JP2014100822A5 - - Google Patents

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JP2014100822A5
JP2014100822A5 JP2012252905A JP2012252905A JP2014100822A5 JP 2014100822 A5 JP2014100822 A5 JP 2014100822A5 JP 2012252905 A JP2012252905 A JP 2012252905A JP 2012252905 A JP2012252905 A JP 2012252905A JP 2014100822 A5 JP2014100822 A5 JP 2014100822A5
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mold
temperature
raising
thermosetting resin
shaping
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JP2014100822A (en
JP6054714B2 (en
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すなわち本発明の賦形成形方法は、複数本の強化繊維束を含む織物基材の少なくとも一方の表面に熱硬化性樹脂を主成分とする樹脂材料が付着された成形原反材を裁断し積層した積層成形材を成形型に投入配置し、加圧、加熱して複数本の強化繊維束を含む織物基材に付着している樹脂材料を硬化して繊維間及び成形原反材の層間を接着する賦形成形方法において、積層成形材を予熱して成形型へ投入配置する予熱工程と、成形型を型締し加圧する工程と、上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する工程と、成形型を硬化温度に昇温して型を開き離型する工程とを有することを特徴とする。
この本発明の賦形成形方法によって、成形型を熱硬化性樹脂材の硬化温度に加熱することによって熱硬化性樹脂を強化繊維に含侵させた状態で硬化し、繊維積層によって強化して十分な成形品強度の熱硬化性樹脂材を成形することが可能となる。しかも長い昇温時間によってサイクルタイムが過長になることを予熱することによって防止することができる。
That is, the forming method of the present invention cuts and laminates a forming raw material in which a resin material mainly composed of a thermosetting resin is attached to at least one surface of a textile base material including a plurality of reinforcing fiber bundles. The laminated molding material is placed in a molding die, pressed and heated to cure the resin material adhering to the fabric substrate including a plurality of reinforcing fiber bundles, and between the fibers and the interlayer of the molding raw material. In the forming method for bonding, at least one of a preheating step of preheating the laminated molding material and placing it in the molding die, a step of clamping and pressurizing the molding die, and an upper and lower die in the vicinity of the dividing line of the upper and lower die The method has a step of raising the temperature to a required temperature higher than the mold at the curing temperature of the thermosetting resin, and a step of raising the mold to the curing temperature and opening the mold to release the mold. .
By this forming method of the present invention, the mold is heated to the curing temperature of the thermosetting resin material so that the thermosetting resin is impregnated in the reinforcing fibers, and is sufficiently reinforced by fiber lamination. It becomes possible to mold a thermosetting resin material having a strong molded product strength. In addition, it can be prevented by preheating that the cycle time becomes excessive due to the long heating time.

そこで本発明の賦形成形方法によれば上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する工程を備える。
この上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する工程によって部分的に昇温した部分の熱硬化性樹脂が硬化されることによって、外部へのはみ出しが阻止され、樹脂流出をふせぐことができる。この成形型より高い所要の温度とは、外部へのはみ出しを阻止するに充分な程度に昇温した部分の熱硬化性樹脂が短時間に硬化される温度である。
Therefore, according to the forming method of the present invention, there is provided a step of heating at least one of the upper and lower molds in the vicinity of the dividing line of the upper and lower molds to a required temperature higher than that of the mold at the curing temperature of the thermosetting resin. .
By curing at least one of the upper and lower molds at a part of the thermosetting resin that has been partially heated by the process of raising the temperature to a required temperature higher than that of the mold at the curing temperature of the thermosetting resin, Protrusion to the outside is prevented and resin spillage can be prevented. The required temperature higher than that of the mold is a temperature at which the portion of the thermosetting resin whose temperature has been raised enough to prevent the protrusion to the outside is cured in a short time.

この賦形成形方法は、上部型10aと下部型10bの分割線近傍領域の上部型10aと下部型10bのうち少なくとも1方を前記熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する昇温手段PMを用いて行う。この昇温手段PMは図8(a)(b)に示すように、上部型10aの縁部にのみ対向して下部型10bに載置した積層成形材5の縁部外側の下部型10b上に入れ駒型として配置される。入れ駒型PMは上部型10aと下部型10bとの型合わせ面の形状もしくは下部型10bに載置する積層成形材5外形と一致する内側形状を有して形成される。その入れ駒型PMの内側に上部型10aが嵌入して上部型10aと下部型10bとが型合わせされることによって下部型10bに載置する積層成形材5の成形が行われる。 In this forming method, at least one of the upper mold 10a and the lower mold 10b in the vicinity of the dividing line of the upper mold 10a and the lower mold 10b is set to a required temperature higher than that of the molding mold at the curing temperature of the thermosetting resin. This is performed using a temperature raising means PM for raising the temperature. As shown in FIGS. 8A and 8B, the temperature raising means PM is arranged on the lower mold 10b outside the edge of the laminated molding material 5 placed on the lower mold 10b so as to face only the edge of the upper mold 10a. It is arranged as a frame type. The insert piece type PM is formed to have a shape of a mating surface of the upper die 10a and the lower die 10b or an inner shape that matches the outer shape of the laminated molding material 5 placed on the lower die 10b. The upper mold 10a is fitted inside the insert piece mold PM, and the upper mold 10a and the lower mold 10b are mated to form the laminated molding material 5 to be placed on the lower mold 10b.

積層成形材5を予熱して成形型9へ投入配置する予熱工程の後に、上部型10aと下部型10bとが型合わせされることによって製品の成型が行われる。その過程で上部型10aと下部型10bとの型合わせによる圧縮成型と同時に上部型10aと下部型10bの分割線近傍領域の上部型10aと下部型10bを熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する昇温工程が入れ駒型PMを用いて行われる。このように、入れ駒型PMを用いた昇温工程を行わない場合には、上部型10aと下部型10bの分割部分から成型課程における温度上昇による膨張圧で積層成形材5の表面の樹脂の一部が金型合わせ目部分にはみ出しバリを形成する。しかし入れ駒型PMを用いた昇温工程を行うことによって積層成形材5の表面の樹脂は、金型合わせ目部分において昇温硬化し、それが障壁となって樹脂流出が抑止されてバリの形成が最小化される。 After the preheating process in which the laminated molding material 5 is preheated and placed in the molding die 9, the upper die 10a and the lower die 10b are matched with each other to mold the product. In the process, the upper mold 10a and the lower mold 10b in the vicinity of the dividing line of the upper mold 10a and the lower mold 10b are molded simultaneously with the compression molding by matching the upper mold 10a and the lower mold 10b at the curing temperature of the thermosetting resin. A temperature raising step for raising the temperature to a higher required temperature is performed using the insert piece type PM. Thus, in the case where the temperature raising process using the insert piece type PM is not performed, the resin on the surface of the laminated molding material 5 is expanded by the expansion pressure due to the temperature rise in the molding process from the divided part of the upper mold 10a and the lower mold 10b. A part protrudes into the mold joint part to form a burr. However, by performing the temperature raising process using the insert piece type PM, the resin on the surface of the laminated molding material 5 is heated and cured at the mold joint portion, which acts as a barrier to prevent the resin from flowing out. Formation is minimized.

次に本発明の第二の実施の形態の賦形成形方法を図28(a)〜(c)を参照して詳述する。
第二の実施の形態の賦形成形方法では上部型10aと下部型10bの分割線近傍領域の上部型10aと下部型10bのうち少なくとも1方を近赤外線放射装置20によって近赤外線で加熱し、遠赤外線温度センサ−で温度を検知し、近赤外線の強度を調整し所要の温度に昇温させることによって、上部型10aと下部型10bの分割線近傍領域の前記熱硬化性樹脂の硬化温度に昇温する。この第二の実施の形態でも積層成形材14を予熱して成形型9へ投入配置する予熱工程の後に、上部型10aと下部型10bとが型合わせされることによって製品の成型が行われる。その成形型を型締し加圧する過程で上部型10aと下部型10bとの型合わせによる圧縮成型と同時に上部型10aと下部型10bの分割線近傍領域の上部型10aと下部型10bを熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する工程が近赤外線放射装置20を用いて行われる。
Next, the forming method according to the second embodiment of the present invention will be described in detail with reference to FIGS.
In the forming method of the second embodiment, at least one of the upper mold 10a and the lower mold 10b in the region near the dividing line of the upper mold 10a and the lower mold 10b is heated with near infrared radiation by the near infrared radiation device 20, By detecting the temperature with a far-infrared temperature sensor, adjusting the intensity of near-infrared light and raising the temperature to a required temperature, the temperature of the thermosetting resin in the region near the dividing line of the upper mold 10a and the lower mold 10b is set. Raise the temperature. Also in the second embodiment, after the preheating process in which the laminated molding material 14 is preheated and placed in the molding die 9, the upper mold 10a and the lower mold 10b are matched with each other to mold the product. The upper mold 10a and the lower mold 10b in the region near the dividing line of the upper mold 10a and the lower mold 10b are thermoset simultaneously with the compression molding by the mold matching of the upper mold 10a and the lower mold 10b in the process of clamping and pressurizing the mold. The step of raising the temperature to a required temperature higher than that of the mold at the curing temperature of the conductive resin is performed using the near infrared radiation device 20.

Claims (5)

複数本の強化繊維束を含む織物基材の少なくとも一方の表面に熱硬化性樹脂を主成分とする樹脂材料が付着された成形原反材を裁断し積層した積層成形材を成形型に投入配置し、加圧、加熱して複数本の強化繊維束を含む織物基材に付着している樹脂材料を硬化して繊維間及び成形原反材の層間を接着する賦形成形方法において、積層成形材を予熱して成形型へ投入配置する予熱工程と、成形型を型締し加圧する工程と、上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度で成形型より高い所要の温度に昇温する工程と、成形型を硬化温度に昇温して型を開き離型する工程とを有することを特徴とする賦形成形方法。 Laminate molding material, which is made by cutting and laminating a raw material with a resin material consisting mainly of thermosetting resin on at least one surface of a woven fabric substrate containing multiple reinforcing fiber bundles, is placed in the mold. In the forming method in which the resin material adhering to the textile substrate containing a plurality of reinforcing fiber bundles is cured by pressurization and heating to bond between the fibers and between the layers of the molding raw material, lamination molding At least one of a preheating step of preheating the material and placing it in the mold, a step of clamping and pressurizing the mold, and an upper and lower mold in the vicinity of the dividing line of the upper and lower molds. A forming method characterized by comprising a step of raising the temperature to a required temperature higher than that of the mold and a step of raising the mold to a curing temperature to open and release the mold. 上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度に昇温する工程が近赤外線で加熱し、遠赤外線温度センサ−で温度を検知し、近赤外線の強度を調整し所要の温度に昇温させる工程であることを特徴とする請求項1に記載の賦形成形方法。 The step of raising the temperature of at least one of the upper and lower molds in the vicinity of the upper and lower mold dividing lines to the curing temperature of the thermosetting resin is heated by near infrared rays, the temperature is detected by a far infrared temperature sensor, 2. The forming method according to claim 1, which is a step of adjusting the strength and raising the temperature to a required temperature. 上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度に昇温する工程が上下型の分割線にレーザ光を照射する工程であることを特徴とする請求項1又は請求項2に記載の賦形成形方法。 The step of raising the temperature of at least one of the upper and lower molds in the vicinity of the upper and lower mold dividing lines to the curing temperature of the thermosetting resin is a process of irradiating the upper and lower mold dividing lines with laser light. Item 3. The shaping method according to item 1 or 2. 請求項1〜請求項3のいずれか一に記載の賦形成形方法に用いられる賦形成形型であって、賦形をする上部型と下部型とからなる成形型と、上下型の分割線近傍領域の上下型のうち少なくとも1方を前記熱硬化性樹脂の硬化温度に昇温する昇温手段と、成形型を型締し加圧する手段と、成形型を硬化温度に昇温して型を開き離型する手段とを有することを特徴とする賦形成形型。 It is a shaping type | mold used for the shaping method as described in any one of Claims 1-3, Comprising: The shaping | molding die which consists of the upper type | mold and lower type | mold which shape, and the dividing line of an up-and-down type | mold A temperature raising means for raising the temperature of at least one of the upper and lower molds in the vicinity region to the curing temperature of the thermosetting resin, a means for clamping and pressurizing the mold, and a mold by raising the mold to the curing temperature And a forming mold characterized by having means for opening and releasing the mold. 前記昇温手段が入れ駒であることを特徴とする請求項4記載の賦形成形型。 The shaping mold according to claim 4, wherein the temperature raising means is a slot.
JP2012252905A 2012-11-19 2012-11-19 Forming method and forming mold Active JP6054714B2 (en)

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JP2014100822A5 true JP2014100822A5 (en) 2015-12-24
JP6054714B2 JP6054714B2 (en) 2016-12-27

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JP6811573B2 (en) * 2016-09-21 2021-01-13 三光合成株式会社 Formed type and formed type method

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JPS5812723A (en) * 1981-07-15 1983-01-24 Matsushita Electric Works Ltd Manufacture of laminated board
JPH0433855A (en) * 1990-05-30 1992-02-05 Dainippon Ink & Chem Inc Manufacture of metal foil-plated laminated plate
JP2001179877A (en) * 1999-12-24 2001-07-03 Sumitomo Bakelite Co Ltd Method for manufacturing laminated sheet
JP2001279554A (en) * 2000-03-29 2001-10-10 Mitsubishi Rayon Co Ltd Reinforced fiber woven fabric and method of weaving the same
JP5712038B2 (en) * 2011-04-21 2015-05-07 三光合成株式会社 Forming method

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