A). May be good.

○ 図6(b)に示すように、縫い糸13は、積層繊維層12の最外層の面内糸層11cに沿って配列された留め糸14と係合してループ状に折り返して積層繊維層12に挿入される折り返し挿入部13aの挿入位置が、積層繊維層12の幅方向(図6(b)の左右方向)の内側から外側に向かって変更されるように順次挿入されて形成されたものでもよい。   As shown in FIG. 6 (b), the sewing thread 13 engages with the fastening thread 14 arranged along the outermost in-plane thread layer 11c of the laminated fiber layer 12, and is folded back into a loop shape to form the laminated fiber layer. The insertion position of the folded back insertion portion 13a inserted into 12 is sequentially inserted so as to be changed from the inner side to the outer side in the width direction of the laminated fiber layer 12 (left and right direction in FIG. 6B). It may be a thing.

○ 縫い糸13は、留め糸14と係合してループ状に折り返して積層繊維層12に挿入された折り返し挿入部13aの根元部16において、留め糸14に向かう方向の入側部13cと、留め糸14に係合して折り返してくる方向の出側部13dとが同一方向に屈曲されていればよい。したがって、縫い糸13は、折り返し挿入部13aが一定ピッチではなく異なる間隔で挿入されてもよい。   The sewing thread 13 is engaged with the fastening thread 14, folded back in a loop and inserted into the laminated fiber layer 12, at the root part 16 of the folded insertion part 13 a, and an entry side part 13 c in the direction toward the fastening thread 14, The exit side portion 13d in the direction of being engaged with the yarn 14 and being turned back may be bent in the same direction. Therefore, the sewing thread 13 may be inserted at different intervals, instead of the fixed insertion pitch 13a.

○ 面内糸層11を構成する繊維束は炭素繊維に限らず、例えば、ガラス繊維やセラミック繊維等の無機繊維、あるいは、アラミド繊維、ポリ−p−フェニレンベンゾビスオキサゾール繊維、ポリアリレート繊維、超高分子量ポリエチレン繊維等の高強度の有機繊維であってもよく、要求性能に応じて適宜選択される。例えば、繊維強化複合材料に対する剛性・強度の要求性能が高い場合は、炭素繊維が好ましい。繊維束に安価なガラス繊維を用いると低コストとなる。   ○ The fiber bundle constituting the in-plane thread layer 11 is not limited to carbon fiber, for example, inorganic fiber such as glass fiber or ceramic fiber, or aramid fiber, poly-p-phenylenebenzobisoxazole fiber, polyarylate fiber, ultra It may be a high-strength organic fiber such as a high molecular weight polyethylene fiber, and is appropriately selected according to the required performance. For example, when the required performance of rigidity and strength for the fiber reinforced composite material is high, carbon fiber is preferable. If an inexpensive glass fiber is used for the fiber bundle, the cost becomes low.

○ 積層繊維層12を疑似等方性で面内4軸配向に構成する面内糸層11a〜11dの積層順序は、外層を面内糸層11c(+45度層)又は面内糸層11d(−45度層)にする順に限らない。   ○ The lamination order of the in-plane yarn layers 11a to 11d that constitute the laminated fiber layer 12 in a pseudo-isotropic and in-plane four-axis orientation is such that the outer layer is the in-plane yarn layer 11c (+45 degree layer) or the in-plane yarn layer 11d ( -45 degree layer).

○ 積層繊維層12は少なくとも2軸配向であればよく、疑似等方性で面内4軸配向に限らない。例えば、配向角が0度、60度及び−60度に配列した糸で面内3軸の積層繊維層12を構成したり、面内4軸の積層繊維層12を構成する場合に配向角が0度及び90度の他の面内配列糸の配向角を±45°以外の配向角としたりしてもよい。また、積層繊維層12を配向角が0度及び90度の面内2軸配向としてもよい。   The laminated fiber layer 12 only needs to be at least biaxially oriented, and is not limited to in-plane tetraaxial orientation with pseudo-isotropic properties. For example, when the in-plane triaxial laminated fiber layer 12 is composed of yarns having an orientation angle of 0 degrees, 60 degrees, and −60 degrees, or the in-plane 4-axis laminated fiber layer 12 is formed, the orientation angle is The orientation angle of other in-plane aligned yarns of 0 degree and 90 degrees may be an orientation angle other than ± 45 °. The laminated fiber layer 12 may be in-plane biaxial orientation with orientation angles of 0 degrees and 90 degrees.

○ 三次元繊維強化複合材を構成するマトリックス樹脂は熱硬化性樹脂に限らず、例えば、ポリアミド、ポリブチレンテレフタレート、ポリカーボネート、ポリオキシメチレン、ポリフェニレンエーテル等の熱可塑性樹脂を使用してもよい。   The matrix resin constituting the three-dimensional fiber reinforced composite material is not limited to a thermosetting resin, and for example, a thermoplastic resin such as polyamide, polybutylene terephthalate, polycarbonate, polyoxymethylene, or polyphenylene ether may be used.

以下の技術的思想(発明)は前記実施形態から把握できる。
(1)面内糸層が積層された少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体であって、前記留め糸は前記積層繊維層のいずれか一方の最外層上に配列され、前記縫い糸は、前記留め糸と係合してループ状に折り返して前記積層繊維層に挿入された折り返し挿入部と、前記積層繊維層の前記留め糸が配列された側と反対側の面の外側に配列された反留め糸側配列部とを有し、前記折り返し挿入部の根元部において、前記留め糸に向かう方向の入側部と、前記留め糸に係合して折り返してくる方向の出側部とが同一方向に屈曲されている。
The following technical idea (invention) can be understood from the embodiment.
(1) A fiber structure in which a laminated fiber layer having at least biaxial orientation in which in-plane yarn layers are laminated is bound with a sewing thread and a fastening thread, wherein the fastening thread is one of the laminated fiber layers The sewing thread is arranged on one outermost layer, the sewing thread is engaged with the fastening thread, folded back in a loop shape and inserted into the laminated fiber layer, and the fastening thread of the laminated fiber layer is arranged. An anti-fastening thread side arraying portion arranged on the outer side of the opposite side surface, and an entry side portion in a direction toward the fastening yarn at a root portion of the folded insertion portion, and an engagement with the fastening yarn The exit side in the direction of folding back is bent in the same direction.

Pz…配列面、10…繊維構造体としての三次元繊維構造体、11,11a,11b,11c,11d…面内糸層、12…積層繊維層、13…縫い糸、13a…折り返し挿入部、13b…反留め糸側配列部、13c…入側部、13d…出側部、14…留め糸、16…根元部。   Pz: arrangement surface, 10: three-dimensional fiber structure as a fiber structure, 11, 11a, 11b, 11c, 11d ... in-plane thread layer, 12 ... laminated fiber layer, 13 ... sewing thread, 13a ... folded insertion part, 13b ... anti-fastener side arrangement part, 13c ... entry side part, 13d ... exit side part, 14 ... fastener thread, 16 ... root part.

Claims (2)

面内糸層が積層された少なくとも2軸配向となる積層繊維層を、縫い糸と留め糸とで結束してなる繊維構造体を強化基材とする三次元繊維強化複合材であって、
前記繊維構造体は、前記留め糸が前記積層繊維層のいずれか一方の最外層上に配列され、
前記縫い糸は、前記留め糸と係合してループ状に折り返して前記積層繊維層に挿入された折り返し挿入部と、前記積層繊維層の前記留め糸が配列された側と反対側の面の外側に配列された反留め糸側配列部とを有し、前記折り返し挿入部の根元部において、前記留め糸に向かう方向の入側部と、前記留め糸に係合して折り返してくる方向の出側部とが同一方向に屈曲されていることを特徴とする三次元繊維強化複合材。
A three-dimensional fiber reinforced composite material comprising a fiber structure formed by binding a laminated fiber layer having at least biaxial orientation in which in-plane yarn layers are laminated together with a sewing thread and a fastening thread,
In the fiber structure, the fastening thread is arranged on the outermost layer of any one of the laminated fiber layers,
The sewing thread is engaged with the fastening thread, folded back in a loop shape and inserted into the laminated fiber layer, and the outer side of the surface of the laminated fiber layer opposite to the side where the fastening thread is arranged. And at the base part of the folded back insertion part, an entry side part in the direction toward the fastening thread and an output in the direction of folding back by engaging with the fastening thread. A three-dimensional fiber reinforced composite material characterized in that the side portion is bent in the same direction.
前記縫い糸は、前記積層繊維層の幅方向の一方の端部から1ピッチより離れた位置で折り返し状に挿入された後、1ピッチ戻る位置で折り返し状に挿入され、以降の挿入位置が3ピッチ先の位置と、前記3ピッチ先の位置から1ピッチ戻る位置とを繰り返さすように挿入されている請求項1に記載の三次元繊維強化複合材。   The sewing thread is inserted in a folded shape at a position apart from one pitch from one end in the width direction of the laminated fiber layer, and then inserted in a folded shape at a position returning by one pitch. The three-dimensional fiber-reinforced composite material according to claim 1, wherein the three-dimensional fiber reinforced composite material is inserted so as to repeat a previous position and a position returned by one pitch from the three pitch ahead position.
JP2013092472A 2013-04-25 2013-04-25 Three-dimensional fiber-reinforced composite material Pending JP2014213521A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109624351A (en) * 2018-11-21 2019-04-16 长安大学 A kind of pre- latex bonded fibre beam preparation method for 3 D weaving
JP2020525586A (en) * 2017-06-28 2020-08-27 キネティック リミテッド Product containing reinforcing fiber and shape memory alloy wire and method of manufacturing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020525586A (en) * 2017-06-28 2020-08-27 キネティック リミテッド Product containing reinforcing fiber and shape memory alloy wire and method of manufacturing the same
CN109624351A (en) * 2018-11-21 2019-04-16 长安大学 A kind of pre- latex bonded fibre beam preparation method for 3 D weaving

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