JP2021075485A - Pest control agent and pest control method - Google Patents

Abstract

To provide a pest control composition and a method for controlling pests.SOLUTION: The present disclosure provides a pest control composition containing fluxametamide and teflubenzuron, and a method for controlling pests.SELECTED DRAWING: None

Description

The present invention relates to a pest control agent composition and a pest control method.

Fluxametamide, which is the first active ingredient compound in the composition of the present invention, is known to have an activity related to a pest control agent as an isoxazoline-substituted benzamide compound (see, for example, Patent Document 1).

Further, teflubenzurone, which is the second active ingredient compound in the composition of the present invention, is known to have an activity related to a pest control agent as a urea derivative (see, for example, Patent Document 2).
International Publication No. 2007/026965 Pamphlet Japanese Unexamined Patent Publication No. 57-126460

Today, the development of pest control agents for the purpose of controlling various pests such as agricultural and horticultural pests, forest pests, and sanitary pests has been widely promoted, and a wide variety of chemicals have been put into practical use. However, in recent years, as a result of pests acquiring pesticide resistance due to the long-term use of such drugs, there are increasing cases where it is difficult to control them with conventional drugs. Some of these drugs are also highly toxic, and some are disrupting ecosystems by remaining in the environment for long periods of time. Therefore, it is always expected to develop a new drug that not only has a high pest control effect but also has low toxicity and low persistence.

However, on the other hand, considering the diversity of insects and pathogens as a group of organisms, the mode of damage, and the variety of scenes of damage, all control situations can be achieved by using these new drugs or existing known drugs alone. It is extremely difficult to effectively control all pests. Therefore, there is a strong demand for a new method for controlling pests that are difficult to control by appropriately combining a plurality of pest control agents to induce a higher control effect.

In view of these circumstances, the present inventors are diligent in developing a pest control agent that exhibits excellent pest control activity and has little adverse effect on non-target organisms such as mammals, fish and natural enemies / beneficial insects. As a result of continuing research, the present invention including the following forms has been completed.

That is, the present invention relates to the following compositions [1] to [2] (hereinafter referred to as the composition of the present invention) and the control method of [3] (hereinafter referred to as the method of the present invention).

[1]
A pest control agent composition containing fluxametamid or a salt thereof and teflubenzurone or a salt thereof.

[2]
The pest control agent composition according to the above [1], wherein the weight ratio of fluxametamid or a salt thereof to teflubenzurone or a salt thereof is 100: 1 to 1: 100.

[3]
A method for controlling pests, which comprises treating fluxametamid or a salt thereof and teflubenzurone or a salt thereof simultaneously or in close proximity in time.

The composition of the present invention and the method of the present invention exert an excellent synergistic control effect on pests, and also have a sufficient synergistic control effect on pests that have acquired resistance to existing pest control agents. Demonstrate. Therefore, the present invention can provide a useful novel pest control agent composition and an effective control method using them.

Fluxametamide, which is the first active ingredient of the composition of the present invention, is known as an isoxazoline-substituted benzamide compound and is represented by the following formula (1) (CAS No .: 928783-29-3, generic name: fluxametamide). Is. Fluxamethamide is, for example, a known compound described in International Patent Application Publication No. 2007/026965.

Fluxamethamides include optically active substances due to the presence of one asymmetric carbon atom on the isoxazoline ring, but include racemates or optically active substances.

Fluxamethamide may also include a mixture containing the E-form in any proportion.

Fluxamethamide can be made into an acid addition salt according to a conventional method, for example, salts of hydrohalogenates such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydroiodide, nitric acid, sulfuric acid, phosphoric acid, etc. Salts of inorganic acids such as chloric acid and perchloric acid, salts of sulfonic acids such as methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, formic acid, acetic acid, propionic acid, tri Fluoroacetic acid, fumaric acid, tartaric acid, oxalic acid, maleic acid, malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid, citric acid and other carboxylic acid salts or glutamate and aspartic acid and other amino acids. Can be salt.

Alternatively, fluxamethamide can be made into a metal salt according to a conventional method, for example, an alkali metal salt such as lithium, sodium or potassium, an alkaline earth metal salt such as calcium, barium or magnesium or an aluminum salt. Can be done.

Teflubenzuron, which is the second active ingredient of the composition of the present invention, is known as a urea derivative and is a compound represented by the following formula (2) (CAS No .: 83121-18-0, generic name: teflubenzuron). .. Teflubenzlon is, for example, a known compound described in Japanese Patent Application Publication No. 57-126460.

Teflubenzlon can be made into an acid addition salt according to a conventional method, for example, salts of hydrohalogen acids such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydroiodide, nitric acid, sulfuric acid, phosphoric acid, etc. Salts of inorganic acids such as chloric acid and perchloric acid, salts of sulfonic acids such as methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, formic acid, acetic acid, propionic acid, tri Fluoroacetic acid, fumaric acid, tartaric acid, oxalic acid, maleic acid, malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid, citric acid and other carboxylic acid salts or glutamate and aspartic acid and other amino acids. Can be salt.

Alternatively, teflubenzlon can be made into a metal salt according to a conventional method, for example, an alkali metal salt such as lithium, sodium or potassium, an alkaline earth metal salt such as calcium, barium or magnesium or an aluminum salt. Can be done.

The active ingredients in the composition of the present invention, fluxametamid and teflubenzurone, can be applied by various application methods as follows.
1. 1. Simultaneous application, that is,
a) Mixed application (ie, for example as a mixture such as a ready-to-use formulation, or as a tank mixture)
b) Individual application (ie, application in separate tanks) or
2. Continuous individual application, in this case the order, generally has no effect on the results of this control method.

Therefore, the method of controlling pests is to apply fluxametamid and teflubenzurone separately or together, or by a mixture of fluxametamid and teflubenzurone, before or after sowing, or before or after plant emergence, seeds. It is done by spraying or dusting on plants or soil.

The ratio between the active ingredient in the composition of the present invention and the active ingredient in the method of the present invention is usually 500: 1 to 1: 100, preferably 20: 1 to 1:50, particularly 5: 1 to 1:20 for fluxametamid and teflubenzlone. It can be applied by weight ratio.

The weight ratio of fluxametamid and teflubenzurone in the composition of the present invention and the method of the present invention is usually used in the range of 100: 1 to 1: 100, preferably 20: 1 to 1:20, particularly 10: 1 to 1:10. You can.

The preferable treatment amount of fluxametamid and teflubenzurone in the composition of the present invention and the method of the present invention depends on the type of the target pest to be controlled and the like, but usually fluxametamide is 0.1 to 1000 gai / ha and teflubenzurone is 0.1 to 1000 gai. / Ha, preferably the former is 1 to 300 gai / ha and the latter is 1 to 300 gai / ha.

The composition of the present invention comprises so-called agricultural pests that harm agricultural and horticultural crops and trees, agricultural diseases, so-called livestock pests that parasitize livestock and poultry, so-called sanitary pests that adversely affect the human living environment such as houses, and similar. It can be applied to pests that occur and harm in the scene. Specific examples of pests that can be controlled using the composition of the present invention are as follows, but the pests are not limited to these.

Pests include the sawfly Chestnut gall wasp (Dryocosmus kuriphilus), the Argentine ant (Linepithema humile), the army ant Army ant (Eciton burchelli, E. schmitti), the black ant Japanese carpenter ant (Camponotus japonicus), and the ant (Camponotus japonicus). , Bulldog ant (Myrmecia spp.), Fire ant (Solenopsis spp.), Asian giant hornet (Vespa mandarina), Japanese yellow hornet (Vespa simillima), Large rose sawfly (Arge pagana) ), Sawfly European pine sawfly (Neodiprion sertifer), Chestnut sawfly (Apethymus kuri), Seguro sawfly Cabbage sawfly (Athalia infumata), Sawfly Turnip sawfly (Athalia rosae), etc.
Nashichibiga Pear leaf miner (Bucculatrix pyrivorella), Chanohosoga Tea leafroller (Caloptilia theivora), Kinmonhosoga Apple leafminer (Phyllonorycter ringoniella), Mikanhamogriga Citrus leafminer (Phyllocnistis citrella), Imokibaga Sweat Chilo suppressalis Persimmon fruit moth (Stathmopoda masinissa), Pyraloid moth Peach fruit moth (Carposina sasakii), Diamondback moth Allium leafminer (Acrolepiopsis sapporensis), Yamanoimokoga Yam leafminer (Acrolepiopsis suzukiella) ), Diamondback moth (Plutella xylostella), Chilo suppressalis Rice stem borer (Chilo suppressalis), Bluegrass webworm (Parapediasia teterrella), Cabbage webworm (Hellula undalis), Kobunomeiga Rice leafroller (Cnaphalo moth (Conogethes punctiferalis), cotton corn borer Cucumber moth (Diaphania indica), corn borer Mulberry pyralid (Glyphodes pyloalis), corn borer Asian corn borer (Ostrinia furnacalis), European corn borer European corn bo rer (Ostrinia nubilalis), Azuki bean borer (Ostrinia scapulalis), Morokoshimadarameiga Lesser corn stalk borer (Elasmopalpus lignosellus), Shiroichimojimadarameiga Limabean pod borer (Etiella zinckenella) ), Codling Moth Cherry tree borer (Synanthedon hector), Kubia Caskashiba (Toleria romanovi), Iraga Oriental moth (Monema flavescens), Aoi Raga (Parasa consocia), Hirohelia Oiraga (Parasa lepida), Kuroshita Aoi Raga (Parasa siniea) martini), apple tortrix moth (Illiberis pruni), Umeska cycloba (Illiberis rotundata), Himebokuto Carpenter moth (Cossus insularis), Codling moth (Cydia pomonella), Sumomohime sinki Plum fruit moth (Grapholita dimorpha), Oriental fruit moth (Grapholita dimorpha) Grapholita molesta), Soybean pod borer (Leguminivora glycinivorella), Soybean podworm (Matsumuraeses phaseoli), Grape berry moth (Endopiza viteana), Chanokokakumonhamaki Smaller tea tortrix (Adoxo) Kumon Hamaki Summer fruit tortrix (Adoxophyes orana fasciata), Ringo Monhamaki Asian leafroller (Archips breviplicanus), Midareka Kumon Hamaki Apple tortrix (Archips fu) scocupreanus), Chahamaki Oriental tea tortrix (Homona magnanima), Tobihamaki Dark fruit-tree tortrix (Pandemis heparana), Matsukareha Pine moth (Dendrolimus spectabilis), Tsugacareha Jananese hemlock caterpillar (Dendrolimus moans) Yoshikareha Drinker moth (Euthrix potatoria), Kalehaga Oriental lappet (Gastropacha orientalis), Kunugia undans, Yamada Kaleha (Kunugia yamadai), Tomato hornworm Tomato hornworm (Manduca quinquemaculata), Tomato hornworm (Manduca quinquemaculata) webworm moth (Hyphantria cunea), Kunugia tiger moth (Lemyra imparilis), Yanehosoba (Eilema fuscodorsalis), Tsumakihosoba (Eilema laevis), Dokuga Oriental tussock moth (Artaxa subflava) Euproctis pseudoconspersa), Swan moth (Sphrageidus similis), Gypsy moth (Lymantria dispar), White-spotted tussock moth (Orgyia thyellina), Futaobikoyaga Rice green caterpillar (Naranga aenesc) potato leaf worm (Aedia leucomelas), Yotoga Cabbage army worm (M) amestra brassicae), Awayoto Oriental armyworm (Pseudaletia separata), Spodoptera litura Lawn grass cutworm (Spodoptera depravata), Southern armyworm (Spodoptera eridania), Spodoptera litura Beet armyworm (Spodoptera exigua) Leafworm Cotton leafworm (Spodoptera littoralis), Spodoptera litura Common cutworm (Spodoptera litura), Helicoverpa armigera, Cotton bollworm Oriental tobacco budworm (Helicoverpa assulta), Corn earworm Tobacco budworm (Heliothis viresc) zea), Helicoverpa armigera Black cutworm (Agrotis ipsilon), Helicoverpa armigera Turnip moth (Agrotis segetum), Helicoverpa armigera Asiatic common looper (Autographa nigrisigna), Spodoptera litura Threespotted plusia (Ctenoplusia agnata), Soibean looper Uwaba Cabbage looper (Trichoplusia ni), Japanese giant looper (Ascotis selenaria), Helicoverpa armigera Large white (Pieris brassicae), Spodoptera litura Cabbage white butterfly (Pieris rapae crucivora), Spodoptera litura (Alabama ar Gillacea), Lepidoptera insects such as sugarcane borer (Diatraea sacharalis),
Agromyzidae Melon fly (Bactrocera cucurbitae), Agromyzidae Oriental fruit fly (Bactrocera dorsalis), Queensland fruit fly (Bactrocera tryoni), Agromyzidae Japanese orange fly (Bactrocera tsuneonis) fly (Anastrepha ludens), leafminer Apple maggot (Rhagoletis pomonella), leafminer leafminer Rice leaf miner (Agromyza oryzae), leafminer Pea leaf miner (Chromatomyia horticola), leafminer leafminer Cabbage leafminer (Liriomyza brassicae) ), Agromyzidae Stone leek leafminer (Liriomyza chinensis), Agromyzidae Pea leafminer (Liriomyza huidobrensis), Tomato leafminer (Liriomyza sativae), Agromyzidae Serpentine leafminer (Liriomyza trifolii) Agromyzidae Smaller rice leaf miner (Hydrellia griseola), Tsetse fly (Glossina morsitans, G. palpalis), Agromyzidae Forest fly (Hippobosca equina), Sheep ked (Melophagus ovinus) Sheep ked (Melophagus ovinus) corn maggot (Delia platura), Agromyzidae D. Beet leaf miner (Pegomya cunicularia), Himei Eflies Lesser house fly (Fannia canicularis), Sheep headfly (Hydrotaea irritans), Sweet fly (Morellia simplex), Face fly (Musca autumnalis), Flies Housefly (Musca autumnalis) domestica), Australian bush fly (Musca vetustissima), flies Horn fly (Haematobia irritans), flies Stable fly (Stomoxys calcitrans), flies (Calliphora lata), flies Bottle fly (Calliphora vicina), old world flies (Calliphora vicina) -worm fly (Chrysomya bezziana), Blow fly (Chrysomya chloropyga), Obikin fly Oriental latrine fly (Chrysomya megacephala), American Obikin fly (Cochliomyia hominivorax), Crokin fly Black blow fly (Phormia regina), Rurikin fly (Phormia regina). Northern blowfly (Protophormia terraenovae), sheep fly Australian sheep blowfly (Lucilia cuprina), green fly fly (Lucilia illustris), hirozukin fly Common green bottle fly (Lucilia sericata), bot flies (Cuterebra spp.) (Dermatobia hominis), Atokauma fly Horse nose bot fly (Gasterophilus haemorrhoidalis), Horse fly Horse bot fly (Gasterophilus) intestinalis), Anopheles mosquito Throat bot fly (Gasterophilus nasalis), Anopheles mosquito Warble fly (Hypoderma bovis), Anopheles mosquito Common cattle grub (Hypoderma lineatum), Anopheles Sheep nasal bot fly (Oestrus ovis) Flesh fly (Sarcophaga peregrina), Splayed deerfly (Chrysops caecutiens), Meclaab Deer fly (Chrysops suavis), Common horse fly (Haematopota pluvialis), Greenhead horse fly (Tabanus nigrovittatus), Ushiab Horse fly (Tabanus trigonus), Anopheles pod gall midge (Asphondylia yushimai), Hessian fly (Mayetiola destructor), Anopheles mosquito Orange wheat blossom midge (Sitodiplosis mosellana), Anopheles mosquito, Biting midge (Culicoides) Nukaka Black gnat (Leptoconops nipponensis), Chiacio obyu (Prosimulium yezoensis), Black fly (Simulium ochraceum), Anopheles gambiae African malaria mosquito (Anopheles gambiae), Anopheles gambiae, Anopheles hyrcanus sinesis Yellow fever mosquito (Aedes aegypti), Anopheles mosquito Asian tiger mosquito (Aedes albopictus), Anopheles mosquito House m osquito (Culex pipiens molestus), Culex pipiens house mosquito (Culex pipiens pallens), Culex tritaeniorhynchus, Culex tritaeniorhynchus, Sandfly (Phlebotomus spp.), Psychodidae Moth fly (Telmatoscopus albipunctus)
Chigoe flea (Ceratophyllus gallinae), Chigoe flea (Tunga penetrans), Dog flea (Ctenocephalides canis), Cat flea (Ctenocephalides felis), Cat flea (Ctenocephalides felis), Chigoe flea (Echidnophaga gallinae) , Siphonaptera insects such as Oriental rat flea (Xenopsylla cheopis),
Tobacco beetle (Lasioderma serricorne), common bean weevil (Acanthoscelides obtectus), adzuki bean beetle (Callosobruchus chinensis), grape tiger beetle Grape borer (Xylotrechus pyrrhoderus) White-spotted longicorn beetle (Anoplophora malasiaca), Japanese pine sawyer (Monochamus alternatus), Yellow-spotted longicorn beetle (Psacothea hilaris), Colorado beetle beetle (Phaedon cochleariae), Inedro beetle Rice leaf beetle (Oulema oryzae), Madara Casahara beetle Reaf beetle (Demotina fasciculata), Uri beetle Cucurbit leaf beetle (Aulacophora femoralis), Tensite beetle Beet flea beetle Northern corn rootworm (Diabrotica barberi), Juichihoshiurihamushi Southern corn rootworm (Diabrotica undecimpunctata), Western corn rootworm (Diabrotica virgifera), Kisujinomi beetle Striped flea beetle (Phyllotreta striolata) ticollis), Ingentento Mexican been beetle (Epilachna varivestis), Onijuya Hoshitento Large twenty-eight-spotted ladybird (Epilachna vigintioctomaculata), Nijuya Hoshitento Twentyeight-spotted ladybird (Epilachna vigintioctopunctata) , Pollen beetle (Meligethes aeneus), peach weevil Peach curculio (Rhynchites heros), arimodoki weevil Sweetpotato weevil (Cylas formicarius), weevil West Indian sweet potato weevil (Euscepes postfasciatus) White-fringed beetle (Graphognatus leucoloma), weevil Black vine weevil (Otiorhynchus sulcatus), Alfalfa weevil (Hypera postica), Granaria weevil Granary weevil ), Shibaosa weevil Hunting billbug (Sphenophorus venatus vestitus), rice weevil Rice plant weevil (Echinocnemus squameus), rice weevil Rice water weevil (Lissohoptrus oryzophilus) ), Marukubikushikometsuki Sweetpotato wireworm (Melanotus fo) rtnumi), Sugarcane wireworm (Melanotus tamsuyensis), Koaohanamuri Citrus flower chafer (Gametis jucunda), Nagachakogane Yellowish elongate chafer (Heptophylla picea), Douganebuibui Cupreous chafer (Anomala cuprea) Japanese beetle (Popillia japonica), Coleoptera insects such as Rove beetle (Paederus fuscipes),
Aphid Asian citrus psyllid (Diaphorina citri), Aphid Pear sucker (Psylla pyrisuga), Aphid Camellia spiny whitefly (Aleurocanthus camelliae), Aphid Aphid Orange spiny whitefly (Aleurocanthus spiniferus) Aphid Sweetpotato whitefly (Bemisia tabaci), Aphid Citrus whitefly (Dialeurodes citri), Greenhouse whitefly (Trialeurodes vaporariorum), Pea aphid (Acyrthosiphon pisum), Aphid (Acyrthosiphon pisum), Aphid (Acyrthosiphon pisum) (Aphis fabae), soybean aphid (Aphis glycines), cotton aphid Cotton aphid (Aphis gossypii), apple aphid Green apple aphid (Aphis pomi), snow aphid Spiraea aphid (Aphis spiraecola), potato aphid ), Leaf curl plum aphid (Brachycaudus helichrysi), Daikon aphid Cabbage aphid (Brevicoryne brassicae), Walnut aphid (Chromaphis juglandicola), Russian wheat aphid Russian wheat aphid aphid (Dysaphis plantaginea), Momokofuki aphid Mealy plum aphid (H) yalopterus pruni), fake aphid Turnip aphid (Lipaphis erysimi), tulip aphid Potato aphid (Macrosiphum euphorbiae), black margined aphid Blackmargined aphid (Monellia caryella), peach aphid green peach aphid Lettuce aphid (Nasonovia ribisnigri), Neotoxoptera formosana, Bird cherry-oat aphid (Rhopalosiphum padi), Aphid aphid Rice root aphid (Rhopalosiphum rufiabdominalis) ), English grain aphid (Sitobion avenae), greenbug (Schizaphis graminum), black citrus aphid (Toxoptera aurantii), brown citrus aphid (Toxoptera citricida), apple aphid aphid (Eriosoma lanigerum), grape aphid Grape phylloxera (Viteus vitifolii), horn aphid Indian wax scale (Ceroplastes ceriferus), ruby aphid Red wax scale (Ceroplastes rubens) Aonidiella aurantii), San jose scale (Comstockaspis perniciosa), Tea scale (F) iorinia theae), Chanomarukaigaramushi Peony scale (Pseudaonidia paeoniae), Kuwashirokaigaramushi Mulberry scale (Pseudaulacaspis pentagona), Umeshirokaigaramushi White peach scale (Pseudaulacaspis prunicola), Niseyanonekaigaramushi Citrus snow scale Euonymus scale (Unaspis euonymi), Yanone scale insect Arrowhead scale (Unaspis yanonensis), Owaraj scale insect Giant margarodid scale (Drosicha corpulenta), Iselia scale insect Cottony cushion scale (Icerya purchasi), Nascona scale insect Cotton Citrus scale insect Citrus mealybug (Planococcus citri), Japanese scale insect Japanese mealybug (Planococcus kuraunhiae), Kuwakon scale insect Comstock mealybug (Pseudococcus comstocki), Grape mealybug (Pseudococcus brown) rice planthopper (Nilaparvata lugens), white-backed rice planthopper (Sogatella furcifera), scale leafhopper (Epiacanthus stramineus), Indian cotton leafhopper (Amrasca devastans), green scale insect , Futaten Yokobai Aster leafhopper (Ma crosteles fascifrons), Himeftaten Yokobai (Macrosteles striifrons), Tsumaguro Yokobai Green rice leafhopper (Nephotettix cincticeps), Futaten Himeyokobai Grape Leafhopper (Arboridia apicalis), Potato Leafhopper Potato Leafhopper (Empoasca fabae) , Chanomidorihimeyokobai Tea green leafhopper (Empoasca onukii), Mamenomidorihimeyokobai Bean's smaller green leafhopper (Empoasca sakaii), Buchihigekamemushi Sloe bug (Dolycoris baccarum), Nagame Cabbage bug (Eurydema rugosa) bug (Eysarcoris aeneus), stink bug (Eysarcoris lewisi), stink bug White-spotted stink bug (Eysarcoris ventralis), stink bug Sheild bug (Glaucias subpunctatus), stink bug green stink bug (Nezara antennata), Southern green stink bug (Nezara viridula), Redbanded stink bug (Piezodorus guildinii), Redbanded shield bug (Piezodorus hybneri), Chabane stink bug bug (Plautia crossota), stink bug Japanese black rice bug (Scotinophora lurida), stink bug Bean bug (Riptortus clavatus), spider helicopter Hemiptera Rice bug (Leptocorisa chinensis), Hemiptera: Rice stink bug (Cletus punctiger), Hemiptera: Squash bug (Paradasynus spinosus), Hemiptera: Rhopalid bug (Rhopalus maculatus), Hemiptera: leucopterus), Kanshakobanagakamemushi Oriental chinch bug (Cavelerius saccharivorus), Kobanehyotannagakamemushi Seed bug (Togo hemipterus), Akahoshikamemushi Red cotton bug (Dysdercus cingulatus), Venezuelan serrata bug (Triatoma dimidiata), Brazilian turtle Kissing bug (Triatoma infestans), green stink bug (Acrosternum hilare), blown stink bag brown stink bug (Euschistus servus), southern green stink bug (Nezara) viridula), Turnished plant bug (Lygus lineolaris), Stink bag (Dichelops furcatus), Sugar canspitle bag sugarcane spittlebug (Mahanarva fimbriolata), Tsutsujigunbai Azalea lace bug (Stephanitis pyrioides), Tokojirami Bed bug ), Pale greenplant bug (Apolygus spinolae), Western tarnished plant bug (Lygus hesperus), Sabiirokasumikame Tarnished plant bug (Ly) gus lineolaris), Nagamugi Kasumi turtle Rice stink bug (Stenodema sibiricum), Akasujikasumi turtle Sorghum plant bug (Stenotus rubrovittatus), Rice leaf bug (Trigonotylus caelestialium), Kurotobikasumi turtle Island fleahopper Hemiptera insects such as fleahopper (Pseudatomoscelis seriatus),
Thrips thrips (Frankliniella intonsa), Thrips thrips Western flower thrips (Frankliniella occidentalis), Thrips thrips Greenhouse thrips (Heliothrips haemorrhoidalis), Thrips thrips (Heliothrips haemorrhoidalis) Thrips (Thysanoptera) insects such as Thrips Onion thrips (Thrips tabaci), Thrips palmi Karny Japanese gall-forming thrips (Ponticulothrips diospyrosi)
Chicken Lice Body louse (Menacanthus cornutus), Usuiro Chicken Lice Small body louse (Menacanthus pallidulus), Chicken Lice Chicken body louse (Menacanthus stramineus), Chicken Lice Lice Chicken shaft louse (Menacanthus stramineus) (Cuclotogaster heterographa), Kakuagohajirami Brown chicken louse (Goniodes dissmilis), Himeniwatorihajirami Fluff louse (Goniodes gallinae), Maruhajirami Large hen louse (Goniodes gigas), Niwatori Nagahajirami Wing louse ), Cat louse (Felicola subrostrata), Dog biting louse (Trichodectes canis), Ushijirami Short-nosed cattle louse (Haematopinus eurysternus), Ushijirami Tail switch louse (Haematopinus quadripertusus) Buffalo louse (Haematopinus tuberculatus), Inujirami Dog sucking louse (Linognathus setosus), Ushihosojirami Long-nosed cattle louse (Linognathus vituri), Rabbit louse (Haemodipsus ventricosus), Kebukaushijirami Little blue cat Pediculus humanus), Hatsukanezumi Lice Mouse louse (Polypla) x serratus), Psocodea insects such as lice Crab louse (Pthirus pubis),
Desert locust (Schistocerca gregaria), Australian plague locust (Chortoicetes terminifera), Tonosama locust (Locusta migratoria), Oxya japonica Lesser paddy grasshopper (Oxya japonica), Oxya japonica (Teleogryllus emma), Orthoptera insects such as Kera Oriental mole cricket (Gryllotalpa orientalis),
Chabane termite German cockroach (Blattella germanica), Wamon termite American cockroach (Periplaneta americana), Kurogokiburi Smoky-brown cockroach (Periplaneta fuliginosa), Yamato termite Japanese cockroach (Periplaneta japonica), Daikoku termite Termite Western dry-wood termite (Incisitermes minor), termite Formosan subterranean termite (Coptotermes formosanus), termite Japanese subterranean termite (Reticulitermes speratus), termite Black-winged subterranean termite (Odontotermes formosanus) ,
Collembola hexapods such as Rootfeeding springtail (Onychiurus folsomi), Onychiurus sibiricus, Garden springtail (Bourletiella hortensis), etc.
Isopoda crustaceans such as Pill bug (Armadillidium vulgare) and Common rough woodlouse (Porcellio scaber)
Argulus coregoni, Japanese fishlouse (Argulus japonicus), Argulus scutiformis and other Lepidoptera crustaceans,
Siphonostomatoida crustaceans such as sea louse (Caligus curtus, C. elongatus), salmon louse (Lepeophtheirus salmonis), etc.
Itch mite Storage mite (Glycyphagus destructor), Itch mite House itch mite (Glycyphagus domesticus), Itch mite Brown-legged grain mite (Aleuroglyphus ovatus), Itch mite Cheese mite (Tyrophagus putrescentiae) , Itch mite Feather mite (Pterolichus obtusus), Itch mite Feather mite (Megninia cubitalis), Itch mite American house dust mite (Dermatophagoides farinae), Itch mite House dust mite (Dermatophagoides pteronys) bovis), Inumimi itch mite Dog ear mite (Otodectes cynotis), Ushikyusen itch mite Psoroptic mite (Psoroptes communis), Rabbit ear mite (Psoroptes cuniculi), Sheep scab mite (Psoroptes cuniculi) Sarcoptes scabiei), Astigmata mites such as Cat mange mite (Notoedres cati),
Oribatida mites such as Yesa Saladani (Haplochthonius simplex),
Minami Tsumedani (Chelacaropsis moorei), Neko Tsumedani (Cheyletiella blakei), Rabbit Tsumedani Rabbit fur mite (Cheyletiella parasitovorax), Inutsumedani (Cheyletiella yasguri), Hosotsumedani (Cheyletiella yasguri), Hosotsumedani (Cheyletus eruditus) ), Cat follicle mite (Demodex cati), Face mite (Demodex folliculorum), Wheat curl mite (Aceria tulipae), Pear rust mite (Eriophyes chibaensis), Peach bud mite (Eriophyes chibaensis) ), Pearleaf blister mite (Eriophyes pyri), Tea rust mite (Acaphylla theavagrans), Tomato russet mite (Aculops lycopersici), Pink citrus rust mite (Aculops pelek) mite (Aculus schlechtendali), citrus rust mite (Phyllocoptruta oleivora), Chano dust mite Broad mite (Polyphagotarsonemus latus), cyclamen dust mite Cyclamen mite (Phytonemus pallidus) Citrus red mite (Panonychus citri), spider mite Spider mite (Panonychus mori), apple spider mite European red mit e (Panonychus ulmi), Kanzawa spider mite (Tetranychus kanzawai), Nami spider mite Two-spotted spider mite (Tetranychus urticae), Hakusai mite (Penthaleus erythrocephalus), Wheat mite Winter grain mite (Penthaleus major) Prostigmata (Prostigmata) such as Trombiculid mite (Helenicula miyagawai), Leptotrombidium akamushi, Leptotrombidium pallida, Tetsutsugamushi mite (Leptotrombidium scutellare), etc.
English fowl tick (Argas persicus), Kazuki tick Soft tick (Ornithodoros moubata), Relapsing fever tick (Ornithodoros turicata), Spinose ear tick (Otobius megnini), Lone star tick (Lone star tick) Amblyomma americanum), Mexican Gulf tick Gulf coast tick (Amblyomma maculatum), Tsuriganechi tick (Haemaphysalis campanulata), Kitchi tick (Haemaphysalis flava), Futatogechi tick Bush tick (Haemaphysalis longicornis), Otogechi tick (Haemaphysalis longicornis), Otogechi tick (Haemaphysalis longicornis) aegyptium), Mediterranean tick (Hyalomma marginatum), Tick Tick Tropical cattle tick (Boophilus microplus), Tick Tick (Ixodes nipponensis), Tick Tick (Ixodes ovatus), Western Tick Tick (Ixodes pacif) (Ixodes persulcatus), sheep tick Castor bean tick (Ixodes ricinus), black-legged tick (Ixodes scapularis), tropical horse tick (Anocentor nitens), rocky mountain wood tick (Dermacentor andersoni), west coast tick Pacific Coast tick (Dermacentor occidentalis), Amimeka bear tick Ornate cow tick (Dermacentor reticulatus), American Dot American dog tick (Dermacentor variabilis), Rhipicentor spp., American cattle tick (Rhipicephalus annulatus), Brown dog tick (Rhipicephalus sanguineus), etc. ,
Red mite (Dermanyssus gallinae), Ornithonyssus tropical rat mite (Ornithonyssus bacoti), Northern fowl mite (Ornithonyssus sylviarum), Honeybee mite (Varroa destructor), Varroa destructor, etc. (Mesostigmata) Mites,
Apple snail (Pomacea canaliculata) and other snails (Architaenioglossa) gastropods,
African slug Giant African snail (Achatina fulica), slug Terrestrial slug (Limax marginatus), slug Slug (Meghimatium bilineatum), Acusta despecta sieboldiana, etc. Eyes (Stylommatophora) Slugs,
Giant kidney worm (Dioctophyma renale), ringed capillaria annulata, twisted trichuris Cropworm (Capillaria contorta), liver trichuris Capillary liver worm (Capillaria hepatica), perforator trichuris (Capillaria hepatica) perforans), Filipino capillaria philippinensis, Capillaria suis, Whipworm Whipworm (Trichuris discolor), Whipworm Whipworm (Trichuris ovis), Pig whipworm (Trichuris suis), Human Enoplida nematodes such as Human whipworm (Trichuris trichiura), Dog whipworm (Trichuris vulpis), Trichuris spiralis, etc.
Intestinal threadworm (Strongyloides papillosus), cat manure nematode (Strongyloides planiceps), pig manure nematode Pig threadworm (Strongyloides ransomi), human manure nematode Threadworm (Strongyloides stercoralis), Micronema spp. Threadworm (Rhabditida) Threadworm,
Brazilian hookworm Hookworm (Ancylostoma braziliense), dog hookworm Dog hookworm (Ancylostoma caninum), Zubini hookworm Old World hookworm (Ancylostoma duodenale), cat hookworm Cat hookworm (Ancylostoma tubaeforme), narrow-headed cowworm The Northern hookworm Cattle hookworm (Bunostomum phlebotomum), Small ruminant hookworm (Bunostomum trigonocephalum), New World hookworm (Necator americanus), Cyatostomum spp. spp.), Cylicostephanus spp., Donkey roundworm (Strongylus asini), Teethless roundworm (Strongylus edentatus), Horse roundworm Blood worm (Strongylus equinus), Common roundworm Blood worm (Strongylus vulgaris) Large-mouthed bowel worm (Chabertia ovina), Indian intestinal nodular worm (Oesophagostomum brevicaudatum), Colombian intestinal nodule worm (Oesophagostomum columbianum), Oesophagostomum dentatum, American Nodular worm (Oesophagostomum georgianum), Nodular worm (Oesophagostomum maplestonei), Nodular worm (Oesophagostomum quadrispinulatum), Nodular worm (Oesophagostomum radiatum) dular worm (Oesophagostomum venulosum), scrijabin worm (Syngamus skrjabinomorpha), chicken worm Gapeworm (Syngamus trachea), pig kidney worm Swine kidney worm (Stephanurus dentatus), couperia cattle bankrupt worm (Cooperia oncophora) Insect Red stomach worm (Hyostrongylus rubidus), wrinkled gastric hair worm Stomach hair worm (Trichostrongylus axei), serpentine hair-like nematode (Trichostrongylus colubriformis), oriental hair-like nematode Oriental trichostrongylus (Trichostrongylus orientalis), haemonchus red stomach worm (Haemonchus contortus), cattle stomach worm (Mecistocirrus digitatus), Ostertagia worm (Ostertagia ostertagi), filamentous lungworm Common lungworm (Dictyocaulus filaria), cow lungworm Bovine lungworm (Dictyocaulus viviparus), Thin-necked intestinal worm (Nematodirus filicollis), Swine lungworm (Metastrongylus elongatus), Lungworm (Filaroides hirthi), Lungworm (Crenosoma aerophila), Fox lungworm (Fox lungworm) Crenosoma vulpis), Canton worm Rat lung worm (Angiostrongylus cantonensis), Dictyocaulus French heartworm (Angiostrongylus vasorum), Protostrongylus spp.
Rice white tip nematode (Aphelenchoides besseyi), Pine wood nematode (Bursaphelenchus xylophilus), etc.
Potato cyst nematode (Globodera rostochiensis), wheat cyst nematode Cereal cyst nematode (Heterodera avenae), soybean cyst nematode (Heterodera glycines) -knot nematode (Meloidogyne hapla), Southern root-knot nematode (Meloidogyne incognita), Javanese root-knot nematode (Meloidogyne javanica), Minaminegusare nematode Coffee root-lesion nematode Root-lesion nematode (Pratylenchus loosi), Pratylenchus cobb's root-lesion nematode (Pratylenchus penetrans), Walnut root-lesion nematode (Pratylenchus vulnus), etc.
Oxyurida nematodes such as the human pinworm Pinworm (Enterobius vermicularis), the horse pinworm Equine pinworm (Oxyuris equi), and the rabbit pinworm Rabbit pinworm (Passalurus ambiguus),
Pig roundworm Pig roundworm (Ascaris suum), horse roundworm Horse roundworm (Parascaris equorum), small dog roundworm Dog roundworm (Toxascaris leonina), dog roundworm Dog intestinal roundworm (Toxocara canis), cat roundworm Feline roundworm (Toxocara cati), cattle roundworm Large Cattle roundworm (Toxocara vitulorum), Anisakis spp., Pseudoterranova spp., Caecal worm (Heterakis gallinarum), Chicken roundworm (Ascaridia galli), etc. Nematode,
Guinea worm (Dracunculus medinensis), Dolores gnathostomiasis (Gnathostoma doloresi), Gnathostoma hispidum, Japanese gnathostomiasis (Gnathostoma nipponicum), Reddish-coloured worm (Gnathostoma spinigerum) , Dog stomach worm (Physaloptera canis), Cat stomach worm (Physaloptera felidis, P. praeputialis), Lara gastric worm Feline / canine stomach worm (Physaloptera rara), Oriental eyeworm Eye worm (Thelazia callipaeda), Bovine eyeworm (Thelazia rhodesi), Large mouth stomach worm (Draschia megastoma), Equine stomach worm (Habronema microstoma), Stomach worm (Habronema muscae), Gullet worm (Gullet worm) Gongylonema pulchrum), Thick stomach worm (Ascarops strongylina), Cattle parafilaria (Parafilaria bovicola), Parafilaria multipapillosa, Okinawa filamentous insect (Stephanofilaria okinawaensis), Bancroft filaria Wuchereria bancrofti), Malay filamentous worm (Brugia malayi), cervical filamentous worm Neck threadworm (Onchocerca cervicalis), Gibson filamentous worm (Onchocerca gibsoni), pharyngeal filamentous worm Cattle filarial worm (Onchocerca gutturosa), rotating filamentous worm (Onchocerca vol Bovine filarial worm (Setaria digitata), Peri Rotal nematodes such as toneal worm (Setaria equina), lip papillary filamentous worm (Setaria labiatopapillosa), marshall filamentous worm (Setaria marshalli), heartworm Dog heartworm (Dirofilaria immitis), loa filamentous worm African eye worm (Loa loa) Eye (Spirurida) nematode,
Acanthocephalas such as Acanthocephala (Moniliformis moniliformis), Giant thorny-headed worm (Macracanthorhynchus hirudinaceus),
Pseudo-leaf such as Diphyllobothrium latum, Diphyllobothrium nihonkaiense, Manson tapeworm (Spirometra erinaceieuropaei), Diphyllobothrium grandis, etc. Eye (Pseudophyllidea) tapeworm,
Wired tapeworm (Mesocestoides lineatus), wheeled tapeworm Chicken tapeworm (Raillietina cesticillus), spiny tapeworm Fowl tapeworm (Raillietina echinobothrida), square tapeworm Chicken tapeworm (Raillietina tetragona), spore tapeworm Canine tapeworm (Taenia hydatigena), Canine tapeworm (Taenia multiceps), Sheep measles (Taenia ovis), Dog tapeworm (Taenia pisiformis), Beef tapeworm (Taenia saginata), Tapeworm (Taenia serialis) ), Pork tapeworm (Taenia solium), Feline tapeworm (Taenia taeniaeformis), Hydatid tapeworm (Echinococcus granulosus), Small fox tapeworm (Echinococcus multilocularis), Tapeworm (Echinococcus oligarthrus), Vogel tapeworm (Echinococcus vogeli), reduced tapeworm Rat tapeworm (Hymenolepis diminuta), small tapeworm Dwarf tapeworm (Hymenolepis nana), tapeworm Double-pored dog tapeworm (Dipylidium caninum), wedge-shaped tapeworm Insects (Amoebotaenia sphenoides), Tapeworms (Choanotaenia infundibulum), Tapeworms (Metroliasthes coturnix), Tapeworms Equine tapeworm (Anoplocephala magna), Tapeworms Cecal tapeworm (Anoplocephala perfoliata), Papillary tapeworms (Anoplocephala perfoliata) Paranoplocephala mamillana), Beneden tapeworm Common tapeworm (Moniezia be) nedeni), Moniezia expansa, Cyclophyllidea tapeworms such as Stilesia spp.
Blood fluke (Schistosoma haematobium), Schistosoma japonicum, Schistosoma japonicum, Schistosoma mansoni, Schistosoma mansoni, etc.
Echinostoma cinetorchis, Echinostoma hortense, Giant liver fluke (Fasciola gigantica), Fasciola hepatica, Fasciolopsis buski, Fasciolopsis buski Echinostomida insects, such as Homalogaster paloniae,
Continental fluke (Dicrocoelium chinensis), fluke Lancet liver fluke (Dicrocoelium dendriticum), African fluke African lancet fluke (Dicrocoelium hospes), small pancreatic fluke (Eurytrema coelomaticum), pancreatic fluke Pancreatic fluke (Eurytrema coelomaticum) Plagiorchiida flukes such as Paragonimus miyazakii, Paragonimus ohirai, Westermann fluke Lung fluke (Paragonimus westermani),
Amphimerus spp., Chinese liver fluke (Clonorchis sinensis), Cat liver fluke (Opisthorchis felineus), Southeast Aasian liver fluke (Opisthorchis viverrini), Pseum .), Metrokis spp., Parametorchis spp., Intestinal fluke (Heterophyes heterophyes), Metagonimus yokokawai, Pygidiopsis summa, etc. Opisthorchiida) Sucker,
Amoeba species such as Entamoeba histolytica, E. invadens,
Futago Babesia (Babesia bigemina), cow Babesia (Babesia bovis), large horse Babesia (Babesia caballi), dog Babesia (Babesia canis), cat Babesia (Babesia felis), Gibson dog Babesia (Babesia gibsoni), large pyroplasma (Babesia ovata) ), Cytauxzoon felis, tropical pyroplasma disease Tyrelia (Theileria annulata), pseudocoastal heat Tyrelia (Theileria mutans), small pyroplasma (Theileria orientalis), eastern coastal fever Tyrelia (Theileria parva), etc. Piroplasmida spores,
Haemoproteus mansoni, Leucocytozoon caulleryi, Plasmodium falciparum, Plasmodium malariae, Plasmodium ovale, Plasmodium ovale Haemosporida spores, such as Plasmodium vivax
Caryospora spp., Eimeria acervulina, Eimeria bovis, Eimeria brunetti, Eimeria maxima, Eimeria necatrix, Eimeria necatrix Obinoidalis (Eimeria ovinoidalis), rabbit liver sarcocystis (Eimeria stiedae), chicken sarcocystis (Eimeria tenella), dog sarcocystis (Isospora canis), cat sarcocystis (Isospora felis), pig sarcocystis (Isospora suis) , Tyzzeria anseris, Tyzzeria perniciosa, Wenyonella anatis, Wenyonella gagari, dog Cryptosporidium canis, cat cryptosporisdium, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis, sarcocystis. Cryptosporidium hominis, Cryptosporidium meleagridis, Cryptosporidium muris, Cryptosporidium parvum, Sarcocystis sarcocystis Sarcocystis sarcocystis Felis (Sarcocystis felis), human sarcocystis hominis, Sarcocystis miescheriana, Sarcocystis neurona, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella, Sarcocystis tenella gondi i), true coccidia (Eucoccidiorida) parasitic protozoa, such as dog hepatozoon (Hepatozoon canis), cat hepatozoon (Hepatozoon felis),
Vestibuliferida ciliates, such as Balantidium coli,
Trichomonadida flagellates such as Histomonas meleagridis, Pentatrichomonas hominis, and Trichomonas tenax,
Giardia intestinalis, Giardia muris, Hexamita meleagridis, Hexamita parva and other Diplomonadida flagellates,
Donovan Leishmania donovani, Leishmania infantum, Leishmania major, Tropical Leishmania tropica, Trypanosoma brucei gambiense, Trypanosoma trypanosoma, Trypanosoma brucei rhodesi Trypanosoma cruzi, Trypanosoma equiperdum, Trypanosoma evansi and other Kinetoplastida whipworms,
However, pests in the field of agriculture and horticulture and external or endoparasites such as livestock, poultry, and pet animals that can be controlled by using the compound of the present invention are not limited to these.

The composition of the present invention and the method of the present invention are extremely effective against pests that have developed resistance to existing pesticides such as organic phosphorus-based compounds, carbamate-based compounds or pyrethroid-based compounds, and are extremely effective against pests that have developed resistance to existing pesticides. Coleoptera (Coleoptera), Membrane (Coleoptera), Scales (Coleoptera), Diptera (Flies), Hidden (Flies), All-wings (Azamiuma), Half-wings (Acarids and Insects such as Coleoptera (Coleoptera), Coleoptera (Flies and Acites), Straight-winged (Butterfly), Coleoptera (Coleoptera), Coleoptera (Coleoptera), Mucus (Acarina) , Coleoptera (Coleoptera), Coleoptera (Coleoptera, Pseudomonas aeruginosa, Pseudomonas aeruginosa, Coleoptera) Mites such as Midorihashiridani (Coleoptera, Coleoptera), Mite suborder (Himedani family, Tick family), Spike mite suborder (Wakumo family, Osashidani family, Hegiitadani family), abdominal and footworms, Coleoptera, Coleoptera, Circle Pests belonging to Coleoptera, Coleoptera, Coleoptera, Coleoptera, Coleoptera, Coleoptera, etc. can be effectively controlled at low concentrations. On the other hand, the composition of the present invention and the method of the present invention have an extremely adverse effect on mammals, fish, crustaceans and beneficial insects (useful insects such as honeybees and bumblebees and natural enemies such as honeybees, bumblebees, tachinid flies and stink bugs). It has few useful features.

The composition of the present invention can be used as it is as a mixture, but is usually mixed with a suitable solid carrier or liquid carrier, and if desired, a surfactant, a penetrant, a spreading agent, a thickener, an antifreeze, and the like. Add binders, anti-caking agents, disintegrants, antifoaming agents, preservatives, anti-decomposition agents, etc. to add liquids (soluble concentrates), emulsions (emulsifiable concentrates), wettable powders (wettable powders), aqueous solvents ( water soluble powder, water dispersible granule, water soluble granule, suspension concentrate, concentrated emulsion, suspoemulsion, microemulsion (suspoemulsion) It can be put into practical use in any formulation such as microemulsion, dustable powder, granule, tablet and emulsifiable gel. Further, from the viewpoint of labor saving and safety improvement, the preparation of any of the above dosage forms can be provided by encapsulating it in a water-soluble package such as a water-soluble capsule and a bag of a water-soluble film.

Solid carriers include, for example, quartz, square stone, sea foam stone, dolomite, choke, kaolinite, pyrophyllite, cericite, halosite, metahalosite, wood-brush clay, frog-eye clay, pottery stone, gicrite, allophene. Natural minerals such as calcined clay, pearlite, silas balloon, vermiculite, attapargas clay and calcined diatomaceous clay, natural minerals such as silas, kira, talc, bentonite, active clay, acidic clay, pebble, attapargit, zeolite and diatomaceous clay. Quality calcined products such as magnesium carbonate, calcium carbonate, sodium carbonate, sodium hydrogen carbonate, ammonium sulfate, sodium sulfate, magnesium sulfate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate and potassium chloride and other inorganic salts such as glucose and fructose. , Sugars such as sucrose and lactose, eg polysaccharides such as starch, powdered cellulose and dextrin, eg organic substances such as urea, urea derivatives, salts of benzoic acid and benzoic acid, such as wood flour, cork flour, corn cob, walnut shell And plants such as tobacco stems, fly ash, white carbon (for example, hydrous synthetic silica, anhydrous synthetic silica, hydrous synthetic silicate, etc.), fertilizer and the like.

Liquid carriers include, for example, _{aromatic hydrocarbons such as xylene, alkyl (C 9} or C ₁₀ etc.) benzene, phenylxysilyl ester and alkyl (C ₁ or C ₃ etc.) naphthalene, machine oil, normal paraffin, iso paraffin and Aliphatic hydrocarbons such as naphthen, mixtures of aromatic hydrocarbons such as kerosine and aliphatic hydrocarbons, alcohols such as ethanol, isopropanol, cyclohexanol, phenoxyethanol and benzyl alcohol, ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol , Polyhydric alcohols such as polyethylene glycol and polypropylene glycol, ethers such as propyl cellosolve, butyl cellosolve, phenyl cellosolve, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether and propylene glycol monophenyl ether. , Acetphenone, cyclohexanones and esters such as γ-butyrolactone, fatty acid methyl esters, succinic acid dialkyl esters, glutamate dialkyl esters, adipic acid dialkyl esters and phthalic acid dialkyl esters, N-alkyl (C ₁ , C ₈ or C ₁₂₎ Etc.) Acid amides such as pyrrolidone, fats and oils such as soybean oil, linseed oil, rapeseed oil, coconut oil, cottonseed oil and castor oil, dimethylsulfoxide and water.

These solid and liquid carriers may be used alone or in combination of two or more.

Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl (mono or di) phenyl ether, polyoxyethylene (mono, di or tri) styrylphenyl ether, polyoxyethylene polyoxypropylene block copolymer, and polyoxy. Ethylene fatty acid (mono or di) ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, castor oil ethylene oxide adduct, acetylene glycol, acetylene alcohol, acetylene glycol ethylene oxide adduct, acetylene alcohol ethylene oxide adduct and alkyl Nonionic surfactants such as glycosides, alkyl sulfate ester salts, alkylbenzene sulfonates, lignin sulfonates, alkyl sulfosuccinates, naphthalene sulfonates, alkylnaphthalene sulfonates, salts of formalin condensates of naphthalene sulfonic acid, Formalin Condensate Salt of Alkylnaphthalene Sulphonic Acid, Polyoxyethylene Alkyl Ether Sulfate or Phosphate Ester Salt, Polyoxyethylene (Mono or Di) Alkylphenyl Ether Sulfate or Phosphate Ester Salt, Polyoxyethylene (Mono, Di or Tri) Styryl Anionic surfactants such as phenyl ether sulfuric acid or phosphate ester salts, polycarboxylic acid salts (eg, polyacrylic acid salts, polymale salts and copolymers of maleic acid and olefins) and polystyrene sulfonates, alkylamines. Examples thereof include cationic surfactants such as salts and alkyl quaternary ammonium salts, amphoteric surfactants such as amino acid type and betaine type, silicone-based surfactants and fluorine-based surfactants.

The content of these surfactants is not particularly limited, but is usually preferably in the range of 0.05 to 20 parts by weight with respect to 100 parts by weight of the pharmaceutical product of the present invention. In addition, these surfactants may be used alone or in combination of two or more.

Next, a compounding example of the formulation when the composition of the present invention is used is shown. However, the formulation examples of the present invention are not limited to these. In the following formulation examples, "parts" means parts by weight, and "active ingredient compound" is a general term for fluxametamide and teflubenzurone, which are the active ingredients of the composition of the present invention.

[Wettable powder]
Active ingredient compound 0.1 to 80 parts Solid carrier 5 to 98.9 parts Surfactant 1 to 10 parts Others 0 to 5 parts Other examples include anticaking agents and decomposition inhibitors.

[Emulsifiable concentrate]
Active ingredient compound 0.1 to 30 parts Liquid carrier 45 to 95 parts Surfactant 4.9 to 15 parts Others 0 to 10 parts Other examples include spreading agents and decomposition inhibitors.

[Suspension concentrate]
Active ingredient compound 0.1 to 70 parts Liquid carrier 15 to 98.89 parts Surfactant 1 to 12 parts Others 0.01 to 30 parts Other examples include antifreeze agents and thickeners.

[Water dispersible granule]
Active ingredient compound 0.1 to 90 parts Solid carrier 0 to 98.9 parts Surfactant 1 to 20 parts Others 0 to 10 parts Other examples include binders, decomposition inhibitors and the like.

[Liquid (soluble concentrate)]
Active ingredient compound 0.01 to 70 parts Liquid carrier 20 to 99.99 parts Others 0 to 10 parts Other examples include antifreeze agents and spreading agents.

[Granule]
Active ingredient compound 0.01 to 80 parts Solid carrier 10 to 99.99 parts Others 0 to 10 parts Other examples include binders, decomposition inhibitors and the like.

[Dustable powder]
Active ingredient compound 0.01 to 30 parts Solid carrier 65 to 99.99 parts Others 0 to 5 parts Other examples include anti-drift agents and anti-decomposition agents.

Next, examples of pesticide preparations containing the composition of the present invention as an active ingredient will be shown more specifically, but the present invention is not limited thereto.

In the following formulation examples, "parts" means parts by weight.

[Formulation Example 1] Wettable powder Fluxamethamide 10 parts Teflubenzlon 10 parts Pyrophyllite 76 parts Solpol 5039 2 parts (Mixture of nonionic surfactant and anionic surfactant: Toho Chemical Industry Co., Ltd. trade name)
Carplex # 80D Part 2 (Synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd. trade name)
The above is uniformly mixed and pulverized to obtain a wettable powder.

[Formulation Example 2] Emulsifiable concentrate
Fluxametamide 3 parts Teflubenzlon 2 parts Xylene 75 parts N-methylpyrrolidone 15 parts Solpol 2680 5 parts (Mixture of nonionic surfactant and anionic surfactant: Toho Chemical Industry Co., Ltd. trade name)
The above is uniformly mixed to obtain an emulsion.

[Formulation Example 3] Suspension concentrate
Fluxamethamide 15 parts Teflubenzron 10 parts Agrisol S-710 10 parts (Nonionic surfactant: Kao Corporation trade name)
Lunox 1000C 0.5 part (anionic surfactant: Toho Chemical Industry Co., Ltd. trade name)
After uniformly mixing 0.2 parts of xanthan gum and 64.3 parts of water, wet pulverization is used as a suspension agent.

[Formulation Example 4] Water dispersible granule
Fluxamethamide 40 parts Teflubenzlon 35 parts Hytenol NE-15 5 parts (anionic surfactant: Dai-ichi Kogyo Seiyaku Co., Ltd. trade name)
Vanillex N 10 parts (anionic surfactant: Nippon Paper Industries, Ltd. trade name)
Carplex # 80D 10 parts (Synthetic hydrous silicic acid: Shionogi Co., Ltd. trade name)
After uniformly mixing and pulverizing the above, a small amount of water is added, the mixture is stirred and mixed, granulated by an extrusion type granulator, and dried to obtain a granule wettable powder.

[Formulation Example 5] Granule
Fluxamethamide 3 parts Teflubenzlon 2 parts Bentonite 50 parts Talc 45 parts After crushing, add a small amount of water, stir and mix, granulate with an extrusion granulator, and dry to make granules.

[Formulation Example 6] Dustable powder
Fluxamethamide 2 parts Teflubenzlon 1 part Carplex # 80D 0.5 parts (White carbon: Shionogi Pharmaceutical Co., Ltd. trade name)
95 parts of kaolinite Diisopropyl phosphate 1.5 parts or more are uniformly mixed and pulverized to obtain a powder.

At the time of use, the wettable powder, emulsion, flowable agent, and granular wettable powder are diluted 50 to 20000 times with water and sprayed so that the active ingredient is 0.005 to 50 kg per hectare (ha).

[Test example]
Next, in order to clarify the usefulness of the present invention, the following efficacy test examples will be specifically described, but the present invention is not limited to these.

[Test Example 1] Efficacy test against Spodoptera litura A pharmaceutical solution having a predetermined concentration was prepared by diluting a preparation of Fluxametamide and teflubenzuron with water containing a spreading agent. The cabbage leaves were placed in the chemical solution and immersed for 10 seconds. Next, the treated cabbage leaves were transferred to a 7 cm petri dish lined with filter paper, one per petri dish, and air-dried. After the air-drying was completed, 7 Spodoptera litura 3rd instar larvae were released per petri dish. After releasing the insects, the petri dish was housed in a homeothermic chamber at 25 ° C.

The number of dead larvae after 6 days of treatment was investigated, and the dead larva rate was calculated from the following formula. The test was conducted in a double system.

Death rate (%) = number of dead insects / number of test insects x 100
Table 1 shows the results regarding the mortality rate of each drug solution.

The synergistic effect can be calculated from the mortality rate for each drug solution concentration by using the Colby method (Colby S.R. 1967, Weeds 15, 20-22). The calculation method is as follows.

E = X + Y-XY / 100
X: Observation value of agent A at x concentration (death rate)
Observation value of agent B at Y: y concentration (death rate)
E: Expected mortality rate (expected value) during mixed treatment of agents A and B
If the result (death rate) obtained in the test example is larger than the expected value, it has a synergistic effect, if the expected value is larger than the observed value, it has an antagonistic effect, and if the observed value and the expected value are the same, it is additive. It is analyzed as an action.
[Table 1]
―――――――――――――――――――――――――――――――――――――――
Concentration (ppm) Death rate (%) Expected value ―――――――――――――――――――――――――――――――――――――― ―
fluxametamide 50 100 ―
0.06 85.7 ―
teflubenzuron 25 100 ―
0.4 92.9 ―
fluxametamide + teflubenzuron 50 + 25 100 100
0.06 + 0.4 100 99
No processing ― 0 ―
―――――――――――――――――――――――――――――――――――――――

The composition of the present invention and the method of the present invention can be used for controlling various pests.

Claims (3)

A pest control composition containing fluxametamid and teflubenzurone. The pest control agent composition according to claim 1, wherein the weight ratio of fluxametamid to teflubenzurone is 100: 1 to 1: 100. A method for controlling pests, which comprises treating fluxametamide and teflubenzurone simultaneously or in close proximity in time.