JP2014047391A - Pretreatment method and pretreatment apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a pretreatment technique before plating in which when plating treatment is performed by making a plating object surface of a plating object face downward, influence of air bubbles or the like to a fine via or a fine trench formed on the plating object surface is suppressed as much as possible, and plating treatment can be surely performed.SOLUTION: There is provided a pretreatment method of plating treatment in which plating liquid is supplied to a plating object W in which a plating object surface is made to face downward, plating liquid is made to contact the plating object surface, and plating is performed. A plating object W is laid at an upper part 112 of a pretreatment tank, a plating object is heated, an inside of a pretreatment tank 110 is decompressed to be 9 hPa-40 hPa, water of 10°C-30°C is supplied to the inside of the pretreatment tank, gas in the pretreatment tank is replaced by a vaporization water, water is filled in the pretreatment tank to make water contact the plating object surface, then atmospheric air is introduced in the pretreatment tank to make the inside to be the atmospheric pressure, and water is made to attach to the plating object surface.

Description

  The present invention relates to a pretreatment when performing plating treatment on an object to be plated such as a semiconductor wafer or a printed wiring board. In particular, the plating target surface of the object to be plated is directed downward toward the plating target surface. The present invention relates to a pretreatment technique of plating treatment in which plating is performed while supplying a liquid.

  In recent years, various plating processes have been performed on objects to be plated such as electronic substrates such as semiconductor wafers and printed wiring boards. A jet type plating apparatus is known as one of apparatuses for performing a plating process on such a plating object. This jet plating apparatus generally has a plating tank that is capable of supplying a plating solution from the bottom, and a peripheral edge of a plating object placed along the opening of the plating tank, and is directed downward. A plating solution is supplied toward the target surface to perform a plating process.

  In this jet plating process, the plating solution supplied as a jet from below flows along the entire surface of the plating target surface, so that uniform plating can be performed on the entire surface of the plating target surface. Furthermore, in this jet type plating apparatus, since the plating object can be sequentially replaced by changing the object to be plated placed in the opening of the plating tank, it is widely used as an apparatus suitable for small lot production and automation of the plating process (for example, Patent Document 1, Patent Document 2).

  In recent years, various embedding plating processes have been performed in the gaps between the wirings formed on the wafer surface and in the gaps between vias and wiring circuits formed on the printed wiring board. The progress of the miniaturization of the gaps and vias between the wirings is remarkable. The following problems have begun to be pointed out when embedding plating treatment is performed on such fine vias and trenches with a jet type plating apparatus.

  In the jet-type plating process, the plating target surface of the object to be plated is directed downward. Therefore, when the plating solution is supplied from below, the gas in the plating solution is collected on the plating target surface. Then, when bubbles enter the vias or trenches, there is a case where the buried plating process cannot be performed reliably. In order to remove the influence of such bubbles, bubbles are formed in gaps such as vias and trenches by subjecting the surface to be plated to hydrophilic treatment in advance or adding an additive that improves the hydrophilicity of the plating solution. It has been proposed that no be left behind. However, in the case of jet-type plating treatment, the surface to be plated faces downward, so it is difficult to sufficiently perform hydrophilic treatment on all vias and trenches. At present, it is very difficult to completely remove the bubbles present in the glass.

JP-A-8-74088 JP 2002-173794 A

  The present invention has been made under the circumstances as described above, and when performing the plating process with the plating target surface of the object to be plated facing downward, the micro vias and trenches formed on the plating target surface are not affected. Thus, the present invention provides a pretreatment method for plating treatment that can suppress the influence of bubbles and the like as much as possible and perform the plating treatment reliably.

  In order to solve the above problems, the present invention is a pretreatment method of a plating process in which plating is performed by supplying a plating solution to an object to be plated with the surface to be plated down, and bringing the plating solution into contact with the surface to be plated. Then, the object to be plated is placed on the upper part of the pretreatment tank, the object to be plated is heated, the inside of the pretreatment tank is decompressed to 9 hPa to 40 hPa, and water at 10 ° C. to 30 ° C. is supplied into the pretreatment tank. Then, the gas in the pretreatment tank is replaced with vaporized water, the pretreatment tank is filled with water and water is brought into contact with the surface to be plated, and then the atmosphere is introduced into the pretreatment tank to atmospheric pressure. And water is attached to the surface to be plated.

  In the present invention, in a state in which the plating target surface of the object to be plated is directed downward, it becomes possible to reliably adhere water to the entire surface of the plating target, so in the subsequent contact with the plating solution, The influence of bubbles on the surface to be plated can be suppressed as much as possible. In particular, according to the pretreatment method of the present invention, water can be made to enter a gap such as a minute via or a trench in advance, and a state in which bubbles inside the gap are completely removed can be realized. It is possible to reliably perform the filling plating process in the trench or the like.

  In the pretreatment method of the present invention, the pressure in the pretreatment tank is reduced to a pressure corresponding to a saturated water vapor pressure of 9 hPa to 40 hPa with the surface to be plated placed on the upper part of the pretreatment tank. And while performing this pressure reduction operation | work, 10 to 30 degreeC water is supplied in a pretreatment tank. If it does so, the gas which exists in the space in a pretreatment tank will be in the state where it was filled with saturated water vapor. That is, the gas in the pretreatment tank is replaced with vaporized water. Then, in the state where the space in the pretreatment tank is filled with saturated water vapor, the inside of the pretreatment tank is filled with water, and water is brought into contact with the entire surface to be plated. Thereby, the hydrophilic process which made water contact the whole surface to be plated can be performed. In addition, when the gas in the pretreatment tank is replaced with vaporized water, the vaporized water is filled in the space in the gap such as a minute via or trench, and the gas in the gap, that is, the bubble It is possible to completely remove such gases.

  The reason why the reduced pressure in the pretreatment tank in the present invention is 9 hPa to 40 hPa corresponds to the saturated water vapor pressure at a water temperature of 10 ° C to 30 ° C. In the pretreatment method of the present invention, the object to be plated placed in the pretreatment tank is heated when water is condensed on and adheres to the surface to be plated when the inside of the pretreatment tank is depressurized. This heating temperature is preferably about 5 ° C. higher than the temperature of the water supplied by the surface to be plated of the object to be plated. It is preferable to heat so that it may become a C-35 degreeC.

  In the pretreatment method of the present invention, it is preferable to use deaerated water as the water supplied to the pretreatment tank. This is because if it is deaerated water, it is possible to more reliably prevent bubbles from adhering to the surface to be plated.

  The pretreatment method of the present invention is provided with a placing portion for placing an object to be plated with the plating target surface downward, a treatment tank provided with water supply, discharge means, and decompression means, This can be realized by a pretreatment device having a lid for pressing and fixing the object to be placed on the placing part, provided with a heating means for heating the object to be placed.

  According to the present invention, when performing the plating process with the surface to be plated of the object to be plated facing downward, the influence of bubbles and the like is suppressed as much as possible to the minute vias and trenches formed on the surface to be plated. Thus, the plating process can be reliably performed.

The schematic sectional drawing of a pre-processing apparatus. Cross-sectional observation photograph of test substrate. Cross-sectional observation photograph of test substrate.

  Embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows a schematic cross-sectional view of a pretreatment apparatus according to the present invention.

  The pretreatment apparatus 100 according to the present embodiment includes a pretreatment tank 110 and a lid 120, and a placement unit 112 for an object to be plated W in which a seal 111 is disposed is provided inside the pretreatment tank 110. . The mounting portion 112 and the seal 111 are configured so that the periphery of the plating target surface of the object to be plated can be mounted. Further, the lid 120 is provided with a wafer pressing part 121 and a heater 122.

  A water supply pipe 113 is provided at the bottom of the pretreatment tank 110, and a drain pipe 114 is connected to the water supply pipe 113. The pretreatment tank is provided with a decompression pipe 115 for adjusting the pressure in the tank. And these automatic control valves V1-V6 are arrange | positioned at each of these piping. A vacuum pump P is connected to the outside of the valve V6, and the outside of the valve V5 on the opposite side is an open port so that the atmosphere can be introduced into the tank. A catch tank 116 is disposed in the middle of the decompression pipe 115 and the drain pipe 114. The catch tank 116 determines that the tank has been filled with water by opening the valve V4 when water is supplied to the tank by starting to flow into the catch tank. .

  Next, the operation of the preprocessing device shown in FIG. 1 will be described. The lid 120 is removed, and the object to be plated W is arranged on the seal 111 of the placement part 112 with the surface to be plated of the object W to be plated facing downward. Then, the object to be plated is attached by the lid part 120, and the object to be plated W is pressed and fixed to the mounting part 112. The periphery of the plating target surface of the workpiece W is fixed in a liquid-tight manner by a seal 111. Then, it heats from the heater 122 so that the temperature of the to-be-plated object W may be 35 degreeC.

  The valves V1, V2, V3, V4, and V5 are closed, V6 is opened, and the vacuum pump P is driven. The vacuum pressure in the tank is adjusted to 23.8 torr (31.7 hPa, saturated water vapor pressure at a water temperature of 25 ° C.), the vacuum pump P is adjusted, and the valve V1 of the water supply pipe 113 is opened while the pressure is reduced. Water at 25 ° C. is supplied to such an extent that it slightly accumulates at the bottom of the tank. The supplied water is degassed pure water. When the pressure in the tank is reduced, the object to be plated is heated to 35 ° C., so that no condensation occurs on the surface to be plated.

  When the inside of the tank is depressurized to 23.8 torr and the inside space of the tank is filled with vaporized water (saturated steam), the valve V1 of the water supply pipe 113 is opened again, and the tank Pure water is supplied until the inside is filled with pure water. As a supply method at this time, pure water is slowly supplied so that the horizontal water surface gradually rises toward the surface to be plated. By supplying such pure water, gas such as bubbles is prevented from remaining on the plating target surface.

  When the tank is filled with pure water, the valve V4 is kept open so that pure water is supplied until the pure water flows into the catch tank 116. After the tank is filled with pure water and pure water is in contact with the surface to be plated, the supply of pure water and the vacuum pump P are stopped, the valve V6 is closed, and the valve V5 is opened. The air is introduced into the tank, and the inside of the tank is returned to the atmospheric pressure. And the valve | bulb V2, V3 is opened, the pure water in a tank is discharged | emitted, the cover part 120 is removed, and the to-be-plated object W is taken out in the state which orient | assigned the plating object surface to the downward direction. Thereafter, the object to be plated W with the surface to be plated directed downward is placed on a jet-type plating apparatus, and a predetermined plating process is performed.

  Next, the result of performing the hole filling plating process on the substrate using the pretreatment apparatus of the present invention will be described. As the object to be plated, a test substrate in which a plurality of blind via holes having a diameter of 20 μm and a depth of 100 μm was formed was used. Moreover, the copper plating solution (product name: Microfab Cu520 / manufactured by Nippon Electroplating Engineers Co., Ltd.) was used for the hole filling plating process of the blind via hole.

  As for the effect of the pretreatment apparatus of the present invention, after performing the pretreatment of the test substrate, a test substrate is produced when the hole filling plating process is performed and when the hole filling plating process is performed without the pretreatment, This was done by observing and confirming the state of the filling plating in the hole. 2 and 3 show cross-sectional observation photographs.

  FIG. 2 shows a test substrate with pretreatment, and FIG. 3 shows a test substrate without pretreatment. As can be seen from FIG. 2, it was found that the copper plating was completely embedded in the hole. On the other hand, in the case of FIG. 3, it was confirmed that the copper plating process was not performed on the bottom side of the hole (the portion that looks dark in the hole in FIG. 3).

  According to the present invention, since the plating target surface of the object to be plated can be directed downward with respect to the minute vias and trenches formed on the plating target surface, the small lot production and the plating processing can be performed. Automation can be suitably performed.

DESCRIPTION OF SYMBOLS 100 Pretreatment apparatus 110 Pretreatment tank 111 Seal 112 Placement part 113 Supply pipe 114 Drain pipe 115 Decompression pipe 116 Catch tank 120 Lid W W

Claims (2)

A pretreatment method of a plating process in which plating is performed by supplying a plating solution to the object to be plated with the plating target surface facing downward, and bringing the plating solution into contact with the plating target surface,
Place the object to be plated on the top of the pretreatment tank, heat the object to be plated,
The pressure in the pretreatment tank is reduced to 9 to 40 hPa, and water at 10 ° C. to 30 ° C. is supplied into the pretreatment tank, the gas in the pretreatment tank is replaced with vaporized water, and the pretreatment tank is filled. Fill the surface to be plated with water,
Then, the pretreatment method characterized by introducing air into the pretreatment tank to atmospheric pressure and attaching water to the surface to be plated. A pretreatment tank provided with a placement unit for placing an object to be plated with the plating target surface down, and provided with water supply, discharge means and decompression means;
A pretreatment device comprising: a lid for pressing and fixing the object to be placed on the placing part, provided with a heating means for heating the object to be placed.