JP2017132732A - Eyelashes cosmetics - Google Patents
Eyelashes cosmetics Download PDFInfo
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- JP2017132732A JP2017132732A JP2016015733A JP2016015733A JP2017132732A JP 2017132732 A JP2017132732 A JP 2017132732A JP 2016015733 A JP2016015733 A JP 2016015733A JP 2016015733 A JP2016015733 A JP 2016015733A JP 2017132732 A JP2017132732 A JP 2017132732A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 37
- 210000000720 eyelash Anatomy 0.000 title claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000004927 clay Substances 0.000 claims abstract description 8
- 239000002798 polar solvent Substances 0.000 claims abstract description 6
- -1 fatty acid ester Chemical class 0.000 claims description 19
- 229940008099 dimethicone Drugs 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 6
- 229920006037 cross link polymer Polymers 0.000 claims description 5
- 229920002050 silicone resin Polymers 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 3
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- 229910000271 hectorite Inorganic materials 0.000 description 4
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- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- AQKOHYMKBUOXEB-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-(16-methylheptadecanoyloxy)oxolan-2-yl]-2-(16-methylheptadecanoyloxy)ethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCC(C)C)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC(C)C AQKOHYMKBUOXEB-RYNSOKOISA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229940009868 aluminum magnesium silicate Drugs 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
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- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- FWLORMQUOWCQPO-UHFFFAOYSA-N benzyl-dimethyl-octadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 FWLORMQUOWCQPO-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
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- 239000003599 detergent Substances 0.000 description 1
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
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- 239000003995 emulsifying agent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
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- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
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- LAPRIVJANDLWOK-UHFFFAOYSA-N laureth-5 Polymers CCCCCCCCCCCCOCCOCCOCCOCCOCCO LAPRIVJANDLWOK-UHFFFAOYSA-N 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、成分中にシリコーン樹脂を含有し、かつ水の含有量が0.5質量%以下であり、カールキープ力があり、耐水性がありながらも温水で化粧を落とすことが容易であることを特徴とする睫毛化粧料に関する。 The present invention contains a silicone resin in the components and has a water content of 0.5% by mass or less, has a curl keeping power, and is easy to remove makeup with warm water while having water resistance. It is related with the eyelash cosmetic characterized by this.
従来、睫毛化粧料(マスカラ、アイメイクアップ化粧料)は耐水性やカールキープ力を重視する油性材料で構成されるウォータープルーフタイプ(以下WPタイプ)、専用リムーバーなどを必要せず、温水で化粧を落とすことが可能で簡便なクレンジング性を重視するフィルムタイプ(FMタイプ)がある。しかし近年、耐水性やカールキープ力を備え、簡便に化粧を落とすことができるようなニーズが求められているが、それを満たすようなものはない。 Conventionally, eyelash cosmetics (mascara and eye makeup cosmetics) are made with warm water without the need for a waterproof type (hereinafter referred to as WP type) composed of an oil-based material that emphasizes water resistance and curl-keeping power. There is a film type (FM type) that emphasizes easy cleansing properties. However, in recent years, there has been a demand for water resistance and curl keeping power that can easily remove makeup. However, there is no one that satisfies them.
従来、WPタイプでは、シリコーン樹脂を使用して皮膜形成させるもの(特許文献1)、デキストリン脂肪酸エステルを使用して皮膜形成させるもの(特許文献2)などがある。しかし、化粧を落とすにはオイルクレンジング剤や専用メイクリムーバーが必須で市場ニーズを満たすものではない。その中で市場にあるWPタイプの睫毛化粧料はカールキープ力を求めるためにシリコーン樹脂を含むものが多い。 Conventionally, in the WP type, there are a film forming using a silicone resin (Patent Document 1) and a film forming using a dextrin fatty acid ester (Patent Document 2). However, in order to remove makeup, oil cleansing agents and exclusive makeup removers are essential and do not meet market needs. Among them, WP type eyelash cosmetics on the market often contain a silicone resin in order to obtain curl keeping power.
また、FMタイプでは水を基材として、アクリルエマルジョンを使用して皮膜形成させるもの(特許文献3)、ウレタンエマルジョンを使用して皮膜形成させるもの(特許文献4)などがある。これらはマスカラを落とすことが簡便であるが、カールキープ力はWPタイプと比較して、大きく劣ってしまい、市場ニーズを満たすものではない。さらには両機能を併せ持つような提案がなされている(特許文献5)が、結局は市場が求める十分なカールキープ力を満たすものではないのに加え、オイルクレンジングを必要としている。 The FM type includes water as a base material and a film formed using an acrylic emulsion (Patent Document 3), and a film formed using a urethane emulsion (Patent Document 4). Although it is easy to drop the mascara, the curl keeping force is greatly inferior to the WP type and does not satisfy the market needs. Further, a proposal has been made to have both functions (Patent Document 5), but eventually it does not satisfy the sufficient curl-keeping force required by the market, and requires oil cleansing.
カールキープ力、耐水性があり、かつ温水で落とすことが容易である睫毛化粧料のニーズがあるが、それは未だ満たされていない。 There is a need for eyelash cosmetics that have curl-keeping power, water resistance, and are easy to remove with warm water, but it is not yet met.
鋭意研究の結果、本願発明者は、上記課題を解決する本発明の睫毛化粧料を見出した。すなわち、
(A)皮膜形成性シリコーン化合物、
(B)有機変性粘土化合物、
(C)親水性界面活性剤、及び
(D)非プロトン性極性溶剤
を含有し、水の含有量が0.5質量%以下である、睫毛化粧料である。
As a result of intensive studies, the present inventors have found the eyelash cosmetic of the present invention that solves the above-mentioned problems. That is,
(A) a film-forming silicone compound,
(B) an organically modified clay compound,
(C) A hydrophilic surfactant and (D) an aprotic polar solvent, and a water content of 0.5% by mass or less.
本発明の睫毛化粧料は、カールキープ力、耐水性があり、温水で化粧を落とすことが容易である。 The eyelash cosmetic of the present invention has curl keeping power and water resistance, and it is easy to remove makeup with warm water.
本発明には種々の代替形態が可能であるが、本明細書では本発明の特定の態様について詳述する。しかしながら、本明細書における特定の態様の記述は、本発明を特定の形態に限定しようと意図するものではなく、本発明は特許請求の範囲に規定した本発明の真意および範囲に含まれる全ての代替形を包含できる。 While the invention is susceptible to various alternatives, specific details of the invention are described in detail herein. However, the description of specific embodiments in this specification is not intended to limit the present invention to a specific form, and the present invention is intended to cover all within the spirit and scope of the invention as defined by the claims. Alternative forms can be included.
定義
[睫毛化粧料]
睫毛(まつげ)化粧料とは、マスカラ、アイメイクアップ化粧料とも呼ばれ、睫毛を濃く、長く、又はカールしているように見せるためのものである。
Definition [lash cosmetic]
Eyelash cosmetics are also called mascara and eye makeup cosmetics, and are intended to make the eyelashes appear dark, long, or curled.
本発明の睫毛化粧料の形態は特に限定されない。例えば液状、乳液状、ジェル状、クリーム状、固形状等が挙げられる。 The form of the eyelash cosmetic of the present invention is not particularly limited. Examples thereof include liquid, emulsion, gel, cream and solid.
[皮膜形成性シリコーン化合物]
本発明の睫毛化粧料は一種又は二種以上の皮膜形成性シリコーン化合物を含有し、その含有量は0.1質量%〜40質量%であり、好ましくは1質量%〜30質量%であり、より好ましくは3質量%〜20質量%である。0.1質量%以下であると良好なカール力が得られず、40質量%以上であるとマスカラ皮膜を温水で容易に落とすことができない。シリコーン樹脂は化粧品上許容されるものであれば良い。その一例として以下の物質があげられ、これらのうち一種または二種以上が任意に選択されるが、それに特に限定されなく誘導体でも構わない。:シリコーン架橋重合体、シリコーンブロック共重合体、シリコーングラフト共重合体、シリコーンクロスポリマー、シリコーンガムなどの高重合ジメチコン、シリコーンワックス、末端又は側鎖をシリル化変性した重合体(シリコーン化多糖化合物など)などがある。さらに具体例として以下の物質があげられる:トリメチルシロキシケイ酸、ポリメチルシルセスキオキサン、ポリプロピルシルセスキオキサン、ポリフェニルシルセスキオキサン、(アクリレーツ/ジメチコン)コポリマー、(アクリレーツ/メタクリル酸ポリトリメチルシロキシ)コポリマー、(ジメチコン/ビニルトリメチルシロキシケイ酸)クロスポリマー、トリ(トリメチルシロキシ)シリルプロピルカルバミド酸プルラン。
[Film-forming silicone compound]
The eyelash cosmetic of the present invention contains one or more film-forming silicone compounds, and the content thereof is 0.1% by mass to 40% by mass, preferably 1% by mass to 30% by mass, More preferably, it is 3 mass%-20 mass%. If it is 0.1% by mass or less, good curling force cannot be obtained, and if it is 40% by mass or more, the mascara film cannot be easily removed with warm water. Any silicone resin may be used as long as it is cosmetically acceptable. Examples thereof include the following substances, and one or two or more of these substances are arbitrarily selected, but are not particularly limited thereto and may be a derivative. : Highly polymerized dimethicone such as silicone cross-linked polymer, silicone block copolymer, silicone graft copolymer, silicone cross polymer, silicone gum, silicone wax, polymer with silylated modification of terminal or side chain (siliconized polysaccharide compound, etc. )and so on. Specific examples include the following materials: trimethylsiloxysilicic acid, polymethylsilsesquioxane, polypropylsilsesquioxane, polyphenylsilsesquioxane, (acrylates / dimethicone) copolymer, (acrylates / polytrimethyl methacrylate). Siloxy) copolymer, (dimethicone / vinyltrimethylsiloxysilicic acid) crosspolymer, pullulan tri (trimethylsiloxy) silylpropylcarbamate.
[有機変性粘土化合物]
本発明の睫毛化粧料は一種又は二種以上の有機変性粘土化合物を含有し、その含有量は0.1質量%〜25質量%であり、好ましくは1質量%〜20質量%であり、より好ましくは3質量%〜15質量%である。0.1質量%以下であると期待されるカール力が得られず、使用感が悪化する。また25質量%以上であると滑らかな使用感が得られず、使用感が悪化する。有機変性粘土化合物は化粧品上許容されるものであれば特に限定されない。例えば、モンモリロナイト、バイデライト、ノントロナイト、サポナイト、ヘクトライト等の天然あるいは合成の粘土鉱物を第4級アンモニウム塩型カチオン界面活性剤で変性した化合物である。その例として以下の物質が挙げられるがそれに限定されない:ジメチルアルキルアンモニウムヘクトライト、ベンジルジメチルステアリルアンモニウムヘクトライト、ジメチルジステアリルアンモニウムヘクトライト、塩化ジステアリルジメチルアンモニウム処理ケイ酸アルミニウムマグネシウム。
[Organic modified clay compound]
The eyelash cosmetic of the present invention contains one or more organically modified clay compounds, and the content thereof is 0.1% by mass to 25% by mass, preferably 1% by mass to 20% by mass, and more. Preferably they are 3 mass%-15 mass%. The curling force expected to be 0.1% by mass or less cannot be obtained, and the usability is deteriorated. On the other hand, if it is 25% by mass or more, a smooth feeling of use cannot be obtained, and the feeling of use deteriorates. The organically modified clay compound is not particularly limited as long as it is cosmetically acceptable. For example, it is a compound obtained by modifying a natural or synthetic clay mineral such as montmorillonite, beidellite, nontronite, saponite, hectorite or the like with a quaternary ammonium salt type cationic surfactant. Examples include, but are not limited to, the following materials: dimethylalkylammonium hectorite, benzyldimethylstearylammonium hectorite, dimethyldistearylammonium hectorite, distearyldimethylammonium chloride treated aluminum magnesium silicate.
[親水性界面活性剤]
本発明の睫毛化粧料は一種又は二種以上の親水性界面活性剤を含有し、その含有量は0.1質量%〜25質量%であり、好ましくは1質量%〜10質量%であり、より好ましくは3質量%〜8質量%である。0.1質量%以下であると乾燥したマスカラ皮膜は温水で容易に落とすことができず、また25質量%以上であるとマスカラ皮膜強度が弱くなり、求められるカール力を満たすことができない。親水性界面活性剤は化粧品上許容されるものであれば特に限定されない。その例としてカチオン性界面活性剤、アニオン性界面活性剤、両性界面活性剤、及び非イオン性界面活性剤が挙げられる。好ましくは非イオン性界面活性剤である。
[Hydrophilic surfactant]
The eyelash cosmetic of the present invention contains one or more hydrophilic surfactants, and the content thereof is 0.1% by mass to 25% by mass, preferably 1% by mass to 10% by mass, More preferably, it is 3 mass%-8 mass%. If it is 0.1% by mass or less, the dried mascara film cannot be easily removed with warm water, and if it is 25% by mass or more, the mascara film strength becomes weak and the required curling force cannot be satisfied. The hydrophilic surfactant is not particularly limited as long as it is cosmetically acceptable. Examples thereof include cationic surfactants, anionic surfactants, amphoteric surfactants, and nonionic surfactants. Nonionic surfactants are preferred.
また、親水性界面活性剤のHLBは7以上、10以上、又は14以上であってよいがそれに限定されない。好ましくはHLB7以上の非イオン性界面活性剤である。 Further, the HLB of the hydrophilic surfactant may be 7 or more, 10 or more, or 14 or more, but is not limited thereto. Preferably, it is a nonionic surfactant of HLB7 or higher.
[非イオン性界面活性剤]
上記の非イオン性界面活性剤は化粧品上許容されるものであれば特に限定されない。その例として以下の物質が挙げられるが、それに限定されない:ポリオキシエチレン(20)セチルエーテル、ポリオキシエチレン(2)セチルエーテル、ポリオキシエチレン(5)ラウリルエーテル等のポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン・ポリオキシプロピレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンプロピレングリコール脂肪酸エステル、脂肪族アルカノールアミド、ポリエーテル変性シリコーン、ポリグリセリン変性シリコーン。
[Nonionic surfactant]
The nonionic surfactant is not particularly limited as long as it is cosmetically acceptable. Examples include, but are not limited to, the following materials: polyoxyethylene (20) cetyl ether, polyoxyethylene (2) cetyl ether, polyoxyethylene alkyl ethers such as polyoxyethylene (5) lauryl ether, poly Oxyethylene alkylphenyl ether, polyoxyethylene / polyoxypropylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, aliphatic alkanolamide, polyether-modified silicone, polyglycerin-modified silicone.
[ポリオキシエチレンソルビタン脂肪酸エステル]
上記のポリオキシエチレンソルビタン脂肪酸エステルは化粧品上許容されるものであれば特に限定されない。その例として以下の物質が挙げられるが、それに限定されない:ポリソルベート21、PEG−20ソルビタンココエート、ポリソルベート40、ステアリン酸PEG−6ソルビタン、ポリソルベート60、ポリソルベート65、オレイン酸PEG−6ソルビタン、イソステアリン酸PEG−20ソルビタン、ポリソルベート80、ポリソルベート85、トリイソステアリン酸PEG−160ソルビタン、PEG−20ソルビタンココエート。
[Polyoxyethylene sorbitan fatty acid ester]
The polyoxyethylene sorbitan fatty acid ester is not particularly limited as long as it is cosmetically acceptable. Examples include, but are not limited to, the following materials: polysorbate 21, PEG-20 sorbitan cocoate, polysorbate 40, PEG-6 sorbitan stearate, polysorbate 60, polysorbate 65, PEG-6 sorbitan oleate, PEG-isostearate 20 sorbitan, polysorbate 80, polysorbate 85, PEG-160 sorbitan triisostearate, PEG-20 sorbitan cocoate.
[ポリエーテル変性シリコーン]
上記のポリエーテル変性シリコーンは化粧品上許容されるものであれば特に限定されない。その例として以下の物質が挙げられるが、それに限定されない:PEG−11メチルエーテルジメチコン、PEG/PPG−20/22ブチルエーテルジメチコン、PEG−9ジメチコン、PEG−3ジメチコン、PEG−9メチルエーテルジメチコン、PEG−10ジメチコン、PEG−32メチルエーテルジメチコン。
[Polyether-modified silicone]
The polyether-modified silicone is not particularly limited as long as it is cosmetically acceptable. Examples include, but are not limited to, the following materials: PEG-11 methyl ether dimethicone, PEG / PPG-20 / 22 butyl ether dimethicone, PEG-9 dimethicone, PEG-3 dimethicone, PEG-9 methyl ether dimethicone, PEG -10 dimethicone, PEG-32 methyl ether dimethicone.
[ポリグリセリン変性シリコーン]
上記のポリグリセリン変性シリコーンは化粧品上許容されるものであれば特に限定されない。その例として以下の物質が挙げられるが、それに限定されない:ポリグリセリル−3ジシロキサンジメチコン、ポリグリセリル−3ポリジメチルシロキシエチルジメチコン。
[Polyglycerin-modified silicone]
The polyglycerin-modified silicone is not particularly limited as long as it is cosmetically acceptable. Examples include, but are not limited to, the following materials: polyglyceryl-3 disiloxane dimethicone, polyglyceryl-3 polydimethylsiloxyethyl dimethicone.
[非プロトン性極性溶剤]
本発明の睫毛化粧料は一種又は二種以上の非プロトン性極性溶剤を含有し、その含有量は限定されない。その含有量は0.1質量%〜15質量%であり、好ましくは0.5質量%〜10質量%であり、より好ましくは1質量%〜7質量%である。0.1質量%以下であると、期待されるカール力が得られず、15質量%以上であると滑らかな使用感が得られず、使用感が悪化する。非プロトン性極性溶剤は化粧品上許容されるものであれば特に限定されない。その例として以下の物質が挙げられるがそれに限定されない:炭酸プロピレン、クエン酸トリエチル、乳酸オクチルドデシル、リンゴ酸ジイソステアリル、イソステアリン酸ポリグリセリル−2、ジイソステアリン酸ポリグリセリル−2、トリイソステアリン酸ポリグリセリル−2、(イソステアリン酸/セバシン酸)ジトリメチロールプロパンオリゴエステル、トリエチルヘキサン酸エリスリチル、トリポリヒドロキシステアリン酸ジペンタエリスリチル、イソステアリン酸トレハロースエステルズ、ペンタイソステアリン酸ジペンタエリスリチル、ヒドロキシステアリン酸エチルヘキシル、ポリヒドロキシステアリン酸。
[Aprotic polar solvent]
The eyelash cosmetic of the present invention contains one or more aprotic polar solvents, and the content thereof is not limited. The content is 0.1% by mass to 15% by mass, preferably 0.5% by mass to 10% by mass, and more preferably 1% by mass to 7% by mass. When it is 0.1% by mass or less, the expected curling force cannot be obtained, and when it is 15% by mass or more, a smooth feeling of use cannot be obtained and the feeling of use deteriorates. The aprotic polar solvent is not particularly limited as long as it is cosmetically acceptable. Examples include, but are not limited to, the following materials: propylene carbonate, triethyl citrate, octyldodecyl lactate, diisostearyl malate, polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, (Istearic acid / sebacic acid) ditrimethylolpropane oligoester, erythrityl triethylhexanoate, dipentaerythrityl tripolyhydroxystearate, trehalose esters of isostearate, dipentaerythrityl pentaisostearate, ethylhexyl hydroxystearate, polyhydroxystearic acid.
また、期待されるカールキープ力及び/又は滑らかな使用感のためには、非プロトン性極性油剤の粘度が25℃で1000mPas以下であることが好ましい。 Further, for the expected curl-keeping force and / or smooth use feeling, the viscosity of the aprotic polar oil is preferably 1000 mPas or less at 25 ° C.
本発明の睫毛化粧料において、水の含有量が0.5質量%以下である。これは、睫毛化粧料が水を含有しない又は0.5質量%以下の水を含有することを意味する。水を含有する場合、意図的に加えてもよく、不可避な吸湿作用により含有されてもよい。その含有量は、0.5質量%未満であってもよく、0.3質量%以下/未満であってもよく、0.2質量%以下/未満であってもよく、0.1質量%以下/未満であってもよい。水を0.5質量%より多く含有すると粘度の調整が難しいだけでなく、期待するカール力が得られない。 In the eyelash cosmetic of the present invention, the water content is 0.5% by mass or less. This means that the eyelash cosmetic does not contain water or contains 0.5% by mass or less of water. When water is contained, it may be added intentionally or may be contained by an inevitable hygroscopic action. The content thereof may be less than 0.5% by mass, may be 0.3% by mass or less / less than, may be 0.2% by mass or less / less than, and may be 0.1% by mass. Below / less than. When water is contained in an amount of more than 0.5% by mass, it is difficult to adjust the viscosity, and an expected curling force cannot be obtained.
本発明の睫毛化粧料は、本発明の効果を損ねない限り、更に公知の化粧料原料であって配合可能であると当業者が通常考えるものを一種又は二種以上含有してもよい。例えば、揮発性油剤、界面活性剤、ゲル化剤、抗ケーキング剤、乳化剤、分散化剤、安定剤、保湿剤、増粘剤、固形化剤、結合剤、増量剤、不透明化剤、滑沢剤、顔料、紫外線散乱剤、紫外線吸収剤、pH調整剤、抗酸化剤、抗菌剤、防腐剤、スキンケア剤、潤滑剤、収斂剤、エモリエント剤、ツヤ出し剤、光沢剤、消泡剤、撥水性被膜剤、保護剤等が挙げられる。これら2つ以上の用途・効果が重複しているものも使用出来る。 The eyelash cosmetic of the present invention may further contain one or more of those known to those skilled in the art as a known cosmetic raw material that can be formulated as long as the effects of the present invention are not impaired. For example, volatile oils, surfactants, gelling agents, anti-caking agents, emulsifiers, dispersing agents, stabilizers, humectants, thickeners, solidifying agents, binders, extenders, opacifiers, lubricants Agents, pigments, UV scattering agents, UV absorbers, pH adjusters, antioxidants, antibacterial agents, antiseptics, skin care agents, lubricants, astringents, emollients, glossing agents, brighteners, antifoaming agents, repellents An aqueous film agent, a protective agent, etc. are mentioned. Those in which two or more uses / effects overlap can be used.
本発明の睫毛化粧料において、本発明の成分(A)〜(D)以外の不揮発性油剤の含有量が5質量%以下であってもよい。これは、睫毛化粧料が不揮発性油剤を含有しない又は5質量%以下の不揮発性油剤を含有することを意味する。その含有量は5質量%以下であってもよく、3質量%以下であってもよく、1質量%以下であってもよい。「不揮発性」とは常温常圧で揮発しにくい性質を意味し、例えば常圧で沸点が260℃以上の性質を意味する。好ましくは不揮発性油剤を含有しない又は不可避に混入される量のみ含有する。 In the eyelash cosmetic of the present invention, the content of the nonvolatile oil agent other than the components (A) to (D) of the present invention may be 5% by mass or less. This means that the eyelash cosmetic does not contain a non-volatile oil agent or contains 5% by mass or less of a non-volatile oil agent. The content thereof may be 5% by mass or less, 3% by mass or less, or 1% by mass or less. “Non-volatile” means a property that does not easily volatilize at normal temperature and pressure, for example, a property having a boiling point of 260 ° C. or higher at normal pressure. Preferably, the non-volatile oil agent is not contained or contained only in an amount inevitably mixed.
本発明の睫毛化粧料は、当業者の技術常識に従い慣用の処方例に従って製造出来る。各成分を配合する方法、順序等は当業者の技術常識に従い任意である。 The eyelash cosmetics of the present invention can be produced according to common formulation examples according to the common technical knowledge of those skilled in the art. The method of mixing each component, the order, etc. are arbitrary according to the common general knowledge of those skilled in the art.
以下、具体例を挙げて本発明を更に詳細に説明するが、これらの実施例は本発明の技術的範囲を何ら限定するものではない。当業者は要求されるカールキープ力、温水洗浄容易性、その他の条件に応じて適宜配合を調整できる。なお、以下の実施例及び比較例における配合量(含有量)は全て質量%である。 Hereinafter, the present invention will be described in more detail with specific examples, but these examples do not limit the technical scope of the present invention. A person skilled in the art can appropriately adjust the formulation according to the required curl keeping power, ease of washing with hot water, and other conditions. In addition, all the compounding quantities (contents) in the following Examples and Comparative Examples are mass%.
(実施例及び比較例)
下記の表1に掲げた組成を有する睫毛化粧料を常法に従って調製した。これらの睫毛化粧料のカールキープ力、温水洗浄容易性及び耐水性を、以下の評価基準に基づいて評価した。例1〜4が実施例、例5〜9が比較例である。
(Examples and Comparative Examples)
Eyelash cosmetics having the compositions listed in Table 1 below were prepared according to a conventional method. These eyelash cosmetics were evaluated for curl-keeping power, hot water washability and water resistance based on the following evaluation criteria. Examples 1 to 4 are examples, and examples 5 to 9 are comparative examples.
評価基準:
<カールキープ力>
専門パネル20名による使用テストを行った。試料を睫毛に塗布し、睫毛のカールキープの状態を評価し、下記のように分類した。
◎:17名以上が、カールキープ良好と回答
○:13〜16名が、カールキープ良好と回答
△:8〜12名が、カールキープ良好と回答
×:7名以下が、カールキープ良好と回答
*カールキープとは塗布直後の睫毛のカールとの比較で4時間後、睫毛のカールの変化がないことをいう。
Evaluation criteria:
<Curl keeping power>
A use test was conducted by 20 specialist panels. The sample was applied to the eyelashes, the state of the eyelash curl was evaluated, and classified as follows.
◎: 17 or more responded that the curl keep was good ○: 13-16 responded that the curl keep was good △: 8-12 responded that the curl keep was good ×: 7 or less responded that the curl keep was good * Curl keep means that there is no change in the curl of the eyelash after 4 hours compared to the curl of the eyelash immediately after application.
<温水洗浄容易性>
調製したマスカラをガラス板に均一に塗り、室温で2時間乾燥させた。そのガラス板を40度のお湯につけ、指で擦りその洗浄容易性を評価し、下記のように分類した。
◎:すべて落ちる
○:9割程度落ちる
△:5割程度落ちる
×:落ちない
<Ease of washing with hot water>
The prepared mascara was uniformly applied to a glass plate and dried at room temperature for 2 hours. The glass plate was placed in 40 ° C. hot water and rubbed with a finger to evaluate its ease of cleaning, and classified as follows.
◎: All fall ○: About 90% fall △: About 50% fall ×: Not fall
<耐水性>
調製したマスカラをガラス板に均一に塗り、室温で2時間乾燥させた。そのガラス板を25度の水につけ、指で擦り、その皮膜耐水性を評価し、下記のように分類した。
○:皮膜片がガラス板から剥がれることがなく、つけた水に皮膜が溶出しない
×:皮膜片がガラス板から剥がれたり、つけた水に皮膜が溶出して水が濁る
The prepared mascara was uniformly applied to a glass plate and dried at room temperature for 2 hours. The glass plate was soaked in water at 25 degrees and rubbed with a finger to evaluate the water resistance of the film, and classified as follows.
○: The film piece does not peel off from the glass plate, and the film does not elute in the applied water. ×: The film piece peels off from the glass plate, or the film elutes in the applied water and the water becomes cloudy.
Claims (11)
(B)有機変性粘土化合物、
(C)親水性界面活性剤、及び
(D)非プロトン性極性溶剤
を含有し、水の含有量が0.5質量%以下である、睫毛化粧料。 (A) a film-forming silicone compound,
(B) an organically modified clay compound,
(C) A hydrophilic surfactant, and (D) An aprotic polar solvent, and a water content is 0.5% by mass or less.
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JP6097417B1 (en) * | 2016-01-16 | 2017-03-15 | ジェイオーコスメティックス株式会社 | Oily eyelash cosmetic and makeup method |
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CN108785142B (en) * | 2018-09-26 | 2021-06-04 | 深圳市裕农科技股份有限公司 | Mascara and preparation method thereof |
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