JPH01263109A - Tackifier composition for surface protecting tacky film - Google Patents
Tackifier composition for surface protecting tacky filmInfo
- Publication number
- JPH01263109A JPH01263109A JP63092496A JP9249688A JPH01263109A JP H01263109 A JPH01263109 A JP H01263109A JP 63092496 A JP63092496 A JP 63092496A JP 9249688 A JP9249688 A JP 9249688A JP H01263109 A JPH01263109 A JP H01263109A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- polymer
- weight
- block
- pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 35
- -1 isocyanate compound Chemical class 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001400 block copolymer Polymers 0.000 claims abstract description 10
- 239000012948 isocyanate Substances 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 5
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000000853 adhesive Substances 0.000 claims description 34
- 230000001070 adhesive effect Effects 0.000 claims description 34
- 239000002313 adhesive film Substances 0.000 claims description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 4
- 239000005977 Ethylene Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000005011 phenolic resin Substances 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 6
- 239000012790 adhesive layer Substances 0.000 description 5
- 238000004873 anchoring Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920002633 Kraton (polymer) Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920005672 polyolefin resin Polymers 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229910000576 Laminated steel Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、金属板、ガラス板、合成樹脂板、ラミネート
鋼板等の板状物品の表面に剥離自在に粘着されて、これ
らの物品表面の傷防止、ゴミ付着防止等のために使用さ
れる表面保護粘着フィルムにお＆）る粘着剤層用として
使用される粘着剤組成物に関するものであり、当該粘着
剤組成物を用いて製造された表面保護粘着フィルムを貼
付して長時間、屋外等に放置した後においても、粘着剤
が板状物品に残ることなく容易に剥離することができる
という効果を有する表面保護粘着フィルム用粘着剤組成
物に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention is applied to a material that is removably adhered to the surface of a plate-shaped article such as a metal plate, a glass plate, a synthetic resin plate, a laminated steel plate, etc. It relates to an adhesive composition used as an adhesive layer in a surface protection adhesive film used for scratch prevention, dust adhesion prevention, etc., and is manufactured using the adhesive composition. An adhesive composition for a surface protection adhesive film that has the effect of being able to be easily peeled off without any adhesive remaining on a plate-shaped article even after the surface protection adhesive film is attached and left outdoors for a long time. Regarding.
従来、比較的長時間放置されても粘着力の経口変化の少
ない、表面保護粘着フィルム用の粘着剤として、Ａ−Ｂ
−Ａ （式中、Ａはスチレン重合体ブロックを、Ｂはエ
チレン、ブチレン共重合体ブロックを示す）で表される
ブロックコポリマーに対して粘着付与樹脂を配合したも
のが知られているが、当該粘着剤は表面保護用フィルム
（即ち、支持体）として使用されるポリエチレン、ポリ
プロピレンフィルム等のオレフィン樹脂フィルム等との
投錨性に劣るため、支持層である表面保護用フィルムと
粘着剤層との間で界面破壊を生じ、糊残りが発生すると
いう問題点がある。Conventionally, A-B has been used as an adhesive for surface protection adhesive films, which shows little change in adhesive strength even if left for a relatively long time.
A block copolymer represented by -A (wherein A represents a styrene polymer block and B represents an ethylene and butylene copolymer block) is blended with a tackifying resin. Adhesives have poor anchoring properties with olefin resin films such as polyethylene and polypropylene films used as surface protection films (i.e., supports), so there is a possibility that the adhesive will not be able to anchor between the surface protection film, which is a support layer, and the adhesive layer. There is a problem in that interfacial destruction occurs and adhesive residue is generated.
この問題点を解決するために、上記粘着剤組成物を共押
出しする方法が知られているが、それを製造するための
設Ｏトま大であり、さらに、支持体である表面保護用フ
ィルムと粘着剤層の金型内部での流動性をコントロール
しなければならないという技術的課題が残されている。In order to solve this problem, a method of coextruding the above-mentioned pressure-sensitive adhesive composition is known, but it requires a large amount of equipment to produce it, and it also requires a surface protection film as a support. However, there remains the technical issue of controlling the fluidity of the adhesive layer inside the mold.
従って、本発明の目的は支持体である表面保護用フィル
ムに対する投錨力に極めて優れた表面保護粘着フィルム
用粘着剤組成物を提供することである。即ち、当該粘着
剤組成物を、たとえばポリエチレン、ポリプロピレン等
のオレフィン樹脂フィルム等に塗布することによって製
造された表面保護粘着フィルムを長期保存しても糊残り
が生じず、容易に剥離することが可能である粘着剤組成
物を提供することである。Therefore, an object of the present invention is to provide a pressure-sensitive adhesive composition for a surface protection pressure-sensitive adhesive film that has extremely excellent anchoring power to a surface protection film that is a support. That is, even if a surface protection adhesive film manufactured by applying the adhesive composition to an olefin resin film such as polyethylene or polypropylene is stored for a long period of time, no adhesive remains and it can be easily peeled off. An object of the present invention is to provide a pressure-sensitive adhesive composition.
〔課題を解決するための手段〕
前記課題は本発明、即ち式Ａ−Ｂ−Ａ （式中、Ａはス
チレン重合体ブロックを、Ｂはエチレン、ブチレン共重
合体ブロックを示す）で表されるブロックコポリマー（
以下、ポリマー（１）ともいう）１００重量部に対して
、Ａ−Ｂ−Ａ （式中、ＡおよびＢは前記と同意義）で
表されるブロックコポリマーをα、β不飽和脂肪酸にて
変成してなるブロックポリマー〔以下、ポリマー（ＩＩ
）ともいう〕５５〜１００重量部および粘着付与性樹脂
０〜１００重量部を含有する組成物の上記各成分の総Ｍ
１００重量部に対して、多価イソシアネート化合物０．
１〜１０重量部を配合してなる表面保護材用粘着剤組成
物によって解決される。[Means for Solving the Problems] The above problems are solved by the present invention, which is represented by the formula A-B-A (wherein A represents a styrene polymer block and B represents an ethylene and butylene copolymer block). Block copolymer (
A block copolymer represented by A-B-A (wherein A and B have the same meanings as above) was modified with α and β unsaturated fatty acids based on 100 parts by weight of polymer (1). [hereinafter referred to as polymer (II)]
)] 55 to 100 parts by weight and 0 to 100 parts by weight of the tackifying resin.
0.0% polyvalent isocyanate compound per 100 parts by weight.
This problem can be solved by a pressure-sensitive adhesive composition for surface protection material containing 1 to 10 parts by weight.
本発明で使用されるポリマー（１）に関してＡは、スチ
レン重合体ブロックであるが、その好ましい重量平均分
子量は２０００〜１０００００程度であり、またその好
ましいガラス転移温度は、２０゛Ｃ以上、好ましくは５
０°Ｃ以上である。Regarding the polymer (1) used in the present invention, A is a styrene polymer block, and its preferable weight average molecular weight is about 2,000 to 100,000, and its preferable glass transition temperature is 20°C or higher, preferably 5
The temperature is 0°C or higher.
本発明で使用されるポリマー（１）に関してＢは、エチ
レンとブチレンとの共重合体ブロックであるが、その好
ましい分子量はｔｏｏｏｏ〜３０００００程度であり、
またその好ましいガラス転移温度は、−２０”Ｃ以下、
好ましくは一１０’Ｃ以下である。Regarding the polymer (1) used in the present invention, B is a copolymer block of ethylene and butylene, and its preferable molecular weight is about toooo to 300,000,
Further, the preferable glass transition temperature is -20"C or less,
Preferably it is -10'C or less.
ポリマー（１）に関してＡおよびＢの好ましい配合重量
比は、Ａ／Ｂ＝５／９５〜５０１５０である。ポリマー
Ａの好ましい例としては、例えば５ｈｅｌｌ化学社製の
クレイトンＧ−１６５０、クレイトンＧ〜１６５２等が
挙げられる。The preferred weight ratio of A and B for polymer (1) is A/B = 5/95 to 50,150. Preferred examples of polymer A include Kraton G-1650 and Kraton G-1652 manufactured by 5hell Chemical Co., Ltd., for example.
本発明においては、ポリマー（１）は式Ａ−Ｂ（式中、
ＡおよびＢは前記と同意義）で表されるブロックコポリ
マー〔以下、ポリマー（［［）ともいう）を含んだ態様
であってもよい、その含量は、ポリマー（Ｉ）１００重
量部に対して、通常５〜５０、好ましくは１０〜４０で
ある。In the present invention, polymer (1) has the formula AB (wherein,
A and B have the same meanings as above) [hereinafter also referred to as polymer ([)] may be included in the block copolymer, the content of which is based on 100 parts by weight of polymer (I) , usually 5 to 50, preferably 10 to 40.
ポリマー（ＩＩＩ）に関してＡとＢの重量比は、Ａ／Ｂ
＝５／９５〜５０１５０であることが好ましい。The weight ratio of A and B for polymer (III) is A/B
It is preferable that it is =5/95-50150.
ポリマー（１）とポリマー（Ｉ［［）との混合物の例と
しては、例えば５ｈｅｌｌ化学社製のクレイトンＧ−１
６５７等が挙げられる。As an example of a mixture of polymer (1) and polymer (I[[), for example, Kraton G-1 manufactured by 5hell Chemical Co., Ltd.
657 etc. are mentioned.
ポリマー（Ｉｔ）に関してα、β不飽和脂肪酸による変
成に使用されるα、β不飽和脂肪酸とじては、炭素数３
〜２３、好ましくは３〜６のモノカルボン酸、ジカルボ
ン酸が好ましく、具体的にはアクリル酸、クロトン酸、
シトラコン酸、イタコン酸、無水マレイン酸等が例示さ
れる。The α, β unsaturated fatty acids used in the modification of the polymer (It) with α, β unsaturated fatty acids have 3 carbon atoms.
-23, preferably 3-6 monocarboxylic acids and dicarboxylic acids, specifically acrylic acid, crotonic acid,
Examples include citraconic acid, itaconic acid, and maleic anhydride.
ポリマー（■）の変成は、通常ポリマー（ｆｆ）をα、
β不飽和脂肪酸と付加せしめることによって行われる。The modification of the polymer (■) is usually carried out by converting the polymer (ff) into α,
This is done by adding β-unsaturated fatty acids.
ポリマー（Ｉｔ）としては、例えばＡ−Ｂ−Ａブロック
ポリマーに対して無水マレイン酸等のα−β−不飽和脂
肪酸無水物を付加した後、加水分解を行うことによって
得られるもの等が例示される。Examples of the polymer (It) include those obtained by adding an α-β-unsaturated fatty acid anhydride such as maleic anhydride to an A-B-A block polymer and then hydrolyzing it. Ru.
ポリマー（ＩＩ）の好ましい例としては、例えば、５ｈ
ｅｌｌ化学社製クレイトンＦＧ−１９０１Ｘ等が挙げら
れる。Preferred examples of polymer (II) include, for example, 5h
Examples include Clayton FG-1901X manufactured by Ell Chemical Co., Ltd.
ポリマー（ｎ）の配合量はポリマー（Ｉ）〔ポリマー（
Ｉ）とポリマー（ＩＩ［）との混合物の場合には両者の
総量３１００重量部に対して５〜１００重量部、好まし
くは１０〜５０重量部である。The blending amount of polymer (n) is as follows: polymer (I) [polymer (
In the case of a mixture of I) and polymer (II[), the amount is 5 to 100 parts by weight, preferably 10 to 50 parts by weight, based on the total amount of 3100 parts by weight of both.
本発明の組成物中には粘着付与性樹脂を配合してもよい
。粘着付与性樹脂としては、目的に応じて種々のものを
用いることができるが、−船釣には、相溶性がよく、粘
着力を向上しうる特性を有するものが使用される。具体
的には、たとえばフェノール樹脂、ロジン、ピネン樹脂
、石油樹脂、スチレン樹脂、クマロン樹脂等が適してい
る。その添加量は、ポリマー（Ｉ）（下リマ−（１）と
ポリマー（ＩＩＩ）との混合物の場合には両者の総量３
１００重量部に対して０〜１００重量部、好ましくは１
０〜６０重量部の範囲である。粘着付与性樹脂が１００
重量部を越えると長期貼付は後の接着力の上昇が著しく
、剥離の際に糊残りを生しやすい。A tackifying resin may be added to the composition of the present invention. Various tackifying resins can be used depending on the purpose, but for boat fishing, those having good compatibility and properties that can improve adhesive strength are used. Specifically, for example, phenol resin, rosin, pinene resin, petroleum resin, styrene resin, coumaron resin, etc. are suitable. In the case of a mixture of polymer (I) (lower polymer (1) and polymer (III), the total amount of both is 3.
0 to 100 parts by weight per 100 parts by weight, preferably 1
The range is 0 to 60 parts by weight. Tackifying resin is 100
If the weight part is exceeded, the adhesive strength after long-term application will increase significantly, and adhesive residue will likely be left when peeled off.
本発明の粘着剤組成物には、上記ポリマー（１）〔ポリ
マー四）とポリマー（ＩＩＩ）との混合物の場合には両
者の総量〕、ポリマー（１１）および粘着付与性樹脂の
総量１００重量部に対して、多価イソシアネート化合物
が０．１〜１０重量部、好ましくは０．３〜５の割合で
配合される。The pressure-sensitive adhesive composition of the present invention contains 100 parts by weight of the above-mentioned polymer (1) [total amount of polymer (4) and polymer (III) in the case of a mixture of both], polymer (11), and tackifying resin. The polyvalent isocyanate compound is blended in an amount of 0.1 to 10 parts by weight, preferably 0.3 to 5 parts by weight.
多価イソシアネート化合物は、２個以上のイソシアネー
ト基を含むものであり、例えば２．４−トルイレジンイ
ソシアナート、４．４″ −ジフェニルメタンジイソシ
アナート、トリイソシアナート、ヘキサメチレンジイソ
シアナート、ナフタリン １．５−ジイソシアナート、
トリメチロールプロパントルイジンジイソシアナートＡ
ｄｄｕｃｔ体等が例示される。Polyvalent isocyanate compounds include two or more isocyanate groups, such as 2,4-toluyredine isocyanate, 4.4''-diphenylmethane diisocyanate, triisocyanate, hexamethylene diisocyanate, naphthalene 1 .5-diisocyanate,
Trimethylolpropane toluidine diisocyanate A
An example is a dduct form.
本発明の接着剤組成物中には、さらに目的に応じて、通
常用いられる各種ゴム、軟化剤、充填剤、紫外線吸収剤
、老化防止剤の如き各種材料を本発明の主旨に反しない
範囲で使用してもよい。Depending on the purpose, the adhesive composition of the present invention may further contain various commonly used materials such as various rubbers, softeners, fillers, ultraviolet absorbers, and anti-aging agents within the scope of the invention. May be used.
本発明の粘着剤組成物は表面保護用フィルムに積層させ
ることによって使用される。表面保護用フィルムとして
は、溶融押出して表面保護粘着フィルムの支持体となり
うる材料にて構成されていることが好ましい。例えばポ
リオレフィン系樹脂フィルム（例えば、ポリエチレン、
ポリプロピレン等）よりなるものが好適である。The adhesive composition of the present invention is used by laminating it on a surface protection film. The surface protection film is preferably made of a material that can be melt-extruded to serve as a support for the surface protection adhesive film. For example, polyolefin resin films (e.g. polyethylene,
A material made of polypropylene (such as polypropylene) is preferred.
表面保護用フィルムは、さらに投錨性を上げるために、
当該フィルムの片面、もしくは両面にコロナ放電処理を
施すことが好ましい。In order to further improve anchoring properties, the surface protection film
It is preferable to subject one or both sides of the film to corona discharge treatment.
本発明の粘着剤組成物を使用して製造された表面保護用
粘着フィルムの各層の厚みは、好ましくは次の通りであ
る。即ち、粘着剤層は、好ましくは２００μｍ以下、よ
り好ましくは５〜５０μｍであり、表面保護用フィルム
層は、３００μｍ以下、好ましくは１０〜１００μｍで
ある。The thickness of each layer of the surface protection adhesive film produced using the adhesive composition of the present invention is preferably as follows. That is, the adhesive layer preferably has a thickness of 200 μm or less, more preferably 5 to 50 μm, and the surface protection film layer has a thickness of 300 μm or less, preferably 10 to 100 μm.
実施例１〜３・比較例１〜２
第１表の粘着剤組成物の項目に示した組成物の２５％ト
ルエン溶液を、第１表の表面保護用フィルム項目に示し
た表面保護用フィルム上に塗布して表面保護用粘着フィ
ルムを製造した。Examples 1 to 3/Comparative Examples 1 to 2 A 25% toluene solution of the composition shown in the adhesive composition section of Table 1 was applied onto the surface protection film shown in the surface protection film section of Table 1. An adhesive film for surface protection was produced by coating the film on the surface of the film.
当該表面保護用粘着フィルムについて、粘着力、６０°
Ｃ×３０日後の糊残り、サンシャインウェザ−メータ２
００時間による糊残りについて試験し、その結果を第１
表に示した。Regarding the adhesive film for surface protection, the adhesive strength is 60°
C x Glue residue after 30 days, Sunshine Weather Meter 2
The adhesive residue after 00 hours was tested and the results were
Shown in the table.
（試験方法）
粘着カニ
５ＵＳ４３０ＢＡ仮に２５ｎｍ幅の表面保護用粘着フィ
ルムを２ｋｇ圧着ローラーにて貼付は試験片とする。こ
の試験片を温度２３゛Ｃ±２゛Ｃ，湿度６５±１５％Ｒ
Ｈに１時間以上放置後、ショツパー式振子型引張り試験
機にて毎分３００＋ｎｍの速度で引張り、１８０°剥離
粘着力を測定する。(Test Method) Adhesive Crab 5US430BA is temporarily attached with a 25 nm wide adhesive film for surface protection as a test piece using a 2 kg pressure roller. This test piece was tested at a temperature of 23°C±2°C and a humidity of 65±15%R.
After being left in H for 1 hour or more, it was pulled at a speed of 300+ nm per minute using a Schopper pendulum type tensile tester to measure the 180° peel adhesive strength.
６０°Ｃ×３０日後の糊残り：
上記試験片を６０°Ｃ±２°Ｃの加熱オーブン中に投入
し、３０日間保存後、常態に２時間以上放置し、約１０
０ｍ／分のスピードで剥離した時、被着体に貼着剤が残
るかどうか判定する。Adhesive residue after 60°C x 30 days: The above test piece was placed in a heating oven at 60°C ± 2°C, and after being stored for 30 days, it was left under normal conditions for more than 2 hours, and the adhesive remained for about 10 days.
It is determined whether the adhesive remains on the adherend when it is peeled off at a speed of 0 m/min.
サンシャインウェザ−メーター２００時間による糊残り
：
上記試験片をサンシャインウェザ−メーターに投入し、
２００時間経過後取り出し、常態に２時゛間以上放置し
、上記と同様の試験を行う。Adhesive residue after 200 hours of Sunshine Weather Meter: Place the above test piece into the Sunshine Weather Meter,
After 200 hours have elapsed, it is taken out, left to stand for at least 2 hours, and then tested in the same way as above.
本発明の表面保護粘着フィルム用粘着剤組成物は、表面
保護用フィルムに対する投錨力に優れており、当該粘着
剤組成物を用いて製造された表面保護用粘着フィルムを
貼付して長刀間高温所、屋外等に放置した後においても
、粘着剤が板状物品に残ることなく容易に剥離すること
ができるという効果を有する。The adhesive composition for a surface protection adhesive film of the present invention has excellent anchoring power for a surface protection film, and the adhesive composition for surface protection produced using the adhesive composition can be attached to a high-temperature place. This has the effect that the adhesive does not remain on the plate-shaped article and can be easily peeled off even after being left outdoors or the like.
また、本発明の表粘着剤組成物は投錨性に優れるため、
当該粘着剤組成物を用いて製造された表面保護用粘着フ
ィルムの貼合せ作業時に誤って接着剤面同士が接着した
場合でも、粘着剤層が脱落することなく剥離することが
できるという効果を有する。In addition, since the surface adhesive composition of the present invention has excellent anchoring properties,
Even if the adhesive surfaces accidentally adhere to each other during lamination of a surface protection adhesive film produced using the adhesive composition, the adhesive layer can be peeled off without falling off. .
Claims (1)
Ｂはエチレン、ブチレン共重合体ブロックを示す）で表
されるブロックコポリマー１００重量部に対して、Ａ−
Ｂ−Ａ（式中、ＡおよびＢは前記と同意義）で表される
ブロックコポリマーをα、β不飽和脂肪酸にて変成して
なるブロックポリマー５〜１００重量部、および粘着付
与性樹脂０〜１００重量部を含有する組成物の上記各成
分の総量１００重量部に対して、多価イソシアネート化
合物０．１〜１０重量部を配合してなる表面保護粘着フ
ィルム用粘着剤組成物。Formula A-B-A (where A is a styrene polymer block,
B indicates an ethylene, butylene copolymer block)
5 to 100 parts by weight of a block polymer obtained by modifying a block copolymer represented by B-A (wherein A and B have the same meanings as above) with α and β unsaturated fatty acids, and 0 to 100 parts by weight of a tackifying resin. An adhesive composition for a surface protection adhesive film, which comprises blending 0.1 to 10 parts by weight of a polyvalent isocyanate compound with respect to 100 parts by weight of the above-mentioned components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63092496A JPH01263109A (en) | 1988-04-14 | 1988-04-14 | Tackifier composition for surface protecting tacky film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63092496A JPH01263109A (en) | 1988-04-14 | 1988-04-14 | Tackifier composition for surface protecting tacky film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01263109A true JPH01263109A (en) | 1989-10-19 |
Family
ID=14055908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63092496A Pending JPH01263109A (en) | 1988-04-14 | 1988-04-14 | Tackifier composition for surface protecting tacky film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01263109A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5308676A (en) * | 1991-09-20 | 1994-05-03 | Shell Oil Company | Torchable roll roofing membrane |
| USH1564H (en) * | 1991-07-09 | 1996-07-02 | Shell Oil Company | Functionalized block copolymers cured with isocyanates |
-
1988
- 1988-04-14 JP JP63092496A patent/JPH01263109A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USH1564H (en) * | 1991-07-09 | 1996-07-02 | Shell Oil Company | Functionalized block copolymers cured with isocyanates |
| US6211292B1 (en) | 1991-07-09 | 2001-04-03 | Shell Oil Company | Functionalized block copolymers cured with isocyanates |
| US5308676A (en) * | 1991-09-20 | 1994-05-03 | Shell Oil Company | Torchable roll roofing membrane |
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