JP2014016301A - Method and system for decontaminating object contaminated by radioactive material - Google Patents

Method and system for decontaminating object contaminated by radioactive material Download PDF

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JP2014016301A
JP2014016301A JP2012155336A JP2012155336A JP2014016301A JP 2014016301 A JP2014016301 A JP 2014016301A JP 2012155336 A JP2012155336 A JP 2012155336A JP 2012155336 A JP2012155336 A JP 2012155336A JP 2014016301 A JP2014016301 A JP 2014016301A
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water
decontamination
cleaning
cleaning liquid
decontaminated
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Yasuhiro Yugawa
恭啓 湯川
Takashi Kamitoku
敬 神徳
Nobuo Kurio
暢雄 栗生
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BINOS CORP
Obayashi Corp
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Obayashi Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method and a system for decontaminating an object contaminated by a radioactive material that can reduce the concentration of radioactive cesium to 100 Bq/kg or less, included in a decontamination object contaminated by a radioactive material.SOLUTION: A system for decontaminating an object contaminated by a radioactive material comprises: a washing liquid storing tank 2 for conditioning and storing a natural surfactant washing liquid: a washing machine 4 for performing cavitation jet washing using a natural surfactant as a washing liquid; a collection tank 6 for collecting the natural surfactant washing liquid and a decontamination object; a nano-bubble washing liquid storing tank 8 for conditioning and storing a carbonic acid nano-bubble washing liquid; a washing machine 9 for performing cavitation jet washing using a carbonic acid nano-bubble water as a washing liquid; a classification machine 14 for classifying the decontamination object and suspension water; a washing waste liquid storing tank 15 for collecting the suspension water; and a suspension water treating machine 16 for separating deposit from water to be treated by aggregating, adsorbing, and precipitating radioactive materials and fine particles in the suspension water by using an aggregating, adsorbing, and precipitating agent. The cavitation jet washing is performed by using the natural surfactant washing liquid, and then by using the carbonic acid nano-bubble washing liquid.

Description

本発明は、放射性物質に汚染された不燃物(校庭や園庭、公園などの土壌、浄水場から発生する汚泥、海砂、瓦くずなど)と、可燃物(チップ化された倒木、流木および間伐材、落ち葉など)の放射性セシウム濃度を100Bq/kg以下に除染し、建設資材および燃料などとして再利用が可能となる、放射性物質に汚染された被除染物の除染方法、および除染システムに関する。   The present invention includes incombustible materials contaminated with radioactive materials (soils such as schoolyards, gardens and parks, sludge generated from water treatment plants, sea sand, tile scraps, etc.) and combustible materials (chip fallen trees, driftwood and Decontamination method and decontamination of decontaminated materials contaminated with radioactive materials that can be decontaminated to a concentration of 100 Bq / kg or less for thinned wood, fallen leaves, etc.) and reused as construction materials and fuel About the system.

放射性物質に汚染された土壌の除染は、独立行政法人日本原子力研究開発機構(JAEA)が、内閣府委託事業「福島第一原子力発電所事故に係る避難区域等における除染実証業務」を委託されて平成23年度に「除染技術実証試験事業」で実施した。また、福島県は平成23年度に「除染技術実証事業実地試験」を実施した。JAEAのホームページ(非特許文献1)および福島県のホームページに掲載されている報告書によれば、機械的な除染方法はボールミル装置、破砕装置および高圧ジェット装置などを、化学的な除染方法はシュウ酸溶解を適用したが、いずれの除染方法も土壌の放射性セシウム濃度は100Bq/kg以下に低下していない。   Japan Atomic Energy Agency (JAEA) commissions the government agency commissioned project “Decontamination Demonstration in Evacuation Zones, etc. Related to Fukushima Daiichi Nuclear Power Station Accident” for decontamination of soil contaminated with radioactive materials In 2011, the “Decontamination Technology Demonstration Test Project” was conducted. In 2011, Fukushima Prefecture conducted a “decontamination technology demonstration project field trial”. According to a report published on the JAEA website (Non-patent Document 1) and the website of Fukushima Prefecture, the mechanical decontamination methods include ball mill equipment, crushing equipment, and high-pressure jet equipment, and chemical decontamination methods. Applied oxalic acid dissolution, but none of the decontamination methods reduced the radioactive cesium concentration in the soil to 100 Bq / kg or less.

独立行政法人日本原子力研究開発機構ホームページ、“(3)除染技術実証試験事業の結果報告、平成23年度除染技術実証試験事業”、平成24年3月26日、[平成24年6月25日検索]、インターネットURL:http://www.jaea.go.jp/fukushima/decon04/ke05.pdfJapan Atomic Energy Agency website, “(3) Report on decontamination technology verification test results, 2011 decontamination technology verification test project”, March 26, 2012, [June 25, 2012 Day search], Internet URL: http://www.jaea.go.jp/fukushima/decon04/ke05.pdf

環境省告示第76号において、東日本大震災により生じた災害廃棄物の再生利用した製品の平均的な放射性セシウム(Cs-134とCs-137の合計)濃度は市場に流通する前の段階で100Bq/kg以下と設定されている。放射性セシウムに汚染された土壌および間伐材などを100Bq/kg以下に除染できなければ、建設資材などとして再利用できず、放射性廃棄物の保管量が低減されない、あるいは増加するなどの課題が有る。   According to Ministry of the Environment Notification No.76, the average concentration of radioactive cesium (total of Cs-134 and Cs-137) in products recycled from disaster waste caused by the Great East Japan Earthquake is 100 Bq / It is set as kg or less. If soil and thinned wood contaminated with radioactive cesium cannot be decontaminated to 100 Bq / kg or less, they cannot be reused as construction materials, and there is a problem that the amount of radioactive waste stored cannot be reduced or increased. .

また、除染後の洗浄廃液を浄化処理して洗浄水として再利用できなければ、洗浄廃液が放射性液体廃棄物となるため、放射性液体廃棄物の保管量が増加する課題が有る。除染後の洗浄廃液の放射性セシウム濃度は、以下に示す環境省の基準値以下に浄化する必要がある。
Cs-134濃度(Bq/L)/60(Bq/L)+Cs-137濃度(Bq/L)/90(Bq/L) ≦ 1
Further, if the cleaning waste liquid after decontamination is purified and cannot be reused as cleaning water, the cleaning waste liquid becomes radioactive liquid waste, and there is a problem that the storage amount of the radioactive liquid waste increases. The radioactive cesium concentration in the cleaning waste liquid after decontamination needs to be purified below the standard value of the Ministry of the Environment shown below.
Cs-134 concentration (Bq / L) / 60 (Bq / L) + Cs-137 concentration (Bq / L) / 90 (Bq / L) ≦ 1

そこで、本発明は、放射性物質に汚染された被除染物の放射性セシウム濃度を100Bq/kg以下に除染できる放射性物質に汚染された被除染物の除染方法、および除染システムを提供することを課題とする。   Therefore, the present invention provides a decontamination method and a decontamination system for a decontaminated object contaminated with a radioactive substance that can be decontaminated to a radioactive cesium concentration of the decontaminated object contaminated with a radioactive substance to 100 Bq / kg or less. Is an issue.

また、本発明は、放射性物質に汚染された被除染物の放射性セシウム濃度を100Bq/kg以下に除染できるとともに、除染後の洗浄廃液の放射性セシウム濃度を、環境省の基準値以下に浄化できる放射性物質により汚染された被除染物の除染方法、および除染システムを提供することを課題とする。   In addition, the present invention can decontaminate the radioactive cesium concentration of the decontaminated material contaminated with radioactive substances to 100 Bq / kg or less, and purify the radioactive cesium concentration of the cleaning waste liquid after decontamination to a standard value or less of the Ministry of the Environment. It is an object to provide a decontamination method and a decontamination system for an object to be decontaminated contaminated with a radioactive substance.

本発明の他の課題は、以下の記載により明らかとなる。   Other problems of the present invention will become apparent from the following description.

上記課題は以下の各発明によって解決される。   The above problems are solved by the following inventions.

(請求項1)
放射性物質に汚染された被除染物の除染方法において、天然界面活性剤洗浄液を用いてキャビテーション噴流式洗浄し、その後に炭酸ナノバブル洗浄液を用いてキャビテーション噴流式洗浄することを特徴とする放射性物質に汚染された被除染物の除染方法。
(Claim 1)
In a decontamination method of a decontaminated object contaminated with a radioactive substance, a cavitation jet cleaning is performed using a natural surfactant cleaning liquid, followed by a cavitation jet cleaning using a carbonic acid nanobubble cleaning liquid. Decontamination method for contaminated objects to be decontaminated.

(請求項2)
天然界面活性剤洗浄液の調整工程と、天然界面活性剤を洗浄液としたキャビテーション噴流式洗浄工程と、炭酸ナノバブル洗浄液の調整工程と、炭酸ナノバブル水を洗浄液としたキャビテーション噴流式洗浄工程と、被除染物と懸濁水(放射性物質および微細粒子を含む)に分級する工程と、凝集吸着沈殿剤により懸濁水中の放射性物質および微細粒子を凝集吸着沈殿させて沈殿物と被処理水を分離する工程と、被処理水を除染用の洗浄水として再利用することを特徴とする請求項1記載の放射性物質に汚染された被除染物の除染方法。
(Claim 2)
Natural surfactant cleaning liquid adjustment process, cavitation jet cleaning process using natural surfactant as cleaning liquid, carbonated nanobubble cleaning liquid adjustment process, cavitation jet cleaning process using carbonated nanobubble water, and decontaminated product And a step of classifying the suspension into water (including radioactive substances and fine particles), a step of aggregating and precipitating radioactive substances and fine particles in the suspension water with an agglomeration adsorbing precipitant, and separating the precipitate and the water to be treated; The method for decontamination of a decontaminated material contaminated with a radioactive substance according to claim 1, wherein the water to be treated is reused as cleaning water for decontamination.

(請求項3)
前記天然界面活性剤洗浄液の天然界面活性剤濃度は0.01〜0.1%の範囲で作液することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。
(Claim 3)
3. The removal of a decontaminated material contaminated with a radioactive substance according to claim 1 or 2, wherein the natural surfactant concentration of the natural surfactant cleaning liquid is in the range of 0.01 to 0.1%. Dyeing method.

(請求項4)
前記炭酸ナノバブル洗浄液は、ナノバブル発生器のナノバブル水生成量(L/min)に対して二酸化炭素ガスを2.5〜100%の範囲でナノバブル発生器に供給して作液することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。
(Claim 4)
The carbonic acid nanobubble cleaning liquid is produced by supplying carbon dioxide gas to the nanobubble generator in a range of 2.5 to 100% with respect to the nanobubble water generation amount (L / min) of the nanobubble generator. The decontamination method of the to-be-decontaminated thing contaminated with the radioactive substance of Claim 1 or 2.

(請求項5)
前記天然界面活性剤を洗浄液としたキャビテーション噴流式洗浄工程と、前記炭酸ナノバブル水を洗浄液としたキャビテーション噴流式洗浄工程には15〜25MPaの駆動用高圧水を供給することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。
(Claim 5)
The high-pressure water for driving of 15 to 25 MPa is supplied to the cavitation jet cleaning process using the natural surfactant as a cleaning liquid and the cavitation jet cleaning process using the carbonated nanobubble water as a cleaning liquid. Or the decontamination method of the to-be-decontaminated material contaminated with the radioactive substance of 2.

(請求項6)
前記凝集吸着沈殿剤には、パラクロレラ・バイノス(Parachlorella sp. binos)を乾燥させたバイノスパウダーを含むことを特徴とする請求項2記載の放射性物質に汚染された被除染物の除染方法。
(Claim 6)
3. The method for decontamination of a decontaminated material contaminated with a radioactive substance according to claim 2, wherein the coagulation adsorbing precipitant contains binos powder obtained by drying Parachlorella sp. Binos. .

(請求項7)
前記凝集吸着沈殿剤は、除染後の洗浄廃液に0.1〜0.5g/L添加することを特徴とする請求項2又は6記載の放射性物質に汚染された被除染物の除染方法。
(Claim 7)
The method for decontamination of a decontaminated object contaminated with a radioactive substance according to claim 2 or 6, wherein the agglomerated adsorbing precipitant is added in an amount of 0.1 to 0.5 g / L to the cleaning waste liquid after decontamination. .

(請求項8)
放射性物質に汚染された被除染物の除染システムにおいて、天然界面活性剤洗浄液を調整・貯留する洗浄液貯槽と、天然界面活性剤を洗浄液としてキャビテーション噴流式洗浄する洗浄機と、天然界面活性剤洗浄液および被除染物を回収する回収槽と、炭酸ナノバブル洗浄液を調整・貯留するナノバブル洗浄液貯槽と、炭酸ナノバブル水を洗浄液としてキャビテーション噴流式洗浄する洗浄機と、被除染物と懸濁水(放射性物質および微細粒子を含む)を分級する分級機と、懸濁水を回収する洗浄廃液貯槽と、凝集吸着沈殿剤により懸濁水中の放射性物質および微細粒子を凝集吸着沈殿させて沈殿物と被処理水を分離する懸濁水処理機とで構成されることを特徴とする放射性物質に汚染された被除染物の除染システム。
(Claim 8)
In a decontamination system for decontaminated materials contaminated with radioactive substances, a cleaning liquid storage tank that adjusts and stores a natural surfactant cleaning liquid, a cleaning machine that uses a natural surfactant as a cleaning liquid and a cavitation jet cleaning, and a natural surfactant cleaning liquid A recovery tank for recovering the decontaminated material, a nanobubble cleaning liquid storage tank for adjusting and storing the carbonic acid nanobubble cleaning liquid, a washing machine for cavitation jet cleaning using the carbonic acid nanobubble water as a cleaning liquid, (Including particles), a washing waste liquid storage tank that collects suspended water, and agglomerated adsorptive precipitants that aggregate and adsorb the radioactive substances and fine particles in the suspended water to separate the precipitate and the water to be treated. A decontamination system for an object to be decontaminated by a radioactive material, comprising a suspension water treatment machine.

本発明の効果は、以下の通りである。   The effects of the present invention are as follows.

(1)除染後の被除染物(土壌、チップ化された倒木、流木および間伐材など)は、放射性セシウム(Cs-134+Cs-137の合計)濃度が100Bq/kg以下に低下しているため、建設資材等への再利用が可能である。 (1) Decontaminated materials after decontamination (soil, chipped fallen trees, driftwood, thinned wood, etc.) have a radioactive cesium (Cs-134 + Cs-137 total) concentration of 100 Bq / kg or less. It can be reused for construction materials.

(2)100Bq/kg以下の除染後土壌は80%以上回収できるため、災害廃棄物の保管量の大幅な低減と再生利用が促進される。 (2) Since 80% or more of the decontaminated soil of 100 Bq / kg or less can be recovered, the amount of disaster waste stored can be greatly reduced and reused.

(3)浄化処理した洗浄廃液は、放射性セシウム濃度が検出下限値以下、CODが20mg/L以下であるため、洗浄水として再利用が可能である。 (3) The cleaning waste liquid subjected to the purification treatment can be reused as cleaning water because the radioactive cesium concentration is not more than the detection lower limit value and the COD is not more than 20 mg / L.

(4)浄化処理した洗浄廃液を放流した場合は、放射能濃度が検出下限値以下、CODが20mg/L以下であるため、環境への影響は無い。 (4) When the cleaned cleaning waste liquid is discharged, the radioactivity concentration is not more than the detection lower limit value and the COD is not more than 20 mg / L, so there is no influence on the environment.

本発明に係る除染システムを説明する装置フロー図Apparatus flow diagram for explaining a decontamination system according to the present invention 本発明に係る土壌除染の実施手順Implementation procedure of soil decontamination according to the present invention 本発明に係る土壌除染後の洗浄廃液の処理手順Treatment procedure of washing waste liquid after soil decontamination according to the present invention

以下、本発明の実施の形態を図面に基づいて説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

本発明において、放射性物質に汚染された被除染物とは、不燃物としては、校庭や園庭、公園などの土壌、浄水場から発生する汚泥、海砂、瓦くずなど、可燃物としては、チップ化された倒木、流木および間伐材、落ち葉などが例示できる。 In the present invention, to-be-contaminated materials contaminated with radioactive substances are non-combustible materials such as schoolyards, gardens, parks, soil, sludge generated from water treatment plants, sea sand, waste tiles, etc. Examples include chipped fallen trees, driftwood, thinned wood, and fallen leaves.

(機器構成)
図1は放射性物質に汚染された被除染物の除染システムの機器構成を示す。
(Equipment configuration)
FIG. 1 shows an apparatus configuration of a decontamination system for an object to be decontaminated contaminated with a radioactive substance.

本実施の形態においては、放射性物質に汚染された被除染物として、土壌を用いた。   In the present embodiment, soil is used as a decontamination object contaminated with radioactive substances.

汚染土壌は2段階で除染した。第1段の除染は、所定量の除染前土壌1と洗浄液貯槽2で調整した天然界面活性剤洗浄液を受ける供給槽3と、天然界面活性剤洗浄液と混合された土壌1を洗浄する第1段キャビテーション噴流式洗浄機4と、第1段キャビテーション噴流式洗浄機4に接続された駆動用高圧水を供給する第1段プランジャーポンプ5と、第1段キャビテーション噴流式洗浄機4を通過した土壌1および天然界面活性剤洗浄液を回収する回収槽6とで構成される。   Contaminated soil was decontaminated in two stages. In the first stage of decontamination, a supply tank 3 that receives a predetermined amount of soil 1 before decontamination and a cleaning liquid storage tank 2 that receives a natural surfactant cleaning liquid, and a soil 1 mixed with the natural surfactant cleaning liquid are cleaned. Passed through a first stage cavitation jet washer 4, a first stage plunger pump 5 for supplying driving high-pressure water connected to the first stage cavitation jet washer 4, and a first stage cavitation jet washer 4 And a collection tank 6 for collecting the natural surfactant cleaning liquid.

回収槽6内の上澄み液(天然界面活性剤洗浄液)を洗浄廃液貯槽15に排出後に第2段の除染を行う。   After discharging the supernatant liquid (natural surfactant cleaning liquid) in the recovery tank 6 to the cleaning waste liquid storage tank 15, the second stage decontamination is performed.

第2段の除染は、第1段除染後の土壌7を収納した回収槽6内に所定量の炭酸ナノバブル洗浄液を供給するナノバブル洗浄液貯槽8と、炭酸ナノバブル洗浄液と混合された土壌7を洗浄する第2段キャビテーション噴流式洗浄機9と、第2段キャビテーション噴流式洗浄機9に接続された駆動用高圧水を供給する第2段プランジャーポンプ10とで構成される。   In the second stage decontamination, a nanobubble cleaning liquid storage tank 8 for supplying a predetermined amount of carbonic acid nanobubble cleaning liquid into a collection tank 6 storing the soil 7 after the first stage decontamination, and soil 7 mixed with the carbonic acid nanobubble cleaning liquid are used. A second-stage cavitation jet type washing machine 9 to be washed and a second-stage plunger pump 10 for supplying driving high-pressure water connected to the second-stage cavitation jet type washing machine 9 are configured.

なお、炭酸ナノバブル洗浄液は、二酸化炭素ガスボンベ11が接続されたナノバブル発生器12により作液する。また、第1段プランジャーポンプ5および第2段プランジャーポンプ10は水貯槽13に接続されている。   The carbonic acid nanobubble cleaning liquid is produced by the nanobubble generator 12 to which the carbon dioxide gas cylinder 11 is connected. The first stage plunger pump 5 and the second stage plunger pump 10 are connected to a water storage tank 13.

第2段キャビテーション噴流式洗浄機9を通過した土壌7および炭酸ナノバブル洗浄液は湿式分級機14に移送される。湿式分級機14では、75μm以上の土壌と、75μm未満の土壌とに分級される。   The soil 7 and the carbonated nanobubble cleaning liquid that have passed through the second-stage cavitation jet cleaning machine 9 are transferred to the wet classifier 14. In the wet classifier 14, it classifies into the soil of 75 micrometers or more and the soil of less than 75 micrometers.

湿式分級機14より分級された75μm未満の土壌は懸濁水とともに洗浄廃液として浄化処理される。洗浄廃液の浄化処理は、湿式分級機14から移送された懸濁水を受ける洗浄廃液貯槽15と、洗浄廃液を凝集吸着沈殿する懸濁水処理機16と、懸濁水処理機16に接続された凝集吸着沈殿剤供給部17とで構成される。   The soil of less than 75 μm classified by the wet classifier 14 is purified as a washing waste liquid together with the suspended water. The cleaning treatment of the cleaning waste liquid includes a cleaning waste liquid storage tank 15 that receives the suspended water transferred from the wet classifier 14, a suspension water processing machine 16 that coagulates and precipitates the cleaning waste liquid, and an aggregation adsorption connected to the suspension water processing machine 16. And a precipitating agent supply unit 17.

(除染の実施)
図1に示した装置を用い、放射性物質に汚染された土壌の除染を実施した。除染前土壌1からはCs-134とCs-137が検出され、その濃度は合計で750Bq/kgであった。また、粒度分布を測定した結果、75μm未満の粒子は15%、75μm以上の粒子が85%であった。
(Execution of decontamination)
Using the apparatus shown in FIG. 1, decontamination of soil contaminated with radioactive substances was performed. Cs-134 and Cs-137 were detected from the soil 1 before decontamination, and the total concentration was 750 Bq / kg. As a result of measuring the particle size distribution, 15% of the particles were less than 75 μm and 85% were 75 μm or more.

図2に土壌の除染方法を示す。除染手順は以下の通りである。   FIG. 2 shows a soil decontamination method. The decontamination procedure is as follows.

1.洗浄液貯槽2にて主成分がサーファクチンナトリウムの天然界面活性剤0.01%の洗浄液を90L作液する。
2.供給槽3に土壌1を30kgと、天然界面活性剤洗浄液を90L投入する。
3.第1段プランジャーポンプ5を起動し、15MPaの駆動用高圧水を第1段キャビテーション噴流式洗浄機4に供給する。
4.供給槽3と第1段キャビテーション噴流式洗浄機4とに亘って接続された配管3a内は負圧となるため、供給槽3内の土壌1と天然界面活性剤洗浄液はキャビテーション噴流式洗浄機4に吸引される。キャビテーション噴流式洗浄機4内ではキャビテーションが発生し、土壌1はキャビテーション噴流式洗浄機4を通過する間に洗浄液中で研磨・破砕されて洗浄される。
1. In the cleaning liquid storage tank 2, 90 L of a cleaning liquid containing 0.01% of a natural surfactant whose main component is surfactin sodium is prepared.
2. 30 kg of soil 1 and 90 L of a natural surfactant cleaning solution are charged into the supply tank 3.
3. The first-stage plunger pump 5 is activated and 15 MPa of driving high-pressure water is supplied to the first-stage cavitation jet cleaning machine 4.
4). Since the inside of the pipe 3a connected between the supply tank 3 and the first stage cavitation jet type washing machine 4 becomes negative pressure, the soil 1 and the natural surfactant washing liquid in the supply tank 3 are transferred to the cavitation jet type washing machine 4. Sucked into. Cavitation occurs in the cavitation jet cleaning machine 4, and the soil 1 is ground, crushed and washed in the cleaning liquid while passing through the cavitation jet cleaning machine 4.

5.第1段キャビテーション噴流式洗浄機4を通過した土壌1と天然界面活性剤洗浄液は回収槽6に回収される。
6.回収槽6内の上澄み液(天然界面活性剤洗浄液)を洗浄廃液貯槽15に移送する。天然界面活性剤洗浄液に浮上している土壌微細粒子(75μm未満)も洗浄廃液貯槽15に移送される。
7.二酸化炭素ガスボンベ11より二酸化炭素ガスをナノバブル発生器12に供給するとともに、ナノバブル洗浄液貯槽8の水をナノバブル発生器12に循環させ、ナノバブル洗浄液貯槽8にて炭酸ナノバブル洗浄液を90L作液する。なお、本実施例では、ナノバブル発生器12のナノバブル水生成量が4L/minであるため、二酸化炭素ガスの供給量はナノバブル水生成量に対して2.5%(0.1L/min)である。
8.炭酸ナノバブル洗浄液90Lを回収槽6に投入する。
5. The soil 1 and the natural surfactant cleaning liquid that have passed through the first-stage cavitation jet cleaning machine 4 are recovered in the recovery tank 6.
6). The supernatant liquid (natural surfactant cleaning liquid) in the recovery tank 6 is transferred to the cleaning waste liquid storage tank 15. Soil fine particles (less than 75 μm) floating in the natural surfactant cleaning liquid are also transferred to the cleaning waste liquid storage tank 15.
7). While supplying carbon dioxide gas from the carbon dioxide gas cylinder 11 to the nanobubble generator 12, water in the nanobubble cleaning liquid storage tank 8 is circulated to the nanobubble generator 12, and 90 L of carbonic acid nanobubble cleaning liquid is produced in the nanobubble cleaning liquid storage tank 8. In this example, since the nanobubble water generation amount of the nanobubble generator 12 is 4 L / min, the supply amount of carbon dioxide gas is 2.5% (0.1 L / min) with respect to the nanobubble water generation amount. is there.
8). 90 L of carbonic acid nanobubble cleaning liquid is put into the collection tank 6.

9.第2段プランジャーポンプ10を起動し、15MPaの駆動用高圧水を第2段キャビテーション噴流式洗浄機9に供給する。
10.回収槽6と第2段キャビテーション噴流式洗浄機9とに亘って接続された配管6a内は負圧となるため、回収槽6内の土壌7と炭酸ナノバブル洗浄液は第2段キャビテーション噴流式洗浄機9に吸引される。第2段キャビテーション噴流式洗浄機9内ではキャビテーションが発生し、土壌7は第2段キャビテーション噴流式洗浄機9を通過する間に洗浄液中で研磨・破砕されて洗浄される。また、土壌表面を覆っている天然界面活性剤は、炭酸ナノバブル洗浄液により濯がれる。
11.第2段キャビテーション噴流式洗浄機9を通過した土壌7と炭酸ナノバブル洗浄液は湿式分級機14に移送される。
12.湿式分級機14により洗浄後土壌を75μm未満の土壌と75μm以上の土壌とに分級するとともに、75μm未満の土壌が含まれる洗浄廃液を分離する。
13.75μm以上の土壌の放射能濃度を測定する。
9. The second-stage plunger pump 10 is activated and 15 MPa of driving high-pressure water is supplied to the second-stage cavitation jet cleaning machine 9.
10. Since the pipe 6a connected between the recovery tank 6 and the second stage cavitation jet type washing machine 9 has a negative pressure, the soil 7 and the carbonated carbon nanobubble cleaning liquid in the recovery tank 6 are in the second stage cavitation jet type washing machine. 9 sucked. Cavitation occurs in the second-stage cavitation jet cleaning machine 9, and the soil 7 is ground, crushed and washed in the cleaning liquid while passing through the second-stage cavitation jet cleaning machine 9. Moreover, the natural surfactant covering the soil surface is rinsed with a carbonic acid nanobubble cleaning solution.
11. The soil 7 and the carbonic acid nanobubble cleaning liquid that have passed through the second stage cavitation jet cleaning machine 9 are transferred to the wet classifier 14.
12 The wet classifier 14 classifies the soil after washing into soil having a size of less than 75 μm and soil having a size of 75 μm or more, and separates a washing waste liquid containing soil having a size less than 75 μm.
13. Measure the radioactivity concentration of soil of 75μm or more.

上記手順により除染した結果、75μm以上の土壌のCs-134とCs-137の合計濃度は80Bq/kgであった。また、75μm以上の土壌は25kg回収され、除染後土壌の回収率は83%であった。   As a result of decontamination by the above procedure, the total concentration of Cs-134 and Cs-137 in the soil of 75 μm or more was 80 Bq / kg. Further, 25 kg of soil having a size of 75 μm or more was recovered, and the recovery rate of soil after decontamination was 83%.

以上のことより、本発明の除染方法は放射性セシウムに汚染された土壌を100Bq/kg以下に除染できることがわかった。   From the above, it was found that the decontamination method of the present invention can decontaminate soil contaminated with radioactive cesium to 100 Bq / kg or less.

本発明の除染方法の特徴は、洗浄液に天然界面活性剤洗浄液と炭酸ナノバブル洗浄液を適用したことである。天然界面活性剤洗浄液は、第1段キャビテーション噴流式洗浄機4に負圧で吸引されると体積が一旦膨張するが、高圧(15MPa)の第1段キャビテーション噴流式洗浄機4内では体積が収縮する。体積の膨張と収縮により天然界面活性剤のミセル(天然界面活性剤の集合体)は超微細化される。一方、土壌は第1段キャビテーション噴流式洗浄機4内で研磨、破砕されて粗粒子の一部が微細粒子あるいは超微細粒子となる。これら粒子の表面は天然界面活性剤に覆われるため(例えば、超微細粒子表面は超微細ミセルに覆われる)、反発しあって75μm以上の粗粒子は洗浄液に沈降し、75μm未満の微細粒子および超微細粒子は洗浄液中に浮上することで、75μm以上の土壌粒子と75μm未満の土壌粒子の分離が容易となる。   A feature of the decontamination method of the present invention is that a natural surfactant cleaning solution and a carbonic acid nanobubble cleaning solution are applied to the cleaning solution. The natural surfactant cleaning liquid expands once when it is sucked into the first stage cavitation jet cleaning machine 4 under negative pressure, but the volume shrinks in the first stage cavitation jet cleaning machine 4 at high pressure (15 MPa). To do. Due to the expansion and contraction of the volume, the micelle (natural surfactant aggregate) of the natural surfactant is made ultrafine. On the other hand, the soil is ground and crushed in the first stage cavitation jet washer 4 so that some of the coarse particles become fine particles or ultrafine particles. Since the surface of these particles is covered with a natural surfactant (for example, the surface of ultrafine particles is covered with ultrafine micelles), the repulsive coarse particles of 75 μm or more settle in the washing liquid, and the fine particles of less than 75 μm and The ultrafine particles float in the cleaning liquid, so that it becomes easy to separate the soil particles of 75 μm or more and the soil particles of less than 75 μm.

また、炭酸ナノバブル洗浄液は第2段キャビテーション噴流式洗浄機9に負圧で吸引され、高圧(15MPa)の第2段キャビテーション噴流式洗浄機9内を通過して大気圧に解放される。第2段キャビテーション噴流式洗浄機9内は外部から導入した空気と洗浄液中の二酸化炭素が混在するため、大量の気泡が圧力変動に伴って生成と消滅を繰り返すことで破壊力の大きなキャビテーションが発生して土壌が研磨、破砕される。   Further, the carbonic acid nanobubble cleaning liquid is sucked into the second-stage cavitation jet cleaning machine 9 with a negative pressure, passes through the high-pressure (15 MPa) second-stage cavitation jet cleaning machine 9, and is released to atmospheric pressure. Because the air introduced from the outside and carbon dioxide in the cleaning liquid coexist in the second stage cavitation type washing machine 9, cavitation with a large destructive force is generated by repeating generation and disappearance of a large number of bubbles with pressure fluctuation. The soil is then ground and crushed.

上記現象により、75μm以上の土壌は強力に除染され、放射性セシウム濃度が100Bq/kg以下に低下したと考えられる。   Due to the above phenomenon, the soil of 75 μm or more is strongly decontaminated, and the radioactive cesium concentration is considered to have decreased to 100 Bq / kg or less.

環境省告示第76号において、東日本大震災により生じた災害廃棄物の再生利用した製品の平均的な放射性セシウム濃度は市場に流通する前の段階で100Bq/kg以下と設定されている。   In the Ministry of the Environment Notification No. 76, the average radioactive cesium concentration of products recycled from disaster waste caused by the Great East Japan Earthquake is set to 100 Bq / kg or less before being put on the market.

なお、チップ化された材木および落ち葉についても本発明の除染方法により放射性セシウム濃度は100Bq/kg以下に除染できることを確認した。   In addition, it was confirmed that the radioactive cesium concentration can be decontaminated to 100 Bq / kg or less by using the decontamination method of the present invention for the timber and the fallen leaves that are made into chips.

従って、本発明の除染方法を適用することにより放射能で汚染された土壌および間伐材などの80%以上は再生利用することが可能であることから、災害廃棄物の保管量の大幅な低減と、建設資材等への再利用が促進される。   Therefore, by applying the decontamination method of the present invention, it is possible to recycle more than 80% of soil and thinned wood contaminated with radioactivity, so that the amount of disaster waste stored can be greatly reduced. And reuse for construction materials is promoted.

独立行政法人日本原子力研究開発機構(JAEA)は、内閣府委託事業「福島第一原子力発電所事故に係る避難区域等における除染実証業務」を受け、平成23年度に「除染技術実証試験事業」を実施した。また、福島県は独自に平成23年度に「除染技術実証事業実地試験」を実施した。試験結果はJAEAおよび福島県のホームページに掲載されている。土壌の除染結果も掲載されているが、いずれの除染技術も100Bq/kg以下に除染されていない。   Independent administrative agency Japan Atomic Energy Agency (JAEA) received the “Decontamination Demonstration Project in Evacuation Zones, etc. Related to the Fukushima Daiichi Nuclear Power Station Accident” commissioned by the Cabinet Office. Was carried out. In addition, Fukushima Prefecture independently conducted a “decontamination technology demonstration project field test” in FY2011. The test results are posted on the JAEA and Fukushima Prefecture websites. Soil decontamination results are also listed, but none of the decontamination techniques have been decontaminated to 100 Bq / kg or less.

従って、本発明の除染方法は放射能で汚染された土壌を100Bq/kg以下に除染できる唯一の技術である。   Therefore, the decontamination method of the present invention is the only technique capable of decontaminating radioactively contaminated soil to 100 Bq / kg or less.

なお、除染の実施例は本発明の好ましい実施形態について詳述したが、本発明は特定の実施形態に限定されるものではなく、特許請求の範囲に記載された本発明の要旨の範囲内において、種々の変形・変更が可能であることはいうまでもない。   Although the examples of decontamination have described in detail preferred embodiments of the present invention, the present invention is not limited to specific embodiments, and is within the scope of the gist of the present invention described in the claims. Needless to say, various modifications and changes are possible.

除染条件は天然界面活性剤濃度が0.01〜0.1%、炭酸ナノバブル洗浄液を作液する際の二酸化炭素ガス供給量がナノバブル生成量の2.5〜100%、プランジャーポンプの駆動用高圧水の圧力が15〜25MPaの範囲で100Bq/kg以下に除染できることを確認した。また、洗浄後土壌の分級と洗浄液との分離は、振動篩装置やハイメッシュセパレーターが適用できる。   The decontamination conditions include a natural surfactant concentration of 0.01 to 0.1%, a carbon dioxide gas supply amount of 2.5 to 100% of the nanobubble generation amount when producing a carbonated nanobubble cleaning solution, and a plunger pump drive It was confirmed that decontamination can be performed to 100 Bq / kg or less when the pressure of the high pressure water for use is in the range of 15 to 25 MPa. Moreover, a vibration sieve device or a high mesh separator can be applied to the classification of the soil after washing and the separation of the washing liquid.

(洗浄廃液処理の実施)
図3に洗浄廃液の浄化手順を示す。浄化手順は以下の通りである。
(Implementation of cleaning waste liquid treatment)
FIG. 3 shows a cleaning waste liquid purification procedure. The purification procedure is as follows.

1.湿式分級機14の洗浄廃液を洗浄廃液貯槽15に移送する。
2.洗浄廃液貯槽15の洗浄廃液を懸濁水処理機16に移送する。
3.懸濁水処理機16の洗浄廃液に凝集吸着沈殿剤供給部17より凝集吸着沈殿剤(バイノスパウダーを含む)を0.3g/L添加する。
4.5〜10分間で放射性物質と土壌微細粒子が凝集吸着して沈殿する。
5.ろ布により沈殿物とろ液とに分離する。
6.ろ液の放射能濃度を測定する。
7.ろ液の放射能濃度が以下に示す環境省の基準値以下であることを確認し洗浄液として再利用する。
Cs-134濃度(Bq/L)/60(Bq/L)+Cs-137濃度(Bq/L)/90(Bq/L) ≦ 1
8.沈殿物(汚泥)の放射能濃度を測定し保管する。
1. The cleaning waste liquid of the wet classifier 14 is transferred to the cleaning waste liquid storage tank 15.
2. The cleaning waste liquid in the cleaning waste liquid storage tank 15 is transferred to the suspension water treatment machine 16.
3. Aggregated adsorptive precipitant (including binos powder) is added to the washing waste liquid of the suspension water treatment machine 16 from the aggregate adsorbent / precipitant supply unit 17 at 0.3 g / L.
Radioactive material and soil fine particles are aggregated and adsorbed in 4.5 to 10 minutes.
5. Separated into precipitate and filtrate by filter cloth.
6). Measure the radioactivity concentration of the filtrate.
7). Confirm that the radioactivity concentration of the filtrate is below the standard value of the Ministry of the Environment shown below, and reuse it as a cleaning solution.
Cs-134 concentration (Bq / L) / 60 (Bq / L) + Cs-137 concentration (Bq / L) / 90 (Bq / L) ≦ 1
8). Measure and store the radioactive concentration of sediment (sludge).

上記手順により洗浄廃液を浄化処理した結果、ろ液の放射性セシウム濃度は検出下限値(20Bq/L)以下であった。また、ろ液のCOD濃度も20mg/L以下であった。なお、浄化処理した洗浄廃液量は450Lであった。   As a result of purifying the cleaning waste liquid by the above procedure, the concentration of radioactive cesium in the filtrate was below the lower limit of detection (20 Bq / L). Further, the COD concentration of the filtrate was 20 mg / L or less. The amount of cleaning waste liquid subjected to the purification treatment was 450 L.

沈殿物(汚泥)は10kg回収され、放射性セシウム濃度は1,000Bq/kgであった。   10 kg of sediment (sludge) was recovered, and the radioactive cesium concentration was 1,000 Bq / kg.

なお、凝集吸着沈殿剤はパラクロレラ・バイノス(Parachlorella sp.binos)を乾燥させたバイノスパウダーが10〜25重量%、その他に硫酸アルミニウム20〜25重量%、石膏及び/又は炭酸ナトリウム重量30〜40%、珪藻土8〜15重量%、ソーダ灰などのアルカリ物質15〜20重量%、高分子フロック剤重量1〜7%とで構成される。パラクロレラ・バイノスはアルギン酸生産能を有するパラクロレラ属微細藻類のことを言い、出願人(株式会社バイノス)は有用な新規パラクロレラ属微細藻類及びその利用方法を提供すべく国際出願を行った(WO2010/024367号公報)。   The aggregated adsorbing precipitant is 10 to 25% by weight of binos powder obtained by drying Parachlorella sp. Binos, 20 to 25% by weight of aluminum sulfate, gypsum and / or sodium carbonate weight of 30 to 30%. 40%, diatomaceous earth 8 to 15% by weight, alkaline substance 15 to 20% by weight such as soda ash, and polymer flocculant weight 1 to 7%. Parachlorella binos refers to Parachlorella microalgae capable of producing alginic acid, and the applicant (Bainos Co., Ltd.) filed an international application to provide useful new Parachlorella microalgae and methods for using the same ( WO2010 / 024367).

以上のことよりバイノスパウダーを含む凝集吸着沈殿剤は、洗浄廃液中の放射性セシウム濃度を検出下限値以下に浄化できることがわかった。また、天然界面活性剤も凝集吸着するため洗浄廃液中のCOD濃度は20ppm以下に低減できることがわかった。   From the above, it was found that the aggregated adsorbing precipitant containing binos powder can purify the radioactive cesium concentration in the washing waste liquid below the detection lower limit value. It was also found that the COD concentration in the cleaning waste liquid can be reduced to 20 ppm or less because the natural surfactant is also aggregated and adsorbed.

従って、浄化処理した洗浄廃液は洗浄水として再利用可能であるため、原理的には放射性液体廃棄物は発生しない。また、浄化処理した廃液を放流したとしても放射性物質濃度は検出下限値以下、COD濃度は20ppm以下であるため環境への影響は無い。   Therefore, since the cleaning waste liquid after the purification treatment can be reused as cleaning water, in principle, no radioactive liquid waste is generated. Even if the purified waste liquid is discharged, the radioactive substance concentration is not more than the detection lower limit value, and the COD concentration is not more than 20 ppm.

なお、除染廃液処理の実施例は本発明の好ましい実施形態について詳述したが、本発明は特定の実施形態に限定されるものではなく、特許請求の範囲に記載された本発明の要旨の範囲内において、種々の変形・変更が可能であることはいうまでもない。バイノスパウダーを含む凝集吸着沈殿剤は、添加量0.1〜0.5g/Lの範囲において浄化処理廃液の放射性セシウム濃度は検出下限値以下、COD濃度は20ppm以下であることを確認した。   In addition, although the Example of the decontamination waste liquid processing explained in detail about the preferred embodiment of the present invention, the present invention is not limited to the specific embodiment, and the gist of the present invention described in the claims is described. It goes without saying that various modifications and changes can be made within the range. It was confirmed that the concentration of radioactive cesium in the waste liquid for purification treatment was not more than the detection lower limit value and the COD concentration was not more than 20 ppm in the range of addition amount of 0.1 to 0.5 g / L for the aggregated adsorbing precipitant containing binos powder.

(効果)
本発明の実施例では、洗浄液に天然界面活性剤と炭酸ナノバブル洗浄液を用い、キャビテーション噴流式洗浄機により汚染土壌を除染した。また、除染後の洗浄廃液はバイノスパウダーを含む凝集吸着沈殿剤により浄化処理した。本発明の効果は、以下の通りである。
(effect)
In the Example of this invention, the natural soil and the carbonic acid nano bubble washing | cleaning liquid were used for washing | cleaning liquid, and the contaminated soil was decontaminated with the cavitation jet type washing machine. In addition, the cleaning waste liquid after decontamination was purified with an agglomerated adsorptive precipitant containing binos powder. The effects of the present invention are as follows.

(1)除染後の土壌、チップ化された材木および落ち葉などは、放射性セシウム(Cs-134+Cs-137の合計)濃度が100Bq/kg以下に低下しているため、建設資材および燃料等への再利用が可能である。 (1) Soil after decontamination, chipped timber and fallen leaves have a radioactive cesium (total of Cs-134 + Cs-137) concentration reduced to 100 Bq / kg or less. Can be reused.

(2)100Bq/kg以下の除染後土壌は80%以上回収できるため、災害廃棄物の保管量の大幅な低減と再生利用が促進される。 (2) Since 80% or more of the decontaminated soil of 100 Bq / kg or less can be recovered, the amount of disaster waste stored can be greatly reduced and reused.

(3)浄化処理した洗浄廃液は、放射性セシウム濃度が検出下限値以下、CODが20mg/L以下であるため、洗浄水として再利用が可能である。 (3) The cleaning waste liquid subjected to the purification treatment can be reused as cleaning water because the radioactive cesium concentration is not more than the detection lower limit value and the COD is not more than 20 mg / L.

(4)浄化処理した洗浄廃液を放流した場合は、放射能濃度が検出下限値以下、CODが20mg/L以下であるため、環境への影響は無い。 (4) When the cleaned cleaning waste liquid is discharged, the radioactivity concentration is not more than the detection lower limit value and the COD is not more than 20 mg / L, so there is no influence on the environment.

1:除染前土壌
2:洗浄液貯槽
3:供給槽
4:第1段キャビテーション噴流式洗浄機
5:第1段プランジャーポンプ
6:回収槽
7:第1段除染後土壌
8:ナノバブル洗浄液貯槽
9:第2段キャビテーション噴流式洗浄機
10:第2段プランジャーポンプ
11:二酸化炭素ガスボンベ
12:ナノバブル発生器
13:水貯槽
14:湿式分級機
15:洗浄廃液貯槽
16:懸濁水処理機
17:凝集吸着沈殿剤供給部
1: Soil before decontamination 2: Washing liquid storage tank 3: Supply tank 4: First stage cavitation jet washing machine 5: First stage plunger pump 6: Recovery tank 7: Soil after first stage decontamination 8: Nano bubble washing liquid storage tank 9: Second stage cavitation jet type washing machine 10: Second stage plunger pump 11: Carbon dioxide gas cylinder 12: Nano bubble generator 13: Water storage tank 14: Wet classifier 15: Washing waste liquid storage tank 16: Suspended water treatment machine 17: Aggregation adsorption precipitant supply section

Claims (8)

放射性物質に汚染された被除染物の除染方法において、天然界面活性剤洗浄液を用いてキャビテーション噴流式洗浄し、その後に炭酸ナノバブル洗浄液を用いてキャビテーション噴流式洗浄することを特徴とする放射性物質に汚染された被除染物の除染方法。   In a decontamination method of a decontaminated object contaminated with a radioactive substance, a cavitation jet cleaning is performed using a natural surfactant cleaning liquid, followed by a cavitation jet cleaning using a carbonic acid nanobubble cleaning liquid. Decontamination method for contaminated objects to be decontaminated. 天然界面活性剤洗浄液の調整工程と、天然界面活性剤を洗浄液としたキャビテーション噴流式洗浄工程と、炭酸ナノバブル洗浄液の調整工程と、炭酸ナノバブル水を洗浄液としたキャビテーション噴流式洗浄工程と、被除染物と懸濁水(放射性物質および微細粒子を含む)に分級する工程と、凝集吸着沈殿剤により懸濁水中の放射性物質および微細粒子を凝集吸着沈殿させて沈殿物と被処理水を分離する工程と、被処理水を除染用の洗浄水として再利用することを特徴とする請求項1記載の放射性物質に汚染された被除染物の除染方法。   Natural surfactant cleaning liquid adjustment process, cavitation jet cleaning process using natural surfactant as cleaning liquid, carbonated nanobubble cleaning liquid adjustment process, cavitation jet cleaning process using carbonated nanobubble water, and decontaminated product And a step of classifying the suspension into water (including radioactive substances and fine particles), a step of aggregating and precipitating radioactive substances and fine particles in the suspension water with an agglomeration adsorbing precipitant, and separating the precipitate and the water to be treated; The method for decontamination of a decontaminated material contaminated with a radioactive substance according to claim 1, wherein the water to be treated is reused as cleaning water for decontamination. 前記天然界面活性剤洗浄液の天然界面活性剤濃度は0.01〜0.1%の範囲で作液することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。   3. The removal of a decontaminated material contaminated with a radioactive substance according to claim 1 or 2, wherein the natural surfactant concentration of the natural surfactant cleaning liquid is in the range of 0.01 to 0.1%. Dyeing method. 前記炭酸ナノバブル洗浄液は、ナノバブル発生器のナノバブル水生成量(L/min)に対して二酸化炭素ガスを2.5〜100%の範囲でナノバブル発生器に供給して作液することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。   The carbonic acid nanobubble cleaning liquid is produced by supplying carbon dioxide gas to the nanobubble generator in a range of 2.5 to 100% with respect to the nanobubble water generation amount (L / min) of the nanobubble generator. The decontamination method of the to-be-decontaminated thing contaminated with the radioactive substance of Claim 1 or 2. 前記天然界面活性剤を洗浄液としたキャビテーション噴流式洗浄工程と、前記炭酸ナノバブル水を洗浄液としたキャビテーション噴流式洗浄工程には15〜25MPaの駆動用高圧水を供給することを特徴とする請求項1又は2記載の放射性物質に汚染された被除染物の除染方法。   The high-pressure water for driving of 15 to 25 MPa is supplied to the cavitation jet cleaning process using the natural surfactant as a cleaning liquid and the cavitation jet cleaning process using the carbonated nanobubble water as a cleaning liquid. Or the decontamination method of the to-be-decontaminated material contaminated with the radioactive substance of 2. 前記凝集吸着沈殿剤には、パラクロレラ・バイノス(Parachlorella sp. binos)を乾燥させたバイノスパウダーを含むことを特徴とする請求項2記載の放射性物質に汚染された被除染物の除染方法。   3. The method for decontamination of a decontaminated material contaminated with a radioactive substance according to claim 2, wherein the coagulation adsorbing precipitant contains binos powder obtained by drying Parachlorella sp. Binos. . 前記凝集吸着沈殿剤は、除染後の洗浄廃液に0.1〜0.5g/L添加することを特徴とする請求項2又は6記載の放射性物質に汚染された被除染物の除染方法。   The method for decontamination of a decontaminated object contaminated with a radioactive substance according to claim 2 or 6, wherein the agglomerated adsorbing precipitant is added in an amount of 0.1 to 0.5 g / L to the cleaning waste liquid after decontamination. . 放射性物質に汚染された被除染物の除染システムにおいて、天然界面活性剤洗浄液を調整・貯留する洗浄液貯槽と、天然界面活性剤を洗浄液としてキャビテーション噴流式洗浄する洗浄機と、天然界面活性剤洗浄液および被除染物を回収する回収槽と、炭酸ナノバブル洗浄液を調整・貯留するナノバブル洗浄液貯槽と、炭酸ナノバブル水を洗浄液としてキャビテーション噴流式洗浄する洗浄機と、被除染物と懸濁水(放射性物質および微細粒子を含む)を分級する分級機と、懸濁水を回収する洗浄廃液貯槽と、凝集吸着沈殿剤により懸濁水中の放射性物質および微細粒子を凝集吸着沈殿させて沈殿物と被処理水を分離する懸濁水処理機とで構成されることを特徴とする放射性物質に汚染された被除染物の除染システム。   In a decontamination system for decontaminated materials contaminated with radioactive substances, a cleaning liquid storage tank that adjusts and stores a natural surfactant cleaning liquid, a cleaning machine that uses a natural surfactant as a cleaning liquid and a cavitation jet cleaning, and a natural surfactant cleaning liquid A recovery tank for recovering the decontaminated material, a nanobubble cleaning liquid storage tank for adjusting and storing the carbonic acid nanobubble cleaning liquid, a washing machine for cavitation jet cleaning using carbonic acid nanobubble water as the cleaning liquid, and the decontaminated material and suspended water (radioactive substances and fine water). (Including particles), a washing waste liquid storage tank that collects suspended water, and agglomerated adsorptive precipitants that aggregate and adsorb the radioactive substances and fine particles in the suspended water to separate the precipitate and the water to be treated. A decontamination system for an object to be decontaminated by a radioactive material, comprising a suspension water treatment machine.
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