JP2014114246A - Insecticidal, acarid killing, nematode killing, mollusk killing, disinfection or bacterium killing composition and pest control method of pest - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a novel insecticidal, acarid killing, nematode killing, mollusk killing, disinfection or bacterium killing composition; and a pest control method of pest.SOLUTION: An insecticidal, acarid killing, nematode killing, mollusk killing, disinfection or bacterium killing composition includes: an isoxazoline-substituted benzamide compound represented by a formula (1) [in the formula, A, Aand Aeach independently denote a carbon atom or a nitrogen atom; G denotes a benzene ring or the like; W denotes an oxygen atom or a sulfur atom; X denotes a halogen atom, a C-Chaloalkyl or the like; Y denotes a halogen atom, a C-Calkyl or the like], and one or two or more selected from salts thereof; and one or two or more selected from well-known insecticidal, acarid killing, nematode killing, mollusk killing, disinfection or bacterium killing compounds.

Description

  The present invention comprises mixing an isoxazoline-substituted benzamide compound or a salt thereof and a known insecticide, acaricide, nematicide, molluscicide, fungicide or bactericide active ingredient compound. It relates to a pest control agent as a feature.

  The isoxazoline-substituted benzamide compounds and salts thereof represented by the following formula (1) of the present invention are known compounds, and their activity as pest control agents are known (for example, see Patent Documents 1 and 2). .

  In addition, the compounds described as the compound group A having the insecticidal activity, acaricidal activity, nematicidal activity, molluscicidal activity, bactericidal activity or bactericidal activity, which are the second active ingredient compounds in the present invention, are all It is publicly known (for example, refer nonpatent literature 1).

Further, the isoxazoline-substituted benzamide compound represented by the following formula (1) of the present invention and a salt thereof, and certain known insecticides, acaricides, nematicides, molluscicides, fungicides or fungicides. A composition containing an active ingredient compound of a bacterial agent is known (see, for example, Patent Documents 3, 4 and 5).
International Publication No. 2005/085216 Pamphlet International Publication No. 2007/026965 Pamphlet JP 2009-108046 A JP2012-153620A JP 2012-153621 A The Pesticide Manual, 14th edition, The British Crop Protection Council, 2006

  Today, the development of insecticides, acaricides and fungicides for the control of various pests such as agricultural and horticultural pests, forest pests, and hygiene pests is widely promoted, and a wide variety of drugs are put into practical use. However, in recent years, as a result of the long-term use of such drugs, pests have acquired insecticide resistance, and pathogens have acquired fungicide resistance. As a result, there are increasing situations in which it is difficult to control with conventional drugs. Some of these drugs are highly toxic and some are perturbing the ecosystem by remaining in the environment for a long time. Therefore, development of a novel drug having not only a high pest control effect but also low toxicity and low persistence is always expected.

  On the other hand, considering the diversity of insects and pathogens as a group of organisms, the mode of damage, and the variety of scenes of harm, all these control scenes can be achieved simply by using these new drugs or existing known drugs alone. It is very difficult to control all pests effectively. Therefore, a new method for controlling pests that are difficult to control is also strongly induced by appropriately combining multiple insecticides, acaricides, nematicides, molluscs, bactericides or bactericides to induce higher control efficacy. It has been requested.

  In view of such circumstances, the present inventors have conducted intensive research to develop a pest control agent that exhibits excellent pest control activity and has less adverse effects on non-target organisms such as mammals, fish, natural enemies, and beneficial insects. As a result, the isoxazoline-substituted benzamide compound represented by the following formula (1) or a salt thereof and certain known insecticidal, acaricidal, nematicidal, molluscicidal, compound having bactericidal or bactericidal activity And a composition containing the above-mentioned has an excellent synergistic insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal effect that cannot be predicted from the use of each of them alone. completed.

  That is, the present invention relates to the following compositions [1] to [4] (hereinafter referred to as the present composition) and the control methods [5] to [8] (hereinafter referred to as the present method). Is.

[1]
An insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal composition comprising a synergistically effective amount of at least two active compounds,
1) One or more active compounds I are of the formula (1):

[Wherein, A ¹ , A ² and A ³ each independently represents a carbon atom or a nitrogen atom,
G represents a benzene ring, a nitrogen-containing 6-membered aromatic heterocycle, a furan ring, a thiophene ring or a 5-membered aromatic heterocycle containing two or more heteroatoms selected from an oxygen atom, a sulfur atom and a nitrogen atom;
W represents an oxygen atom or a sulfur atom,
X is a halogen atom, nitro, azido, -SCN, -SF _5, cyano, C ₁ -C ₆ alkyl, optionally substituted by R ⁴ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₈ cycloalkyl , optionally substituted by R ⁴ (C ₃ ~C ₈₎ cycloalkyl, E1～E19, optionally substituted by C ₂ -C _{6 ^{alkenyl, R 4 (C 2 ~C 6}} ) alkenyl, C ₅ ~ C ₁₀ cycloalkenyl, C ₅ -C ₁₀ halo cycloalkenyl, optionally substituted by C ₂ -C _{6 ^{alkynyl, R 4 (C 2 ~C 6}} ) ^{alkynyl, -OH, -OR 5, -OS (} O) ₂ R ⁵ , -SH, -S (O) _r R ⁵ , -N (R ⁷ ) R ⁶ , -N = C (R ^7a ) R ^6a , -C (O) R ⁸ , -C (R ⁸ ) = NOH, -C (R ⁸ ) = NOR ⁹ , M3, M13, M30, -C (O) OR ⁹ , -C (O) SR ⁹ , -C (O) NH ₂ , -C (O) N ( R ¹⁰ ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ¹⁰ ) R ⁹ , M23 to M26, M28, M29 , -S (O) ₂ OR ⁹ , -S (O) ₂ NH ₂ , -S (O) ₂ N (R ¹⁰ ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ¹¹ , phenyl, (Z ) Feni substituted by _p1 Or D1 to D38, and when m represents an integer of 2 or more, each X may be the same as or different from each other,
Further, when two Xs are adjacent to each other, the two adjacent Xs are -CH ₂ CH ₂ CH _2- , -CH ₂ CH ₂ O-, -CH ₂ OCH _2- , -OCH ₂ O-, -CH ₂ CH ₂ S-, -CH ₂ SCH _2- , -CH ₂ CH ₂ N (R ¹² )-, -CH ₂ N (R ¹² ) CH _2- , -CH ₂ CH ₂ CH ₂ CH _2- , -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH _2- , -CH ₂ OCH ₂ O-, -OCH ₂ CH ₂ O-, -OCH ₂ CH ₂ S-, -CH ₂ CH = CH-,- OCH = CH-, -SCH = CH-, -N (R ¹² ) CH = CH-, -OCH = N-, -SCH = N-, -N (R ¹² ) CH = N-, -N (R ¹² By forming N = CH-, -CH = CHCH = CH-, -OCH ₂ CH = CH-, -N = CHCH = CH-, -N = CHCH = N- or -N = CHN = CH- A 5-membered ring or a 6-membered ring may be formed together with the carbon atom to which each of two Xs is bonded. At this time, the hydrogen atom bonded to each carbon atom forming the ring is optionally substituted by Z. In addition, when simultaneously substituted with two or more Z, each Z may be the same as or different from each other,
Y is a halogen atom, nitro, azido, -SCN, -SF _5, cyano, C ₁ -C ₆ alkyl, optionally substituted by R ⁴ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₈ cycloalkyl , optionally substituted by R ⁴ (C ₃ ~C ₈₎ cycloalkyl, E1~E18, C ₂ ~C ₆ alkinyl, optionally substituted by R ⁴ (C ₂ ~C ₆₎ alkynyl, -OH, -OR ⁵ , -OS (O) ₂ R ⁵ , -SH, -S (O) _r R ⁵ , -NH ₂ , -N (R ⁷ ) R ⁶ , -N (R ⁷ ) C (O) R ^8a , -N = C (R ^7a ) R ^6a , -C (O) NH ₂ , -C (O) N (R ¹⁰ ) R ⁹ , -C (S) NH ₂ , -C (S) N (R ¹⁰ ) R ⁹ , —Si (R ^11a ) (R ^11b ) R ¹¹ , phenyl, phenyl substituted by (Z) _p1 or D1 to D38, and when n represents an integer of 2 or more, each Y is They may be the same or different from each other,
Further, when two Ys are adjacent to each other, the two adjacent Ys are —CH ₂ CH ₂ CH ₂ —, —CH ₂ CH ₂ O—, —CH ₂ OCH ₂ —, —OCH ₂ O—, —CH ₂ CH ₂ S-, -CH ₂ SCH _2- , -SCH ₂ S-, -CH ₂ CH ₂ CH ₂ CH _2- , -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH ₂ -,- By forming CH ₂ OCH ₂ O-, -OCH ₂ CH ₂ O-, -OCH ₂ CH ₂ S-, -SCH ₂ CH ₂ S-, -OCH = N- or -SCH = N- A 5-membered ring or a 6-membered ring may be formed together with the carbon atom to which each Y is bonded, and at this time, the hydrogen atom bonded to each carbon atom forming the ring may be optionally substituted by Z Furthermore, when two or more Z are substituted at the same time, each Z may be the same as or different from each other,
R ¹ is hydrogen atom, cyano, optionally substituted by C ₁ -C ₁₂ alkyl, optionally substituted by R ¹³ (C ₁ ~C ₁₂₎ alkyl, C ₃ -C ₁₂ cycloalkyl, R ¹³ ( C ₃ -C ₁₂₎ cycloalkyl, E2~E6, E9, E12~E15, E18 , C 2 ~C 12 alkenyl, optionally substituted by R ¹³ (C ₂ ~C ₁₂₎ alkenyl, C ₅ -C ₁₄ cycloalkenyl, C ₅ -C ₁₄ halo cycloalkenyl, optionally substituted by C ₃ -C _{12 ^{alkynyl, R 13 (C 3 ~C 12}} ) ^{alkynyl, -C (O) R 14,} -C (R 14) = NOH, -C (R ¹⁴ ) = NOR ¹⁵ , M3, M13, M30, -C (R ¹⁴ ) = NN (R ¹⁷ ) R ¹⁶ , -C (O) OR ¹⁵ , -C (O) SR ¹⁵ , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ¹⁵ , -C (S) SR ¹⁵ , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (= NR ¹⁶ ) OR ¹⁵ , -C (= NOR ¹⁵ ) OR ¹⁵ , M7, M17, M23, M26, -C (= NR ¹⁶ ) SR ¹⁵ , M9, M19, M24, M28, -C (= NR ¹⁶ ) N (R ¹⁷ ) R ¹⁶ , -C (= NCN) N (R ¹⁷ ) R ¹⁶ , -C (= NOR ¹⁵ ) N (R ¹⁷ ) R ¹⁶ , -C (= NNO ₂ ) N (R ¹⁷ ) R ¹⁶ , M11, M21 ^{, M25, M29, -OR 15,} - SR ¹⁵ , -S (O) ₂ R ¹⁵ , -S (O) ₂ N (R ¹⁷ ) R ¹⁶ , -N (R ¹⁷ ) R ¹⁶ , -N = C (R ^17a ) R ^16a , -C (O ) ON = C (R ^17a ) R ^16a , -SN (R ¹⁹ ) R ¹⁸ , phenyl, phenyl substituted by (Z) _p1 , D1-D25 or D27-D38,
R ² is hydrogen atom, cyano, C ₁ -C ₁₂ alkyl, (C ₁ -C ₁₂ ) alkyl, C ₃ -C ₁₂ cycloalkyl, C ₃ -C ₁₂ alkenyl, C ₃ optionally substituted by R ^13a -C ₁₂ haloalkenyl, C ₅ -C ₁₄ cycloalkenyl, C ₅ -C ₁₄ halo cycloalkenyl, C ₃ -C ₁₂ alkynyl, C ₃ -C ₁₂ ^{haloalkynyl, -C (O) R 14a,} -C (O ) OR ^15a , -C (O) SR ^15a , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ^15a , -C (S) SR ^15a , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (O) C (O) OR ^15a , -OR ¹⁵ , -SR ¹⁵ , -N (R ¹⁷ ) R ¹⁶ , -N = C (R ^17a ) R ^16a , -S (O) ₂ R ^{15a represents} -S (O) ₂ N (R ¹⁷ ) R ¹⁶ , -SN (R ¹⁹ ) R ¹⁸ , phenyl or phenyl substituted by (Z) _p1 , or R ² together with R ¹ = C (R ^2a ) R ^1a , or R ² and R ¹ together form a C _{2 to} C ₇ alkylene chain, whereby the nitrogen to which R ¹ and R ² are bonded Indicates that a 3- to 8-membered ring may be formed with the atom, The alkylene chain oxygen atom may contain one sulfur atom or a nitrogen atom, and a halogen atom, C ₁ -C ₆ alkyl group, C ₁ -C ₆ haloalkyl group, C ₁ -C ₆ alkoxy (C ₁ -C ₆₎ alkyl group, C ₁ -C ₆ alkoxy group, -CHO group, C ₁ -C ₆ alkylcarbonyl group, C ₁ -C ₆ haloalkylcarbonyl group, C ₁ -C ₆ alkoxycarbonyl group, C ₁ -C ₆ halo alkoxycarbonyl group, C ₁ -C ₆ alkylaminocarbonyl group, C ₁ -C ₆ halo alkylaminocarbonyl group, a phenyl group, a phenyl group substituted by (Z) _p1, D32 group, D33 group, D34 group, D35 group, Optionally substituted by an oxo or thioxo group,
Further alternatively, when the substituent Y is present at the adjacent position, R ² together with Y is —CH ₂ —, —CH ₂ CH ₂ —, —CH ₂ O—, —CH ₂ S—, — By forming CH ₂ N (R ⁶ )-, -CH = CH- or -CH = N-, a 5-membered ring or a 6-membered ring may be formed together with the atoms to which R ² and Y are bonded. At this time, a hydrogen atom is a halogen atom attached to each carbon atom forming the ring, C ₁ -C ₆ alkyl group, C ₁ -C ₆ haloalkyl group, C ₁ -C ₆ alkylidene group, C ₁ -C ₆ Optionally substituted by a haloalkylidene group, an oxo group or a thioxo group,
R ^1a represents a hydrogen atom, C ₁ -C ₆ alkyl, -OR ¹⁵ , -SR ¹⁵ , -S (O) ₂ R ¹⁵ or -N (R ^17b ) R ^16b ,
R ^2a represents R ¹⁴ , -OR ^15a , -SR ^15a , -SC (O) R ^14a , -SC (O) OR ^15a or -N (R ^17c ) R ^16c , or R ^2a is R ^1a Together with C _{4 to} C ₅ alkylene chain or C _{4 to} C ₅ alkenylene chain to form a 5- to 6-membered ring with the carbon atom to which R ^1a and R ^2a are bonded. In this case, this alkylene chain or alkenylene chain may contain 1 to 3 oxygen atoms, sulfur atoms or nitrogen atoms, and is a halogen atom, nitro group, cyano group, C ₁ -C ₆ alkyl group, C ₁ -C ₆ haloalkyl group, C ₁ -C ₆ alkoxy group, C ₁ -C ₆ haloalkoxy group, C ₁ -C ₆ alkylthio group may be optionally substituted by C ₁ -C ₆ haloalkylthio group, or R ^17c group ,
R ³ represents a halogen atom, cyano, optionally substituted by C ₁ -C ₆ alkyl, optionally substituted by R ⁴ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₈ cycloalkyl, R ⁴ ( C ₃ -C ₈₎ cycloalkyl, substituted E1~E19, C ₃ ~C ₆ alkenyl, optionally substituted by R ⁴ (C ₂ ~C ₆₎ alkenyl, C ₃ -C ₆ alkynyl, optionally by R ⁴ been (C ₂ ~C ₆₎ ^{alkynyl, -OR 5, -S (O)} r R 5, -N (R 10) R 9, -C (O) R 8, -C (R 8) = NOH, -C (R ⁸ ) = NOR ⁹ , M3, M13, M30, -C (O) OR ⁹ , -C (O) SR ⁹ , -C (O) NH ₂ , -C (O) N (R ¹⁰ ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ¹⁰ ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ^{11 represents} -P (O) (OR ²⁰ ) ₂ , phenyl, phenyl substituted by (Z) _p1 or D1-D38,
D1 to D38 each represent an aromatic heterocycle represented by the following structural formula;

Z is a halogen atom, nitro, cyano, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₄ alkoxy (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ haloalkoxy (C ₁ ~ C ₄₎ alkyl, C ₁ -C ₄ alkylthio (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ haloalkylthio (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ alkylsulfinyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ haloalkylsulfinyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ alkylsulfonyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ haloalkylsulfonyl (C ₁ ~C ₄₎ alkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, -OH, C ₁ ~C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, C ₁ -C ₆ alkylsulfonyloxy, C ₁ -C ₆ haloalkyl sulfonyloxy, C ₁ -C ₆ alkylthio, C ₁ -C ₆ haloalkylthio, C ₁ -C ₆ alkylsulfinyl, C ₁ -C ₆ Haroaruki Sulfinyl, C ₁ -C ₆ alkylsulfonyl, C ₁ -C ₆ haloalkylsulfonyl, -NH _2, C ₁ ~C ₆ alkyl amino, di (C ₁ -C ₆ alkyl) amino, C ₁ -C ₆ alkoxycarbonyl, C ₁ -C _{6 haloalkoxycarbonyl, -C (O) NH 2,} C 1 ~C 6 alkyl amino carbonyl, C ₁ -C ₆ haloalkylcarbonyl aminocarbonyl, di (C ₁ -C ₆ alkyl) aminocarbonyl, -C (S _{) NH 2, -S (O)} 2 NH 2, C 1 ~C 6 alkylaminosulfonyl, di (C ₁ -C ₆ alkyl) aminosulfonyl, phenyl optionally substituted by phenyl or halogen atom, p1, when p2, p3 or p4 represents an integer of 2 or more, each Z may be the same as or different from each other;
Further, when two Zs are adjacent to each other, the two adjacent Zs are -CH ₂ CH ₂ CH _2- , -CH ₂ CH ₂ O-, -CH ₂ OCH _2- , -OCH ₂ O-, -CH ₂ CH ₂ S-, -CH ₂ SCH _2- , -CH ₂ CH ₂ CH ₂ CH ₂ CH _2- , -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH _2- , -CH ₂ OCH ₂ O- , -OCH ₂ CH ₂ O-, -CH ₂ CH ₂ CH ₂ S-, -OCH ₂ CH ₂ S- or -CH = CH-CH = CH- may form a 5- or 6-membered ring together with the carbon atom, this time, the hydrogen atoms bonded to each carbon atom forming the ring is a halogen atom, a cyano group, a nitro group, C ₁ -C ₄ alkyl group may be optionally substituted by C ₁ -C ₄ haloalkyl groups, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio group,
E1 to E19 each represents a saturated heterocyclic ring represented by the following structural formula;

R ⁴ is a halogen atom, cyano, C _{3 to} C ₈ cycloalkyl, C _{3 to} C ₈ halocycloalkyl, E1 to E19, —OH, —OR ⁵ , —SH, —S (O) _r R ⁵ , — N (R ⁷ ) R ⁶ , -N (R ⁷ ) C (O) R ^8a , -C (O) OR ⁹ , -C (O) N (R ¹⁰ ) R ⁹ , -Si (R ^11a ) (R ^11b ) represents R ¹¹ , phenyl, (Z) phenyl substituted by _p1 or D1-D38,
R ⁵ is optionally substituted by C ₁ -C ₆ alkyl, optionally substituted by R ²³ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₈ cycloalkyl, R ²³ (C ₃ ~C ₈ ) cycloalkyl, E2~E6, E12~E15, E18, C 2 ~C 6 alkenyl, optionally substituted by R ²³ (C ₂ ~C ₆₎ alkenyl, C ₅ -C ₁₀ cycloalkenyl, C ₅ -C ₁₀ halo cycloalkenyl, C ₃ -C ₆ alkynyl, optionally substituted by R ²³ (C ₃ ~C ₆₎ alkynyl, C ₁ -C ₆ alkylcarbonyl, C ₁ -C ₆ alkoxycarbonyl, phenyl, (Z) _represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38 substituted by _p1 ,
R ⁶ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ halocycloalkyl, C ₃ -C ₆ optionally substituted by R ²³ alkenyl, C ₃ -C ₆ haloalkenyl, C ₃ -C ₆ alkynyl, C ₃ -C ₆ ^{haloalkynyl, -C (O) R 8,} -C (O) OR 9, -C (O) SR 9, - C (O) NH ₂ , -C (O) N (R ¹⁰ ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ¹⁰ ) R ⁹ , -C (O) C (O) R ⁹ , -C (O) C (O) OR ⁹ , -OH, -S (O) ₂ R ⁹ , -S (O) ₂ N (R ¹⁰⁾ R ^9, represents a ^{-P (O) (oR 20)} 2 or ^{-P (S) (oR 20)} 2,
R ⁷ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²³ , C ₃ -C ₈ cycloalkyl, C ₃ -C ₆ alkenyl, C ₃ -C ₆ haloalkenyl, C ₃ -C ₆ alkynyl, C ₃ -C ₆ haloalkynyl, -CHO, C ₁ -C ₆ alkylcarbonyl, or represents C ₁ -C ₆ haloalkylcarbonyl or C ₁ -C ₆ alkoxycarbonyl, or , R ⁷ together with R ⁶ forms a C ₂ -C ₆ alkylene chain, thereby representing that a 3- to 7-membered ring may be formed with the nitrogen atom to which R ⁶ and R ⁷ are bonded; in this case the alkylene chain is an oxygen atom, may contain one sulfur atom or a nitrogen atom, and optionally substituted halogen atom, C ₁ -C ₆ alkyl group, C ₁ -C ₆ haloalkyl group, the oxo group or thioxo group May have been
R ^6a represents C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, C ₃ -C ₆ alkenyloxy, phenoxy or phenoxy substituted by (Z) _p1 ;
R ^7a represents a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ alkenyl, phenyl or phenyl substituted by (Z) _{p 1} , or R ^7a is R ^6a Together with C ₄ -C ₆ alkylene chain to form a 5- to 7-membered ring together with the carbon atom to which R ^6a and R ^7a are bonded, and this alkylene chain is May contain one oxygen or sulfur atom,
R ⁸ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²³ , C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ halocycloalkyl, E 4- E6, E12~E14, C ₃ ~C ₆ alkenyl, C ₃ -C ₆ haloalkenyl, C ₅ -C ₁₀ cycloalkenyl, C ₅ -C ₁₀ halo cycloalkenyl, C ₃ -C ₆ alkynyl or C ₃ -C ₆ Represents haloalkynyl,
R ^8a represents phenyl, phenyl substituted by (Z) _p1 or D1-D38,
R ⁹ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²³ , C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ halocycloalkyl, E2 -E6, E12 ~E19, C ₃ ~C ₆ alkenyl, C ₃ -C ₆ haloalkenyl, C ₃ -C ₆ alkynyl, C ₃ -C ₆ haloalkynyl, phenyl, phenyl substituted by (Z) _p1, D1~D25 or D27 ~ Represents D38,
R ¹⁰ is a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₆ alkoxy (C ₁ ~C ₄₎ alkyl, C ₁ -C ₆ alkylthio (C ₁ ~C ₄₎ alkyl, cyano (C ₁ ~C ₆₎ alkyl, or represents C ₃ -C ₆ alkenyl or C ₃ -C ₆ alkynyl, or, R ¹⁰ is R ^{9 represents} a C ₂ -C ₆ alkylene chain to form a 3- to 7-membered ring together with the nitrogen atom to which R ⁹ and R ¹⁰ are bonded. oxygen atom may contain one sulfur atom or a nitrogen atom, and a halogen atom, C ₁ -C ₆ alkyl group, C ₁ -C ₆ alkoxy group, -CHO group, C ₁ -C ₆ alkylcarbonyl group or a C It may be optionally substituted by ₁ -C ₆ alkoxycarbonyl group,
R ¹¹ represents C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy, phenyl or phenyl substituted by (Z) _p1 ;
R ^11a and R ^11b each independently represent C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl or C ₁ -C ₆ alkoxy;
R ¹² is a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxycarbonyl (C ₁ -C ₄ ) alkyl, C ₁ -C ₆ haloalkoxycarbonyl (C ₁ -C ₄₎ alkyl, phenyl (C ₁ -C ₄₎ alkyl, (Z) phenyl substituted by _p1 (C ₁ -C ₄₎ alkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₃ ~ C ₆ represents alkynyl, C ₃ -C ₆ haloalkynyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ alkoxycarbonyl, C ₁ -C ₆ haloalkoxycarbonyl, phenyl substituted by phenyl or (Z) _p1,
Further, when Z is present at the adjacent position to R ¹² is, -CH ₂ and adjacent R ¹² and _{Z CH 2 CH 2 CH 2 -} , -CH = CH-CH = CH-, -N = CH- An atom to which each of R ¹² and Z is bonded by forming CH = CH-, -CH = N-CH = CH-, -CH = CH-N = CH- or -CH = CH-CH = N- may form a 6-membered ring with a substituted this time, a hydrogen atom is a halogen atom attached to each carbon atom forming the ring, optionally by C ₁ -C ₄ alkyl or C ₁ -C ₄ haloalkyl group May have been
R ¹³ and R ^13a are each independently a halogen atom, nitro, cyano, C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ halocycloalkyl, hydroxy (C ₃ -C ₈ ) cycloalkyl, C ₁ -C ₄ alkoxy (C ₃ ~C ₈₎ cycloalkyl, E1~E19, C ₅ ~C ₁₀ cycloalkyl, C ₅ -C ₁₀ halo ^{cycloalkenyl, -OR 24, -N (R 25} ) R 24, -SH, - S (O) _r R ²⁶ , -C (O) R ²⁷ , -C (R ²⁷ ) = NOH, -C (R ²⁷ ) = NOR ²⁸ , -C (O) OH, -C (O) OR ²⁸ , -C (O) SR ²⁸ , -C (O) NH ₂ , -C (O) N (R ²⁹ ) R ²⁸ , -C (O) N (R ²⁹ ) OR ²⁸ , -C (O) N (R ²⁹ ) N (R ^28a ) R ²⁸ , -C (O) C (O) OR ²⁸ , -C (S) OR ²⁸ , -C (S) SR ²⁸ , -C (S) NH ₂ , -C (S ) N (R ²⁹ ) R ²⁸ , -C (= NR ²⁹ ) OR ²⁸ , -C (= NR ²⁹ ) SR ²⁸ , -C (= NR ²⁹ ) N (R ^28a ) R ²⁸ , -C (= NOR ²⁸ ) N (R ^28a ) R ²⁸ , -S (O) ₂ OH, -S (O) ₂ NH ₂ , -S (O) ₂ N (R ²⁹ ) R ²⁸ , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , -P (phenyl) ₂ , -P (O) (phenyl) ₂ , M1 to M30, phenyl, (Z ) phenyl substituted by _p1 , Naphthyl or D1-D38,
M1 to M30 each represents a partially saturated heterocyclic ring represented by the following structural formula,

R ¹⁴ And R ^14a Each independently represents a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E3-E6, E12-E14, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C ₂ ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl, naphthyl or D1-D38 substituted by
R ¹⁵ And R ^15a Are each independently C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E2-E6, E12-E19, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38, substituted by
R ¹⁶ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E2-E6, E12-E19, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, -C (O) R ²⁷ , -C (O) OR ²⁸ , -C (O) SR ²⁸ , -C (O) NH ₂ , -C (O) N (R ²⁹ ) R ²⁸ , -C (S) R ²⁷ , -C (S) OR ²⁸ , -C (S) SR ²⁸ , -C (S) NH ₂ , -C (S) N (R ²⁹ ) R ²⁸ , -S (O) ₂ R ²⁸ , -S (O) ₂ NH ₂ , -S (O) ₂ N (R ²⁹ ) R ²⁸ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ¹⁷ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Cycloalkyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylsulfonyl (C ₁ ~ C _Four ) Alkyl, cyano (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl or C _Three ~ C ₆ Represents haloalkynyl or R ¹⁷ Is R ¹⁶ Together with C ₂ ~ C ₆ By forming an alkylene chain, R ¹⁶ And R ¹⁷ Represents that it may form a 3- to 7-membered ring together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E1-E19, phenyl (C ₂ ~ C _Four ) Alkenyl, di (C ₁ ~ C ₆ Alkyl) amino, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ^17a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Alkylthio or di (C ₁ ~ C ₆ Alkyl) amino or R ^17a Is R ^16a Together with C _Three ~ C _Five By forming an alkylene chain, R ^16a And R ^17a Represents a 4- to 6-membered ring together with the carbon atom to which is bonded, wherein the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16b Is a hydrogen atom, C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents haloalkyl,
R ^17b Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl or R ^17b Is R ^16b Together with C _Three ~ C _Five By forming an alkylene chain, R ^16b And R ^17b Represents a 4- to 6-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain an oxygen atom, a sulfur atom or a nitrogen atom, and C ₁ ~ C ₆ Alkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16c Is a hydrogen atom, nitro, cyano, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Alkynyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, -NH ₂ , C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C ₆ Alkyl) amino, -NHC (O) R ²⁷ , -NHC (O) OR ²⁸ , -NHC (O) SR ²⁸ , -NHC (O) NH ₂ , -NHC (O) N (R ²⁹ ) R ²⁸ , -NHC (S) OR ²⁸ , -NHC (S) SR ²⁸ , -NHC (S) NH ₂ , -NHC (S) N (R ²⁹ ) R ²⁸ , -NHS (O) ₂ R ²⁸ , -NHS (O) ₂ NH ₂ Or -NHS (O) ₂ N (R ²⁹ ) R ²⁸ Represents
R ^17c Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl or R ^17c Is R ^16c Together with C _Three ~ C _Five By forming an alkylene chain, R ^16c And R ^17c Represents a 4- to 6-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain an oxygen atom, a sulfur atom or a nitrogen atom, and C ₁ ~ C ₆ Alkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ¹⁸ C ₁ ~ C ₁₂ Alkyl, C ₁ ~ C ₁₂ Haloalkyl, C ₁ ~ C ₁₂ Alkoxy (C ₁ ~ C ₁₂ ) Alkyl, cyano (C ₁ ~ C ₁₂ ) Alkyl, C ₁ ~ C ₁₂ Alkoxycarbonyl (C ₁ ~ C ₁₂ ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₁₂ Alkenyl, C _Three ~ C ₁₂ Haloalkenyl, C _Three ~ C ₁₂ Alkynyl, C _Three ~ C ₁₂ Haloalkynyl, C ₁ ~ C ₁₂ Alkylcarbonyl, C ₁ ~ C ₁₂ Alkoxycarbonyl, -C (O) ON = C (CH _Three ) SCH _Three , -C (O) ON = C (SCH _Three ) C (O) N (CH _Three ) ₂ , Phenyl or (Z) _p1 Represents phenyl substituted by
R ¹⁹ C ₁ ~ C ₁₂ Alkyl, C ₁ ~ C ₁₂ Haloalkyl, C ₁ ~ C ₁₂ Alkoxy (C ₁ ~ C ₁₂ ) Alkyl, cyano (C ₁ ~ C ₁₂ ) Alkyl, C ₁ ~ C ₁₂ Alkoxycarbonyl (C ₁ ~ C ₁₂ ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₁₂ Alkenyl, C _Three ~ C ₁₂ Haloalkenyl, C _Three ~ C ₁₂ Alkynyl, C _Three ~ C ₁₂ Haloalkynyl, phenyl or (Z) _p1 Represents phenyl substituted by or R ¹⁹ Is R ¹⁸ Together with C _Four ~ C ₇ By forming an alkylene chain, R ¹⁸ And R ¹⁹ Represents that it may form a 5- to 8-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain one oxygen atom or sulfur atom, and C ₁ ~ C _Four Alkyl group or C ₁ ~ C _Four Optionally substituted by an alkoxy group,
R ²⁰ C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents haloalkyl,
R ^{twenty one} Is a halogen atom, cyano, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, hydroxy (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C _Four Alkyl) amino, C ₁ ~ C ₆ Alkoxycarbonyl, phenyl or (Z) _p1 Each of R's is represented by q1 to q8 each representing an integer of 2 or more. ^{twenty one} May be the same as or different from each other, and two R ^{twenty one} Are substituted on the same carbon atom, two R ^{twenty one} Together oxo, thioxo, imino, C ₁ ~ C ₆ Alkylimino, C ₁ ~ C ₆ Alkoxyimino or C ₁ ~ C ₆ Represents that an alkylidene may be formed,
R ^{twenty two} Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, -OH, benzyloxy, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (S) N (R ³⁴ ) R ³³ , -S (O) ₂ R ³² , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl or D3 substituted by
R ^{twenty three} Is a halogen atom, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E1-E19, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Haloalkylthio, C ₁ ~ C ₆ Alkylsulfonyl, C ₁ ~ C ₆ Haloalkylsulfonyl, C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C ₆ Alkyl) amino, -CHO, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, C ₁ ~ C ₆ Haloalkoxycarbonyl, C ₁ ~ C ₆ Alkylaminocarbonyl, di (C ₁ ~ C ₆ Alkyl) aminocarbonyl, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ^{twenty four} Is a hydrogen atom, C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E2-E6, E12-E19, C _Three ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) R ³² , -C (O) C (O) OR ³² , -C (S) R ³¹ , -C (S) OR ³² , -C (S) SR ³² , -C (S) N (R ³⁴ ) R ³³ , -S (O) ₂ R ³² , -S (O) ₂ N (R ³⁴ ) R ³³ , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38, substituted by
R ^{twenty five} Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Alkynyl, C ₁ ~ C ₆ Alkoxy, phenyl or (Z) _p1 Represents phenyl substituted by or R ^{twenty five} Is R ^{twenty four} Together with C ₂ ~ C _Five By forming an alkylene chain, R ^{twenty four} And R ^{twenty five} Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group, C ₁ ~ C ₆ Alkoxycarbonyl group, phenyl group, (Z) _p1 May be substituted by a phenyl group, an oxo group or a thioxo group substituted by
R ²⁶ C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E2-E6, E12-E19, C _Three ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) R ³² , -C (O) C (O) OR ³² , -C (S) R ³¹ , -C (S) OR ³² , -C (S) SR ³² , -C (S) N (R ³⁴ ) R ³³ , -SH, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Haloalkylthio, phenylthio, (Z) _p1 Phenylthio substituted by -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D9, D10, D12, D14-D17, D30, D32 or D34 substituted by
R ²⁷ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Cycloalkyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkylsulfonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, phenyl or (Z) _p1 Represents phenyl substituted by
R ²⁸ C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E1-E7, E12-E19, C ₂ ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C ₂ ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ^28a Is a hydrogen atom or C ₁ ~ C _Four Represents alkyl,
R ²⁹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, phenyl or (Z) _p1 Represents phenyl substituted by or R ²⁹ Is R ²⁸ Together with C ₂ ~ C _Five By forming an alkylene chain, R ²⁸ And R ²⁹ Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group, C ₁ ~ C ₆ Alkoxycarbonyl group, phenyl group or (Z) _p1 Optionally substituted by a phenyl group substituted by
R ³⁰ Is a halogen atom, nitro, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E4, E5, E7, E8, E10, E12, E13, E15, E16, E18, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, -OH, -OR ³² , -OC (O) R ³¹ , -OC (O) OR ³² , -OC (O) N (R ³⁴ ) R ³³ , -OC (S) N (R ³⁴ ) R ³³ , -SH, -S (O) _r R ³² , -SC (O) R ³¹ , -SC (O) OR ³² , -SC (O) N (R ³⁴ ) R ³³ , -SC (S) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) R ³³ , -N (R ³⁴ ) CHO, -N (R ³⁴ ) C (O) R ³¹ , -N (R ³⁴ ) C (O) OR ³² , -N (R ³⁴ ) C (O) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) C (S) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) S (O) ₂ R ³² , -C (O) R ³¹ , -C (O) OH, -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) OR ³² , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , -P (phenyl) ₂ , -P (O) (phenyl) ₂ , Phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ³¹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Halocycloalkyl, E4, E5, E12, E13, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C ₂ ~ C ₈ Alkynyl, C ₂ ~ C ₈ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ³² C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E4, E5, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Three ~ C ₈ Represents alkynyl or phenyl,
R ³³ C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E4, E5, E12, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Three ~ C ₈ Alkynyl, phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ³⁴ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₆ Alkenyl or C _Three ~ C ₆ Represents alkynyl or R ³⁴ Is R ³³ Together with C ₂ ~ C _Five By forming an alkylene chain, R ³³ And R ³⁴ Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C _Four Alkyl group, C ₁ ~ C _Four Alkoxy group, -CHO group, C ₁ ~ C _Four Alkylcarbonyl group, C ₁ ~ C _Four Alkoxycarbonyl group, phenyl group or (Z) _p1 Optionally substituted by a phenyl group substituted by
R ³⁵ Is cyano, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Halocycloalkyl, E4, E5, E12, E13, C ₁ ~ C _Four Alkoxy, C ₁ ~ C _Four Haloalkoxy, phenoxy, (Z) _p1 Phenoxy substituted by C ₁ ~ C _Four Alkylthio, C ₁ ~ C _Four Haloalkylthio, phenylthio, (Z) _p1 Phenylthio, substituted by C ₁ ~ C _Four Alkylsulfonyl, C ₁ ~ C _Four Haloalkylsulfonyl, phenylsulfonyl, (Z) _p1 Phenylsulfonyl substituted by -N (R ³⁷ ) R ³⁶ , C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, di (C ₁ ~ C ₆ Alkyl) aminocarbonyl, tri (C ₁ ~ C _Four Alkyl) silyl, phenyl, (Z) _p1 Represents phenyl, naphthyl or D1-D38 substituted by
R ³⁶ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, phenylcarbonyl or (Z) _p1 Represents phenylcarbonyl substituted by
R ³⁷ Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl,
m represents an integer of 0, 1, 2, 3, 4 or 5,
n represents an integer of 0, 1, 2, 3 or 4;
p1 represents an integer of 1, 2, 3, 4 or 5;
p2 represents an integer of 0, 1, 2, 3 or 4;
p3 represents an integer of 0, 1, 2, or 3,
p4 represents an integer of 0, 1 or 2;
p5 represents an integer of 0 or 1,
q1 represents an integer of 0, 1, 2, or 3,
q2 represents an integer of 0, 1, 2, 3, 4 or 5;
q3 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
q4 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7, 8, or 9;
q5 represents an integer of 0, 1, 2, 3, 4, 5 or 6,
q6 represents an integer of 0, 1, 2, 3, or 4;
q7 represents an integer of 0, 1 or 2,
q8 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7 or 8,
r represents an integer of 0, 1 or 2;
t represents an integer of 0 or 1. ]
An isoxazoline-substituted benzamide compound represented by: or a tautomer, enantiomer, diastereomer or salt thereof,
2) One or more active compounds II are the following active ingredient groups A to G:
Active ingredient group A (bactericide): acibenzolar-S-methyl (acibenzolar-S-methyl), acipetacs (acypetacs), aldimorph (aldimorph), ametoctrazine (ametoctradin), amisulbrom (amisulbrom), ambam (amobam), ampropylphos (Ampropylfos), anilazine, azaconazole, azoxystrobin, benalaxyl, benalaxyl-M, benodanil, benomyl, bench avaricarb -Benthiavalicarb-isopropyl, benthiazole, biphenyl, bitertanol, bixafen, bordeaux mixture, boscalid, bromuconazole, bupirimate ), Lime-sulfur mixture (c alcium polysulfide, captan, carbendazim, carboxin, carpropamid, carvone, cheshunt mixture, chinomethionat, chloroneb, Chloropicrin, chlorothalonil, chlozolinate, climbazole, basic carbonate, copper carbonate, copper hydroxide, copper naphthenate, copper Oleate, copper oxychloride, copper sulfate, copper sulfate, basic, cresol, cufraneb, cyazofamid, cyflufenamide (Cyflufenamid), simoxanil (cym oxanil), cyproconazole, cyprodinil, dazomet, diclofluanide, dichlorophen, dichlorophenrazol, diclocymet, diclomezine , Dicloran, diethofencarb, difenoconazole, diflumetorim, dimethomorph, dimoxystrobin, dinoxyazole, diniconazole-M, diniconazole-M dinobuton), dinocap, dinocap-4, dinocap-6, diphenylamine, dithianon, DNOC, dodemorph-acetate ) Dodine, dorazoxolon, edifenphos, enestrobin, epoxiconazole, etaconazole, ethaboxam, ethirimol, ethoxyquin, ethodiazole (Etridiazole), famoxadone, fenamidone, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenitropan, fenoxanil, fenpicanil (Fenpiclonil), fenpropidin, fenpropimorph, fentin, ferbam, ferimzone, fluazinam, fludioxonil (Fludioxonil), flumorph, fluopicolide, fluopyram, fluorimide, fluotrimazole, fluoxastrobin, fluquinconazole, flusilazole , Flusulfamide, flutianil, flutolanil, flutriafol, fluxapyroxad, folpet, fosetyl-aluminium, fuberidazole , Furalaxyl, furametpyr, furconazole, furmecyclox, guazatine, hexachlorobenzene, hexaconazole Hymexazol, imazalil, imibenconazole, iminoctadine-albesilate, iminoctadine-triacetate, ipconazole, iprobenfos (iprobenfos) ), Iprovalicarb, isoprothiolane, isopyrazam, isotianil, kasugamycin, kresoxim-methyl, laminarin, mancopper, mancozeb ), Mandipropamid, maneb, mepanipyrim, mepronil, metalaxyl, metalaxyl-M, metam, metconazol (Metconazole), metfuroxam, metiram, metinominostrobin, metolafenone, metsulfovax, milneb, myclobutanil, nabam, natamycin natamycin), organic nickel (nickel bis (dimethyldithiocarbamate)), nitrothal-isopropyl, nuarimol, offurace, orysastrobin, oxadixyl, oxine copper , Oxpoconazole fumarate, oxycarboxin, pefurazoate, penconazole, penencycuron, penflufen, pentachlorophenol (pent achlorophenol (PCP)), penthiopyrad, orthophenylphenol (2-phenylphenol), phthalide, picoxystrobin, piperalin, polycarbamate, polyoxins, polyoxins -D (polyoxorim), potassium azide, potassium hydrogen carbonate, probenazole, prochloraz, procymidone, propamocarb hydrochloride, propiconazole ), Propineb, proquinazid, prothioconazole, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyrazophos (pyraz) ophos, pyribencarb-methyl, pyrifenox, pyrimemethanil, pyriofenone, pyroquilon, quinacetol-sulfate, quinoxyfen, quintozen (Quintozene), sedaxane, silthiofam, simeconazole, sodium hydrogen carbonate, sodium hypochlorite, spiroxamine, sulfur, tebuconazole ( tebuconazole), tebufloquin, tecoram, tetraconazole, thiabendazole, thifluzamide, thiophanate-methyl, thiram, thiazinyl (Tiadinil), tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazoxide, tributyltin oxide, tricyclazole, Tridemorph, trifloxystrobin, triflumizole, triforine, triticonazole, validamycin, valifenalate, vinclozolin, zinc Zinc naphthenate, zinc sulfate, ziram, zoxamide, shiitake mycelium extract, shiitake fruiting body extract, BCF-082 (test name) and ZF-9646 (test name) ).

  Active ingredient group B (nematicide): cadusafos, dichlofenthion, etoprophos, fenamiphos, fluensulfone, fosthiazate, fosthietate, fisthietan, imiafos ), Isamifos, isazofos, methyl bromide, methyl isothiocyanate, oxamyl, sodium azide, BYI-1921 (test name) and MAI -08015 (study name).

  Active ingredient group C (insecticide): abamectin, acephate, acetamiprid, alaniccarb, aldicarb, allethrin, azamethiphos, azinphos-ethyl ethyl), azinphos-methyl, bacillus thuringiensis, bendiocarb, benfluthrin, benfuracarb, bensultap, bifenthrin, bioarthrin (Bioallethrin), bioresmethrin, bistrifluron, buprofezin, butocarboxim, carbaryl, carbofuran, carbosulfan, Cartap, chlorantraniliprole, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormeazu, chlorpyrifos ), Chlorpyrifos-methyl, chromafenozide, clothianidin, cyanophos, cyantraniliprole, cycloprothrin, cyfluthrin, beta-cyfluthrin ( beta-cyfluthrin), cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermetrin hrin), beta-cypermethrin, zeta-cypermethrin, cyphenothrin, cyromazine, deltamethrin, diafenthiuron, diazinon ), Dichlorvos, diflubenzuron, dimethoate, dimethylvinphos, dinotefuran, diofenolan, disulfoton, emamectin-benzoate, penth ), Endosulfan, alpha-endosulfan, EPN, esfenvalerate, ethiofencarb, ethiprole, etofol Etofenprox, etrimfos, fenitrothion, fenobucarb, fenoxycarb, fenthion, fenvalerate, fipronil, flometoquin, flonicamid flonicamid), fluazuron, flubendiamide, flucycloxuron, flucythrinate, flufenerim, flufenoxuron, flumethrin, flupyradifurone , Fluvalinate, tau-fluvalinate, fonofos, furathiocarb, halofenozide, hexaflumuron, hydramethy Nona (hydramethylnon), imidacloprid (imidacloprid), imiprothrin, indoxacarb (indoxacarb), indoxacarb-MP (indoxacarb-MP), isoprocarb (isoprocarb), isoxathion (isoxathion), lepimectin (lepimectin), rufenuron ( lufenuron, malathion, meperfluthrin, metaflumizone, metaldehyde, methacrifos, methamidophos, methidathion, methomyl, methoprene, methoprene (Methoxychlor), methoxyfenozide, metofluthrin, muscalure, nitenpyram, novaluron, novifluuron, nov Omethoate, oxydemeton-methyl, parathion-methyl, permethrin, phenothrin, phenothate, phorate, phorate, phosalone, phosmet ( phosmet, phoxim, pirimicarb, pirimiphos-methyl, profenofos, prothiofos, pymetrozine, pyraclofos, pyrethrin (pyrethrins), pyridalylpy ), Pyrifluquinazon, pyriprole, pyriproxyfen, resmethrin, rotenone, silafluofen, spinetoram, spinosad, spirote Tramato (spirotetramat), sulfotep (sulfotep), sulfoxaflor (sulfoxaflor), tebufenozide (tebufenozide), teflubenzuron (teflubenzuron), tefluthrin (tefluthrin), terbufos (terbufos), tetrachlorovinphos (tetrachlorvinphos), tetramethrin (-tetramethrin) T-80-phthalthrin (d-tetramethrin), tetramethylfluthrin, thiacloprid, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon , Tolfenpyrad, tralomethrin, transfluthrin, triazamate, trichlorfon, triflumuron, ANM-1 8 (test name) and IKI-3106 (test name).

  Active ingredient group D (acaricide): acequinocyl, acrinathrin, amidoflumet, amitraz, azocyclotin, benzoximate, bifenazate, bromopropiate Bromopropylate, clofentezine, cyenopyrafen, cyflumetofen, dicohol, dienochlor, etoxazole, fenazaquin, fenbutatin oxide, fenbutatin oxide Fenothiocarb, fenpropathrin, fenpyroximate, fluacrypyrim, formenanate, halfenprox, hex Hexythiazox, milbemectin, propargite, pyridaben, pyrimidifen, spirodiclofen, spiromesifen, tebufenpyrad and NNI-071 (Trial) ).

  Active ingredient group E (Anthelmintic): acriflavine, albendazole, atovaguone, azithromycin, bithionol, bromofenofos, cambendazole, carnidazole (Carnidazole), chloroquine, clazuril, clindamycin hydrochloride, clorsulon, closantel, coumaphos, cymiazol, dichlorophen, diethylcarba Diazinecarbamazine, diminazene, disophenol, dithiazanine iodide, doxycycline hydrochloride, doramectin, emodepside, eprino Eprinomectin, febantel, fenbendazole, flubendazole, furazolidone, glycalpyramide, imidocarb, ivermectin, levamisole, Mebendazole, mefloquine, melarsamine dihydrochloride, metronidazole, metyridine, milbemycin oxime, monepantel, morantel tartrate, morantel tartrate moxidectin, nicarbazin, niclosamide, nitroscanate, nitroxynil, omphalotin, oxantate pamoate el pamoate, oxantel tartrate, oxfendazolee, oxibendazole, oxyclozanide, pamaquine, phenothiazine, piperazine adipate, citric acid Piperazine citrate, piperazine phosphate, PNU-97333 (paraherquamide A), PNU-141962 (2-deoxyparaherquamide), praziquantel, primaquine, propetamphos, propoxur , Pyrantel pamoate, pyrimethamine, santonin, selamectin, sulfadimethoxine, sulfadoxine, sulfamerazine sulfamerazine), sulfamonomethoxine (sulfamonomethoxine), sulfamoyl dapsone (sulfamoildapsone), thiabendazole (thiabendazole), tinidazole (tinidazole), toltrazuril (toltrazuril), tri bromine Saran (tribromsalan) and triclabendazole (triclabendazole).

  Active ingredient group F (antibacterial agents): amoxicillin, ampicillin, bethoxazin, bithionol, bronopol, cefapirin, cefazolin, cefquinome, cefquinome, cefquinome (Ceftiofur), chlortetracycline, clavulanic acid, danofloxacin, difloxacin, difloxacin, dinitolmide, enrofloxacin, florfenicol, lincomycin (Lincomycin), lomefloxacin, marbofloxacin, miloxacin, mirosamycin, nitrapyrin, norfloxacin, octyrinone (octh) ilinone), ofloxacin, orbifloxacin, oxolinic acid, oxytetracycline, penicillin, streptomycin, thiamphenicol, thiamphenicol, tiamulin fumarate, tilmicosin phosphate, tylosin phosphate, tylosin phosphate, tulathromycin, valnemulin, calcined shell calcium (calcium oxide), taralomyces Genus, Trichoderma and Unioniolium.

Active ingredient group G (antifungal agent): ketoconazole and miconazole nitrate;
Said insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal composition which is a compound selected from.

[2]
The substituent of formula (1) described in [1] above has the following meaning:
[Wherein A ¹ represents a carbon atom or a nitrogen atom,
A ² and A ³ represent a carbon atom,
G represents a benzene ring,
X is a halogen atom, nitro, cyano, C ₁ -C ₆ represents alkyl, C ₁ -C ₆ haloalkyl, the -OR ⁵ or -S (O) _{r R} ^5, when m is 2 or 3, each of the X may be the same as or different from each other;
Y is a halogen atom, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₃ alkoxy (C ₁ ~C ₃₎ alkyl, -SR ^5, or -N (R ⁷⁾ R ⁶ Represent,
R ¹ is hydrogen atom, C ₁ -C ₆ alkyl, optionally substituted by R ¹³ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₆ cycloalkyl, optionally substituted by R ¹³ (C ₃ -C ₆₎ cycloalkyl, E4, E5, E12, C 3 ~C 6 alkenyl, C ₃ -C ₆ haloalkenyl, C ₃ -C ₆ alkynyl, C ₁ -C ₆ alkylcarbonyl, -CH = NOR ^15, - C (O) OR ¹⁵ , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ¹⁵ , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (OR ¹⁵ ) = NOR ¹⁵ , -C (NH ₂ ) = NCN, -C (NH ₂ ) = NOR ¹⁵ , -C (NH ₂ ) = NNO ₂ , -N (R ¹⁷ ) R ¹⁶ , phenyl, phenyl substituted by (Z) _p1 , D5-D8, D10, D17 or D32-D35,
R ² is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ alkenyl, C ₃ -C optionally substituted by R ^13a ₆ ^{alkynyl, -C (O) R 14a,} -C (O) oR 15a, -C (O) C (O) oR 15a, -C (S) or represents oR ^15a or C ₁ -C ₆ haloalkylthio, Alternatively, R ² represents that may form together with ^{R 1 = C (R 2a)} R 1a,
R ^1a represents C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy or -N (R ^17b ) R ^16b ,
R ^2a represents C ₁ -C ₆ alkyl, C ₁ -C ₆ alkylthio or —N (R ^17c ) R ^16c , or R ^2a together with R ^1a represents —N (R ^17c ) CH═ It represents that by forming CHS-, a 5-membered ring may be formed with the carbon atom to which R ^1a and R ^2a are bonded,
R ³ represents C ₁ -C ₆ haloalkyl,
Z is a halogen atom, nitro, cyano, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy or C ₁ -C ₆ alkylsulfonyloxy, p1 and p2 are an integer of 2 or more Each Z may be the same as or different from each other;
R ⁵ represents C ₁ -C ₆ alkyl or C ₁ -C ₆ haloalkyl,
R ⁶ represents C ₁ -C ₆ alkyl, —CHO, C ₁ -C ₆ alkylcarbonyl or C ₁ -C ₆ alkoxycarbonyl,
R ⁷ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ¹² represents C ₁ -C ₆ alkyl;
R ¹³ is a halogen atom, cyano, C ₃ -C ₆ ^{cycloalkyl, E4, E7, -OR 24,} -N (R 25) R 24, -S (O) r R 26, C 1 ~C 6 alkyl carbonyl ^{, -C (R 27) = NOR} 28, -C (O) N (R 29) R 28, -C (S) NH 2, phenyl, phenyl substituted by _{(Z) p1, D1, D5} , D7, D8, D10, D13, D16, D17, D22, D32 or D34,
R ^13a represents cyano, -OR ²⁴ , -S (O) _r R ²⁶ or D32,
R ^14a is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₄ alkoxy (C ₁ -C ₄ ) alkyl, C ₁ -C ₄ alkylthio (C ₁ -C ₄ ) alkyl, C ₁ -C ₄ alkylsulfinyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ alkylsulfonyl (C ₁ ~C ₄₎ alkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ Alkynyl, phenyl, phenyl substituted by (Z) _p1 or D32,
R ¹⁵ represents C ₁ -C ₆ alkyl, (C ₁ -C ₄ ) alkyl or C ₂ -C ₆ alkenyl optionally substituted by R ³⁰ ,
R ^15a is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₄ alkoxy (C ₁ -C ₄ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₃ -C ₆ alkynyl or phenyl,
R ¹⁶ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₄ ) alkyl optionally substituted by R ³⁰ , C ₃ -C ₆ alkenyl, C ₁ -C ₆ alkylcarbonyl, C ₁ -C ₆ haloalkylcarbonyl, C ₁ -C ₆ alkoxycarbonyl, represents phenyl, phenyl, the D32 or D34 substituted by (Z) _p1,
R ¹⁷ represents a hydrogen atom, C ₁ -C ₆ alkyl, C ₃ -C ₆ alkenyl or C ₃ -C ₆ alkynyl,
R ^16b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ^17b represents a hydrogen atom or a C ₁ -C ₆ alkyl,
R ^16c represents a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl or C ₁ -C ₆ alkoxy;
R ^17c represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²¹ represents C ₁ -C ₆ alkyl;
R ²⁴ represents a hydrogen atom, C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl, -C (O) R ³¹ or -C (O) OR ³² ,
R ²⁵ represents a hydrogen atom or C ₁ -C ₄ haloalkyl,
R ²⁶ represents C ₁ -C ₆ alkyl,
R ²⁷ represents a hydrogen atom or a C ₁ -C ₄ alkyl,
R ²⁸ is C ₁ -C ₄ alkyl, (C ₁ -C ₄ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₄ alkenyl or C ₃ -C ₄ alkynyl optionally substituted by R ³⁰ . Represent,
R ²⁹ represents a hydrogen atom or C ₁ -C ₄ alkyl,
R ³⁰ represents a halogen atom, C ₃ -C ₆ cycloalkyl, —OH, C ₁ -C ₄ alkoxycarbonyl, phenyl, phenyl substituted by (Z) _{p 1} or D 32,
R ³¹ represents C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl or C ₃ -C ₆ cycloalkyl,
R ³² represents C ₁ -C ₄ alkyl,
m represents an integer of 1, 2 or 3,
n represents an integer of 0 or 1,
p1 represents an integer of 1, 2 or 3,
p2 represents an integer of 0, 1 or 2;
p3 and p4 represent an integer of 0 or 1,
q2 represents an integer of 0 or 1,
q3 and q4 represent 0,
t represents 0]
The insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition of the above-mentioned [1], comprising a compound I having the formula I, or a tautomer, enantiomer, diastereomer or salt thereof.

[3]
[1] to [2] above, comprising an active compound II selected from the group D consisting of acequinosyl, cyflumetofen, dienochlor, etoxazole, phenazaquin, phenbutatin oxide, milbemectin, sienopyrafen, propargite, spirodiclofen and spiromesifen The insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition according to any one of the above.

[4]
Any one of the above [1] to [2], comprising an active compound III selected from the group C consisting of chlorfenapyr, pyridaben, acephate, acetamiprid, flonicamid, imidacloprid, nitenpyram, pyrifluquinazone, pymetrozine, thiacloprid, thiamethoxam, clothianidin and tolfenpyrad. The insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition according to item 1.

[5]
One or more active compounds I described in [1] above and one or more active compounds II described in [1] above are treated simultaneously or close in time Pest and disease control method.

[6]
One or more active compounds I described in [2] above and one or more active compounds II described in [1] above are treated simultaneously or close in time. Pest and disease control method.

[7]
One or more active compounds I according to any one of [1] to [2] above and one or two or more active compounds II according to [3] above simultaneously or for a time A method for controlling pests and mites, characterized in that they are treated in close proximity.

[8]
One or more active compounds I according to any one of [1] to [2] above and one or more active compounds II according to [4] above simultaneously or for a time A method for controlling pests and mites, characterized in that they are treated in close proximity.

[9]
Termite insect pest control composition comprising an isoxazoline-substituted benzamide compound represented by the formula (1) described in [1] above or a salt thereof as an active ingredient.

[10]
A method for controlling termite pests, which comprises applying an effective amount of the isoxazoline-substituted benzamide compound represented by the formula (1) described in [1] or a salt thereof.

  The composition of the present invention and the method of the present invention exhibit an excellent synergistic control effect against various pests and a sufficient synergistic control effect against pests that have acquired resistance to existing pest control agents. Demonstrate.

  Further, the isoxazoline-substituted benzamide compound represented by the formula (1) contained in the composition of the present invention exhibits an excellent control effect against non-agricultural and horticultural pests such as termites.

  Therefore, the present invention can provide a useful novel pest control composition and an effective control method using them.

The compound represented by the formula (1) included in the present invention may have an E-isomer and a Z-isomer geometric isomer depending on the kind of the substituent. , Z-form or a mixture containing E-form and Z-form in any proportion. In addition, the compound represented by the formula (1) included in the present invention has an optically active substance resulting from the presence of one or two or more asymmetric carbon atoms, but the formula (1) of the present invention. The compound represented by the formula includes all optically active substances or racemates. Furthermore, in the compound represented by the formula (1) of the present invention, when R ² is a hydrogen atom, the presence of a tautomer represented by the following formula is considered in some cases. These structures are also included.

  Among the compounds represented by the formula (1) included in the present invention, those that can be converted into acid addition salts according to a conventional method are, for example, hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydrogen iodide. Hydrohalic acid salts such as acids, inorganic acid salts such as nitric acid, sulfuric acid, phosphoric acid, chloric acid, perchloric acid, methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfone Salts of sulfonic acids such as acids, formic acid, acetic acid, propionic acid, trifluoroacetic acid, fumaric acid, tartaric acid, succinic acid, maleic acid, malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid, citric acid A salt of a carboxylic acid such as an acid or a salt of an amino acid such as glutamic acid or aspartic acid can be used.

  Alternatively, among the compounds represented by the formula (1) included in the present invention, those that can be converted into a metal salt according to a conventional method are, for example, alkali metal salts such as lithium, sodium, and potassium, calcium, and barium. , An alkaline earth metal salt such as magnesium, or an aluminum salt.

  The isoxazoline-substituted benzamide compound represented by the formula (1) contained as the first active ingredient of the composition of the present invention is an international patent application publication (WO 2005/085216 publication) or an international patent application publication (WO 2007/026965 publication). ) And the like. In addition, the mechanism of action of isoxazoline-substituted benzamide compounds is different from conventional drugs such as organochlorine insecticides, organophosphorus insecticides, carbamate insecticides, and pyrethroid insecticides. It is also effective against pests that have developed resistance. Furthermore, the isoxazoline-substituted benzamide compound represented by the formula (1) and a salt thereof cause a certain amount of pests to die at an extremely low dose and have a residual effect, resulting in a remarkable control effect. It is something that demonstrates. However, it goes without saying that it is impossible to control all pests or diseases in all fields by using only the isoxazoline-substituted benzamide compound represented by the formula (1) or a salt thereof.

  Further, the isoxazoline-substituted benzamide compound represented by the formula (1) contained as the first active ingredient of the composition of the present invention is WO 2005/085216 pamphlet, WO 2007/026965 pamphlet or JP It can synthesize | combine according to the manufacturing method described in 2009-108046 gazette.

Examples of isoxazoline-substituted benzamide compounds represented by the formula (1) contained as the first active ingredient of the composition of the present invention are shown in Table 1, and their physical property values include melting point or proton nuclear magnetic resonance ( ¹ H— NMR) Chemical shift values are shown in Table 2, but the isoxazoline-substituted benzamide compounds used as active ingredients of the pest control composition of the present invention are not limited to these.

  In Table 1, “Et” represents an ethyl group. Similarly, i-Pr or Pr-i represents an isopropyl group, Ph represents a phenyl group, and D10-2a, D32-1a, D34- The aromatic heterocycles represented by 1a, D34-1c, and D35-1c each have the following structure.

For example, the notation [CH ₂ (D10-2a)] represents a thiazol-4-ylmethyl group, and the notation [(D34-1c) CN] represents a 5-cyanopyrimidin-2-yl group.

  In Table 1, the saturated heterocyclic rings represented by E4-1a, E5-2a, E5-2b, and E5-2c each have the following structure.

Furthermore, in Table 1, the numbers representing the substitution positions of the substituents (X) _m and (Y) _n correspond to the positions of the numbers described in the following structural formulas, respectively. Represents “unsubstituted”, and the descriptions of “(E)” and “(Z)” indicate that the (E) -form and the (Z) -form are 90% or more in the mixing ratio of geometric isomers, respectively. Represents something.

Moreover, the symbols described in Table 2 have the following meanings.
s: singlet, d: doublet, t: triplet, q: quartet, m: multiplet, brs: broad peak.
Table 1

――――――――――――――――――――――――――――――――――――
No. (X) _m (Y) _n WR ² R ¹
――――――――――――――――――――――――――――――――――――
1 3,5-Cl ₂ 2-CH ₃ OC (O) OCH ₃ CH ₂ OEt
2 3,5-Cl ₂ 2-Cl OH CH ₂ OCH ₂ CF ₃
3 3,5-Cl ₂ 2-Br OH CH ₂ OCH ₂ CF ₃
4 3,5-Cl ₂ 2-CH ₃ OH CH ₂ OCH ₂ CF ₃
5 3,5-Cl ₂ 2-CH ₃ OC (O) OCH ₃ CH ₂ OCH ₂ CF ₃
6 3,5-Cl ₂ -SH E4-1a
7 3,5-Cl ₂ 2-Cl OH E4-1a
8 3,5-Cl ₂ 2-Br OH E4-1a
9 3,5-Cl ₂ 2-CH ₃ OH E4-1a
10 3,5-Cl ₂ 2-CH ₃ OH E5-2a
11 3,5-Cl ₂ 2-CH ₃ OH E5-2b
12 3,5-Cl ₂ 2-CH ₃ OH E5-2c
13 3,5-Cl ₂ 2-Cl OH CH ₂ C (O) NHEt
14 3,5-Cl ₂ 2-Br OH CH ₂ C (O) NHEt
15 3,5-Cl ₂ 2-IOH CH ₂ C (O) NHEt
16 3,5-Cl ₂ 2-Cl OH CH ₂ C (O) NHPr-i
17 3,5-Cl ₂ 2-IOH CH ₂ C (O) NHPr-i
18 3,5-Cl ₂ 2-Cl OH CH ₂ C (O) NHCH ₂ CH ₂ Cl
19 3,5-Cl ₂ 2-Br OH CH ₂ C (O) NHCH ₂ CH ₂ Cl
20 3,5-Cl ₂ 2-CH ₃ OH CH ₂ C (O) NHCH ₂ CF ₃
21 3,5-Cl ₂ 2-NO ₂ OH CH ₂ C (O) NHCH ₂ CF ₃
22 3,5-Cl ₂ 2-NH ₂ OH CH ₂ C (O) NHCH ₂ CF ₃
23 3,5-Cl ₂ 2-NHC (O) CH ₃ OH CH ₂ C (O) NHCH ₂ CF ₃
24 3,5-Cl ₂ 2-CH ₃ OH CH ₂ C (O) NHCH (CF ₃ ) OH
25 3,5-Cl ₂ 2-Cl OH CH (CH ₃ ) C (O) NHEt
26 3,5-Cl ₂ 2-IOH CH (CH ₃ ) C (O) NHEt
27 3,5-Cl ₂ 2-Cl OH CH (CH ₃ ) C (O) NHCH ₂ CH ₂ Cl
28 3,5-Cl ₂ 2-Br OH CH (CH ₃ ) C (O) NHCH ₂ CH ₂ Cl
29 3,5-Cl ₂ 2-IOH CH (CH ₃ ) C (O) NHCH ₂ CH ₂ Cl
30 3,5-Cl ₂ 2-Cl OH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
31 3,5-Cl ₂ 2-Br OH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
32 3,5-Cl ₂ 2-IOH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
33 3,5-Cl ₂ 2-CH ₃ OH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
34 3,5-Cl ₂ 2-CH ₃ OHC (CH ₃ ) ₂ C (O) NHCH ₂ CF ₃
35 3,5-Cl ₂ 2-CH ₃ OH CH (CN) (Ph-2-F)
36 3,5-Cl ₂ 2-CH ₃ OH CH (CN) (Ph-4-F)
37 3,5-Cl ₂ 2-CH ₃ OH CH (CN) (Ph-4-Cl)
38 3,5-Cl ₂ 2-CH ₃ OH CH (CN) (Ph-4-CN)
39 3,5-Cl ₂ 2-Br OH CH ₂ (D10-2a)
40 3,5-Cl ₂ 2-IOH CH ₂ (D10-2a)
41 3,5-Cl ₂ 2-CH ₃ OH CH ₂ (D10-2a)
42 3,5-Cl ₂ 2-CH ₃ OC (O) OCH ₃ CH ₂ (D32-1a)
43 3,5-Cl ₂ 2-CH ₃ OH CH = NOCH ₃ (E)
44 3,5-Cl ₂ 2-CH ₃ OH CH = NOCH ₃ (Z)
45 3,5-Cl ₂ 2-CH ₃ OH CH = NOEt
46 3,5-Cl ₂ 2-CH ₃ OH CH = NOEt (Z)
47 3,5-Cl ₂ 2-CH ₃ OC (O) Et C (O) OCH ₃
48 3,5-Cl ₂ 2-CH ₃ OH Ph-2-F-4-CN
49 3,5-Cl ₂ 2-Br OH (D34-1c) Cl
50 3,5-Cl ₂ 2-CH ₃ OC (O) CH ₃ (D34-1c) Cl
51 3,5-Cl ₂ 2-CH ₃ OC (O) OCH ₃ (D34-1c) Cl
52 3,5-Cl ₂ 2-CH ₃ OH (D34-1c) I
53 3,5-Cl ₂ 2-CH ₃ OH (D34-1c) CN
54 3,5-Cl ₂ 2-CH ₃ OC (O) Pr-i (D34-1c) CN
55 3,5-Cl ₂ 2-CH ₃ OH (D35-1c) CN
56 3,5-Cl ₂ 2-Cl OHN (CH ₃ ) Ph
57 3,5-Cl ₂ 2-IOHN (CH ₃ ) Ph
58 3,5-Cl ₂ 2-Cl OHN (CH ₃ ) (D34-1a)
59 3,5-Cl ₂ 2-Br OHN (CH ₃ ) (D34-1a)
60 3,5-Cl ₂ 2-IOHN (CH ₃ ) (D34-1a)
61 3,5- (CF ₃ ) ₂ -OH CH ₂ C (O) NHCH ₂ CF ₃
62 3,5- (CF ₃ ) ₂ − OH CH ₂ (D10-2a)
63 3,5- (CF ₃ ) ₂ − OH CH ₂ (D32-1a)
64 3,4,5-Cl ₃ − OH E4-1a
65 3,4,5-Cl ₃ − SH E4-1a
66 3,4,5-Cl ₃ − OH CH ₂ C (O) NHCH ₂ CF ₃
67 3,4,5-Cl ₃ -OH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
68 3,4,5-Cl ₃ − OH CH ₂ (D10-2a)
69 3,4,5-Cl ₃ − OH CH ₂ OEt
70 3,4,5-Cl ₃ − OH CH ₂ OCH ₂ CF ₃
71 3,4-Cl ₂ -5-CF ₃ -OH CH ₂ OCH ₂ CF ₃
72 3,4-Cl ₂ -5-CF ₃ -OH E4-1a
73 3,4-Cl ₂ -5-CF ₃ -SH E4-1a
74 3,4-Cl ₂ -5-CF ₃ -OH CH ₂ C (O) NHCH ₂ CF ₃
75 3-Cl-4-F-5-CF ₃ 2-CH ₃ OH CH ₂ C (O) NHCH ₂ CF ₃
76 3,5-Cl ₂ -4-OCHF ₂ 2-CH ₃ OH CH ₂ C (O) NHCH ₂ CF ₃
77 3,5- (CF ₃ ) ₂ − OH CH (CH ₃ ) C (O) NHCH ₂ CF ₃
78 3,4-Cl ₂ -5-CF ₃ -OH CH ₂ (D10-2a)
79 3,4-Cl ₂ -5-CF ₃ − SH CH ₂ (D10-2a)
80 3,4-Cl ₂ -5-CF ₃ − OH CH = NOCH ₃
81 3,4-Cl ₂ -5-CF ₃ − SH CH = NOCH ₃ (Z)
82 3,4-Cl ₂ -5-CF ₃ -OH CH = NOEt
83 3,4-Cl ₂ -5-CF ₃ -SH CH = NOEt (Z)
――――――――――――――――――――――――――――――――――――
Table 2 ――――――――――――――――――――――――――――――――――――
No. Melting point (℃) / ¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz)
――――――――――――――――――――――――――――――――――――
1 112.0-114.0
2 δ7.55-7.75 (m, 3H), 7.50 (s, 2H), 7.44 (t, J = 1.8Hz, 1H),
7.2-7.3 (m, 1H), 5.02 (d, J = 7.1Hz, 2H), 3.95-4.2 (m, 3H),
3.72 (d, J = 17.4Hz, 1H).
3 δ7.89 (s, 1H), 7.69 (d, J = 7.2Hz, 1H), 7.59 (d, J = 7.2Hz, 1H),
7.50 (s, 2H), 7.45 (t, J = 1.5Hz, 1H), 6.8-7.0 (m, 1H),
5.04 (d, J = 7.5Hz, 2H), 4.0-4.2 (m, 3H), 3.70 (d, J = 17.4Hz, 1H).
4 111.0-114.0
5 (CDCl ₃ , Me ₄ Si, 400MHz) δ7.5-7.6 (m, 4H), 7.43 (t, J = 2.0Hz, 1H),
7.25 (d, J = 8.0Hz, 1H), 5.43 (s, 2H), 4.15 (q, J = 8.6Hz, 2H),
4.09 (d, J = 17.2Hz, 1H), 3.70 (d, J = 17.2Hz, 1H), 3.67 (s, 3H),
2.39 (s, 3H).
6 (CDCl ₃ , Me ₄ Si, 700MHz) δ7.82 (d, J = 7.7Hz, 2H), 7.65-7.75 (m, 3H),
7.51 (s, 2H), 7.44 (s, 1H), 6.1-6.2 (m, 1H), 4.05-4.15 (m, 2H),
3.92 (dd, J = 15.4, 7.0Hz, 1H), 3.70 (d, J = 17.5Hz, 1H),
2.35-2.45 (m, 1H), 2.1-2.2 (m, 1H), 1.95-2.1 (m, 2H).
7 165.0-167.0
8 δ7.80 (s, 1H), 7.35-7.65 (m, 5H), 6.65 (d, J = 7.5Hz, 1H),
5.75-5.9 (m, 1H), 4.07 (d, J = 17.4Hz, 1H), 3.8-4.05 (m, 2H),
3.72 (d, J = 17.4Hz, 1H), 2.15-2.35 (m, 1H), 1.85-2.1 (m, 3H).
9 154.0-156.0
10 154.0-158.0
11 δ7.64 (d, J = 8.4Hz, 1H), 7.35-7.55 (m, 6H), 5.2-5.35 (m, 1H),
4.07 (d, J = 17.1Hz, 1H), 3.69 (d, J = 17.1Hz, 1H), 3.0-3.3 (m, 3H),
2.83 (dd, J = 14.4, 6.6Hz, 1H), 2.5-2.7 (m, 2H), 2.46 (s, 3H).
12 δ7.35-7.55 (m, 6H), 6.64 (d, J = 7.5Hz, 1H), 4.9-5.0 (m, 1H),
4.09 (d, J = 17.4Hz, 1H), 3.71 (d, J = 17.4Hz, 1H),
3.44 (dd, J = 12.6, 7.2Hz, 1H), 3.0-3.3 (m, 3H), 2.55-2.7 (m, 1H),
2.45 (s, 3H), 2.3-2.45 (m, 1H).
13 211.0-213.0
14 δ7.86 (s, 1H), 7.64 (d, J = 8.1Hz, 1H), 7.55 (d, J = 8.1Hz, 1H),
7.50 (s, 2H), 7.43 (t, J = 5.1Hz, 1H), 7.18 (t, J = 4.8Hz, 1H),
6.4-6.5 (m, 1H), 4.11 (d, J = 4.8Hz, 2H), 4.07 (d, J = 17.4Hz, 1H),
3.71 (d, J = 17.4Hz, 1H), 3.2-3.4 (m, 2H), 1.16 (t, J = 8.1Hz, 3H).
15 (CDCl ₃ , Me ₄ Si, 400 MHz) δ8.1-8.15 (m, 1H), 7.65-7.75 (m, 1H),
7.4-7.55 (m, 4H), 6.83 (bs, 1H), 6.23 (bs, 1H), 4.0-4.15 (m, 3H),
3.69 (d, J = 17.1Hz, 1H), 3.3-3.4 (m, 2H), 1.15-1.2 (m, 3H).
16 146.0-148.0
17 (CDCl ₃ , Me ₄ Si, 400 MHz) δ8.1-8.15 (m, 1H), 7.65-7.75 (m, 1H),
7.4-7.55 (m, 4H), 6.77 (bs, 1H), 5.95-6.05 (m, 1H),
4.0-4.15 (m, 4H), 3.69 (d, J = 17.1Hz, 1H), 1.19 (d, J = 6.4Hz, 6H).
18 83.0-86.0
19 142.0-146.0
20 173.5-175.5
21 103.0-105.0
22 δ7.4-7.55 (m, 4H), 6.85-7.0 (m, 3H), 6.55-6.7 (m, 1H),
5.65 (bs, 2H), 4.14 (d, J = 5.1Hz, 2H), 4.04 (d, J = 17.1Hz, 1H),
3.85-4.05 (m, 2H), 3.65 (d, J = 17.1Hz, 1H).
23 δ10.95 (s, 1H), 8.72 (s, 1H), 7.5-7.65 (m, 2H), 7.49 (s, 2H),
7.42 (d, J = 1.8Hz, 1H), 7.25-7.4 (m, 1H), 6.45-6.6 (m, 1H),
4.17 (d, J = 5.5Hz, 2H), 4.11 (d, J = 17.7Hz, 1H), 3.9-4.05 (m, 2H),
3.73 (d, J = 17.7Hz, 1H), 2.19 (s, 3H).
24 δ7.62 (dd, J = 9.0, 2.4Hz, 1H), 7.35-7.55 (m, 6H),
6.90 (t, J = 5.7Hz, 1H), 5.7-5.85 (m, 1H), 5.54 (bs, 1H),
4.24 (dd, J = 17.1, 5.7Hz, 1H), 4.08 (d, J = 17.4Hz, 1H),
4.04 (dd, J = 17.1, 5.7Hz, 1H), 3.71 (d, J = 17.4Hz, 1H),
2.38 (s, 3H).
25 δ7.6-7.75 (m, 3H), 7.50 (s, 2H), 7.4-7.5 (m, 1H),
6.85-6.95 (m, 1H), 5.9-6.0 (m, 1H), 4.55-4.7 (m, 1H),
4.06 (d, J = 17.4Hz, 1H), 3.69 (d, J = 17.4Hz, 1H), 3.25-3.4 (m, 2H),
1.50 (d, J = 6.9Hz, 3H), 1.18 (t, J = 7.2Hz, 3H).
27 δ7.6-7.75 (m, 3H), 7.50 (s, 2H), 7.4-7.5 (m, 1H),
6.86 (d, J = 7.5Hz, 1H), 6.52 (bs, 1H), 4.65-4.8 (m, 1H),
4.06 (d, J = 17.4Hz, 1H), 3.6-3.75 (m, 3H), 1.45-1.6 (m, 5H).
28 δ7.86 (s, 1H), 7.64 (d, J = 7.2Hz, 1H), 7.54 (d, J = 7.2Hz, 1H),
7.49 (s, 2H), 7.43 (t, J = 1.8Hz, 1H), 6.85-7.05 (m, 2H),
4.75 (qui, J = 7.2Hz, 1H), 4.07 (d, J = 17.4Hz, 1H),
3.70 (d, J = 17.4Hz, 1H), 3.5-3.65 (m, 4H), 1.51 (d, J = 7.2Hz, 3H).
29 101.0-104.0
30 δ7.6-7.75 (m, 3H), 7.50 (s, 2H), 7.45 (s, 1H), 6.8-7.0 (m, 2H),
4.7-4.85 (m, 1H), 4.06 (d, J = 17.4Hz, 1H), 3.8-4.05 (m, 2H),
3.69 (d, J = 17.4Hz, 1H), 1.53 (d, J = 7.2Hz, 3H).
31 δ7.7-7.85 (m, 1H), 7.65-7.75 (m, 1H), 7.3-7.55 (m, 5H),
6.95-7.1 (m, 1H), 4.83 (qui, J = 7.2Hz, 1H),
4.07 (d, J = 17.4Hz, 1H), 3.8-4.0 (m, 2H), 3.70 (d, J = 17.4Hz, 1H),
1.51 (d, J = 7.2Hz, 3H).
32 103.0-105.0
33 166.0-168.0
34 δ7.35-7.55 (m, 7H), 6.20 (s, 1H), 4.10 (d, J = 17.4Hz, 1H),
3.9-4.0 (m, 2H), 3.70 (d, J = 17.4Hz, 1H), 2.45 (s, 3H),
1.70 (s, 6H).
35 139.0-143.0
36 δ7.35-7.6 (m, 8H), 7.1-7.2 (m, 2H), 6.25-6.4 (m, 2H),
4.06 (d, J = 17.4Hz, 1H), 3.69 (d, J = 17.4Hz, 1H), 2.48 (s, 3H).
37 (DMSO-d ₆ , Me ₄ Si, 300MHz) δ7.4-7.6 (m, 10H), 6.36 (d, J = 8.4Hz, 1H),
6.30 (d, J = 8.4Hz, 1H), 4.07 (d, J = 17.4Hz, 1H),
3.68 (d, J = 17.4Hz, 1H), 2.49 (s, 3H).
38 98.0-102.0
39 165.0-168.0
40 δ8.80 (s, 1H), 8.11 (s, 1H), 7.65-7.75 (m, 1H), 7.35-7.55 (m, 5H),
6.52 (s, 1H), 4.80 (d, J = 5.4Hz, 2H), 4.06 (d, J = 17.4Hz, 1H),
3.67 (d, J = 17.4Hz, 1H).
41 137.0-139.0
42 δ8.56 (d, J = 4.8Hz, 1H), 7.65-7.7 (m, 1H), 7.5-7.55 (m, 4H),
7.35-7.45 (m, 2H), 7.15-7.3 (m, 2H), 5.21 (s, 2H),
4.09 (d, J = 17.4Hz, 1H), 3.70 (d, J = 17.4Hz, 1H), 3.58 (s, 3H),
2.40 (s, 3H).
43 (CDCl ₃ , Me ₄ Si, 400MHz) δ8.58 (d, J = 14.2Hz, 1H), 7.85 (d, 14.2Hz, 1H),
7.4-7.6 (m, 6H), 4.09 (d, J = 17.4Hz, 1H), 3.78 (s, 3H),
3.70 (d, J = 17.4Hz, 1H), 2.51 (s, 3H).
44 173.0-173.5
45 143.0-146.0
46 149.0-150.0
47 135.0-136.0
48 δ8.70 (d, J = 8.2Hz, 1H), 7.8-7.95 (m, 1H), 7.35-7.7 (m, 8H),
4.10 (d, J = 17.5Hz, 1H), 3.72 (d, J = 17.5Hz, 1H), 2.56 (s, 3H).
49 135.0-137.0
50 178.0-179.5
51 104.0-107.0
52 181.0-183.0
53 124.0-127.0
54 150.0-153.0
55 112.0-115.0
56 δ7.65-7.9 (m, 3H), 7.4-7.55 (m, 3H), 7.25-7.35 (m, 3H),
6.85-7.0 (m, 3H), 4.07 (d, J = 17.4Hz, 1H), 3.70 (d, J = 17.4Hz, 1H),
3.34 and 3.11 (s, 3H).
57 δ8.14 and 8.10 (s, 1H), 7.7-7.8 (m, 1H), 7.4-7.6 (m, 5H),
7.2-7.35 (m, 2H), 6.85-7.05 (m, 3H),
4.06 and 4.01 (d, J = 17.4Hz, 1H), 3.69 and 3.64 (d, J = 17.4Hz, 1H),
3.37 and 3.13 (s, 3H).
58 224.0-225.0
59 219.0-222.0
60 205.0-207.0
61 171.0-172.0
62 166.0-167.0
63 δ8.55-8.6 (m, 1H), 8.10 (s, 2H), 7.96 (s, 2H), 7.93 (s, 1H),
7.85 (bs, 1H), 7.65-7.8 (m, 3H), 7.3-7.4 (m, 1H),
7.2-7.3 (m, 1H), 4.75 (d, J = 4.5Hz, 2H), 4.23 (d, J = 17.4Hz, 1H),
3.80 (d, J = 17.4Hz, 1H).
64 115.0-116.0
65 90.0-93.0
66 δ7.87 (d, J = 8.4Hz, 2H), 7.72 (d, J = 8.4Hz, 2H), 7.64 (s, 2H),
7.48 (t, J = 5.1Hz, 1H), 7.36 (t, J = 6.3Hz, 1H),
4.26 (d, J = 5.1Hz, 2H), 4.11 (d, J = 17.4Hz, 1H), 3.85-4.05 (m, 2H),
3.71 (d, J = 17.4Hz, 1H).
67 189.0-192.0
68 117.0-120.0
69 δ7.86 (d, J = 8.4Hz, 2H), 7.74 (d, J = 8.4Hz, 2H), 7.65 (s, 2H),
6.87 (bs, 1H), 4.96 (d, J = 6.9Hz, 2H), 4.11 (d, J = 17.4Hz, 1H),
3.6-3.8 (m, 3H), 1.23 (t, J = 7.2Hz, 3H).
70 δ7.87 (d, J = 8.7Hz, 2H), 7.76 (d, J = 8.7Hz, 2H), 7.65 (s, 2H),
7.00 (bs, 1H), 5.07 (d, J = 6.9Hz, 2H), 4.0-4.2 (m, 3H),
3.71 (d, J = 17.4Hz, 1H).
71 δ7.95 (bs, 1H), 7.8-7.95 (m, 3H), 7.79 (s, 1H), 7.77 (s, 1H),
6.98 (bs, 1H), 5.07 (d, J = 6.9Hz, 2H), 4.0-4.25 (m, 3H),
3.73 (d, J = 17.4Hz, 1H).
72 161.0-163.0
73 δ7.93 (s, 1H), 7.7-7.9 (m, 4H), 7.55-7.7 (m, 2H), 6.1-6.2 (m, 1H),
4.05-4.2 (m, 2H), 3.91 (q, J = 7.5Hz, 1H), 3.72 (d, J = 17.4Hz, 1H),
2.3-2.35 (m, 1H), 1.9-2.25 (m, 3H).
74 δ8.01 (s, 1H), 7.8-7.95 (m, 3H), 7.7-7.8 (m, 2H), 7.4-7.7 (m, 2H),
4.22 (d, J = 4.8Hz, 2H), 4.16 (d, J = 17.4Hz, 1H), 3.85-4.1 (m, 2H),
3.73 (d, J = 17.4Hz, 1H).
75 149.0-150.5
76 δ7.65 (s, 2H), 7.2-7.55 (m, 4H), 6.95 (bs, 1H), 6.61 (t, J = 73.5Hz, 1H),
4.22 (d, J = 4.8Hz, 2H), 4.10 (d, J = 17.4Hz, 1H), 3.85-4.0 (m, 2H),
3.69 (d, J = 17.4Hz, 1H), 2.45 (s, 3H).
77 δ8.09 (s, 2H), 7.97 (s, 1H), 7.86 (d, J = 8.4Hz, 2H), 7.77 (d, J = 8.4Hz, 2H),
7.25-7.4 (m, 1H), 6.95-7.15 (m, 1H), 4.75-4.9 (m, 1H),
4.22 (d, J = 17.4Hz, 1H), 3.8-4.05 (m, 2H), 3.77 (d, J = 17.4Hz, 1H),
1.51 (d, J = 6.9Hz, 3H).
78 δ8.80 (s, 1H), 7.94 (d, J = 2.1Hz, 1H), 7.8-7.9 (m, 3H),
7.69 (d, J = 8.1Hz, 2H), 7.30 (d, J = 2.1Hz, 1H), 7.27 (bs, 1H),
4.78 (d, J = 5.4Hz, 2H), 4.15 (d, J = 17.4Hz, 1H), 3.74 (d, J = 17.4Hz, 1H).
79 δ8.80 (t, J = 2.1Hz, 1H), 8.60 (bs, 1H), 7.93 (s, 1H), 7.8-7.9 (m, 3H),
7.6-7.7 (m, 2H), 7.39 (t, J = 1.2Hz, 1H), 5.11 (d, J = 4.8Hz, 2H),
4.15 (d, J = 17.4Hz, 1H), 3.72 (d, J = 17.4Hz, 1H).
80 121.0-125.0
81 δ9.81 (d, J = 9.0Hz, 1H), 8.30 (d, J = 9.0Hz, 1H), 7.8-8.0 (m, 4H),
7.73 (d, J = 8.4Hz, 2H), 4.16 (d, J = 17.4Hz, 1H), 3.97 (s, 3H),
3.74 (d, J = 17.4Hz, 1H).
82 74.0-75.0
83 δ9.83 (d, J = 9.0Hz, 1H), 8.30 (d, J = 9.0Hz, 1H), 7.8-8.0 (m, 4H),
7.73 (d, J = 8.4Hz, 2H), 4.22 (q, J = 6.9Hz, 2H), 4.16 (d, J = 17.4Hz, 1H),
3.74 (d, J = 17.4Hz, 1H), 1.33 (t, J = 6.9Hz, 3H).

The proton nuclear magnetic resonance chemical shift value was measured at 300 MHz in deuterated chloroform solvent using Me ₄ Si (tetramethylsilane) as a reference substance.

The other active ingredient compound used together with the isoxazoline-substituted benzamide compound represented by the formula (1) of the present invention is known as an insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal compound. It is shown together with Compound No. in Table 3 below. These compounds tend to increase the amount of sprayed medicine and the number of spraying due to the emergence of resistant pests or resistant bacteria, and the lack of insecticidal sterilization spectrum and residual effects. There are also cases where improvements are required from the viewpoint of environmental safety, such as an increase in the risk to aquatic organisms.
Table 3 ――――――――――――――――――――――――――――――――――――
No. Compound name (generic name) No. Compound name (generic name)
――――――――――――――――――――――――――――――――――――
a acibenzoral-S-methyl jd potassium polysulfide
b acylaminobenzamide je proquinazide
c Asipetax jf Prothiocarb
d Aldimorph jg Prothioconazole
e Amisulbrom jh Piracarbolide
f ambam ji pyraclostrobin
g Ampropylphos jj Pyrididinitrile
h Anilazine jk Pyroxycycloa
i Allyl alcohol jl Piroxysulfur
j Aurerofungin jm Phenylphenol
k azaconazole jn quinomethionate
l Ajitiram jo quinoxifen
m azoxystrobin jp kinzen
n Barium polysulfide jq Quinacetor
o Benalaxyl jr quinazamid
p penodalil js quinconazole
q Benomyl jt Ravenzazole
r Benquinox ju Sodium bicarbonate
s Ventalron jv Sodium hypochlorite
t bench avari carb jw sulfur
u Benchazole jx Spiroxamine
v Benzalkonium chloride jy salicylanilide
w benzmacrill jz silthiofam
x benzamorph ka simeconazole
y Benzohydroxamic acid kb Sodium azide
z Vinapacryl kc Sodium orthopenyl penoxide
aa biphenyl kd sodium pentachlorophenoxide
ab vitertanol ke sodium polysulfide
ac bitionol kf tebuconazole
ad betoxazine kg technazen
ae Bordeaux liquid kh tetraconazole
af Blastcidin-S ki thiabendazole
ag boscalid kj thiadiazine
ah bromoconazole kk tifluzamide
ai buprimate kl thiophanate-methyl
aj buthiobeto km chiram
ak butylamine kn torquelophos-methyl
al calcium polysulfide ko trilfuranide
am capta fall kp triazimehon
an captan kq triazimenol
ao Copper oxychloride kr Triazoxide
ap carpropamide ks tricyclazole
aq carbamorph kt tridemorph
ar carbendazine ku triflumizole
as carboxin kv triforin
at carvone kw triticonazole
au Cheshund Mixture kx
av Kinomethionate ky Tecolum
aw cloben bench az kz
ax chloraniformane la tisiofen
ay chloranil lb thiochlorfenfim
az chlorphenazole lc thiomersam
ba chloronebu ld thiophanate
bb chloropicrin le thioquinox
bc chlorothalonil lf thiazinyl
bd chloroquinox lg thioximide
be Clozolinate lh Trimmer Curia Setate
bf crimbazole li triamifos
bg clotrimazole lj triarimol
bh Copper Acetate lk Triazbutyl
bi Basic copper carbonate ll Tributyltin oxide
bj cupric hydroxide lm trickle amide
bk Copper naphthalene ln Trifloxystrobin
bl copper oreite lo validamycin
bm copper sulfate lp vinclozolin
bn Basic copper sulfate lq Zinc sulfate
bo copper zinc chloromate lr genev
bp cresol ls ziram
bq kufraneb lt zoxamide
br cuprobum lu zarylamide
bs cyazofamide lv zinc naphthenate
bt cyclafluamide lw shiitake mycelium extract
bu cycloheximide lx bronopol
bv cyflufenamide ly formaldehyde
bw simoxanyl lz nitraprine
bx cypendazole ma oxolinic acid
by cyproconazole mb oxytetracycline
bz cyprodinil mc streptomycin
ca cyprofram md teclophthalam
cb dazomet me thiomersal
cc dby sea bm mf iminin
cd devacarb mg rubavirin
ce decafentin mh aldoxicarb
cf dehydroacetate mi kazusahos
cg dicron mj diclofenthion
ch dichlorophen mk DSP
ci Diclozoline ml etoprophos
cj Diclobutrazol mm Fensulfothion
ck diclofuranide mn fostiazate
cl Dichromedin mo Fostietan
cm Dichlorane mp Isoamidophos
cn Dietofencarb mq Isazofos
co diethylpyrocarbonate mr oxamyl
cp Diclocimet ms Phenamifos
cq difenoconazole mt thionazine
cr diflumethrin mu acequinosyl
cs dimethylomele mv acrinathrin
ct dimethomorph mw amitraz
cu dimoxystrobin mx bifenazate
cv diniconazole my bromopropyrate
cw Diniconazole-M mz Chlorobenzilate
cx dinobton na clofentezin
cy Zino Cup nb Siflumethofen
cz zinocup-4 nc cyhexatin
da Zino Cup-6 nd Zico Fall
db zinocton ne dienochlor
dc dinosulfone nf etoxazole
dd zinoterbon ng phenazaquin
de diphenylamine nh phenbutatin oxide
df dipyrithione ni fenpropatoline
dg dinosulfiram nj phenproxymate
dh Zitalimphos nk Fenothiocarb
di dithianon nl full acrylpyrim
dj dns nm nm halfenprox
dk dodemorph nn hexythiazox
dl dojin no milbemectin
dm drazoxolone np sienopyrafen
dn Edefenophos nq Propargit
do epoxiconazole nr pyridaben
dp etaconazole ns pyrimidifene
dq Ethymol nt Spirodiclofen
dr etridianol nu spiromesifen
ds etem nv tebufenpyrad
dt ethoxyquin nw abamectin
du Ethyl Mercury Acetate nx Acephate
dv ethyl mercury bromide ny acetamiprid
dw methylmercury chloride nz alanicarb
dx ethyl mercury phosphate oa aldicarb
dy famoxazone ob allethrin
dz phenalimol oc azinephos-methyl
ea febuconazole od bacillus thuringiensis
eb fenamidon oe bendiocarb
ec Fendazoslam of Benfuracarb
ed fenfram og bensl tap
ee Fenhexamide oh bifenthrin
ef phenoxanyl oi buprofezin
eg fenpiclonil oj butcarboxyne
eh phenpropidin ok carbaryl
ei fenpropimorph ol carbofuran
ej fen chin om carbosulfan
ek Velvan on Cartap
el ferrimson oo chlorfenapyr
em Fluazinam op Chlorpyrifos
en fludioxonil oq chlorfenvinphos
eo fluoroimide or chlorfluazuron
ep fluquinconazole os clothianidin
eq flusilazole ot chromafenozide
er Fursulfamide ou Clopyrifos-methyl
es flutolanil ov cycloprotorin
et Furtria Fall ow Sifluthrin
eu Folpet ox beta-cyfluthrin
ev focetyl-aluminum oy cypermethrin
ew fuberidazole oz cyromazine
ex flaxil pa cihalothrin
ey furametopir pb lambda-cyhalothrin
ez phenaminosulf pc deltamethrin
fa Fenapanil pd Diafentiuron
fb fenitropan pe diazinon
fc Full Met Bar pf Diacroden
fd full morph pg dichlorvos
fe fluotrimazole ph diflubenzuron
ff Fluoxastrobin pi Dimethylvinphos
fg full carbanyl pj dinotefuran
fh fluconazole pk diophenolan
fi Fluconazole-cis pl disulfone
fj Furumecyclox pm Dimethoate
fk phlophanate pn emamectin benzoate
fl Guazatine po EPN
fm gliodin pp esfenvalerate
fn griseofulvin pq ethiophene carb
fo hexachlorobenzene pr ethiprole
fp hexaconazole ps etofenprox
fq Himexazole pt Etrimfos
fr haracrinate pu fenitrothion
fs hexachlorobutadiene pv fenocarb
ft hexylthiophos pw phenoxycarb
fu hydroxyquinoline sulfate px fenpropatoline
fw imazaril py fenthion
fx imibenconazole pz fenvalerate
fy iminotadine qa fipronil
fz ipconazole qb flonicamid
ga iprobenfos qc fulvendiamide
gb iprodione qd flucitrinate
gc isoprothiolane qe flufenerim
gd iprovaricarb qf flufenoxuron
ge isopyrazam qg flufenprox
gf kasugamycin qh fulvalinate
gg Cresoxime-methyl qi tau-fulvalinate
gh mancopper qj honohos
gi Mancozeb qk formethanate
gj mannebu ql formothion
gk mepanipyrim qm furatiocarb
gl mepronil qn halofenozide
gm metalaxyl qo hexaflumuron
gn metconazole qp hydramethylnon
go metasulfocarb qq imidacloprid
gp methylam qr isofenphos
gq metminostrobin qs indoxacarb
gr microbutanyl qt isoprocarb
gs mevenil qu isoxathion
gt mecarbinzide qv lufenuron
gu mercuric chloride qw malathion
gv mercuric oxide qx metal dehydride
gw mercuric chloride qy methamidophos
gx metalaxyl-M qz methidathion
gy metam ra methacrifos
gz metalloxolone rb metaflumizone
ha female floxam rc metal carve
hb methyl bromide rd mesomil
hc methyl isothiocyanate re mesoprene
hd methyl mercury benzoate rf methoxychlor
he Methyl Mercury Dicyandiamide rg Methoxyphenozide
hf metminostrobin rh monocrotophos
hg metolaphenone ri muscarole
hh metsulfobax rj nitenpyram
hi Milneb rk Pyrifluquinazone
hj microzoline rl ometoate
hk methoxymethyl mercury chloride rm oxydemeton-methyl
hl nabum rn oxydepropos
hn nitrotar-isopropyl ro parathion
ho nuarimol rp parathion-methyl
hp natamycin rq permethrin
hq Nicobifen rr Fentate
hr Nitrostyrene rs Foxime
hs octirinon rt holate
ht off race ru ho salon
hu oxadixyl rv phosmet
hv oxycarboxyl rw phosphamidon
hw oxpoconazole fumarate rx pirimicarb
hx OCH ry pyrimifos-methyl
hy orisatrobin rz profenofos
hz organic copper sa prothiophos
ia perfazoate sb propaphos
ib penconazole sc protrifenbut
ic pencyclon sd pymetrozine
id pentiopyrad se pyracrofos
ie phthalide sf pyridalyl
if piperalin sg pyriproxyfen
ig polyoxin sh rotenon
ih Potassium bicarbonate si Sulprophos
ii Probenazole sj Silafluophene
ij prochloraz sk spinosad
ik prosimidone sl sulfoxaflor
il propamocarb hydrochloride sm tebufenozide
im propiconazole sn teflubenzuron
in Propinebu so Tefluthrin
io pyrazophos sp terbufos
ip pirifenox sq tetrachlorobinphos
iq pyrimethanil sr thiacloprid
ir pirocuron ss thiocyclam
is pentachlorophenol st thiodicarb
it urea phenylmercury su thiamethoxam
iu phenyl mercury acetate sv thiophanox
iv Phenyl Mercury Chloride sw Thiometone
iw phenyl mercury night sx tolfenpyrad
ix Phenyl Mercury Salicylate sy Tralomethrin
iy phosdifen sz trichlorphone
iz picoxystrobin ta triazuron
ja polycarbamate tb triflumuron
jb polyoxorim tc bamidethione
jc potassium azide td mesoplane
fv Nickel bis (dimethyldithiocarbamate)
te triazamate tf tebufenozide
tg delta meslin th hydramethylnon
ti noballon tj chlorantranylprol
tk Cyantraniprolol tl befrazoate
tm benomyl tn trichoderma atrovilide
to Talalomyces sativas tp hydroxyisoxazole
tq Isotianil tr Spinetram
ts Pirochiron tt pivlubumid (ISO application pending)
tu from Metokin tvIKI-3106
tw full pyraziflon ――――――――――――――――――――――――――――――――――――
The characteristics of the composition of the present invention and the method of the present invention are as follows. Firstly, the efficacy of insecticide, acaricide, nematicide, mollusc, bactericidal or bactericidal is clear as compared with the case where each drug is applied alone. In addition to being enhanced, it provides immediate insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal effects. Second, the existing insecticidal, acaricidal, nematicidal, molluscicidal, broad insecticidal, acaricidal, nematicidal, molluscicidal, germicidal or bactericidal spectrum not seen in bactericides or bactericides It is that aftereffect is induced. Thirdly, compared to the case where each drug is used alone, the amount of dropped drug can be reduced.

  That is, the composition of the present invention and the method of the present invention exhibit synergistic insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal effects. This synergistic insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal effect is predicted from the insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal effect of each single agent. It can be said that the usefulness of the composition of the present invention and the method of the present invention is that it can exert a more reliable control effect than various compounds alone against various pests.

Among the compounds shown in Table 3 above, compounds that have a synergistically improved control effect on mites, particularly when combined with the isoxazoline-substituted benzamide compound represented by Formula (1), are listed below. Shown in Table 4.
[Table 4]
――――――――――――――――――――――――――――――――――――
No. Compound name (generic name) No. Compound name (generic name)
――――――――――――――――――――――――――――――――――――
mu acechinosyl np sienopyrafen
nb siflumethofen nq propargite
ne dienochlor nt spirodiclofen
nf etoxazole nu spiromesifen
nh phenbutatin oxide oo chlorfenapyr
no Milbemectin ――――――――――――――――――――――――――――――――――――
In addition, among the compounds shown in Table 3 above, compounds that have a synergistically improved control effect on the tobacco moth, particularly when combined with the isoxazoline-substituted benzamide compound represented by the formula (1), are described below. Table 5 shows.
[Table 5]
――――――――――――――――――――――――――――――――――――
No. Compound name (generic name) No. Compound name (generic name)
――――――――――――――――――――――――――――――――――――
sf pyridalyl sk spinosad
mo milbemectin tj chlorantranylprol
ot Chromafenozide pn Emamectin Benate
pr ethiprol px phenpropatrin
qc fulvendiamide rd mesomil
tg delta meslin oo chlorfenapyr
nx acephate od bacillus thurigensis
qf Flufenoxuron qs Indoxacarb --------------
Next, specific examples of combinations of compounds having a synergistic pest control effect are listed below. In the following notation, for example, “1 + a” represents a combination of the No. 1 compound in Table 1 and the acibenzolar-S-methyl in No. a in Table 2.

Examples of compound combinations: 1 + a, 1 + b, 1 + c, 1 + d, 1 + e, 1 + f, 1 + g, 1 + h, 1 + i, 1 + j, 1 + k, 1 + l, 1 + m, 1 + n, 1 + o, 1 + p, 1 + q, 1 + r, 1 + s, 1 + t, 1 + u, 1 + v, 1 + w, 1 + x, 1 + y, 1 + z, 1 + aa, 1 + ab, 1 + ac, 1 + ad, 1 + ae, 1 + af, 1 + ag, 1 + ah, 1 + ai, 1 + aj, 1 + ak, 1 + al, 1 + am, 1 + an, 1 + ao, 1 + ap, 1 + aq, 1 + ar, 1 + as, 1 + at, 1 + au, 1 + av, 1 + aw, 1 + ax, 1 + ay, 1 + az, 1 + ba, 1 + bb, 1 + bc, 1 + bd, 1 + be, 1 + bf, 1 + bg, 1 + bh, 1 + bi, 1 + bj, 1 + bk, 1 + bl, 1 + bm, 1 + bn, 1 + bo, 1 + bp, 1 + bq, 1 + br, 1 + bs, 1 + bt, 1 + bu, 1 + bv, 1 + bw, 1 + bx, 1 + by, 1 + bz, 1 + ca, 1 + cb, 1 + cc, 1 + cd, 1 + ce, 1 + cf, 1 + cg, 1 + ch, 1 + ci, 1 + cj, 1 + ck, 1 + cl, 1 + cm, 1 + cn, 1 + co, 1 + cp, 1 + cq, 1 + cr, 1 + cs, 1 + ct, 1 + cu, 1 + cv, 1 + cw, 1 + cx, 1 + cy, 1 + cz, 1 + da, 1 + db, 1 + dc, 1 + dd, 1 + de, 1 + df, 1 + dg, 1 + dh, 1 + di, 1 + dj, 1 + dk, 1 + dl, 1 + dm, 1 + dn, 1 + do, 1 + dp, 1 + dq, 1 + dr, 1 + ds, 1 + dt, 1 + du, 1 + dv, 1 + dw, 1 + dx, 1 + dy, 1 + dz, 1 + ea, 1 + eb, 1 + ec, 1 + ed, 1 + ee, 1 + ef, 1 + eg, 1 + eh, 1 + ei, 1 + ej, 1 + ek, 1 + el, 1 + em, 1 + en, 1 + eo, 1 + ep, 1 + eq, 1 + er, 1 + es, 1 + et, 1 + eu, 1 + ev, 1 + ew, 1 + ex, 1 + ey, 1 + ez, 1 + fa, 1 + fb, 1 + fc, 1 + fd, 1 + fe, 1 + ff, 1 + fg, 1 + fh, 1 + fi, 1 + fj, 1 + fk, 1 + fl, 1 + fm, 1 + fn, 1 + fo, 1 + fp, 1 + fq, 1 + fr, 1 + fs, 1 + ft, 1 + fu, 1 + fv, 1 + fw, 1 + fx, 1 + fy, 1 + fz, 1 + ga, 1 + gb, 1 + gc, 1 + gd, 1 + ge, 1 + gf, 1 + gg, 1 + gh, 1 + gi, 1 + gj, 1 + gk, 1 + gl, 1 + gm, 1 + gn, 1 + go, 1 + gp, 1 + gq, 1 + gr, 1 + gs, 1 + gt, 1 + gu, 1 + gv, 1 + gw, 1 + gx, 1 + gy, 1 + gz, 1 + ha, 1 + hb, 1 + hc, 1 + hd, 1 + he, 1 + hf, 1 + hg, 1 + hh, 1 + hi, 1 + hj, 1 + hk, 1 + hl, 1 + hm, 1 + hn, 1 + ho, 1 + hp, 1 + hq, 1 + hr, 1 + hs, 1 + ht, 1 + hu, 1 + hv, 1 + hw, 1 + hx, 1 + hy, 1 + hz, 1 + ia, 1 + ib, 1 + ic, 1 + id, 1 + ie, 1 + if, 1 + ig, 1 + ih, 1 + ii, 1 + ij, 1 + ik, 1 + il, 1 + im, 1 + in, 1 + io, 1 + ip, 1 + iq, 1 + ir, 1 + is, 1 + it, 1 + iu, 1 + iv, 1 + iw, 1 + ix, 1 + iy, 1 + iz, 1 + ja, 1 + jb, 1 + jc, 1 + jd, 1 + je, 1 + jf, 1 + jg, 1 + jh, 1 + ji, 1 + jj, 1 + jk, 1 + jl, 1 + jm, 1 + jn, 1 + jo, 1 + jp, 1 + jq, 1 + jr, 1 + js, 1 + jt, 1 + ju, 1 + jv, 1 + jw, 1 + jx, 1 + jy, 1 + jz, 1 + ka, 1 + kb, 1 + kc, 1 + kd, 1 + ke, 1 + kf, 1 + kg, 1 + kh, 1 + ki, 1 + kj, 1 + kk, 1 + kl, 1 + km, 1 + kn, 1 + ko, 1 + kp, 1 + kq, 1 + kr, 1 + ks, 1 + kt, 1 + ku, 1 + kv, 1 + kw, 1 + kx, 1 + ky, 1 + kz, 1 + la, 1 + lb, 1 + lc, 1 + ld, 1 + le, 1 + lf, 1 + lg, 1 + lh, 1 + li, 1 + lj, 1 + lk, 1 + ll, 1 + lm, 1 + ln, 1 + lo, 1 + lp, 1 + lq, 1 + lr, 1 + ls, 1 + lt, 1 + lu, 1 + lv, 1 + lw, 1 + lx, 1 + ly, 1 + lz, 1 + ma, 1 + mb, 1 + mc, 1 + md, 1 + me, 1 + mf, 1 + mg, 1 + mh, 1 + mi, 1 + mj, 1 + mk, 1 + ml, 1 + mm, 1 + mn, 1 + mo, 1 + mp, 1 + mq, 1 + mr, 1 + ms, 1 + mt, 1 + mu, 1 + mv, 1 + mw, 1 + mx, 1 + my, 1 + mz, 1 + na, 1 + nb, 1 + nc, 1 + nd, 1 + ne, 1 + nf, 1 + ng, 1 + nh, 1 + ni, 1 + nj, 1 + nk, 1 + nl, 1 + nm, 1 + nn, 1 + no, 1 + np, 1 + nq, 1 + nr, 1 + ns, 1 + nt, 1 + nu, 1 + nv, 1 + nw, 1 + nx, 1 + ny, 1 + nz, 1 + oa, 1 + ob, 1 + oc, 1 + od, 1 + oe, 1 + of, 1 + og, 1 + oh, 1 + oi, 1 + oj, 1 + ok, 1 + ol, 1 + om, 1 + on, 1 + oo, 1 + op, 1 + oq, 1 + or, 1 + os, 1 + ot, 1 + ou, 1 + ov, 1 + ow, 1 + ox, 1 + oy, 1 + oz, 1 + pa, 1 + pb, 1 + pc, 1 + pd, 1 + pe, 1 + pf, 1 + pg, 1 + ph, 1 + pi, 1 + pj, 1 + pk, 1 + pl, 1 + pm, 1 + pn, 1 + po, 1 + pp, 1 + pq, 1 + pr, 1 + ps, 1 + pt, 1 + pu, 1 + pv, 1 + pw, 1 + px, 1 + py, 1 + pz, 1 + qa, 1 + qb, 1 + qc, 1 + qd, 1 + qe, 1 + qf, 1 + qg, 1 + qh, 1 + qi, 1 + qj, 1 + qk, 1 + ql, 1 + qm, 1 + qn, 1 + qo, 1 + qp, 1 + qq, 1 + qr, 1 + qs, 1 + qt, 1 + qu, 1 + qv, 1 + qw, 1 + qx, 1 + qy, 1 + qz, 1 + ra, 1 + rb, 1 + rc, 1 + rd, 1 + re, 1 + rf, 1 + rg, 1 + rh, 1 + ri, 1 + rj, 1 + rk, 1 + rl, 1 + rm, 1 + rn, 1 + ro, 1 + rp, 1 + rq, 1 + rr, 1 + rs, 1 + rt, 1 + ru, 1 + rv, 1 + rw, 1 + rx, 1 + ry, 1 + rz, 1 + sa, 1 + sb, 1 + sc, 1 + sd, 1 + se, 1 + sf, 1 + sg, 1 + sh, 1 + si, 1 + sj, 1 + sk, 1 + sl, 1 + sm, 1 + sn, 1 + so, 1 + sp, 1 + sq, 1 + sr, 1 + ss, 1 + st, 1 + su, 1 + sv, 1 + sw, 1 + sx, 1 + sy, 1 + sz, 1 + ta, 1 + tb, 1 + tc, 1 + td, 1 + te, 1 + tf, 1 + tg, 1 + th, 1 + ti, 1 + tj,
4 + a, 4 + b, 4 + c, 4 + d, 4 + e, 4 + f, 4 + g, 4 + h, 4 + i, 4 + j, 4 + k, 4 + l, 4 + m, 4 + n, 4 + o, 4 + p, 4 + q, 4 + r, 4 + s, 4 + t, 4 + u, 4 + v, 4 + w, 4 + x, 4 + y, 4 + z, 4 + aa, 4 + ab, 4 + ac, 4 + ad, 4 + ae, 4 + af, 4 + ag, 4 + ah, 4 + ai, 4 + aj, 4 + ak, 4 + al, 4 + am, 4 + an, 4 + ao, 4 + ap, 4 + aq, 4 + ar, 4 + as, 4 + at, 4 + au, 4 + av, 4 + aw, 4 + ax, 4 + ay, 4 + az, 4 + ba, 4 + bb, 4 + bc, 4 + bd, 4 + be, 4 + bf, 4 + bg, 4 + bh, 4 + bi, 4 + bj, 4 + bk, 4 + bl, 4 + bm, 4 + bn, 4 + bo, 4 + bp, 4 + bq, 4 + br, 4 + bs, 4 + bt, 4 + bu, 4 + bv, 4 + bw, 4 + bx, 4 + by, 4 + bz, 4 + ca, 4 + cb, 4 + cc, 4 + cd, 4 + ce, 4 + cf, 4 + cg, 4 + ch, 4 + ci, 4 + cj, 4 + ck, 4 + cl, 4 + cm, 4 + cn, 4 + co, 4 + cp, 4 + cq, 4 + cr, 4 + cs, 4 + ct, 4 + cu, 4 + cv, 4 + cw, 4 + cx, 4 + cy, 4 + cz, 4 + da, 4 + db, 4 + dc, 4 + dd, 4 + de, 4 + df, 4 + dg, 4 + dh, 4 + di, 4 + dj, 4 + dk, 4 + dl, 4 + dm, 4 + dn, 4 + do, 4 + dp, 4 + dq, 4 + dr, 4 + ds, 4 + dt, 4 + du, 4 + dv, 4 + dw, 4 + dx, 4 + dy, 4 + dz, 4 + ea, 4 + eb, 4 + ec, 4 + ed, 4 + ee, 4 + ef, 4 + eg, 4 + eh, 4 + ei, 4 + ej, 4 + ek, 4 + el, 4 + em, 4 + en, 4 + eo, 4 + ep, 4 + eq, 4 + er, 4 + es, 4 + et, 4 + eu, 4 + ev, 4 + ew, 4 + ex, 4 + ey, 4 + ez, 4 + fa, 4 + fb, 4 + fc, 4 + fd, 4 + fe, 4 + ff, 4 + fg, 4 + fh, 4 + fi, 4 + fj, 4 + fk, 4 + fl, 4 + fm, 4 + fn, 4 + fo, 4 + fp, 4 + fq, 4 + fr, 4 + fs, 4 + ft, 4 + fu, 4 + fv, 4 + fw, 4 + fx, 4 + fy, 4 + fz, 4 + ga, 4 + gb, 4 + gc, 4 + gd, 4 + ge, 4 + gf, 4 + gg, 4 + gh, 4 + gi, 4 + gj, 4 + gk, 4 + gl, 4 + gm, 4 + gn, 4 + go, 4 + gp, 4 + gq, 4 + gr, 4 + gs, 4 + gt, 4 + gu, 4 + gv, 4 + gw, 4 + gx, 4 + gy, 4 + gz, 4 + ha, 4 + hb, 4 + hc, 4 + hd, 4 + he, 4 + hf, 4 + hg, 4 + hh, 4 + hi, 4 + hj , 4 + hk, 4 + hl, 4 + hm, 4 + hn, 4 + ho, 4 + hp, 4 + hq, 4 + hr, 4 + hs, 4 + ht, 4 + hu, 4 + hv, 4 + hw, 4 + hx, 4 + hy, 4 + hz, 4 + ia, 4 + ib, 4 + ic, 4 + id, 4 + ie, 4 + if, 4 + ig, 4 + ih, 4 + ii , 4 + ij, 4 + ik, 4 + il, 4 + im, 4 + in, 4 + io, 4 + ip, 4 + iq, 4 + ir, 4 + is, 4 + it, 4 + iu, 4 + iv, 4 + iw, 4 + ix, 4 + iy, 4 + iz, 4 + ja, 4 + jb, 4 + jc, 4 + jd, 4 + je, 4 + jf, 4 + jg, 4 + jh , 4 + ji, 4 + jj, 4 + jk, 4 + jl, 4 + jm, 4 + jn, 4 + jo, 4 + jp, 4 + jq, 4 + jr, 4 + js, 4 + jt, 4 + ju, 4 + jv, 4 + jw, 4 + jx, 4 + jy, 4 + jz, 4 + ka, 4 + kb, 4 + kc, 4 + kd, 4 + ke, 4 + kf, 4 + kg , 4 + kh, 4 + ki, 4 + kj, 4 + kk, 4 + kl, 4 + km, 4 + kn, 4 + ko, 4 + kp, 4 + kq, 4 + kr, 4 + ks, 4 + kt, 4 + ku, 4 + kv, 4 + kw, 4 + kx, 4 + ky, 4 + kz, 4 + la, 4 + lb, 4 + lc, 4 + ld, 4 + le, 4 + lf , 4 + lg, 4 + lh, 4 + li, 4 + lj, 4 + lk, 4 + ll, 4 + lm, 4 + ln, 4 + lo, 4 + lp, 4 + lq, 4 + lr, 4 + ls, 4 + lt, 4 + lu, 4 + lv, 4 + lw, 4 + lx, 4 + ly, 4 + lz, 4 + ma, 4 + mb, 4 + mc, 4 + md, 4 + me , 4 + mf, 4 + mg, 4 + mh, 4 + mi, 4 + mj, 4 + mk, 4 + ml, 4 + mm, 4 + mn, 4 + mo, 4 + mp, 4 + mq, 4 + mr, 4 + ms, 4 + mt, 4 + mu, 4 + mv, 4 + mw, 4 + mx, 4 + my, 4 + mz, 4 + na, 4 + nb, 4 + nc, 4 + nd , 4 + ne, 4 + nf, 4 + ng, 4 + nh, 4 + ni, 4 + nj, 4 + nk, 4 + nl, 4 + nm, 4 + nn, 4 + no, 4 + np, 4 + nq, 4 + nr, 4 + ns, 4 + nt, 4 + nu, 4 + nv, 4 + nw, 4 + nx, 4 + ny, 4 + nz, 4 + oa, 4 + ob, 4 + oc , 4 + od, 4 + oe, 4 + of, 4 + og, 4 + oh, 4 + oi, 4 + oj, 4 + ok, 4 + ol, 4 + om, 4 + on, 4 + oo, 4 + op, 4 + oq, 4 + or, 4 + os, 4 + ot, 4 + ou, 4 + ov, 4 + ow, 4 + ox, 4 + oy, 4 + oz, 4 + pa, 4 + pb , 4 + pc, 4 + pd, 4 + pe, 4 + pf, 4 + pg, 4 + ph, 4 + pi, 4 + pj, 4 + pk, 4 + pl, 4 + pm, 4 + pn, 4 + po, 4 + pp, 4 + pq, 4 + pr, 4 + ps, 4 + pt, 4 + pu, 4 + pv, 4 + pw, 4 + px, 4 + py, 4 + pz, 4 + qa , 4 + qb, 4 + qc, 4 + qd, 4 + qe, 4 + qf, 4 + qg, 4 + qh, 4 + qi, 4 + qj, 4 + qk, 4 + ql, 4 + qm, 4 + qn, 4 + qo, 4 + qp, 4 + qq, 4 + qr, 4 + qs, 4 + qt, 4 + qu, 4 + qv, 4 + qw, 4 + qx, 4 + qy, 4 + qz , 4 + ra, 4 + rb, 4 + rc, 4 + rd, 4 + re, 4 + rf, 4 + rg, 4 + rh, 4 + ri, 4 + rj, 4 + rk, 4 + rl, 4 + rm, 4 + rn, 4 + ro, 4 + rp, 4 + rq, 4 + rr, 4 + rs, 4 + rt, 4 + ru, 4 + rv, 4 + rw, 4 + rx, 4 + ry , 4 + rz, 4 + sa, 4 + sb, 4 + sc, 4 + sd, 4 + se, 4 + sf, 4 + sg, 4 + sh, 4 + si, 4 + sj, 4 + sk, 4 + sl, 4 + sm, 4 + sn, 4 + so, 4 + sp, 4 + sq, 4 + sr, 4 + ss, 4 + st, 4 + su, 4 + sv, 4 + sw, 4 + sx , 4 + sy, 4 + sz, 4 + ta, 4 + tb, 4 + tc, 4 + td, 4 + te, 4 + tf, 4 + tg, 4 + th, 4 + ti, 4 + tj,
5 + a, 5 + b, 5 + c, 5 + d, 5 + e, 5 + f, 5 + g, 5 + h, 5 + i, 5 + j, 5 + k, 5 + l, 5 + m, 5 + n, 5 + o, 5 + p, 5 + q, 5 + r, 5 + s, 5 + t, 5 + u, 5 + v, 5 + w, 5 + x, 5 + y, 5 + z, 5 + aa, 5 + ab, 5 + ac, 5 + ad, 5 + ae, 5 + af, 5 + ag, 5 + ah, 5 + ai, 5 + aj, 5 + ak, 5 + al, 5 + am, 5 + an, 5 + ao, 5 + ap, 5 + aq, 5 + ar, 5 + as, 5 + at, 5 + au, 5 + av, 5 + aw, 5 + ax, 5 + ay, 5 + az, 5 + ba, 5 + bb, 5 + bc, 5 + bd, 5 + be, 5 + bf, 5 + bg, 5 + bh, 5 + bi, 5 + bj, 5 + bk, 5 + bl, 5 + bm, 5 + bn, 5 + bo, 5 + bp, 5 + bq, 5 + br, 5 + bs, 5 + bt, 5 + bu, 5 + bv, 5 + bw, 5 + bx, 5 + by, 5 + bz, 5 + ca, 5 + cb, 5 + cc, 5 + cd, 5 + ce, 5 + cf, 5 + cg, 5 + ch, 5 + ci, 5 + cj, 5 + ck, 5 + cl, 5 + cm, 5 + cn, 5 + co, 5 + cp, 5 + cq, 5 + cr, 5 + cs, 5 + ct, 5 + cu, 5 + cv, 5 + cw, 5 + cx, 5 + cy, 5 + cz, 5 + da, 5 + db, 5 + dc, 5 + dd, 5 + de, 5 + df, 5 + dg, 5 + dh, 5 + di, 5 + dj, 5 + dk, 5 + dl, 5 + dm, 5 + dn, 5 + do, 5 + dp, 5 + dq, 5 + dr, 5 + ds, 5 + dt, 5 + du, 5 + dv, 5 + dw, 5 + dx, 5 + dy, 5 + dz, 5 + ea, 5 + eb, 5 + ec, 5 + ed, 5 + ee, 5 + ef, 5 + eg, 5 + eh, 5 + ei, 5 + ej, 5 + ek, 5 + el, 5 + em, 5 + en, 5 + eo, 5 + ep, 5 + eq, 5 + er, 5 + es, 5 + et, 5 + eu, 5 + ev, 5 + ew, 5 + ex, 5 + ey, 5 + ez, 5 + fa, 5 + fb, 5 + fc, 5 + fd, 5 + fe, 5 + ff, 5 + fg, 5 + fh, 5 + fi, 5 + fj, 5 + fk, 5 + fl, 5 + fm, 5 + fn, 5 + fo, 5 + fp, 5 + fq, 5 + fr, 5 + fs, 5 + ft, 5 + fu, 5 + fv, 5 + fw, 5 + fx, 5 + fy, 5 + fz, 5 + ga, 5 + gb, 5 + gc, 5 + gd, 5 + ge, 5 + gf, 5 + gg, 5 + gh, 5 + gi, 5 + gj, 5 + gk, 5 + gl, 5 + gm, 5 + gn, 5 + go, 5 + gp, 5 + gq, 5 + gr, 5 + gs, 5 + gt, 5 + gu, 5 + gv, 5 + gw, 5 + gx, 5 + gy, 5 + gz, 5 + ha, 5 + hb, 5 + hc, 5 + hd, 5 + he, 5 + hf, 5 + hg, 5 + hh, 5 + hi, 5 + hj , 5 + hk, 5 + hl, 5 + hm, 5 + hn, 5 + ho, 5 + hp, 5 + hq, 5 + hr, 5 + hs, 5 + ht, 5 + hu, 5 + hv, 5 + hw, 5 + hx, 5 + hy, 5 + hz, 5 + ia, 5 + ib, 5 + ic, 5 + id, 5 + ie, 5 + if, 5 + ig, 5 + ih, 5 + ii , 5 + ij, 5 + ik, 5 + il, 5 + im, 5 + in, 5 + io, 5 + ip, 5 + iq, 5 + ir, 5 + is, 5 + it, 5 + iu, 5 + iv, 5 + iw, 5 + ix, 5 + iy, 5 + iz, 5 + ja, 5 + jb, 5 + jc, 5 + jd, 5 + je, 5 + jf, 5 + jg, 5 + jh , 5 + ji, 5 + jj, 5 + jk, 5 + jl, 5 + jm, 5 + jn, 5 + jo, 5 + jp, 5 + jq, 5 + jr, 5 + js, 5 + jt, 5 + ju, 5 + jv, 5 + jw, 5 + jx, 5 + jy, 5 + jz, 5 + ka, 5 + kb, 5 + kc, 5 + kd, 5 + ke, 5 + kf, 5 + kg , 5 + kh, 5 + ki, 5 + kj, 5 + kk, 5 + kl, 5 + km, 5 + kn, 5 + ko, 5 + kp, 5 + kq, 5 + kr, 5 + ks, 5 + kt, 5 + ku, 5 + kv, 5 + kw, 5 + kx, 5 + ky, 5 + kz, 5 + la, 5 + lb, 5 + lc, 5 + ld, 5 + le, 5 + lf , 5 + lg, 5 + lh, 5 + li, 5 + lj, 5 + lk, 5 + ll, 5 + lm, 5 + ln, 5 + lo, 5 + lp, 5 + lq, 5 + lr, 5 + ls, 5 + lt, 5 + lu, 5 + lv, 5 + lw, 5 + lx, 5 + ly, 5 + lz, 5 + ma, 5 + mb, 5 + mc, 5 + md, 5 + me , 5 + mf, 5 + mg, 5 + mh, 5 + mi, 5 + mj, 5 + mk, 5 + ml, 5 + mm, 5 + mn, 5 + mo, 5 + mp, 5 + mq, 5 + mr, 5 + ms, 5 + mt, 5 + mu, 5 + mv, 5 + mw, 5 + mx, 5 + my, 5 + mz, 5 + na, 5 + nb, 5 + nc, 5 + nd , 5 + ne, 5 + nf, 5 + ng, 5 + nh, 5 + ni, 5 + nj, 5 + nk, 5 + nl, 5 + nm, 5 + nn, 5 + no, 5 + np, 5 + nq, 5 + nr, 5 + ns, 5 + nt, 5 + nu, 5 + nv, 5 + nw, 5 + nx, 5 + ny, 5 + nz, 5 + oa, 5 + ob, 5 + oc , 5 + od, 5 + oe, 5 + of, 5 + og, 5 + oh, 5 + oi, 5 + oj, 5 + ok, 5 + ol, 5 + om, 5 + on, 5 + oo, 5 + op, 5 + oq, 5 + or, 5 + os, 5 + ot, 5 + ou, 5 + ov, 5 + ow, 5 + ox, 5 + oy, 5 + oz, 5 + pa, 5 + pb , 5 + pc, 5 + pd, 5 + pe, 5 + pf, 5 + pg, 5 + ph, 5 + pi, 5 + pj, 5 + pk, 5 + pl, 5 + pm, 5 + pn, 5 + po, 5 + pp, 5 + pq, 5 + pr, 5 + ps, 5 + pt, 5 + pu, 5 + pv, 5 + pw, 5 + px, 5 + py, 5 + pz, 5 + qa , 5 + qb, 5 + qc, 5 + qd, 5 + qe, 5 + qf, 5 + qg, 5 + qh, 5 + qi, 5 + qj, 5 + qk, 5 + ql, 5 + qm, 5 + qn, 5 + qo, 5 + qp, 5 + qq, 5 + qr, 5 + qs, 5 + qt, 5 + qu, 5 + qv, 5 + qw, 5 + qx, 5 + qy, 5 + qz , 5 + ra, 5 + rb, 5 + rc, 5 + rd, 5 + re, 5 + rf, 5 + rg, 5 + rh, 5 + ri, 5 + rj, 5 + rk, 5 + rl, 5 + rm, 5 + rn, 5 + ro, 5 + rp, 5 + rq, 5 + rr, 5 + rs, 5 + rt, 5 + ru, 5 + rv, 5 + rw, 5 + rx, 5 + ry , 5 + rz, 5 + sa, 5 + sb, 5 + sc, 5 + sd, 5 + se, 5 + sf, 5 + sg, 5 + sh, 5 + si, 5 + sj, 5 + sk, 5 + sl, 5 + sm, 5 + sn, 5 + so, 5 + sp, 5 + sq, 5 + sr, 5 + ss, 5 + st, 5 + su, 5 + sv, 5 + sw, 5 + sx , 5 + sy, 5 + sz, 5 + ta, 5 + tb, 5 + tc, 5 + td, 5 + te, 5 + tf, 5 + tg, 5 + th, 5 + ti, 5 + tj,
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One or more active compounds I and one or more active compounds II can be applied by various application methods as follows.
1. Simultaneous application, ie
a) Mixed application (ie as a mixture, eg ready-to-use formulations or as a tank mix)
b) Individual application (ie application in separate tanks), or
2. The continuous individual application, in this case the sequence, generally does not have any influence on the results of the control method.

  Thus, a method for controlling pests, mites, nematodes, molluscs, pests and bacteria applies at least one active compound I and at least one active compound II separately or together Or by spraying or dusting seeds, plants or soil with a mixture of at least one active compound I and at least one active compound II before or after sowing or before or after plant emergence. Done.

  The ratio between the active ingredients in the composition of the present invention and the method of the present invention is usually 500: 1 to 1: 100, preferably 20: one or more active compounds I and one or more active compounds II. It can be applied in a weight ratio of 1 to 1:50, in particular 5: 1 to 1:20.

  The weight ratio of the isoxazoline-substituted benzamide compound represented by formula (1) and the insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal agent in the composition and method of the present invention depends on the properties of the compound. And 100: 1 to 1: 100, preferably 20: 1 to 1:20, particularly 10: 1 to 1:10.

  The preferred treatment amount of the active ingredient compound in the composition of the present invention and the method of the present invention depends on the type of the target pest to be controlled, etc., but usually the compound represented by the formula (1) is 0.1 to 1000 gai / ha, the compound selected from the compound group A is 0.1 to 1000 gai / ha, preferably the former is 1 to 300 gai / ha and the latter is 1 to 300 gai / ha.

  The composition of the present invention is a so-called agricultural pest that harms agricultural and horticultural crops and trees, agricultural diseases, so-called livestock pests parasitic on livestock poultry, so-called sanitary pests that adversely affect the human living environment such as houses, and the like It can be applied to mites, nematodes, and molluscs that occur and harm the scene. Specific examples of pests, mites, nematodes, molluscs, and diseases that can be controlled using the composition of the present invention include the following, but are not limited thereto.

The pests include the chestnut bees Chestnut gall wasp (Dryocosmus kuriphilus), the Argentine ant Argentine ant (Linepithema humile), the Gantai ant Army ant (Eciton burchelli, E. schmitti), the black carp ant Japanese carpenter ant (Camponotus japonicus), or oh ihime , Bulldog ant (Myrmecia spp.), Fire Ant (Solenopsis spp.), Asian giant hornet (Vespa mandarina), Japanese yellow hornet (Vespa simillima), Large roseana fly (Arge pag) ), Pine bee European pine sawfly (Neodiprion sertifer), chestnut bee Chestnut sawfly (Apethymus kuri), sedge bee Cabbage sawfly (Athalia infumata), bee turnip Turnip sawfly (Athalia rosae), etc.
Pear leaf miner (Bucculatrix pyrivorella), tea leaf roller (Caloptilia theivora), golden leaf soy Apple leafminer (Phyllonorycter ringoniella), citrus leafminer (Phyllocnistis citrella), immobilized leaflet Persimmon fruit moth (Stathmopoda masinissa), Peach fruit moth (Carposina sasakii), Allium leafminer (Acrolepiopsis sapporensis), Yami leafminer (Acrolepiopsis suzukiella), Peach fruit moth (Pel fruit) ), Diamondback moth (Plutella xylostella), red stem borer (Chilo suppressalis), Shibatatsuga Bluegrass webworm (Parapediasia teterrella) Cabbage webworm (Hellula undalis), Rice leaf roller (Cnaphalocrocis medinalis), Yellow moth moth (Conogethes punctiferalis), Cotton moth (Diaphania indica), Mulberry pyras (Mulberry pyras) Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), Azuki bean borer (Ostrinia scapulalis), Sorghum moth Lesser corn stalk borer (Elasmopalpus lignosellus), ella borer L Tree borer Peach tree borer (Synanthedon exitiosa), Cosca Shiba Cherry tree borer (Synanthedon hector), Kubiakasukashiba (Toleria romanovi), Iraga Oriental moth (Monema flavescens), Aura Iga (Parasa consocia), Hiloheira Oiraga (Parasa) lepida), Parasa siniea, Parana siniea, Artona martini, Illiberis pruni, Illiberis rotundata, Carpenter moth (Cossus insularis), Codlingmon lum, Cydia Fruit moth (Grapholita dimorpha), Oriental fruit moth (Grapholita molesta), Bean pod borer (Leguminivora glycinivorella), Bean podworm (Matsumuraeses phaseoli), Grapeberry moss (Grape berryite moth) Smaller tea tortrix (Adoxophyes honmai), Apple coconut oyster Summer fruit tortrix (Adoxophyes orana fasciata), Apple peach oyster Asiatic leafroller (Archips breviplicanus), Midareka kumamaki Apple tortrix (Archips fuscocupreanus) Oriental tea tortrix (Homona magnanima), Tobihamaki Dark fruit-tree tortrix (Pandemis heparana), Matsukareha Pine moth (Dendrolimus spectabilis), Tsukakareha Jananese hemlock caterpillar (Dendrolimus superans), Takekareha, Japanese bamboo thrix ha Euthrix potatoria, Oriental lappet (Gastropacha orientalis), Kunugia undans, Kunugia yamadai, Tomato hornworm (Manduca quinquemaculata), Tobacco hornworm (Alliga moth) cunea), Mulberry tiger moth (Lemyra imparilis), white flies (Eilema fuscodorsalis), black buckwheat (Eilema laevis), white moths udoconspersa), Swan moth (Sphrageidus similis), Gypsy moth (Lymantria dispar), White-spotted tussock moth (Orgyia thyellina), Rice green caterpillar (Naranga aenescens), Naranga aenescens leaf worm (Aedia leucomelas), mushroom Cabbage armyworm (Mamestra brassicae), Ayayoto Oriental armyworm (Pseudaletia separata), Japanese swordfish Lawn grass cutworm (Spodoptera depravata), Southern army worm Southern armyworm (ex armed worm) Fall army worm Fall armyworm (Spodoptera frugiperda), cotton leaf worm Cotton leafworm (Spodoptera littoralis), common cutworm (Spodoptera litura), giant bollworm (Helicoverpa armigera), tobacco moth Orienta l tobacco budworm (Helicoverpa assulta), tobacco bad worm Tobacco budworm (Heliothis virescens), American tobacco moth Corn earworm (Helicoverpa zea), Japanese red moth Black cutworm (Agrotis ipsilon), Kaburaya moth Turnip moth (Agrotis segetum) ), Honey beetle Threespotted plusia (Ctenoplusia agnata), soy bean looper, soybean looper (Pseudoplusia includens), nettle cabbage cabbage looper (Trichoplusia ni), mugwort Japanese giant looper (Ascotis selenaria), brass white white butterfly Lis , Lepidoptera (Lepidoptera) such as Cabbage white butterfly (Pieris rapae crucivora), Ichimongiseri Straight swift (Parnara guttata), cotton leaf worm cotton leafworm (Alabama argillacea), sugarcane borer (Diatraea sacharalis) Insect,
The fruit fly Melon fly (Bactrocera cucurbitae), the fruit fly Oriental fruit fly (Bactrocera dorsalis), the Queensland fruit fly Queensland fruit fly (Bactrocera tryoni), the fruit fly Japanese orange fly (Bactrocera tsuneonis), the Mediterranean fruit fly Mediterraneitis fly (Anastrepha ludens), ring-fly fly Apple maggot (Rhagoletis pomonella), rice leaf fly Rice leaf miner (Agromyza oryzae), leaf flyer Pea leaf miner (Chromatomyia horticola), oil leaf fly Cabbage leafminer (Liriomyza brassicae) ), Green leaf fly Stone leek leafminer (Liriomyza chinensis), green leaf fly Pea leafminer (Liriomyza huidobrensis), tomato leaf fly Tomato leafminer (Liriomyza sativae), bean leaf fly Serpentine leafminer (Liriom yza trifolii), Japanese fruit fly (Drosophila suzukii), Small leaf rice leaf miner (Hydrellia griseola), Tsetse fly (Glossina morsitans, G. palpalis), White fly, Forest fly (Hippobca) Melophagus ovinus), Onion fly (Delia antiqua), Seed corn maggot (Delia platura), sugar beet fly, Beet leaf miner (Pegomya cunicularia), Lesser house fly (Fannia canicularis), Sheep head fly (Hritae flyfly) ), Sweet fly (Morellia simplex), Face fly (Musca autumnalis), Housefly (Musca domestica), Australian bush fly (Musca vetustissima), Horn flies Horn fly (Haematobia irritans), Stable fly (Stable fly) Stomoxys calci trans, Calliphora lata, Bottle fly (Calliphora vicina), Old world screw-worm fly (Chrysomya bezziana), Blow fly (Chrysomya chloropyga), Oriental latrine fly (Chrysomya, Chrysomya America) New World screw-worm fly (Cochliomyia hominivorax), Black blow fly (Phormia regina), Northern blowfly (Protophormia terraenovae), sheep fly, Australian sheep blowfly (Lucilia cuprina), Green bottle fly (Lucilia illustris) Common green bottle fly (Lucilia sericata), Bot flies (Cuterebra spp.), Human fly botfly (Dermatobia hominis), Horse-nosed bot fly (Gasterophilus haemorrhoidalis), Horse-fly Horis bottest t fly (Gasterophilus nasalis), Bullflies Warble fly (Hypoderma bovis), Common cattle grub (Hypoderma lineatum), Sheep nasal bot fly (Oestrus ovis), Fresh fly Flesh fly (Sarcophaga carnaria), perch Srina ), Splayed deerfly (Chrysops caecutiens), Mekurabu Deer fly (Chrysops suavis), Common horse fly (Haematopota pluvialis), Greenhead horsefly (Greenhead horse fly (Tabanus nigrovittatus)) ), Soybean pod gall midge (Asphondylia yushimai), Hessian fly Hessian fly (Mayetiola destructor), mud wings Orange wheat blossom midge (Sitodiplosis mosellana), chick nuka Biting midge (Culicoides arakawae), L nipponens is), Black-tailed Blackfish (Prosimulium yezoensis), Black fly (Simulium ochraceum), African Malaria mosquito (Anopheles gambiae), Red-backed Shrimp (Anopheles hyrcanus sinesis), Anophelestosi aegypti), Asian tiger mosquito (Aedes albopictus), Chikaeka House mosquito (Culex pipiens molestus), Akaieka House mosquito (Culex pipiens pallens), Culex tritaeniorhynchus, moth P Diptera insects such as Telmatoscopus albipunctatus)
Chicken flea Hen flea (Ceratophyllus gallinae), Japanese flea Chigoe flea (Tunga penetrans), Dog flea Dog flea (Ctenocephalides canis), Cat flea Cat flea (Ctenocephalides felis), Chicken flea Sticktight flea (Echidnopha human ritual) , Siphonaptera insects such as Oriental rat flea (Xenopsylla cheopis),
Tobacco beetle (Lasioderma serricorne), Common bean weevil (Acanthoscelides obtectus), Adzuki bean beetle (Callosobruchus chinensis), Grape borer (Xylotrechus pyrrhoder beetle beetle) White-spotted longicorn beetle (Anoplophora malasiaca), Japanese pine sawyer (Monochamus alternatus), Yellow-spotted longicorn beetle (Psacothea hilaris), Colorado potato beetle Colorado beetle beetle (Phaedon cochleariae), rice leaf beetle Rice leaf beetle (Oulema oryzae), spotted leaf beetle (Demotina fasciculata), leaf beetle Cucurbit leaf beetle (Aulacophora femoralis) Beet flea beetle (Chaetocnema concinna), Northern corn rootworm (Diabrotica barberi), Southern corn rootworm (Diabrotica undecimpunctata), Western corn rootworm Western corn rootworm (Diabrotica virgifera), Triped P flea beetle striolata), Solanum flea beetle (Psylliodes angusticollis), green beetle Mexican been beetle (Epilachna varivestis), large twenty-eight-spotted ladybird (Epilachna vigintioctomawata bird), (Epilachna vigintioctopunctata), Epuraea domina, Pollen beetle (Meligethes aeneus), Peach curculio (Rhynchites heros), Sweetpotato weevil (Cylas formicarius), potato weevil West Indian sweet potato weevil (Euscepes postfasciatus), cotton weevil Boll weevil (Anthonomus grandis), white-flying beetle White-fringed beetle (Graphognatus leucoloma), horned weevil weevil Octopus weevil Alfalfa weevil (Hypera postica), Granary weevil (Sitophilus granarius), Chinese weevil Maize weevil (Sitophilus zeamais), Shibao weevil Hunting billbug (Sphenophorus venatus vestitus), Ezo weevil weevil (Lissohoptrus oryzophilus), yellow mealworm (Tenebrio molitor), red flour beetle (Tribolium castaneum), sweet potato wireworm (Melanotus fortnumi), citrus fruit Tsuruga Sugarcane wireworm (Melanotus tamsuyensis), Coreus crested citrus flower chafer (Gametis jucunda), Nagachakogane, Yellowish elongate chafer (Heptophylla picea), Douganebuibu Cupreous chafer (Anomala cuprea), Japanese beetle ), Coleoptera insects such as Rove beetle (Paederus fuscipes),
Asian citrus psyllid (Diaphorina citri), pear sucker Pear sucker (Psylla pyrisuga), Chatel spiny whitefly (Aleurocanthus camelliae), orange spiny whitefly (Aleurocanthus spiniferus), white leaffly (Aleurocanthus spiniferus) Whitefly Sweetpotato whitefly (Bemisia tabaci), Citrus whitefly (Dialeurodes citri), Greenhouse whitefly (Trialeurodes vaporariorum), Pea aphid (Acyrthosiphon pisum), Bean accura bee crab aphid (Aphis fabae), Soybean Aphid (Aphis glycines), Cotton Aphid (Aphis gossypii), Apple Aphid (Aphis pomi), Spiraea aphid (Aphis pomi) Aphis spiraecola), Foxglove aphid (Aulacorthum solani), Leaf curl plum aphid (Brachycaudus helichrysi), Japanese aphid Cabbage aphid (Brevicoryne brassiae), Walnut aphid Wola Russian wheat aphid (Diuraphis noxia), plantain beetle Rosy apple aphid (Dysaphis plantaginea), peach beetle Mealy plum aphid (Hyalopterus pruni), black pea aphid Turnip aphid (Lipaphis erysimi), tulip beetle aphid Margin door aphid (Monellia caryella), peach aphid Green peach aphid (Myzus persicae), Lettuce aphid (Nasonovia ribisnigri), Nephia Onion aphid (N eotoxoptera formosana), wheat cherry-oat aphid (Rhopalosiphum padi), rice aphid Rice root aphid (Rhopalosiphum rufiabdominalis), wheat leaf aphid (Sitobion akebiae), English grain aito avenae), Greenbug (Schizaphis graminum), Black citrus aphid (Toxoptera aurantii), Brown citrus aphid (Toxoptera citricida), Apple weevil Wooly apple aphid (Eriosoma lanigerum), Grape aphid Viteus vitifolii), hornet beetle Indian wax scale (Ceroplastes ceriferus), ruby weevil Red wax scale (Ceroplastes rubens), citrus scale insect (Coccus pseudomagnoliarum), red beetle California red scale (Aonidiella aurantii), pear Scale scale San jose scale (Comstockaspis perniciosa), scale scale tea scale (Teori scale), scale scale scale Peony scale (Pseudaonidia paeoniae), scale beetle scale Mulberry scale (Pseudaulacaspis pentagona), white scale scale Pula scale pi Citrus snow scale (Unaspis citri), Euonymus scale (Unaspis euonymi), Agarhead scale (Unaspis yanonensis), Giant margarodid scale (Drosicha corottenta scale) purchasi), worm beetle Cotton mealy bug (Phenacoccus solani), citrus mealybug (Citrus mealybug (Planococcus citri)), Japanese mealybug (Planococcus kuraunhiae), stag beetle Comstock me alybug (Pseudococcus comstocki), grape mealybug (Pseudococcus maritimus), brown brown planthopper (Laodelphax striatella), brown rice planthopper (Nilaparvata lugens), white-backedella planta (Gifer) Leafhopper (Epiacanthus stramineus), Indian cotton leafhopper (Amrasca devastans), Greens leafhopper (Bardsley leafhopper (Balclutha saltuella)), Aster leafhopper (Macrosteles fascifrons), Green leafy leafhopper (Macrosteles striifrons) leafhopper (Nephotettix cincticeps), Grape Leafhopper (Arboridia apicalis), Potato Leafhopper (Empoasca fabae), Emporasca nipponica, Chanomi Green leafhopper (Empoasca onukii), Bean's smaller green leafhopper (Empoasca sakaii), Sleek bug (Dolycoris baccarum), Sea turtle Cabbage bug (Eurydema rugosa), Spined whitespot ), White-spotted stink bug (Eysarcoris lewisi), white-spotted stink bug (Eysarcoris ventralis), blue-headed stink bug Sheild bug (Glaucias subpunctatus), brown marmorink stink bug (Halyomorpha haly) Nezara antennata), Southern green stink bug (Nezara viridula), Redbanded stink bug (Piezodorus guildinii), Redbanded shield bug (Piezodorus hybneri), Brown-winged crossota (Brown-winged cross bug) Japanese black rice bug (Scotinophora lurida), Bean bug (Riptortus clavatus), Spider helicopter Rice bug (Leptocorisa chinensis), Japanese stink bug Rice stink bug (Cletus punctiger), Southern bug shrimp bug (Paradasynus spinosus), Red-backed Helicopod Bug Rhopalid bug (Rhopalus maculatus), American Red-footed Beetle True chinch bug (Blissus leucopterus), Japanese Red-headed Bug, Oriental chinch bug (Cavelerius saccharivorus) Red cotton bug (Dysdercus cingulatus), Venezuelan sand turtle Blood-sucking bug (Rhodnius prolixus), Mexican sand turtle Kissing bug (Triatoma dimidiata), Brazilian sand turtle Kissing bug (Triatoma infestans), green stink bug sternumhil Aster ), Blown Stink bag brown stink bug (Euschistus servus), Southern green stink bag (Nezara viridula), Tarnished plant bug (Lygus lineolaris), Stink bag (Dichelops furcatus), Sugar canspitle bag sugarcane spittlebug (Mahanarva fimbriolata), azalea lace bug (Stephanitis pyrioides), bed bug Bed bug (Cimex lectularius), bluefin turtle Pale greenplant bug (Apolygus spinolae), western tarnished plant bug (Lygus hesperus) Tarnished plant bug (Lygus lineolaris), Nagamushikasikameka Rice stink bug (Stenodema sibiricum), Akasujikasikameka Sorghum plant bug (Stenotus rubrovittatus), Rice fossil turtle Rice leaf bug (Trigonotylus caelestlium) Hemiptera insects such as and fleahopper (Halticus insularis), Cotton fleahopper (Pseudatomoscelis seriatus), Flower thrips (Frankliniella intonsa), Green lizard Yellow tea thrips (Scirtothrips dorsalis), Southern thrips Melon thrips (Thrips palmi), Black thrips Onion thrips (Thrips tabaci), Japanese gall-forming thrips (optonicthrips) ,
Chick shaft louse (Menopon hallid) (Cuclotogaster heterographa), brown fin louse (Goniodes dissmilis), bluefin louse Fluff louse (Goniodes gallinae), large bald larvae Large hen louse (Goniodes gigas), chicken swallow louse (Duru) ), Cat louse Cat louse (Felicola subrostrata), dog lice Dog biting louse (Trichodectes canis), cattle lice Short-nosed cattle louse (Haematopinus eurysternus), cattle lice Tail switch louse (Haematopinus quadripertusus), pig louse L inus suis), buffalo louse (Haematopinus tuberculatus), dog lice Dog sucking louse (Linognathus setosus), bovine white lice Long-nosed cattle louse (Linognathus cattle louse (Haemodipsus ventricosus ), Human louse Head louse (Pediculus humanus), mouse louse Mouse louse (Polyplax serratus), pheasant Crab louse (Pthirus pubis), etc.
Desert locust (Schistocerca gregaria), Australian platypus locust Australian plague locust (Chortoicetes terminifera), locust grasshopper Migratory locust (Locusta migratoria), red-eye locust Lesser paddy grasshopper (Oxya japonica), red-eye grass oxen (Teleogryllus emma), Kela Oriental mole cricket (Gryllotalpa orientalis), etc., Orthoptera insects,
German cockroach (Blattella germanica), American cockroach (Periplaneta americana), Black cockroach Smoky-brown cockroach (Periplaneta jafonica), Japanese cockroach (Periplaneta japonica), Daikokuus tomato (America) Termite Western dry-wood termite (Incisitermes minor), Common termite Formosan subterranean termite (Coptotermes formosanus), Japanese termite Japanese subterranean termite (Reticulitermes speratus), Thai termite Black-winged subterranean termite (Odontotermes formosanus) ,
Rootfeeding springtail (Onychiurus folsomi), Siberian white beetle (Onychiurus sibiricus), Garb spring spring (Bourletiella hortensis), etc.
Isopoda crustaceans such as Pill bug (Armadillidium vulgare), common rough woodlouse (Porcellio scaber),
Butterflyfish (Arguloida) crustaceans such as butterfly (Argulus coregoni), butterfly Japanese fishlouse (Argulus japonicus), sea butterfly (Argulus scutiformis)
Sea louse (Caligus curtus, C. elongatus), Salmon rose Salmon louse (Lepeophtheirus salmonis) and other crustaceans (Siphonostomatoida) crustaceans,
Sayaashi mite Storage mite (Glycyphagus destructor), house ticks mite (Glycyphagus domesticus), wheat mite Brown-legged grain mite (Aleuroglyphus ovatus), black mite Cheese mite (Tyrophagus putrescentiae), spiny mite Tyrophas , Hyugata mite Feather mite (Pterolichus obtusus), chick mite Feather mite (Megninia cubitalis), white house mite American house dust mite (Dermatophagoides farinae), yellow leopard mite bovis), Dog ear mite (Otodectes cynotis), Cattle cypress mite Psoroptic mite (Psoroptes communis), Rabbit ear mite Rabbit ear mite (Psoroptes cuniculi), Sheep cucumber Nhizendani Sheep scab mite (Psoroptes ovis), SENKOU mites Itch mite (Sarcoptes scabiei), cat foraminous mites Cat mange mite (Notoedres cati) mites suborder such as (Astigmata) mites,
Orabatida mites, such as the house salad ni (Haplochthonius simplex)
Sperm tick (Chelacaropsis moorei), cat tick (Cheyletiella blakei), rabbit tick Rabbit fur mite (Cheyletiella parasitovorax), crested tick (Cheyletiella yasguri), crested tick (Cheyletus eruditus), tick mite (Cheyletus eruditus) ), Caterpillar mites Cat follicle mite (Demodex cati), Acne mites Face mite (Demodex folliculorum), Tulip rust mites Wheat curl mite (Aceria tulipae), Black rust mites Pear rust mite (Eriophyes chibaensis), Peach bud insi ), Pearleaf blister mite (Eriophyes pyri), tea rust mite Tea rust mite (Acaphylla theavagrans), tomato rust mite Tomato russet mite (Aculops lycopersici), citrus mite Pink citrus rust mite (Aculops pelekassi) e rust mite (Aculus schlechtendali), Citrus rust mite Citrus rust mite (Phyllocoptruta oleivora), mite broad mite (Polyphagotarsonemus latus), cyclamen mite Cyclamen mite (Phytonemus pallidus), chuone mus mite Mite spider mite Citrus red mite (Panonychus citri), Mite spider mite Spider mite (Panonychus mori), Apple spider mite European red mite (Panonychus ulmi), Kanzawa spider mite Kanzawa spider mite (Tetranychus kanzawai), Nami spider mite Two mite Two-spot mite erythrocephalus), wheat mite Winter grain mite (Penthaleus major), Etsurombicula wichmanni, Miyagata pine tsutsumugi Trombiculid mite (Helenicula miyagawai), red tsutsugamushi (Leptotrombidium akamushi), yellow tsutsugamushi Prostigmata mites, such as Leptotrombidium pallida, Tsutsutsugamushi mite (Leptotrombidium scutellare),
English fowl tick (Argas persicus), tick soft tick (Ornithodoros moubata), relapsing fever tick (Ornithodoros turicata), spinose ear tick (Otobius megnini), Lone star tick (Lone star tick) Amblyomma americanum, Gulf coast tick (Amblyomma maculatum), Tick tick (Haemaphysalis campanulata), Tick tick (Haemaphysalis flava), Bite tick (Haemaphysalis longicornis), Mega physic tick (Haemaphysalis longicornis) aegyptium), Mediterranean tick (Hyalomma marginatum), Tropical cattle tick (Boophilus microplus), Ixodes nipponensis, Yamato tick (Ixodes ovatus), Western black-legge d tick (Ixodes pacifcus), Schulze tick Taiga tick (Ixodes persulcatus), Sheep tick Castor bean tick (Ixodes ricinus), Black-legged tick (Ixodes scapularis), Tropical horse tick (Anocentor nitens), Rocky Mountains Rocky Mountain wood tick (Dermacentor andersoni), Pacific Coast tick (Dermacentor occidentalis), Amikemeka tick Ornate cow tick (Dermacentor reticulatus), American dog tick American dog tick (Dermacentor variabilis), Ripicentor spp. Tick American cattle tick (Rhipicephalus annulatus), Brown dog tick (Rhipicephalus sanguineus) and other ticks (Metastigmata) ticks,
Red mite (Dermanyssus gallinae), house dust mite Tropical rat mite (Ornithonyssus bacoti), northern fowl mite (Ornithonyssus sylviarum), honey bee mite Honeybee mite (Varroa destructor), honeybee mite Varroa mite Varroa mite (Mesostigmata) mites,
Pancreas (Architaenioglossa) gastropod, such as Apple snail (Pomacea canaliculata)
Giant African snail (Achatina fulica), terrestrial slug (Limax marginatus), slug slug (Meghimatium bilineatum), Korean round snail (Acusta despecta sieboldiana), Miss maimai Land snio (Euhadra mai) Eyes (Stylommatophora) gastropods,
Giant kidney worm (Dioctophyma renale), ringed capillary worm Thread worms (Capillaria annulata), torsion capillary nematode Cropworm (Capillaria contorta), liver capillary nematode Capillary liver worm (Capillaria hepatica), penetrating capillary nematode (Capillaria) perforans), Philippine Capillaria philippinensis, Capillaria suis, Caterpillar Whipworm (Trichuris discolor), Whipworm Whipworm (Trichuris ovis), Pig whipworm Pig Whipworm (Trichuris suis), human Enoplida nematodes such as the whipworm Human whipworm (Trichuris trichiura), dog whipworm Dog whipworm (Trichuris vulpis), Trichinella pork worm (Trichinella spiralis),
桿 such as Nipple faecal nematode Intestinal threadworm (Strongyloides papillosus), cat fecal nematode (Strongyloides planiceps), pig fecal nematode Pig threadworm (Strongyloides ransomi), human fecal nematode Threadworm (Strongyloides stercoralis), Micronema spp. Rhabditida nematode,
Brazilian Hookworm (Ancylostoma braziliense), Dog Hookworm Dog hookworm (Ancylostoma caninum), Zubini Hookworm Old World hookworm (Ancylostoma duodenale), Cat Hookworm Cat hookworm (Ancylostoma tubaeforme), Narrowhead Hookworm The Northern hookworm of dogs (Uncinaria stenocephala) Caterpillar Cattle hookworm (Bunostomum phlebotomum), Sheep worm, Small ruminant hookworm (Bunostomum trigonocephalum), American worm New World hookworm (Necator americanus), Cyathostomum spp., Cylicocyclus spyl. spp.), Cylicostephanus spp., Donkeys (Strongylus asini), edentulous (Strongylus edentatus), Horse worms Blood worm (Strongylus equinus), Common worms Blood worm (Strongylus vulgaris) Large-mouthed bowel worm (Chabertia ovina), Indian nodular worm (Oesophagostomum brevic) audatum), Colombian nodule worm (Oesophagostomum columbianum), Nodule worm (Oesophagostomum dentatum), Nodular worm (Oesophagostomum georgianum), Nodular worm (Oesophagostomum columbianum) Nodular worm (Oesophagostomum quadrispinulatum), cattle intestinal nodular worm (Oesophagostomum radiatum), goat intestinal nodular worm (Oesophagostomum venulosum), scrijabin worm (Syngamus skrjabinomorpha), chicken worm moth trachea (Syngamus skrjabinomorpha) Swine kidney worm (Stephanurus dentatus), Couperia cattle bankrupt worm (Cooperia oncophora), red stomach worm (Hyostrongylus rubidus), stomach hair worm (Trichostrongylus axei), serpentine ciliate nematode (Trichostrongylus colubriformis), Oriental ciliate nematode Oriental trichostrongylus (Trichostrongylus orientalis), torsion stomachworm Red stomach worm (Haemonchus co ntortus), cattle stomach worm (Mecistocirrus digitatus), Ostertag stomach worm (Ostertagia ostertagi), filamentous lungworm Common lungworm (Dictyocaulus filaria), bovine lungworm Bovine lungworm (Dictyocaulus viviparus) Insect worms (Nematodirus filicollis), Swine lungworm (Metastrongylus elongatus), Lungworm (Filaroides hirthi), Lungworm (Crenosoma aerophila), Fox lungworm (Crenosoma vulpis) Strong lungida nematodes such as Rat lung worm (Angiostrongylus cantonensis), Schistosoma nematode French heartworm (Angiostrongylus vasorum), Protostrongylus spp.
Rice white nematode (Aphelenchoides besseyi), Pine wood nematode (Bursaphelenchus xylophilus) nematode (Aphelenchida) nematode,
Potato cyst nematode (Globodera rostochiensis), wheat cyst nematode Cereal cyst nematode (Heterodera avenae), soybean cyst nematode (Seterbean cyst nematode (Heterodera glycines)), arenaria root nematode (Peterut root-Menot nematode) -knot nematode (Meloidogyne hapla), Southern root-knot nematode (Meloidogyne incognita), Java root-knot nematode (Meloidogyne javanica), Southern root-kion nematode Coffee root-lesion nematode (Pratylus nechade) Root-lesion nematode (Pratylenchus loosi), Cobb's root-lesion nematode (Pratylenchus penetrans), Crested nematode Walnut root-lesion nematode (Pratylenchus vulnus), etc. lenchida) nematode,
Oxyurida nematodes such as human worm Pinworm (Enterobius vermicularis), horse worm Equine pinworm (Oxyuris equi), rabbit worm Rabbit pinworm (Passalurus ambiguus),
Pig roundworm (Ascaris suum), Horse roundworm Horse roundworm (Parascaris equorum), Dog roundworm Dog roundworm (Toxascaris leonina), Dog roundworm Dog intestinal roundworm (Toxocara canis), Cat roundworm Feline roundworm (Toxocara cati), Cattle roundworm Large cattle roundworm (Toxocara vitulorum), Anisakis spp., Pseudoterranova spp., chicken caecal caecal worm (Heterakis gallinarum), chicken roundworm (Ascaridia galli) and other roundworms (Ascaridida) Nematode,
Medinaworm Guinea worm (Dracunculus medinensis), Dolores jaw-and-mouth beetle (Gnathostoma doloresi), Ganthostoma hispidum, Japanese jaw-and-mouth beetle (Gnathostoma nipponicum), Reddish-coloured worm (Gnathostoma spinigerum) Dog stomach worm (Physaloptera canis), cat stomach worm (Physaloptera felidis, P. praeputialis), lala gastroworm Feline / canine stomach worm (Physaloptera rara), oriental eyeworm Eye worm (Thelazia callipaeda), Bovine eyeworm (Thelazia rhodesi), Large mouth stomach worm (Draschia megastoma), Equine stomach worm (Habronema microstoma), Stomach worm (Habronema muscae), Beautiful esophagus Gullet worm ( Gongylonema pulchrum), Thick stomach worm (Ascarops strongylina), Parafilaria (Parafilaria bovicola), Parafilaria multipapillosa, Stephanofilaria okinawaensis), Bancroft filaria (Wuchereria bancrofti), Malay filamentous worm (Brugia malayi), Neck threadworm (Onchocerca cervicalis), Gibson filamentous worm (Onchocerca gibsoni), Cattle filarial worm (Onchocercer gautum) ), Convolvulus (Onchocerca volvulus), finger filamentous worm Bovine filarial worm (Setaria digitata), equine filamentous peritoneal worm (Setaria equina), papillary larva (Setaria labiatopapillosa), marshall filariae (Setaria marshalli), dog Spirurida nematodes, such as the dog heartworm (Dirofilaria immitis) and the African eye worm (Loa loa),
Bald worms such as Moniliformis moniliformis, Giant thorny-headed worm (Macracanthorhynchus hirudinaceus),
Artificial leaves such as Fish tapeworm (Diphyllobothrium latum), Diphyllobothrium nihonkaiense, Manson tapeworm (Spirometra erinaceieuropaei), Diplogonoporus grandis Eye (Pseudophyllidea) tapeworm,
Wire worms (Mesocestoides lineatus), striped worms Chicken tapeworm (Raillietina cesticillus), spiny cleft worm Fowl tapeworm (Raillietina echinobothrida), square tapeworm Chicken tapeworm (Raillietina tetragona), canine tapeworm (Taenia hydatigena), Canine tapeworm (Taenia multiceps), sheep worm Sheep measles (Taenia ovis), beetle tapeworm Dog tapeworm (Taenia pisiformis), striped beetle Beef tapeworm (Taenia saginata), striped worm Tapeworm (Taenia serialis) ), Rodentworm Pork tapeworm (Taenia solium), caterpillar Feline tapeworm (Taenia taeniaeformis), single tapeworm Hydatid tapeworm (Echinococcus granulosus), multi-budworm, small fox tapeworm (Echinococcus multilocularis), cat (Echinococcus oligarthrus), Vogel's crustacean (Echinococcus vogeli), reduced tapeworm Rat tapeworm (Hymenolepis diminuta), small tapeworm Dwarf tapeworm (Hymenolepis nana), crustacea double-pored dog tapeworm (Dipylidium ca ninum), cuneate tapeworms (Amoebotaenia sphenoides), funnel-like crustaceans (Choanotaenia infundibulum), quail crustaceans (Metroliasthes coturnix), crustacea Equine tapeworm (Anoplocephala magna), phytophyte crustacean Cecal tapeworm (Anoplocephala perfoliata), papillae Insects Dwarf equine tapeworm (Paranoplocephala mamillana), Benedenta worm Common tapeworm (Moniezia benedeni), expanded tapeworm Sheep tapeworm (Moniezia expansa), Stysia spp.
Striated insects (Pharyngostomum cordatum), Schistosoma haematobium, Schistosoma haematobium, Schistosoma japonicum, Schistosoma japonicum, Schistosoma mansoni, etc.
Echinostoma cinetorchis, Echinostoma hortense, Giant liver fluke (Fasciola gigantica), Liver common liver fluke (Fasciola hepatica), Fasciolopsis buski, Flat belly twin Echinostomida, such as Homalogaster paloniae,
Continental flukes (Dicrocoelium chinensis), moth-type flukes Lancet liver fluke (Dicrocoelium dendriticum), African moth-type flukes African lancet fluke (Dicrocoelium hospes), small pancreatic folds (Eurytrema coelomaticum), pancreatic folds Pancreatic fluke (Eurytrema pancreaticum) Paragonimus miyazakii, Paragonimus ohirai, Westermann Lung fluke (Paragonimus westermani), etc. Platimorchiida
Amphimerus spp., Liver fluke Chinese liver fluke (Clonorchis sinensis), Cat liver fluke Cat liver fluke (Opisthorchis felineus), Thai liver fluke Southeast Aasian liver fluke (Opisthorchis viverrini), Pseudamphistom spp .), Metrochis spp., Parametorchis spp., Malformed fluke (Heterophyes heterophyes), Metagonimus yokokawai, foregut fluke (Pygidiopsis summa), etc. Opisthorchiida) fluke,
Amoeba such as Entamoeba histolytica, E. invadens,
Futago Babesia (Babesia bigemina), Cattle Babesia bovis, Big Horse Babesia caballi, Dog Babesia canis, Cat Babesia felis, Gibson dog Babesia gibsoni, Large Piroplasma (Babesia ovata) ), Cytauxzoon felis, tropical piroplasmosis Tyleria (Theileria annulata), pseudocoastal fever Tyreria (Theileria mutans), small piroplasma (Theileria orientalis), east coast fever Tyrelia (Theileria parva), etc. Piroplasmida sporophytes,
Haemoproteus mansoni, chicken leucocytozone (Leucocytozoon caulleryi), Plasmodium falciparum, Plasmodium malariae, Plasmodium ovale, Plasmodium ovale Haemosporida spores such as Plasmodium vivax,
Caryospora spp., Eimeria acervulina, Eimeria bovis, Eimeria brunetti, Eimeria maxima, Eimeria necatrix, Eimeria necatrix Eimeria ovinoidalis, rabbit liver coccidium (Eimeria stiedae), chicken cecal coccidium (Eimeria tenella), dog isospora canis, feline isospora (Isospora felis), porcine isospora suis (Isospora suis), Tizeria aleni , Tyzzeria anseris, Tyzzeria perniciosa, Wenyonella anatis, Wenyonella gagari, Cryptosporidium canis, cat crypt Cryptosporidium felis, Cryptosporidium hominis, turkey Cryptosporidium meleagridis, Cryptosporidium muris, small Cryptosporidium parvco, sarcosis (Sarcocystis cruzi), Sarcocystis felis, Sarcocystis hominis, Sarcocystis miescheriana, Sarcocystis neurona, Sarcocystis colostis tenis S tenis Sarcocystis ovalis), Toxoplasma gondii, dog hepatozoon (Hepatozoon canis), cat hepatozoon (Hepatozoon felis), etc. cidiorida) spores,
Vestibuliferida ciliates, such as large intestine barantidium coli,
Histomanas meleagridis, Pentatrichomonas hominis, Trichomonas tenax and other Trichomonadida flagellates,
Dipromonads (Diplomonadida) flagellates such as Giardia intestinalis, Giardia muris, turkey hexamita (Hexamita meleagridis), Hexamita parva,
Leishmania donovani, Leishmania infantum, Leishmania major, Leishmania tropica, Trypanosoma brucei gambiense, Trypanosoma brucei cruise, Trypanosoma brucei rhodesi Trypanosoma cruzi, Trypanosoma equiperdum, Trypanosoma evansi, etc. Kinotoplastida flagellates,
However, pests in the field of agriculture and horticulture that can be controlled using the compounds of the present invention and external or internal parasites such as livestock, poultry, and pet animals are not limited to these.

On the other hand, as a specific disease, for example,
Diseases of konjac: dry rot Dry rot (Fusarium oxysporum, F. solani f. Sp. Radicicola), white silkworm Stem rot (Athelia rolfsii), root rot Root rot (Pythium aristosporum), leaf blight Bacterial leaf blight ( Acidovorax konjaci), rot soft rot (Erwinia carotovora subsp. Carotovora).

Diseases of taro: Leaf mold (Cladosporium colocasiae), dry rot Dry rot (Fusarium oxysporum f. Sp. Colocasiae), black rot Black rot (Ceratocystis sp.), Plague Phytophthora blight (Phytophthora colocasiae), root rot Disease (Pythium aristosporum, P. myriotylum), Bacterial soft rot (Pectobacterium carotovorum),
Diseases of leek crops: Yellow spot Leaf spot (Heterosporium allii), Black spot disease Alternaria leaf spot (Alternaria porri), Leaf blight Leaf spot (Pleospora herbarum, Stemphylium botryosum, S. vesicarium), Pink root rot (Pyrenochaeta terrestris, Pyrenochaeta sp.), Leaf blight leaf blight (Botrytis cinerea, B. byssoidea, B. squamosa), red mold gray mold (Botrytis cinerea), onion gray rot Onion gray mold neck rot (Botrytis allii), small sclerotial rot (Botrytis squamosa), small sclerotia disease Leaf blight (Ciborinia allii), dry rot dry rot (Fusarium oxysporum), dry rot fungus Fusarium basal rot (Fusarium oxysporum f. sp. allii, F. solani f. sp. radicicola), onion fusarium basal rot (Fusarium oxysporum f. cepae), rust Rust (Puccinia allii), smut Smut (Urocystis cepulae), black rot Mycorrhizal disease Allium white rot (Sclerotium cepivorum), white Silk blight Southern blight (Athelia rolfsii), seedling blight Damping-off (Rhizoctonia solani, Pythium sp.), Downy mildew (Peronospora destructor), plague Phytophthora blight (Phytophthora nicotianae), white plague Leaf blight (Phytophthora) ), Onion rot disease Onion soft rot (Burkholderia cepacia), spring rot Bacterial rot (Pseudomonas cichorii, P. marginalis pv. Marginalis, Erwinia sp.), Leek strain rot fungus Bacterial basal bulb rot (Pseudomonas sp.), Soft rot Disease Bacterial soft rot (Pectobacterium carotovorum).

  Diseases of asparagus: Brown spot disease Leaf spot (Cercospora asparagi), Spot disease Stemphylium leaf spot (Stemphylium botryosum), Stem blight Stem blight (Phomopsis asparagi).

  Potato disease: Brown rot (Fusarium oxysporum, F. solani f. Sp. Pisi, f. Sp. Radicicola), anthracnose Anthracnose (Glomerella cingulata), leaf astringency Leaf spot (Pseudophloeosporella dioscoreae).

  Diseases of rice: Stem rot (Helminthosporium sigmoideum var. Irregulare), Brown spot (Cochliobolus miyabeanus), Seedling blight (Phoma sp., Trichoderma viride, Fusarium solani, Gibberella avenacea, Mucor) fragilis, Rhizopus arrhizus, R. chinensis, R. oryzae, Pythium arrhenomanes, P. graminicola, P. irregulare, P. spinosum, P. sylvaticum), rice smoldering disease False smut (Villosiclava virens), “Bakaane” dise (Gibberella fujikuroi), blast disease Blast (Magnaporthe grisea), staphylococcal nuclear disease Stem rot (Magnaporthe salvinii), blight disease, Sheath blight (Thanatephorus cucumeris), Bacterial grain rot (Burkholderia gladioli, B. glumae), Bacterial seedling blight (Burkholderia plantarii), brown stripe disease Bacterial brown stripe (Acidovorax avenae subsp. Avenae), white leaf blight Bacterial leaf blight (Xanthomonas oryzae pv. Oryzae), inner bud browning disease Bacterial palea browning (Pantoe a ananatis).

  Diseases of wheat: Wheat leaf blight Speckled leaf blotch (Mycosphaerella graminicola), Blight blight Glume blotch (Phaeosphaeria nodorum), Spot disease Spot blotch (Cochliobolus sativus), Barley spot leaf disease Barley stripe (Pyrenophora graminea) Disease Barley net blotch (Pyrenophora teres), Barley powdery mildew (Blumeria graminis f. Sp. Hordei), Wheat powdery mildew (Blumeria graminis f. Sp. Tritici), Rye powdery mildew (Blumeria graminis f. Sp. Secalis), eye spot disease Eyespot (Tapesia acuformis, T. yallundae), snow rot large-sized mycobacterial disease Sclerotinia snow blight (Sclerotinia borealis), ergot disease Ergot (Claviceps purpurea), Fusarium blight (Fusarium crookwellense, F. culmorum, Gibberella avenacea, G. zeae), blight Take-all (Gaeumannomyces graminis), red snow rot Snow mold (Monographella nivalis), streak disease Cephalosporium stripe (Cephalospori) um gramineum), cloudy disease Scald (Rhynchosporium secalis), black rust Stem rust (Puccinia graminis), barley leaf rust (Puccinia hordei), red rust Brown rust (Puccinia recondita), yellow rust Stripe rust (Puccinia) striiformis var. striiformis), smut Flag smut (Urocystis agropyri), black scab Covered smut (Ustilago hordei), naked smut Loose smut (Ustilago nuda), wheat bun (Tilletia caries, T. laevis) Barley nagusa smut (Tilletia controversa), snow rot microbacterial disease Typhula snow blight (Typhula incarnate, T. ishikariensis var. Ishikariensis), strain rot, Foot-rot (Ceratobasidium cornigerum), brown snow rot Browning rot (Pythium graminicola, P. horinouchiense, P. iwayamai, P. okanoganense, P. paddicum, P. vanterpoolii, P. volutum), rye head blight Bacterial halo blight (Pseudomonas syringae pv. Coronafaciens), black-bump disease Bacterial black node (Pseudomonas syringae pv. syringae).

  Diseases of Shiba: Dollar spot (Sclerotinia homoeocarpa), Fairy rings disease (Bovista dermoxantha, Conocybe apala, Lepista subnuda, Lycoperdon curtisii, L. perlatum, Marasmius oreades), pseudo-leaf rot Rhizoctonia patch (Ceratobasidium patch) ), Leaf rot, Brown patch, Large patch (Rhizoctonia solani), Rust (Puccinia zoysiae), Pythium blight (Pythium graminicola, P. periplocum, P. vanterpoolii).

  Sugarcane diseases: Leaf scorch leaf scorch (Stagonospora sacchari), top rot (Fusarium moniliforme var. Majus, Gibberella fujikuroi, G. fujikuroi var. Subglutinans), yellow rust Orange rust (Puccinia kuehnii) Brown rust (Puccinia melanocephala), smut Sugarcane smut (Sporisorium scitamineum).

  Maize diseases: sesame leaf blight, Southern leaf blight (Cochliobolus heterostrophus), soot scab, Northern leaf blight (Setosphaeria turcica), seedling blight Seedling blight (Gibberella avenacea, Penicillium sp.), Southern rust (Puccinia polysora) ), Smut, Corn smut (Ustilago maydis), blight, Sheath blight (Thanatephorus cucumeris), root rot, Browning root rot (Pythium arrhenomanes, P. graminicola).

  Banana disease: Sigatoka disease Black sigatoka (Mycosphaerella fijiensis), yellow leaf sigatoka leaf spot (Mycosphaerella musicola), Panama disease (Fusarium oxysporum f. Sp. Cubense).

  Diseases of ginger crops: Leaf spot (Mycosphaerella zingiberis), Ginger white spot disease (Phyllosticta zingiberis), Blast (Pyricularia zingiberis), Blight (Rhizoctonia solani), Root rot (Pythiumul) , P. zingiberis).

  Sugar beet diseases: brown spot disease Cercospora leaf spot (Cercospora beticola), spot disease Ramularia leaf spot (Ramularia beticola), snake eye disease Leaf spot (Pleospora betae), powdery mildew Powdery mildew (Erysiphe betae), leaf rot leaf blight Root rot Root rot (Thanatephorus cucumeris), black root disease Aphanomyces root rot (Aphanomyces cochlioides), seedling blight Damping-off (Pleospora betae, Fusarium sp., Colletotrichum dematium, Rhizoctonia solani, Aphanomyces cochliobaryanum, Pythium)

  Diseases of spinach: Brown spot disease Leaf spot (Cercospora beticola), Spot disease Leaf mold (Cladosporium variabile), wilt disease Fusarium wilt (Fusarium oxysporum f. Sp. Spinaciae), anthracnose disease Anthracnose (Colletotrichum dematium f. Spinacia) Diseases Foot rot (Rhizoctonia solani), root rot Root rot (Aphanomyces cochlioides), downy mildew (Peronospora farinosa f. Sp. Spinaciae), withering disease Damping-off (Pythium aphanidermatum, P. myriotylum, P. paroecandrum) , P. ultimum var. Ultimum), Bacterial leaf spot (Pseudomonas syringae pv. Spinaciae).

  Grape Diseases: Brown Spot Disease Isariopsis leaf spot (Pseudocercospora vitis), Black Mold Anthracnose (Elsinoe ampelina), Powdery Mildew Powdery mildew (Uncinula necator), Gray Mold (Botrytis cinerea), Swelling Arm (Diaporthe) kyushuensis), bud blight Bud blight (Diaporthe rudis), vine split disease Dead arm (Phomopsis viticola), late rot Ripe rot (Colletotrichum acutatum, Glomerella cingulata), rust disease Rust (Physopella ampelopsidis), downy mildew (downy mildew) Plasmopara viticola).

  Diseases of leguminous crops: Purple stain (Cercospora kikuchii), Ring bean ring spot (Cercospora zonata), peanut brown leaf spot (Mycosphaerella arachidis), groundnut black astringent leaf spot (Mycosphaerella berkeleyi), Pea brown spot disease Mycosphaerella blight (Mycosphaerella pinodes), angular leaf spot (Phaeoisariopsis griseola), pea brown spot disease Ascochyta blight (Ascochyta pisi), broad bean brown spot disease (Didymella fabae), powdery mildew (Pwdery mildew) Erysiphe pisi, Sphaerotheca fuliginea), gray mold (Botrytis cinerea), broad bean red spot disease Chocolate spot (Botrytis cinerea, B. elliptica, B. fabae), sclerotia stem rot (Sclerotinia sclerotiorum), black root rot Crown and root rot (Calonectria ilicicola), pea blight Root rot (Fusarium arthrosporioides, F. avenaceum, F. sporotrichioides), common bean root rot Fusarium root-rot (Fusar) ium cuneirostrum), Fusarium wilt (Fusarium oxysporum f. sp. adzukicola), Stem wilt (Fusarium avenaceum, F. oxysporum f. sp. fabae), pea root rot (Fusarium solani f. sp. gregata), soybean rust, soybean rust (Phakopsora pachyrhizi), azuki rust Rust (Uromyces phaseoli var. azukicola), kidney bean rust Rust (Uromyces phaseoli var. phaseoli), rust Rust (Uromyces viciae-fabae var. viciae-fabae ), White silkworm Southern blight (Athelia rolfsii), soybean downy mildew (Peronospora manshurica), soybean stem blight Phytophthora root and stem rot (Phytophthora sojae), azuki bean Stem plague (Phytophthora vignae f. Sp. Adzukicola), soybean leaf burning Bacterial pustule (Xanthomonas campestris pv. Glycines), soybean spot bacterial disease Bacterial blight (Pseudomonas savastanoi pv. Glycinea) phaseolicola), azuki bean bacterial disease (Pseudomonas syringae pv. syringae).

  Hop diseases: powdery mildew (Oidium sp., Sphaerotheca intermedia), gray mold (Botrytis cinerea), wilt disease, Hop wilt (Verticillium albo-atrum), downy mildew (Pseudoperonospora humuli).

  Fig disease: yeast rot Souring (Candida sorbosa, Candida sp., Pichia kluyveri), common scab Fig scab (Sphaceloma caricae), gray mold (Botrytis cinerea), bacterial wilt Ceratocystis canker (Ceratocystis fimbriata), White root rot (Rosellinia necatrix), anthracnose Anthracnose (Glomerella cingulata), rust Rust (Phakopsora nishidana), black mold Rhizopus rot (Rhizopus stolonifer var. Stolonifer), plague White powdery rot (Phytophthora palmiv).

  Diseases of mulberry: Backy mildew (Phyllactinia moricola), shoot blight Twig blight (Hypomyces solani f. Sp. Mori, f. Sp. Pisi, Gibberella baccata), head blight Dieback (Diaporthe nomurai), white crest White root rot (Rosellinia necatrix), purple striped feather Violet root rot (Helicobasidium longisporum), red astringency Red rust (Aecidium mori), bacteriostatic bacterial disease Bacterial blight (Pseudomonas syringae pv. Mori), branch soft rot Shoot soft rot (Pectobacterium carotovorum).

  Rose diseases: Stem blight Stem canker (Leptosphaeria coniothyrium), powdery mildew Powdery mildew (Podosphaera pannosa, Uncinuliella simulans), black spot disease Black spot (Diplocarpon rosae), gray mold disease Botrytis blight (Botrytis cinerea), rust disease Rust ( Kuehneola japonica, Phragmidium fusiforme, P. mucronatum, P. rosae-multiflorae), downy mildew (Peronospora sparsa), root gall disease Crown gall (Agrobacterium tumefaciens).

  Strawberry Diseases: Janame Disease Leaf spot (Mycosphaerella fragariae), Powdery Mildew Powdery mildew (Sphaerotheca aphanis var. Aphanis), Gray Mold (Botrytis cinerea), Dwarf Fusarium wilt (Fusarium oxysporum f. Sp. Fragariae) ), Leaf spot leaf blight (Phomopsis obscurans), anthrax Crown rot (Colletotrichum acutatum, C. fragariae, Glomerella cingulata), plague Phytophthora rot (Phytophthora cactorum, P. nicotianae, Phytophthora sp.), Root rot stele Phytophthora fragariae).

  Diseases of loquat: Sesame color spot disease Entomosporium leaf spot (Diplocarpon mespili), gray leaf spot (Pestalotia eriobotrifolia, Pestalotiopsis funereal, P. neglecta), white root rot (Rosellinia necatrix), anthracnose disease Anthracnose ( Colletotrichum acutatum, Glomerella cingulata), Cancer canker (Pseudomonas syringae pv. Eriobotryae).

  Diseases of apples: Black spot disease Fruit spot (Mycosphaerella pomi), spotted leaf disease Alternaria blotch (Alternaria mali), black spot disease Scab (Venturia Inaequalis), ring-shaped disease Ring rot (Botryosphaeria berengeriana f. Sp. Piricola), soot spot Fly speck (Schizothyrium pomi), powdery mildew (Podosphaera leucotricha), brown spot Blotch (Diplocarpon mali), moniliosis Blossom blight (Monilinia mali), rot Valsa canker (Valsa ceratosperma), white root rot (Rosellinia necatrix), anthrax Bitter rot (Colletotrichum acutatum, Glomerella cingulata), soot spot Sooty blotch (Phyllachora pomigena), purple leaf rot Violet root rot (Helicobasidium longisporum), red rot Rust (Gymnosporangium yamadae) blight (Erwinia amylovora).

  Pear diseases: Black spot disease Black spot (Alternaria kikuchiana), Brown spot disease Brown spot (Stemphylium sp.), Black star disease Scab (Venturia nashicola), Ring rot Ring rot (Botryosphaeria berengeriana f. Sp. Piricola) Diseases Shoot blight (Botryosphaeria dothidea), powdery mildew Powdery mildew (Phyllactinia mali), blight disease Phomopsis canker (Phomopsis fukushii), keratocarcinoma Coral spot (Nectria cinnabarina), white root rot (Rosellinia) necatrix), Anthracnose (Colletotrichum acutatum, Glomerella cingulata), Rust (Gymnosporangium asiaticum), Plague Phytophthora fruit rot (Phytophthora cactorum, P. syringae), Bacterial black spot (syringae p. syringae. Fire blight (Erwinia amylovora).

Diseases of apricot: Scab (Venturia carpophila), Zonate leaf spot (Grovesinia pruni), Brown rot (Monilinia fructicola, M. fructigena, M. laxa), Black blight Shoot blight (Coryneum sp.), Anthracnose (Gloeosporium sp., Colletotrichum acutatum), Bacterial shot hole (Xanthomonas campestris pv. Pruni).
Plum disease: Scab (Venturia carpophila), Gray mold (Botrytis cinerea), Zonate leaf spot (Grovesinia pruni), Brown rot (Monilia mumecola, Monilinia fructicola, M. laxa) ), Anthracnose (Colletotrichum acutatum, Glomerella cingulata), Sooty blotch (Peltaster sp.), Chloranthy (Blastospora smilacis), Bacterial canker (Pseudomonas syringae pv. Morsprunorum)
Diseases of plums: Plum pockets (Taphrina pruni), brown rot (Monilinia fructicola, M. fructigena), anthracnose (Colletotrichum acutatum), black leaf spot Bacterial leaf spot (Xanthomonas arboricola pv. Pruni).

  Peach diseases: Leaf curl (Taphrina deformans), black scab Scab (Venturia carpophila), wart skin Blister canker (Botryosphaeria berengeriana f. Sp. Perscicae), powdery mildew Powdery mildew (Podosphaera pannosa, P. tridactyla var) tridactyla), ash blight Brown rot (Monilinia fructicola, M. fructigena), homoposis rot Phomopsis rot (Phomopsis sp.), blight Cytospora canker (Leucostoma persoonii), anthracnose Anthracnose (Colletotrichum acutatum, Glomerella cing) Fruit red spot (Ellisembia sp.), Brown rust (Tranzschelia discolor), Bacterial shot hole (Xanthomonas arboricola pv. Pruni, Pseudomonas syringae pv. Syringae, Brenneria nigrifluens).

  Diseases of sweet potato: Brown perforated disease Cylindrosporium leaf spot (Mycosphaerella cerasella, Blumeriella jaapii), brown rot (Monilinia fructicola, M. fructigena, M. laxa), juvenile sclerotia young-fruit rot (Monilinia kusanoi), White root rot (Rosellinia necatrix), anthracnose Anthracnose (Colletotrichum acutatum, Glomerella cingulata), black mold Rhizopus rot (Rhizopus stolonifer var. Stolonifer), resinous bacterial disease Bacterial canker (Pseudomonas syringae, P. s. P. S. syringae, P. viridiflava).

  Diseases of cucurbits: black scab Scab (Cladosporium cucumerinum), brown spot disease Corynespora leaf spot (Corynespora cassiicola), vine blight Gummy stem blight (Didymella bryoniae), powdery mildew (Erysiphe betae, Leveillula taurica, Oidium sp.) , Podosphaera xanthii, Sphaerotheca fuliginea), gray mold (Botrytis cinerea), sclerotia, Sclertinia rot (Sclerotinia sclerotiorum), Fusarium wilt (Fusarium oxysporum f. Sp. Cucumerigen, f. La. sp. luffae, f. sp. melonis, f. sp. niveum), Fusarium basal rot (Fusarium solani f. sp. cucurbitae), Cucumber homoposis root rot (Phomopsis sp.), Root rot (Monosporascus cannonballus), pumpkin vitiligo disease Plectosporium blight (Monographella cucumerina), anthracnose Anthracnose (Colletotrichum orbiculare, Glomerella cingulata), white silkworm Southern blight (Athelia rolfsii), seedling blight Damping-off (Rhizoctytholi acearum, P. debaryanum, P. spinosum), downy mildew (Pseudoperonospora cubensis), watermelon brown rot, Brown rot (Phytophthora capsici), plague Phytophthora rot (Phytophthora capsici, P. cryptogea, P. melonis, P. ), Cotton rot Pythium fruit rot (Pythium aphanidermatum), Bacterial fruit blotch (Acidovorax avenae subsp. Citrulli), brown spot Bacterial spot (Xanthomonas campestris pv. Cucurbitae), Marginal blight (Pseudomonas marginalis pv. Marginalis, P. viridiflava), Angular leaf spot (Pseudomonas syringae pv. Lachrymans).

  Diseases of chestnut: Endobia canker (Cryphonectria parasitica), Anthracnose (Glomerella cingulata).

  Diseases of cruciferous vegetables: white spot (Pseudocercosporella capsellae), black leg disease (Leptosphaeria maculans), black spot disease Alternaria leaf spot (Alternaria brassicae, A. brassicicola, A. japonica), black soot disease Alternaria sooty spot (Alternaria brassicicola), Wasabi ink-filled black leg (Phoma wasabiae), gray mold (Botrytis cinerea), rape snow mold (Sclerotinia nivalis, Typhula japonica, T. incarnate, T. ishikariensis var. ishikariensis), mycorrhizal disease Sclerotinia rot (Sclerotinia sclerotiorum), yellow yellow (Fusarium oxysporum f. sp. conglutinans), Japanese radish yellow yellow (Fusarium oxysporum f. sp. raphani), black spot Verticillium black spot (Verticillium black spot disease) Verticillium albo-atrum, V. dahliae), Chinese cabbage yellowing disease Yellows (Verticillium dahliae), cabbage verticillium wilt Verticillium wilt (Verticillium longisporum), anthracnose Anthracnose (Co lletotrichum dematium, C. destructivum, C. higginsianum), Damping-off (Rhizoctonia solani), clubroot (Plasmodiophora brassicae), white rust (Albugo macrospora), wasabi white rust (Albugo wasabiae), Komatsuna downy mildew Downy mildew (Hyaloperonospora brassicae), Wasabi downy mildew (Peronospora alliariae-wasabi), downy mildew (Peronospora parasitica), cabbage seedling disease Damping-off (Pythium buismaniae) , P. zingiberis, Rhizoctonia solani), withering disease Damping-off (Pythium sp.), Black rot Black rot (Xanthomonas campestris pv. Campestris), broccoli flower rot, Head rot (Pseudomonas fluorescens, P. viridiflava, Pectobacterium car ), Bacterial black spot (Pseudomonas syringae pv. Maculicola), Bacterial soft rot (Pectobacterium carotovorum, P. wasabiae).

  Papaya disease: soft rot Phytophthora blight (Phytophthora nicotianae).

  Diseases of okra: Leaf leaf mold (Pseudocercospora abelmoschi), fruit black spot disease Alternaria rot (Alternaria alternata), ring rot pod spot (Phoma exigua var. Exigua), powdery mildew Powdery mildew (Leveillula taurica), gray Mold mold Gray mold (Botrytis cinerea), black root disease Black root rot (Thielaviopsis basicola), seedling blight Damping-off (Rhizoctonia solani, Pythium ultimum var. Ultimum, Pythium sp.), Leaf blight (Pseudomonas cichorii, P) viridiflava).

  Mango disease: Anthracnose (Colletotrichum acutatum, Glomerella cingulata).

  Diseases of citrus: Yellow spot Greasy spot (Mycosphaerella citri, M. horii), common scab Scab (Elsinoe fawcettii), black rot Black rot (Alternaria citri), green mold common green mold (Penicillium digitatum), blue mold disease Blue mold (Penicillium italicum), gray mold (Botrytis cinerea), black spot Melanose (Diaporthe citri), small sunspot Melanose like blemish (Alternaria citri, Diaporthe rudis), white coat rot (Rosellinia necatrix), Anthracnose (Glomerella cingulata), brown rot (Phytophthora citricola, P. citrophthora, P. nicotianae, P. palmivora), scab disease Citrus canker (Xanthomonas citri subsp. Citri).

  Diseases of kiwifruit: Sooty spot (Pseudocercospora actinidiae), soft rot of fruit soft rot (Botryosphaeria dothidea, Lasiodiplodia theobromae, Diaporthe sp.), Gray mold (Botrytis cinerea), white root rot (white root rot) Rosellinia necatrix), Anthracnose (Colletotrichum acutatum, Glomerella cingulata), Bacterial bacterial disease Bacterial blossom blight (Pseudomonas marginalis pv. Marginalis, P. syringae pv. Syringae, P. viridiflava) actinidiae).

  Oyster diseases: angular leaf spot (Cercospora kaki), circular leaf spot (Mycosphaerella nawae), black spot (Fusicladium levieri), soot spot Fly speck (Schizothyrium pomi), powdery mildew Powdery mildew (Phyllactinia kakicola), gray mold (Botrytis cinerea), black leaf spot (Discostroma sp.), Anthracnose Anthracnose (Glomerella cingulata).

  Blueberry diseases: Gray mold (Botrytis cinerea), Valdensia leaf blight (Valdensia heterodoxa).

  Tea diseases: Brown round spot (Cercospora chaae, Pseudocercospora ocellata), Anthracnose (Discula theae-sinensis), Ring blight Gray blight (Pestalotiopsis longiseta, P. theae), White root rot (Rosellinia necatrix), leaf blight Brown blight (Glomerella cingulata), net blast Net blister blight (Exobasidium reticulatum), blast Blister blight (Exobasidium vexans), black leaf rot Black rot (Ceratobasidium sp.) Disease Bacterial shoot blight (Pseudomonas syringae pv. Theae).

  Perilla disease: Spot disease Corynespora leaf spot (Corynespora cassiicola), Rust (Coleosporium plectranthi).

  Sesame Diseases: White Silk Disease Stem rot (Athelia rolfsii), Bacterial wilt (Ralstonia solanacearum), Bacterial leaf spot (Pseudomonas syringae pv. Sesami).

  Diseases of sweet potato: stem rot (Fusarium oxysporum f. Sp. Batatas, F. solani), black spot black rot (Ceratocystis fimbriata), purple leaf rot Violet root rot (Helicobasidium longisporum), soft rot Soft rot ( Rhizopus stolonifer var. Stolonifer, R. tritici), withering disease Soil rot (Streptomyces ipomoeae).

  Tomato diseases: Leaf mold (Mycovellosiella fulva), mold mold Cercospora leaf mold (Pseudocercospora fuligena), brown ring disease Corynespora target spot (Corynespora cassiicola), ring blight disease Early blight (Alternaria solani), leaf spot disease spot (Stemphylium lycopersici, S. solani), brown root rot (Pyrenochaeta lycopersici), powdery mildew Powdery mildew (Leveillula taurica, Oidium neolycopersici, Oidium sp.), gray mold (Botrytis cinerea), fungus Stem rot (Sclerotinia sclerotiorum), Fusarium wilt (Fusarium oxysporum f. Sp. Lycopersici), Crown and root rot (Fusarium oxysporum f. Sp. Radicis-lycopersici), Verticillium wilt Verticillium dahliae), white silk disease Southern blight (Athelia rolfsii), seedling blight Damping-off (Rhizoctonia solani, Pythium vexans), plague Late blight (Phytophthora infestans), scab disease Bacterial canker (Clavibacter michig) anensis subsp. michiganensis), bacterial wilt (Ralstonia solanacearum), bacterial spot Bacterial spot (Xanthomonas campestris pv. vesicatoria), soft rot Bacterial soft rot (Pectobacterium carotovorum).

  Eggplant diseases: Leaf mold (Mycovellosiella nattrassii), brown spot disease (Paracercospora egenula), black blight Black blight (Corynespora cassiicola), brown spot Early blight (Alternaria solani), powdery mildew Powdery mildew (Erysiphe cichoracearum, Leveillula taurica, Sphaerotheca fuliginea), Gray mold (Botrytis cinerea), Mycorrhizal disease Stem rot (Sclerotinia sclerotiorum), Semi-blight (Fusarium oxysporum f. Sp. Melongenae), Verticium wilt Verticillium dahliae), brown spot disease (Phomopsis vexans), white silkworm Southern blight (Athelia rolfsii), seedling blight Damping-off (Rhizoctonia solani), brown rot Brown rot (Phytophthora capsici), plague late blight ( Phytophthora infestans), bacterial wilt (Ralstonia solanacearum), brown leaf blight Necrotic leaf spot (Pseudomonas cichorii).

  Potato Diseases: Summer blight Early blight (Alternaria solani), Dry rot Dry rot (Fusarium oxysporum, Fusarium solani f. Sp. Eumartii, f. Sp. Radicicola), Anthracnose (Colletotrichum coccodes), Black scurf (Thanatephorus cucumeris), powdery scab, Powdery Scab (Spongospora subterranea f. Sp. Subterranea), plague Late blight (Phytophthora infestans), ring rot Ring rot (Clavibacter michiganensis subsp. Sepedonicus), scab Scab (Streptomyces sp) Bacterial wilt (Ralstonia solanacearum), black leg (Dickeya dianthicola, Pectobacterium atrosepticum, P. carotovorum), soft rot Bacterial soft rot (Pectobacterium carotovorum).

  Diseases of pepper peppers: Spot disease Frogeye leaf spot (Cercospora capsici), Black blight Corynespora blight (Corynespora cassiicola), White spot disease Stemphyrium leaf spot (Stemphylium lycopersici), powdery mildew Powdery mildew (Leveillula taurica) mold (Botrytis cinerea), mycorrhizal disease Sclerotinia rot (Sclerotinia sclerotiorum), wilt Fusarium wilt (Fusarium oxysporum), anthracnose Anthracnose (Colletotrichum acutatum, C. capsici, C. nigrum), white silk disease Southern blight (Athelia) Damping-off (Rhizoctonia solani), plague Phytophthora blight (Phytophthora capsici), bacterial wilt Bacterial wilt (Ralstonia solanacearum), bacterial spot Bacterial spot (Xanthomonas campestris pv. Vesicaacter), soft rot Brot Pectobacterium carotovorum).

  Tobacco disease: Red spot disease Brown spot (Alternaria alternata), back fracture Sore shin (Rhizoctonia solani), plague Black shank (Phytophthora nicotianae), blight Bacterial wilt (Ralstonia solanacearum).

  Celery disease: Spot blight Early blight (Cercospora apii), leaf blight Late blight (Septoria apiicola), soft rot Bacterial soft rot (Pectobacterium carotovorum).

  Mitsuba's diseases: Sclerotinia rot (Sclerotinia sclerotiorum), blight (Fusarium oxysporum f. Spii), rust Rust (Puccinia tokyensis), blight (Rhizoctonia solani), downy mildew (Plasmopara) nivea), root rot (Pythium aphanidermatum, P. apleroticum, Pythium sp.).

  Diseases of carrots: Spot disease Cercospora blight (Cercospora carotae), black leaf blight Leaf blight (Alternaria dauci), black spot disease Alternaria black rot (Alternaria radicina), powdery mildew Powdery mildew (Erysiphe heraclei), mycorrhizal disease Sclerotinia rot (Sclerotinia minor, S. sclerotiorum), dry rot Dry rot (Fusarium solani f. Sp. Radicicola, Gibberella avenacea), purple coat feather Violet root rot (Helicobasidium longisporum), white silkworm Southern blight (Athelia rolfsii), white Silk blight Southern blight (Athelia rolfsii), root rot Damping-off (Rhizoctonia solani), blot rot Brown blotted root rot (Pythium sulcatum), root gall (Agrobacterium tumefaciens), soft rot Bacterial soft rot (Pectobacterium carotovorum).

  Diseases of parsley: Spot disease Leaf spot (Cercospora apii), powdery mildew Powdery mildew (Erysiphe heraclei), plague (Phytophthora nicotianae), soft rot Bacterial soft rot (Pectobacterium carotovorum).

  Diseases of crabs: common scab Spot anthracnose (Elsinoe araliae), wilt disease (Phytophthora cactorum).

  Diseases of Udo: Black spot disease spot spot (Alternaria panax, Alternaria sp.), Sclerotia disease Sclerotinia rot (Sclerotinia sclerotiorum), wilt disease Verticillium wilt (Verticillium dahliae, V. nigrescens), white silk disease Southern blight (Athelia rolfsii) The plague Phytophthora rot (Phytophthora cactorum).

  Lettuce diseases: Gray mold (Botrytis cinerea), sclerotia Stem rot (Sclerotinia sclerotiorum), root rot Root rot (Fusarium oxysporum f. Sp. Lactucae), bottom rot Bottom rot (Rhizoctonia solani) Downy mildew (Bremia lactucae), Bacterial spot (Xanthomonas axonopodis pv. Vitians), rot Bacterial rot (Pseudomonas cichorii, P. marginalis pv. Marginalis, P. viridiflava), soft rot Bacterial soft carrot (Pectobacterium) ).

  Diseases of chrysanthemum: black spot disease spot spot (Septoria chrysanthemella), brown spot disease leaf blight (Septoria obesa), flower rot ray blight (Didymella chrysanthemi), powdery mildew powdery mildew (Erysiphe cichoracearum var. Cichoracearum), gray mold disease Botrytis blight (Botrytis cinerea), sclerotia Stem rot (Sclerotinia sclerotiorum), half body wilt Wilt (Verticillium dahliae), brown rust Rust (Phakopsora artemisiae), white rust Rust (Puccinia horiana), black rust Rust (Puccinia) tanaceti var. tanaceti), flower blight Petal blight (Itersonilia perplexans), white silk disease Southern blight (Athelia rolfsii), blight Root and stem rot (Ceratobasidium cornigerum, Rhizoctonia solani), downy mildew (Peronospora danica) Phytophthora rot (Phytophthora cactorum, Phytophthora sp.), Crown gall (Agrobacterium tumefaciens), Bacterial wilt (Ralstonia solanacearum), Bacterial stem rot (Pectobacterium c) arotovorum).

  Diseases of syringae: leaf blight Leaf blight (Cercospora chrysanthemi), anthracnose Anthracnose (Colletotrichum acutatum), downy mildew (Peronospora chrysanthemi-coronarii).

  Diseases of sunflower: Brown spot disease (Septoria helianthi), black spot disease spot spot (Alternaria helianthi), powdery mildew Powdery mildew (Erysiphe cichoracearum, Golovinomyces cichoracearum var. Latisporus, Oidium sp., Podosphaera fusca) Gray mold (Botrytis cinerea), mycorrhizal disease Sclerotinia rot (Sclerotinia sclerotiorum), seedling blight Root and stem rot (Rhizoctonia solani), downy mildew (Plasmopara halstedii), spotted bacterial disease Bacterial leaf spot (Pseudomonas syringae pv) helianthi), cavity disease (Pectobacterium carotovorum).

  Buffalo disease: Verticillium wilt (Verticillium dahliae), white silkworm Southern blight (Athelia rolfsii).

Burdock diseases: Black spot disease (Phoma exigua var. Exigua), powdery mildew (Powdery mildew (Podosphaera fusca)), black streak disease (Black streak (Itersonilia perplexans)), black bruise (Black scurf (Rhizoctonia solani)), root rot (Pythium irregulare), Bacterial spot (Xanthomonas campestris pv. Nigromaculans).
However, plant diseases that can be controlled using the compounds of the present invention are not limited to these.

  That is, the composition of the present invention and the method of the present invention are also extremely effective against pests that have developed resistance to existing insecticides such as organophosphorus compounds, carbamate compounds, or pyrethroid compounds. Eyes (Coleoptera), Hymenoptera (Hymenoptera), Lepidoptera (Lepidoptera), Diptera (Flyes), Lepidoptera (Fleas), Common moths (Thrips), Hemiptera (stink bugs) Eyes and horizontal eyes), chewing jaws (betish eyes and lice eyes), straight eyes (butterfly eyes), reticulate eyes (cockroaches), isopic eyes (termite eyes), mucous eyes (flying eyes), etc. Insects, crustaceans (Coleoptera: Crustacea), Coralids (Acaridaceae, Acaridaceae, Acaridaceae, Acaridaceae), Acarids (Acaridaceae, Acaridaceae, Acaridaceae, Acaridaceae, Acaridaceae, Spider Mite Family, green spider mite family, tsutsugamushi department), tick sub (Acaridaceae, Tickidae), Acarididae (Asteridae, Pterodactylidae, Hemiidae), etc., mites, gastropods and whipworms, helminths, roundworms, leaf nematodes, barrens, It is possible to effectively control pests belonging to nematodes such as Coleoptera, Camaranus, Coleoptera, and Circumferential elegans at low concentrations. On the other hand, the composition of the present invention and the method of the present invention have extremely adverse effects on mammals, fish, crustaceans and beneficial insects (useful insects such as honeybees, bumblebees, natural enemies such as honeybees, wasps, mistletoe, and stink bugs). It has few useful features.

When the isoxazoline-substituted benzamide compound represented by the formula (1) and the compound shown in Table 2 above are combined, the composition of the present invention and the method of the present invention are particularly effective against mites and hemipodid pests. Although it has an excellent synergistic effect, it has a better synergistic effect on mites, mites, mites, kanzawa mites, and other mites, and aphids and whiteflies in the order of hemids.

  The isoxazoline-substituted benzamide compound represented by the formula (1) of the present invention can be produced, for example, according to the method described in International Publication No. 2005/085216 pamphlet or International Publication No. 2007/026965 pamphlet.

  The composition of the present invention uses, as a mixture, one or more selected from the isoxazoline-substituted benzamide compound represented by the formula (1) and a salt thereof and one or more selected from the compound group A. However, it is usually mixed with a suitable solid carrier or liquid carrier, and if desired, a surfactant, a penetrating agent, a spreading agent, a thickening agent, an antifreezing agent, a binder, an anti-caking agent, a disintegrating agent, Add antifoaming agent, antiseptic, anti-decomposition agent, etc., soluble concentrate, emulsion (emulsifiable concentrate), wettable powder, water soluble powder, granular wettable powder (water dispersible granule, water soluble granule, suspension concentrate, concentrated emulsion, suspoemulsion, microemulsion, dustable powder It can be put to practical use in preparations of any dosage form such as granules, tablets, and emulsifiable gels. Further, from the viewpoint of labor saving and safety improvement, the preparations of any of the above dosage forms can be provided by being enclosed in a water-soluble package such as a water-soluble capsule and a bag of a water-soluble film.

  Examples of the solid carrier include quartz, calcite, gypsum, dolomite, chalk, kaolinite, pyrophyllite, sericite, halosite, metahalosite, kibushi clay, glazed clay, porcelain stone, siegrite, and allophane. Natural minerals such as shirasu, kira, talc, bentonite, activated clay, acid clay, pumice, attapulgite, zeolite and diatomaceous earth, for example, calcined clay, perlite, shirasu balloon, vermiculite, attapulgus clay and calcined diatomaceous earth Baked products such as magnesium carbonate, calcium carbonate, sodium carbonate, sodium bicarbonate, ammonium sulfate, sodium sulfate, magnesium sulfate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate and potassium chloride, such as glucose, fructose , And Sugars such as sugar and lactose, polysaccharides such as starch, powdered cellulose and dextrin, organic materials such as urea, urea derivatives, benzoic acid and benzoic acid salts, such as wood flour, cork flour, corn cobs, walnut shells and Examples include plants such as tobacco stalks, fly ash, white carbon (for example, hydrous synthetic silica, anhydrous synthetic silica, hydrous synthetic silicate, etc.) and fertilizers.

Examples of the liquid carrier include xylene, alkyl (C ₉ or C ₁₀ etc.) benzene, phenyl xylyl ethane and alkyl (C ₁ or C ₃ etc.) naphthalene and other aromatic hydrocarbons, machine oil, normal paraffin, isoparaffin and Aliphatic hydrocarbons such as naphthene, mixtures of aromatic and aliphatic hydrocarbons such as kerosene, alcohols such as ethanol, isopropanol, cyclohexanol, phenoxyethanol and benzyl alcohol, ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol , Polyhydric alcohols such as polyethylene glycol and polypropylene glycol, propyl cellosolve, butyl cellosolve, phenyl cellosolve, propylene glycol monomethyl ether, propylene Ethers such as recall monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether and propylene glycol monophenyl ether, ketones such as acetophenone, cyclohexanone and γ-butyrolactone, fatty acid methyl esters, dialkyl esters of succinic acid, dialkyl esters of glutamic acid, adipine Esters such as acid dialkyl esters and phthalic acid dialkyl esters, acid amides such as N-alkyl (C ₁ , C ₈ or C ₁₂ ) pyrrolidone, soybean oil, linseed oil, rapeseed oil, coconut oil, cottonseed oil and castor oil Examples include fats and oils, dimethyl sulfoxide and water.

  These solid and liquid carriers may be used alone or in combination of two or more.

  Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl (mono or di) phenyl ether, polyoxyethylene (mono, di or tri) styryl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene Ethylene fatty acid (mono or di) ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, castor oil ethylene oxide adduct, acetylene glycol, acetylene alcohol, ethylene oxide adduct of acetylene glycol, ethylene oxide adduct of acetylene alcohol and alkyl Nonionic surfactants such as glycosides, alkyl sulfate esters, alkylbenzene sulfonates, lignin sulfonates, Killsulfosuccinate, naphthalenesulfonate, alkylnaphthalenesulfonate, salt of formalin condensate of naphthalenesulfonic acid, salt of formalin condensate of alkylnaphthalenesulfonic acid, polyoxyethylene alkyl ether sulfate or phosphate ester salt, polyoxy Ethylene (mono or di) alkyl phenyl ether sulfate or phosphate ester salt, polyoxyethylene (mono, di or tri) styryl phenyl ether sulfate or phosphate ester salt, polycarboxylate (eg polyacrylate, polymaleate and Copolymers of maleic acid and olefins, etc.) and anionic surfactants such as polystyrene sulfonates, cationic surfactants such as alkylamine salts and alkyl quaternary ammonium salts, amino acid types and beties Amphoteric surfactants such as mold, and silicone-based surfactants and fluorinated surfactants.

  The content of these surfactants is not particularly limited, but is usually preferably in the range of 0.05 to 20 parts by weight with respect to 100 parts by weight of the preparation of the present invention. These surfactants may be used alone or in combination of two or more.

    Next, formulation examples of preparations when using the composition of the present invention are shown. However, the formulation examples of the present invention are not limited to these. In the following formulation examples, “part” means part by weight, and “active ingredient compound” is a general term for a compound selected from the isoxazoline-substituted benzamide compound represented by the formula (1) and its salt and the compound group A. is there.

[Wettable powder]
Active ingredient compound 0.1-80 parts Solid carrier 5-98.9 parts Surfactant 1-10 parts Others 0-5 parts Others include, for example, anti-caking agents and decomposition inhibitors.

[Emulsifiable concentrate]
Active ingredient compound 0.1-30 parts Liquid carrier 45-95 parts Surfactant 4.9-15 parts Others 0-10 parts Others include, for example, spreading agents, decomposition inhibitors and the like.

[Suspension concentrate]
Active ingredient compound 0.1 to 70 parts Liquid carrier 15 to 98.89 parts Surfactant 1 to 12 parts Others 0.01 to 30 parts Others include, for example, antifreezing agents and thickeners.

[Granular wettable powder (water dispersible granule)]
Active ingredient compound 0.1 to 90 parts Solid carrier 0 to 98.9 parts Surfactant 1 to 20 parts Others 0 to 10 parts Others include, for example, binders and decomposition inhibitors.

[Soluble concentrate]
Active ingredient compound 0.01 to 70 parts Liquid carrier 20 to 99.99 parts Others 0 to 10 parts Other examples include antifreezing agents and spreading agents.

[Granule]
Active ingredient compound 0.01-80 parts Solid carrier 10-99.99 parts Others 0-10 parts Others include, for example, binders, decomposition inhibitors and the like.

[Dustable powder]
Active ingredient compound 0.01 to 30 parts Solid carrier 65 to 99.99 parts Others 0 to 5 parts Other examples include a drift inhibitor and a decomposition inhibitor.

  Next, although the example of an agrochemical formulation which uses this invention composition as an active ingredient is shown more concretely, this invention is not limited to these.

  In the following formulation examples, “parts” means parts by weight.

[Formulation Example 1] Wetting Agent Compound No. 11 10 parts Compound No. mu 10 parts Pyrophyllite 76 parts Solpol 5039 2 parts (mixture of nonionic surfactant and anionic surfactant: Toho Chemical Co., Ltd. trade name)
Carplex # 80D 2 parts (Synthetic hydrous silicic acid: Shionogi & Co., Ltd. trade name)
The above is uniformly mixed and ground to obtain a wettable powder.

[Composition Example 2] Emulsifiable concentrate
Compound No. 13 3 parts Compound No. nr 2 parts xylene 75 parts N-methylpyrrolidone 15 parts Solpol 2680 5 parts (mixture of nonionic surfactant and anionic surfactant: Toho Chemical Co., Ltd. trade name)
The above is uniformly mixed to obtain an emulsion.

[Composition Example 3] Suspension concentrate
Compound No. 14 15 parts Compound No. 14 no 10 parts Agrisol S-710 10 parts (Nonionic surfactant: trade name of Kao Corporation)
Lnox 1000C 0.5 part (anionic surfactant: Toho Chemical Co., Ltd. trade name)
Xanthan gum 0.2 parts Water 64.3 parts After uniformly mixing the above, wet pulverize to make a suspension.

[Formulation 4] Granule wettable powder (water dispersible granule)
Compound No. 15 40 parts Compound No. 15 ny 35 parts Hytenol NE-15 5 parts (anionic surfactant: Daiichi Kogyo Seiyaku Co., Ltd. trade name)
Vanillex N 10 parts (anionic surfactant: Nippon Paper Industries Co., Ltd. trade name)
Carplex # 80D 10 parts (Synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd. trade name)
After uniformly mixing and pulverizing the above, a small amount of water is added, stirred and mixed, granulated with an extrusion granulator, and dried to obtain a granulated wettable powder.

[Formulation Example 5] Granule
Compound No. 16 3 parts Compound No. nx 2 parts bentonite 50 parts talc 45 parts After uniformly mixing and pulverizing the above, a small amount of water is added, stirred and mixed, granulated with an extrusion granulator, and dried to form granules.

[Formulation 6] dustable powder
Compound No. 17 2 parts Compound No. nb 1 part Carplex # 80D 0.5 part (white carbon: Shionogi & Co., Ltd. trade name)
Kaolinite 95 parts Diisopropyl phosphate 1.5 parts or more uniformly mixed and pulverized to obtain a powder.

  In use, the above wettable powder, emulsion, flowable powder and granular wettable powder are diluted 50 to 20000 times with water and sprayed so that the active ingredient is 0.005 to 50 kg per hectare (ha).

[Test example]
Next, in order to clarify the usefulness of the present invention, it will be specifically described in the following efficacy test examples, but the present invention is not limited to these.

[Test Example 1] Efficacy test against peach aphid The compounds listed in Table 1 and the compounds listed in Table 3 were each made into 10% emulsion (25% wettable powder depending on the compound). A pharmaceutical solution having a predetermined concentration was prepared by diluting the formulation with water containing a spreading agent. Next, kanban leaves (about 5 mm × 5 mm) were made and placed in a petri dish, and then 20 adult peach aphids per leaf piece were inoculated. The prepared test leaf pieces were each sprayed with 5 ml of a chemical solution of a predetermined concentration, air-dried, capped, and stored in a thermostatic chamber at 25 ° C. The number of dead insects after 4 days was investigated, and the dead insect rate was calculated from the following formula. The test was conducted in a two-ward system. The results are shown in Table 6.

Mortality (%) = dead insects / test insects x 100
The synergy was calculated from the mortality rate for each chemical concentration using the Colby method (Colby SR 1976, Weeds 15, 20-22). The calculation method is as follows.

E = X + Y-XY / 100
X: observed value of agent A at x concentration (death rate)
Y: Observed value of B agent at y concentration (death rate)
E: Expected death rate during mixing treatment of agent A and agent B If the obtained result is larger than the expected value, the synergistic effect, if the expected value is larger than the observed value, the antagonism, the observed value If the expected value is the same, it is analyzed as an additive effect. The combinations showing synergistic effects are shown below.
[Table 6]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 1 50 30
Compound ny 0.5 42
Compound os 0.5 50
Compound qq 0.5 33
Compound rj 0.5 21
Compound sd 1.0 53
Compound su 1.0 56
Compound qb 1.0 51
Compound rk 1.0 44
Compound sr 1.0 53
Compound tw 5.0 42
Compound No.1 + Compound ny 50 + 0.5 100
Compound No.1 + Compound os 50 + 0.5 96
Compound No.1 + Compound qq 50 + 0.5 99
Compound No.1 + Compound rj 50 + 0.5 82
Compound No.1 + Compound sd 50 + 1.0 73
Compound No.1 + Compound su 50 + 1.0 77
Compound No.1 + Compound qb 50 + 1.0 88
Compound No.1 + Compound rk 50 + 1.0 100
Compound No.1 + Compound sr 50 + 1.0 83
Compound No.1 + Compound tw 50 + 5.0 62
Compound No. 4 50 34
Compound No. 4 + Compound ny 50 + 0.5 73
Compound No. 4 + Compound os 50 + 0.5 71
Compound No.4 + Compound qq 50 + 0.5 98
Compound No.4 + Compound rj 50 + 0.5 77
Compound No.4 + Compound sd 50 + 1.0 80
Compound No.4 + Compound su 50 + 1.0 95
Compound No.4 + Compound qb 50 + 1.0 76
Compound No.4 + Compound rk 50 + 1.0 82
Compound No.4 + Compound sr 50 + 1.0 84
Compound No.4 + Compound tw 50 + 5.0 65
Compound No. 5 50 49
Compound No.5 + Compound ny 50 + 0.5 75
Compound No. 5 + Compound os 50 + 0.5 76
Compound No.5 + Compound qq 50 + 0.5 83
Compound No.5 + Compound rj 50 + 0.5 69
Compound No.5 + Compound sd 50 + 1.0 78
Compound No.5 + Compound su 50 + 1.0 92
Compound No.5 + Compound qb 50 + 1.0 94
Compound No.5 + Compound rk 50 + 1.0 83
Compound No.5 + Compound sr 50 + 1.0 78
Compound No.5 + Compound tw 50 + 5.0 72
Compound No. 9 50 43
Compound No. 9 + Compound ny 50 + 0.5 83
Compound No. 9 + Compound os 50 + 0.5 76
Compound No. 9 + Compound qq 50 + 0.5 73
Compound No. 9 + Compound rj 50 + 0.5 79
Compound No. 9 + Compound sd 50 + 1.0 88
Compound No. 9 + Compound su 50 + 1.0 100
Compound No. 9 + Compound qb 50 + 1.0 88
Compound No. 9 + Compound rk 50 + 1.0 81
Compound No. 9 + Compound sr 50 + 1.0 75
Compound No. 9 + Compound tw 50 + 5.0 68
Compound No. 20 50 42
Compound No. 20 + Compound ny 50 + 0.5 75
Compound No. 20 + Compound os 50 + 0.5 83
Compound No. 20 + Compound qq 50 + 0.5 92
Compound No. 20 + Compound rj 50 + 0.5 75
Compound No. 20 + Compound sd 50 + 1.0 82
Compound No. 20 + Compound su 50 + 1.0 100
Compound No. 20 + Compound qb 50 + 1.0 85
Compound No. 20 + Compound rk 50 + 1.0 84
Compound No. 20 + Compound sr 50 + 1.0 95
Compound No. 20 + Compound tw 50 + 5.0 70
Compound No. 33 100 20
Compound No. 33 + Compound ny 100 + 0.5 58
Compound No. 33 + Compound os 100 + 0.5 63
Compound No.33 + Compound qq 100 + 0.5 83
Compound No. 33 + Compound rj 100 + 0.5 55
Compound No. 33 + Compound sd 100 + 1.0 67
Compound No. 33 + Compound su 100 + 1.0 82
Compound No.33 + Compound qb 100 + 1.0 75
Compound No.33 + Compound rk 100 + 1.0 62
Compound No.33 + Compound sr 100 + 1.0 68
Compound No.33 + Compound tw 50 + 5.0 58
Compound No. 44 100 56
Compound No. 44 + Compound ny 100 + 0.5 78
Compound No. 44 + Compound os 100 + 0.5 80
Compound No.44 + Compound qq 100 + 0.5 83
Compound No.44 + Compound rj 100 + 0.5 71
Compound No.44 + Compound sd 100 + 1.0 89
Compound No.44 + Compound su 100 + 1.0 82
Compound No.44 + Compound qb 100 + 1.0 100
Compound No.44 + Compound rk 100 + 1.0 93
Compound No.44 + Compound sr 100 + 1.0 99
Compound No.44 + Compound tw 50 + 5.0 78
Compound No. 46 100 60
Compound No. 46 + Compound ny 100 + 0.5 79
Compound No. 46 + Compound os 100 + 0.5 83
Compound No. 46 + Compound qq 100 + 0.5 85
Compound No.46 + Compound rj 100 + 0.5 70
Compound No. 46+ Compound sd 100 + 1.0 93
Compound No. 46 + Compound su 100 + 1.0 100
Compound No. 46+ Compound qb 100 + 1.0 97
Compound No. 46+ Compound rk 100 + 1.0 91
Compound No. 46 + Compound sr 100 + 1.0 85
Compound No.46 + Compound tw 50 + 5.0 92
Compound No. 53 50 54
Compound No. 53 + Compound ny 50 + 0.5 77
Compound No. 53 + Compound os 50 + 0.5 89
Compound No. 53 + Compound qq 50 + 0.5 77
Compound No. 53 + Compound rj 50 + 0.5 77
Compound No. 53 + Compound sd 50 + 1.0 89
Compound No. 53 + Compound su 50 + 1.0 98
Compound No. 53 + Compound qb 50 + 1.0 86
Compound No. 53 + Compound rk 50 + 1.0 76
Compound No. 53 + Compound sr 50 + 1.0 84
Compound No. 53 + Compound tw 50 + 5.0 75
Compound No. 55 50 48
Compound No. 55 + Compound ny 50 + 0.5 74
Compound No. 55 + Compound os 50 + 0.5 77
Compound No. 55 + Compound qq 50 + 0.5 88
Compound No. 55 + Compound rj 50 + 0.5 64
Compound No. 55 + Compound sd 50 + 1.0 89
Compound No. 55 + Compound su 50 + 1.0 92
Compound No. 55 + Compound qb 50 + 1.0 94
Compound No. 55 + Compound rk 50 + 1.0 91
Compound No.55 + Compound sr 50 + 1.0 87
Compound No.55 + Compound tw 50 + 5.0 74
Compound No. 47 50 55
Compound No. 47 + Compound ny 50 + 0.5 82
Compound No. 47 + Compound os 50 + 0.5 88
Compound No. 47 + Compound qq 50 + 0.5 93
Compound No. 47 + Compound rj 50 + 0.5 81
Compound No. 47 + Compound sd 50 + 1.0 87
Compound No. 47 + Compound su 50 + 1.0 91
Compound No. 47 + Compound qb 50 + 1.0 99
Compound No. 47 + Compound rk 50 + 1.0 78
Compound No. 47 + Compound sr 50 + 1.0 80
Compound No. 47 + Compound tw 50 + 5.0 82
Compound No. 50 50 38
Compound No. 50 + Compound ny 50 + 0.5 70
Compound No. 50 + Compound os 50 + 0.5 94
Compound No. 50 + Compound qq 50 + 0.5 71
Compound No. 50 + Compound rj 50 + 0.5 74
Compound No. 50 + Compound sd 50 + 1.0 84
Compound No. 50 + Compound su 50 + 1.0 83
Compound No. 50 + Compound qb 50 + 1.0 89
Compound No. 50 + Compound rk 50 + 1.0 72
Compound No. 50 + Compound sr 50 + 1.0 75
Compound No.50 + Compound tw 50 + 5.0 83
Compound No. 51 50 38
Compound No. 51 + Compound ny 50 + 0.5 100
Compound No. 51 + Compound os 50 + 0.5 100
Compound No. 51 + Compound qq 50 + 0.5 97
Compound No. 51 + Compound rj 50 + 0.5 73
Compound No. 51 + Compound sd 50 + 1.0 89
Compound No.51 + Compound su 50 + 1.0 91
Compound No. 51 + Compound qb 50 + 1.0 93
Compound No. 51 + Compound rk 50 + 1.0 82
Compound No. 51 + Compound sr 50 + 1.0 94
Compound No. 51 + Compound tw 50 + 5.0 91
―――――――――――――――――――――――――――――
Test Example 2 Efficacy Test for Tobacco Whitefly (B Biotype) Each of the compounds listed in Table 1 and the compounds listed in Table 3 was 10% emulsion (25% water depending on the compound). The drug was diluted with water containing a spreading agent to prepare a drug solution having a predetermined concentration. Next, kidney beans (about 5 mm × 5 mm) were made and placed in a petri dish, and then 20 tobacco whitefly adults per leaf piece were inoculated. The prepared test leaf pieces were each sprayed with 5 ml of a chemical solution of a predetermined concentration, air-dried, capped, and stored in a thermostatic chamber at 25 ° C. The number of dead insects after 4 days was investigated, and the dead insect rate was calculated from the following formula. The test was conducted in a two-ward system. The results are shown in Table 7.

Mortality (%) = dead insects / test insects x 100
The synergy was calculated from the mortality rate for each chemical concentration using the Colby method (Colby SR 1976, Weeds 15, 20-22). The calculation method is as follows.

E = X + Y-XY / 100
X: observed value of agent A at x concentration (death rate)
Y: Observed value of B agent at y concentration (death rate)
E: Expected death rate during mixing treatment of agent A and agent B If the obtained result is larger than the expected value, the synergistic effect, if the expected value is larger than the observed value, the antagonism, the observed value If the expected value is the same, it is analyzed as an additive effect. The combinations showing synergistic effects are shown below.
[Table 7]
―――――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――――
Compound No. 1 50 47
Compound rd 100 10
Compound su 10 65
Compound nr 3 55
Compound sg 0.01 60
Compound sd 50 35
Compound oi 500 50
Compound oo 100 23
Compound oz 100 5
Compound pw 20 25
Compound td 1000 34
Compound qs 100 5
Compound te 10 10
Compound st 100 5
Compound tf 100 5
Compound pc 50 10
Compound mr 10 5
Compound qo 50 10
Compound ny 5 55
Compound on 10 5
Compound pp 100 10
Compound sr 10 55
Compound pb 100 10
Compound th 100 10
Compound rg 100 10
Compound rj 10 30
Compound sf 100 5
Compound ti 50 5
Compound sx 10 35
Compound mn 10 10
Compound os 5 50
Compound No.1 + Compound rd 50 + 100 60
Compound No.1 + Compound su 50 + 10 85
Compound No.1 + Compound nr 50 + 3 80
Compound No.1 + Compound sg 50 + 0.01 85
Compound No.1 + Compound sd 50 + 50 95
Compound No.1 + Compound oi 50 + 500 85
Compound No.1 + Compound oo 50 + 100 63
Compound No.1 + Compound oz 50 + 100 65
Compound No.1 + Compound pw 50 + 20 70
Compound No.1 + Compound td 50 + 1000 70
Compound No.1 + Compound qs 50 + 100 55
Compound No.1 + Compound te 50 + 10 55
Compound No.1 + Compound st 50 + 100 65
Compound No.1 + Compound tf 50 + 100 70
Compound No.1 + Compound pc 50 + 50 78
Compound No.1 + Compound mr 50 + 10 68
Compound No.1 + Compound qo 50 + 50 55
Compound No.1 + Compound ny 50 + 5 80
Compound No.1 + Compound on 50 + 10 70
Compound No.1 + Compound pp 50 + 100 60
Compound No.1 + Compound sr 50 + 10 85
Compound No.1 + Compound pb 50 + 100 68
Compound No.1 + Compound th 50 + 100 78
Compound No.1 + Compound rg 50 + 100 60
Compound No.1 + Compound rj 50 + 10 75
Compound No.1 + Compound sf 50 + 100 55
Compound No.1 + Compound ti 50 + 50 58
Compound No.1 + Compound sx 50 + 10 78
Compound No.1 + Compound mn 50 + 10 80
Compound No.1 + Compound os 50 + 5 80
Compound No. 4 50 52
Compound No.4 + Compound rd 50 + 100 65
Compound No.4 + Compound su 50 + 10 90
Compound No. 4+ Compound nr 50 + 3 85
Compound No.4 + Compound sg 50 + 0.01 85
Compound No.4 + Compound sd 50 + 50 75
Compound No.4 + Compound oi 50 + 500 85
Compound No.4 + Compound oo 50 + 100 70
Compound No.4 + Compound oz 50 + 100 65
Compound No.4 + Compound pw 50 + 20 75
Compound No.4 + Compound td 50 + 1000 75
Compound No.4 + Compound qs 50 + 100 65
Compound No.4 + Compound te 50 + 10 70
Compound No.4 + Compound st 50 + 100 60
Compound No.4 + Compound tf 50 + 100 60
Compound No.4 + Compound pc 50 + 50 75
Compound No. 4+ Compound mr 50 + 10 65
Compound No.4 + Compound qo 50 + 50 60
Compound No. 4+ Compound ny 50 + 5 85
Compound No.4 + Compound on 50 + 10 70
Compound No.4 + Compound pp 50 + 100 70
Compound No.4 + Compound sr 50 + 10 90
Compound No.4 + Compound pb 50 + 100 65
Compound No. 4 + Compound th 50 + 100 68
Compound No.4 + Compound rg 50 + 100 70
Compound No.4 + Compound rj 50 + 10 73
Compound No.4 + Compound sf 50 + 100 65
Compound No.4 + Compound ti 50 + 50 58
Compound No.4 + Compound sx 50 + 10 73
Compound No.4 + Compound mn 50 + 10 78
Compound No.4 + Compound os 50 + 5 83
Compound No. 5 50 52
Compound No.5 + Compound rd 50 + 100 58
Compound No.5 + Compound su 50 + 10 83
Compound No. 5+ Compound nr 50 + 3 80
Compound No.5 + Compound sg 50 + 0.01 80
Compound No.5 + Compound sd 50 + 50 63
Compound No. 5 + Compound oi 50 + 500 75
Compound No.5 + Compound oo 50 + 100 68
Compound No.5 + Compound oz 50 + 100 68
Compound No.5 + Compound pw 50 + 20 63
Compound No.5 + Compound td 50 + 1000 70
Compound No.5 + Compound qs 50 + 100 60
Compound No. 5+ Compound te 50 + 10 55
Compound No. 5 + Compound st 50 + 100 58
Compound No.5 + Compound tf 50 + 100 58
Compound No.5 + Compound pc 50 + 50 63
Compound No. 5+ Compound mr 50 + 10 58
Compound No.5 + Compound qo 50 + 50 68
Compound No. 5+ Compound ny 50 + 5 88
Compound No. 5+ Compound on 50 + 10 90
Compound No.5 + Compound pp 50 + 100 78
Compound No.5 + Compound sr 50 + 10 78
Compound No.5 + Compound pb 50 + 100 60
Compound No. 5 + Compound th 50 + 100 60
Compound No. 5+ Compound rg 50 + 100 58
Compound No. 5+ Compound rj 50 + 10 68
Compound No.5 + Compound sf 50 + 100 58
Compound No. 5 + Compound ti 50 + 50 50
Compound No.5 + Compound sx 50 + 10 78
Compound No. 5 + Compound mn 50 + 10 63
Compound No.5 + Compound os 50 + 5 78
Compound No. 9 50 45
Compound No. 9 + Compound rd 50 + 100 60
Compound No. 9+ Compound su 50 + 10 93
Compound No. 9+ Compound nr 50 + 3 83
Compound No. 9 + Compound sg 50 + 0.01 83
Compound No. 9+ Compound sd 50 + 50 73
Compound No. 9 + Compound oi 50 + 500 78
Compound No. 9 + Compound oo 50 + 100 68
Compound No. 9 + Compound oz 50 + 100 55
Compound No. 9+ Compound pw 50 + 20 68
Compound No. 9+ Compound td 50 + 1000 73
Compound No. 9 + Compound qs 50 + 100 60
Compound No. 9+ Compound te 50 + 10 58
Compound No. 9 + Compound st 50 + 100 60
Compound No. 9+ Compound tf 50 + 100 73
Compound No. 9 + Compound pc 50 + 50 75
Compound No. 9+ Compound mr 50 + 10 60
Compound No. 9+ Compound qo 50 + 50 68
Compound No. 9+ Compound ny 50 + 5 85
Compound No. 9 + Compound on 50 + 10 58
Compound No. 9 + Compound pp 50 + 100 73
Compound No. 9+ Compound sr 50 + 10 85
Compound No. 9+ Compound pb 50 + 100 63
Compound No. 9 + Compound th 50 + 100 68
Compound No. 9+ Compound rg 50 + 100 68
Compound No. 9+ Compound rj 50 + 10 73
Compound No. 9 + Compound sf 50 + 10 60
Compound No. 9 + Compound ti 50 + 50 58
Compound No. 9 + Compound sx 50 + 10 78
Compound No. 9 + Compound mn 50 + 10 68
Compound No. 9+ Compound os 50 + 5 85
Compound No. 20 50 48
Compound No. 20 + Compound rd 50 + 100 68
Compound No. 20 + Compound su 50 + 10 90
Compound No. 20+ Compound nr 50 + 3 88
Compound No. 20 + Compound sg 50 + 0.01 88
Compound No. 20 + Compound sd 50 + 50 75
Compound No. 20 + Compound oi 50 + 500 83
Compound No. 20 + Compound oo 50 + 100 90
Compound No. 20 + Compound oz 50 + 100 60
Compound No. 20 + Compound pw 50 + 20 73
Compound No. 20 + Compound td 50 + 1000 85
Compound No. 20 + Compound qs 50 + 100 65
Compound No. 20 + Compound te 50 + 10 68
Compound No. 20 + Compound st 50 + 100 68
Compound No. 20 + Compound tf 50 + 100 70
Compound No. 20 + Compound pc 50 + 50 63
Compound No. 20+ Compound mr 50 + 10 63
Compound No. 20+ Compound qo 50 + 50 60
Compound No. 20+ Compound ny 50 + 5 88
Compound No. 20 + Compound on 50 + 10 65
Compound No. 20 + Compound pp 50 + 100 63
Compound No. 20 + Compound sr 50 + 10 80
Compound No. 20 + Compound pb 50 + 100 70
Compound No. 20 + Compound th 50 + 100 65
Compound No. 20 + Compound rg 50 + 100 73
Compound No. 20+ Compound rj 50 + 10 68
Compound No. 20 + Compound sf 50 + 100 65
Compound No. 20 + Compound ti 50 + 50 68
Compound No. 20 + Compound sx 50 + 10 78
Compound No. 20+ Compound mn 50 + 10 78
Compound No. 20+ Compound os 50 + 5 95
Compound No. 33 50 30
Compound No. 33 + Compound rd 50 + 100 50
Compound No. 33 + Compound su 50 + 10 80
Compound No. 33+ Compound nr 50 + 3 75
Compound No. 33 + Compound sg 50 + 0.01 80
Compound No. 33 + Compound sd 50 + 50 75
Compound No. 33 + Compound oi 50 + 500 65
Compound No. 33 + Compound oo 50 + 100 63
Compound No. 33 + Compound oz 50 + 100 48
Compound No. 33+ Compound pw 50 + 20 53
Compound No. 33 + Compound td 50 + 1000 83
Compound No. 33+ Compound qs 50 + 100 48
Compound No. 33 + Compound te 50 + 10 48
Compound No. 33 + Compound st 50 + 100 45
Compound No. 33+ Compound tf 50 + 100 53
Compound No. 33 + Compound pc 50 + 50 45
Compound No. 33+ Compound mr 50 + 10 48
Compound No. 33+ Compound qo 50 + 50 55
Compound No. 33+ Compound ny 50 + 5 70
Compound No. 33+ Compound on 50 + 1 75
Compound No. 33 + Compound pp 50 + 100 38
Compound No. 33+ Compound sr 50 + 10 78
Compound No. 33+ Compound pb 50 + 100 55
Compound No. 33 + Compound th 50 + 100 45
Compound No. 33+ Compound rg 50 + 100 43
Compound No. 33+ Compound rj 50 + 10 68
Compound No. 33 + Compound sf 50 + 100 65
Compound No. 33+ Compound ti 50 + 5 78
Compound No. 33 + Compound sx 50 + 10 65
Compound No. 33 + Compound mn 50 + 10 65
Compound No. 33+ Compound os 50 + 5 78
Compound No. 44 10 52
Compound No.44 + Compound rd 10 + 100 63
Compound No. 44+ Compound su 10 + 10 93
Compound No. 44+ Compound nr 10 + 3 85
Compound No.44 + Compound sg 10 + 0.01 95
Compound No.44 + Compound sd 10 + 50 78
Compound No. 44 + Compound oi 10 + 500 88
Compound No. 44 + Compound oo 10 + 100 100
Compound No. 44 + Compound oz 10 + 100 68
Compound No.44 + Compound pw 10 + 20 78
Compound No.44 + Compound td 10 + 1000 78
Compound No.44 + Compound qs 10 + 100 68
Compound No. 44 + Compound te 10 + 10 70
Compound No. 44 + Compound st 10 + 100 74
Compound No.44 + Compound tf 10 + 100 60
Compound No. 44 + Compound pc 10 + 50 68
Compound No. 44+ Compound mr 10 + 10 88
Compound No.44 + Compound qo 10 + 50 80
Compound No. 44+ Compound ny 10 + 5 85
Compound No. 44 + Compound on 10 + 10 85
Compound No.44 + Compound pp 10 + 100 65
Compound No.44 + Compound sr 10 + 10 80
Compound No. 44+ Compound pb 10 + 100 70
Compound No. 44 + Compound th 10 + 100 74
Compound No. 44 + Compound rg 10 + 100 70
Compound No. 44+ Compound rj 10 + 10 75
Compound No.44 + Compound sf 10 + 100 60
Compound No. 44+ Compound ti 10 + 50 85
Compound No.44 + Compound sx 10 + 10 75
Compound No. 44 + Compound mn 10 + 10 65
Compound No. 44+ Compound os 10 + 5 90
Compound No. 46 10 48
Compound No. 46 + Compound rd 10 + 100 75
Compound No. 46 + Compound su 10 + 10 100
Compound No. 46+ Compound nr 10 + 3 88
Compound No. 46 + Compound sg 10 + 0.01 85
Compound No.46 + Compound sd 10 + 50 78
Compound No. 46 + Compound oi 10 + 500 78
Compound No. 46 + Compound oo 10 + 100 75
Compound No. 46 + Compound oz 10 + 100 75
Compound No. 46+ Compound pw 10 + 20 68
Compound No. 46+ Compound td 10 + 1000 73
Compound No. 46+ Compound qs 10 + 100 65
Compound No. 46 + Compound te 10 + 10 58
Compound No. 46 + Compound st 10 + 100 58
Compound No. 46 + Compound tf 10 + 100 60
Compound No. 46 + Compound pc 10 + 50 68
Compound No. 46+ Compound mr 10 + 10 58
Compound No. 46+ Compound qo 10 + 50 63
Compound No. 46+ Compound ny 10 + 5 80
Compound No. 46 + Compound on 10 + 10 60
Compound No.46 + Compound pp 10 + 100 68
Compound No. 46 + Compound sr 10 + 10 85
Compound No. 46+ Compound pb 10 + 100 63
Compound No. 46 + Compound th 10 + 100 80
Compound No. 46+ Compound rg 10 + 100 85
Compound No. 46+ Compound rj 10 + 10 75
Compound No. 46 + Compound sf 10 + 100 65
Compound No. 46+ Compound ti 10 + 50 88
Compound No.46 + Compound sx 10 + 10 73
Compound No. 46+ Compound mn 10 + 10 78
Compound No. 46+ Compound os 10 + 5 85
Compound No. 47 50 33
Compound No. 47 + Compound rd 50 + 100 70
Compound No. 47+ Compound su 50 + 10 85
Compound No. 47+ Compound nr 50 + 3 78
Compound No. 47 + Compound sg 50 + 0.01 85
Compound No. 47+ Compound sd 50 + 50 65
Compound No. 47 + Compound oi 50 + 500 80
Compound No. 47 + Compound oo 50 + 100 55
Compound No. 47 + Compound oz 50 + 100 55
Compound No. 47+ Compound pw 50 + 20 68
Compound No. 47+ Compound td 50 + 1000 78
Compound No. 47+ Compound qs 50 + 100 90
Compound No. 47+ Compound te 50 + 10 95
Compound No. 47 + Compound st 50 + 100 68
Compound No. 47 + Compound tf 50 + 100 75
Compound No. 47 + Compound pc 50 + 50 75
Compound No. 47+ Compound mr 50 + 10 83
Compound No. 47+ Compound qo 50 + 50 88
Compound No. 47+ Compound ny 50 + 5 75
Compound No. 47+ Compound on 50 + 10 58
Compound No. 47 + Compound pp 50 + 100 70
Compound No. 47+ Compound sr 50 + 10 88
Compound No. 47+ Compound pb 50 + 100 100
Compound No. 47 + Compound th 50 + 100 58
Compound No. 47+ Compound rg 50 + 100 60
Compound No. 47+ Compound rj 50 + 10 78
Compound No. 47 + Compound sf 50 + 100 80
Compound No. 47 + Compound ti 50 + 50 75
Compound No. 47 + Compound sx 50 + 10 68
Compound No. 47 + Compound mn 50 + 10 60
Compound No. 47+ Compound os 50 + 5 75
Compound No. 50 50 45
Compound No. 50 + Compound rd 50 + 100 88
Compound No. 50+ Compound su 50 + 10 88
Compound No. 50+ Compound nr 50 + 3 80
Compound No. 50 + Compound sg 50 + 0.01 85
Compound No. 50 + Compound sd 50 + 50 68
Compound No. 50+ Compound oi 50 + 500 88
Compound No. 50 + Compound oo 50 + 100 65
Compound No. 50+ Compound oz 50 + 100 88
Compound No. 50 + Compound pw 50 + 20 75
Compound No. 50 + Compound td 50 + 1000 75
Compound No. 50 + Compound qs 50 + 100 65
Compound No. 50 + Compound te 50 + 10 83
Compound No. 50 + Compound st 50 + 100 80
Compound No. 50 + Compound tf 50 + 100 70
Compound No. 50 + Compound pc 50 + 50 65
Compound No. 50+ Compound mr 50 + 10 60
Compound No. 50+ Compound qo 50 + 50 65
Compound No. 50+ Compound ny 50 + 5 78
Compound No. 50+ Compound on 50 + 10 88
Compound No. 50 + Compound pp 50 + 100 95
Compound No. 50 + Compound sr 50 + 10 98
Compound No. 50+ Compound pb 50 + 100 65
Compound No. 50 + Compound th 50 + 100 55
Compound No. 50+ Compound rg 50 + 100 70
Compound No. 50+ Compound rj 50 + 10 70
Compound No. 50 + Compound sf 50 + 100 58
Compound No. 50 + Compound ti 50 + 50 55
Compound No. 50 + Compound sx 50 + 10 75
Compound No. 50+ Compound mn 50 + 10 70
Compound No. 50+ Compound os 50 + 5 80
Compound No. 51 50 53
Compound No. 51 + Compound rd 50 + 100 68
Compound No. 51 + Compound su 50 + 10 90
Compound No. 51+ Compound nr 50 + 3 83
Compound No. 51 + Compound sg 50 + 0.01 88
Compound No. 51 + Compound sd 50 + 50 78
Compound No. 51 + Compound oi 50 + 500 78
Compound No. 51 + Compound oo 50 + 100 68
Compound No. 51 + Compound oz 50 + 100 70
Compound No. 51+ Compound pw 50 + 20 68
Compound No. 51 + Compound td 50 + 1000 75
Compound No. 51 + Compound qs 50 + 100 60
Compound No. 51 + Compound te 50 + 10 83
Compound No. 51 + Compound st 50 + 100 80
Compound No. 51 + Compound tf 50 + 100 85
Compound No. 51 + Compound pc 50 + 50 68
Compound No. 51+ Compound mr 50 + 10 63
Compound No. 51 + Compound qo 50 + 50 65
Compound No. 51+ Compound ny 50 + 5 85
Compound No. 51 + Compound on 50 + 10 80
Compound No.51 + Compound pp 50 + 100 85
Compound No. 51 + Compound sr 50 + 10 100
Compound No. 51+ Compound pb 50 + 100 68
Compound No. 51 + Compound th 50 + 100 68
Compound No. 51 + Compound rg 50 + 100 75
Compound No. 51+ Compound rj 50 + 10 83
Compound No. 51 + Compound sf 50 + 100 70
Compound No. 51 + Compound ti 50 + 50 68
Compound No. 51 + Compound sx 50 + 10 78
Compound No. 51 + Compound mn 50 + 10 78
Compound No. 51 + Compound os 50 + 5 83
Compound No. 53 10 53
Compound No. 53 + Compound rd 10 + 100 65
Compound No. 53 + Compound su 10 + 10 98
Compound No. 53+ Compound nr 10 + 3 85
Compound No. 53 + Compound sg 10 + 0.01 100
Compound No. 53 + Compound sd 10 + 50 80
Compound No. 53 + Compound oi 10 + 500 88
Compound No. 53 + Compound oo 10 + 100 78
Compound No. 53 + Compound oz 10 + 100 68
Compound No. 53+ Compound pw 10 + 20 75
Compound No. 53 + Compound td 10 + 1000 78
Compound No. 53 + Compound qs 10 + 100 60
Compound No. 53 + Compound te 10 + 10 68
Compound No. 53 + Compound st 10 + 100 75
Compound No. 53 + Compound tf 10 + 100 70
Compound No. 53 + Compound pc 10 + 50 78
Compound No. 53+ Compound mr 10 + 10 65
Compound No. 53+ Compound qo 10 + 50 70
Compound No. 53 + Compound ny 10 + 5 83
Compound No. 53+ Compound on 10 + 10 78
Compound No. 53 + Compound pp 10 + 100 68
Compound No. 53 + Compound sr 10 + 10 78
Compound No. 53+ Compound pb 10 + 10 65
Compound No. 53 + Compound th 10 + 100 68
Compound No. 53 + Compound rg 10 + 100 63
Compound No. 53+ Compound rj 10 + 10 78
Compound No. 53 + Compound sf 10 + 100 68
Compound No. 53 + Compound ti 10 + 50 85
Compound No. 53 + Compound sx 10 + 10 75
Compound No. 53 + Compound mn 10 + 10 70
Compound No. 53 + Compound os 10 + 5 88
Compound No. 55 50 58
Compound No. 55+ Compound rd 50 + 100 70
Compound No. 55+ Compound su 50 + 10 88
Compound No. 55+ Compound nr 50 + 3 95
Compound No. 55 + Compound sg 50 + 0.01 90
Compound No. 55+ Compound sd 50 + 50 85
Compound No. 55 + Compound oi 50 + 500 100
Compound No. 55 + Compound oo 50 + 100 78
Compound No. 55 + Compound oz 50 + 100 78
Compound No. 55+ Compound pw 50 + 20 78
Compound No. 55+ Compound td 50 + 1000 78
Compound No. 55+ Compound qs 50 + 100 68
Compound No. 55+ Compound te 50 + 10 85
Compound No. 55 + Compound st 50 + 100 78
Compound No. 55 + Compound tf 50 + 100 75
Compound No. 55 + Compound pc 50 + 50 70
Compound No. 55+ Compound mr 50 + 10 85
Compound No. 55+ Compound qo 50 + 50 88
Compound No. 55+ Compound ny 50 + 5 85
Compound No. 55+ Compound on 50 + 10 78
Compound No. 55 + Compound pp 50 + 100 78
Compound No. 55+ Compound sr 50 + 10 90
Compound No. 55+ Compound pb 50 + 100 100
Compound No. 55 + Compound th 50 + 100 78
Compound No. 55+ Compound rg 50 + 100 85
Compound No. 55+ Compound rj 50 + 10 88
Compound No. 55 + Compound sf 50 + 100 75
Compound No. 55 + Compound ti 50 + 50 85
Compound No.55 + Compound sx 50 + 10 78
Compound No. 55+ Compound mn 50 + 10 85
Compound No. 55+ Compound os 50 + 5 85
―――――――――――――――――――――――――――――――
[Test Example 3] Efficacy test against female adult spider mite Each of the compounds described in Table 1 and the compounds described in Table 3 was added to a 10% emulsion (25% wettable powder depending on the compound). A pharmaceutical solution having a predetermined concentration was prepared by diluting the formulation with water containing a spreading agent. Next, kidney beans (about 1.5 mm x 1.5 mm) were made and placed in a petri dish, and then 10 adult nymph mite per leaf piece were inoculated. The prepared test leaf pieces were each sprayed with 5 ml of a chemical solution of a predetermined concentration, air-dried, capped, and stored in a thermostatic chamber at 25 ° C. The number of dead insects after 4 days was investigated, and the dead insect rate was calculated from the following formula. The test was conducted in a two-ward system. The results are shown in Table 8.

Mortality (%) = dead insects / test insects x 100
The synergy was calculated from the mortality rate for each chemical concentration using the Colby method (Colby SR 1976, Weeds 15, 20-22). The calculation method is as follows.

E = X + Y-XY / 100
X: observed value of agent A at x concentration (death rate)
Y: Observed value of B agent at y concentration (death rate)
E: Expected death rate during mixing treatment of agent A and agent B If the obtained result is larger than the expected value, the synergistic effect, if the expected value is larger than the observed value, the antagonism, the observed value If the expected value is the same, it is analyzed as an additive effect. The combinations showing synergistic effects are shown below.
[Table 8]
―――――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――――
Compound No. 1 1 25
Compound No. 4 1 10
Compound No. 5 1 15
Compound No. 9 1 25
Compound No. 20 1 25
Compound No. 33 1 20
Compound No. 44 1 45
Compound No. 46 1 50
Compound No. 47 1 20
Compound No. 50 1 10
Compound No. 51 1 20
Compound No. 53 1 25
Compound No. 55 1 30
Compound mu 1 55
Compound oo 1 50
Compound pn 1 65
Compound np 2 45
Compound nb 2 50
Compound nr 3 50
Compound nf 0.1 35
Compound nw 0.5 55
Compound nh 20 40
Compound mo 1 50
Compound nq 15 50
Compound nt 50 45
Compound nu 50 60
Compound tt 2 45
Compound mx 3 30
Compound No.1 + Compound mu 1 + 1 75
Compound No.1 + Compound oo 1 + 1 70
Compound No.1 + Compound pn 1 + 1 75
Compound No.1 + Compound np 1 + 2 65
Compound No.1 + Compound nb 1 + 2 65
Compound No.1 + Compound nr 1 + 3 65
Compound No.1 + Compound nf 1 + 0.1 70
Compound No.1 + Compound nw 1 + 0.5 80
Compound No.1 + Compound nh 1 + 20 90
Compound No.1 + Compound mo 1 + 1 90
Compound No.1 + Compound mq 1 + 15 95
Compound No.1 + Compound nt 1 + 50 60
Compound No.1 + Compound nu 1 + 50 65
Compound No.1 + Compound tt 1 + 2 75
Compound No.1 + Compound mx 1 + 3 50
Compound No. 4 1 10
Compound No.4 + Compound mu 1 + 1 65
Compound No.4 + Compound oo 1 + 1 80
Compound No. 4 + Compound pn 1 + 1 90
Compound No.4 + Compound np 1 + 2 95
Compound No.4 + Compound nb 1 + 2 70
Compound No.4 + Compound nr 1 + 3 65
Compound No. 4 + Compound nf 1 + 0.1 65
Compound No.4 + Compound nw 1 + 0.5 70
Compound No.4 + Compound nh 1 + 20 70
Compound No. 4 + Compound mo 1 + 1 100
Compound No.4 + Compound mq 1 + 15 95
Compound No.4 + Compound nt 1 + 50 60
Compound No.4 + Compound nu 1 + 50 65
Compound No.4 + Compound tt 1 + 2 70
Compound No.4 ＋ Compound mx 1 + 3 55
Compound No. 5 1 15
Compound No.5 + Compound mu 1 + 1 70
Compound No.5 + Compound oo 1 + 1 80
Compound No. 5 + Compound pn 1 + 1 90
Compound No.5 + Compound np 1 + 2 55
Compound No.5 + Compound nb 1 + 2 60
Compound No. 5 + Compound nr 1 + 3 65
Compound No.5 + Compound nf 1 + 0.1 75
Compound No. 5 + Compound nw 1 + 0.5 65
Compound No. 5 + Compound nh 1 + 20 55
Compound No. 5 + Compound mo 1 + 1 65
Compound No. 5 + Compound mq 1 + 15 60
Compound No.5 + Compound nt 1 + 50 55
Compound No.5 + Compound nu 1 + 50 70
Compound No. 5 + Compound tt 1 + 2 80
Compound No.5 + Compound mx 1 + 3 85
Compound No. 9 1 25
Compound No.9 + Compound mu 1 + 1 75
Compound No. 9 + Compound oo 1 + 1 75
Compound No. 9 + Compound pn 1 + 1 80
Compound No. 9 + Compound np 1 + 2 95
Compound No. 9 + Compound nb 1 + 2 70
Compound No. 9 + Compound nr 1 + 3 65
Compound No. 9 + Compound nf 1 + 0.1 55
Compound No. 9 + Compound nw 1 + 0.5 70
Compound No. 9 + Compound nh 1 + 20 65
Compound No. 9 + Compound mo 1 + 1 65
Compound No. 9 + Compound mq 1 + 15 65
Compound No. 9 + Compound nt 1 + 50 90
Compound No. 9 + Compound nu 1 + 50 75
Compound No. 9 + Compound tt 1 + 2 85
Compound No. 9 + Compound mx 1 + 3 80
Compound No. 20 1 25
Compound No. 20 + Compound mu 1 + 1 80
Compound No. 20 + Compound oo 1 + 1 75
Compound No. 20 + Compound pn 1 + 1 75
Compound No. 20 + Compound np 1 + 2 60
Compound No. 20 + Compound nb 1 + 2 65
Compound No. 20 + Compound nr 1 + 3 70
Compound No. 20 + Compound nf 1 + 0.1 80
Compound No. 20 + Compound nw 1 + 0.5 95
Compound No. 20 + Compound nh 1 + 20 90
Compound No. 20 + Compound mo 1 + 1 75
Compound No. 20 + Compound mq 1 + 15 65
Compound No. 20 + Compound nt 1 + 50 70
Compound No. 20 + Compound nu 1 + 50 75
Compound No. 20 + Compound tt 1 + 2 65
Compound No.20 + Compound mx 1 + 3 50
Compound No. 33 1 20
Compound No.33 + Compound mu 1 + 1 95
Compound No.33 + Compound oo 1 + 1 75
Compound No. 33 + Compound pn 1 + 1 75
Compound No.33 + Compound np 1 + 2 70
Compound No.33 + Compound nb 1 + 2 85
Compound No.33 + Compound nr 1 + 3 80
Compound No. 33 + Compound nf 1 + 0.1 55
Compound No.33 + Compound nw 1 + 0.5 65
Compound No.33 + Compound nh 1 + 20 55
Compound No. 33 + Compound mo 1 + 1 75
Compound No.33 + Compound mq 1 + 15 70
Compound No. 33 + Compound nt 1 + 50 60
Compound No.33 + Compound nu 1 + 50 75
Compound No.33 + Compound tt 1 + 2 60
Compound No.33 + Compound mx 1 + 3 55
Compound No. 44 1 45
Compound No.44 + Compound mu 1 + 1 90
Compound No.44 + Compound oo 1 + 1 85
Compound No. 44 + Compound pn 1 + 1 85
Compound No.44 + Compound np 1 + 2 70
Compound No.44 + Compound nb 1 + 2 75
Compound No. 44 + Compound nr 1 + 3 75
Compound No.44 + Compound nf 1 + 0.1 65
Compound No.44 + Compound nw 1 + 0.5 80
Compound No.44 + Compound nh 1 + 20 80
Compound No.44 + Compound mo 1 + 1 75
Compound No.44 + Compound mq 1 + 15 75
Compound No.44 + Compound nt 1 + 50 85
Compound No.44 + Compound nu 1 + 50 80
Compound No.44 + Compound tt 1 + 2 75
Compound No.44 + Compound mx 1 + 3 65
Compound No. 46 1 50
Compound No. 46 + Compound mu 1 + 1 80
Compound No. 46 + Compound oo 1 + 1 80
Compound No. 46 + Compound pn 1 + 1 85
Compound No. 46 + Compound np 1 + 2 75
Compound No. 46 + Compound nb 1 + 2 80
Compound No. 46+ Compound nr 1 + 3 95
Compound No. 46 + Compound nf 1 + 0.1 90
Compound No. 46 + Compound nw 1 + 0.5 85
Compound No.46 + Compound nh 1 + 20 90
Compound No. 46 + Compound mo 1 + 1 95
Compound No. 46 + Compound mq 1 + 15 80
Compound No. 46 + Compound nt 1 + 50 85
Compound No. 46 + Compound nu 1 + 50 90
Compound No. 46 + Compound tt 1 + 2 75
Compound No.46 + Compound mx 1 + 3 70
Compound No. 47 1 20
Compound No. 47 + Compound mu 1 + 1 90
Compound No. 47 + Compound oo 1 + 1 80
Compound No. 47 + Compound pn 1 + 1 75
Compound No. 47 + Compound np 1 + 2 80
Compound No. 47 + Compound nb 1 + 2 65
Compound No. 47 + Compound nr 1 + 3 60
Compound No. 47 + Compound nf 1 + 0.1 55
Compound No. 47 + Compound nw 1 + 0.5 70
Compound No. 47 + Compound nh 1 + 20 55
Compound No. 47 + Compound mo 1 + 1 65
Compound No. 47 + Compound mq 1 + 15 65
Compound No. 47 + Compound nt 1 + 50 60
Compound No. 47 + Compound nu 1 + 50 70
Compound No. 47 + Compound tt 1 + 2 60
Compound No. 47 + Compound mx 1 + 3 45
Compound No. 50 1 10
Compound No. 50 + Compound mu 1 + 1 70
Compound No. 50 + Compound oo 1 + 1 60
Compound No. 50 + Compound pn 1 + 1 70
Compound No. 50 + Compound np 1 + 2 65
Compound No. 50 + Compound nb 1 + 2 60
Compound No. 50 + Compound nr 1 + 3 70
Compound No. 50 + Compound nf 1 + 0.1 55
Compound No. 50 + Compound nw 1 + 0.5 60
Compound No. 50 + Compound nh 1 + 20 50
Compound No. 50 + Compound mo 1 + 1 55
Compound No. 50 + Compound mq 1 + 15 65
Compound No. 50 + Compound nt 1 + 50 55
Compound No. 50 + Compound nu 1 + 50 65
Compound No. 50 + Compound tt 1 + 2 70
Compound No. 50 + Compound mx 1 + 3 50
Compound No. 51 1 20
Compound No. 51 + Compound mu 1 + 1 70
Compound No. 51 + Compound oo 1 + 1 70
Compound No. 51 + Compound pn 1 + 1 75
Compound No. 51 + Compound np 1 + 2 50
Compound No. 51 + Compound nb 1 + 2 65
Compound No. 51 + Compound nr 1 + 3 65
Compound No. 51 + Compound nf 1 + 0.1 55
Compound No. 51 + Compound nw 1 + 0.5 95
Compound No. 51 + Compound nh 1 + 20 90
Compound No. 51 + Compound mo 1 + 1 75
Compound No. 51 + Compound mq 1 + 15 80
Compound No. 51 + Compound nt 1 + 50 60
Compound No. 51 + Compound nu 1 + 50 75
Compound No. 51 + Compound tt 1 + 2 95
Compound No.51 + Compound mx 1 + 3 55
Compound No. 53 1 25
Compound No. 53 + Compound mu 1 + 1 80
Compound No. 53 + Compound oo 1 + 1 95
Compound No. 53 + Compound pn 1 + 1 80
Compound No. 53 + Compound np 1 + 2 85
Compound No. 53 + Compound nb 1 + 2 65
Compound No. 53 + Compound nr 1 + 3 80
Compound No. 53 + Compound nf 1 + 0.1 85
Compound No. 53 + Compound nw 1 + 0.5 70
Compound No. 53 + Compound nh 1 + 20 65
Compound No. 53 + Compound mo 1 + 1 70
Compound No. 53 + Compound mq 1 + 15 70
Compound No. 53 + Compound nt 1 + 50 65
Compound No. 53 + Compound nu 1 + 50 75
Compound No. 53 + Compound tt 1 + 2 60
Compound No. 55 1 30
Compound No.55 + Compound mx 1 + 3 75
Compound No. 55 + Compound mu 1 + 1 75
Compound No. 55 + Compound oo 1 + 1 70
Compound No. 55 + Compound pn 1 + 1 85
Compound No. 55 + Compound np 1 + 2 90
Compound No. 55 + Compound nb 1 + 2 75
Compound No. 55 + Compound nr 1 + 3 85
Compound No. 55 + Compound nf 1 + 0.1 55
Compound No. 55 + Compound nw 1 + 0.5 75
Compound No. 55 + Compound nh 1 + 20 60
Compound No. 55 + Compound mo 1 + 1 85
Compound No. 55 + Compound mq 1 + 15 95
Compound No. 55 + Compound nt 1 + 50 75
Compound No. 55 + Compound nu 1 + 50 75
Compound No. 55 + Compound tt 1 + 2 70
Compound No. 55 + Compound mx 1 + 3 65
―――――――――――――――――――――――――――――――
[Test Example 4] Effect test on Pythium seed wilt disease Add 200 ml of water to 100 ml of Pythium fungus cultured in vermiculite medium, stir with a mixer, and add 75 ml of fungus to 1 kg of soil. Mix to adjust the contaminated soil.

  Put 60ml of contaminated soil in a plastic bag as the floor soil, adjust the compounds listed in Tables 1 and 3 and the active ingredients listed in Table 4 to the prescribed concentrations in the formulation examples, 5 ml sprayed on the soil in the bag. The mixture was stirred 30 times in a plastic bag, added to a 90 ml styrene cup, and 20 ml of water was irrigated as initial irrigation.

  The seeded rice bran (variety: Koshihikari) 3g was sown, 30ml of soil was added, a seedling sheet was applied, the seedling sheet was sprouting for 4 days, and then left in a 4 ° C constant temperature room for 3 days to promote disease. Thereafter, the seedlings were grown for 10 days.

  The soil was washed away, and the number of dead strains, growth-suppressed strains and healthy strains were measured, and the disease severity was calculated according to the following formula. The number of surveys was 100 randomly selected stocks.

Disease severity = [Σ (number of disease-causing strains by disease degree × morbidity index) / (surveyed strain × 3)] × 100
[Disease index]
0: Healthy stock
1: Growth-inhibiting strain
3: Withered strain The results are shown in Table 9.
[Table 9]
―――――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Disease severity ―――――――――――――――――――――――――――――――
Compound No. 1 100 79.2
Compound No. 4 100 82.7
Compound No. 5 100 72.3
Compound No. 9 100 75.3
Compound No. 20 100 81.3
Compound No. 33 100 80.0
Compound No. 44 100 83.7
Compound No. 46 100 78.3
Compound No. 47 100 75.3
Compound No. 50 100 86.7
Compound No. 51 100 76.3
Compound No. 53 100 87.3
Compound No. 55 100 76.3
Compound e 500 1.7
Compound No.1 + Compound e 100 + 500 1.3
Compound No.4 + Compound e 100 + 500 1.3
Compound No.5 + Compound e 100 + 500 1.3
Compound No. 9 + Compound e 100 + 500 1.7
Compound No. 20 + Compound e 100 + 500 0.7
Compound No. 33 + Compound e 100 + 500 1.7
Compound No. 44 + Compound e 100 + 500 1.7
Compound No. 46 + Compound e 100 + 500 1.3
Compound No. 47 + Compound e 100 + 500 1.3
Compound No. 50 + Compound e 100 + 500 1.7
Compound No. 51 + Compound e 100 + 500 1.3
Compound No. 53 + Compound e 100 + 500 1.3
Compound No. 55 + Compound e 100 + 500 1.7
―――――――――――――――――――――――――――――――
[Test Example 5] Effect test on Rhizoctonia seedling blight A 200 ml water was added to 100 ml of Rhizoctonia fungus cultured in vermiculite medium, and the mixture was stirred with a mixer to prepare a fungus solution. 75 ml of the fungus solution was mixed with 1 kg of soil to prepare contaminated soil.
200 ml of contaminated soil is put in a plastic bag, and the compound described in Table 1 and the compound described in Table 3 are each formulated into a 10% emulsion (or 25% wettable powder depending on the compound). Then, 5 ml was sprayed on the contaminated soil in the plastic bag after adjusting to a predetermined concentration with tap water. After stirring 30 times in a plastic bag, the soil was put into a 200 ml styrene cup, seeded with 5 soybean seeds (variety: Enrei), and grown for 14 days in a 20 ° C. greenhouse while irrigating every day.

Disease severity = [Σ (number of disease-causing strains by disease degree × morbidity index) / (surveyed strain × 3)] × 100
[Disease index]
0: Healthy stock
1: Growth-inhibiting strain
3: Withered strain The results are shown in Table 10.
[Table 10]
―――――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Disease severity ―――――――――――――――――――――――――――――――
Compound No. 1 100 91.1
Compound No. 4 100 86.7
Compound No. 5 100 86.7
Compound No. 9 100 91.1
Compound No. 20 100 84.4
Compound No. 33 100 86.7
Compound No. 44 100 91.1
Compound No. 46 100 82.2
Compound No. 47 100 91.1
Compound No. 50 100 86.7
Compound No. 51 100 84.4
Compound No. 53 100 91.1
Compound No. 55 100 84.4
Compound kk 100 4.4
Compound No.1 + Compound kk 100 + 100 4.4
Compound No.4 + Compound kk 100 + 100 4.4
Compound No.5 + Compound kk 100 + 100 4.4
Compound No. 9 + Compound kk 100 + 100 2.2
Compound No.20 + Compound kk 100 + 100 2.2
Compound No.33 + Compound kk 100 + 100 2.2
Compound No.44 + Compound kk 100 + 100 4.4
Compound No. 46 + Compound kk 100 + 100 4.4
Compound No.47 + Compound kk 100 + 100 4.4
Compound No. 50 + Compound kk 100 + 100 4.4
Compound No. 51 + Compound kk 100 + 100 4.4
Compound No. 53 + Compound kk 100 + 100 4.4
Compound No. 55 + Compound kk 100 + 100 4.4
―――――――――――――――――――――――――――――――
[Test Example 6] Efficacy test against damselfish larvae 60 g of sterile soil was placed in a petri dish (inner diameter 5.5 cm, height 6 cm), and a carrot cut into sticks was placed in the center of the petri dish. Here, 4 moth larvae were released per petri dish. One day after insect release, the compound described in Table 1 was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent to prepare a drug solution of a predetermined concentration. . 1.2 ml of this drug solution was irrigated on the surface to be uniform. After irrigation, the petri dish was placed in a constant temperature room at 25 ° C. The number of dead larvae 15 days after the treatment was investigated, and the death rate was determined from the following formula. In addition, the test was performed by 2 continuous systems. The results are shown in Table 11.

Mortality (%) = dead insects / test insects x 100
[Table 11]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 7] Efficacy test against adult worms The above-mentioned compounds shown in Table 1 were formulated into a 5% emulsion, and the preparation was diluted with water containing admix as a spreading agent. A chemical solution having a concentration was prepared. Fifteen dried soybeans were put into this chemical solution and immersed for 10 seconds. Next, the soaked soybeans were transferred to a 7 cm petri dish with filter paper and 5 per 1 petri dish and air-dried. After air-drying, 5 adult insects were released per petri dish. After the insect was released, the petri dish was placed in a constant temperature room at 25 ° C. The number of adult worms 6 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in a triple system. The results are shown in Table 12.

Mortality (%) = dead insects / test insects x 100
[Table 12]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 8] Efficacy test against 4th instar larvae of the red bearded winged mosquito The compound described in Table 1 above was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent. Thus, a chemical solution with a predetermined concentration was prepared. Wheat ears were placed in this chemical and immersed for 10 seconds. Next, the soaked ears were transferred to a 7 cm petri dish with filter paper and 3 pans per petri dish and air-dried. After air drying, 5 4th instar larvae of red bearded winged worms were released per petri dish. After the insect was released, the petri dish was placed in a constant temperature room at 25 ° C. The number of larvae killed 5 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 13.

Mortality (%) = dead insects / test insects x 100
[Table 13]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 9] Efficacy test against Akasika-kasika turtles The above-mentioned compounds listed in Table 1 were formulated into 5% emulsion, and the preparations were diluted with water containing admix as a spreading agent. A chemical solution having a concentration was prepared. A spike of dogfish was placed in this chemical solution and immersed for 10 seconds. Next, the soaked ears were transferred to a 7 cm petri dish with filter paper and 3 pans per petri dish and air-dried. After air-drying, 5 Akasujikasika-mame adults were released per petri dish. After the insect was released, the petri dish was placed in a constant temperature room at 25 ° C. The number of adult mortality 2 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 14.

Mortality (%) = dead insects / test insects x 100
[Table 14]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 10] Efficacy test against adult croton thrips The above-mentioned compounds listed in Table 1 were formulated into a 5% emulsion, and the preparation was diluted with water containing admix as a spreading agent to obtain a predetermined concentration. The chemical solution was prepared. Next, a strawberry leaf disk (3 cm in diameter) was made and placed on wet filter paper on a 7 cm diameter styrene cup. Five croton thrips adults per leaf piece were inoculated each and covered with a net cover to avoid the escape of adults. The prepared test leaf pieces were each sprayed with 2.5 ml of a chemical solution having a predetermined concentration. After spraying, the petri dish was placed in a constant temperature room at 25 ° C. The number of adult mortality 2 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 15.

Mortality (%) = dead insects / test insects x 100
[Table 15]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 11] Efficacy test against adult Aobahagoromo The compound described in Table 1 above was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent to obtain a predetermined concentration. A drug solution was prepared. Next, the branch with the new leaf of the mandarin orange was immersed in the chemical | medical solution of predetermined concentration, and it put into the waist high petri dish (diameter 12cm, height 10cm), and air-dried. After air-drying, 5 adults of Aobahagoromomo were inoculated per petri dish. After the inoculation, the petri dish was placed in a thermostatic chamber at 25 ° C. after being covered with a lid to avoid the escape of adults. The number of adult mortality 6 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 16.

Mortality (%) = dead insects / test insects x 100
[Table 16]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 12] Efficacy test against Chadokuga infancy larvae The compound described in Table 1 above was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent, and the prescribed A chemical solution having a concentration was prepared. Tea leaves were put into this chemical solution and immersed for 10 seconds. Next, the treated tea leaves were transferred to a 7 cm petri dish with filter paper and transferred 3 pieces per petri dish and air-dried. After the air drying, 5 Chadokuga larvae were released per petri dish. After the insect was released, the petri dish was housed in a constant temperature room at 25 ° C. The number of larvae killed 5 days after the treatment was investigated, and the mortality rate was determined from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 17.

Mortality (%) = dead insects / test insects x 100
[Table 17]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 13] Efficacy test against 3rd instar larvae of Tamanaginu The compound described in Table 1 above was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent. A chemical solution having a concentration was prepared. Cabbage leaves were put into this chemical solution and immersed for 10 seconds. Next, one processed cabbage leaf was transferred to a 7 cm petri dish with filter paper and dried in air. After air-drying, 5 Tamanagin uwaba 3rd instar larvae were released per petri dish. After the insect was released, the petri dish was placed in a constant temperature room at 25 ° C. The number of larvae killed 5 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 18.

Mortality (%) = dead insects / test insects x 100
[Table 18]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 14] Efficacy test against 3rd instar larvae of the Artemisia perforatum is formulated in a 5% emulsion and diluted with water containing admix as a spreading agent. A chemical solution with a predetermined concentration was prepared. Tea leaves were put into this chemical solution and immersed for 10 seconds. Next, the treated tea leaves were transferred to a 7 cm petri dish with filter paper and three per petri dish and air-dried. After air drying, 5 wormwood worms were released per petri dish. After the insect was released, the petri dish was housed in a constant temperature room at 25 ° C. . The number of larvae killed 5 days after the treatment was investigated, and the mortality rate was determined from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 19.

Mortality (%) = dead insects / test insects x 100
[Table 19]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 15] Efficacy test against pestworms The above-mentioned compounds shown in Table 1 were formulated into a 5% emulsion, and the preparation was diluted with water containing admix as a spreading agent. A drug solution was prepared. A chemical solution of a predetermined concentration was sprayed on pestworms generated in the apple orchard (3 L / tree). The number of insects and larvae per 50 leaves per tree before treatment and 7 days after treatment was counted. In addition, the test was conducted in 1 ward 1 tree 2 continuous system. The results are shown in Table 20.
[Table 20]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Number of adults and larvae
Before treatment Seven days after treatment ――――――――――――――――――――――――――――――
Compound No. 20 100 254 7
Compound No. 44 100 221 1
No treatment 0 190 191
―――――――――――――――――――――――――――――
[Test Example 16] Efficacy test against hatched whitefly larvae The above-mentioned compounds listed in Table 1 were formulated into a 5% emulsion, and the preparation was diluted with water containing admix as a spreading agent. A chemical solution with a predetermined concentration was prepared. The tea leaves spawned by Chatter's whitefly were collected, the adults were removed, and placed with the back of the leaves on wet cotton wool in a 7 cm petri dish. After 2.5 ml of a predetermined concentration of chemical solution was sprayed on the tea leaves, the petri dish was stored in a thermostatic chamber at 25 ° C. The number of larvae killed 24 days after the treatment was investigated, and the mortality rate was determined from the following formula. In addition, the test was conducted in a two-segment system of 50 to 70 eggs in one ward. The results are shown in Table 21.
Mortality (%) = dead insects / test insects x 100
[Table 21]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 17] Efficacy test against adult Lombine mite: The compound described in Table 1 above was formulated into a 5% emulsion, and the formulation was diluted with water containing admix as a spreading agent. A drug solution was prepared. A filter paper having a diameter of 4.2 cm was prepared, dipped in onion powder water (tap water: onion powder = 10: 1), and then air-dried. Three sheets of this filter paper were stacked and placed in a petri dish. 980 μl of a drug solution diluted to a predetermined concentration was dropped into the petri dish so as to be uniformly applied using a pipette. After dropping, 20 adult mite mites were released per petri dish. After the insect was released, the petri dish was stored in a constant temperature room at 25 ° C. The number of adult worms 3 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted by 1 ward 2 continuous system. The results are shown in Table 22.
Mortality (%) = dead insects / test insects x 100
[Table 22]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 18] Efficacy test against termites (Reticulitermes flavipes) The compounds described in Table 1 were formulated into a 5% emulsion, and the preparation was diluted with tap water to prepare a chemical solution having a predetermined concentration. 0.5 ml of a chemical solution diluted to a predetermined concentration was dropped into 10 g of river sand, and the river sand and the chemical solution were mixed. A 6-cm diameter petri dish prepared separately was spread with 1% agar (approximately 2.0 cm square), river sand mixed with the drug, and a filter paper slice as food, and 10 termites (Workers) were released. After the insect was released, the petri dish was stored in a constant temperature room at 25 ° C. The number of termite worms 6 days after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in a 10-headed 2-unit system. The results are shown in Table 23.
Mortality (%) = dead insects / test insects x 100
[Table 23]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 10 100
Compound No. 44 10 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 19] Residual effect test on termites (Reticulitermes flavipes) After conducting an efficacy test according to the method described in Test Example 18 above, river sand was collected and stored in a constant temperature room at 25 ° C. Ten termites (Workers) were released in river sand after 20 days of storage from the first test. The petri dish after insect release was stored in a constant temperature room at 25 ° C. The mortality of termites 6 days after the treatment was investigated, and the mortality was determined from the following formula.

This residual effect test was carried out by performing the same operation as described above and using river sand 146 days, 322 days and 664 days after the first test. In addition, the test was conducted in a triple system with 10 heads in 1 district. The results are shown in Table 24.
Mortality (%) = dead insects / test insects x 100
[Table 24]
―――――――――――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
River sand storage days 20 days 146 days 322 days later 664 days later ――――――――――――――――――――――――――――――――――――――
Compound No. 20 100 100 100 100 100
Compound No. 44 100 100 100 100 100
No treatment 0 20 13 20
―――――――――――――――――――――――――――――――――――――
[Test Example 20] Efficacy test against chica squid larvae The compounds listed in Table 1 were dissolved in dimethyl sulfoxide and diluted with distilled water to prepare a chemical solution having a predetermined concentration. To a 24-well plate containing distilled water, 10-20 first-aged larvae of chikaeika and tetramine (food for ornamental fish) as an appropriate amount were added. A drug solution diluted to a predetermined concentration was added dropwise to the Chikaeka larvae and tetramine mixed water. After dropping, the petri dish was stored in a constant temperature room at 25 ° C. The number of larvae killed one day after the treatment was investigated, and the mortality rate was determined from the following formula. In addition, the test was conducted by 1 ward 2 continuous system. The results are shown in Table 25.
Mortality (%) = dead insects / test insects x 100
[Table 25]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 0.01 100
Compound No. 44 0.01 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 21] Efficacy test against Chikaeka adults The compounds described in Table 1 above were formulated into a 5% emulsion, and the formulation was diluted with tap water to prepare a chemical solution having a predetermined concentration. Next, 10 adult females of Chikaeka were placed in a petri dish (diameter 6 cm, height 6 cm) with filter paper and anesthetized with carbon dioxide. To the petri dish containing the chikaeka prepared in this way, 2.5 ml of chemical solution of a predetermined concentration was sprayed per petri dish. After the spraying treatment, a 3 cm petri dish containing absorbent cotton moistened with 3% sucrose solution was added as a bait, the lid was put on, and the petri dish was stored in a constant temperature room at 25 ° C. The number of adult worms one day after the treatment was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 26.

Mortality (%) = dead insects / test insects x 100
[Table 26]
―――――――――――――――――――――――――――――
Active ingredient Concentration (ppm) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 100 100
Compound No. 44 100 100
No treatment 0 0
―――――――――――――――――――――――――――――
[Test Example 22] Seed treatment efficacy test against P. pylori larvae The compounds listed in Table 1 were dissolved in acetone to prepare a chemical solution having a predetermined concentration. In a 50 ml Falcon tube, corn seed and an acetone solution diluted to a predetermined concentration were added, stirred well, and then air-dried. Five treated seeds were put into a petri dish with a diameter of 7 cm on which filter paper was laid, and five larvae of the white rice larvae grown to about 7 mm were released. After the release, the petri dish was stored in a dark place at 25 degrees. The number of dead larvae 7 days after release was investigated, and the mortality rate was calculated from the following formula. In addition, the test was conducted in two consecutive systems. The results are shown in Table 27.

Mortality (%) = dead insects / test insects x 100
[Table 27]
―――――――――――――――――――――――――――――
Active ingredient Concentration (mg ai / seed) Death rate (%)
―――――――――――――――――――――――――――――
Compound No. 20 0.06 100
Compound No. 44 0.06 100
No treatment 0 0
―――――――――――――――――――――――――――――

  The composition of the present invention and the method of the present invention can be used for controlling various pests.

Claims (8)

An insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal composition comprising a synergistically effective amount of at least two active compounds,
1) One or more active compounds I are of the formula (1):

[Where A ¹ , A ² And A ^Three Each independently represents a carbon atom or a nitrogen atom,
G represents a benzene ring, a nitrogen-containing 6-membered aromatic heterocycle, a furan ring, a thiophene ring or a 5-membered aromatic heterocycle containing two or more heteroatoms selected from an oxygen atom, a sulfur atom and a nitrogen atom;
W represents an oxygen atom or a sulfur atom,
X is a halogen atom, nitro, azide, -SCN, -SF _Five , Cyano, C ₁ ~ C ₆ Alkyl, R ^Four Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ^Four Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E1-E19, C ₂ ~ C ₆ Alkenyl, R ^Four Optionally replaced by (C ₂ ~ C ₆ ) Alkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C ₂ ~ C ₆ Alkynyl, R ^Four Optionally replaced by (C ₂ ~ C ₆ ) Alkynyl, -OH, -OR ^Five , -OS (O) ₂ R ^Five , -SH, -S (O) _r R ^Five , -N (R ⁷ ) R ⁶ , -N = C (R ^7a ) R ^6a , -C (O) R ⁸ , -C (R ⁸ ) = NOH, -C (R ⁸ ) = NOR ⁹ , M3, M13, M30, -C (O) OR ⁹ , -C (O) SR ⁹ , -C (O) NH ₂ , -C (O) N (R ^Ten ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ^Ten ) R ⁹ , M23 to M26, M28, M29, -S (O) ₂ OR ⁹ , -S (O) ₂ NH ₂ , -S (O) ₂ N (R ^Ten ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ¹¹ , Phenyl, (Z) _p1 Represents phenyl substituted by or D1 to D38, and when m represents an integer of 2 or more, each X may be the same as or different from each other;
Furthermore, when two Xs are adjacent, the two adjacent Xs are -CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ O-, -CH ₂ OCH ₂ -, -OCH ₂ O-, -CH ₂ CH ₂ S-, -CH ₂ SCH ₂ -, -CH ₂ CH ₂ N (R ¹² )-, -CH ₂ N (R ¹² ) CH ₂ -, -CH ₂ CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH ₂ -, -CH ₂ OCH ₂ O-, -OCH ₂ CH ₂ O-, -OCH ₂ CH ₂ S-, -CH ₂ CH = CH-, -OCH = CH-, -SCH = CH-, -N (R ¹² ) CH = CH-, -OCH = N-, -SCH = N-, -N (R ¹² ) CH = N-, -N (R ¹² ) N = CH-, -CH = CHCH = CH-, -OCH ₂ By forming CH = CH-, -N = CHCH = CH-, -N = CHCH = N- or -N = CHN = CH-, a 5-membered ring or 6 together with the carbon atom to which each of the two X bonds is attached. A hydrogen atom bonded to each carbon atom forming the ring may be optionally substituted with Z, and further substituted with two or more Z at the same time. Each Z may be the same as or different from each other,
Y is a halogen atom, nitro, azide, -SCN, -SF _Five , Cyano, C ₁ ~ C ₆ Alkyl, R ^Four Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ^Four Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E1-E18, C ₂ ~ C ₆ Alkynyl, R ^Four Optionally replaced by (C ₂ ~ C ₆ ) Alkynyl, -OH, -OR ^Five , -OS (O) ₂ R ^Five , -SH, -S (O) _r R ^Five , -NH ₂ , -N (R ⁷ ) R ⁶ , -N (R ⁷ ) C (O) R ^8a , -N = C (R ^7a ) R ^6a , -C (O) NH ₂ , -C (O) N (R ^Ten ) R ⁹ , -C (S) NH ₂ , -C (S) N (R ^Ten ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ¹¹ , Phenyl, (Z) _p1 Each of Y may be the same as or different from each other when n represents an integer of 2 or more.
Furthermore, when two Ys are adjacent, the two adjacent Ys are -CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ O-, -CH ₂ OCH ₂ -, -OCH ₂ O-, -CH ₂ CH ₂ S-, -CH ₂ SCH ₂ -, -SCH ₂ S-, -CH ₂ CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH ₂ -, -CH ₂ OCH ₂ O-, -OCH ₂ CH ₂ O-, -OCH ₂ CH ₂ S-, -SCH ₂ CH ₂ By forming S-, -OCH = N- or -SCH = N-, a 5-membered ring or a 6-membered ring may be formed together with the carbon atom to which each of two Ys is bonded. The hydrogen atom bonded to each carbon atom to be formed may be optionally substituted with Z. Further, when simultaneously substituted with two or more Z, each Z may be the same as each other or They may be different,
R ¹ Is a hydrogen atom, cyano, C ₁ ~ C ₁₂ Alkyl, R ¹³ Optionally replaced by (C ₁ ~ C ₁₂ ) Alkyl, C _Three ~ C ₁₂ Cycloalkyl, R ¹³ Optionally replaced by (C _Three ~ C ₁₂ ) Cycloalkyl, E2-E6, E9, E12-E15, E18, C ₂ ~ C ₁₂ Alkenyl, R ¹³ Optionally replaced by (C ₂ ~ C ₁₂ ) Alkenyl, C _Five ~ C ₁₄ Cycloalkenyl, C _Five ~ C ₁₄ Halocycloalkenyl, C _Three ~ C ₁₂ Alkynyl, R ¹³ Optionally replaced by (C _Three ~ C ₁₂ ) Alkynyl, -C (O) R ¹⁴ , -C (R ¹⁴ ) = NOH, -C (R ¹⁴ ) = NOR ¹⁵ , M3, M13, M30, -C (R ¹⁴ ) = NN (R ¹⁷ ) R ¹⁶ , -C (O) OR ¹⁵ , -C (O) SR ¹⁵ , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ¹⁵ , -C (S) SR ¹⁵ , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (= NR ¹⁶ ) OR ¹⁵ , -C (= NOR ¹⁵ ) OR ¹⁵ , M7, M17, M23, M26, -C (= NR ¹⁶ SR ¹⁵ , M9, M19, M24, M28, -C (= NR ¹⁶ ) N (R ¹⁷ ) R ¹⁶ , -C (= NCN) N (R ¹⁷ ) R ¹⁶ , -C (= NOR ¹⁵ ) N (R ¹⁷ ) R ¹⁶ , -C (= NNO ₂ ) N (R ¹⁷ ) R ¹⁶ , M11, M21, M25, M29, -OR ¹⁵ , -SR ¹⁵ , -S (O) ₂ R ¹⁵ , -S (O) ₂ N (R ¹⁷ ) R ¹⁶ , -N (R ¹⁷ ) R ¹⁶ , -N = C (R ^17a ) R ^16a , -C (O) ON = C (R ^17a ) R ^16a , -SN (R ¹⁹ ) R ¹⁸ , Phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ² Is a hydrogen atom, cyano, C ₁ ~ C ₁₂ Alkyl, R ^13a Optionally replaced by (C ₁ ~ C ₁₂ ) Alkyl, C _Three ~ C ₁₂ Cycloalkyl, C _Three ~ C ₁₂ Alkenyl, C _Three ~ C ₁₂ Haloalkenyl, C _Five ~ C ₁₄ Cycloalkenyl, C _Five ~ C ₁₄ Halocycloalkenyl, C _Three ~ C ₁₂ Alkynyl, C _Three ~ C ₁₂ Haloalkynyl, -C (O) R ^14a , -C (O) OR ^15a , -C (O) SR ^15a , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ^15a , -C (S) SR ^15a , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (O) C (O) OR ^15a , -OR ¹⁵ , -SR ¹⁵ , -N (R ¹⁷ ) R ¹⁶ , -N = C (R ^17a ) R ^16a , -S (O) ₂ R ^15a , -S (O) ₂ N (R ¹⁷ ) R ¹⁶ , -SN (R ¹⁹ ) R ¹⁸ , Phenyl or (Z) _p1 Represents phenyl substituted by or R ² Is R ¹ Together with = C (R ^2a ) R ^1a Or R ² And R ¹ Together with C ₂ ~ C ₇ By forming an alkylene chain, R ¹ And R ² Represents that a 3- to 8-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, C ₁ ~ C ₆ Alkoxy (C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group, C ₁ ~ C ₆ Haloalkylcarbonyl group, C ₁ ~ C ₆ Alkoxycarbonyl group, C ₁ ~ C ₆ Haloalkoxycarbonyl group, C ₁ ~ C ₆ Alkylaminocarbonyl group, C ₁ ~ C ₆ Haloalkylaminocarbonyl group, phenyl group, (Z) _p1 Optionally substituted by a phenyl group, D32 group, D33 group, D34 group, D35 group, oxo group or thioxo group substituted by
Further alternatively, when substituent Y is present at the adjacent position, R ² Together with Y-CH ₂ -, -CH ₂ CH ₂ -, -CH ₂ O-, -CH ₂ S-, -CH ₂ N (R ⁶ )-, -CH = CH- or -CH = N- ² And Y may form a 5-membered ring or a 6-membered ring together with the atoms to which each is bonded, in which case the hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, C ₁ ~ C ₆ Alkylidene group, C ₁ ~ C ₆ Optionally substituted by a haloalkylidene group, an oxo group or a thioxo group,
R ^1a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, -OR ¹⁵ , -SR ¹⁵ , -S (O) ₂ R ¹⁵ Or -N (R ^17b ) R ^16b Represents
R ^2a R ¹⁴ , -OR ^15a , -SR ^15a , -SC (O) R ^14a , -SC (O) OR ^15a Or -N (R ^17c ) R ^16c Or R ^2a Is R ^1a Together with C _Four ~ C _Five Alkylene chain or C _Four ~ C _Five By forming an alkenylene chain, R ^1a And R ^2a Represents that it may form a 5- to 6-membered ring with the carbon atom to which is bonded, and in this case, the alkylene chain or alkenylene chain may contain 1 to 3 oxygen atoms, sulfur atoms or nitrogen atoms, and a halogen atom , Nitro group, cyano group, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, C ₁ ~ C ₆ Alkoxy group, C ₁ ~ C ₆ Haloalkoxy group, C ₁ ~ C ₆ Alkylthio group, C ₁ ~ C ₆ Haloalkylthio group or R ^17c Optionally substituted by a group,
R ^Three Is a halogen atom, cyano, C ₁ ~ C ₆ Alkyl, R ^Four Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ^Four Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E1-E19, C _Three ~ C ₆ Alkenyl, R ^Four Optionally replaced by (C ₂ ~ C ₆ ) Alkenyl, C _Three ~ C ₆ Alkynyl, R ^Four Optionally replaced by (C ₂ ~ C ₆ ) Alkynyl, -OR ^Five , -S (O) _r R ^Five , -N (R ^Ten ) R ⁹ , -C (O) R ⁸ , -C (R ⁸ ) = NOH, -C (R ⁸ ) = NOR ⁹ , M3, M13, M30, -C (O) OR ⁹ , -C (O) SR ⁹ , -C (O) NH ₂ , -C (O) N (R ^Ten ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ^Ten ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
D1 to D38 each represent an aromatic heterocycle represented by the following structural formula;


Z is a halogen atom, nitro, cyano, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfinyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylsulfinyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Halocycloalkyl, -OH, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, C ₁ ~ C ₆ Alkylsulfonyloxy, C ₁ ~ C ₆ Haloalkylsulfonyloxy, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Haloalkylthio, C ₁ ~ C ₆ Alkylsulfinyl, C ₁ ~ C ₆ Haloalkylsulfinyl, C ₁ ~ C ₆ Alkylsulfonyl, C ₁ ~ C ₆ Haloalkylsulfonyl, -NH ₂ , C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C ₆ Alkyl) amino, C ₁ ~ C ₆ Alkoxycarbonyl, C ₁ ~ C ₆ Haloalkoxycarbonyl, -C (O) NH ₂ , C ₁ ~ C ₆ Alkylaminocarbonyl, C ₁ ~ C ₆ Haloalkylaminocarbonyl, di (C ₁ ~ C ₆ Alkyl) aminocarbonyl, -C (S) NH ₂ , -S (O) ₂ NH ₂ , C ₁ ~ C ₆ Alkylaminosulfonyl, di (C ₁ ~ C ₆ Alkyl) aminosulfonyl, phenyl or phenyl optionally substituted by a halogen atom, and when p1, p2, p3 or p4 represents an integer of 2 or more, each Z may be the same as or different from each other You can,
Furthermore, when two Zs are adjacent, the two adjacent Zs are -CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ O-, -CH ₂ OCH ₂ -, -OCH ₂ O-, -CH ₂ CH ₂ S-, -CH ₂ SCH ₂ -, -CH ₂ CH ₂ CH ₂ CH ₂ -, -CH ₂ CH ₂ CH ₂ O-, -CH ₂ CH ₂ OCH ₂ -, -CH ₂ OCH ₂ O-, -OCH ₂ CH ₂ O-, -CH ₂ CH ₂ CH ₂ S-, -OCH ₂ CH ₂ By forming S— or —CH═CH—CH═CH—, a 5-membered ring or a 6-membered ring may be formed together with the carbon atom to which each of two Zs is bonded, and at this time, a ring is formed. The hydrogen atom bonded to each carbon atom is a halogen atom, cyano group, nitro group, C ₁ ~ C _Four Alkyl group, C ₁ ~ C _Four Haloalkyl group, C ₁ ~ C _Four An alkoxy group or C ₁ ~ C _Four Optionally substituted with an alkylthio group,
E1 to E19 each represents a saturated heterocyclic ring represented by the following structural formula;

R ^Four Is a halogen atom, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E1-E19, -OH, -OR ^Five , -SH, -S (O) _r R ^Five , -N (R ⁷ ) R ⁶ , -N (R ⁷ ) C (O) R ^8a , -C (O) OR ⁹ , -C (O) N (R ^Ten ) R ⁹ , -Si (R ^11a ) (R ^11b ) R ¹¹ , Phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ^Five C ₁ ~ C ₆ Alkyl, R ^{twenty three} Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ^{twenty three} Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E2-E6, E12-E15, E18, C ₂ ~ C ₆ Alkenyl, R ^{twenty three} Optionally replaced by (C ₂ ~ C ₆ ) Alkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl, R ^{twenty three} Optionally replaced by (C _Three ~ C ₆ Alkynyl, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, phenyl, (Z) _p1 Represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38, substituted by
R ⁶ C ₁ ~ C ₆ Alkyl, R ^{twenty three} Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, -C (O) R ⁸ , -C (O) OR ⁹ , -C (O) SR ⁹ , -C (O) NH ₂ , -C (O) N (R ^Ten ) R ⁹ , -C (S) OR ⁹ , -C (S) SR ⁹ , -C (S) NH ₂ , -C (S) N (R ^Ten ) R ⁹ , -C (O) C (O) R ⁹ , -C (O) C (O) OR ⁹ , -OH, -S (O) ₂ R ⁹ , -S (O) ₂ N (R ^Ten ) R ⁹ , -P (O) (OR ²⁰ ) ₂ Or -P (S) (OR ²⁰ ) ₂ Represents
R ⁷ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ^{twenty three} Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, -CHO, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl or C ₁ ~ C ₆ Represents alkoxycarbonyl or R ⁷ Is R ⁶ Together with C ₂ ~ C ₆ By forming an alkylene chain, R ⁶ And R ⁷ Represents that it may form a 3- to 7-membered ring together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Optionally substituted by a haloalkyl group, an oxo group or a thioxo group,
R ^6a C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, C _Three ~ C ₆ Alkenyloxy, phenoxy or (Z) _p1 Represents phenoxy substituted by
R ^7a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Alkenyl, phenyl or (Z) _p1 Represents phenyl substituted by or R ^7a Is R ^6a Together with C _Four ~ C ₆ By forming an alkylene chain, R ^6a And R ^7a Represents that it may form a 5- to 7-membered ring together with the carbon atom to which is bonded, in which case the alkylene chain may contain one oxygen atom or one sulfur atom,
R ⁸ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ^{twenty three} Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E4-E6, E12-E14, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl or C _Three ~ C ₆ Represents haloalkynyl,
R ^8a Is phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ⁹ C ₁ ~ C ₆ Alkyl, R ^{twenty three} Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E2-E6, E12-E19, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ^Ten Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Cycloalkyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkylthio (C ₁ ~ C _Four ) Alkyl, cyano (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₆ Alkenyl or C _Three ~ C ₆ Represents alkynyl or R ^Ten Is R ⁹ Together with C ₂ ~ C ₆ By forming an alkylene chain, R ⁹ And R ^Ten Represents that it may form a 3- to 7-membered ring together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ¹¹ C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C ₆ Alkoxy, phenyl or (Z) _p1 Represents phenyl substituted by
R ^11a And R ^11b Are each independently C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl or C ₁ ~ C ₆ Represents alkoxy,
R ¹² Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C ₆ Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Alkoxycarbonyl, C ₁ ~ C ₆ Haloalkoxycarbonyl, phenyl or (Z) _p1 Represents phenyl substituted by
In addition, R ¹² If Z is adjacent to ¹² And Z are -CH ₂ CH ₂ CH ₂ CH ₂ -, -CH = CH-CH = CH-, -N = CH-CH = CH-, -CH = N-CH = CH-, -CH = CH-N = CH- or -CH = CH-CH = N -By forming R ¹² And Z may form a 6-membered ring together with the atom to which each of Z is bonded. At this time, the hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, C ₁ ~ C _Four Alkyl group or C ₁ ~ C _Four Optionally substituted by a haloalkyl group,
R ¹³ And R ^13a Each independently represents a halogen atom, nitro, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, hydroxy (C _Three ~ C ₈ ) Cycloalkyl, C ₁ ~ C _Four Alkoxy (C _Three ~ C ₈ ) Cycloalkyl, E1-E19, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, -OR ^{twenty four} , -N (R ^{twenty five} ) R ^{twenty four} , -SH, -S (O) _r R ²⁶ , -C (O) R ²⁷ , -C (R ²⁷ ) = NOH, -C (R ²⁷ ) = NOR ²⁸ , -C (O) OH, -C (O) OR ²⁸ , -C (O) SR ²⁸ , -C (O) NH ₂ , -C (O) N (R ²⁹ ) R ²⁸ , -C (O) N (R ²⁹ ) OR ²⁸ , -C (O) N (R ²⁹ ) N (R ^28a ) R ²⁸ , -C (O) C (O) OR ²⁸ , -C (S) OR ²⁸ , -C (S) SR ²⁸ , -C (S) NH ₂ , -C (S) N (R ²⁹ ) R ²⁸ , -C (= NR ²⁹ ) OR ²⁸ , -C (= NR ²⁹ SR ²⁸ , -C (= NR ²⁹ ) N (R ^28a ) R ²⁸ , -C (= NOR ²⁸ ) N (R ^28a ) R ²⁸ , -S (O) ₂ OH, -S (O) ₂ NH ₂ , -S (O) ₂ N (R ²⁹ ) R ²⁸ , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , -P (phenyl) ₂ , -P (O) (phenyl) ₂ , M1-M30, phenyl, (Z) _p1 Represents phenyl, naphthyl or D1-D38 substituted by
M1 to M30 each represents a partially saturated heterocyclic ring represented by the following structural formula,

R ¹⁴ And R ^14a Each independently represents a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E3-E6, E12-E14, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C ₂ ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl, naphthyl or D1-D38 substituted by
R ¹⁵ And R ^15a Are each independently C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E2-E6, E12-E19, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38, substituted by
R ¹⁶ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E2-E6, E12-E19, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C _Three ~ C ₆ Alkynyl, C ₂ ~ C ₆ Haloalkynyl, -C (O) R ²⁷ , -C (O) OR ²⁸ , -C (O) SR ²⁸ , -C (O) NH ₂ , -C (O) N (R ²⁹ ) R ²⁸ , -C (S) R ²⁷ , -C (S) OR ²⁸ , -C (S) SR ²⁸ , -C (S) NH ₂ , -C (S) N (R ²⁹ ) R ²⁸ , -S (O) ₂ R ²⁸ , -S (O) ₂ NH ₂ , -S (O) ₂ N (R ²⁹ ) R ²⁸ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ¹⁷ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Cycloalkyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Haloalkylsulfonyl (C ₁ ~ C _Four ) Alkyl, cyano (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl or C _Three ~ C ₆ Represents haloalkynyl or R ¹⁷ Is R ¹⁶ Together with C ₂ ~ C ₆ By forming an alkylene chain, R ¹⁶ And R ¹⁷ Represents that it may form a 3- to 7-membered ring together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E1-E19, phenyl (C ₂ ~ C _Four ) Alkenyl, di (C ₁ ~ C ₆ Alkyl) amino, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ^17a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Alkylthio or di (C ₁ ~ C ₆ Alkyl) amino or R ^17a Is R ^16a Together with C _Three ~ C _Five By forming an alkylene chain, R ^16a And R ^17a Represents a 4- to 6-membered ring together with the carbon atom to which is bonded, wherein the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16b Is a hydrogen atom, C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents haloalkyl,
R ^17b Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl or R ^17b Is R ^16b Together with C _Three ~ C _Five By forming an alkylene chain, R ^16b And R ^17b Represents a 4- to 6-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain an oxygen atom, a sulfur atom or a nitrogen atom, and C ₁ ~ C ₆ Alkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ^16c Is a hydrogen atom, nitro, cyano, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Alkynyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, -NH ₂ , C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C ₆ Alkyl) amino, -NHC (O) R ²⁷ , -NHC (O) OR ²⁸ , -NHC (O) SR ²⁸ , -NHC (O) NH ₂ , -NHC (O) N (R ²⁹ ) R ²⁸ , -NHC (S) OR ²⁸ , -NHC (S) SR ²⁸ , -NHC (S) NH ₂ , -NHC (S) N (R ²⁹ ) R ²⁸ , -NHS (O) ₂ R ²⁸ , -NHS (O) ₂ NH ₂ Or -NHS (O) ₂ N (R ²⁹ ) R ²⁸ Represents
R ^17c Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl or R ^17c Is R ^16c Together with C _Three ~ C _Five By forming an alkylene chain, R ^16c And R ^17c Represents a 4- to 6-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain an oxygen atom, a sulfur atom or a nitrogen atom, and C ₁ ~ C ₆ Alkyl group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group or C ₁ ~ C ₆ Optionally substituted by an alkoxycarbonyl group,
R ¹⁸ C ₁ ~ C ₁₂ Alkyl, C ₁ ~ C ₁₂ Haloalkyl, C ₁ ~ C ₁₂ Alkoxy (C ₁ ~ C ₁₂ ) Alkyl, cyano (C ₁ ~ C ₁₂ ) Alkyl, C ₁ ~ C ₁₂ Alkoxycarbonyl (C ₁ ~ C ₁₂ ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₁₂ Alkenyl, C _Three ~ C ₁₂ Haloalkenyl, C _Three ~ C ₁₂ Alkynyl, C _Three ~ C ₁₂ Haloalkynyl, C ₁ ~ C ₁₂ Alkylcarbonyl, C ₁ ~ C ₁₂ Alkoxycarbonyl, -C (O) ON = C (CH _Three ) SCH _Three , -C (O) ON = C (SCH _Three ) C (O) N (CH _Three ) ₂ , Phenyl or (Z) _p1 Represents phenyl substituted by
R ¹⁹ C ₁ ~ C ₁₂ Alkyl, C ₁ ~ C ₁₂ Haloalkyl, C ₁ ~ C ₁₂ Alkoxy (C ₁ ~ C ₁₂ ) Alkyl, cyano (C ₁ ~ C ₁₂ ) Alkyl, C ₁ ~ C ₁₂ Alkoxycarbonyl (C ₁ ~ C ₁₂ ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₁₂ Alkenyl, C _Three ~ C ₁₂ Haloalkenyl, C _Three ~ C ₁₂ Alkynyl, C _Three ~ C ₁₂ Haloalkynyl, phenyl or (Z) _p1 Represents phenyl substituted by or R ¹⁹ Is R ¹⁸ Together with C _Four ~ C ₇ By forming an alkylene chain, R ¹⁸ And R ¹⁹ Represents that it may form a 5- to 8-membered ring together with the nitrogen atom to which is bonded, wherein the alkylene chain may contain one oxygen atom or sulfur atom, and C ₁ ~ C _Four Alkyl group or C ₁ ~ C _Four Optionally substituted by an alkoxy group,
R ²⁰ C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents haloalkyl,
R ^{twenty one} Is a halogen atom, cyano, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, hydroxy (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkoxycarbonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C _Four Alkyl) amino, C ₁ ~ C ₆ Alkoxycarbonyl, phenyl or (Z) _p1 Each of R's is represented by q1 to q8 each representing an integer of 2 or more. ^{twenty one} May be the same as or different from each other, and two R ^{twenty one} Are substituted on the same carbon atom, two R ^{twenty one} Together oxo, thioxo, imino, C ₁ ~ C ₆ Alkylimino, C ₁ ~ C ₆ Alkoxyimino or C ₁ ~ C ₆ Represents that an alkylidene may be formed,
R ^{twenty two} Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, -OH, benzyloxy, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (S) N (R ³⁴ ) R ³³ , -S (O) ₂ R ³² , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl or D3 substituted by
R ^{twenty three} Is a halogen atom, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E1-E19, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₆ Haloalkoxy, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Haloalkylthio, C ₁ ~ C ₆ Alkylsulfonyl, C ₁ ~ C ₆ Haloalkylsulfonyl, C ₁ ~ C ₆ Alkylamino, di (C ₁ ~ C ₆ Alkyl) amino, -CHO, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, C ₁ ~ C ₆ Haloalkoxycarbonyl, C ₁ ~ C ₆ Alkylaminocarbonyl, di (C ₁ ~ C ₆ Alkyl) aminocarbonyl, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ^{twenty four} Is a hydrogen atom, C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E2-E6, E12-E19, C _Three ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) R ³² , -C (O) C (O) OR ³² , -C (S) R ³¹ , -C (S) OR ³² , -C (S) SR ³² , -C (S) N (R ³⁴ ) R ³³ , -S (O) ₂ R ³² , -S (O) ₂ N (R ³⁴ ) R ³³ , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D1, D2, D4-D6, D8-D10, D12-D19, D21, D23, D25, D27 or D30-D38, substituted by
R ^{twenty five} Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C ₁ ~ C _Four Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C _Four Alkylthio (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Alkynyl, C ₁ ~ C ₆ Alkoxy, phenyl or (Z) _p1 Represents phenyl substituted by or R ^{twenty five} Is R ^{twenty four} Together with C ₂ ~ C _Five By forming an alkylene chain, R ^{twenty four} And R ^{twenty five} Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Haloalkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group, C ₁ ~ C ₆ Alkoxycarbonyl group, phenyl group, (Z) _p1 May be substituted by a phenyl group, an oxo group or a thioxo group substituted by
R ²⁶ C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E2-E6, E12-E19, C _Three ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, -C (O) R ³¹ , -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) R ³² , -C (O) C (O) OR ³² , -C (S) R ³¹ , -C (S) OR ³² , -C (S) SR ³² , -C (S) N (R ³⁴ ) R ³³ , -SH, C ₁ ~ C ₆ Alkylthio, C ₁ ~ C ₆ Haloalkylthio, phenylthio, (Z) _p1 Phenylthio substituted by -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , Phenyl, (Z) _p1 Represents phenyl, D9, D10, D12, D14-D17, D30, D32 or D34 substituted by
R ²⁷ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₆ Cycloalkyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkoxy (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkylthio (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Alkylsulfonyl (C ₁ ~ C _Four ) Alkyl, C ₁ ~ C ₆ Haloalkylsulfonyl (C ₁ ~ C _Four ) Alkyl, phenyl (C ₁ ~ C _Four ) Alkyl, (Z) _p1 Phenyl substituted by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, phenyl or (Z) _p1 Represents phenyl substituted by
R ²⁸ C ₁ ~ C ₈ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₈ ) Alkyl, C _Three ~ C ₈ Cycloalkyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Cycloalkyl, E1-E7, E12-E19, C ₂ ~ C ₈ Alkenyl, R ³⁰ Optionally replaced by (C ₂ ~ C ₈ ) Alkenyl, C _Three ~ C ₈ Alkynyl, R ³⁰ Optionally replaced by (C _Three ~ C ₈ ) Alkynyl, phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ^28a Is a hydrogen atom or C ₁ ~ C _Four Represents alkyl,
R ²⁹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ³⁰ Optionally replaced by (C ₁ ~ C ₆ ) Alkyl, C _Three ~ C ₆ Alkenyl, C _Three ~ C ₆ Haloalkenyl, C _Three ~ C ₆ Alkynyl, C _Three ~ C ₆ Haloalkynyl, phenyl or (Z) _p1 Represents phenyl substituted by or R ²⁹ Is R ²⁸ Together with C ₂ ~ C _Five By forming an alkylene chain, R ²⁸ And R ²⁹ Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C ₆ Alkyl group, C ₁ ~ C ₆ Alkoxy group, -CHO group, C ₁ ~ C ₆ Alkylcarbonyl group, C ₁ ~ C ₆ Alkoxycarbonyl group, phenyl group or (Z) _p1 Optionally substituted by a phenyl group substituted by
R ³⁰ Is a halogen atom, nitro, cyano, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₈ Halocycloalkyl, E4, E5, E7, E8, E10, E12, E13, E15, E16, E18, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Haloalkenyl, -OH, -OR ³² , -OC (O) R ³¹ , -OC (O) OR ³² , -OC (O) N (R ³⁴ ) R ³³ , -OC (S) N (R ³⁴ ) R ³³ , -SH, -S (O) _r R ³² , -SC (O) R ³¹ , -SC (O) OR ³² , -SC (O) N (R ³⁴ ) R ³³ , -SC (S) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) R ³³ , -N (R ³⁴ ) CHO, -N (R ³⁴ ) C (O) R ³¹ , -N (R ³⁴ ) C (O) OR ³² , -N (R ³⁴ ) C (O) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) C (S) N (R ³⁴ ) R ³³ , -N (R ³⁴ ) S (O) ₂ R ³² , -C (O) R ³¹ , -C (O) OH, -C (O) OR ³² , -C (O) SR ³² , -C (O) N (R ³⁴ ) R ³³ , -C (O) C (O) OR ³² , -Si (R ^11a ) (R ^11b ) R ¹¹ , -P (O) (OR ²⁰ ) ₂ , -P (S) (OR ²⁰ ) ₂ , -P (phenyl) ₂ , -P (O) (phenyl) ₂ , Phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ³¹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Halocycloalkyl, E4, E5, E12, E13, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Five ~ C _Ten Cycloalkenyl, C _Five ~ C _Ten Halocycloalkenyl, C ₂ ~ C ₈ Alkynyl, C ₂ ~ C ₈ Haloalkynyl, phenyl, (Z) _p1 Represents phenyl or D1-D38 substituted by
R ³² C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E4, E5, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Three ~ C ₈ Represents alkynyl or phenyl,
R ³³ C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, R ³⁵ Optionally replaced by (C ₁ ~ C _Four ) Alkyl, C _Three ~ C ₆ Cycloalkyl, E4, E5, E12, C ₂ ~ C ₈ Alkenyl, C ₂ ~ C ₈ Haloalkenyl, C _Three ~ C ₈ Alkynyl, phenyl, (Z) _p1 Represents phenyl, D1-D25 or D27-D38, substituted by
R ³⁴ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Haloalkyl, C _Three ~ C ₈ Cycloalkyl, C _Three ~ C ₆ Alkenyl or C _Three ~ C ₆ Represents alkynyl or R ³⁴ Is R ³³ Together with C ₂ ~ C _Five By forming an alkylene chain, R ³³ And R ³⁴ Represents that a 3- to 6-membered ring may be formed together with the nitrogen atom to which is bonded, and at this time, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and a halogen atom, C ₁ ~ C _Four Alkyl group, C ₁ ~ C _Four Alkoxy group, -CHO group, C ₁ ~ C _Four Alkylcarbonyl group, C ₁ ~ C _Four Alkoxycarbonyl group, phenyl group or (Z) _p1 Optionally substituted by a phenyl group substituted by
R ³⁵ Is cyano, C _Three ~ C ₆ Cycloalkyl, C _Three ~ C ₆ Halocycloalkyl, E4, E5, E12, E13, C ₁ ~ C _Four Alkoxy, C ₁ ~ C _Four Haloalkoxy, phenoxy, (Z) _p1 Phenoxy substituted by C ₁ ~ C _Four Alkylthio, C ₁ ~ C _Four Haloalkylthio, phenylthio, (Z) _p1 Phenylthio, substituted by C ₁ ~ C _Four Alkylsulfonyl, C ₁ ~ C _Four Haloalkylsulfonyl, phenylsulfonyl, (Z) _p1 Phenylsulfonyl substituted by -N (R ³⁷ ) R ³⁶ , C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, di (C ₁ ~ C ₆ Alkyl) aminocarbonyl, tri (C ₁ ~ C _Four Alkyl) silyl, phenyl, (Z) _p1 Represents phenyl, naphthyl or D1-D38 substituted by
R ³⁶ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, C ₁ ~ C ₆ Alkylcarbonyl, C ₁ ~ C ₆ Haloalkylcarbonyl, C ₁ ~ C ₆ Alkoxycarbonyl, phenylcarbonyl or (Z) _p1 Represents phenylcarbonyl substituted by
R ³⁷ Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl,
m represents an integer of 0, 1, 2, 3, 4 or 5,
n represents an integer of 0, 1, 2, 3 or 4;
p1 represents an integer of 1, 2, 3, 4 or 5;
p2 represents an integer of 0, 1, 2, 3 or 4;
p3 represents an integer of 0, 1, 2, or 3,
p4 represents an integer of 0, 1 or 2;
p5 represents an integer of 0 or 1,
q1 represents an integer of 0, 1, 2, or 3,
q2 represents an integer of 0, 1, 2, 3, 4 or 5;
q3 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
q4 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7, 8, or 9;
q5 represents an integer of 0, 1, 2, 3, 4, 5 or 6,
q6 represents an integer of 0, 1, 2, 3, or 4;
q7 represents an integer of 0, 1 or 2,
q8 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7 or 8,
r represents an integer of 0, 1 or 2;
t represents an integer of 0 or 1. ]
An isoxazoline-substituted benzamide compound represented by: or a tautomer, enantiomer, diastereomer or salt thereof,
2) One or more active compounds II are the following active ingredient groups A to G:
Active ingredient group A (bactericidal agent): acibenzoral-S-methyl, acipetax, aldimorph, amethoctrazine, amisulbrom, ambam, ampropylphos, anilazine, azaconazole, azoxystrobin, benalaxyl, benalaxyl-M, benodanyl, benomyl, bencher Valicarb-isopropyl, benazole, biphenyl, viteltanol, bixafen, bordeaux solution, boscalid, bromconazole, bupirimate, lime sulfur combination, captan, carbendazim, carboxin, carpropamide, carvone, chestnut mixture, quinomethionate, chloronebu, Chlorpicrin, chlorothalonil, clozolinate, crimbazole, basic copper carbonate, cupric hydroxide, copper naphthenate, copper oleate, salt Copper chloride, copper sulfate, basic copper sulfate, cresol, kufuraneb, cyazofamide, cyflufenamide, simoxanyl, cyproconazole, cyprodinil, dazomet, diclofluanide, dichlorophen, diclobutrazole, diclocimet, diclomedin, dichlorane, dietofencarb, Difenoconazole, diflumetrim, dimethomorph, dimoxystrobin, diniconazole, diniconazole-M, dinobutone, dinocup, dinocup-4, dinocup-6, diphenylamine, dithianon, denouc, dodemorph acetate, dodine, drazoxolone, edifenphos, enestrobine , Epoxiconazole, etaconazole, ethaboxam, etilimol, ethoxyquin, etridiazole, famoxadone, fu Namidone, Fenarimol, Fenbuconazole, Fenfram, Fenhexamide, Fenitropan, Phenoxanyl, Fenpiclonyl, Fenpropidin, Fenpropimorph, Fentine, Farbum, Ferimzone, Fluazinam, Fludioxonil, Flumorph, Fluopicolide, Fluopyram, Fluorimide, Fluotrimazole , Fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, fluthanyl, flutolanil, flutriahol, floxapyroxad, folpette, fosetyl-aluminum, fuberidazole, flaxyl, framethopyl, fluconazole, flumeciclos, guazatine, hexachlorobenzene , Hexaconazole, himexazole, imazalil, imibenconazo , Iminotadine-albesylate, iminoctadine acetate, ipconazole, iprobenphos, iprodione, iprovaricarb, isoprothiolane, isopyrazam, isothianyl, kasugamycin, cresoxime-methyl, laminarin, mankappa, mancozeb, mandipropamide, manneb, mepanil methirapyl, mepanil Metalaxyl-M, Metam, Metoconazole, Metofloxam, Metramum, Metominostrobin, Metraphenone, Metosulfofax, Milneb, Microbutanyl, Nervam, Natamycin, Organonickel, Nitrotal-isopropyl, Nualimol, Offrace, Orisatrobin, Oxazixil, Oxyquinoline copper, Oxpoconazole fumarate, oxycarboxyl, pefrazo , Penconazole, pencyclon, penflufen, pentachlorophenol, penthiopyrad, orthophenylphenol, fusalide, picoxystrobin, piperalin, polycarbamate, polyoxin, polyoxin-D, potassium azide, potassium bicarbonate, probenazole, prochloraz, procimidone, Propamocarb hydrochloride, propiconazole, propineb, proquinazide, prothioconazole, pyraclostrobin, pyramethostrobin, pyroxystrobin, pyrazophos, pyribencarbmethyl, pyriphenox, pyrimethanil, pyriophenone, pyroxylone, quinacetol-sulfate, Quinoxyphene, quintozene, sedaxane, silthiofam, cimeconazole, sodium bicarbonate, hypochlorous acid Thorium, spiroxamine, sulfur, tebuconazole, tebufloquine, tecolone, tetraconazole, thiabendazole, tifluzamide, thiophanate-methyl, thiuram, thiazinyl, tolurophos-methyl, tolylfuranide, triadimethone, triadimenol, triazoxide, tributyltin oxide, tricyclazole, Tridemorph, Trifloxystrobin, Triflumizole, Trifolin, Triticonazole, Validamycin, Varifenalate, Vinclozoline, Zincnaphthenate, Zinc sulfate, Diram, Zoxamide, Shiitake mycelium extract, Shiitake fruit body extract, BCF- 082 and ZF-9646.
Active ingredient group B (nematicide): kazusafos, diclofenthion, etoprofos, phenamifos, fluenesulfone, phostiazete, fosthiethane, imiciaphos, isamidophos, isazophos, methyl bromide, methylisothiocyanate, oxamyl, sodium azide, BYI-1921 and MAI-08015.
Active ingredient group C (insecticide): abamectin, acephate, acetamiprid, alanicarb, aldicarb, alesulin, azamethiphos, azinphos-ethyl, azinphos-methyl, bacillus thuringiensis, bendiocarb, benfurthrin, benfuracarb, bensultap, bifenthrin, bioreslin , Violesmethrin, bistrifluron, buprofezin, butocarboxyme, carbaryl, carbofuran, carbosulfan, cartap, chloranthraniprole, chlorethoxyphos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormefos, chlorpyrifos, chlorpyrifos -Methyl, chromaphenozide, clothianidin, cyanophos, cyantraniliprole, cycloprotorin, Flutrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, ciphenothrin, cyromazine, deltamethrin, diafenthiuron, diazinon, dichlorvos, Diflubenzuron, dimethoate, dimethylvinphos, dinotefuran, geophenolan, disulfone, emamectin benzoate, empentrin, endosulfan, alpha-endosulfan, EPN, esfenvalerate, etiophencarb, ethiprole, etofenprox, etrimfos, fenitrothion, fenocarb, phenoxycarb Fenvalerate, fipronil, furo Tokin, flonicamid, fluazuron, flubenzilamide, flucycloxuron, flucitrinate, flufenemlim, flufenoxuron, flumethrin, flupyrazifrone, fluvalinate, tau-fluvalinate, honofos, furiocarb, halofenozide, hexaflumuron, hydramethylnon, Imidacloprid, imiprothrin, indoxacarb, indoxacarb-MP, isoprocarb, isoxathion, repimectin, lufenuron, malathion, meperfluthrin, metaflumizone, metaldehyde, methacrifos, methamidophos), metidathion, mesomil, mesoprene, methoxychlor, methoxyphenothromed Nitenpyram, Novallon, Nobiflumuron, Ometoate, Oxy (Demeton-methyl, parathion-methyl), permethrin, phenothrin, phentoate, folate, hosalon, phosmet, phoxime, pyrimicarb, pyrimiphos-methyl, profenofos, prothiophos, pymetrozine, pyraclophos, pyrethrin, pyridalyl, pyrifluquinazone, pyriprolol, pyriproxyfen, resmethrin , Rotenone, silafluophene, spinetram, spinosad, spirotetramate, sulfotep, sulfoxafurol, tebufenozide, teflubenzuron, tefluthrin, terbufos, tetrachlorobinphos, tetramethrin, dT-80-phthalthrin, tetramethylfluthrin, thiacloprid, thiamethoxam , Thiodicarb, Thiophanox, Thiometon, Tolfenpi De, tralomethrin, transfluthrin, triazamate, trichlorfon, triflumuron, ANM-138 and IKI-3106.
Active ingredient group D (acaricide): acequinosyl, acrinathrin, amidoflumet, amitraz, azocyclotin, benzoximate, biphenazate, bromopropyrate, clofentedine, cienopyrafen, cyflumetofen, dicohol, dienochlor, etoxazole, phenazaquin, fenbutatin-oxide , Phenothiocarb, fenpropatoline, fenpyroximate, fluacrylpyrim, formethanate, harfenprox, hexythiazox, milbemectin, propargite, pyridaben, pyrimidifen, spirodiclofen, spiromesifen, tebufenpyrad and NNI-0711.
Active ingredient group E (Anthelmintic): acriflavine, albendazole, atovacon, azithromycin, bithionol, bromfenofos, cambendazole, carnidazole, chloroquine, clazyl, clindamycin, chlorthrone, closantel, coumaphos, cymazole, dichlorophen, diethyl Carbamazine, diminazen, disophenol, dithiazanine iodide, doxycycline, doramectin, emodepside, eprinomectin, fevantel, fenbendazole, fulbendazole, furazolidone, glycalpyramide, imidocarb, ivermectin, levamisole, mebendazole, mefloquine, melarquine dihydrochloride, Metronidazole, methylidyne, milbemycin oxime, monepantel, morantel tartrate, moxy Kuctin, Nicarbazin, Niclosamide, Nitroscanate, Nitroxinyl, Omphalotin, Oxantel pamoate, Oxantel tartrate, Oxfendazole, Oxybendazole, Oxyclozanide, Pamaquine, Phenothiazine, Piperazine adipate, Piperazine citrate, Piperazine phosphate, PNU-97333 , PNU-141962, Pradiquantel, Primaquine, Propetamphos, Propoxur, Pyrantel pamoate, Pyrimethamine, Santonin, Seramectin, Sulfadimethoxine, Sulfadoxine, Sulfamelazine, Sulfamonomethoxine, Sulfamoyldapson, Thiabendazole, Tinidazole, Toltrazil, Tribrom Saran and triclabendazole.
Active ingredient group F (antibacterial agent): amoxicillin, ampicillin, betoxazine, bithionol, bronopol, cefapirin, cefazolin, cefquinome, ceftiofur, chlortetracycline, clavulanic acid, danofloxacin, difloxacin, dinitramide, enrofloxacin, florfenicol, linco Mycin, Lomefloxacin, Marvofloxacin, Miloxacin, Milosamycin, Nitrapyrin, Norfloxacin, Octylinone, Ofloxacin, Orbifloxacin, Oxolinic acid, Oxytetracycline, Penicillin, Streptomycin, Thiamphenicol, Tiamulin fumarate, Tilmicosine phosphate Tylosin valerate, tylosin phosphate, turathromycin, barnemlin, calcined shellfish Beam, Talaromyces genus, Trichoderma spp. And Yuniochiriumu genus.
Active ingredient group G (antifungal agent): ketoconazole and miconazole nitrate;
Said insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal composition which is a compound selected from. The substituent of formula (1) according to claim 1 has the following meaning:
[Wherein A ¹ represents a carbon atom or a nitrogen atom,
A ² and A ³ represent a carbon atom,
G represents a benzene ring,
X is a halogen atom, nitro, cyano, C ₁ -C ₆ represents alkyl, C ₁ -C ₆ haloalkyl, the -OR ⁵ or -S (O) _{r R} ^5, when m is 2 or 3, each of the X may be the same as or different from each other;
Y is a halogen atom, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₃ alkoxy (C ₁ ~C ₃₎ alkyl, -SR ^5, or -N (R ⁷⁾ R ⁶ Represent,
R ¹ is hydrogen atom, C ₁ -C ₆ alkyl, optionally substituted by R ¹³ (C ₁ ~C ₆₎ alkyl, C ₃ -C ₆ cycloalkyl, optionally substituted by R ¹³ (C ₃ -C ₆₎ cycloalkyl, E4, E5, E12, C 3 ~C 6 alkenyl, C ₃ -C ₆ haloalkenyl, C ₃ -C ₆ alkynyl, C ₁ -C ₆ alkylcarbonyl, -CH = NOR ^15, - C (O) OR ¹⁵ , -C (O) N (R ¹⁷ ) R ¹⁶ , -C (S) OR ¹⁵ , -C (S) N (R ¹⁷ ) R ¹⁶ , -C (OR ¹⁵ ) = NOR ¹⁵ , -C (NH ₂ ) = NCN, -C (NH ₂ ) = NOR ¹⁵ , -C (NH ₂ ) = NNO ₂ , -N (R ¹⁷ ) R ¹⁶ , phenyl, phenyl substituted by (Z) _p1 , D5-D8, D10, D17 or D32-D35,
R ² is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ alkenyl, C ₃ -C optionally substituted by R ^13a ₆ ^{alkynyl, -C (O) R 14a,} -C (O) oR 15a, -C (O) C (O) oR 15a, -C (S) or represents oR ^15a or C ₁ -C ₆ haloalkylthio, Alternatively, R ² represents that may form together with ^{R 1 = C (R 2a)} R 1a,
R ^1a represents C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy or -N (R ^17b ) R ^16b ,
R ^2a represents C ₁ -C ₆ alkyl, C ₁ -C ₆ alkylthio or —N (R ^17c ) R ^16c , or R ^2a together with R ^1a represents —N (R ^17c ) CH═ It represents that by forming CHS-, a 5-membered ring may be formed with the carbon atom to which R ^1a and R ^2a are bonded,
R ³ represents C ₁ -C ₆ haloalkyl,
Z is a halogen atom, nitro, cyano, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy or C ₁ -C ₆ alkylsulfonyloxy, p1 and p2 are an integer of 2 or more Each Z may be the same as or different from each other;
R ⁵ represents C ₁ -C ₆ alkyl or C ₁ -C ₆ haloalkyl,
R ⁶ represents C ₁ -C ₆ alkyl, —CHO, C ₁ -C ₆ alkylcarbonyl or C ₁ -C ₆ alkoxycarbonyl,
R ⁷ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ¹² represents C ₁ -C ₆ alkyl;
R ¹³ is a halogen atom, cyano, C ₃ -C ₆ ^{cycloalkyl, E4, E7, -OR 24,} -N (R 25) R 24, -S (O) r R 26, C 1 ~C 6 alkyl carbonyl ^{, -C (R 27) = NOR} 28, -C (O) N (R 29) R 28, -C (S) NH 2, phenyl, phenyl substituted by _{(Z) p1, D1, D5} , D7, D8, D10, D13, D16, D17, D22, D32 or D34,
R ^13a represents cyano, -OR ²⁴ , -S (O) _r R ²⁶ or D32,
R ^14a is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₄ alkoxy (C ₁ -C ₄ ) alkyl, C ₁ -C ₄ alkylthio (C ₁ -C ₄ ) alkyl, C ₁ -C ₄ alkylsulfinyl (C ₁ ~C ₄₎ alkyl, C ₁ -C ₄ alkylsulfonyl (C ₁ ~C ₄₎ alkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ Alkynyl, phenyl, phenyl substituted by (Z) _p1 or D32,
R ¹⁵ represents C ₁ -C ₆ alkyl, (C ₁ -C ₄ ) alkyl or C ₂ -C ₆ alkenyl optionally substituted by R ³⁰ ,
R ^15a is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₄ alkoxy (C ₁ -C ₄ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₃ -C ₆ alkynyl or phenyl,
R ¹⁶ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₄ ) alkyl optionally substituted by R ³⁰ , C ₃ -C ₆ alkenyl, C ₁ -C ₆ alkylcarbonyl, C ₁ -C ₆ haloalkylcarbonyl, C ₁ -C ₆ alkoxycarbonyl, represents phenyl, phenyl, the D32 or D34 substituted by (Z) _p1,
R ¹⁷ represents a hydrogen atom, C ₁ -C ₆ alkyl, C ₃ -C ₆ alkenyl or C ₃ -C ₆ alkynyl,
R ^16b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ^17b represents a hydrogen atom or a C ₁ -C ₆ alkyl,
R ^16c represents a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl or C ₁ -C ₆ alkoxy;
R ^17c represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²¹ represents C ₁ -C ₆ alkyl;
R ²⁴ represents a hydrogen atom, C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl, -C (O) R ³¹ or -C (O) OR ³² ,
R ²⁵ represents a hydrogen atom or C ₁ -C ₄ haloalkyl,
R ²⁶ represents C ₁ -C ₆ alkyl,
R ²⁷ represents a hydrogen atom or a C ₁ -C ₄ alkyl,
R ²⁸ is C ₁ -C ₄ alkyl, (C ₁ -C ₄ ) alkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₄ alkenyl or C ₃ -C ₄ alkynyl optionally substituted by R ³⁰ . Represent,
R ²⁹ represents a hydrogen atom or C ₁ -C ₄ alkyl,
R ³⁰ represents a halogen atom, C ₃ -C ₆ cycloalkyl, —OH, C ₁ -C ₄ alkoxycarbonyl, phenyl, phenyl substituted by (Z) _{p 1} or D 32,
R ³¹ represents C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl or C ₃ -C ₆ cycloalkyl,
R ³² represents C ₁ -C ₄ alkyl,
m represents an integer of 1, 2 or 3,
n represents an integer of 0 or 1,
p1 represents an integer of 1, 2 or 3,
p2 represents an integer of 0, 1 or 2;
p3 and p4 represent an integer of 0 or 1,
q2 represents an integer of 0 or 1,
q3 and q4 represent 0,
The insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition according to claim 1, comprising Compound I having t represents 0], or a tautomer, enantiomer, diastereomer or salt thereof.   3. An active compound II selected from the group D consisting of acequinosyl, cyflumetofen, dienochlor, etoxazole, phenazaquin, phenbutatin oxide, milbemectin, sienopyrafen, propargite, spirodiclofen and spiromesifen. The insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition according to any one of the above.   3. An active compound II selected from the group C consisting of chlorfenapyr, pyridaben, acephate, acetamiprid, flonicamid, imidacloprid, nitenpyram, pyrifluquinazone, pymetrozine, thiacloprid, thiamethoxam, clothianidin and tolfenpyrad. An insecticidal, acaricidal, nematicidal, bactericidal or bactericidal composition as described in the section.   One or more active compounds I according to claim 1 and one or more active compounds II according to claim 1 are treated simultaneously or close in time. How to control pests and diseases.   One or more active compounds I according to claim 2 and one or more active compounds II according to claim 1 are treated simultaneously or close in time. How to control pests and diseases.   One or more active compounds I according to any one of claims 1 to 2 and one or more active compounds II according to claim 3 are simultaneously or temporally close to each other. A method for controlling pests and ticks, characterized by   The one or more active compounds I according to any one of claims 1 to 2 and the one or more active compounds II according to claim 4 are simultaneously or temporally close to each other. A method for controlling pests and ticks, characterized by