JP2014163179A - Heat insulation method of building - Google Patents

Heat insulation method of building Download PDF

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JP2014163179A
JP2014163179A JP2013036954A JP2013036954A JP2014163179A JP 2014163179 A JP2014163179 A JP 2014163179A JP 2013036954 A JP2013036954 A JP 2013036954A JP 2013036954 A JP2013036954 A JP 2013036954A JP 2014163179 A JP2014163179 A JP 2014163179A
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building
sheet
outdoor side
pillars
heat insulation
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Yoichi Minato
洋一 湊
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MX ENGINEERING KK
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MX ENGINEERING KK
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Abstract

PROBLEM TO BE SOLVED: To provide a heat insulation method of a building, capable of sufficiently exhibiting heat insulation and heat shielding in the building, minimizing end materials to be discarded in construction, preventing the infiltration of rainwater from the outdoor, and coping with dew condensation.SOLUTION: Reflection sheets each formed by pasting an aluminum foil on a flexible synthetic resin sheet are arranged on outdoor sides of pillars, studs, beds, and members around windows so that the aluminum foils are positioned on outdoor sides of a building. A hard urethane resin foamable liquid is foamed and sprayed into a clearance between each reflection sheet and each of the pillars, the studs, the beds, and the members around the windows to form a hard urethane resin foam layer, and outer wall materials are arranged with vent layers in which air is circulated in the vertical direction, each of the vent layers being interposed between the outer wall material and the outdoor side of the reflection sheet.

Description

本発明は、建築物の断熱工法に関する。   The present invention relates to a heat insulating construction method for buildings.

住宅等の建築物にあっては、室内環境を好適に維持するために、屋外の冷気や熱気を遮断する断熱材として、従来からグラスウール、ロックウール、ウレタンボード、発泡合成樹脂材等が用いられている。また、外気熱を遮蔽する遮熱材としては、アルミニウム箔等が用いられている。
そして、これらの断熱材と遮熱材を組み合わせた、発泡合成樹脂ボードにアルミニウム箔を貼り合わせた板状のアルミニウム熱線反射材も存在しており、これを、柱、軒桁、土台、窓まわり等の屋外側に取り付け、柱、軒桁、土台、窓まわり等の屋内側との間隔区画内に、液状の硬質ウレタン樹脂発泡材を吹き付けて発泡させて充填する断熱工法が存在している(特許文献1参照)。
In buildings such as houses, glass wool, rock wool, urethane boards, foamed synthetic resin materials, etc. have been used as heat insulating materials to block outdoor cold air and hot air in order to maintain an indoor environment. ing. An aluminum foil or the like is used as a heat shielding material that shields outside air heat.
And there is also a plate-like aluminum heat ray reflective material that combines these heat insulating materials and heat shield materials, with aluminum foil bonded to a foamed synthetic resin board. There is a heat insulation method that is installed on the outdoor side such as pillars, eaves girders, foundations, windows, etc., and is blown and filled with liquid hard urethane resin foam in the space between the indoor side ( Patent Document 1).

このアルミニウム箔とポリエチレン系発泡シートを結合して形成したアルミニウム熱線反射材と、硬質ウレタン樹脂発泡層とを組合せることにより、断熱、遮熱、保温及び防露に優れた性能を発揮するものである。   By combining the aluminum heat ray reflective material formed by combining this aluminum foil and a polyethylene foam sheet, and the rigid urethane resin foam layer, it exhibits excellent performance in heat insulation, heat insulation, heat retention and dew prevention. is there.

特開2007−138558号公報JP 2007-138558 A

しかしながら、上記特許文献1に記載された断熱材及びその工法にあっては、例えば柱・間柱、土台、窓まわりの屋外側にボード状のアルミニウム熱線反射材を固定する際に、施工個所の寸法に合わせて定形のアルミニウム熱線反射材を切断することから、廃棄する端材が生じ、無駄が発生せざるを得なかった。また、断熱材の端部に、気密テープを貼着して隙間を塞ぐものの、その気密テープ部分から雨水が浸入するおそれがあり、一層の防水対策が求められていた。
加えて、省エネルギー基準による地域区分で、厳冬期には−20℃にもなるI地域の北海道や、II地域の東北・長野の山間部などの寒冷地においては、特に断熱効果が大きい断熱構造が用いられているが、暖房を効かせた屋内と屋外との温度差が大きいことから、上記のような断熱構造の室内側に結露を生じることが多々あり、この水分や湿気が建物の木材等を腐らせる原因ともなっていた。
However, in the heat insulating material and the construction method described in Patent Document 1, for example, when fixing a board-shaped aluminum heat ray reflective material to the outdoor side around a pillar / intermediate pillar, base, and window, the dimensions of the construction site Since the regular aluminum heat ray reflective material is cut in accordance with the above, waste material to be discarded is generated and waste is inevitably generated. In addition, although an airtight tape is attached to the end of the heat insulating material to close the gap, rainwater may enter from the airtight tape portion, and further waterproof measures have been required.
In addition, the heat insulation structure has a particularly large heat insulation effect in cold regions such as Hokkaido in the I region, which reaches -20 ° C in severe winters, and in the mountainous areas of the Tohoku and Nagano regions in the II region. Although it is used, because there is a large temperature difference between indoors and outdoors where heating is effective, condensation often occurs on the indoor side of the heat insulation structure as described above. It was also a cause of rotting.

本発明は、前述の事情に鑑みて為されたものであって、建築物における断熱・遮熱を十分に発揮するとともに、施工にあたって廃棄する端材を極力少なくし、かつ屋外からの雨水の浸入を防ぎ、結露にも対処することができる建築物の断熱工法を提供することを目的とするものである。   The present invention has been made in view of the above-described circumstances, and exhibits sufficient heat insulation and heat insulation in buildings, minimizes scraps discarded in construction, and intrudes rainwater from outside. The object of the present invention is to provide a heat insulating construction method for buildings that can prevent condensation and cope with condensation.

本発明の建築物の断熱工法は、可撓性を有する合成樹脂シートにアルミニウム箔を貼着した反射シートを、該アルミニウム箔が建物の屋外側に位置するようにして柱・間柱、土台・窓まわりの屋外側に配設する工程と、前記反射シートと柱・間柱、土台・窓まわりの室内側に配設した内壁下地との間隙に硬質ウレタン樹脂発泡性液を発泡させて吹き付けて硬質ウレタン樹脂発泡層を形成する工程と、該反射シートの端縁と前記柱・間柱、土台・窓まわりとの接合部分に反射シートの屋外側からブチルゴム系防水テープを貼着する工程と、前記反射シートの屋外側に上下方向に空気が流通する通気層を介在させて外壁材を配設する工程と、を備えることを特徴とする。
これにより、本発明の建築物の断熱工法によれば、外壁材からの輻射熱を反射シートにより通気層側に反射し、そしてその熱を通気層を通る空気の流れにより屋外へと排出することができるとともに、反射しきれずに反射シートを伝達した熱は、硬質ウレタン樹脂発泡層により確実に断熱することができる。また反射シートの施工に際して、従来のボードタイプと異なり、一般にロール状に巻回されるシート体にあっては、切断することで無駄になる端材が発生せず、施工に係るコストの低減に寄与することができる。それに加え、ブチルゴム系防水テープを屋外側から反射シートの端縁に貼着することにより、反射シートの端縁からの雨水の浸入を防いで好適な防水機能を発揮することができる。
The heat insulating construction method for a building according to the present invention includes a reflective sheet in which an aluminum foil is bonded to a flexible synthetic resin sheet, and a column / intermediate column, base / window such that the aluminum foil is positioned on the outdoor side of the building. Rigid urethane foam is sprayed and blown into the gap between the reflection sheet and the inner wall substrate arranged on the indoor side around the reflection sheet and the pillars / intermediate pillars, windows, and windows. A step of forming a resin foam layer, a step of sticking a butyl rubber waterproof tape from the outdoor side of the reflection sheet to a joint portion between an edge of the reflection sheet and the pillar / intermediate column, base / window, and the reflection sheet And a step of disposing an outer wall member with an air-permeable layer through which air flows in the vertical direction on the outdoor side.
Thereby, according to the heat insulation construction method of the building of the present invention, the radiant heat from the outer wall material is reflected to the ventilation layer side by the reflection sheet, and the heat can be discharged to the outdoors by the flow of air through the ventilation layer. In addition, the heat transmitted through the reflection sheet without being completely reflected can be reliably insulated by the hard urethane resin foam layer. In addition, unlike the conventional board type, when the reflective sheet is constructed, the sheet body generally wound in a roll shape does not generate scraps that are wasted by cutting, thereby reducing the cost of construction. Can contribute. In addition, by sticking the butyl rubber waterproof tape to the edge of the reflection sheet from the outdoor side, it is possible to prevent rainwater from entering from the edge of the reflection sheet and exhibit a suitable waterproof function.

また、反射シートは、アルミニウム箔とポリエチレンラミネート層とポリエチレン繊維織布とを積層して構成されることを特徴とする。   Further, the reflection sheet is characterized by being formed by laminating an aluminum foil, a polyethylene laminate layer, and a polyethylene fiber woven fabric.

また、反射シートは、柱・間柱、胴差し・軒桁、土台・窓まわりの屋外側に、ステープルにより固定されることを特徴とする。   Further, the reflection sheet is characterized by being fixed with staples on the outdoor side around the pillars / intermediate pillars, torches / eave girders, foundations / windows.

また、換気ファンと蓄熱エレメントを備え、一方が吸気中に他方が排気する1対又は複数対からなる換気ユニットを建物の室内と屋外を挿通させて配設することを特徴とする。   In addition, a ventilation fan and a heat storage element are provided, and one or a plurality of pairs of ventilation units, one of which is inhaled while the other is exhausted, are disposed through the building interior and exterior.

また、ホウ素系防腐剤を反射シートが取り付けられる建物の木部に塗布することを特徴とする。   Further, the present invention is characterized in that a boron-based preservative is applied to a wooden part of a building to which a reflection sheet is attached.

本発明に係る建築物の断熱工法を示す説明図である。It is explanatory drawing which shows the heat insulation construction method of the building which concerns on this invention. 本発明に係る建築物の断熱工法に用いるアルミニウム複合断熱シートの説明図である。It is explanatory drawing of the aluminum composite heat insulation sheet used for the heat insulation construction method of the building which concerns on this invention. 本発明に係る建築物の断熱工法を示す説明図である。It is explanatory drawing which shows the heat insulation construction method of the building which concerns on this invention. 本発明に係る建築物の断熱工法に用いる換気システムを示す説明図である。It is explanatory drawing which shows the ventilation system used for the heat insulation construction method of the building which concerns on this invention.

以下、添付図面を参照しながら、本発明の建築物の断熱工法の形態を詳細に説明する。図1〜図4は、本発明の実施の形態を例示する図であり、これらの図において、同一の符号を付した部分は同一物を表わし、基本的な構成及び動作は同様であるものとする。   Hereinafter, the form of the heat insulation construction method of a building of the present invention is explained in detail, referring to an accompanying drawing. 1 to 4 are diagrams illustrating embodiments of the present invention. In these drawings, the same reference numerals denote the same components, and the basic configuration and operation are the same. To do.

<構成>
図1は、本発明の一実施形態を示しており、木造在来工法における住宅の壁構造、特に土台まわり若しくは窓まわりを表している。図中1は壁構造、2は胴差し・軒桁、3は土台・窓まわり、4はアルミニウム複合断熱シート、5は硬質ウレタン樹脂発泡材、6はアルミニウム複合断熱シート4と外壁材7との間に設けられた通気層、8はプラスターボード等の内壁下地である。
柱・間柱は、図1に示す胴差し・軒桁2と土台・窓まわり3の間に上下方向に位置し、硬質ウレタン樹脂発泡材5が介在する間隙を設定している。
<Configuration>
FIG. 1 shows an embodiment of the present invention, and represents a wall structure of a house in a wooden conventional construction method, particularly a base or window. In the figure, 1 is a wall structure, 2 is a girder, eaves girder, 3 is a base / window circumference, 4 is an aluminum composite heat insulating sheet, 5 is a hard urethane resin foam material, 6 is an aluminum composite heat insulating sheet 4 and an outer wall material 7 A ventilation layer 8 provided between them is an inner wall base such as a plaster board.
The pillars / intermediate pillars are positioned in the vertical direction between the trunk / eave girder 2 and the base / window periphery 3 shown in FIG. 1, and set a gap in which the rigid urethane resin foam material 5 is interposed.

アルミニウム複合断熱シート4は、図2に示すように、アルミニウム箔41と、透明なポリエチレンラミネート層42と、強度を有するポリエチレン繊維織布43の3層が貼着されて構成されたシート体であり、軽量性、柔軟性、可撓性、耐水性を有する。このアルミニウム複合断熱シート4は、厚さが約0.12ミリメートルときわめて薄いにも拘わらず、破裂強度と引張り強度が大きいことから施工性に優れるとともに、建築材料として使いやすいように、予め長尺なロール状に巻回された形で提供されている。
このアルミニウム複合断熱シート4は、約96%という大きな熱反射率を有していることから、断熱構造の屋外側に配設することで、大きな遮熱効果が発揮される。
As shown in FIG. 2, the aluminum composite heat insulating sheet 4 is a sheet body configured by adhering three layers of an aluminum foil 41, a transparent polyethylene laminate layer 42, and a polyethylene fiber woven fabric 43 having strength. , Light weight, softness, flexibility, water resistance. Although this aluminum composite heat insulating sheet 4 has a very thin thickness of about 0.12 millimeters, it has a large bursting strength and tensile strength, so that it has excellent workability and is easy to use as a building material. Provided in a rolled form.
Since this aluminum composite heat insulating sheet 4 has a large heat reflectance of about 96%, a large heat shielding effect is exhibited by disposing it on the outdoor side of the heat insulating structure.

5は硬質ウレタン樹脂発泡材であり、柱・間柱と胴差し・軒桁2と土台・窓まわり3を挟むように屋外側に貼られたアルミニウム複合断熱シート4と、同じく屋外側に貼られた内壁下地8との間隙に位置する。   5 is a hard urethane resin foam material, which is affixed on the outdoor side, and an aluminum composite heat insulating sheet 4 affixed on the outdoor side so as to sandwich the pillars, studs, trunks, eaves girder 2, base and window periphery 3 Located in the gap with the inner wall base 8.

図3は、本実施例の断熱工法を窓まわりに実施する場合を一例として示すものであり、アルミサッシのまわりに本願発明の断熱構造を施工する状態を上から見たものである。この実施例にあっては、アルミサッシ9の屋外側に、アルミニウム複合断熱シート4の下端が、防水性能を発揮するブチルゴム系粘着テープ10により接着固定されている状態を示しており、このブチルゴム系粘着テープ10を使用することにより、アルミサッシ9を伝わって流れる雨水等がアルミニウム複合断熱シート4の隙間から室内に浸入するおそれがなくなるものである。もちろん、ブチルゴム系粘着テープ10は、窓まわり以外の土台まわり等にも使用することができるものである。   FIG. 3 shows, as an example, the case where the heat insulation method of the present embodiment is carried out around a window, and shows a state in which the heat insulation structure of the present invention is applied around an aluminum sash from above. In this embodiment, a state in which the lower end of the aluminum composite heat insulating sheet 4 is bonded and fixed to the outdoor side of the aluminum sash 9 with a butyl rubber adhesive tape 10 that exhibits waterproof performance is shown. By using the adhesive tape 10, there is no possibility that rainwater or the like flowing through the aluminum sash 9 will enter the room through the gaps in the aluminum composite heat insulating sheet 4. Of course, the butyl rubber-based pressure-sensitive adhesive tape 10 can also be used around a base other than around the window.

図4は、本発明の断熱構造において、断熱とともに必要となる換気システムを示している。これは、換気ファン11と蓄熱エレメント12を備えた1対又は複数対の換気ユニット13を、建物の壁に配設するものであり、従来のダクトを用いた換気システムと比較して簡易な構造となっている。この1対又は複数対の換気ユニット13は、図示しないコントローラに接続され、一方の換気ユニット13を吸気(屋外から室内に)させるとともに、他方の換気ユニット13を排気(室内から屋外に)させ、これを数十秒〜数分ごとに相互に反転することで吸気・排気を切り替えるものである。   FIG. 4 shows a ventilation system required together with heat insulation in the heat insulation structure of the present invention. In this structure, one or more pairs of ventilation units 13 including a ventilation fan 11 and a heat storage element 12 are arranged on the wall of a building, and the structure is simpler than that of a conventional ventilation system using a duct. It has become. The one or more pairs of ventilation units 13 are connected to a controller (not shown), and inhale one ventilation unit 13 (outdoor to indoor) and exhaust the other ventilation unit 13 (indoor to outdoor), This is reversed between several tens of seconds to several minutes to switch between intake and exhaust.

すなわち、冬季において外気温が0℃の場合に、排気時には、室内の23℃の空気の熱を蓄熱エレメント12に蓄積して、屋外に3℃の空気を排気するとともに、吸気時には、0℃の冷たい空気を蓄熱エレメント12で暖めて17℃の空気にして室内に取り込むものである。
換気ユニット13は、消費電力は数W/h以下と小さいものの、ファンの音を抑えて運転した場合でもその換気量は10m/h程度あり、結露防止のための換気能力としては十分となる。これにより、換気ユニット13を24時間連続運転させることも可能である。
That is, when the outside air temperature is 0 ° C. in the winter season, the heat of the indoor 23 ° C. air is accumulated in the heat storage element 12 at the time of exhaust, and the air of 3 ° C. is exhausted outdoors, and at the time of intake, the temperature is 0 ° C. Cold air is warmed by the heat storage element 12 and is taken into the room as 17 ° C. air.
Although the power consumption of the ventilation unit 13 is as low as several W / h or less, the ventilation volume is about 10 m 3 / h even when operated with the fan sound suppressed, which is sufficient as a ventilation capacity for preventing condensation. . Thereby, it is also possible to operate the ventilation unit 13 continuously for 24 hours.

<工法>
上述した構成からなる本実施形態の断熱構造の工法について、以下に詳述する。
まず、アルミニウム複合断熱シート4を、柱・間柱、胴差し・軒桁2、土台・窓まわり3の屋外側に、鋲打機を用いてステープルで固定する。この際、アルミニウム複合断熱シート4はロール状に巻回されているので、必要な分だけロールから繰り出して切断して用い、廃棄する端材がほとんど発生しない。そして、薄く可撓性を有するアルミニウム複合断熱シート4であっても、ステープルで止める間隔を細かくすることにより、ボードと同じようにピンと張った状態で平坦な面を保持することができる。
<Method>
The construction method of the heat insulation structure of the present embodiment having the above-described configuration will be described in detail below.
First, the aluminum composite heat insulating sheet 4 is fixed with staples to the outdoor side of the pillars / intermediate pillars, torso / eave girder 2, base / window periphery 3 by using a hammer. At this time, since the aluminum composite heat insulating sheet 4 is wound in a roll shape, the necessary amount of scrap material is not generated when it is unwound from the roll, cut and used. And even if it is the thin aluminum composite heat insulation sheet 4 which has flexibility, a flat surface can be hold | maintained in the state tensioned like the board by making the space | interval stopped with a staple fine.

そして施工現場において、アルミニウム複合断熱シート4と内壁下地8との間に、硬質ウレタン樹脂発泡性液を発泡させて吹き付けることにより、硬質ウレタン樹脂発泡材5を形成する。
アルミニウム複合断熱シート4と外壁材7との間には、20〜30ミリメートル程度の間隔の通気層6を形成する。
これにより、夏に温まった外壁材7から屋内側への輻射熱をアルミニウム複合断熱シート4のアルミニウム箔41が反射し、この熱を、通気層6の下方から上方へと通じる空気の流れにより屋外に排出することができる。この通気層6の空気の流れを作るためには、特段にファン等を設置する必要がなく、自然の空気の対流を利用することで足りるものである。
At the construction site, the hard urethane resin foam material 5 is formed by foaming and spraying a hard urethane resin foamable liquid between the aluminum composite heat insulating sheet 4 and the inner wall base 8.
Between the aluminum composite heat insulating sheet 4 and the outer wall material 7, a ventilation layer 6 having an interval of about 20 to 30 millimeters is formed.
Thereby, the aluminum foil 41 of the aluminum composite heat insulating sheet 4 reflects the radiant heat from the outer wall material 7 warmed in the summer to the indoor side, and this heat is transferred outdoors by the flow of air that passes from below to above the ventilation layer 6. Can be discharged. In order to create the air flow in the ventilation layer 6, it is not necessary to install a fan or the like, and it is sufficient to use natural air convection.

さらに、特に図示しないが、アルミニウム複合断熱シート4を配設する木部にホウ素系化合物を主成分とする木材保存剤を塗布することとする。これにより、木部が結露等により腐朽することを防止することができる。   Further, although not particularly illustrated, a wood preservative mainly composed of a boron-based compound is applied to the wood portion on which the aluminum composite heat insulating sheet 4 is disposed. Thereby, it can prevent that a xylem rots by condensation etc.

本発明の断熱工法は、住宅産業において利用することができるものである。   The heat insulation method of the present invention can be used in the housing industry.

4 アルミニウム複合断熱シート
41 アルミニウム箔
42 ポリエチレンラミネート層
43 ポリエチレン繊維織布
5 硬質ウレタン樹脂発泡材
6 通気層
7 外壁材
8 内壁下地
9 アルミサッシ
10 ブチルゴム系粘着テープ
11 換気ファン
12 蓄熱エレメント
13 換気ユニット
4 Aluminum composite heat insulating sheet 41 Aluminum foil 42 Polyethylene laminate layer 43 Polyethylene fiber woven fabric 5 Hard urethane resin foam 6 Venting layer 7 Outer wall material 8 Inner wall base 9 Aluminum sash 10 Butyl rubber adhesive tape 11 Ventilation fan 12 Thermal storage element 13 Ventilation unit

Claims (5)

可撓性を有する合成樹脂シートにアルミニウム箔を貼着した反射シートを、該アルミニウム箔が建物の屋外側に位置するようにして柱・間柱、土台・窓まわりの屋外側に配設する工程と、
前記反射シートと柱・間柱、土台・窓まわりの室内側に配設した内壁下地との間隙に硬質ウレタン樹脂発泡性液を発泡させて吹き付けて硬質ウレタン樹脂発泡層を形成する工程と、
該反射シートの端縁と前記柱・間柱、土台・窓まわりとの接合部分に反射シートの屋外側からブチルゴム系防水テープを貼着する工程と、
前記反射シートの屋外側に上下方向に空気が流通する通気層を介在させて外壁材を配設する工程と、を備えることを特徴とする建築物の断熱工法。
A step of disposing a reflective sheet in which an aluminum foil is bonded to a flexible synthetic resin sheet on the outdoor side of a pillar / intermediate column, a base / window, such that the aluminum foil is positioned on the outdoor side of the building; ,
Forming a hard urethane resin foam layer by foaming and spraying a hard urethane resin foaming liquid in a gap between the reflective sheet and the pillars / intermediate pillars, the base and the inner wall base disposed around the window;
A step of sticking a butyl rubber waterproof tape from the outdoor side of the reflective sheet to the junction between the edge of the reflective sheet and the pillar / intermediate pillar, the base, and the window periphery;
And a step of arranging an outer wall material on the outdoor side of the reflection sheet with a ventilation layer through which air flows in the vertical direction.
反射シートは、アルミニウム箔とポリエチレンラミネート層とポリエチレン繊維織布とを積層して構成されることを特徴とする請求項1記載の建築物の断熱工法。   The heat insulating construction method for a building according to claim 1, wherein the reflection sheet is formed by laminating an aluminum foil, a polyethylene laminate layer, and a polyethylene fiber woven fabric. 反射シートは、柱・間柱、胴差し・軒桁、土台・窓まわりの屋外側に、ステープルにより固定されることを特徴とする請求項1又は2記載の建築物の断熱工法。   The heat insulating construction method for a building according to claim 1 or 2, wherein the reflection sheet is fixed by staples on the outdoor side around the pillars / intermediate columns, torches / eave girders, foundations / windows. 換気ファンと蓄熱エレメントを備え、一方が吸気中に他方が排気する1対又は複数対からなる換気ユニットを建物の室内と屋外を挿通させて配設することを特徴とする請求項1又は2記載の建築物の断熱工法。   3. A ventilation unit comprising a ventilation fan and a heat storage element, wherein one or a plurality of ventilation units, one of which is exhausted while the other is exhausted, is disposed through the building interior and exterior. Insulation method of building. ホウ素系防腐剤を反射シートが取り付けられる建物の木部に塗布することを特徴とする請求項1又は2記載の建築物の断熱工法。   The heat insulation method for a building according to claim 1 or 2, wherein a boron-based preservative is applied to a wooden part of a building to which a reflection sheet is attached.
JP2013036954A 2013-02-27 2013-02-27 Heat insulation method of building Pending JP2014163179A (en)

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JP7384358B2 (en) 2020-04-27 2023-11-21 株式会社島津製作所 Structural analysis method for organic compounds
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