JP2014019906A - Production device for electroplated steel sheet - Google Patents

Production device for electroplated steel sheet Download PDF

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JP2014019906A
JP2014019906A JP2012159456A JP2012159456A JP2014019906A JP 2014019906 A JP2014019906 A JP 2014019906A JP 2012159456 A JP2012159456 A JP 2012159456A JP 2012159456 A JP2012159456 A JP 2012159456A JP 2014019906 A JP2014019906 A JP 2014019906A
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steel plate
electrode
plating
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insoluble
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JP5900213B2 (en
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Shunsuke Tokui
俊介 徳井
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JFE Steel Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a production device for an electroplated steel sheet in which the repair of a worn insoluble electrode is facilitated, further, only the worn part can be repaired, and repair cost can be reduced.SOLUTION: The production device comprises: an insoluble electrode of performing energizing to a space with a steel sheet and continuously performing electroplating to the running steel sheet; and a plurality of engagement members sagged with a self fluxing electrode and the insoluble electrode, respectively, and electrically connected with the self fluxing electrode and the insoluble electrode. The insoluble electrode has: a body part in which the maximum face is confronted with the steel sheet; and a contact part engaged by each engagement member and further electrically connected, and the body part and the contact part are detachably formed.

Description

本発明は、自溶性電極および不溶性電極を用いて、自溶性電極を消費しつつ電気めっきを行う電気めっき鋼板の製造装置に関する。   The present invention relates to an apparatus for producing an electroplated steel sheet that uses a self-fluxing electrode and an insoluble electrode to perform electroplating while consuming the self-fluxing electrode.

従来、錫めっき等の電気めっき鋼板の製造は、鋼板と電極に電気をかけることによって行われている。電気めっき鋼板としては、錫めっき、亜鉛めっきなどが挙げられるが、例えば、錫めっきでは、錫を電気めっきする電気錫めっきライン(ETL:Electrolytic Tinning Line)で行われている(特許文献1参照)。
このような電気錫めっきライン、即ち、錫めっき鋼板の製造ラインにおいて、不溶性電極を用いる場合には、錫イオンは薬剤によって供給される。一方、可溶性又は自溶性錫電極を陽極として使用している場合には、錫電極自身が溶融されることによって、錫イオンを供給している。そのため、時間の経過と共に錫電極自身が消費されていく。したがって、連続的にめっき処理を行うラインにおいて自溶性錫電極を用いる場合には、所定量消費される毎に電極を交換したり、補充することが行われている。
Conventionally, manufacture of an electroplated steel sheet such as tin plating is performed by applying electricity to the steel sheet and the electrode. Examples of the electroplated steel sheet include tin plating and zinc plating. For example, tin plating is performed on an electro tinning line (ETL) for electroplating tin (see Patent Document 1). .
In such an electric tin plating line, that is, a tin-plated steel sheet production line, when an insoluble electrode is used, tin ions are supplied by a chemical. On the other hand, when a soluble or self-fluxing tin electrode is used as the anode, tin ions are supplied by melting the tin electrode itself. Therefore, the tin electrode itself is consumed over time. Therefore, when a self-fluxing tin electrode is used in a continuous plating line, the electrode is replaced or replenished every time a predetermined amount is consumed.

このように自溶性錫電極を使用して電気めっきを行う場合には、錫電極自身が溶融されつつ、錫イオンを供給することにより、鋼板のめっき処理が行われるが、電流効率は100%ではないこと等の原因により、稼働時間が増加するにつれてめっき液中の錫濃度が増加するので、めっき液の濃度調整を行う必要がある。
しかしながら、めっき液の濃度調整を行うと、錫以外の他の薬液の濃度調整も必要になるため、コストがかかっていた。
そのため、自溶性錫電極の一部を不溶性電極に変えてめっき処理を行うことにより、めっき液中の錫濃度の増加を防止することが行われていた。
Thus, when electroplating using a self-fluxing tin electrode, the tin electrode is melted while supplying the tin ions, and the steel sheet is plated, but the current efficiency is 100%. Since the tin concentration in the plating solution increases as the operation time increases due to the absence of the plating solution, it is necessary to adjust the concentration of the plating solution.
However, when the concentration of the plating solution is adjusted, it is necessary to adjust the concentration of a chemical solution other than tin, which is costly.
Therefore, an increase in the tin concentration in the plating solution has been prevented by changing the part of the self-fluxing tin electrode into an insoluble electrode and performing the plating treatment.

ところで、前述のとおり、自溶性錫電極を用いる錫めっき鋼板の製造ラインにおいては、時間の経過とともに自溶性錫電極が消費されるので、自溶性錫電極の交換や補充を行う必要がある。
自溶性錫電極の交換や補充のために鋼板の走行を停止すると生産性が低下してしまうので、自溶性錫電極に鉤状の係合部を設けて、水平に設置された棒状(管状)の係止部材に係合させて着脱容易に支持し(垂下し)、鋼板の走行を停止せずに交換や補充をすることが行われている。
By the way, as mentioned above, in the production line of the tin-plated steel plate using a self-fluxing tin electrode, since a self-fluxing tin electrode is consumed with time, it is necessary to replace or replenish the self-fluxing tin electrode.
If the travel of the steel plate is stopped for replacement or replenishment of the self-fluxing tin electrode, the productivity will be lowered. Therefore, a self-fluxing tin electrode is provided with a hook-like engagement portion and is installed in a horizontal shape (tubular) It is possible to easily support and detach (hang down) by engaging with the locking member, and to replace and replenish without stopping the running of the steel plate.

そのため、前述のように自溶性錫電極に代えて不溶性電極を配置して、めっき液中の錫濃度の増加を防止する場合にも、不溶性電極に係合部を設けて、不溶性電極を係止部材に係合させて支持している。   For this reason, in order to prevent the tin concentration in the plating solution from increasing by replacing the self-fluxing tin electrode with the insoluble electrode as described above, an engaging portion is provided on the insoluble electrode to lock the insoluble electrode. It is supported by engaging with a member.

特開2006−348354号公報JP 2006-348354 A

前述のように、自溶性錫電極および不溶性電極に係合部を設けて、棒状の係止部材に係合させて電極を支持する場合には、自溶性錫電極および不溶性電極と係止部材とを電気的に接続し、係止部材を介して自溶性錫電極および不溶性電極に電力を供給する必要がある。
不溶性電極は、使用時間が増加するにつれて、係止部材との接触部が徐々に摩耗してしまうため、係止部材との接触部が摩耗した状態で電力を供給すると、不溶性電極と係止部材との間で放電が発生してしまう。そのため、不溶性電極の交換や補修が必要となるが、不溶性電極は素材として、白金等を用いるため非常に高価であり、補修費用が高くなってしまうという問題があった。
As described above, when the self-fluxing tin electrode and the insoluble electrode are provided with an engaging portion and engaged with the rod-shaped locking member to support the electrode, the self-fluxing tin electrode, the insoluble electrode and the locking member Must be electrically connected to each other, and power must be supplied to the self-soluble tin electrode and the insoluble electrode via the locking member.
Since the insoluble electrode gradually wears away from the contact portion with the locking member as the usage time increases, when power is supplied in a state where the contact portion with the locking member is worn, the insoluble electrode and the locking member Discharge occurs between the two. Therefore, it is necessary to replace or repair the insoluble electrode. However, since the insoluble electrode is made of platinum or the like as a material, there is a problem that the repair cost becomes high.

本発明の目的は、上記従来技術の問題点を解消することにあり、自溶性電極を用いる電気めっき鋼板の製造装置において、めっき液中のイオン濃度を調整するために不溶性電極を配置してめっき処理を行う場合に、摩耗した不溶性電極の補修を容易にすると共に、摩耗した部分のみを補修できるようにして、補修費用を低減することができる電気めっき鋼板の製造装置を提供することにある。   An object of the present invention is to eliminate the above-described problems of the prior art, and in an electroplated steel sheet manufacturing apparatus using self-fluxing electrodes, plating is performed by disposing insoluble electrodes in order to adjust the ion concentration in the plating solution. An object of the present invention is to provide an apparatus for producing an electroplated steel sheet that facilitates repair of a worn insoluble electrode and enables repair of only the worn portion, thereby reducing the repair cost.

上記目的を達成するために、本発明は、パスラインに沿って配置されめっき液が満たされた複数のめっきセル内を連続的に走行する鋼板に電気めっきを行う電気めっき鋼板の製造装置において、少なくとも一部が前記めっきセル内のめっき液に浸漬され、鋼板に対面して配置されて、鋼板との間に通電して溶融されながら、走行する鋼板に連続的に電気めっきを行う少なくとも1つの自溶性電極と、少なくとも一部がめっきセル内のめっき液に浸漬され、鋼板に対面して配置されて、鋼板との間に通電して、走行する鋼板に連続的に電気めっきを行う少なくとも1つの不溶性電極と、自溶性電極および不溶性電極をそれぞれ垂下し、自溶性電極及び不溶性電極と電気的に接続される複数の係止部材とを備え、不溶性電極は、最大面が鋼板に対面する本体部と、係止部材に係止されると共に、電気的に接続される接触部とを有し、本体部と接触部とが、着脱可能に形成されることを特徴とする電気めっき鋼板の製造装置を提供する。   In order to achieve the above object, the present invention provides an apparatus for producing an electroplated steel sheet that performs electroplating on a steel sheet that runs continuously in a plurality of plating cells that are arranged along a pass line and filled with a plating solution. At least one part that is immersed in a plating solution in the plating cell, arranged facing the steel plate, and continuously electroplated on the running steel plate while being energized and melted between the steel plate. At least one of the self-fluxing electrode and at least a part of which is immersed in a plating solution in the plating cell, arranged facing the steel plate, energized between the steel plate and continuously electroplating the traveling steel plate. Two insoluble electrodes and a plurality of locking members that are respectively suspended from the self-soluble electrode and the insoluble electrode and electrically connected to the self-soluble electrode and the insoluble electrode. An electroplated steel sheet comprising: a main body portion that is engaged with the engaging member, and a contact portion that is electrically connected, wherein the main body portion and the contact portion are detachable. A manufacturing apparatus is provided.

ここで、自溶性電極は、鋼板の搬送方向と直交する幅方向に複数配置されることが好ましい。
また、不溶性電極は、鋼板の搬送方向と直交する幅方向に複数配置され、複数の不溶性電極の本体部の鋼板に対面する面は、鋼板に平行な同一面上に形成されることが好ましい。
また、係止部材は、鋼板の搬送方向と直交する幅方向に延在する棒状の部材であり、鋼板の表面に対して傾斜して配置されることが好ましい。
Here, it is preferable that a plurality of self-fluxing electrodes are arranged in the width direction orthogonal to the conveying direction of the steel sheet.
Moreover, it is preferable that a plurality of insoluble electrodes are arranged in the width direction orthogonal to the conveying direction of the steel plate, and the surfaces of the main body portions of the plurality of insoluble electrodes facing the steel plate are formed on the same plane parallel to the steel plate.
Moreover, a locking member is a rod-shaped member extended in the width direction orthogonal to the conveyance direction of a steel plate, and it is preferable to incline with respect to the surface of a steel plate.

また、不溶性電極は、少なくとも表面が白金からなることが好ましい。
また、不溶性電極は、本体部と接触部とを固定する固定部材を有し、固定部材の少なくとも表面は、本体部の表面と同じ材質からなることが好ましい。
Moreover, it is preferable that at least the surface of the insoluble electrode is made of platinum.
The insoluble electrode preferably has a fixing member that fixes the main body and the contact portion, and at least the surface of the fixing member is preferably made of the same material as the surface of the main body.

また、不溶性電極は、前記自溶性電極が配置されないめっきセルに配置されることが好ましい。
また、複数のめっきセル内のめっき液を循環させる循環手段を有することが好ましい。
The insoluble electrode is preferably disposed in a plating cell in which the self-fluxing electrode is not disposed.
Moreover, it is preferable to have a circulating means for circulating the plating solution in the plurality of plating cells.

本発明によれば、不溶性電極が、係止部材との接触部を着脱可能に形成されることにより、係止部材との接触部が摩耗した場合でも、摩耗した部分のみを交換することで補修することができるので、容易に補修できると共に、白金等の高価な材料が用いられている不溶性電極の補修費用を低減することができる。   According to the present invention, the insoluble electrode is formed so that the contact portion with the locking member is detachable, so that even when the contact portion with the locking member is worn, only the worn portion is repaired. Therefore, it can be easily repaired, and the repair cost of the insoluble electrode in which an expensive material such as platinum is used can be reduced.

本発明に係る電気めっき鋼板の製造装置の一例を概念的に示す図である。It is a figure which shows notionally an example of the manufacturing apparatus of the electroplated steel plate which concerns on this invention. 図1に示す電気めっき鋼板の製造装置の自溶性電極と鋼板とのめっきパスを示す概略断面図である。It is a schematic sectional drawing which shows the plating path | pass with the self-fluxing electrode and steel plate of the manufacturing apparatus of the electroplating steel plate shown in FIG. 図1に示す電気めっき鋼板の製造装置の不溶性電極と鋼板とのめっきパスを示す概略断面図である。It is a schematic sectional drawing which shows the plating path | pass with the insoluble electrode and steel plate of the manufacturing apparatus of the electroplated steel plate shown in FIG. 図3に示すめっきパスの側面図である。FIG. 4 is a side view of the plating pass shown in FIG. 3. (A)は、図4に示す不溶性電極をa方向から見た部分拡大図であり、(B)は、(A)のB−B線断面図である。(A) is the elements on larger scale which looked at the insoluble electrode shown in FIG. 4 from the a direction, (B) is the BB sectional drawing of (A).

以下に、本発明に係る電気めっき鋼板の製造装置を、添付の図面に示す好適実施形態を参照して詳細に説明する。   Below, the manufacturing apparatus of the electroplating steel plate which concerns on this invention is demonstrated in detail with reference to suitable embodiment shown to an accompanying drawing.

図1に、本発明の電気めっき鋼板の製造装置の一例を概念的に示す。
図1に示す電気めっき鋼板の製造装置は、電気錫めっきライン又はETL(Electrolytic Tinning Line)と呼ばれる電気錫めっき鋼板の製造ラインとしても用いられるもので、図示しない駆動源によって駆動される搬送ロール等(図示せず)によって搬送されて、走行する鋼板11に連続的に電気錫めっき等の電気めっきをするためのもので、電気めっきラインを構成するように連続的に配設された複数のめっきセルを有する。
以下の説明では、電気錫めっきの場合を具体的な代表例として説明するが、本発明はこれに限定されず、自溶性電極および不溶性電極を用いる電気めっきであれば、どのようなものにも適用可能である。例えば、錫めっきの他、亜鉛めっき、ニッケルめっき等を挙げることができる。
In FIG. 1, an example of the manufacturing apparatus of the electroplating steel plate of this invention is shown notionally.
The electroplated steel sheet manufacturing apparatus shown in FIG. 1 is also used as an electrotin-plated steel sheet or an electrotin-plated steel sheet manufacturing line called ETL (Electrolytic Tinning Line), such as a transport roll driven by a drive source (not shown). (Not shown) for carrying out electroplating such as electrotin plating on the traveling steel plate 11 continuously, and a plurality of platings continuously arranged so as to constitute an electroplating line Has a cell.
In the following description, the case of electrotin plating will be described as a specific representative example, but the present invention is not limited to this, and any electroplating using a self-fluxing electrode and an insoluble electrode can be used. Applicable. For example, in addition to tin plating, zinc plating, nickel plating, and the like can be given.

また、本発明が適用される電気めっき鋼板の製造装置10は、電気めっき工程を実施するめっきセクションであるが、そのライン速度や、めっき鋼板の板厚や板幅、陽極30に印加される電流等は、特に限定されるものではない。
また、各めっきセル12においては、陽極30を引き上げることにより、めっきパス34の形成自体を無くすこともできるが、鋼板11に対向して配置される陽極30への通電を選択的に停止することにより、めっきパス34の機能を選択的に無くし、鋼板11表面へのめっきを選択的に停止することができるように構成されている。
The electroplated steel sheet manufacturing apparatus 10 to which the present invention is applied is a plating section for performing an electroplating process. The line speed, the plate thickness and width of the plated steel sheet, and the current applied to the anode 30 Etc. are not particularly limited.
Further, in each plating cell 12, the formation of the plating path 34 can be eliminated by pulling up the anode 30, but the energization to the anode 30 disposed facing the steel plate 11 is selectively stopped. Thus, the function of the plating path 34 is selectively eliminated, and the plating on the surface of the steel plate 11 can be selectively stopped.

電気めっき鋼板の製造装置10は、鋼板の搬送方向の最上流側のめっきセル12bと、めっきセル12bの下流側の複数のめっきセル12aと、めっきセル12(12a、12b)内のめっき液22を循環させるための循環タンク14と、めっき液22を循環タンク14からめっきセル12(12a、12b)に送液するためのポンプ16とを有する。   The electroplated steel plate manufacturing apparatus 10 includes a plating cell 12b on the most upstream side in the conveying direction of the steel plate, a plurality of plating cells 12a on the downstream side of the plating cell 12b, and a plating solution 22 in the plating cells 12 (12a, 12b). And a pump 16 for feeding the plating solution 22 from the circulation tank 14 to the plating cell 12 (12a, 12b).

各めっきセル12aは、内部にめっき液22が満たされためっきタンク20と、めっき液22に浸漬され、鋼板11を搬送する浸漬ロール24と、めっきタンク20の側壁部20aの上部に各々配設され、鋼板11を搬送する搬送ロール26と、鋼板11に電気的に接触して通電する通電ロール28と、下部がめっき液22内に浸漬され、鋼板11に対面して配置される陽極(アノード)30と、各めっきセル12a内の各陽極30と各通電ロール28との間に電力を供給する直流電源(図示せず)と、を有する。   Each of the plating cells 12a is disposed on a plating tank 20 filled with a plating solution 22, an immersion roll 24 that is immersed in the plating solution 22 and transports the steel plate 11, and an upper portion of the side wall portion 20a of the plating tank 20. A transport roll 26 that transports the steel plate 11, an energizing roll 28 that is in electrical contact with the steel plate 11 and energized, and an anode (anode) whose lower part is immersed in the plating solution 22 and that faces the steel plate 11. ) 30 and a DC power source (not shown) for supplying power between each anode 30 and each energizing roll 28 in each plating cell 12a.

めっきタンク20は、内部に錫めっき液等のめっき液22を貯留するものであり、めっき液22が満たされた内部には、浸漬ロール24と、複数の自溶性電極40からなる陽極(アノード)30とが配置される。
浸漬ロール24は、めっきタンク20内のめっき液22に浸漬され、鉛直上方からめっき液22内に侵入し下方に走行する鋼板11を巻き掛けて鉛直上方に搬送する搬送ロールである。
The plating tank 20 stores therein a plating solution 22 such as a tin plating solution, and an anode (anode) composed of a dipping roll 24 and a plurality of self-fluxing electrodes 40 inside the plating solution 22. 30 are arranged.
The immersion roll 24 is a transport roll that is immersed in the plating solution 22 in the plating tank 20, winds the steel plate 11 that enters the plating solution 22 from above and travels downward, and conveys it vertically upward.

搬送ロール26は、隣接する2つのめっきタンク20の側壁部20aの上部に各々配設され、鋼板11を巻き掛けて、上流側のめっきタンク20内の浸漬ロール24から下流側のめっきタンク20内の浸漬ロール24に搬送する搬送ロールである。
通電ロール28は、各搬送ロール26に巻き掛けられて搬送される鋼板11に電気的に接触して通電し、鋼板11を陰極として機能させるためのロールである。
The transport rolls 26 are respectively arranged on the upper portions of the side wall portions 20a of the two adjacent plating tanks 20, wound around the steel plate 11, and from the immersion roll 24 in the upstream plating tank 20, into the downstream plating tank 20. It is a conveyance roll conveyed to the immersion roll 24.
The energizing roll 28 is a roll for electrically contacting and energizing the steel sheet 11 that is wound around and conveyed by each of the conveying rolls 26 so that the steel sheet 11 functions as a cathode.

陽極30は、めっきタンク20内のめっき液22に浸漬され、上流側の搬送ロール26と浸漬ロール24とで搬送されている鋼板11、および、浸漬ロール24と下流側の搬送ロール26とで搬送されている鋼板11の各表裏面にそれぞれ対向して所定間隔離間して配置され、陰極となる鋼板11との間で通電して、めっきパス34を形成するものである。   The anode 30 is immersed in the plating solution 22 in the plating tank 20, and is transported by the steel plate 11 transported by the upstream transport roll 26 and the immersion roll 24, and by the immersion roll 24 and the downstream transport roll 26. The steel plates 11 are arranged to face the front and back surfaces of the steel plates 11 so as to be spaced apart from each other by a predetermined distance, and are energized between the steel plates 11 serving as cathodes to form plating paths 34.

ここで、図示例の各めっきセル12aにおいては、めっきタンク20内のめっき液22中を搬送される鋼板11の表裏面にそれぞれ対向して陽極30が配置されており、鋼板11の一方の面と陽極30によって錫めっき等の電気めっきのための1つのめっきパス34が形成される。即ち、図示例の各めっきセル12において形成されるめっきパス34は、上流側の搬送ロール26と浸漬ロール24とで搬送されている鋼板11の表裏面と各面に対向する陽極30によって形成される2つのダウンパスと、浸漬ロール24と下流側の搬送ロール26とで搬送されている鋼板11の表裏面と各面に対向する陽極30によって形成される2つのアップパスとで構成される。   Here, in each plating cell 12a in the illustrated example, the anode 30 is disposed to face the front and back surfaces of the steel plate 11 conveyed in the plating solution 22 in the plating tank 20, and one surface of the steel plate 11 is disposed. The anode 30 forms one plating path 34 for electroplating such as tin plating. That is, the plating path 34 formed in each plating cell 12 in the illustrated example is formed by the front and back surfaces of the steel plate 11 conveyed by the upstream conveying roll 26 and the immersion roll 24 and the anode 30 facing each surface. And two up paths formed by the front and back surfaces of the steel plate 11 conveyed by the immersion roll 24 and the downstream conveyance roll 26 and the anode 30 facing each surface.

図2に、めっきセル12a内の陽極30(アノード)と鋼板11とのめっきパス34を示す。
めっきパス34は、鋼板11と、鋼板11の両面に配置される陽極30からなり、図面での鋼板11の下面側に配置される陽極30aから形成されるめっきパス34aと、鋼板11の上面側に配置される陽極30bからなるめっきパス34bからなる。なお、めっきパス34aとめっきパス34bとは、同様の構成を有するものであるので、めっきパス34aを代表例として説明する。
FIG. 2 shows a plating path 34 between the anode 30 (anode) and the steel plate 11 in the plating cell 12a.
The plating pass 34 includes a steel plate 11 and anodes 30 disposed on both surfaces of the steel plate 11. The plating pass 34 a formed from the anode 30 a disposed on the lower surface side of the steel plate 11 in the drawing, and the upper surface side of the steel plate 11. The plating path 34b is composed of the anode 30b disposed on the surface. Since the plating pass 34a and the plating pass 34b have the same configuration, the plating pass 34a will be described as a representative example.

図2に示すように、めっきパス34aの陽極30aは、鋼板11の下面側に配置され、それぞれ、鋼板11の、走行方向と直交する幅方向に配列された複数、例えば、図示例では6本の自溶性電極40(40a〜40f)と、自溶性電極40を係止する係止部材(フィーダーバー)38とを有する。   As shown in FIG. 2, the anodes 30a of the plating path 34a are arranged on the lower surface side of the steel plate 11, and each of the anodes 30a is arranged in the width direction perpendicular to the traveling direction of the steel plate 11, for example, six in the illustrated example. Self-fluxing electrode 40 (40a to 40f) and a locking member (feeder bar) 38 for locking the self-fluxing electrode 40.

自溶性電極40は、錫等のめっき金属で形成される棒状の部材であり、上部にフック(鉤状部)を有し、係止部材38にフックを引っ掛けることにより、一部がめっき液22内に浸漬され垂下された状態で係止部材38に支持される。
また、自溶性電極40は、係止部材38と電気的に接続されて、係止部材38を介して直流電源(図示せず)から電力を供給される。これにより、めっき液22中を搬送される鋼板11に通電し、自身から錫等のめっき金属(錫イオン等のめっき金属イオン)を溶出させ、それをめっき液22に接触している鋼板11の表裏面に電析させて、めっき処理をおこなう。
The self-fluxing electrode 40 is a rod-shaped member formed of a plating metal such as tin. The self-fluxing electrode 40 has a hook (a hook-shaped portion) on the upper part, and a part of the plating solution 22 is obtained by hooking the hook on the locking member 38. It is supported by the locking member 38 in a state where it is dipped in and suspended.
The self-fluxing electrode 40 is electrically connected to the locking member 38 and is supplied with electric power from a DC power source (not shown) via the locking member 38. Thereby, it supplies with electricity to the steel plate 11 conveyed in the plating solution 22, elutes the plating metal such as tin (plating metal ion such as tin ion) from itself, and the steel plate 11 in contact with the plating solution 22 Electrodeposition is performed on the front and back surfaces and plating is performed.

係止部材38は、自溶性電極40を係止するための棒状の部材であり、めっきタンク20の上方に、鋼板11の幅方向を長手方向として、鋼板11の表面に対して所定の傾斜角度で傾斜して配置されている。また、係止部材38は、長手方向に垂直な断面が略矩形状であり、鉛直方向の上面は鋼板11から離間する方向において下方に傾斜している(図4参照)。
また、係止部材38には、直流電源(図示せず)が接続され直流電源から電力が供給される。
The locking member 38 is a rod-shaped member for locking the self-fluxing electrode 40, and has a predetermined inclination angle with respect to the surface of the steel plate 11, with the width direction of the steel plate 11 as the longitudinal direction above the plating tank 20. It is arranged at an angle. The locking member 38 has a substantially rectangular cross section perpendicular to the longitudinal direction, and the upper surface in the vertical direction is inclined downward in a direction away from the steel plate 11 (see FIG. 4).
Further, a direct current power source (not shown) is connected to the locking member 38 and power is supplied from the direct current power source.

前述のとおり、自溶性電極40を用いて電気めっきを行う場合には、時間の経過とともに自溶性電極40が消費されるので、自溶性電極40の交換や補充を行う必要があるが、自溶性電極40の交換や補充のために鋼板11の走行を停止すると生産性が低下してしまう。
これに対して、自溶性電極40を幅方向で複数に分割して、各電極にフック(鉤状部)を形成し、棒状の係止部材38に係止させて自溶性電極40を支持する構成とすることで、鋼板11の走行中であっても自溶性電極40の両端部において、自溶性電極40の一部分の取り付け取り外しができるので、鋼板11の走行を停止せずに交換や補充をすることができる。
As described above, when electroplating is performed using the self-fluxing electrode 40, the self-fluxing electrode 40 is consumed over time, and thus it is necessary to replace or replenish the self-fluxing electrode 40. If the travel of the steel plate 11 is stopped for the replacement or replenishment of the electrode 40, the productivity is lowered.
On the other hand, the self-fluxing electrode 40 is divided into a plurality of parts in the width direction, hooks are formed on the respective electrodes, and the self-fluxing electrode 40 is supported by being latched by a rod-shaped latching member 38. By adopting the structure, even when the steel plate 11 is traveling, a part of the self-fluxing electrode 40 can be attached and detached at both ends of the self-soluble electrode 40. Therefore, replacement and replenishment can be performed without stopping the traveling of the steel plate 11. can do.

具体的に、自溶性電極40の交換、補充について、図2中の下側のめっきパス34aを用いて説明する。
めっきパス34aの陽極30aの自溶性電極40(40a〜40f)のうち、図中左端の自溶性電極40aが抜き取るべき予め設定された厚さとなると、左端の自溶性電極40aは抜き取られ、その右側にあった残りの自溶性電極40b〜40fがそれぞれ電極幅分だけ左側に移動される。右端の空いた領域には新しい自溶性電極40が取り付けられ、6つの自溶性電極40により、新たに陽極30aが形成される。
このように、陽極30aを複数の自溶性電極40で形成し、一方の端側から薄くなった自溶性電極40を抜き取り、残った自溶性電極40を順次移動させて、新しい自溶性電極40を他端側に取り付けて、自溶性電極40の交換、補充を行うので、鋼板11の走行を停止させる必要がなく、生産性が低下することを防止できる。
Specifically, replacement and replenishment of the self-fluxing electrode 40 will be described using the lower plating pass 34a in FIG.
Among the self-fluxing electrodes 40 (40a to 40f) of the anode 30a of the plating pass 34a, when the self-fluxing electrode 40a at the left end in the figure has a preset thickness to be extracted, the left-most self-dissolving electrode 40a is extracted and the right side thereof The remaining self-dissolving electrodes 40b to 40f are moved to the left by the electrode width. A new self-fluxing electrode 40 is attached to the vacant region at the right end, and an anode 30 a is newly formed by the six self-fluxing electrodes 40.
In this way, the anode 30a is formed with a plurality of self-fluxing electrodes 40, the thin self-fluxing electrode 40 is extracted from one end side, and the remaining self-fluxing electrodes 40 are sequentially moved to obtain a new self-fluxing electrode 40. Since it replaces and replenishes the self-fluxing electrode 40 by attaching to the other end side, it is not necessary to stop the travel of the steel plate 11, and it is possible to prevent the productivity from decreasing.

めっきセル12bは、複数のめっきセル12aの上流側に配置されている。
なお、めっきセル12bは、自溶性電極40に代えて不溶性電極42が配置される以外は、めっきセル12aと同じ構成を有するので、同じ部材には同じ符号を付し、以下の説明は異なる部分を主に行う。
The plating cell 12b is disposed on the upstream side of the plurality of plating cells 12a.
The plating cell 12b has the same configuration as the plating cell 12a except that an insoluble electrode 42 is disposed instead of the self-fluxing electrode 40. Therefore, the same reference numerals are given to the same members, and the following description is different. Mainly.

めっきセル12bは、内部にめっき液22が満たされためっきタンク20と、めっき液22に浸漬され、鋼板11を搬送する浸漬ロール24と、めっきタンク20の側壁部20aの上部に各々配置され、鋼板11を搬送する搬送ロール26と、鋼板11に電気的に接触して通電する通電ロールと、下部がめっき液22に浸漬され、鋼板11に対面して配置される陽極(アノード)32と、めっきセル12b内の陽極32と通電ロール28との間に電力を供給する直流電源(図示せず)と、を有する。   The plating cell 12b is respectively disposed on the plating tank 20 filled with the plating solution 22, the immersion roll 24 that is immersed in the plating solution 22 and transports the steel plate 11, and the upper portion of the side wall portion 20a of the plating tank 20. A transport roll 26 that transports the steel plate 11, an energizing roll that is in electrical contact with the steel plate 11, and an anode (anode) 32 that is immersed in the plating solution 22 and faces the steel plate 11. A direct current power source (not shown) for supplying electric power between the anode 32 and the energizing roll 28 in the plating cell 12b.

陽極32は、めっきタンク20内のめっき液22に浸漬され、浸漬ロール24と下流側の搬送ロール26とで搬送される鋼板11の裏面に対面して所定間隔離間して配置され、陰極となる鋼板11との間で通電してめっきパス36を形成するものである。   The anode 32 is immersed in the plating solution 22 in the plating tank 20 and is arranged at a predetermined distance from the back surface of the steel plate 11 conveyed by the immersion roll 24 and the downstream conveyance roll 26 to become a cathode. The plating path 36 is formed by energizing the steel plate 11.

図3に、めっきセル12b内の陽極32と鋼板11とのめっきパス36を示す。なお、図3においては、図中上側を鋼板11の裏面として図示している。
めっきパス36は、鋼板11と鋼板11の裏面に配置される陽極32とから形成される。
図3に示すように、めっきパス36の陽極32は、鋼板11の裏面側に配置され、鋼板11の幅方向に配列された複数の、図示例では6本の不溶性電極42(42a〜42f)と、不溶性電極42を係止する係止部材(フィーダーバー)38とを有する。
FIG. 3 shows a plating path 36 between the anode 32 and the steel plate 11 in the plating cell 12b. In FIG. 3, the upper side in the drawing is illustrated as the back surface of the steel plate 11.
The plating path 36 is formed from the steel plate 11 and the anode 32 disposed on the back surface of the steel plate 11.
As shown in FIG. 3, the anode 32 of the plating path 36 is arranged on the back surface side of the steel plate 11 and has a plurality of, in the illustrated example, six insoluble electrodes 42 (42 a to 42 f) arranged in the width direction of the steel plate 11. And a locking member (feeder bar) 38 for locking the insoluble electrode 42.

図4に、めっきパス36の側面図を示し、図5(A)に、図4の不溶性電極42をa方向から見た部分拡大図を示し、図5(B)に、(A)のB−B線断面図を示す。
不溶性電極42は、棒状の部材であり、鋼板11と対面する最大面を有する本体部44、係止部材38に係止する接触部46、ならびに、本体部44と接触部46とを固定する固定部材であるボルト48、ナット50およびワッシャ52を有する。
4 shows a side view of the plating path 36, FIG. 5A shows a partially enlarged view of the insoluble electrode 42 of FIG. 4 viewed from the direction a, and FIG. -B line sectional drawing is shown.
The insoluble electrode 42 is a rod-shaped member, and has a main body portion 44 having a maximum surface facing the steel plate 11, a contact portion 46 that is locked to the locking member 38, and a fixing that fixes the main body portion 44 and the contact portion 46. It has a bolt 48, a nut 50, and a washer 52, which are members.

本体部44は、母材がチタンで表面が白金でめっきされた棒状の部材で、最大面を鋼板11の裏面に対面させて、長手方向を鉛直方向に一致させて配置される。
図5(A)および(B)に示すように、本体部44の鋼板11と対面する面の反対側の面には、接触部46が固定される。接触部46が固定される位置には、接触部46を固定するためのボルト48が貫通する貫通孔44aが形成されている。また、本体部44の長手方向上端部側には、不溶性電極42を係止部材38に係合させる際に不溶性電極42をハンドリングする治具と係合する貫通孔44bが形成されている。
The main body 44 is a rod-like member whose base material is titanium and whose surface is plated with platinum. The main body portion 44 is arranged with the maximum surface facing the back surface of the steel plate 11 and the longitudinal direction being aligned with the vertical direction.
As shown in FIGS. 5A and 5B, the contact portion 46 is fixed to the surface of the main body 44 opposite to the surface facing the steel plate 11. A through hole 44a through which a bolt 48 for fixing the contact portion 46 passes is formed at a position where the contact portion 46 is fixed. Further, a through-hole 44b that engages with a jig for handling the insoluble electrode 42 when the insoluble electrode 42 is engaged with the locking member 38 is formed on the upper end of the main body 44 in the longitudinal direction.

また、図3に示すように、本体部44は、幅方向の配置位置に応じて、異なる厚さに形成されている。すなわち、図に示すように、係止部材38は、鋼板11に対して傾斜して設置されるので、不溶性電極42a〜42fの鋼板11と対面する面が、鋼板11に平行で、かつ、同一面上に配置されるように、鋼板11に近い位置に配置される不溶性電極42aの本体部44は、薄く形成され、鋼板11から遠い位置に配置される不溶性電極42fの本体部44は、厚く形成され、これらの間に配置される不溶性電極42b〜42eは、鋼板11から遠い位置に配置されるものほど、本体部44が厚く形成されている。   Moreover, as shown in FIG. 3, the main-body part 44 is formed in different thickness according to the arrangement position of the width direction. That is, as shown in the figure, since the locking member 38 is installed to be inclined with respect to the steel plate 11, the surfaces of the insoluble electrodes 42a to 42f facing the steel plate 11 are parallel to the steel plate 11 and the same. The main body portion 44 of the insoluble electrode 42a disposed at a position close to the steel plate 11 is formed so as to be thin on the surface, and the main body portion 44 of the insoluble electrode 42f disposed at a position far from the steel plate 11 is thick. The insoluble electrodes 42b to 42e that are formed and arranged between them are formed so that the main body 44 is thicker as the insoluble electrodes 42b to 42e are arranged farther from the steel plate 11.

接触部46は、母材がチタンで表面が白金でめっきされた板状の部材で、本体部44の鋼板11と対面する面とは反対側の面に固定される。また、本体部44と接する面には、接触部46を本体部44に固定するためのボルト48が貫通する貫通孔46aが形成されている。
また、接触部46の鉛直方向下側の面は、鋼板11から離間する方向において下方に傾斜しており、本体部44と共に鉤状部(フック)を形成し、この鉤状部が係止部材38に係合されて、不溶性電極42が垂下され支持されると共に、係止部材38と電気的に接続される。
The contact portion 46 is a plate-like member whose base material is titanium and whose surface is plated with platinum, and is fixed to the surface of the main body portion 44 opposite to the surface facing the steel plate 11. Further, a through hole 46 a through which a bolt 48 for fixing the contact portion 46 to the main body portion 44 passes is formed on the surface in contact with the main body portion 44.
Further, the surface on the lower side in the vertical direction of the contact portion 46 is inclined downward in a direction away from the steel plate 11, and forms a hook-like portion (hook) together with the main body portion 44, and this hook-like portion is a locking member. The insoluble electrode 42 is suspended and supported, and is electrically connected to the locking member 38.

本体部44と接触部46とを固定する固定部材であるボルト48、ナット50およびワッシャ52は、チタンからなる母材に表面が白金でめっきされて形成されている。
このように、本体部44と接触部46とを固定する固定部材の表面を本体部44の表面の材質と同じにすることにより、不溶性電極42の電気的な特性を、本体部と接触部とが一体的に形成された不溶性電極と同等にすることができる。
The bolt 48, the nut 50, and the washer 52, which are fixing members that fix the main body 44 and the contact portion 46, are formed by plating a surface of a base material made of titanium with platinum.
Thus, by making the surface of the fixing member that fixes the main body portion 44 and the contact portion 46 the same as the material of the surface of the main body portion 44, the electrical characteristics of the insoluble electrode 42 are changed between the main body portion and the contact portion. Can be equivalent to an insoluble electrode formed integrally.

係止部材38に係合された不溶性電極42は、係止部材38と電気的に接続されて、係止部材38を介して直流電源(図示せず)から電力を供給される。これにより、めっき液22中を搬送される鋼帯11に通電し、めっき液22中の錫イオンをめっき液22に接触している鋼板11の裏面に電析させてめっき処理を行う。
前述のとおり、自溶性電極40を用いるめっき鋼板の製造ラインにおいては、稼働時間が増加するにつれてめっき液22中の錫(めっき金属)濃度が増加するため、ライン中に不溶性電極42を設置して、不溶性電極42を陽極32としてめっき処理を行い、めっき液22中の錫イオンを消費することにより、めっき液22中の錫濃度の増加を防止する。
The insoluble electrode 42 engaged with the locking member 38 is electrically connected to the locking member 38 and supplied with electric power from a DC power source (not shown) via the locking member 38. Thereby, the steel strip 11 conveyed in the plating solution 22 is energized, and tin ions in the plating solution 22 are electrodeposited on the back surface of the steel plate 11 in contact with the plating solution 22 to perform the plating process.
As described above, in the plated steel sheet production line using the self-fluxing electrode 40, the concentration of tin (plating metal) in the plating solution 22 increases as the operating time increases, so the insoluble electrode 42 is installed in the line. The insoluble electrode 42 is used as the anode 32 to perform plating, and the tin ions in the plating solution 22 are consumed, thereby preventing the tin concentration in the plating solution 22 from increasing.

ここで、前述のとおり、不溶性電極に鉤状部を設けて棒状の係止部材38に係合させて、不溶性電極を支持する場合に、不溶性電極は、使用時間が増加するにつれて、係止部材38との接触部位、図示例においては、係止部材38の上面と接触する接触部の下面が徐々に摩耗してしまうため、係止部材38との接触部位が摩耗した状態で電力を供給すると、不溶性電極と係止部材38との間で放電が発生してしまう。そのため、不溶性電極の交換や補修が必要となるが、不溶性電極は素材として、白金等を用いるため非常に高価であり、不溶性電極の全体を交換すると、補修費用が高くなってしまうという問題があった。   Here, as described above, when the insoluble electrode is provided with a hook-like portion and engaged with the rod-shaped locking member 38 to support the insoluble electrode, the insoluble electrode has a locking member as the usage time increases. 38, in the illustrated example, the lower surface of the contact portion that contacts the upper surface of the locking member 38 gradually wears, so when power is supplied while the contact portion with the locking member 38 is worn. A discharge occurs between the insoluble electrode and the locking member 38. Therefore, it is necessary to replace or repair the insoluble electrode. However, the insoluble electrode is very expensive because platinum or the like is used as a material. If the entire insoluble electrode is replaced, the repair cost becomes high. It was.

これに対して、本発明は、不溶性電極42を、鋼板11に対面する本体部44と、係止部材38に係合され電気的に接続される接触部46とにより形成し、本体部44と接触部46とを着脱可能に固定することにより、係止部材38との接触部位が摩耗した場合にも、係止部材38と接触し摩耗した接触部46のみを交換することができるので、不溶性電極42を容易に補修できると共に、白金等の高価な材料が用いられている不溶性電極42の補修費用を低減することができる。
なお、不溶性電極42と係止部材38とを係止した際に、係止部材38の上面と接触する領域は、不溶性電極42の自重がかかり圧力が高くなるので、接触による摩耗が大きくなる。したがって、少なくとも係止部材38の上面と接触する領域は、接触部46とするのが好ましい。
On the other hand, in the present invention, the insoluble electrode 42 is formed by the main body portion 44 facing the steel plate 11 and the contact portion 46 that is engaged with and electrically connected to the locking member 38. By fixing the contact portion 46 so as to be detachable, even when the contact portion with the locking member 38 is worn, it is possible to replace only the contact portion 46 that has come into contact with the locking member 38 and is insoluble. The electrode 42 can be easily repaired, and the repair cost of the insoluble electrode 42 in which an expensive material such as platinum is used can be reduced.
In addition, when the insoluble electrode 42 and the locking member 38 are locked, the area in contact with the upper surface of the locking member 38 is subjected to the weight of the insoluble electrode 42 and the pressure is increased, so that wear due to contact increases. Therefore, it is preferable that at least a region in contact with the upper surface of the locking member 38 is the contact portion 46.

ここで、図示例においては、不溶性電極42からなる陽極32は、最上流側のめっきセル12bに1つ配置したが、本発明はこれに限定はされず、2以上の陽極32を配置してもよい。
また、不溶性電極42からなる陽極32が配置されるめっきセル12bを1つ有する構成としたが、これに限定はされず、不溶性電極42からなる陽極32が配置されるめっきセル12bを2以上有してもよい。
Here, in the illustrated example, one anode 32 made of the insoluble electrode 42 is disposed in the plating cell 12b on the most upstream side, but the present invention is not limited to this, and two or more anodes 32 are disposed. Also good.
Further, the configuration includes one plating cell 12b in which the anode 32 made of the insoluble electrode 42 is disposed. However, the present invention is not limited to this, and there are two or more plating cells 12b in which the anode 32 made of the insoluble electrode 42 is disposed. May be.

また、めっきセル12bは、自溶性電極40からなる陽極30が配置される複数のめっきセル12aの上流側に配置したが、これに限定はされず、めっきセル12aの間に配置されてもよいし、めっきセル12aの下流側に配置されてもよい。
また、図示例においては、不溶性電極42からなる陽極32は、自溶性電極40からなる陽極30が配置されるめっきセル12aとは異なるめっきセル12bに配置する構成としたが、これに限定はされず、不溶性電極42からなる陽極32と、自溶性電極40からなる陽極30とを同じめっきセルに配置してもよい。
さらに、図示例においては、1つの陽極において、幅方向での電極は、すべて、不溶性電極42か自溶性電極40のどちらかとなっているが、1つの陽極に不溶性電極42と自溶性電極40が混在していてもよい。ただし、自溶性電極の交換のしやすさや、電析状態の差異などを考慮すると、別々の陽極とすることが好ましい。
また、不溶性電極42を配置する数の設定は、自溶性電極からのめっき成分の溶解量と電析量とのバランス等を考慮して適宜決定すればよい。
Moreover, although the plating cell 12b was arrange | positioned in the upstream of the some plating cell 12a by which the anode 30 which consists of the self-fluxing electrode 40 is arrange | positioned, it is not limited to this, You may arrange | position between the plating cells 12a. However, it may be arranged downstream of the plating cell 12a.
In the illustrated example, the anode 32 made of the insoluble electrode 42 is arranged in a plating cell 12b different from the plating cell 12a in which the anode 30 made of the self-fluxing electrode 40 is arranged, but this is not limitative. Instead, the anode 32 made of the insoluble electrode 42 and the anode 30 made of the self-soluble electrode 40 may be disposed in the same plating cell.
Further, in the illustrated example, the electrodes in the width direction in one anode are all either the insoluble electrode 42 or the self-soluble electrode 40, but the insoluble electrode 42 and the self-soluble electrode 40 are provided in one anode. It may be mixed. However, considering the ease of replacement of the self-fluxing electrode and the difference in the electrodeposition state, it is preferable to use separate anodes.
In addition, the number of the insoluble electrodes 42 to be arranged may be appropriately determined in consideration of the balance between the amount of plating component dissolved from the self-soluble electrode and the amount of electrodeposition.

また、図示例においては、不溶性電極42からなる陽極32は、鋼板11の裏面側のアップパスに配置したが、これに限定はされず、鋼板11の表面側に配置してもよく、また、ダウンパスに配置してもよい。
また、図3において、不溶性電極42として、幅方向に分割され、幅方向の配値位置に応じて異なる厚さの複数の電極(42a〜42f)からなる例を示したが、これは、不溶性電極42の設置位置を流動的に選択可能とし、自溶性電極40の取り付け治具(係止部材38)をそのまま転用するために好ましい形態である。ただし、不溶性電極42の位置を固定とする場合には、自溶性電極40の取り付け治具を転用する必要はなく、不溶性電極42用の取り付け治具(係止部材)を設置すればよいので、幅方向の配値位置に応じて厚さを変える必要はなく、不溶性電極42の鋼板11と対面する面が、鋼板11に平行で、かつ、同一面上に配置されるようになっていればよい。また、図3では、幅方向で6分割としているが、分割数は特に限定はされず、また、分割しなくてもよい。
Further, in the illustrated example, the anode 32 made of the insoluble electrode 42 is disposed in the up path on the back surface side of the steel plate 11, but is not limited thereto, and may be disposed on the front surface side of the steel plate 11, It may be arranged in the down path.
Moreover, in FIG. 3, although the example which consists of several electrodes (42a-42f) divided | segmented into the width direction as the insoluble electrode 42, and having different thickness according to the arrangement position of the width direction was shown, this is insoluble. This is a preferred mode for enabling the installation position of the electrode 42 to be fluidly selected and diverting the mounting jig (locking member 38) for the self-soluble electrode 40 as it is. However, when fixing the position of the insoluble electrode 42, it is not necessary to divert the mounting jig for the self-soluble electrode 40, and it is only necessary to install a mounting jig (locking member) for the insoluble electrode 42. It is not necessary to change the thickness according to the arrangement position in the width direction, and the surface of the insoluble electrode 42 that faces the steel plate 11 is parallel to the steel plate 11 and arranged on the same surface. Good. In FIG. 3, the number of divisions is six in the width direction, but the number of divisions is not particularly limited and may not be divided.

また、本実施例においては、不溶性電極42の本体部44および接触部46は、チタンを母材として、表面に白金をめっきして形成されたが、これに限定はされず、全体を白金としてもよい。
また、表面の材質を白金としたが、これに限定はされず、不溶性電極として用いられる各種の金属が適用可能であり、例えば、イリジウム等の金属を用いてもよい。また、母材の材質をチタンとしたが、これに限定はされず、例えば、ステンレス鋼(SUS)等の金属を用いてもよい。
In this embodiment, the main body portion 44 and the contact portion 46 of the insoluble electrode 42 are formed by plating platinum on the surface using titanium as a base material. However, the present invention is not limited to this, and the whole is made of platinum. Also good.
In addition, although the surface material is platinum, the present invention is not limited thereto, and various metals used as insoluble electrodes can be applied. For example, a metal such as iridium may be used. Moreover, although the material of the base material is titanium, the material is not limited to this. For example, a metal such as stainless steel (SUS) may be used.

循環タンク14は、全てのめっきセル12(12a、12b)に接続され、図1中に矢印で示すように、各めっきセル12からめっき液22が流入すると共に、ポンプ16を介して各めっきセル12にめっき液22を供給し、各セルの上部よりオーバーフローしためっき液を循環タンク14に戻す(図示せず)ことにより、めっき液22を循環させる。
また、循環タンク14内では、各めっきセル12から流入しためっき液22は撹拌されてもよい。また、めっき液22内の薬液の濃度調整を行ってもよい。
めっきセル12のめっき液22を循環させることにより、不溶性電極42を有するめっきセル12bによって、めっき液22内の錫イオン(めっき金属イオン)が消費されるので、自溶性電極40を有するめっきセル12a内のめっき液22内の錫イオンの濃度が増加するのを防止することができる。
The circulation tank 14 is connected to all the plating cells 12 (12 a, 12 b), and as shown by arrows in FIG. 1, the plating solution 22 flows from each plating cell 12, and each plating cell is connected via a pump 16. The plating solution 22 is supplied to 12 and the plating solution overflowed from the upper part of each cell is returned to the circulation tank 14 (not shown), whereby the plating solution 22 is circulated.
Further, in the circulation tank 14, the plating solution 22 flowing from each plating cell 12 may be agitated. Further, the concentration of the chemical solution in the plating solution 22 may be adjusted.
By circulating the plating solution 22 in the plating cell 12, tin ions (plating metal ions) in the plating solution 22 are consumed by the plating cell 12 b having the insoluble electrode 42. Therefore, the plating cell 12 a having the self-fluxing electrode 40. It is possible to prevent the concentration of tin ions in the plating solution 22 from increasing.

なお、循環タンク14と各めっきセル12との間のめっき液22の流量は特に限定はなく、各めっきセル12内のめっき液22の錫濃度や薬剤の濃度が所定の範囲に維持されればよい。   The flow rate of the plating solution 22 between the circulation tank 14 and each plating cell 12 is not particularly limited, as long as the tin concentration and the chemical concentration of the plating solution 22 in each plating cell 12 are maintained within a predetermined range. Good.

また、上記実施例においては、循環タンク14およびポンプ16により、全てのめっきセル12(12a、12b)のめっき液22を循環させる構成としたが、本発明はこれに限定はされず、1つのめっきセルに自溶性電極40からなる陽極30と不溶性電極42からなる陽極32とを配置して、1つのめっきセル内において、めっき液22内のめっき金属イオンの濃度が増加することを防止する構成としてもよい。   Moreover, in the said Example, although it was set as the structure which circulates the plating solution 22 of all the plating cells 12 (12a, 12b) with the circulation tank 14 and the pump 16, this invention is not limited to this, One A configuration in which the anode 30 composed of the self-soluble electrode 40 and the anode 32 composed of the insoluble electrode 42 are arranged in the plating cell to prevent the concentration of the plating metal ions in the plating solution 22 from increasing in one plating cell. It is good.

以上、本発明に係る電気めっき鋼板の製造装置について具体的に錫めっきでの実施形態及び実施例を挙げて詳細に説明したが、本発明は以上の実施形態や実施例に限定されるものではなく、本発明の要旨を逸脱しない範囲において、各種の改良や変更を行ってもよいのはもちろんである。   As mentioned above, although the manufacturing apparatus of the electroplating steel plate which concerns on this invention was described in detail, giving the embodiment and the example by tin plating specifically, this invention is not limited to the above embodiment and an Example. Of course, various improvements and modifications may be made without departing from the scope of the present invention.

10 電気めっき鋼板の製造装置
11 鋼板
12a、12b めっきセル
14 循環タンク
16 ポンプ
20 めっきタンク
22 めっき液
24 浸漬ロール
26 搬送ロール
28 通電ロール
30a、30b、32 陽極(アノード)
34a、34b、36 めっきパス
38 係止部材(フィーダーバー)
40、40a、40b、40c、40d、40e、40f 自溶性電極
42、42a、42b、42c、42d、42e、42f 不溶性電極
44 本体部
44a、44b、46a 貫通孔
46 接触部
48 ボルト
50 ナット
52 ワッシャ
DESCRIPTION OF SYMBOLS 10 Electroplating steel plate manufacturing apparatus 11 Steel plate 12a, 12b Plating cell 14 Circulation tank 16 Pump 20 Plating tank 22 Plating solution 24 Immersion roll 26 Transport roll 28 Current supply roll 30a, 30b, 32 Anode (anode)
34a, 34b, 36 Plating pass 38 Locking member (feeder bar)
40, 40a, 40b, 40c, 40d, 40e, 40f Self-dissolving electrode 42, 42a, 42b, 42c, 42d, 42e, 42f Insoluble electrode 44 Body 44a, 44b, 46a Through hole 46 Contact part 48 Bolt 50 Nut 52 Washer

Claims (8)

パスラインに沿って配置され、めっき液が満たされた複数のめっきセル内を連続的に走行する鋼板に電気めっきを行う電気めっき鋼板の製造装置において、
少なくとも一部が前記めっきセル内のめっき液に浸漬され、前記鋼板に対面して配置されて、前記鋼板との間に通電して溶融されながら、走行する前記鋼板に連続的に電気めっきを行う少なくとも1つの自溶性電極と、
少なくとも一部が前記めっきセル内のめっき液に浸漬され、前記鋼板に対面して配置されて、前記鋼板との間に通電して、走行する前記鋼板に連続的に電気めっきを行う少なくとも1つの不溶性電極と、
前記自溶性電極および前記不溶性電極をそれぞれ垂下し、前記自溶性電極および前記不溶性電極と電気的に接続される複数の係止部材とを備え、
前記不溶性電極は、最大面が前記鋼板に対面する本体部と、前記係止部材に係止されると共に、電気的に接続される接触部とを有し、前記本体部と前記接触部とが、着脱可能に形成されることを特徴とする電気めっき鋼板の製造装置。
In an electroplated steel sheet manufacturing apparatus that performs electroplating on a steel sheet that is disposed along a pass line and continuously travels in a plurality of plating cells filled with a plating solution,
At least a portion is immersed in a plating solution in the plating cell, arranged facing the steel plate, and continuously electroplated on the traveling steel plate while being energized and melted between the steel plate. At least one self-fluxing electrode;
At least one part that is immersed in a plating solution in the plating cell, arranged facing the steel plate, energized between the steel plate, and continuously electroplates the traveling steel plate. An insoluble electrode;
The self-fluxing electrode and the insoluble electrode are respectively suspended, and includes a plurality of locking members electrically connected to the self-fluxing electrode and the insoluble electrode,
The insoluble electrode has a main body portion whose maximum surface faces the steel plate, a contact portion that is locked to the locking member and electrically connected, and the main body portion and the contact portion are An apparatus for producing an electroplated steel sheet, which is detachably formed.
前記自溶性電極は、前記鋼板の搬送方向と直交する幅方向に複数配置される請求項1に記載の電気めっき鋼板の製造装置。   The said self-fluxing electrode is a manufacturing apparatus of the electroplating steel plate of Claim 1 arrange | positioned in the width direction orthogonal to the conveyance direction of the said steel plate. 前記不溶性電極は、前記鋼板の搬送方向と直交する幅方向に複数配置され、複数の前記不溶性電極の前記本体部の前記鋼板に対面する面は、前記鋼板に平行な同一面上に形成される請求項1または2に記載の電気めっき鋼板の製造装置。   A plurality of the insoluble electrodes are arranged in the width direction orthogonal to the conveying direction of the steel plate, and the surfaces of the main body portions of the plurality of insoluble electrodes facing the steel plate are formed on the same plane parallel to the steel plate. The apparatus for producing an electroplated steel sheet according to claim 1 or 2. 前記係止部材は、前記鋼板の搬送方向と直交する幅方向に延在する棒状の部材であり、前記鋼板の表面に対して傾斜して配置される請求項1〜3のいずれかに記載の電気めっき鋼板の製造装置。   The said latching member is a rod-shaped member extended in the width direction orthogonal to the conveyance direction of the said steel plate, and is inclined and arrange | positioned with respect to the surface of the said steel plate. Electroplated steel plate manufacturing equipment. 前記不溶性電極は、少なくとも表面が白金からなる請求項1〜4のいずれかに記載の電気めっき鋼板の製造装置。   The apparatus for producing an electroplated steel sheet according to any one of claims 1 to 4, wherein the insoluble electrode has at least a surface made of platinum. 前記不溶性電極は、前記本体部と前記接触部とを固定する固定部材を有し、前記固定部材の少なくとも表面は、前記本体部の表面と同じ材質からなる請求項1〜5のいずれかに記載の電気めっき鋼板の製造装置。   The said insoluble electrode has a fixing member which fixes the said main-body part and the said contact part, The at least surface of the said fixing member consists of the same material as the surface of the said main-body part. Electroplated steel plate manufacturing equipment. 前記不溶性電極は、前記自溶性電極が配置されないめっきセルに配置される請求項1〜6のいずれかに記載の電気めっき鋼板の製造装置。   The said insoluble electrode is a manufacturing apparatus of the electroplating steel plate in any one of Claims 1-6 arrange | positioned in the plating cell in which the said self-fluxing electrode is not arrange | positioned. 複数の前記めっきセル内のめっき液を循環させる循環手段を有する請求項1〜7のいずれかに記載の電気めっき鋼板の製造装置。   The apparatus for producing an electroplated steel sheet according to any one of claims 1 to 7, further comprising circulating means for circulating a plating solution in the plurality of plating cells.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50131821A (en) * 1975-03-03 1975-10-18
JPS53113726A (en) * 1977-03-17 1978-10-04 Nippon Steel Corp Electrolytic treatment of metal strip
JPS63131764U (en) * 1987-02-20 1988-08-29
JP3006846U (en) * 1994-07-18 1995-01-31 ダイソー株式会社 Vertical steel plate plating electrode
JP2007515557A (en) * 2003-12-23 2007-06-14 コラス・スタール・ベー・ブイ Improved metal strip electroplating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50131821A (en) * 1975-03-03 1975-10-18
JPS53113726A (en) * 1977-03-17 1978-10-04 Nippon Steel Corp Electrolytic treatment of metal strip
JPS63131764U (en) * 1987-02-20 1988-08-29
JP3006846U (en) * 1994-07-18 1995-01-31 ダイソー株式会社 Vertical steel plate plating electrode
JP2007515557A (en) * 2003-12-23 2007-06-14 コラス・スタール・ベー・ブイ Improved metal strip electroplating

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