JP2014147922A - Solidified body storage vessel with lighting mechanism of polluted waste - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a treatment and storage method of polluted incineration ash and polluted water including heavy metal and polluted matter, for reducing the final waste quantity.SOLUTION: A solidified body storage vessel 2 with a lighting mechanism has the function of letting an external part know liquid leakage by corrosion by the vessel 2 by lighting, by additionally filling a mixture being a member used as re-resources and adding zeolite and cement to a modifier in the vessel 2 filled with the incineration ash or the polluted water including the polluted matter, hardening them as an agitation kneading object, installing an electrode plate 4 or a magnetic pole plate band resilience fastening metal fitting outside the vessel 2, disposing the vessel 2 in an outside vessel 7 after sealing the vessel 2 by a lid, connecting the electrode plate 4 or a magnetic pole plate to both ends of an insulation coil 5 on the outside of the sealed vessel 2 and connecting both ends of the coil 5 to an insulator metal fitting provided with an electric bulb body in a central part of the wound coil 5.

Description

The present invention relates to the treatment and storage of hazardous pollutants including heavy metals, contaminated incineration ash and contaminated decontaminated water waste.

Conventionally, as a method for processing and storing hazardous contaminated incineration ash and waste water containing heavy metals, cement materials are kneaded in drums and hardened and buried in the ground, and huge intermediate processing facilities and final storage facilities are required. It has been.

Problems to be solved by the invention

In the conventional processing method, it must be finally stored underground. However, there are physical land storage and facility limitations for storing a large amount of waste, and there are elution problems due to deterioration of containers and solidified solids. The cause is the elution problem due to deterioration of the solidified solid due to corrosion and erosion inside and outside the storage container, and the volume of the solidified container is determined according to the container, so filling of contaminated waste and radioactive waste When the amount increases, the ratio of the moisture content of the solidified material and the kneaded material necessary for kneading used for recycling other than contaminated waste and radioactive waste increases, causing deterioration after solidification and corrosion elution, Also, liquid leakage due to container corrosion cannot be detected.
JP 2007-47039 A JP 2006-132718 A JP 8-154524 A JP 2004-137593 A

The object of the present invention is to prevent the elution of harmful substances due to the reduction of the final waste amount and the deterioration of the waste storage container, and to know the leakage detection in advance. Another object of the present invention is to provide a method for treating and storing contaminated waste, which is a member used as a resource.

Means for solving the problem

In order to achieve the above-described object, the invention of claim 1 is directed to coal ash, zeolite, slug, ceramics, which are used as resources in contaminated incineration ash and decontaminated water containing pollutants and heavy metal substances. Stir kneaded mixture of animal fats and oils, vegetable oils and fats, gelatin, natto, rice bran, agar, starch, and cement as appropriate with water, iron powder, sand and cement 1st process, 2nd process which mounted | worn with the electrode plate, the magnetic pole plate band, or the elastic clamp. This electric current and magnetic band container is filled in another container, and from the upper part of the fixed container, zeolite, cement and water stirring and kneaded material are filled into the container, and the container is filled, solidified, and sealed. Third step to harden. A container with a lighting mechanism, wherein both ends of the coil are connected to an insulator metal fitting provided with a light bulb body at the center of a coil connected to and wound around an electrode plate or a magnetic pole plate at both ends of the insulated coil outside the sealed outer container. 4th process to make.

The invention of claim 1 prevents and fixes the diffusion of heavy metal substances, contaminated incineration ash and contaminated decontamination water. In addition, it is used as a remedial agent containing coal ash, zeolite, slug, ceramics, iron powder, sand, and cement, which is a component that heats contaminated decontaminated water waste from 40 to 60 degrees and uses it as a resource. , Gelatin, natto, rice bran, agar, starch, calcium silicate, carbide, caustic soda powder, cement are appropriately filled in animal fats or vegetable fats, stirred, dried and made into granular powder, heavy metal A first step of coating and solidifying the surface of the substance and contaminated incineration ash. This makes it insoluble in normal temperature water.

Next, in order to prevent the corrosion deterioration of the storage container and the deterioration of the solidified material, the insulation coil is connected to the electrode plate on the outside of the container and on the inside of the storage container and on the outside of the container according to the storage purpose place in the ground or deep sea. At the center of the coil around which the coil is wound, connect the both ends of the coil to an insulator fitting provided with a light bulb body, and in the second step of attaching it to a container with a lighting mechanism, a container with an electric current, magnetic band, and light bulb body is attached. . In addition, an insulated copper wire coil is wound around the outside of the container, and the electrode is taken out outside that is insulated and waterproofed with vinyl chloride resin, paraffin, styrene resin, urea resin, melamine resin, and one end is the other end on the copper plate, brass, and silver plate Is a storage container for the second step connected to an iron plate, aluminum, nickel plate or zinc plate.

The container of the second step is filled in the separate container, and a gap of about 15 cm is opened at the bottom of the container and placed in the center of the container. From the top of the container, improver containing the improver raw material, coal ash, zeolite, slug, ceramics, iron powder, sand, and cement is filled with water, then kneaded and hardened, outside the side part of the sealed container Connect the electrode plate to both ends of the insulation coil and connect the coil to both ends of the coiled device at the center of the coil, and install the insulator bracket on the bulb body. A third step of forming a solidified body storage container equipped with an electrode and a magnetic pole, to which a plate band or elastic clamp is attached.

Also, from the process work from the first step to the third step, a weak anion current and magnetic field pressure are generated in the container and the container, attracting heavy metals and pollutants which are cation molecules and ionic electrons, and the atmosphere and the outside Does not spread. As a result, in the container storage process, the corrosion of the container is assumed as a safety measure while preventing corrosion, and the device with the light bulb body mechanism detects abnormalities of the magnetic pole and applied current due to liquid leakage and lights up the light bulb body. Notify the outside by emitting light. In addition, the lighting of the bulb body and the light source bulb of the luminous body can use LED fluorescent lamps or LED bulbs, or conventional fluorescent lamps, incandescent bulbs, fragmented bulbs, etc. it can. A fourth step in which microorganisms, molds, and fungi that decompose heavy metals and contaminants adhere to the outside of the container.

Hereinafter, the present invention will be described in detail with reference to the illustrated embodiments.

[First Embodiment]
The present invention reduces contaminated incineration ash and decontamination water generated in large quantities from debris treatment related to an accident at a nuclear power plant. Moreover, the treatment process of embodiment of the 1st process of the contaminated incineration ash containing heavy metal and the de-washing water waste processing method is shown. The embodiment of the first step is a method for treating the incineration ash and the radioactive cleaning water when the debris generated in the nuclear power plant accident and the large tsunami is incinerated. In FIG. 1, this first embodiment is a method for containing contaminated incineration ash containing heavy metals, cleaning water, and contaminated water. 20% of the agent, 10% of animal oil or vegetable oil, 10% of gelatin, natto, koji, agar, starch, calcium, carbide, caustic soda powder, cement, and 10% are appropriately distributed and stirred. In the case of room temperature water in winter, the reaction is somewhat slow, but if the temperature is set to about 45 to about 65 degrees with a heater, the work process is shortened. First step.

In the first step of the first, second and third embodiments, the gas containing harmful radioactive substances generated from the contaminated water during natural drying or heat drying is a mixture on the water surface. The bubbles are trapped in the bubbles and bubbles generated from the gas, and the water surface is covered with the bubbles and bubbles so that the gas does not diffuse into the atmosphere. Moreover, it becomes only the granular powder which took in the harmful radioactive substance which removed the water | moisture content, without diffusing pollutant gas in air | atmosphere.

Next, in FIG. 2, this second embodiment is an apparatus in which an insulating metal fitting is provided in a light bulb body around a coil central portion in which an insulating coil connected to an electrode plate or a magnetic pole plate is wound around the outer side of an example 100L container. If the purpose of the storage facility usage conditions is different in the ground and the sea in the second process of connecting and attaching the two ends of the coil, the aluminum / copper / zinc electrode plate and magnetic band metal in FIG. Alternatively, the current and magnetic band mounting for attaching the elastic clamp can be exchanged between the inside and the outside.

Next, in FIG. 3, the third embodiment is configured such that the second step, Example 100L container is filled in the Example 200L separate container, and a gap of 10 cm to 15 cm is provided from the bottom of the separate container. Install in the center of the container. A third step of filling a drum can with an appropriate amount of a kneaded product of zeolite, cement, and water into the improver from the top of the container.

Next, in FIG. 4, in the fourth embodiment, a magnetic band iron plate or an aluminum plate electrode plate and a magnetic band metal are clamped to the outside of the side surface of the sealed container that is the upper lid of another container, or A fourth step of forming a solidified body storage container with a final lighting mechanism provided with electrodes and magnetic poles by attaching an elastic clamp is provided.

Next, in the embodiment shown in FIG. 5, a plurality of solidified body storage containers can be stored in a connected state in which the electrodes in the vertical or horizontal direction or between the magnetic poles are stored in the tubular steel tube container with a top lid. Solid storage container with lighting mechanism.

Effect of the invention

In the conventional processing method, there is a limitation of facility and facility for securing physical land for storing a large amount of waste, and there is an elution problem due to deterioration of the container and the solidified product. The cause is the elution problem due to deterioration of the solidified solid due to corrosion and erosion inside and outside the storage container, and the volume of the solidified container is determined according to the container, so filling of contaminated waste and radioactive waste When the amount increases, the proportion of moisture content of the solidified material other than the contaminated waste and radioactive waste and the kneaded material necessary for kneading increases, which is a cause of deterioration after solidification and corrosion elution. When evaporating water, bubbles and bubbles are generated on the surface of the water, and the gas is covered while confining and solidifying the radiation gas, thereby preventing the release of gas and preventing air pollution. In addition, by making the coating dry granular powder, it has a coating that makes it difficult to dissolve even if it is directly exposed to normal temperature water, and has an effect of preventing solutes. By passing a cationic substance and an anionic substance through an electrode plate and a pole plate, an electron ion band, an interference band of a cationic substance and an anionic substance and a resonance band of an electron molecule are formed, and a heavy metal substance and a pollutant, While sealing the cesium, by connecting both ends of the coil to a device in which an insulating metal fitting is provided on the light bulb body at the center of the coil around which the insulating coil connected to the electrode plate or magnetic pole plate is wound, Check for leaks. Moreover, it becomes a container with a light bulb lighting mechanism by electronic energy, so it is separated from the natural world and stored safely. Furthermore, it is packed in a separate container, and is solidified in a gap between the container and the outer container with a concrete member to enhance durability and safety. Alternatively, by attaching a band or elastic clamp to the magnetic pole plate, an interference band is formed between the solidified body storage container, the electrode in the coil in the outer container and the inner container, and the magnetic field electrolysis layer. , Tell the electrode plate and pole plate, attract the contaminants and heavy metals, cesium, and cation electrons in the coil to the center of the container to prevent external leakage, and install the insulator bracket on the bulb body in the center of the coil. By connecting and attaching both ends of the coil to the provided device, the applied current and applied magnetic field due to liquid leakage from the container are sensed, and the electrode body is turned on and light energy by an LED fluorescent lamp or LED bulb. , External Inform the leakage. In addition, the solidified body storage container with a lighting mechanism is housed in a cylindrical steel pipe pipe and connected and connected, so that cylindrical and tunnel storage facilities are possible. Appropriate treatment of pollutants while sequestering microorganisms, molds, and fungi that degrade pollutants, while preventing them from leaking harmful substances and pollutants, while separating them from the natural environment in the food chain In addition, by effectively exhibiting the function of preventing waste liquid leakage due to deterioration of the solidified material, it can be connected and stored in the vertical and horizontal shafts and deep sea on the ground and in the ground. In addition, manufacturing, storage, and safety management are easy and inexpensive.

Diagram Diagram Diagram Cross section Diagram

1. Stirrer 2. Container 3. 3. Kneaded material 4. Electrode plate Coil 6. 6. Molded product Outer container 8. 8. Upper lid band Electrode band 10. Elastic tightening bracket 11. Tubular tube 12. Tightening bolt nut

Claims (3)

In a container filled with incinerated ash containing pollutants or contaminated water, water is added to animal oils or vegetable oils, gelatin, starch, and cement as appropriate. The mixture filled in is solidified into a granular powder containing bubbles while stirring, and an electrode plate, a pole plate band or an elastic clamp is attached to the outside of the sealed container, and the container is placed in the outer container. Coil with a mixture of zeolite and cement in the improving agent, stir-kneaded into a mixture, and sealed from the upper part of the outer container. A solidified body storage container with a lighting mechanism by connecting both ends of a coil to an insulator fitting provided with a light bulb at the center. A container in which incinerated ash containing pollutants or a container filled with contaminated water is used as a resource, a mixture in which zeolite and cement are mixed with an improving agent is agitated and kneaded, and the container is sealed. Attach an electrode plate or pole plate band elastic clamp to the outside of the container, place the container in the outer container, and connect the electrode plate or the pole plate to both ends of the insulation coil outside the sealed container. A solidified body storage container with a lighting mechanism in which both ends of the coil are connected to an insulating metal fitting provided with a light bulb at the center of the wound coil. A plurality of solidified body storage containers extending in a longitudinal direction or a lateral direction from the outer surface direction of the solidified body storage container according to any one of [Claim 1] to [Claim 2], and electrodes A solidified body storage container with a lighting mechanism that is connected to each other or magnetic poles.

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