JP2014029887A - Battery - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a battery that facilitates the production.SOLUTION: A battery includes a battery exterior body, a terminal bolt 3c which is disposed outside the battery exterior body, a winding type power generating element 1 having an active material uncoated part at an end, and a current collecting connection plate 2 connecting the power generating element 1 and the terminal bolt 3c. The power generating element 1 has overlaps of the active material uncoated part halved about a winding shaft, and the current collecting connection plate 2 includes a main body 2a which extends horizontally from the end of the power generating element 1 toward the center of the power generating element 1 and is connected to the terminal bolt 3c, and a plurality of connection plate parts 2b which are projected from the main body 2a to be arranged respectively outside the overlaps of the halved active material uncoated part, and joined with the overlaps of the halved active material uncoated part respectively.

Description

  The present invention relates to a battery including a terminal including a battery lead terminal, a terminal connection member, and an external connection terminal.

  In FIG. 3, the connection structure of the conventional electric power generation element 1, the current collection connection board 2, and the terminal 3 in a large sized nonaqueous electrolyte secondary battery is shown. This non-aqueous electrolyte secondary battery has two long cylindrical power generation elements 1 arranged in parallel. Each power generation element 1 is obtained by winding a positive electrode 1a and a negative electrode 1b in a long cylindrical shape through a separator. The positive electrode 1a carries a positive electrode active material on the surface of a strip-shaped aluminum foil, and the negative electrode 1b is formed of a strip-shaped copper. A negative electrode active material is supported on the surface of the foil. However, each of the positive electrode 1a and the negative electrode 1b is provided with an uncoated portion where no active material is applied on one side end of the belt-like shape so that the aluminum foil and the copper foil are exposed at the uncoated portion. ing. Then, the positive electrode 1a and the negative electrode 1b are shifted in the opposite directions along the winding axis when the power generating element 1 is wound, so that the positive electrode 1a and the negative electrode 1b are disposed on one end surface (lower right in the drawing) of the long cylindrical shape. Only the aluminum foil at the side end of 1a protrudes, and only the copper foil at the side end of the negative electrode 1b protrudes from the other end face (upper left in the figure).

  The two power generation elements 1 and 1 are arranged side by side so that the flat side surfaces of the long cylindrical shape stand upright and overlap each other. Then, the aluminum foil of the positive electrode 1a and the copper foil of the negative electrode 1b protruding from the end face of each power generating element 1 are respectively attached to the corrugated current collecting connection plates 2 and 2 at both end faces of these power generating elements 1 and 1. It comes to connect. Each current collector connection plate 2 is formed by forming two metal plates into corrugated irregularities, overlapping the end portions thereof, and connecting and fixing the terminals 3 to the upper ends of the mating portions. The current collector connection plate 2 to which the terminal 3 on the positive electrode side is connected and fixed is sandwiched between the corrugated plate-like recesses with the aluminum foil of the positive electrode 1a protruding from one end face of the power generation element 1, 1 by ultrasonic welding. The current collector connection plate 2 that is connected and fixed and connected and fixed to the terminal 3 on the negative electrode side is inserted by inserting the copper foil of the negative electrode 1b protruding from the other end face of the power generating elements 1 and 1 into each corrugated recess. The connection is fixed by sonic welding.

  The two power generating elements 1 are housed in a casing-like battery container (not shown), and the upper end opening of the battery container is closed by a cover plate. At this time, the upper end portions of the terminals 3 and 3 pass through the lid plate via an insulating sealing material and project outside. And the inside of the battery exterior body which consists of this battery container and a cover board is filled with electrolyte solution, and it becomes a nonaqueous electrolyte secondary battery.

  Therefore, the non-aqueous electrolyte secondary battery accommodates the two power generation elements 1 and 1 side by side so that the long cylindrical flat side faces upright, and the terminals 3 and 3 are the battery exterior body. Since it protrudes upwards from the both ends of the upper surface, the space efficiency of the installation becomes good.

  However, in the non-aqueous electrolyte secondary battery, the current collector connecting plate 2 connected to the terminal 3 protruding upward is overlapped with the straight portions of the positive electrode 1a and the negative electrode 1b of the horizontal power generation element 1 that are perpendicular to each other. For this reason, there is a problem in that it is difficult to manufacture the substrate 3 by combining corrugated plate materials having a complicated shape or making it difficult to connect to the terminals 3.

  Moreover, in order to increase the current capacity of the current collector connection plate 2, it is necessary to increase the thickness of the corrugated portion to some extent, and it is sufficient even if ultrasonic welding is performed by sandwiching a thin aluminum foil or copper foil. There was also a problem that it could not be welded. In addition, the current collector connection plate 2 needs to be sandwiched by inserting and overlapping aluminum foils and copper foils overlapping each other for each of the two power generating elements 1 into each of the corrugated concave portions. There was also a problem that the sex became worse.

  An object of the present invention is to provide a battery that can be easily manufactured in an improved battery in response to such circumstances.

  The battery according to claim 1 includes a battery exterior body, an external connection terminal disposed outside the battery exterior body, a wound-type power generation element having an active material uncoated portion at an end, and the power generation element. A current collector connection plate for connecting to the external connection terminal, the power generation element has an overlap of the active material uncoated portion divided in two about the winding axis, the current collector connection plate, A main body extending horizontally from the end of the power generation element in the center direction of the power generation element and connected to the external connection terminal, and projecting from the main body, the bisected active material uncoated part It has a plurality of connecting plate portions which are respectively arranged outside the overlap and are joined to each of the overlaps of the bisected active material uncoated portions.

  According to the first aspect of the present invention, since the current collector connection plate can be easily connected to the external connection terminal and the power generation element, the battery can be easily manufactured.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an assembled perspective view illustrating a connection structure between a power generation element and a terminal of a nonaqueous electrolyte secondary battery according to an embodiment of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an assembled perspective view showing a structure of a nonaqueous electrolyte secondary battery according to an embodiment of the present invention. It is an assembly perspective view which shows a prior art example and shows the connection structure of the electric power generation element and terminal of a nonaqueous electrolyte secondary battery.

  Embodiments of the present invention will be described below with reference to the drawings.

  1 to 2 show an embodiment of the present invention. FIG. 1 is an assembled perspective view showing a connection structure between a power generation element and a terminal of a nonaqueous electrolyte secondary battery, and FIG. 2 is a nonaqueous electrolyte 2. It is an assembly perspective view which shows the structure of a secondary battery. In addition, the same number is attached | subjected to the structural member which has the function similar to the prior art example shown in FIG.

  In the present embodiment, a large nonaqueous electrolyte secondary battery will be described as in the conventional example. As shown in FIG. 1, the non-aqueous electrolyte secondary battery has two long cylindrical power generation elements 1 and 1 arranged in parallel. Each power generating element 1 has the same configuration as that of the conventional example, and the aluminum foil at the side end of the positive electrode 1a protrudes from one end surface of the long cylindrical shape, and the copper foil at the side end of the negative electrode 1b from the other end surface. Has come to protrude.

  The two power generation elements 1 and 1 are arranged side by side so that the flat side surfaces of the long cylindrical shape stand upright and overlap each other. And the current collection connection plates 2 and 2 are arrange | positioned at the both ends of these two electric power generation elements 1 and 1, respectively. The current collector connection plates 2 and 2 are each made of a metal plate having a sufficient thickness so that a large current capacity can be obtained. The one on the positive electrode 1a side disposed at one end of the power generation element 1 is made of an aluminum alloy plate. The one on the negative electrode 1b side arranged at the other end is made of a copper alloy plate. Each of the current collector connection plates 2 includes a substantially trapezoidal horizontally disposed main body 2a and four elongated connection plate portions 2b protruding downward from the trapezoidal bottom portion of the main body. In each connection plate portion 2b, a plurality of convex portions protruding from the plate surface are formed at appropriate intervals. That is, each current collector connection plate 2 presses an aluminum alloy plate or a copper alloy plate with a trapezoidal main body 2a and four elongated connection plate portions 2b extending straight from the bottom of the trapezoidal shape in a comb shape. By punching out by machining, forming convex portions on each connecting plate portion 2b, bending these connecting plate portions 2b at right angles to the main body 2a at the base, and twisting each bent connecting plate portion 2b by 90 degrees at the base It is formed. Further, these four connection plate portions 2b are twisted so that the left and right two pairs form a pair, and the opposite sides of each pair of the two connection plate portions 2b rotate in the opposite direction to the main body 2a side. Yes. And the convex part of each connection board part 2b is protrudingly provided so that what may become a pair may protrude in this direction by this twist.

  The length L in the protruding direction of the twisted portion of each connection plate portion 2b is set to be longer than the plate thickness T of the connection plate portion 2b. This is because when the length L is shorter than the plate thickness T, a steep torsion process is applied to the connecting plate portion 2b, stress is concentrated on the twisted portion, and the conductivity is lowered.

  Each of the current collector connection plates 2 has a main body 2 a disposed above both ends of the two power generation elements 1, 1, and the connection plate portion 2 b is disposed along the end faces of these power generation elements 1, 1. To be. That is, the current collecting connection plate 2 made of an aluminum alloy plate is disposed on the end face side where the aluminum foil of the positive electrode 1a of each power generating element 1 protrudes, and the end face side where the copper foil of the negative electrode 1b protrudes consists of a copper alloy plate. A current collector connection plate 2 is disposed. Further, the two connecting plate portions 2b to be paired are arranged on both sides of the metal foil of the positive electrode 1a and the negative electrode 1b protruding from the end face of each power generating element 1. Here, since the metal foil of the positive electrode 1a and the negative electrode 1b is wound on both end faces of each power generation element 1 and protrudes into a long cylindrical shape, these metal foils are curved in a long cylindrical shape. The overlapping portion that is perpendicular to and overlaps with the straight portion between the portions can be divided into two equal parts about the winding axis. And the two connection board parts 2b used as the pair arrange | positioned for every end surface of each electric power generation element 1 are each arrange | positioned on the outer side of the overlap of these metal foils divided into right and left. At this time, the two connecting plate portions 2b to be paired are twisted in such a direction that the inner side sides that were originally facing each other escape from the power generation element 1, so that the metal foil protruding from the end face of each power generation element 1 In particular, the curved portion on the upper side naturally fits between the two connecting plate portions 2b of each pair.

  When the current collector connection plate 2 is arranged in this manner, the metal foils of the positive electrode 1a and the negative electrode 1b of the power generation element 1 are connected and fixed to each connection plate portion 2b by the sandwiching plate 4. That is, at each end face of each power generating element 1, first, the overlap of the straight portions of the metal foil is divided into left and right, and along the connection plate portion 2b on each side, and the connection plate portion 2b and the metal foil are sandwiched between 4 to be sandwiched between. Then, the overlapping of the metal foils of the left and right halves is in close contact with the inner surfaces of the two connecting plate portions 2b that form a pair. Then, the connection plate portion 2b and the metal foil of the positive electrode 1a and the negative electrode 1b are joined by performing ultrasonic welding from both sides of each of the holding plates 4 holding the connection plate portion 2b and the metal foil. . Each sandwiching plate 4 is a strip-shaped relatively thin metal plate folded in half along the longitudinal direction. The sandwiching plate 4 made of an aluminum alloy plate is used on the positive electrode 1a side, and on the negative electrode 1b side. A copper alloy plate clamping plate 4 is used. Since these clamping plates 4 are used only for welding and fixing the connection plate portion 2b and the metal foil securely, it is not necessary to increase the current capacity in particular, and optimum ultrasonic welding is possible. A metal plate having an appropriate thickness can be used. Moreover, since each convex part is formed in each connection board part 2b on the inner surface which overlaps with metal foil, these metal foils receive ultrasonic energy intensively in each convex part, and welding Can be ensured.

  The sandwiching plate 4 is shorter than the length of the straight portion of the cylindrical metal foil of the positive electrode 1a and the negative electrode 1b protruding from the end face of the power generation element 1. In this way, the sandwiching plate 4 can sandwich only the straight portion of the metal foil together with the connection plate portion 2b. This is because when the sandwiching plate 4 is longer than the length of the straight portion of the metal foil, the sandwiching plate 4 sandwiches the upper and lower curved portions of the metal foil protruding in a cylindrical shape, and this metal foil is forcedly pushed. This is because there is a risk of pulling and breaking the holding plate 4 side.

  The positive and negative terminals 3 and 3 of the nonaqueous electrolyte secondary battery of the present embodiment are each composed of a rivet terminal 3a, a terminal connection rod 3b, and a terminal bolt 3c. The rivet terminal 3a is obtained by projecting cylindrical caulking portions from the upper and lower surfaces of a square flange portion having four corners chamfered, and is made of aluminum or an aluminum alloy in the case of the terminal 3 used as a positive electrode terminal. In the case of the terminal 3 used as the negative electrode terminal, it is made of copper or a copper alloy. Since the rivet terminal 3a is in contact with the electrolyte at the lower caulking portion, in the case of a nonaqueous electrolyte secondary battery, it is necessary to use aluminum or an aluminum alloy that does not dissolve in the nonaqueous electrolyte at the positive electrode side on the positive electrode terminal side. On the negative electrode terminal side, it is necessary to use copper, a copper alloy, or the like that is not alloyed with the negative electrode active material. The terminal connection rod 3b is a rectangular metal plate made of a copper alloy, and through holes are formed at both ends. The terminal bolt 3c is a stainless steel hexagon bolt with a bolt portion protruding upward from the top surface of the hexagonal head. Since the terminal connection rod 3b and the terminal bolt 3c do not come into contact with the electrolytic solution, in the case of the terminal connection rod 3b, a copper alloy having a particularly high electrical conductivity and sufficient mechanical strength is used. In the case of the terminal bolt 3c to be connected, stainless steel having particularly high mechanical strength and sufficient conductivity is used.

  The main bodies 2a and 2a of the current collector connection plates 2 and 2 are actually covered with the bottom plate 6 via the lower insulating sealing materials 5 and 5 shown in FIG. It is arrange | positioned at the both ends of the lower surface of. Further, on both ends of the upper surface of the cover plate 6, rivet terminals 3a, 3a, terminal connection rods 3b, 3b, and terminal bolts 3c, 3c of the terminals 3, 3 via upper insulating sealing materials 7, 7 respectively. Is placed. However, each rivet terminal 3 a is formed in the main body 2 a of the current collector connection plate 2 at the tip of the lower crimping portion through a through hole formed in the lower insulating sealing material 5, the cover plate 6 and the upper insulating sealing material 7. It is inserted into the through-hole and fixed by caulking. At this time, the rivet terminal 3 a is insulated from the cover plate 6 by the insulating sealing materials 5 and 7. In addition, the caulking portion below the rivet terminal 3a and the main body 2a of the current collector connection plate 2 are caulked, so that the insulating sealing materials 5 and 7 press the lid plate 6 between them. The through-hole is sealed. Each terminal connection rod 3b disposed on both ends of the upper surface of the cover plate 6 via the upper insulating sealing materials 7 and 7 has the caulking portion above the rivet terminal 3a inserted into one through hole from below. Then, the terminal bolt 3c is inserted into the other through hole from below by being connected and fixed by caulking. At this time, the terminal bolt 3 c is prevented from rotating by fitting the hexagonal head into the hexagonal recess of the upper insulating sealing material 7. The terminal bolt 3c is provided only when the bolt is tightened with a nut through a connection member of an external circuit by keeping the bolt portion fitted and locked in the through hole of the terminal connection rod 3b. Instead of being connected and fixed to 3b, the head and the like are connected and fixed to the terminal connection rod 3b in advance by welding or the like. If the terminal bolt 3c is connected and fixed in advance to the terminal connection rod 3b in this way, even if the external circuit connection member is not sufficiently tightened with the nut, the terminal connection rod 3b is placed on the portion in direct contact with the connection member. In addition to the current flowing, the current can surely flow from the terminal connecting rod 3b to the portion where the nut contacts the connecting member via the terminal bolt 3c, and the contact resistance between the terminal 3 and the connecting member can be reduced. become able to.

  When the terminals 3 and 3 are disposed at both ends of the upper surface of the lid plate 6 as described above, and the current collector connection plates 2 and 2 are attached to both ends of the lower surface of the lid plate 6, these current collectors The power generation elements 1 and 1 are connected to the connection plates 2 and 2 as described above. These two power generation elements 1 are housed inside a casing-like battery container 8 made of a stainless steel plate, and the upper end opening of the battery container 8 is closed by the cover plate 6. Then, the periphery of the cover plate 6 is sealed by welding, the inside of the battery container 8 is filled with an electrolytic solution, and the inside is sealed to form a nonaqueous electrolyte secondary battery. This non-aqueous electrolyte secondary battery accommodates two power generating elements 1 side by side so that the flat side surfaces of the long cylindrical shape stand upright, and the terminal bolts 3c of the terminals 3 are arranged at both ends of the upper surface of the lid plate 6. Since it protrudes upward from the part, the space efficiency of the installation is good.

  According to the non-aqueous electrolyte secondary battery having the above-described configuration, the main body 2a and the connection plate portion 2b of the current collector connection plate 2 having a large current capacity are formed between the positive electrode 1a and the negative electrode 1b of each power generation element 1 and the terminal 3. Therefore, a sufficiently large charge / discharge current can flow. Moreover, the metal foils of the positive electrode 1a and the negative electrode 1b of each power generating element 1 are ultrasonically welded to the connecting plate portion 2b via the sandwiching plate 4 made of a somewhat thin metal plate. There is no longer a tendency to peel off.

  In addition, the main body 2a of the current collector connection plate 2 is disposed horizontally above the two power generation elements 1 and 1 so as to facilitate connection with the terminal 3 penetrating the lid plate, and from the main body 2a to the connection plate. By bending the portion 2b downward and twisting and projecting, the plate surface of the connecting plate portion 2b can be aligned with the vertical metal foil of the positive electrode 1a and the negative electrode 1b protruding from the end surface of each power generating element 1. Connection with these metal foils becomes easy. That is, if each connecting plate portion 2b is not twisted, the metal foil is orthogonal to each other, and connection is not easy. Further, when the connecting plate portion 2b of the current collecting connecting plate 2 is formed by bending downward plate pieces protruding on both sides along the direction in which the power generating elements 1 and 1 of the main body 2a are arranged, the power generating element A metal foil protruding from one end face can be arranged along the plate surface of the connection plate portion 2b, but only one connection plate portion 2b can be assigned to each power generation element 1, and three or more power generations can be made. In the case of a battery in which the elements 1 are arranged side by side, it becomes impossible to collect current from one or more power generating elements 1 in the middle. Moreover, the current collector connection plate 2 of the present embodiment can be manufactured by simply performing a simple process such as punching, bending, and twisting on a single metal plate.

  In addition, since two connecting plate portions 2b are arranged for each end face of each power generating element 1, a sufficient current capacity can be obtained even if the width of the connecting plate portion 2b is reduced. It is possible to reduce the protruding amount of the metal foil from the end face. In addition, the metal foil protruding from each end face of each power generating element 1 is inserted between the two connecting plate portions 2b to be paired, so that the assembling work is facilitated.

  In the above embodiment, the connection plate portion 2b and the metal foil of the positive electrode 1a and the negative electrode 1b are connected between the clamping plates 4 by ultrasonic welding, but welding is performed by other welding such as spot welding. It can also be done. Further, instead of such welding, the connection plate portion 2b and the metal foil can be pressure-bonded by pressing with a strong force from the outside of the sandwiching plate 4. Furthermore, the metal foil can be reliably welded or pressure-bonded even if the connecting plate portion 2b is not formed with a convex portion. Moreover, in the said embodiment, although the case where the clamping board 4 was used for the connection of the connection board part 2b and the metal foil of the positive electrode 1a or the negative electrode 1b was shown, connection components other than the clamping board 4 are used, and any connection components are used. It is also possible to connect without using.

  Moreover, in the said embodiment, although shown about the nonaqueous electrolyte secondary battery which has arrange | positioned the two electric power generation elements 1 and 1 side by side, the number of this electric power generation element 1 is not limited, If it is one or more, how many pieces A non-aqueous electrolyte secondary battery using the power generation element 1 may be used. Furthermore, in the said embodiment, although the case where the current collection connection board 2 arrange | positions the two connection board parts 2b which become a pair for every positive / negative electrode of each electric power generation element 1, the positive / negative electrode of each electric power generation element 1 was shown. It is only necessary that at least one or more connecting plate portions 2b are arranged.

  Moreover, the terminal of this invention consists of a battery extraction terminal, a terminal connection member, and an external connection terminal. The battery lead-out terminal is a conductive component that is connected to the electrode of the power generation element inside the battery exterior body like the rivet terminal 3a of the above-described embodiment, and is insulated and protruded to the outside. The rivet terminal 3a The insulating sealing means is not limited to the method of pressing the insulating sealing materials 5 and 7 by caulking. The terminal connection member is a conductive component that is disposed outside the battery outer casing and connected and fixed to the external protruding portion of the battery lead terminal, like the terminal connection rod 3b of the above embodiment. It is not limited to a shape like 3b, and a connection fixing means with a battery extraction terminal is not limited to crimping. The external connection terminal is a conductive component that is arranged outside the battery exterior body and is connected to an external circuit, like the terminal bolt 3c of the above-described embodiment. However, the external connection terminal has a hexagonal bolt shape like the terminal bolt 3c. The shape is not limited, and connection to an external circuit may be performed by a structure such as a nut shape or a tapered shaft shape other than the bolt portion.

  Moreover, in the said embodiment, although the long cylindrical winding type electric power generation element 1 was demonstrated, also in the case of the lamination type electric power generation element 1, the metal foil of the positive electrode 1a and the negative electrode 1b which protruded from the end surface of lamination | stacking is the same. Can be fixed to the connection. Further, in the present invention, the shape and type of the power generation element 1 are not limited at all, and the connection structure between the current collector connection plate 2 and the power generation element 1 is not particularly limited. Furthermore, in the said embodiment, although the battery exterior body comprised by the battery container 8 and the cover plate 6 was illustrated, the structure of this battery exterior body is not specifically limited. Moreover, although the said embodiment demonstrated the nonaqueous electrolyte secondary battery, the kind of this battery is not specifically limited.

DESCRIPTION OF SYMBOLS 1 Power generation element 1a Positive electrode 1b Negative electrode 2 Current collection connection plate 2a Main body 2b Connection plate part 3 Terminal 3a Rivet terminal 3b Terminal connection rod 3c Terminal bolt 4 Clamping plate

Claims (2)

A battery case;
An external connection terminal disposed outside the battery exterior body;
A wound-type power generation element having an active material uncoated portion at the end;
A current collector connection plate for connecting the power generation element and the external connection terminal;
The power generation element is:
It has an overlap of the active material uncoated part divided into two around the winding axis,
The current collector connection plate is
A main body extending horizontally from the end of the power generation element in the center direction of the power generation element and connected to the external connection terminal;
A plurality of connection plates that protrude from the main body and are respectively arranged outside the overlap of the bisected active material uncoated portions and joined to each of the overlaps of the bisected active material uncoated portions. A battery having a portion. further,
The battery according to claim 1, further comprising an insulating sealing material disposed between a main body portion of the current collector connection plate and the battery exterior body.

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