JP2014097931A - Hair treatment agent - Google Patents
Hair treatment agent Download PDFInfo
- Publication number
- JP2014097931A JP2014097931A JP2012249046A JP2012249046A JP2014097931A JP 2014097931 A JP2014097931 A JP 2014097931A JP 2012249046 A JP2012249046 A JP 2012249046A JP 2012249046 A JP2012249046 A JP 2012249046A JP 2014097931 A JP2014097931 A JP 2014097931A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- treatment agent
- mass
- hair treatment
- higher alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000011282 treatment Methods 0.000 title claims abstract description 66
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 55
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- 239000003093 cationic surfactant Substances 0.000 claims abstract description 19
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- 235000019410 glycyrrhizin Nutrition 0.000 claims abstract description 9
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- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Chemical class 0.000 description 1
- 229920001296 polysiloxane Chemical class 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 229940010310 propylene glycol dioleate Drugs 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- 229940026256 trioctyldodecyl citrate Drugs 0.000 description 1
- BIEMOBPNIWQLMF-UHFFFAOYSA-N tris(2-octyldodecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CC(O)(C(=O)OCC(CCCCCCCC)CCCCCCCCCC)CC(=O)OCC(CCCCCCCC)CCCCCCCCCC BIEMOBPNIWQLMF-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Abstract
Description
本発明は、高粘度の毛髪用処理剤に関するものである。 The present invention relates to a hair treatment agent with high viscosity.
トリートメント、コンディショナーなどの毛髪用処理剤には、毛髪の感触改善のために、カチオン界面活性剤を配合することが一般的となっている。そして、使用目的に応じた粘度に調整するために、高級アルコールを毛髪用処理剤に配合することが多い。また、頭皮の痒みを抑えるために、カチオン界面活性剤及び高級アルコールと共に、グリチルレチン酸などの抗炎症剤を毛髪用処理剤に配合する場合がある(特許文献1参照)。 In general, a cationic surfactant is added to hair treatment agents such as treatments and conditioners to improve the feel of hair. And in order to adjust to the viscosity according to a use purpose, a higher alcohol is often mix | blended with the treatment agent for hair. In order to suppress itching of the scalp, an anti-inflammatory agent such as glycyrrhetinic acid may be added to the hair treatment agent together with a cationic surfactant and a higher alcohol (see Patent Document 1).
ところで、粘度は毛髪や頭皮への塗布容易性に直接関わる一つの要因であるが、粘度を高めるために高級アルコールを多量に配合すれば、毛髪用処理剤の油性感が強くなってしまう。この感触を解消するために、高級アルコールの大量配合を回避しつつ、粘度を高く設定できるトリートメントが特許文献2に開示されており、当該トリートメントは、アニオン界面活性剤及び/又はノニオン界面活性剤、増粘性効果を有することが一般的に知られている水膨潤性粘土鉱物などが所定量配合されたものである。特許文献2の開示と同様、高級アルコールが多量に配合されていないが、粘度が高い毛髪用処理剤が求められる場合がある。 By the way, the viscosity is one factor directly related to the ease of application to the hair and scalp. However, if a higher alcohol is added in a large amount in order to increase the viscosity, the oily feeling of the hair treatment agent becomes strong. In order to eliminate this feeling, a treatment capable of setting a high viscosity while avoiding the mass blending of higher alcohol is disclosed in Patent Document 2, and the treatment includes an anionic surfactant and / or a nonionic surfactant, A water-swellable clay mineral generally known to have a thickening effect is blended in a predetermined amount. Similar to the disclosure of Patent Document 2, a higher amount of higher alcohol is not blended, but a hair treatment agent having a high viscosity may be required.
本発明は、上記事情に鑑み、高級アルコールの配合量を抑えつつも、粘度が高い毛髪用処理剤の提供を目的とする。 In view of the above circumstances, an object of the present invention is to provide a hair treatment agent having a high viscosity while suppressing the blending amount of a higher alcohol.
本発明者等がカチオン界面活性剤及び高級アルコールが配合された水中油型乳化物である毛髪用処理剤の粘度を高めるべく鋭意検討を行った結果、粘土鉱物及びグリチルリチン酸又はその塩を配合すれば、粘度が大幅に高まることを見出し、本発明を完成するに至った。すなわち、本発明に係る毛髪用処理剤は、下記(A)〜(D)が水と配合されたことを特徴とする。
(A)カチオン界面活性剤
(B)高級アルコール
(C)粘土鉱物
(D)グリチルリチン酸及び/又はその塩
As a result of intensive studies by the present inventors to increase the viscosity of a hair treatment agent that is an oil-in-water emulsion containing a cationic surfactant and a higher alcohol, a clay mineral and glycyrrhizic acid or a salt thereof are added. As a result, the present inventors have found that the viscosity is greatly increased and have completed the present invention. That is, the hair treatment agent according to the present invention is characterized in that the following (A) to (D) are blended with water.
(A) Cationic surfactant (B) Higher alcohol (C) Clay mineral (D) Glycyrrhizic acid and / or salt thereof
本発明に係る毛髪用処理剤において、前記(A)カチオン界面活性剤及び前記(B)高級アルコールの合計配合量が5質量%以上であり、前記(A)カチオン界面活性剤に対する前記(B)高級アルコールのモル比([B]/[A]比)が3.0/1以上であると良い。 In the hair treatment agent according to the present invention, the total blending amount of the (A) cationic surfactant and the (B) higher alcohol is 5% by mass or more, and the (B) with respect to the (A) cationic surfactant. The molar ratio of higher alcohol ([B] / [A] ratio) is preferably 3.0 / 1 or more.
本発明に係る毛髪用処理剤の粘度は、10Pa・s以上であると良い。原料として(C)と(D)を配合することで、高級アルコールの配合量を少なくしても、粘度10Pa・s以上を実現できる。この粘度範囲であれば、濡れた状態の長い毛髪及び頭皮への塗布が容易になる。 The viscosity of the hair treatment agent according to the present invention is preferably 10 Pa · s or more. By blending (C) and (D) as raw materials, a viscosity of 10 Pa · s or more can be realized even if the blending amount of the higher alcohol is reduced. If it is this viscosity range, the application | coating to the hair and scalp of the wet state will become easy.
本発明に係る毛髪用処理剤の剤型は、泥状であると良い。原料(A)〜(C)の配合に加えて原料(D)を配合することで、クリーム状の剤型を泥状にすることが可能となる。剤型が泥状であれば、濡れた状態の長い毛髪及び頭皮への塗布が容易になる。 The dosage form of the hair treatment agent according to the present invention is preferably mud. By blending the raw material (D) in addition to the blending of the raw materials (A) to (C), the creamy dosage form can be made mud. If the dosage form is mud, it can be easily applied to wet long hair and scalp.
本発明に係る毛髪用処理剤は、例えば、濡れた毛髪に塗布して用いられる。 The treatment agent for hair according to the present invention is used by applying to wet hair, for example.
本発明によれば、カチオン界面活性剤及び高級アルコールと共に、粘土鉱物及びグリチルリチン酸又はその塩を配合するから、高級アルコールの配合量を抑えつつも、粘度の高い毛髪用処理剤を実現できる。 According to the present invention, since the clay mineral and glycyrrhizic acid or a salt thereof are blended together with the cationic surfactant and the higher alcohol, a hair treatment agent having a high viscosity can be realized while suppressing the blending amount of the higher alcohol.
本発明の実施形態に基づき、本発明を以下に説明する。
本実施形態に係る毛髪用処理剤は、下記(A)〜(D)が水と配合されたものである(水の配合量は、例えば70質量%以上)。また、使用上許容されるのであれば、毛髪用処理剤に配合する原料として公知のものを任意原料として更に配合しても良い。
(A)カチオン界面活性剤
(B)高級アルコール
(C)粘土鉱物
(D)グリチルリチン酸及び/又はその塩
Based on an embodiment of the present invention, the present invention will be described below.
The hair treatment agent according to this embodiment is one in which the following (A) to (D) are blended with water (the blending amount of water is, for example, 70% by mass or more). Moreover, as long as it accept | permits on use, you may further mix | blend a well-known thing as a raw material mix | blended with the processing agent for hair as an arbitrary raw material.
(A) Cationic surfactant (B) Higher alcohol (C) Clay mineral (D) Glycyrrhizic acid and / or salt thereof
((A)カチオン界面活性剤)
カチオン界面活性剤は、毛髪の髪質改善、油滴の分散のために本実施形態の毛髪用処理剤に配合される。
((A) Cationic surfactant)
The cationic surfactant is blended in the hair treatment agent of the present embodiment for improving hair quality and dispersing oil droplets.
上記のカチオン界面活性剤としては、例えば、ジステアリルジメチルアンモニウムクロリド、ジセチルジメチルアンモニウムクロリド、ジココイルジメチルアンモニウムクロリド等のジ長鎖アルキルジメチルアンモニウム塩;ベヘニルトリメチルアンモニウムクロリド、ステアリルトリメチルアンモニウムクロリド、ステアリルトリメチルアンモニウムブロミド、セチルトリメチルアンモニウムブロミド等のモノ長鎖アルキルトリメチルアンモニウム塩;ステアロキシプロピルトリメチルアンモニウムクロリド等の長鎖アルコキシアルキルトリメチルアンモニウム塩;が挙げられる。なお、ここでの「長鎖アルキル」とは、炭素数が8以上の直鎖状又は分枝状のアルキル基を意味し、その炭素数が16以上22以下であると皮膚への刺激の抑制や毛髪に付与する感触の観点から好ましい。 Examples of the cationic surfactant include dilong-chain alkyldimethylammonium salts such as distearyldimethylammonium chloride, dicetyldimethylammonium chloride, dicocoyldimethylammonium chloride; behenyltrimethylammonium chloride, stearyltrimethylammonium chloride, stearyltrimethyl. Mono long-chain alkyltrimethylammonium salts such as ammonium bromide and cetyltrimethylammonium bromide; long-chain alkoxyalkyltrimethylammonium salts such as stearoxypropyltrimethylammonium chloride. The term “long-chain alkyl” as used herein means a linear or branched alkyl group having 8 or more carbon atoms, and when the carbon number is 16 or more and 22 or less, irritation to the skin is suppressed. From the viewpoint of the feel imparted to hair and hair.
本実施形態の毛髪用処理剤におけるカチオン界面活性剤の配合量は、適宜設定されるべきものであるが、例えば1質量%以上5質量%以下であり、2質量%以上4質量%以下が良い。1質量%以上にすることで、毛髪の感触改善に好ましく、5質量%以下にすることで、皮膚刺激の抑制に好ましい。 The blending amount of the cationic surfactant in the hair treatment agent of the present embodiment should be appropriately set. For example, it is 1% by mass to 5% by mass, and preferably 2% by mass to 4% by mass. . Setting it to 1% by mass or more is preferable for improving the feel of hair, and setting it to 5% by mass or less is preferable for suppressing skin irritation.
((B)高級アルコール)
高級アルコールは、粘度調整や毛髪の感触改善のために、本実施形態の毛髪用処理剤に配合される。
((B) higher alcohol)
The higher alcohol is blended in the hair treatment agent of this embodiment for viscosity adjustment and hair feel improvement.
本実施形態の毛髪用処理剤に配合する高級アルコールは、炭素数数16以上22以下のものが良く、例えば、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコールなどの直鎖状飽和アルコール;オレイルアルコールなどの直鎖状不飽和アルコール;ヘキシルデカノール、オクチルドデカノール、イソセチルアルコール、イソステアリルアルコールなどの分岐状飽和アルコール;が挙げられる。これらの高級アルコールの中でも、毛髪用処理剤における油滴の分散安定性の観点から、炭素数16以上22以下の直鎖状飽和アルコールが良く、セチルアルコール及びステアリルアルコールが好ましい。 The higher alcohol to be blended in the hair treatment agent of the present embodiment preferably has 16 to 22 carbon atoms, for example, linear saturated alcohols such as cetyl alcohol, stearyl alcohol, aralkyl alcohol, and behenyl alcohol; oleyl alcohol Linear unsaturated alcohols such as hexyl decanol, octyldodecanol, branched saturated alcohols such as isocetyl alcohol and isostearyl alcohol. Among these higher alcohols, from the viewpoint of dispersion stability of oil droplets in the hair treatment agent, straight chain saturated alcohols having 16 to 22 carbon atoms are preferable, and cetyl alcohol and stearyl alcohol are preferable.
高級アルコールから選ばれた一種又は二種以上を、本実施形態の毛髪用処理剤に配合すると良い。本実施形態の毛髪用処理剤における高級アルコールの配合量は、例えば3質量%以上15質量%以下であり、5質量%以上10質量%以下が良い。3質量%以上にすることで、粘度が高くなり、15質量%以下にすることで、油性感の抑制に好ましい。 One or two or more selected from higher alcohols may be added to the hair treatment agent of this embodiment. The blending amount of the higher alcohol in the hair treatment agent of this embodiment is, for example, 3% by mass to 15% by mass, and preferably 5% by mass to 10% by mass. By setting it to 3% by mass or more, the viscosity is increased, and by setting it to 15% by mass or less, it is preferable for suppressing oiliness.
カチオン界面活性剤及び高級アルコールの合計配合量([A]+[B])は、5質量%以上15質量%以下が良く、8質量%以上13質量%以下が好ましい。[A]+[B]が5質量%以上であれば、高い粘度に設定しやすく、15質量%以下であれば、油性感を抑えやすい。 The total blending amount ([A] + [B]) of the cationic surfactant and the higher alcohol is preferably 5% by mass to 15% by mass, and more preferably 8% by mass to 13% by mass. If [A] + [B] is 5% by mass or more, it is easy to set a high viscosity, and if it is 15% by mass or less, it is easy to suppress the oily feeling.
(A)カチオン界面活性剤に対する(B)高級アルコールのモル比([B]/[A]比)は、適宜設定されるが、3.0/1以上が良い。[B]/[A]比が3.0/1以上であると、高い粘度に設定しやすい。 The molar ratio of (B) higher alcohol to (A) cationic surfactant ([B] / [A] ratio) is appropriately set, but is preferably 3.0 / 1 or more. When the [B] / [A] ratio is 3.0 / 1 or more, it is easy to set a high viscosity.
((C)粘土鉱物)
本実施形態の毛髪用処理剤に配合する粘土鉱物は、水分子を取り込む性質を有する層状粘土鉱物であると良い。粘土鉱物により、頭皮上にある汚れや老廃物が除去される。
((C) clay mineral)
The clay mineral to be blended in the hair treatment agent of the present embodiment is preferably a layered clay mineral having a property of taking in water molecules. The clay mineral removes dirt and waste on the scalp.
本実施形態の毛髪用処理剤には、カオリン、スメクタイト、ベントナイトなどの公知の粘土鉱物から選ばれた一種又は二種以上を配合すると良い。本実施形態の毛髪用処理剤における配合量としては、例えば0.3質量%以上3.0質量%以下であり、0.5質量%以上2.0質量%でも良い。 In the hair treatment agent of this embodiment, one or more selected from known clay minerals such as kaolin, smectite, and bentonite may be blended. As a compounding quantity in the processing agent for hair of this embodiment, they are 0.3 mass% or more and 3.0 mass% or less, for example, 0.5 mass% or more and 2.0 mass% may be sufficient.
((D)グリチルリチン酸及び/又はその塩)
本実施形態の毛髪用処理剤には、抗炎症剤として知られているグリチルリチン酸及びグリチルリチン酸ジカリウムなどのグリチルリチン酸塩から選ばれた一種又は二種以上が配合される。本実施形態の毛髪用処理剤におけるグリチルリチン酸及びその塩の配合量は、例えば0.05質量%以上1質量%以下である。
((D) Glycyrrhizic acid and / or salt thereof)
In the hair treatment agent of the present embodiment, one or more selected from glycyrrhizinates such as glycyrrhizic acid and dipotassium glycyrrhizinate known as anti-inflammatory agents are blended. The compounding quantity of the glycyrrhizic acid and its salt in the hair treatment agent of this embodiment is 0.05 mass% or more and 1 mass% or less, for example.
(任意原料)
上記の通り、本実施形態の毛髪用処理剤には任意原料が配合される。当該任意原料は、油剤、多価アルコール、低級アルコール、糖類、シリコーン、高分子化合物、アミノ酸、動植物抽出物、微生物由来物、ビタミン、無機化合物、香料、防腐剤などである。
(Optional raw material)
As above-mentioned, arbitrary raw materials are mix | blended with the treatment agent for hair of this embodiment. The optional raw materials are oil agents, polyhydric alcohols, lower alcohols, sugars, silicones, polymer compounds, amino acids, animal and plant extracts, microbial substances, vitamins, inorganic compounds, flavors, preservatives, and the like.
本実施形態の毛髪用処理剤における油剤は、エステル油、油脂、炭化水素、ロウを意味する。この油剤を本実施形態の毛髪用処理剤に分散させれば、公知の毛髪用処理剤における油剤と同様、毛髪の感触に影響を及ぼす。本実施形態の毛髪用処理剤における配合量は、特に限定されないが、例えば0.2質量%以上3質量%である。 The oil agent in the treatment agent for hair of this embodiment means ester oil, fats and oils, hydrocarbon, and wax. If this oil agent is dispersed in the hair treatment agent of this embodiment, it affects the feel of the hair in the same manner as the oil agent in the known hair treatment agent. Although the compounding quantity in the hair treatment agent of this embodiment is not specifically limited, For example, they are 0.2 mass% or more and 3 mass%.
上記エステル油としては、例えば、ウンデシレン酸ヘプチル、イソノナン酸イソノニル、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、パルミチン酸セチル、ミリスチン酸ミリスチル、ミリスチン酸オクチルドデシル、イソステアリン酸イソプロピル、イソステアリン酸エチル、2−エチルヘキサン酸セチル、イソステアリン酸ヘキシル、ジ2−エチルヘキサン酸エチレングリコール、ジオレイン酸エチレングリコール、ジ(カプリル・カプリン酸)プロピレングリコール、ジオレイン酸プロピレングリコール、トリイソステアリン酸トリメチロールプロパン、テトラ2−エチルヘキサン酸ペンタエリスチル、ジヘプタン酸ネオペンチルグリコール、イソステアリン酸イソセチル、ジメチルオクタン酸2−オクチルドデシル、乳酸ミリスチル、クエン酸トリオクチルドデシル、リンゴ酸ジイソステアリル、コハク酸ジ2−エチルヘキシル、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、ステアリン酸コレステリルが挙げられる。 Examples of the ester oil include heptyl undecylate, isononyl isononanoate, ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, cetyl palmitate, myristyl myristate, octyldodecyl myristate, isopropyl isostearate, isostearate Ethyl acetate, cetyl 2-ethylhexanoate, hexyl isostearate, ethylene glycol di-2-ethylhexanoate, ethylene glycol dioleate, propylene glycol di (capryl / capric acid), propylene glycol dioleate, trimethylolpropane triisostearate, Tetra-2-ethylhexanoic acid pentaerythryl, diheptanoic acid neopentyl glycol, isostearic acid isocetyl, dimethyl Octanoic acid 2-octyldodecyl, myristyl lactate, trioctyldodecyl citrate, diisostearyl malate, succinate di-2-ethylhexyl, diisopropyl adipate, diisobutyl adipate, stearic acid cholesteryl.
上記油脂は、脂肪酸とグリセリンとのトリエステルを主成分とする公知のものであり、例えば、アーモンド油、アボガド油、オリーブ油、シア脂、シア脂油、月見草油、チャボトケイソウ種子油、ツバキ油、ババス油、ピーナッツ油、ローズヒップ油が挙げられる。 The fats and oils are known ones mainly composed of a triester of a fatty acid and glycerin. For example, almond oil, avocado oil, olive oil, shea fat, shea fat oil, evening primrose oil, chabodia seed oil, camellia oil, babas Oil, peanut oil, rosehip oil.
上記炭化水素としては、例えば、ドデカン、イソドデカン、テトラデカン、ヘキサデカン、及びイソヘキサデカン、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックスが挙げられる。 Examples of the hydrocarbon include dodecane, isododecane, tetradecane, hexadecane, and isohexadecane, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, and microcrystalline wax.
上記ロウは、高級脂肪酸と高級アルコールとのエステルを主成分とするものであり、例えば、ミツロウ、モクロウ、ホホバ油、キャンデリラロウ、カルナウバロウが挙げられる。 The wax is mainly composed of an ester of a higher fatty acid and a higher alcohol, and examples thereof include beeswax, mole, jojoba oil, candelilla wax, and carnauba wax.
(剤型)
本実施形態の毛髪用処理剤の使用時の剤型は、特に限定されない。毛髪が濡れている状態で毛髪用処理剤を頭皮に塗布し、頭皮をマッサージする場合があり、この場合には、剤型が泥状であると、頭皮への毛髪用処理剤の塗布を十分に行える。
(Form)
The dosage form at the time of use of the treatment agent for hair of this embodiment is not specifically limited. The hair treatment agent may be applied to the scalp while the hair is wet, and the scalp may be massaged. In this case, if the dosage form is mud, it is sufficient to apply the hair treatment agent to the scalp. Can be done.
(粘度)
本実施形態の毛髪用処理剤の粘度は、10Pa・s以上40Pa・s以下が良く、10Pa・s以上30Pa・s以下が好ましい。この粘度範囲は、毛髪が濡れている状態での頭皮への塗布に適している。なお、粘度は、B型粘度計を使用して25℃、ロータ回転速度12rpmで計測した60秒後の値である。
(viscosity)
The viscosity of the hair treatment agent of this embodiment is preferably 10 Pa · s to 40 Pa · s, and preferably 10 Pa · s to 30 Pa · s. This viscosity range is suitable for application to the scalp when the hair is wet. The viscosity is a value after 60 seconds measured using a B-type viscometer at 25 ° C. and a rotor rotational speed of 12 rpm.
(製造方法)
本実施形態の毛髪用処理剤の製造方法は、例えば、粘土鉱物以外を配合し、加温しつつ撹拌により原料を十分に分散させてから、粘土鉱物を配合し、撹拌する方法がある。
(Production method)
The method for producing the hair treatment agent of the present embodiment includes, for example, a method in which a material other than clay mineral is blended and the raw materials are sufficiently dispersed by stirring while heating, and then the clay mineral is blended and stirred.
(用途)
本実施形態の毛髪用処理剤の用途は、毛髪の感触を改善する高級アルコールとカチオン界面活性剤が配合されたものであるから、リンス、コンディショナー、トリートメント(例えば、洗い流さないトリートメント、洗い流すトリートメント、整髪兼用トリートメント、多剤式トリートメントの一構成剤、パーマの前処理のためのトリートメント、パーマの後処理のためのトリートメント、カラーリングの前処理のためのトリートメント、カラーリングの後処理のためのトリートメント、ブリーチの前処理のためのトリートメント、ブリーチの後処理のためのトリートメント)が挙げられる。
(Use)
Since the use of the hair treatment agent of the present embodiment is a combination of a higher alcohol and a cationic surfactant that improve the feel of the hair, rinse, conditioner, treatment (for example, non-washing treatment, washing-off treatment, hair styling) Combined treatment, one component of multi-drug treatment, treatment for pre-treatment of perm, treatment for post-treatment of perm, treatment for pre-treatment of coloring, treatment for post-treatment of coloring, Treatment for pre-treatment of bleach and treatment for post-treatment of bleach).
以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 EXAMPLES Hereinafter, although this invention is explained in full detail based on an Example, this invention is not interpreted limitedly based on description of this Example.
水と、塩化ベヘニルトリメチルアンモニウム、セチルアルコール、ステアリルアルコール、カオリン、モロッコ溶岩クレイ、グリチルリチン酸ジカリウム、ウンデシレン酸ヘプチル、市販品A、イソステアリン酸イソステアリル、テトライソステアリン酸ペンタエリスチル、オレイン酸エチル、アジピン酸ジイソプロピル、イソプロパノール、1,3−プロパンジオール、及び香料から選択した原料とを配合して、下記実施例及び比較例の毛髪用処理剤を製造した。 Water, behenyltrimethylammonium chloride, cetyl alcohol, stearyl alcohol, kaolin, Moroccan lava clay, dipotassium glycyrrhizinate, heptyl undecylenate, commercial product A, isostearyl isostearate, pentaerystyl tetraisostearate, ethyl oleate, adipic acid The hair treating agent of the following Example and Comparative Example was manufactured by blending a raw material selected from diisopropyl, isopropanol, 1,3-propanediol, and a fragrance.
実施例2a〜2eの毛髪用処理剤については、これを使用し、シャンプーで洗浄した頭髪と頭皮への塗布、頭皮のマッサージを行い、温水で洗い流し、温風で頭髪を乾燥させた。この毛髪用処理剤の使用において、頭皮への塗布は容易であった。また、下記の通り、「根元の軽さ」と「均一感」を評価した。この評価での基準は、以下の通りである。 The hair treatment agents of Examples 2a to 2e were used, applied to the hair and scalp washed with shampoo, massaged the scalp, rinsed with warm water, and dried with warm air. Application of the hair treatment agent to the scalp was easy. In addition, as described below, “lightness of the root” and “uniformity” were evaluated. The criteria for this evaluation are as follows.
(根元の軽さ)
乾燥後の毛髪の根元が軽い感触かを、評価した。
○:基準より軽い感触であった。
―:基準と同等の感触であった。
×:基準よりも重い感触であった。
(Lightness at the base)
It was evaluated whether the hair root after drying was a light touch.
○: The touch was lighter than the standard.
―: The feel was equivalent to the standard.
X: The touch was heavier than the standard.
(均一感)
乾燥後の毛髪の中間部から毛先まで均一な感触であるかを、評価した。
○:基準より均一な感触であった。
―:基準と同等の感触であった。
×:基準よりも不均一な感触であった。
(Uniform feeling)
It was evaluated whether it was a uniform feel from the middle part of the hair after drying to the end of the hair.
○: The touch was more uniform than the standard.
―: The feel was equivalent to the standard.
X: The touch was more uneven than the reference.
下記表1〜2に、毛髪用処理剤の製造のために水と配合した原料、剤型、粘度を示す。また、表2には、毛髪用処理剤で処理した毛髪の評価結果を併せて示す。 Tables 1 and 2 below show raw materials, dosage forms, and viscosities blended with water for the production of hair treatment agents. Table 2 also shows the evaluation results of the hair treated with the hair treatment agent.
表1においては、(A)〜(B)及び増粘効果がある(C)を配合した比較例1よりも、更に(D)が配合された実施例1a〜1bは、著しく粘度が高かったことを確認できる。また、実施例1a〜1bは、比較例1と異なる泥状の剤型であったことを確認できる。 In Table 1, Examples 1a to 1b, in which (D) was further blended, were significantly higher in viscosity than (A) to (B) and Comparative Example 1 in which (C) had a thickening effect. I can confirm that. Moreover, it can confirm that Example 1a-1b was a mud dosage form different from the comparative example 1. FIG.
Claims (5)
(A)カチオン界面活性剤
(B)高級アルコール
(C)粘土鉱物
(D)グリチルリチン酸及び/又はその塩 A treatment agent for hair, wherein the following (A) to (D) are blended with water.
(A) Cationic surfactant (B) Higher alcohol (C) Clay mineral (D) Glycyrrhizic acid and / or salt thereof
前記(A)カチオン界面活性剤に対する前記(B)高級アルコールのモル比([B]/[A]比)が3.0/1以上である
請求項1に記載の毛髪用処理剤。 The total blending amount of the (A) cationic surfactant and the (B) higher alcohol is 5% by mass or more,
The hair treatment agent according to claim 1, wherein a molar ratio ([B] / [A] ratio) of the (B) higher alcohol to the (A) cationic surfactant is 3.0 / 1 or more.
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US10111815B2 (en) | 2014-06-17 | 2018-10-30 | The Procter And Gamble Company | Composition for hair frizz reduction |
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|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |