JP2014001312A - Autohesion pressure-sensitive adhesive tape - Google Patents

Autohesion pressure-sensitive adhesive tape Download PDF

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JP2014001312A
JP2014001312A JP2012137176A JP2012137176A JP2014001312A JP 2014001312 A JP2014001312 A JP 2014001312A JP 2012137176 A JP2012137176 A JP 2012137176A JP 2012137176 A JP2012137176 A JP 2012137176A JP 2014001312 A JP2014001312 A JP 2014001312A
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adhesive
self
pressure
styrene
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JP6013794B2 (en
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Hiroko Mori
裕子 森
Satoyuki Takimoto
智行 瀧本
Masanori Sato
正則 佐藤
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Nichiban Co Ltd
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Nichiban Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide an autohesion pressure-sensitive adhesive tape with which branches, stems, vines, new treetops etc. of plants are bound together.SOLUTION: An autohesion pressure-sensitive adhesive tape 1 includes a pressure-sensitive adhesive, with which autohesion retention characteristics to retain a suspended state produced by suspending a weight 5 on a loop 3 formed by butt-seaming 2 portions of the pressure-sensitive adhesive with each other are sufficiently obtained in an environment of 23°C or even in an environment of 40°C, applied to one side of a tape-shaped substrate. An elastomer of the pressure-sensitive adhesive is produced by mixing 10-80 wt.% of a styrene-isoprene-styrene block polymer of which the styrene content is 14 to 19 wt.% and 20-90 wt.% of a styrene-isoprene-styrene block polymer of which the styrene content is 25 to 50 wt.%.

Description

本発明は自着性粘着テープに関し、特に野菜等の植物や生物、さらに詳しくは、栽培中の葡萄やトマト等の植物の蔓を支柱や棚等に誘引結束するための粘着テープに関する。   The present invention relates to a self-adhesive pressure-sensitive adhesive tape, and more particularly, to a pressure-sensitive adhesive tape for attracting and binding plants and organisms such as vegetables, and more specifically, plant vines such as grapes and tomatoes during cultivation to pillars and shelves.

一般に、りんご、梨、葡萄等の果実や、きゅうり、トマト、茄子等の野菜、花等の鑑賞用植物といった植物を栽培する場合、栽培中に風や自重によって枝や蔓が折れたり傷つくことを防ぐ必要がある。また、植物が成長する方向を調節してバランスよく成長させることによって植物の健全化を図り、収穫し易くすること等も必要である。そのために、植物の蔓や茎や枝などを支柱や棚にプラスチック等で被覆した針金で括り付けて固定することが行われている。
この結束作業自体は単純なものであるが、生育中の短期間のうちに、膨大な量の結束を行う必要があり、非常に労力を伴う仕事であった。
In general, when growing plants such as fruits such as apples, pears and persimmons, vegetables such as cucumbers, tomatoes and eggplants, and ornamental plants such as flowers, branches and vines are broken or damaged by wind and dead weight during cultivation. It is necessary to prevent. In addition, it is necessary to make the plant healthy and to make it easy to harvest by adjusting the direction in which the plant grows and growing it in a balanced manner. For this purpose, plant vines, stems, branches, and the like are fixed by tying them with support wires or shelves covered with plastic or the like.
This bundling operation itself is simple, but it is necessary to perform a huge amount of bundling within a short period of growth, and is a very labor intensive work.

そうしたことから、出願人らは粘着テープを使用した結束方法を提案してきたが、これは粘着テープの粘着剤面同士を合掌貼りにして結束する方法であり、上記のように針金を使用しないため、安全性が高いという特徴がある(特許文献1)。
また、上記のように粘着テープの粘着剤面同士を合掌貼りにするところから、その粘着剤は、その粘着力よりも粘着剤面同士が貼り付く自着力を大きくするように構成されている(特許文献2)
Therefore, the applicants have proposed a bundling method using an adhesive tape, but this is a method of bundling by sticking the adhesive surfaces of the pressure-sensitive adhesive tape together, and as described above, no wire is used. It is characterized by high safety (Patent Document 1).
In addition, since the adhesive surfaces of the adhesive tape are bonded to each other as described above, the adhesive is configured to increase the self-adhesive force to which the adhesive surfaces adhere to each other than the adhesive force ( Patent Document 2)

上記した各種の栽培は、通常は露地で行われるので平均的な温度として常温の23℃程度を基準にして接着性を問題にすればよいが、上記の栽培がビニールハウスなどのハウス内で行われることも多くなっている。ハウス内においては高温になることも多く、こうした高温領域においては平均的な温度として40℃程度を基準にする必要があるが、上記した常温程度で有効なものでも高温領域では満足な結束状態を得ることが難しい。   Since the above-mentioned various cultivations are usually carried out in an open field, the average temperature should be about 23 ° C. at room temperature, but the above-mentioned cultivation is performed in a house such as a plastic house. There are many things that are often seen. In a house, the temperature is often high, and in such a high temperature region, it is necessary to use an average temperature of about 40 ° C. as a standard. Difficult to get.

実開平3−3571号公報Japanese Utility Model Publication No. 3-3571 特開2004−161962号公報JP 2004-161962 A

本発明は、植物の茎、蔓、枝、新梢などを支柱などに結束することができる粘着テープであるが、これによる結束状態を上記した常温(温度:23℃)においても高温(温度:40℃)においても保持することができるものを得ようとするものである。
更には、結束によって植物の成長に悪影響を与えることがなく、確実に結束できると共に、結束作業性にも優れたものを得ようとするものである。
The present invention is an adhesive tape that can bind stems, vines, branches, new treetops, and the like of a plant to a support or the like. The binding state of the tape is high even at the above-described normal temperature (temperature: 23 ° C.). (40 ° C.).
Furthermore, the present invention is intended to obtain a product that can be reliably bundled and has excellent bundling workability without adversely affecting the growth of the plant by the bundling.

本発明は、テープ状の基材の一面に粘着剤を塗布して粘着剤層を形成した自着性粘着テープにおいて、上記粘着剤のエラストマーが、スチレン含有量が14重量%以上であって19重量%以下のスチレン−イソプレン−スチレンブロックポリマーを10重量%〜80重量%と、スチレン含有量が25重量%以上であって50重量%以下のスチレン−イソプレン−スチレンブロックポリマーを20重量%〜90重量%で混合した混合物を含むものである。そして、この自着性粘着テープは、下記(a)及び(b)を同時に満足するように形成したものである。
(a):幅10mm、長さ100mmの自着性粘着テープの両端部の長さ20mmを残し、中央部の60mmの粘着剤部分に長さ60mmの前記自着性粘着テープと同じ自着性粘着テープを貼付して非粘着化したものを試験片とし、この試験片の両端部の長さ20mmの粘着剤の部分同士を合掌貼りにして形成したループに金属製の直径15mmの支持棒を挿通して支持し、重さ1000gの錘を吊下げ、温度23℃、相対湿度50%の条件下に24時間保持した後に錘が落下しなかったものが1/2以上である。
(b):上記(a)に記載したループに、重さ500gの錘を吊下げ、温度40℃、相対湿度75%の条件下に24時間保持した後に錘が落下しなかったものが1/2以上である。
The present invention provides a self-adhesive pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer is formed by applying a pressure-sensitive adhesive to one surface of a tape-like substrate, and the elastomer of the pressure-sensitive adhesive has a styrene content of 14% by weight or more. 10% to 80% by weight of styrene-isoprene-styrene block polymer up to 20% by weight and 20% to 90% of styrene-isoprene-styrene block polymer having a styrene content of 25% by weight or more and up to 50% by weight. It contains a mixture mixed in weight%. And this self-adhesive adhesive tape is formed so that the following (a) and (b) may be satisfied simultaneously.
(A): Self-adhesiveness same as the self-adhesive pressure-sensitive adhesive tape having a length of 60 mm on the pressure-sensitive adhesive portion of 60 mm in the central portion, leaving a length of 20 mm at both ends of the self-adhesive pressure-sensitive adhesive tape having a width of 10 mm and a length of 100 mm. A non-adhesive tape with an adhesive tape attached is used as a test piece, and a metal support rod having a diameter of 15 mm is attached to a loop formed by joining the parts of the adhesive with a length of 20 mm at both ends of the test piece. A weight of 1000 g was suspended by inserting and supporting, and the weight did not fall after being held for 24 hours under conditions of a temperature of 23 ° C. and a relative humidity of 50% is ½ or more.
(B): A weight having a weight of 500 g is suspended from the loop described in the above (a), and the weight does not fall after being held for 24 hours under conditions of a temperature of 40 ° C. and a relative humidity of 75%. 2 or more.

更には、この自着性粘着テープを、対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着力が10.0N/10mm以上に形成するものである。   Furthermore, this self-adhesive pressure-sensitive adhesive tape is formed so that the adhesive strength to SUS is less than 2.0 N / 10 mm, the probe tack is less than 2.0 N / 5 mmφ, and the self-adhesive strength is 10.0 N / 10 mm or more. .

本発明の自着性粘着テープは、この粘着テープの粘着剤面同士を合掌貼りすることにより、植物の枝、茎、蔓、新梢などを支柱、棚などに容易に固定することができ、露地などにおける栽培のように常温環境における場合は勿論のこと、ビニールハウスにおける栽培のように高温環境下においても、結束状態を維持することができるものである。
更には、粘着テープの粘着力は他の被着体に対して低いため、植物の枝、茎、蔓、新梢などを傷めることなく、植物の成長に対して悪影響を与えることが少ない。
The self-adhesive adhesive tape of the present invention can easily fix plant branches, stems, vines, new treetops, etc., to pillars, shelves, etc. by sticking together the adhesive surfaces of this adhesive tape. It is possible to maintain a united state even in a high temperature environment such as cultivation in a greenhouse, as well as in a room temperature environment such as cultivation in an open field.
Furthermore, since the adhesive strength of the adhesive tape is low with respect to other adherends, it does not adversely affect the growth of plants without damaging plant branches, stems, vines, new treetops and the like.

本発明の自着性粘着テープの自着保持性を測定する方法を示す説明図である。It is explanatory drawing which shows the method of measuring the self-adhesion holding property of the self-adhesive adhesive tape of this invention.

本発明における自着性粘着テープの基材には、クラフト紙、クレープ紙、和紙などの繊維状物質で形成された多孔性材料や、ポリオレフィン系樹脂、ポリエステル系樹脂、塩化ビニル系樹脂、ポリイミド系樹脂などで形成したプラスチックフイルムを適宜に使用することができる。   In the base material of the self-adhesive adhesive tape in the present invention, a porous material formed from a fibrous material such as kraft paper, crepe paper, Japanese paper, polyolefin resin, polyester resin, vinyl chloride resin, polyimide system A plastic film formed of a resin or the like can be used as appropriate.

上記多孔性材料を使用する場合、強度、耐候性、剛性などの特性を調整するために、含浸剤、背面処理剤などによって適宜処理を施すようにすることができる。この多孔性材料の坪量、厚みは用途によって適宜に選択されて特に限定されない。   When the porous material is used, it can be appropriately treated with an impregnating agent, a back surface treating agent or the like in order to adjust properties such as strength, weather resistance and rigidity. The basis weight and thickness of the porous material are appropriately selected depending on the application and are not particularly limited.

プラスチックフイルムは、上記したもののほか、生分解性や光分解性のプラスチックフイルムを使用すると環境面から好ましいものとすることができる。また、上記したものを複数組み合わせて使用することもでき、上記プラスチックフイルム同志を、またはプラスチックフイルムと多孔性材料などを積層して使用することもできる。また、必要に応じて、多孔性のプラスチックフイルムを用いることもできる。   In addition to the above-described plastic film, the use of a biodegradable or photodegradable plastic film can be preferable from the viewpoint of the environment. Further, a plurality of the above-mentioned ones can be used in combination, and the above plastic films can be used, or a plastic film and a porous material can be laminated and used. Moreover, a porous plastic film can also be used as needed.

上記プラスチックフイルムには、下記する粘着剤層を形成する粘着剤との密着性を向上させるために、片面又は両面にコロナ処理やプラズマ処理、プライマー処理などの表面処理を施すようにすることもできる。このプラスチックフイルムを使用した基材の坪量は、特に限定されることなく使用することができる。   The plastic film may be subjected to surface treatment such as corona treatment, plasma treatment, and primer treatment on one side or both sides in order to improve adhesion with the pressure-sensitive adhesive forming the pressure-sensitive adhesive layer described below. . The basis weight of the base material using this plastic film can be used without any particular limitation.

上記基材の一面には粘着剤を塗布して粘着剤層を形成する。この粘着剤層を形成する粘着剤のエラストマーとして、次のようなものが使用される。
このエラストマーは、スチレン含有量が14重量%以上であって19重量%以下のスチレン−イソプレン−スチレンブロックポリマー(SIS)である低スチレンポリマー(低スチレンSIS)と、スチレン含有量が25重量%以上であって50重量%以下のスチレン−イソプレン−スチレンブロックポリマー(SIS)である高スチレンポリマー(高スチレンSIS)の混合物からなる。高スチレンポリマーのスチレン含有量は、30重量%以上であって50重量%以下がより好ましい。
An adhesive is applied to one surface of the substrate to form an adhesive layer. The following are used as the elastomer of the pressure-sensitive adhesive forming the pressure-sensitive adhesive layer.
This elastomer has a low styrene polymer (low styrene SIS) which is a styrene-isoprene-styrene block polymer (SIS) having a styrene content of 14% by weight or more and 19% by weight or less, and a styrene content of 25% by weight or more. And consisting of a mixture of high styrene polymer (high styrene SIS) which is 50% by weight or less of styrene-isoprene-styrene block polymer (SIS). The styrene content of the high styrene polymer is 30% by weight or more and more preferably 50% by weight or less.

上記低スチレンポリマーと高スチレンポリマーの混合割合は、低スチレンポリマーを10重量%〜80重量%とし、高スチレンポリマーを20重量%〜90重量%の割合とする。
好ましくは、低スチレンポリマーを20重量%〜70重量%の割合とし、高スチレンポリマーを30重量%〜80重量%の割合とする。
低スチレンポリマーが10重量%以下になると後記する自着保持性が低下するようになり、80重量%を超えた場合にも自着保持性が低下するようになる。
The mixing ratio of the low styrene polymer and the high styrene polymer is 10% to 80% by weight of the low styrene polymer and 20% to 90% by weight of the high styrene polymer.
Preferably, the low styrene polymer is 20 wt% to 70 wt% and the high styrene polymer is 30 wt% to 80 wt%.
When the amount of the low styrene polymer is 10% by weight or less, the self-adhesion retention described later decreases, and when it exceeds 80% by weight, the self-adhesion retention also decreases.

粘着剤としては、上記エラストマーと粘着付与樹脂、充填剤を含有し、必要に応じて、軟化剤、可塑剤、紫外線吸収剤、老化防止剤などの各種添加剤を配合したものが好ましい。
上記粘着付与樹脂としては、ロジン系樹脂,テルペン系樹脂などの天然物及びその誘導体、脂肪族系石油樹脂、脂環族系石油樹脂、芳香族系石油樹脂、クマロンインデン樹脂,スチレン系樹脂,フェノール系樹脂,キシレン樹脂などの合成樹脂を挙げることができる。
この粘着付与樹脂は、エラストマー100重量部に対して、通常、4〜150重量部、好ましくは10〜100重量部、より好ましくは15〜70重量部で使用される。粘着付与樹脂を配合することにより、粘着剤成分に常温での自着力を付与することができ、常温及び高温の自着保持性を得ることに寄与できる。
The pressure-sensitive adhesive preferably contains the above elastomer, a tackifier resin, and a filler, and if necessary, is blended with various additives such as a softener, a plasticizer, an ultraviolet absorber, and an anti-aging agent.
Examples of the tackifying resin include natural products such as rosin resins and terpene resins and derivatives thereof, aliphatic petroleum resins, alicyclic petroleum resins, aromatic petroleum resins, coumarone indene resins, styrene resins, Examples thereof include synthetic resins such as phenolic resins and xylene resins.
This tackifying resin is usually used in an amount of 4 to 150 parts by weight, preferably 10 to 100 parts by weight, and more preferably 15 to 70 parts by weight with respect to 100 parts by weight of the elastomer. By blending the tackifier resin, self-adhesive strength at room temperature can be imparted to the pressure-sensitive adhesive component, which can contribute to obtaining self-adhesion retention at room temperature and high temperature.

充填剤としては、例えば、炭酸カルシウム、亜鉛華(酸化亜鉛)、けい酸アルミニウム、シリカ、タルク、けい藻土、けい砂、軽石粉、スレート粉、雲母粉、アルミニウムゾル、アルミナホワイト、硫酸アルミニウム、硫酸バリウム、リトポン、硫酸カルシウム、二硫化モリブデン、グラファイト、ガラス繊維、ガラス球、単結晶チタン酸カリ、カーボン繊維、活性亜鉛華、炭酸亜鉛、酸化マグネシウム、塩基性炭酸マグネシウム、リサージ、鉛丹、鉛白、水酸化カルシウム、活性化水酸化カルシウム、酸化チタン等が挙げられる。
これらの充填剤の中でも、炭酸カルシウム、亜鉛華、シリカ、酸化チタンなどが好ましい。これらの充填剤を配合すると、粘着剤に適度の凝集性を付与することができる。
Examples of the filler include calcium carbonate, zinc white (zinc oxide), aluminum silicate, silica, talc, diatomaceous earth, silica sand, pumice powder, slate powder, mica powder, aluminum sol, alumina white, aluminum sulfate, Barium sulfate, lithopone, calcium sulfate, molybdenum disulfide, graphite, glass fiber, glass sphere, single crystal potassium titanate, carbon fiber, activated zinc white, zinc carbonate, magnesium oxide, basic magnesium carbonate, resurge, red lead, lead Examples include white, calcium hydroxide, activated calcium hydroxide, and titanium oxide.
Among these fillers, calcium carbonate, zinc white, silica, titanium oxide and the like are preferable. When these fillers are blended, appropriate cohesiveness can be imparted to the pressure-sensitive adhesive.

充填剤の粒子径の平均値は5μm以下であることが好ましい。この場合、平均粒子径が5μmより小さい小粒子径の微粒子に、平均粒子径が7〜125μmの大粒子径の微粒子の若干量を併用したものにすると、凝集力と粘着力を適度な範囲内に調整することが容易になる。なお、自着粘着力と被着体に対する粘着力等のバランスを考慮して、大粒子径の微粒子は上記基材に塗布した粘着剤の厚さの70%から250%の粒径のものが混在しているものを選ぶことが望ましい。   The average particle diameter of the filler is preferably 5 μm or less. In this case, if a small amount of fine particles having an average particle size of smaller than 5 μm and a small amount of large particles having an average particle size of 7 to 125 μm are used in combination, the cohesive strength and adhesive strength are within an appropriate range. Easy to adjust. In consideration of a balance between self-adhesive adhesive strength and adhesive strength to adherend, the fine particles having a large particle size have a particle diameter of 70% to 250% of the thickness of the adhesive applied to the substrate. It is desirable to choose a mix.

上記大粒子径の微粒子としては、有機微粒子、無機微粒子、及びこれらの混合物を使用することができる。有機微粒子としては塩化ビニリデン系,フェノール樹脂系,尿素樹脂系,エポキシ樹脂系などの有機質系マイクロバルーン、ポリスチレン,ポリメチルメタクリレートなどの合成樹脂微粒子、などが代表的なものである。無機微粒子としては、硼ケイ酸ガラス系などの無機質系マイクロバルーン、炭酸カルシウム、シリカなどの無機充填剤などが挙げられる。   As the fine particles having a large particle diameter, organic fine particles, inorganic fine particles, and a mixture thereof can be used. Representative organic fine particles include organic microballoons such as vinylidene chloride, phenol resin, urea resin, and epoxy resin, and synthetic resin fine particles such as polystyrene and polymethyl methacrylate. Examples of the inorganic fine particles include inorganic microballoons such as borosilicate glass and inorganic fillers such as calcium carbonate and silica.

充填剤は、上記エラストマー100重量部に対して、1〜230重量部であり、好ましくは75〜215重量部である。75〜215重量部にすると、後記する対SUS粘着力、プローブタックの粘着力、及び自着力が適当な値を取るようになって、誘引結束作業の妨げや植物の成長に悪影響を与えることが一層少なくなる。また、230重量部以上では自着保持性を得難い傾向となる。
大粒子径の微粒子を配合する場合には、粘着剤全量基準で、好ましくは0.1〜5重量%、より好ましくは0.2〜3重量%、特に好ましくは0.3〜2重量%の範囲にするとよい。
A filler is 1-230 weight part with respect to 100 weight part of said elastomers, Preferably it is 75-215 weight part. When it is 75 to 215 parts by weight, the adhesive strength against SUS, the adhesive strength of the probe tack, and the self-adhesion force to be described later take appropriate values, which may adversely affect the attraction binding work and the plant growth. Even less. Further, if it is 230 parts by weight or more, it tends to be difficult to obtain self-adhesion retention.
When blending fine particles having a large particle size, it is preferably 0.1 to 5% by weight, more preferably 0.2 to 3% by weight, particularly preferably 0.3 to 2% by weight based on the total amount of the pressure-sensitive adhesive. It should be a range.

軟化剤としては、石油系軟化剤、植物系軟化剤、液状ゴム、液状粘着付与樹脂、合成可塑剤などが挙げられる。軟化剤を配合することにより、凝集性と自着性を調整することができる。   Examples of the softener include petroleum softeners, plant softeners, liquid rubber, liquid tackifying resins, and synthetic plasticizers. By blending a softening agent, cohesion and self-adhesion can be adjusted.

これらの軟化剤は、エラストマー成分などとの相溶性を考慮した上で選択使用される。必要に応じて軟化剤を用いる場合には、自着保持性を損なわない範囲内で使用するとよく、エラストマー成分100重量部に対して、通常、0〜200重量部の割合で使用される。栽培時の植物を結束し、誘引するための植物誘引用の自着性粘着テープのように、自着粘着力を高く、結束対象物への粘着力、タックを低くした方が好ましい場合には、軟化剤は使用しないほうが望ましいことも多い。   These softeners are selected and used in consideration of compatibility with elastomer components and the like. When using a softener as needed, it is good to use within the range which does not impair self-adhesion retention property, and it is normally used in the ratio of 0-200 weight part with respect to 100 weight part of elastomer components. When it is preferable to have high self-adhesive adhesive strength, low adhesive strength to the binding object, and low tack, like the self-adhesive adhesive tape of plant invitation quotes for binding and attracting plants during cultivation Often, it is desirable not to use a softener.

紫外線吸収剤としては、サリチル酸誘導体、ベンゾフェノン系化合物、ベンゾトリアゾール系化合物、シアノアクリレート系化合物等がある。紫外線吸収剤を使用する場合には、エラストマー成分100重量部に対して、通常、0.1〜5重量部の割合で添加される。   Examples of ultraviolet absorbers include salicylic acid derivatives, benzophenone compounds, benzotriazole compounds, and cyanoacrylate compounds. When an ultraviolet absorber is used, it is usually added at a ratio of 0.1 to 5 parts by weight with respect to 100 parts by weight of the elastomer component.

老化防止剤としては、ナフチルアミン系化合物、ジフェニルアミン系化合物、p−フェニレンジアミン系化合物、その他のアミン系化合物、アミン化合物混合物、キノリン系化合物、ヒドロキノン誘導体、モノフェノール系化合物、ビスフェノール系化合物、トリスフェノール系化合物、ポリフェノール系化合物、チオビスフェノール系化合物等が挙げられる。老化防止剤の配合割合は、特に限定されないが、エラストマー成分100重量部に対して、通常、0.1〜5重量部、好ましくは0.5〜2重量部である。   Antiaging agents include naphthylamine compounds, diphenylamine compounds, p-phenylenediamine compounds, other amine compounds, amine compound mixtures, quinoline compounds, hydroquinone derivatives, monophenol compounds, bisphenol compounds, trisphenol compounds. Examples thereof include compounds, polyphenol compounds, and thiobisphenol compounds. The blending ratio of the anti-aging agent is not particularly limited, but is usually 0.1 to 5 parts by weight, preferably 0.5 to 2 parts by weight with respect to 100 parts by weight of the elastomer component.

この自着性粘着テープは、対SUS粘着力が2.0N/10mm未満であり、プローブタックが2.0N/5mmφ未満となるように形成すると好ましい。対SUS粘着力が2.0N/10mm以上、プローブタックが2.0N/5mmφ以上であると、結束の対象物によっては粘着テープが付着する傾向が大きくなって、好ましくないことがある。
また、この自着性粘着テープの自着粘着力(自着力)は7.0N/10mm以上にするとよく、好ましくは10.0N/10mm以上にするとよい。10.0N/10mm以上にすると、良好な自着粘着力が得られるようになる。
This self-adhesive pressure-sensitive adhesive tape is preferably formed so that the adhesive strength against SUS is less than 2.0 N / 10 mm and the probe tack is less than 2.0 N / 5 mmφ. If the adhesive strength to SUS is 2.0 N / 10 mm or more and the probe tack is 2.0 N / 5 mmφ or more, the tendency of the adhesive tape to adhere may increase depending on the object to be bound, which may not be preferable.
Further, the self-adhesive adhesive strength (self-adhesive force) of this self-adhesive adhesive tape may be 7.0 N / 10 mm or more, and preferably 10.0 N / 10 mm or more. When it is 10.0 N / 10 mm or more, good self-adhesive adhesive strength can be obtained.

〔実施例1〕
エラストマーとして「低スチレンSIS(スチレン含有量:16重量%、日本ゼオン社製クインタック3433)」80重量部及び「高スチレンSIS−3(スチレン含有量:48重量%、日本ゼオン社製・クインタック3390)」20重量部に、充填剤として「炭酸カルシウム(丸尾カルシウム社製・スーパー#1500)」115重量部、粘着付与樹脂として「脂肪族石油樹脂(日本ゼオン社製・クイントンA−100)」40重量部、「テルペン系樹脂(ヤスハラケミカル社製・YSレジンPX−1150)」10重量部、老化防止剤として「BASF社製・イルガノックス1010」0.65重量部をトルエン/n−ヘキサンの50:50混合溶剤中で溶解混合することによりゴム系粘着剤を得た。
[Example 1]
80 parts by weight of “low styrene SIS (styrene content: 16% by weight, QUINTAC 3433 manufactured by Nippon Zeon Co., Ltd.)” and “high styrene SIS-3 (styrene content: 48% by weight, manufactured by ZEON CORPORATION, QUINTAC) as elastomers 3390) "in 20 parts by weight, 115 parts by weight of" calcium carbonate (manufactured by Maruo Calcium, Super # 1500) "as a filler, and" aliphatic petroleum resin (manufactured by Nippon Zeon, Quinton A-100) "as a tackifying resin. 40 parts by weight, 10 parts by weight of “terpene resin (Yasuhara Chemical Co., Ltd., YS Resin PX-1150)”, and 0.65 part by weight of “BASF Co., Ltd., Irganox 1010” as an anti-aging agent were added to 50 parts of toluene / n-hexane. : A rubber-based pressure-sensitive adhesive was obtained by dissolving and mixing in a mixed solvent.

厚さ43μmのポリプロピレンフィルムにコロナ処理後、プライマー効果を有する印刷処理を行い、その上に粘着剤層の厚みが20μmになるよう塗布して、幅10mmの粘着テープを調製した。   A polypropylene film having a thickness of 43 μm was subjected to a corona treatment and then subjected to a printing process having a primer effect, and applied thereon so that the thickness of the pressure-sensitive adhesive layer was 20 μm to prepare a pressure-sensitive adhesive tape having a width of 10 mm.

〔実施例2〜8、比較例1〜2〕
表1に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Examples 2-8, Comparative Examples 1-2]
An adhesive tape was produced in the same manner as in Example 1 except that the formulation was changed to the formulation shown in Table 1.

〔実施例9〜16、比較例3〜4〕
「高スチレンSIS−3(スチレン含有量:48重量%)」を「高スチレンSIS−2(スチレン含有量:30重量%、日本ゼオン社製・クインタックSL−165)」に替え、各成分の配合割合を表2に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Examples 9 to 16, Comparative Examples 3 to 4]
“High styrene SIS-3 (styrene content: 48% by weight)” was replaced with “high styrene SIS-2 (styrene content: 30% by weight, manufactured by Nippon Zeon Co., Ltd./Quintac SL-165)”. An adhesive tape was produced in the same manner as in Example 1 except that the blending ratio was changed to the blending formulation shown in Table 2.

〔実施例17〜23、比較例5〕
「低スチレンSIS(スチレン含有量:16重量%)」を80重量部から50重量部に、「高スチレンSIS−3(スチレン含有量:48重量%)」20重量部から50重量部に変更し、炭酸カルシウムの配合割合を表3に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Examples 17 to 23, Comparative Example 5]
“Low styrene SIS (styrene content: 16% by weight)” was changed from 80 parts by weight to 50 parts by weight, and “High styrene SIS-3 (styrene content: 48% by weight)” was changed from 20 parts by weight to 50 parts by weight. A pressure-sensitive adhesive tape was produced in the same manner as in Example 1 except that the blending ratio of calcium carbonate was changed to the blending formulation shown in Table 3.

〔実施例24〜31、比較例6〕
「低スチレンSIS(スチレン含有量:16重量%)」を80重量部から50重量部に、「高スチレンSIS−3(スチレン含有量:48重量%)」を「高スチレンSIS−2(スチレン含有量:30重量%)」に替えて20重量部から50重量部に変更し、炭酸カルシウムの配合割合を表4に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Examples 24-31, Comparative Example 6]
“Low styrene SIS (styrene content: 16% by weight)” was changed from 80 parts by weight to 50 parts by weight, and “High styrene SIS-3 (styrene content: 48% by weight)” was changed to “High styrene SIS-2 (styrene content). In the same manner as in Example 1, except that the amount of calcium carbonate was changed from 20 parts by weight to 50 parts by weight, and the blending ratio of calcium carbonate was changed to the blending formulation shown in Table 4. Was made.

〔実施例32、33〕
「高スチレンSIS−3(スチレン含有量:48重量%)」を「高スチレンSIS−1(スチレン含有量:25重量%、日本ゼオン社製・クインタック3460)」に変更し、各成分の配合割合を表5に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Examples 32 and 33]
“High styrene SIS-3 (styrene content: 48% by weight)” was changed to “high styrene SIS-1 (styrene content: 25% by weight, manufactured by Nippon Zeon Co., Ltd./Quintac 3460)”, and each component was blended An adhesive tape was prepared in the same manner as in Example 1 except that the ratio was changed to the formulation shown in Table 5.

〔比較例7,1,3、8〕
エラストマーを「低スチレンSIS(スチレン含有量:16重量%)」100重量部に変更し、炭酸カルシウムの配合割合を表5に示す配合処方に変更したこと以外は、実施例1と同様にして、粘着テープを作製した。
[Comparative Examples 7, 1, 3, 8]
Except that the elastomer was changed to 100 parts by weight of “low styrene SIS (styrene content: 16% by weight)” and the blending ratio of calcium carbonate was changed to the blending formulation shown in Table 5, the same as in Example 1, An adhesive tape was prepared.

(試験)
上記実施例及び比較例の特性、性能を調べるために、以下に示す自着力試験、対SUS粘着力試験、プローブタック試験、自着保持特性の試験(23℃・1000g)、自着保持特性の試験(40℃・500g)を行った。
(test)
In order to investigate the characteristics and performance of the above examples and comparative examples, the following self-adhesion strength test, SUS adhesion test, probe tack test, self-adhesion retention property test (23 ° C./1000 g), self-adhesion retention property The test (40 degreeC * 500g) was done.

〔自着力試験〕
23℃・50%RHの条件下、実施例及び比較例のテープ(幅10mm)を試験片とし、試験片の粘着面を内側として、貼り合わせ長さが100mm以上になるように重ね、幅50mmの2kgのローラーにより、300mm/minの速度で1往復圧着し、30分間放置した。その後、上記試験片をインストロン型引張り試験機に固定し、剥離速度300mm/minでT型剥離し、そのとき得られた剥離力(N/10mm)を測定した。
[Self-adhesion test]
Under the conditions of 23 ° C. and 50% RH, the tapes of the examples and comparative examples (width 10 mm) are used as test pieces, the adhesive surface of the test pieces is used as the inside, and the bonding length is 100 mm or more, and the width is 50 mm. With a 2 kg roller, one reciprocal pressing was performed at a speed of 300 mm / min and left for 30 minutes. Then, the said test piece was fixed to the Instron type | mold tensile testing machine, T-type peeling was carried out with the peeling speed of 300 mm / min, and the peeling force (N / 10mm) obtained at that time was measured.

〔対SUS粘着力試験〕
23℃・50%RHの条件下、実施例及び比較例のテープ(幅10mm)を試験片とし、JIS Z0237に準じて、鏡面仕上げのSUS304鋼板の表面に、試験片を貼付し、幅50mmの1kgのローラーで圧着した後、1分以内に試験板に対して180°の方向に300mm/minで試験片を剥離し、そのとき得られた剥離力(N/10mm)を測定した。
なお、対SUS粘着力において「<0.1」の表記は、測定器の検出限界値以下であったことを示す。
[Vs. SUS adhesion test]
Under the conditions of 23 ° C. and 50% RH, the tape of Example and Comparative Example (width 10 mm) was used as a test piece, and the test piece was attached to the surface of a mirror-finished SUS304 steel plate according to JIS Z0237. After pressure bonding with a 1 kg roller, the test piece was peeled off at 300 mm / min in a direction of 180 ° with respect to the test plate within 1 minute, and the peel force (N / 10 mm) obtained at that time was measured.
In addition, the notation of “<0.1” in SUS adhesive strength indicates that it was below the detection limit value of the measuring instrument.

〔プローブタック試験〕
23℃・50%RHの条件下、実施例及び比較例のテープ(幅10mm)を試験片とし、ASTM D2979に準じて、試験片をウエイトリングにたるみの無いようにはり付け、直径5mmの円柱プローブを試験片の粘着面に0.98±0.001N/cmの荷重を接触速さ10±0.1mm/秒で、1.0±0.01秒間接触させた後、接触速さと同じ速度でプローブを粘着面から垂直方向に引き剥がすのに要する力(N/5mmφ)を測定した。
なお、後記の実施例8及び比較例2において「−」と表示してあるのは、プローブを試験片に接触させた時に、試験片がウエイトリングから剥離したために測定できなかったことを示す。
[Probe tack test]
Under the conditions of 23 ° C. and 50% RH, the tape of Example and Comparative Example (width 10 mm) was used as a test piece, and the test piece was attached to the weight ring so as not to sag in accordance with ASTM D2979, and a cylinder with a diameter of 5 mm. After contacting the probe to the adhesive surface of the test piece with a load of 0.98 ± 0.001 N / cm 2 at a contact speed of 10 ± 0.1 mm / sec for 1.0 ± 0.01 sec, the same as the contact speed The force (N / 5 mmφ) required to peel the probe from the adhesive surface in the vertical direction at a speed was measured.
In Example 8 and Comparative Example 2 described later, “−” indicates that measurement was not possible because the test piece was peeled off the weight ring when the probe was brought into contact with the test piece.

〔自着保持特性の試験(23℃・1000g)〕
幅10mm、長さ100mmの自着性粘着テープの両端部の長さ20mmの粘着剤の部分(2)を残して、中央部の60mmの粘着剤部分に長さ60mmの前記自着性粘着テープと同じ自着性粘着テープを貼付して非粘着化し、自着性粘着テープの試験片(1)とした。図1に示すように、この試験片(1)の両端部の長さ20mmの粘着剤の部分同士を合掌貼りにし、できたループ(3)に直径15mmの金属製の支持棒(5)を挿通して支持し、重さ1000g(1kg)の錘(5)を吊下げ、温度を23℃、相対湿度(RH)を50%とした状態に24時間保持した後に錘の落下状態を観察した。試験片のサンプル数は4個とした。
評価基準 ○ : 錘の落下が見られない。
△ : 落下しなかった錘が4個中2個以上である。
× : 全ての錘が落下した。
[Self-adhesion retention property test (23 ° C., 1000 g)]
The self-adhesive pressure-sensitive adhesive tape having a length of 60 mm is left in the pressure-sensitive adhesive portion having a length of 20 mm and the pressure-sensitive adhesive portion (2) having a length of 20 mm at both ends of the self-adhesive pressure-sensitive adhesive tape having a width of 10 mm and a length of 100 mm. The same self-adhesive pressure-sensitive adhesive tape as above was affixed to make it non-adhesive, and a test piece (1) of the self-adhesive adhesive tape was obtained. As shown in FIG. 1, 20 mm long adhesive portions at both ends of the test piece (1) are bonded to each other, and a metal support bar (5) having a diameter of 15 mm is attached to the loop (3). The weight (5) having a weight of 1000 g (1 kg) was suspended and held at a temperature of 23 ° C. and a relative humidity (RH) of 50% for 24 hours, and then the falling state of the weight was observed. . The number of test specimens was four.
Evaluation criteria ○: No falling of the weight is observed.
Δ: 2 or more of 4 weights that did not fall.
X: All weights dropped.

〔自着保持特性の試験(40℃・500g)〕
上記自着保持特性の試験(23℃・1000g)と同様にした試験片に、重さ500gの錘を吊下げ、温度を40℃、相対湿度(RH)を75%とした状態に24時間保持した後の状態を観察した。試験片のサンプル数は4個とした。
自着保持特性の試験(40℃・500g)の試験条件は、上記した自着保持特性の試験(23℃・1000g)よりも厳しい条件となっている。
評価基準は、上記自着保持特性の試験(23℃・1000g)の場合と同様である。
[Self-adhesion retention property test (40 ° C, 500 g)]
A weight of 500 g is suspended from a test piece similar to the self-adhesion retention property test (23 ° C./1000 g), and maintained at a temperature of 40 ° C. and a relative humidity (RH) of 75% for 24 hours. The state after the observation was observed. The number of test specimens was four.
The test conditions of the self-adhesion retention characteristic test (40 ° C./500 g) are stricter than the self-adhesion retention characteristic test (23 ° C./1000 g).
The evaluation criteria are the same as in the self-adhesion retention property test (23 ° C./1000 g).

〔総合評価〕
上記各種の試験に基づいて総合評価を行った。
総合評価の評価基準は次のとおりである。
○(良) : 自着保持特性の試験(23℃・1000g)及び自着保持特性の試験(40℃・500g)においていずれも「○」の評価を得たもので、更に、粘着特性として対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着が10.0N/10mm以上の条件を満たすもの。
△(可) : 自着保持特性の試験(23℃・1000g)及び自着保持特性の試験(40℃・500g)においていずれも「○」の評価を得たものであるが、粘着特性として対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着が10.0N/10mm以上の条件を満たさないもの。
又は、自着保持特性の試験(23℃・1000g)において「○」の評価を得、自着保持特性の試験(40℃・500g)においては「△」の評価を得たものであって、粘着特性として対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着が10.0N/10mm以上の条件を満たしているもの。
×(不可) : 自着保持特性の試験(40℃・500g)において「×」の評価となったもの。
〔Comprehensive evaluation〕
A comprehensive evaluation was performed based on the above various tests.
The evaluation criteria for comprehensive evaluation are as follows.
○ (good): Both the self-adhesion retention property test (23 ° C./1000 g) and the self-adhesion retention property test (40 ° C./500 g) were evaluated as “◯”. The SUS adhesive strength is less than 2.0 N / 10 mm, the probe tack is less than 2.0 N / 5 mmφ, and the self-adhesive adhesion is 10.0 N / 10 mm or more.
△ (possible): In the self-adhesion holding property test (23 ° C./1000 g) and the self-adhesion holding property test (40 ° C./500 g), both were evaluated as “◯”. Those that do not satisfy the conditions of SUS adhesive strength of less than 2.0 N / 10 mm, probe tack of less than 2.0 N / 5 mmφ, and self-adhesive adhesion of 10.0 N / 10 mm or more.
Or, in the self-adhesion retention property test (23 ° C./1000 g), the evaluation of “◯” was obtained, and in the self-adhesion retention property test (40 ° C./500 g), the evaluation of “Δ” was obtained. The adhesive properties satisfy the conditions that the adhesive strength to SUS is less than 2.0 N / 10 mm, the probe tack is less than 2.0 N / 5 mmφ, and the self-adhesive adhesion is 10.0 N / 10 mm or more.
X (impossible): Evaluation of “x” in the self-adhesion retention property test (40 ° C./500 g).

(結果)
上記各試験の結果及びこれらの試験の結果に基づく総合評価を表1〜表5に記載した。
(result)
Tables 1 to 5 show the results of the above tests and the overall evaluation based on the results of these tests.

(考察)
表1に示されているように、実施例1〜8は、比較例1、2に比較して自着保持特性(23℃・1000g)と自着保持特性(40℃・500g)において好成績が得られており、特に実施例1〜7のものが一層好ましい。
表2に示す実施例9〜16は、比較例3、4に比較して自着保持特性(23℃・1000g)において好成績が得られている。自着保持特性(40℃・500g)において実施例9の成績が若干劣るが実施例10〜16は好成績が得られている。
(Discussion)
As shown in Table 1, Examples 1 to 8 have better results in self-adhesion retention characteristics (23 ° C./1000 g) and self-adhesion retention characteristics (40 ° C./500 g) than Comparative Examples 1 and 2. Especially, the thing of Examples 1-7 is still more preferable.
In Examples 9 to 16 shown in Table 2, favorable results were obtained in the self-adhesion retention characteristics (23 ° C./1000 g) as compared with Comparative Examples 3 and 4. In the self-adhesion retention characteristics (40 ° C./500 g), the results of Example 9 are slightly inferior, but Examples 10 to 16 have good results.

表3に示す実施例17〜23は、比較例5に比べて自着保持特性(40℃・500g)において好成績が得られている。更に、実施例19〜23は、粘着特性(対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着が10.0N/10mm以上)においても優良な評価が得られている。
表4に示す実施例24〜31は、比較例6に比べて、自着保持特性(23℃・1000g)及び自着保持特性(40℃・500g)において好成績が得られている。中でも、実施例26〜31は、上記粘着特性においても好ましい結果が得られている。
In Examples 17 to 23 shown in Table 3, better results were obtained in the self-adhesion retention characteristics (40 ° C./500 g) than in Comparative Example 5. Furthermore, Examples 19 to 23 have excellent evaluation even in adhesive properties (viscosity to SUS is less than 2.0 N / 10 mm, probe tack is less than 2.0 N / 5 mmφ, and self-adhesion is 10.0 N / 10 mm or more). Is obtained.
In Examples 24 to 31 shown in Table 4, the self-adhesion retention characteristics (23 ° C. · 1000 g) and the self-adhesion retention characteristics (40 ° C. · 500 g) are better than those of Comparative Example 6. Among them, Examples 26 to 31 have preferable results in the above-mentioned adhesive properties.

表5の実施例32、33は自着保持特性(40℃・500g)がやや劣っているものの、自着保持特性(23℃・1000g)で良好な結果が得られ、総合評価は「可」の評価が得られている。これに対して、比較例7、1、3、8は、自着保持特性(23℃・1000g)及び自着保持特性(40℃・500g)のいずれにおいても満足な結果が得られていない。   Although Examples 32 and 33 in Table 5 had slightly poor self-adhesion retention characteristics (40 ° C./500 g), good results were obtained with self-adhesion retention characteristics (23 ° C./1000 g), and the overall evaluation was “OK”. Is obtained. On the other hand, Comparative Examples 7, 1, 3, and 8 do not provide satisfactory results in both the self-adhesion holding characteristics (23 ° C. · 1000 g) and the self-adhesion holding characteristics (40 ° C. · 500 g).

Figure 2014001312
Figure 2014001312

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Figure 2014001312
Figure 2014001312

1 試験片(自着性粘着テープ)
2 試験片の合掌張り部分
3 試験片のループ部分
4 支持棒
5 錘
1 Test piece (self-adhesive adhesive tape)
2 Jointed part of specimen 3 Loop part of specimen 4 Support bar 5 Weight

Claims (6)

テープ状の基材の一面に粘着剤を塗布した自着性粘着テープにおいて、該粘着剤のエラストマーが、スチレン含有量が14重量%以上19重量%以下のスチレン−イソプレン−スチレンブロックポリマーを10重量%〜80重量%と、スチレン含有量が25重量%以上50重量%以下のスチレン−イソプレン−スチレンブロックポリマーを20重量%〜90重量%で混合した混合物を含み、下記(a)と(b)を満たすことを特徴とする自着性粘着テープ。
(a):幅10mm、長さ100mmの自着性粘着テープの両端部の長さ20mmを残し、中央部の60mmの粘着剤部分に長さ60mmの前記自着性粘着テープと同じ自着性粘着テープを貼付して非粘着化したものを試験片とし、この試験片の両端部の長さ20mmの粘着剤の部分同士を合掌貼りにして形成したループに金属製の直径15mmの支持棒を挿通して支持し、重さ1000gの錘を吊下げ、温度23℃、相対湿度50%の条件下に24時間保持した後に錘が落下しなかったものが1/2以上である。
(b):上記(a)に記載したループに、重さ500gの錘を吊下げ、温度40℃、相対湿度75%の条件下に24時間保持した後に錘が落下しなかったものが1/2以上である。
In a self-adhesive adhesive tape in which an adhesive is applied to one surface of a tape-like substrate, the elastomer of the adhesive is 10% by weight of a styrene-isoprene-styrene block polymer having a styrene content of 14% by weight to 19% by weight. % To 80% by weight, and a mixture obtained by mixing 20% to 90% by weight of a styrene-isoprene-styrene block polymer having a styrene content of 25% to 50% by weight, the following (a) and (b) A self-adhesive adhesive tape characterized by satisfying
(A): Self-adhesiveness same as the self-adhesive pressure-sensitive adhesive tape having a length of 60 mm on the pressure-sensitive adhesive portion of 60 mm in the central portion, leaving a length of 20 mm at both ends of the self-adhesive pressure-sensitive adhesive tape having a width of 10 mm and a length of 100 mm. A non-adhesive tape with an adhesive tape attached is used as a test piece, and a metal support rod having a diameter of 15 mm is attached to a loop formed by joining the parts of the adhesive with a length of 20 mm at both ends of the test piece. A weight of 1000 g was suspended by inserting and supporting, and the weight did not fall after being held for 24 hours under conditions of a temperature of 23 ° C. and a relative humidity of 50% is ½ or more.
(B): A weight having a weight of 500 g is suspended from the loop described in the above (a), and the weight does not fall after being held for 24 hours under conditions of a temperature of 40 ° C. and a relative humidity of 75%. 2 or more.
上記粘着剤が上記エラストマー100重量部に対し、粘着付与樹脂を4〜150重量部、充填剤を1〜230重量部含むことを特徴とする請求項1に記載の自着性粘着テープ。   The self-adhesive pressure-sensitive adhesive tape according to claim 1, wherein the pressure-sensitive adhesive contains 4 to 150 parts by weight of a tackifier resin and 1 to 230 parts by weight of a filler with respect to 100 parts by weight of the elastomer. 上記充填剤を75〜215重量部含むことを特徴とする請求項2に記載の自着性粘着テープ。   The self-adhesive pressure-sensitive adhesive tape according to claim 2, comprising 75 to 215 parts by weight of the filler. 上記自着性粘着テープは、対SUS粘着力が2.0N/10mm未満、プローブタックが2.0N/5mmφ未満、自着粘着力が10.0N/10mm以上であることを特徴とする請求項1〜3のいずれかに記載の自着性粘着テープ。   The self-adhesive adhesive tape has a SUS adhesive strength of less than 2.0 N / 10 mm, a probe tack of less than 2.0 N / 5 mmφ, and a self-adhesive adhesive force of 10.0 N / 10 mm or more. The self-adhesive pressure-sensitive adhesive tape according to any one of 1 to 3. 上記エラストマーが、スチレン含有量が14重量%以上19重量%以下のスチレン−イソプレン−スチレンブロックポリマーを20重量%〜70重量%と、スチレン含有量が30重量%以上50重量%以下のスチレン−イソプレン−スチレンブロックポリマーを30重量%〜80重量%で混合した混合物を含むことを特徴とする請求項1〜4のいずれかに記載の自着性粘着テープ。   The elastomer comprises a styrene-isoprene-styrene block polymer having a styrene content of 14% by weight to 19% by weight and a styrene-isoprene having a styrene content of 30% by weight to 50% by weight. The self-adhesive pressure-sensitive adhesive tape according to any one of claims 1 to 4, comprising a mixture obtained by mixing 30% to 80% by weight of a styrene block polymer. 上記充填剤は50重量%以上の炭酸カルシウムを含み、かつ軟化剤を配合しないことを特徴とする請求項2〜5のいずれかに記載の植物誘引用の自着性粘着テープ。   The plant-cited self-adhesive pressure-sensitive adhesive tape according to any one of claims 2 to 5, wherein the filler contains 50% by weight or more of calcium carbonate and does not contain a softening agent.
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JP2016044209A (en) * 2014-08-20 2016-04-04 旭化成ケミカルズ株式会社 Composition for autohesive adhesion and autohesive adhesion tape using the same
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JP7359692B2 (en) 2019-12-26 2023-10-11 ニチバン株式会社 Tape roll for attracting plants

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