JP2014125428A - Cosmetic for eyelashes - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic for eyelashes in which blurs and mascara dregs are not generated, and curling effect hardly deteriorates, even when the eyelashes get wet with water after the cosmetic is applied.SOLUTION: The cosmetic for eyelashes contains the following components (A), (B), and (C): (A) 1-30 mass% as a solid content of a film forming agent which consists of an alkyl (meth)acrylate copolymer; (B) pullulan; and (C) polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an 8-22C alkyl group or alkenyl group with an HLB of 9 or more. In the component (A), (A-1) 30 mass% or more of a film forming agent which consists of an alkyl (meth)acrylate copolymer with a particle size of 10-50 nm.

Description

  The present invention relates to a vaginal cosmetic.

Cosmetics for vases such as mascara are required to have high curling power and excellent makeup.
For example, Patent Document 1 describes that eyelash cosmetics in which pullulan, solid fat, and resin emulsion are combined are excellent in curl-up power and makeup retention.

JP 2011-157289 A

  The present inventor has found that in conventional mascara, when the mascara is applied and then wetted with water such as tears or sweat, bleeding and mascara are generated, the curling effect is reduced, and the mascara becomes lumpy. .

  The present inventor includes a film-forming agent comprising a (meth) acrylic acid alkyl copolymer having a specific particle diameter, and further uses a combination of pullulan and a specific nonionic surfactant to solve the above problems. It has been found that an oil-type cosmetic for glaze can be obtained.

The present invention includes the following components (A), (B) and (C):
(A) Film-forming agent comprising an alkyl (meth) acrylate copolymer The solid content is 1 to 30% by mass,
(B) Pullulan,
(C) A polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms whose HLB is 9 or more, and in component (A), (A-1) The present invention relates to an oil-in-water cosmetic for cosmetics wherein the film-forming agent composed of an alkyl (meth) acrylate copolymer having a particle size of 10 to 50 nm is 30% by mass or more.

  The vaginal cosmetic composition of the present invention is less likely to cause blurring and mascaracus even when it is wetted with water after application, to prevent the curling effect from being lowered, to prevent lumps, and to be bundled. Moreover, it is excellent in cleansing properties with warm water of 40 ° C.

In an Example, sectional drawing at the time of evaluating the curl keeping force after apply | coating mascara is shown.

The film forming agent comprising the (meth) alkyl acrylate copolymer of component (A) used in the present invention contains methacrylic acid and / or acrylic acid monomer, and alkyl methacrylate monomer and / or alkyl acrylate monomer. It is preferable to use a copolymer obtained by emulsion polymerization of the monomer mixture as a main component. If it is generally used for cosmetics, it will not be restrict | limited.
The glass transition temperature (Tg) of the copolymer is preferably from −30 ° C. to 100 ° C., more preferably from −20 ° C. to 70 ° C., from the viewpoint of imparting a curling effect and being excellent in cosmetic durability.
As a component (A), what has the form of the emulsion containing such a copolymer and water can be used, A (meth) acrylic-acid alkyl copolymer emulsion is preferable. The copolymer content (solid content) in the emulsion is not limited, but is preferably 20 to 60% by mass, and more preferably 25 to 55% by mass.

In component (A), even when wet after application, the occurrence of bleeding and mascara is suppressed, the curl effect is less likely to be reduced, the formation of lumps is suppressed, and it is difficult to bundle (A -1) A film-forming agent composed of an alkyl (meth) acrylate copolymer having a particle size of 10 to 50 nm is 30% by mass or more, preferably 35% by mass or more, more preferably 40% by mass or more in the component (A). included.
In addition, the content of the film-forming agent comprising such an (A-1) (meth) alkyl acrylate copolymer is uniformly adhered to the wrinkle after coating and forms a film, so that it is wet with water. However, the occurrence of bleeding and mascara is suppressed, the curl effect is less likely to be reduced, the formation of lumps is suppressed, and the bundle is less likely to be bundled. 1.5 mass% or more is more preferable, 3 mass% or more is further more preferable, 30 mass% or less is preferable, 20 mass% or less is more preferable, and 10 mass% or less is still more preferable. Further, the content of the component (A-1) is preferably 0.3 to 30% by mass, more preferably 1.5 to 20% by mass, and still more preferably 3 to 10% by mass as a solid content in the entire composition. .

(A-1) Commercially available products such as iodosol GH256F (particle size 20 to 40 nm; manufactured by Akzo Nobel) may be used as a film-forming agent composed of an alkyl (meth) acrylate copolymer having a particle size of 10 to 50 nm. it can.
In addition to the component (A-1), as a film forming agent (A-2) comprising a (meth) acrylic acid alkyl copolymer having a particle diameter exceeding 50 nm, iodosol GH34F (manufactured by Akzo Nobel), iodosol GH800F ( Commercial products such as Akzo Nobel), Yodosol GH810F (Aczo Nobel), Daitozol 5000AD (Daito Kasei Kogyo), Daitosol 5000SJ (Daito Kasei Kogyo) can be used.
The particle size of these components (A-2) is preferably 300 nm or less, more preferably 200 nm or less, and even more preferably 150 nm or less.

  Component (A) can be used singly or in combination of two or more, and the content is 1% by mass or more as a solid content in the whole composition from the viewpoint of imparting a curling effect and having a long makeup, % By mass or more is preferable, and 5% by mass or more is more preferable. And it is 30 mass% or less as solid content from the point which is excellent in provision of a curl effect and cosmetics holding | maintenance, 20 mass% or less is preferable, and 15 mass% or less is more preferable. Moreover, content of a component (A) is 1-30 mass% as solid content in all the compositions, 4-20 mass% is preferable, and 5-15 mass% is more preferable.

The component (B) pullulan used in the present invention is a natural polysaccharide in which maltotriose is regularly α-1,6-linked, obtained by culturing Aureobasidium pullulans, a kind of black yeast, using starch as a raw material. .
Pullulan is a water-soluble polymer, but has the characteristic of forming a tough film with moisture resistance, so when combined with an oil-in-water cosmetic, it is compared with other water-soluble polymers. Therefore, it is considered that the makeup holding performance is not easily lowered and contributes to the improvement of the curling performance.
As such pullulan, commercially available products such as cosmetic pullulan (manufactured by Hayashibara) can be used.

  The pullulan preferably has a weight average molecular weight of 50,000 or more, more preferably 100,000 or more, and even more preferably 150,000 or more, from the viewpoint of imparting a curling effect and excellent cosmetic durability. And from the point which provides the high catch feeling at the time of cosmetics use, and the viscosity which is easy to apply | coat to a cocoon, a thing with a weight average molecular weight of 4 million or less is preferable, and 500,000 or less is more preferable.

  Component (B) can be used singly or in combination of two or more, and the content is preferably 0.05% by mass or more in the total composition from the viewpoint of imparting a curling effect and having a long lasting makeup. 5 mass% or more is more preferable, and 1 mass% or more is still more preferable. And from the point which is excellent in makeup lasting and provides the viscosity which is easy to apply to wrinkles, 20 mass% or less is preferable, 10 mass% or less is more preferable, and 7 mass% or less is still more preferable. Moreover, 0.05-20 mass% is preferable in the whole composition, as for content of a component (B), 0.5-10 mass% is more preferable, and 1-7 mass% is still more preferable.

  In the present invention, the mass ratio (A-1) / (B) of the components (A-1) and (B) suppresses the occurrence of bleeding and mascara even when wet after application, resulting in a curling effect. Is preferably 0.1 or more, more preferably 0.4 or more, still more preferably 0.8 or more, preferably 100 or less, more preferably 20 or less, and more preferably 6 or less. Is more preferable. Moreover, 0.1-100 are preferable, as for the mass ratio (A-1) / (B) of a component (A-1) and (B), 0.4-20 are more preferable, and 0.8-6 are further. preferable.

The component (C) polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester used in the present invention has an alkyl group or alkenyl group having 8 to 22 carbon atoms, and maintains the curl effect under high humidity. Those having an alkyl group having 12 to 20 carbon atoms are preferable, and those having an alkyl group having 12 to 18 carbon atoms are more preferable from the viewpoint of not forming a bundle even when wet.
Moreover, HLB is 9 or more, and 9 or more and 15 or less are more preferable.

Here, HLB (hydrophilic-lipophilic balance <Hydrophilic-Lypophilic Balance>) indicates the molecular weight of the hydrophilic group portion in the total molecular weight of the surfactant. For nonionic surfactants, Griffin ( Griffin).
The HLB of the mixed surfactant composed of two or more kinds of nonionic surfactants is obtained as follows. The HLB of the mixed surfactant is obtained by averaging the HLB values of the nonionic surfactants based on the blending ratio.

Mixed HLB = Σ (HLBx × Wx) / ΣWx
HLBx indicates the HLB value of the nonionic surfactant X.
Wx represents the mass (g) of the nonionic surfactant X having a value of HLBx.

As component (C), polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan monooleate, polyoxyethylene coconut oil fatty acid sorbitan, polytetraoleate poly Examples thereof include oxyethylene sorbit.
More specifically, polyoxyethylene sorbitan monolaurate (6E.O.) (HLB13.3), polyoxyethylene sorbitan monolaurate (20E.O.) (HLB13.3), polyoxyethylene sorbitan monostearate ( 6E.O.) (HLB 9.6), polysoxyethylene sorbitan monostearate (20E.O.) (HLB14.9), polyoxyethylene sorbitan tristearate (20E.O.) (HLB10.5), mono Oleic acid polyoxyethylene sorbitan (6E.O.) (HLB10), monooleic acid polyoxyethylene sorbitan (20E.O.) (HLB15), tetraoleic acid polyoxyethylene sorbitan (30E.O.) (HLB10.5) ), Polyoxyethylene tetraoleate Rubitto (40E.O.) (HLB11.8), polyoxyethylene sorbit tetraoleate (60E.O.) (HLB13.8), and the like.

  The component (C) is preferably a polyoxyethylene sorbitan fatty acid ester having a fatty acid having 12 to 20 carbon atoms having an HLB of 9 or more, and a polyoxy having a fatty acid having 12 to 18 carbon atoms having an HLB of 9 or more and 15 or less. Ethylene sorbitan fatty acid esters are more preferred, and polyoxyethylene sorbitan monostearate having an HLB of 9 to 15 is still more preferred.

  Ingredient (C) can be used alone or in combination of two or more, and since it adheres uniformly to the wrinkles and forms a film after application, it has excellent makeup persistence and even when wet, water and mascara The content is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.2% by mass or more in the total composition from the point that the generation of residue is suppressed. And from the point which is excellent in makeup persistence and is excellent in the cleansing property in 40 degreeC warm water, 5 mass% or less is preferable, 3 mass% or less is more preferable, and 2.4 mass% or less is still more preferable. In addition, the content of the component (C) is preferably 0.01 to 5% by mass, more preferably 0.05 to 3% by mass, and still more preferably 0.2 to 2.4% by mass in the entire composition.

  In the present invention, the mass ratio (A-1) / (C) of the components (A-1) and (C) suppresses the occurrence of bleeding and mascara even when wet after application, resulting in a curling effect. Is preferably 0.2 or more, more preferably 1 or more, and more preferably 2.5 or more from the viewpoint of suppressing the formation of lumps, being less likely to be bundled, and being excellent in cleansing properties with warm water at 40 ° C. Preferably, 500 or less is preferable, 100 or less is more preferable, and 30 or less is still more preferable. Moreover, 0.2-500 are preferable, as for the mass ratio (A-1) / (C) of component (A-1) and (C), 1-100 are more preferable, and 2.5-30 are still more preferable.

The vaginal cosmetic of the present invention can further contain (D) an alkyl (meth) acrylate / vinyl acetate copolymer, and can further improve cleansing properties.
The (meth) alkyl acrylate / vinyl acetate copolymer is mainly composed of a monomer mixture containing an alkyl acrylate monomer and / or an alkyl methacrylate monomer and a vinyl acetate monomer. Any copolymer can be used as long as it is a copolymer obtained and is usually used in cosmetics.
The alkyl group of the alkyl (meth) acrylate may be linear or branched, preferably has 1 to 10 carbon atoms, and more preferably has 4 to 8 carbon atoms.

The component (D) alkyl (meth) acrylate / vinyl acetate copolymer has a glass transition temperature (Tg) of -10 ° C to 10 ° C, and further -5 ° C to 5 ° C. It is preferable at the point which is excellent.
The glass transition temperature (Tg) indicates a value measured by a differential scanning calorimeter.

  Component (D) can be used as a copolymer, and can also be used in the form of an emulsion or resin aqueous solution containing a copolymer after polymerization and water.

  Component (D) can be used singly or in combination of two or more, and the content is preferably 0.1% by weight or more as a solid content in the total composition, because it is excellent in cleansing properties with warm water. More preferably, it is more preferably 2% by mass or more. And even if it gets wet after application | coating, 20 mass% or less is preferable, 7 mass% or less is more preferable, and 5 mass% or less is still more preferable from the point which generation | occurrence | production of a bleed and a mascara is suppressed. Moreover, 0.1-20 mass% is preferable as solid content in content of a component (D), 1-7 mass% is more preferable, and 2-5 mass% is still more preferable.

The vaginal cosmetic of the present invention preferably further contains a solid fat (wax) that is usually used in cosmetics.
Solid fat (wax) refers to those having a melting point of 40 ° C. or higher and water-insoluble. Among them, those having a melting point of 60 ° C. or higher and 110 ° C. or lower are preferable, and one or more selected from animal waxes, vegetable waxes, mineral waxes and synthetic waxes can be used. More specifically, rice bran wax, carnauba wax, candelilla wax, beeswax, tree wax, sunflower seed wax, orange wax, lemon wax, shellac wax, ceresin, paraffin wax, microcrystalline wax, polyethylene wax, silicone wax, hydrogenated jojoba Examples include oil, snow wax, and synthetic beeswax. Of these, rice bran wax, carnauba wax, candelilla wax, beeswax, sunflower seed wax, and microcrystalline wax are preferred from the standpoint that makeup persistence and generation of bleeding and mascara are suppressed even when wet after application. .

  The solid fat (wax) can be used singly or in combination of two or more, and even if it is wetted with water after application and makeup persistence, the content of The total composition is preferably 1% by mass or more, more preferably 2% by mass or more, further preferably 3% by mass or more, still more preferably 5% by mass or more, more preferably 40% by mass or less, and more preferably 35% by mass or less. Preferably, 30 mass% or less is still more preferable, and 15 mass% or less is still more preferable. . The solid fat content is preferably 1 to 40% by mass in the total composition, more preferably 2 to 35% by mass, still more preferably 3 to 30% by mass, and even more preferably 5 to 15% by mass. preferable.

The vaginal cosmetic composition of the present invention further comprises components usually used in cosmetics, for example, spherical powders such as polymethyl methacrylate powder, nylon powder, and silica; white pigment, organic pigment, inorganic pigment, iron oxide, carbon black Pigment powders such as titanium mica; powders such as bentonite, talc, kaolin, and the like, and fibers can be included to enhance the long rush effect.
Various powders are used which are surface-treated with silicone, higher fatty acid, higher alcohol, fatty acid ester, metal soap, amino acid, alkylsilane, acrylic silicone, fluorine compound, etc., or those encapsulated in organic or inorganic microcapsules. be able to.
One kind or two or more kinds of powders can be used, and it is preferable to contain 1% by mass or more and 10% by mass or less in the total composition.

  The vaginal cosmetics of the present invention further include surfactants other than those described above, oily components, water-soluble solvents, film agents, inorganic salts, ultraviolet absorbers, ultraviolet scattering agents, humectants, dyes, perfumes, antioxidants, A sequestering agent or the like can be contained.

The vaginal cosmetic of the present invention is an oil-in-water emulsified and dispersed type having one or more selected from water and an aqueous solvent as a continuous phase.
The vaginal cosmetic of the present invention can be produced by uniformly mixing and stirring each component according to a normal method.

As a component (A), when using a film-forming agent comprising a (meth) alkyl acrylate copolymer emulsion,
(A) (meth) alkyl acrylate copolymer emulsion, (A-1) alkyl (meth) acrylate containing 30% by mass or more of (meth) alkyl acrylate copolymer emulsion having a particle diameter of 10 to 50 nm The copolymer emulsion is 1 to 30% by mass as a solid content,
(B) Pullulan, and (C) polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms, wherein HLB is 9 or more, and stirring. Can be manufactured.

  The vaginal cosmetic of the present invention can be a mascara, a mascara base, a mascara top coat or the like, and mascara is preferred among them.

The salmon cosmetic of the present invention is an applicator usually used for mascara, for example, a brush in which fibers are twisted with a wire, an applicator having a comb shape, a coil shape, etc., a resin-molded brush formed into a brush shape using a resin, etc. Can be applied. By using such an applicator, it can be applied uniformly, so that it has water resistance, excellent makeup sustainability, and cleansing properties with warm water can be further improved. In addition, cleansing property means the washing | cleaning property or the ease of washing | cleaning of the cosmetics for glazing with 40 degreeC warm water.
This invention discloses the following compositions further regarding embodiment mentioned above.

<1> The following components (A), (B) and (C):
(A) Film-forming agent comprising a (meth) alkyl acrylate copolymer emulsion 1 to 30% by mass as a solid content,
(B) Pullulan,
(C) A polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms whose HLB is 9 or more, and in component (A), (A-1) An oil-in-water vaginal cosmetic in which the film-forming agent comprising a (meth) alkyl acrylate copolymer having a particle size of 10 to 50 nm is 30% by mass or more.

<2> The content of component (B) is preferably 0.05% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and preferably 20% by mass or less in the total composition. 10% by mass or less is more preferable, and 7% by mass or less is more preferable.
The content of <3> component (C) is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.2% by mass or more, and 5% by mass or less in the entire composition. Is preferable, 3 mass% or less is more preferable, 2.4 mass% or less is still more preferable The cosmetics for vaginals as described in said <1> or <2>.

<4> The mass ratio (A-1) / (B) of the components (A-1) and (B) is preferably 0.1 or more, more preferably 0.4 or more, still more preferably 0.8 or more, 100 or less is preferable, 20 or less is more preferable, and 6 or less is still more preferable, The cosmetics for wrinkles in any one of said <1>-<3>.
<5> The mass ratio (A-1) / (C) of the components (A-1) and (C) is preferably 0.2 or more, more preferably 1 or more, further preferably 2.5 or more, and 500 or less. Is preferable, 100 or less is more preferable, and 30 or less is more preferable. <1>-<4>.
<6> The cosmetic for make-up according to any one of <1> to <5>, wherein the component (C) is preferably a polyoxyethylene sorbitan fatty acid ester having an alkyl group having 12 to 20 carbon atoms and having an HLB of 9 or more. Fee.

<7> The cosmetic for vaginal skin according to any one of <1> to <6>, further comprising (D) an alkyl (meth) acrylate / vinyl acetate copolymer.
<8> Further, it is preferable to contain solid fat, and the content is preferably 1% by mass or more, more preferably 2% by mass or more, further preferably 3% by mass or more, and 5% by mass or more in the total composition. Is more preferably 40% by mass or less, more preferably 35% by mass or less, still more preferably 30% by mass or less, and still more preferably 15% by mass or less, according to any one of the above items <1> to <7>. Cosmetic for salmon.

<9> In the component (A), (A-1) the film-forming agent composed of an alkyl (meth) acrylate copolymer having a particle diameter of 10 to 50 nm is 30% by mass or more, preferably 35% by mass or more, The vaginal cosmetic according to any one of <1> to <8>, wherein 40% by mass or more is more preferable.
<10> The following components (A), (B) and (C):
(A) (meth) alkyl acrylate copolymer emulsion, (A-1) alkyl (meth) acrylate containing 30% by mass or more of (meth) alkyl acrylate copolymer emulsion having a particle diameter of 10 to 50 nm The copolymer emulsion is 1 to 30% by mass as a solid content,
(B) Pullulan, and (C) polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms, wherein HLB is 9 or more, and stirring. An oil-in-water cosmetic for cosmetics manufactured by

Examples 1-15, Comparative Examples 1-5
Manufactures mascara (oil-in-water type) with the composition shown in Tables 1 and 2 and “does not bleed even when wet”, “fiber or mascara does not fall on the lower eyelid even when wet”, “ Sensory evaluation was made of “it does not become lumpy even when wet”, “easy to cleanse with warm water at 40 ° C.”, and “it does not become a bundle even when wet with water”, and the curl keeping power under high humidity was evaluated. The results are shown in Table 1 and Table 2 together.

(Production method)
An oil-in-water mascara was produced by uniformly stirring and mixing the components.

(Evaluation method)
(1) Sensory evaluation:
10 female panelists who use eye drops at least 3 times a day have their oil-in-water mascara applied to their heels. Sensory evaluation was performed according to the following criteria for “not falling on the lower eyelid”, “not getting lumped when wet with water”, “easy to cleanse with warm water at 40 ° C.” and “not getting bundled when wet with water”. Results are shown as a total of 10 people (maximum 50 points minimum 10 points).

(1-1) Does not bleed when wet:
After applying, apply eye drops twice in 8 hours, and then immediately after 8 hours, apply eye drops once. Visually evaluate the state at that time and evaluate from the viewpoint of whether the bottom of the eyes is black due to bleeding. Went.
5: Does not bleed.
4: Almost no blurring.
3: Neither can be said.
2: Slightly blur.
1: Smear.

(1-2) Fiber and mascara do not fall on the lower eyelid even when wet.
From the point of view of whether or not mascara is not falling on the skin, apply eye drops twice in 8 hours after application, and immediately after 8 hours, apply eye drops once. Evaluation was performed.
5: Waste does not fall.
4: Dregs hardly fall off.
3: Neither can be said.
2: The residue falls slightly.
1: Waste falls.

(1-3) Even if it gets wet, it doesn't become lumpy:
After applying, apply eye drops twice in 8 hours, and then immediately after 8 hours, apply eye drops once, and visually evaluate the state at that time and evaluate from the point of view whether or not it is lumpy It was.
5: Don't be ridiculous.
4: Almost no waste.
3: Neither can be said.
2: Slightly stupid.
1: Become a trash.

(1-4) Easy to cleanse with warm water of 40 ° C .:
Evaluation was carried out according to the remaining mascara remaining when cleansing with tap water set at 40 ° C.
5: Cleansing is very fast.
4: Cleansing is fast.
3: Neither can be said.
2: Cleansing is slow.
1: Cleansing is very slow.

(1-5) Even if it gets wet, it doesn't become a bundle:
After applying, apply eye drops twice in 8 hours, and then immediately after 8 hours, drop eye drops once, visually evaluate the state at that time, and evaluate from the viewpoint of whether it is not bundled It was.
5: Not bundled.
4: Almost no bundle.
3: Neither can be said.
2: Slightly bundled.
1: Become a bundle.

(2) Curl keeping power under high humidity:
Take 30 hairs with a length of 0.7-0.8 cm, fix them horizontally and set as shown in FIG. Using a buller, make the hair 60 ° from the side, and apply each oil-in-water mascara 5 times using a mascara brush (outside diameter 5.0 mm), nylon (4 mil), sword diameter (3.4 mm). After standing at 40 ° C. and 75% humidity for 7 hours, the curl angle from the side was measured.

Example 16 (mascara)
An oil-in-water mascara having the following composition was produced by uniformly stirring and mixing the components.
Even when the obtained mascara is wet with water after application, the occurrence of bleeding and mascara is suppressed, it is difficult to cause lumps and bundles, and has high curl keeping power. Moreover, it is excellent in cleansing properties with warm water of 40 ° C.

(component)
Alkyl acrylate copolymer emulsion * 1 20.7 (mass%)
Alkyl acrylate copolymer emulsion * 2 9.5
Pullulan * 3 3.5
Polyoxyethylene sorbitan monostearate (20E.O.) * 4 1.2
Alkyl acrylate / vinyl acetate copolymer emulsion * 10 7.0
Carnauba wax * 11 3.0
Sunflower seed wax * 16 2.0
Beeswax * 12 15.0
Rice bran * 13 1.0
Candelilla Row * 14 1.0
High melting point microcrystalline wax * 15 3.0
Fatty acid (C20-40)) * 17 0.75
Behenic acid 3.0
Stearic acid 3.0
Palmitic acid 1.5
Triethanolamine 0.86
1,3-butylene glycol 3.0
Water Balanced methyl paraoxybenzoate 0.3
Phenoxyethanol 0.3
Black iron oxide 8.5
Total 100
* 16: Sunflower wax (manufactured by Koster Keunen Holland bv)
* 17: Performacid 350ACID (manufactured by New Phase Technology)

Claims (8)

The following components (A), (B) and (C):
(A) Film-forming agent comprising an alkyl (meth) acrylate copolymer The solid content is 1 to 30% by mass,
(B) Pullulan,
(C) A polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms whose HLB is 9 or more, and in component (A), (A-1) An oil-in-water vaginal cosmetic in which the film-forming agent comprising a (meth) alkyl acrylate copolymer having a particle size of 10 to 50 nm is 30% by mass or more.   The vaginal cosmetic according to claim 1, comprising 0.05 to 20% by mass of the component (B).   The cosmetic for salmon according to claim 1 or 2, comprising 0.01 to 5% by mass of the component (C).   The vaginal cosmetic according to any one of claims 1 to 3, wherein the mass ratio (A-1) / (B) of the components (A-1) and (B) is 0.1 to 100.   The weight ratio (A-1) / (C) of component (A-1) and (C) is 0.2-500, The cosmetics for wrinkles of any one of Claims 1-4.   The cosmetic for cosmetics according to any one of claims 1 to 5, wherein the component (C) is a polyoxyethylene sorbitan fatty acid ester having an alkyl group having 12 to 20 carbon atoms and having an HLB of 9 or more.   Furthermore, (D) the cosmetics for glazing of any one of Claims 1-6 containing the (meth) acrylic-acid alkyl-vinyl acetate copolymer. The following components (A), (B) and (C):
(A) (meth) alkyl acrylate copolymer emulsion, (A-1) alkyl (meth) acrylate containing 30% by mass or more of (meth) alkyl acrylate copolymer emulsion having a particle diameter of 10 to 50 nm The copolymer emulsion is 1 to 30% by mass as a solid content,
(B) Pullulan, and (C) polyoxyethylene sorbitan fatty acid ester or polyoxyethylene sorbitol fatty acid ester having an alkyl group or alkenyl group having 8 to 22 carbon atoms, wherein HLB is 9 or more, and stirring. An oil-in-water cosmetic for cosmetics manufactured by