JP2013511963A - Liquid creamer and method for producing them - Google Patents
Liquid creamer and method for producing them Download PDFInfo
- Publication number
- JP2013511963A JP2013511963A JP2012540353A JP2012540353A JP2013511963A JP 2013511963 A JP2013511963 A JP 2013511963A JP 2012540353 A JP2012540353 A JP 2012540353A JP 2012540353 A JP2012540353 A JP 2012540353A JP 2013511963 A JP2013511963 A JP 2013511963A
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- Prior art keywords
- oil
- liquid creamer
- liquid
- emulsifier
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
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- 210000004080 milk Anatomy 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 238000009928 pasteurization Methods 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229940026235 propylene glycol monolaurate Drugs 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 150000003899 tartaric acid esters Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C11/00—Milk substitutes, e.g. coffee whitener compositions
- A23C11/02—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins
- A23C11/04—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins containing non-milk fats but no non-milk proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C11/00—Milk substitutes, e.g. coffee whitener compositions
- A23C11/02—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins
- A23C11/06—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins containing non-milk proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C11/00—Milk substitutes, e.g. coffee whitener compositions
- A23C11/02—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins
- A23C11/08—Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins containing caseinates but no other milk proteins nor milk fats
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/256—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/20—Cream substitutes
- A23L9/22—Cream substitutes containing non-milk fats but no proteins other than milk proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/20—Cream substitutes
- A23L9/24—Cream substitutes containing non-milk fats and non-milk proteins, e.g. eggs or soybeans
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Dispersion Chemistry (AREA)
- Grain Derivatives (AREA)
- Dairy Products (AREA)
Abstract
液体クリーマー及び液体クリーマーの製造方法を提供する。一般的な実施形態において、本開示は、ガム成分、タンパク質、乳化剤系及び油の特定の組み合わせを有する液体クリーマーに関する。乳化剤系は、製品の保存寿命全体にわたって種々の貯蔵条件において相分離を起こさずに、良好な乳化安定性及び扱いやすい粘度を有する液体クリーマーを提供する。液体クリーマーは、飲料に加えた場合に、フェザリング、凝集、沈降分離及び他の相分離の問題を起こさずに、良好な物理化学的安定性を有する。
【選択図】なしA liquid creamer and a method for producing the liquid creamer are provided. In a general embodiment, the present disclosure relates to a liquid creamer having a specific combination of gum ingredients, proteins, emulsifier systems and oils. The emulsifier system provides a liquid creamer with good emulsification stability and manageable viscosity without causing phase separation at various storage conditions throughout the shelf life of the product. Liquid creamers have good physicochemical stability when added to beverages without causing feathering, agglomeration, sedimentation and other phase separation problems.
[Selection figure] None
Description
[0001]本開示は一般に、食品に関する。より詳しくは、本開示は、コーヒー及び茶(tea)などの食品用の液体クリーマーを対象とする。 [0001] The present disclosure relates generally to food products. More particularly, the present disclosure is directed to liquid creamers for food products such as coffee and tea.
[0002]クリーマーは、高温及び低温の飲料、例えば、コーヒー、ココア、茶と共に白色化剤(whitening agent))として広く用いられている。クリーマーは、ミルク及び/又は乳製品クリーム(dairy cream)の代わりに粉末又は粒子状物質、例えば、シリアルと共に使用することも多い。クリーマーは、種々の風味を有することができ、口当たり、こく(body)及びより滑らかな質感を与えることもある。 [0002] Creamers are widely used as whitening agents with hot and cold beverages such as coffee, cocoa, tea. Creamers are often used in conjunction with powdered or particulate material, such as cereals, instead of milk and / or dairy cream. Creamers can have a variety of flavors and may give a mouthfeel, body and a smoother texture.
[0003]クリーマーは液体又は粉末の形態であることができる。粉末の形態は一般に、伝統的な乳製品クリーマーの感じを与えない。粉末クリーマーを使用する別の不利点としては、コーヒーに加えた場合に溶解しにくいこと、及びさらに、飲料が不均質となる可能性を挙げることができる。 [0003] Creamers can be in liquid or powder form. The powder form generally does not give the feeling of a traditional dairy creamer. Another disadvantage of using a powder creamer is that it is difficult to dissolve when added to coffee and, in addition, the beverage can be inhomogeneous.
[0004]新鮮な又は冷蔵された液体の乳製品ホワイトナー(dairy whitener)は通常、良好な口当たりを与える。しかし、このような乳製品ホワイトナーは、乳製品不耐症(dairy intolerance)のある人々の場合には受け入れられない。このような乳製品ホワイトナーは、短期の保存能力のため、使いにくい。さらに、液体乳製品クリーマーは、冷蔵条件下であっても急速に劣化する。 [0004] Fresh or refrigerated liquid dairy whiteners usually give a good mouthfeel. However, such dairy whiteners are not acceptable in the case of people with dairy intolerance. Such dairy whiteners are difficult to use due to their short-term storage capacity. In addition, liquid dairy creamers degrade rapidly even under refrigerated conditions.
[0005]コーヒーホワイトナーとしての非乳製品クリーマー(nondairy creamer)の市場は急速に成長しつつあり、米国はこの種の製品の市場リーダーである。望ましいホワイトナーは、貯蔵期間中は相分離、クリーム分離、ゲル化及び沈降分離を起こさずに保存安定性でなければならず、一定の期間にわたって一定の粘度を保持しなければならない。コーヒー又は茶のような低温又は高温の飲料に加える場合、クリーマーは、急速に溶解し、良好な白色化能を示し、フェザリング及び/又は沈降分離を起こさずに安定であり続け、上質な味を提供することが必要である。 [0005] The market for nondairy creamers as coffee whiteners is growing rapidly and the United States is the market leader for this type of product. Desirable whiteners must be storage stable without storage, phase separation, cream separation, gelation and sedimentation during storage and must maintain a constant viscosity over a period of time. When added to cold or hot beverages such as coffee or tea, creamers dissolve quickly, show good whitening ability, remain stable without causing feathering and / or sedimentation, and have a fine taste It is necessary to provide
[0006]エマルジョン及び懸濁液が熱力学的に安定でないのは、周知である。真の課題は、油及び他の水不溶性物質を含有する液体クリーマー、特に無菌液体クリーマーにおいて、長期貯蔵時間にわたる高温での物理化学的な不安定性の問題を克服することである。例えば、強力な白色化剤である二酸化チタン(「TiO2」)の沈降分離は、白色化能の低下及び貯蔵容器底部の沈降物の白色層による、許容されない外観をもたらす可能性がある。さらに、室温及び高温で貯蔵された液体飲料中のまだ目には見えないクリーム分離が、時間とともに、冷蔵時にボトル内でプラグを生じる可能性がある。他の望ましくない問題としては、液体クリーマーを飲料に、特にコーヒーなどの高温の酸性環境に加えた場合の、フェザリング及び他の種類の飲料不安定化が挙げられる。 [0006] It is well known that emulsions and suspensions are not thermodynamically stable. The real challenge is to overcome the problem of physicochemical instability at high temperatures over long storage times in liquid creamers containing oil and other water-insoluble substances, especially sterile liquid creamers. For example, sedimentation of titanium dioxide (“TiO 2 ”), a strong whitening agent, can result in an unacceptable appearance due to reduced whitening ability and a white layer of sediment at the bottom of the storage vessel. Furthermore, yet invisible cream separation in liquid beverages stored at room temperature and high temperatures can, over time, cause plugs in the bottle when refrigerated. Other undesirable problems include feathering and other types of beverage destabilization when liquid creamers are added to beverages, particularly in hot acidic environments such as coffee.
[0007]前記考察に鑑みて、冷蔵温度又は周囲温度で数ヶ月の貯蔵期間にわたって持続的な扱いやすい粘度及び安定性を有しながら、エマルジョンの破壊及び相分離を起こさない、均質な無菌の保存安定性液体製品を開発することが、課題である。別の主要な課題は、飲料に加えた場合に容易に分散でき、高温及び低温の酸性環境で安定であり、フェザリング、エマルジョンの破壊、脱油、凝集及び沈降分離を起こさない、無菌の保存安定性液体クリーマーを開発することである。 [0007] In view of the above considerations, homogeneous aseptic storage that does not cause emulsion breakage and phase separation while having a manageable viscosity and stability that persists over a storage period of several months at refrigerated or ambient temperatures The challenge is to develop stable liquid products. Another major challenge is aseptic storage that can be easily dispersed when added to beverages, is stable in hot and cold acidic environments, and does not cause feathering, emulsion breaking, deoiling, flocculation and settling separation It is to develop a stable liquid creamer.
[0008]本開示は、食品用の液体クリーマー及びそのような液体クリーマーの製造方法に関する。この液体クリーマーは保存安定性で、無菌であることができる。この液体クリーマーは、高い白色化能及び心地良い口当たりを有することができる。この液体クリーマーは、液体クリーマーの保存寿命全体にわたって種々の貯蔵条件において相分離(例えば、クリーム分離、沈降分離、経時的ゲル化)を起こさずに、扱いやすい粘度において良好な物理化学的性質、特に乳化安定性及び懸濁安定性を保持できる。 [0008] The present disclosure relates to food liquid creamers and methods of making such liquid creamers. This liquid creamer is storage stable and can be sterile. This liquid creamer can have a high whitening ability and a pleasant mouthfeel. This liquid creamer does not undergo phase separation (e.g. cream separation, sedimentation separation, gelation over time) at various storage conditions throughout the shelf life of the liquid creamer, and has good physicochemical properties, particularly at a manageable viscosity Emulsification stability and suspension stability can be maintained.
[0009]一般的な一実施形態において、本開示は、κ−カラギーナンとι−カラギーナンの重量比約1:2〜約1:6のブレンドを含むガム成分、約0.5〜約2.5重量%の範囲のタンパク質、少なくとも2種の乳化剤のブレンドを含む約0.2〜約0.7重量%の範囲の乳化剤系、及び約8〜約20重量%の範囲の油を含む液体クリーマーを開示する。乳化剤系:タンパク質:ガム成分の重量比は、(2〜14):(5〜50):1である。ここでの重量%は、特に断らない限り、液体クリーマーの総重量に基づく。 [0009] In one general embodiment, the present disclosure provides a gum component comprising a blend of kappa-carrageenan and iota-carrageenan in a weight ratio of about 1: 2 to about 1: 6, about 0.5 to about 2.5. A liquid creamer comprising a protein in the range of weight percent, an emulsifier system in the range of about 0.2 to about 0.7 weight percent comprising a blend of at least two emulsifiers, and an oil in the range of about 8 to about 20 weight percent. Disclose. The weight ratio of emulsifier system: protein: gum component is (2-14) :( 5-50): 1. The weight% here is based on the total weight of the liquid creamer unless otherwise specified.
[0010]一実施形態において、ガム成分は、約0.05〜約0.10重量%の範囲である。タンパク質は、カゼイン、カゼイン酸ナトリウム、カゼイン酸カリウム、カゼイン酸カルシウム、大豆タンパク質、エンドウ豆タンパク質、ホエータンパク質又はそれらの組み合わせであることができる。乳化剤は、モノグリセリド、ジグリセリド、モノグリセリドのジアセチル酒石酸エステル、モノグリセリドのコハク酸エステル又はそれらの組み合わせであることができる。 [0010] In one embodiment, the gum component ranges from about 0.05 to about 0.10% by weight. The protein can be casein, sodium caseinate, potassium caseinate, calcium caseinate, soy protein, pea protein, whey protein, or combinations thereof. The emulsifier can be a monoglyceride, a diglyceride, a diacetyl tartaric acid ester of monoglyceride, a succinic acid ester of monoglyceride or a combination thereof.
[0011]一実施形態において、乳化剤は、親水性・親油性バランス値の低い乳化剤などである。あるいは、乳化剤は、親水性・親油性バランス値が中程度の乳化剤であってもよい。 [0011] In one embodiment, the emulsifier is an emulsifier having a low hydrophilic / lipophilic balance value. Alternatively, the emulsifier may be an emulsifier having an intermediate hydrophilic / lipophilic balance value.
[0012]一実施形態において、油は、植物油、例えば、大豆油、ココナッツ油、パーム油、パーム分別油(palm oil franction)、綿実油、キャノーラ油、オリーブ油、ヒマワリ油、高オレイン酸ヒマワリ油、ベニバナ油又はそれらの組み合わせなどである。さらに、一実施形態において、油には、65%以下の飽和脂肪酸及び1%以下のトランス脂肪酸を含む植物油のブレンドが含まれる。 [0012] In one embodiment, the oil is a vegetable oil such as soybean oil, coconut oil, palm oil, palm oil fraction, cottonseed oil, canola oil, olive oil, sunflower oil, high oleic sunflower oil, safflower Oil or a combination thereof. Further, in one embodiment, the oil comprises a blend of vegetable oils containing no more than 65% saturated fatty acids and no more than 1% trans fatty acids.
[0013]一実施形態において、液体クリーマーは緩衝剤を含む。液体クリーマーは、香味料、甘味料、着色剤又はそれらの組み合わせなどの成分を含んでいてもよい。 [0013] In one embodiment, the liquid creamer includes a buffer. Liquid creamers may contain ingredients such as flavorings, sweeteners, colorants, or combinations thereof.
[0014]別の実施形態において、本開示は、安定な液体クリーマーの製造方法を提供する。この方法は、κ−カラギーナンとι−カラギーナンの重量比約1:2〜約1:6のブレンドを含むガム成分、約0.5〜約2.5重量%の範囲のタンパク質、少なくとも2種の低分子量乳化剤のブレンドを含む約0.2〜約0.7重量%の範囲の乳化剤系、及び約8〜約20重量%の範囲の油の組み合わせを水和させて、液体クリーマーを形成するステップと、容器に液体クリーマーを無菌充填するステップとを含む。乳化剤系:タンパク質:ガム成分の重量比は、(2〜14):(5〜50):1である。 [0014] In another embodiment, the present disclosure provides a method for producing a stable liquid creamer. The method comprises a gum component comprising a blend of kappa-carrageenan and iota-carrageenan in a weight ratio of about 1: 2 to about 1: 6, a protein in the range of about 0.5 to about 2.5% by weight, at least two Hydrating a combination of an emulsifier system in the range of about 0.2 to about 0.7% by weight comprising a blend of low molecular weight emulsifiers and an oil in the range of about 8 to about 20% by weight to form a liquid creamer. And aseptically filling the container with a liquid creamer. The weight ratio of emulsifier system: protein: gum component is (2-14) :( 5-50): 1.
[0015]一実施形態において、この方法は、容器に充填するステップの前に、液体クリーマーを熱処理するステップを含む。この方法はまた、容器に充填するステップの前に、液体クリーマーを均質化するステップを含んでいてもよい。 [0015] In one embodiment, the method includes heat treating the liquid creamer prior to filling the container. The method may also include the step of homogenizing the liquid creamer prior to the step of filling the container.
[0016]本開示の利点は、改善された保存安定性液体クリーマーを提供することである。 [0016] An advantage of the present disclosure is to provide an improved shelf stable liquid creamer.
[0017]本開示の別の利点は、高い白色化能を有する液体クリーマーを提供することである。 [0017] Another advantage of the present disclosure is to provide a liquid creamer with high whitening ability.
[0018]本開示のさらに別の利点は、長期貯蔵期間にわたって扱いやすい粘度を保持する液体クリーマーを提供することである。 [0018] Yet another advantage of the present disclosure is to provide a liquid creamer that retains a manageable viscosity over extended storage periods.
[0019]本開示のさらに別の利点は、貯蔵中に及び高温で飲料に加えた場合に脱油、凝集、フェザリング及び/又は沈降分離などの安定性の問題がない、液体クリーマーを提供することである。 [0019] Yet another advantage of the present disclosure is to provide a liquid creamer that is free of stability problems such as deoiling, flocculation, feathering and / or sedimentation separation when added to a beverage during storage and at elevated temperatures. That is.
[0020]本開示の別の利点は、高温で飲料に加えた場合に脱油、凝集、フェザリング及び/又は沈降分離などの安定性の問題がない、液体クリーマーを提供することである。 [0020] Another advantage of the present disclosure is to provide a liquid creamer that is free of stability issues such as deoiling, flocculation, feathering and / or sedimentation when added to beverages at elevated temperatures.
[0021]本開示のさらに別の利点は、良好な口当たり、こく、滑らかな質感及び異臭(off−note)のない良好な風味を有する液体クリーマーを提供することである。 [0021] Yet another advantage of the present disclosure is to provide a liquid creamer having a good mouthfeel, richness, smooth texture and good taste without off-notes.
[0022]さらなる特徴及び利点は、本明細書中に記載してあり、以下の詳細な説明から明らかとなるであろう。 [0022] Additional features and advantages are described herein and will be apparent from the following detailed description.
[0023]本開示は、液体クリーマー及び液体クリーマーの製造方法に関する。この液体クリーマーは、飲料にクリーミング効果を与えるのに十分な量で、任意の適当な飲料に加えることができる。クリーミング効果は、クリーム又は乳製品に関連する品質、例えば、望ましい風味、質感、こく及び/又は色(淡色化又は白色化)を与える。他の実施形態において、液体クリーマーは、安定であり、冷蔵温度(例えば、約4℃)、室温(例えば、約20℃)及び高温(例えば、約30〜38℃)での貯蔵中の相分離の問題(例えば、クリーム分離、プラグ形成、ゲル化、シネレシス、沈降分離など)を克服している。安定な液体クリーマーは、保存寿命安定性、例えば、20℃で少なくとも9ヶ月間、30℃で少なくとも6ヶ月間及び38℃で少なくとも1ヶ月間の保存寿命安定性を有することができる。このような液体クリーマーは一般に、水中油型エマルジョンと称することができ、水性連続相及び油性分散相を有する。 [0023] The present disclosure relates to liquid creamers and methods of manufacturing liquid creamers. This liquid creamer can be added to any suitable beverage in an amount sufficient to provide a creaming effect to the beverage. The creaming effect provides the quality associated with the cream or dairy product, for example the desired flavor, texture, body and / or color (lightening or whitening). In other embodiments, the liquid creamer is stable and phase separated during storage at refrigeration temperature (eg, about 4 ° C.), room temperature (eg, about 20 ° C.) and elevated temperature (eg, about 30-38 ° C.). Problems such as cream separation, plug formation, gelation, syneresis, sedimentation separation, etc. are overcome. A stable liquid creamer can have shelf life stability, for example, shelf life stability of at least 9 months at 20 ° C., at least 6 months at 30 ° C. and at least 1 month at 38 ° C. Such liquid creamers can generally be referred to as oil-in-water emulsions and have an aqueous continuous phase and an oily dispersed phase.
[0024]意外にも、ガム成分、タンパク質、乳化剤系及び油の特定の組み合わせが、特定の範囲及び重量比で、液体クリーマーの物理化学的安定性を著しく改善したことが判明している。例えば、これらの成分の特定の組み合わせは、長期間にわたって種々の貯蔵条件において相分離を起こさずに良好な乳化安定性及び扱いやすい粘度を有する、安定な液体クリーマーを提供する。 [0024] Surprisingly, it has been found that certain combinations of gum ingredients, proteins, emulsifier systems and oils have significantly improved the physicochemical stability of liquid creamers in certain ranges and weight ratios. For example, certain combinations of these components provide a stable liquid creamer that has good emulsion stability and manageable viscosity without phase separation at various storage conditions over a long period of time.
[0025]本明細書中で使用する用語「安定な(安定性)」は、長期間(例えば、少なくとも1ヶ月間)、相分離(例えば、クリーム分離、沈降分離、経時的ゲル化)が最小限である状況又は状態であり続けることを意味する。本開示の実施形態による安定な液体クリーマーは、少なくとも1ヶ月間安定であると認めることでき、一般には、2〜3ヶ月又はそれ以上にわたって安定であり、フェザリング、凝集、沈降分離の問題がない。 [0025] The term "stable" as used herein refers to long term (eg, at least 1 month), minimal phase separation (eg, cream separation, sedimentation separation, gelation over time). It means to remain in a situation or state that is limited. Stable liquid creamers according to embodiments of the present disclosure can be found to be stable for at least one month, and are generally stable for 2-3 months or more, without the problems of feathering, flocculation, and sedimentation separation. .
[0026]本開示の実施形態の安定な液体クリーマーはまた、コーヒーに容易に分散でき、高温及び低温の酸性環境で安定であり、フェザリング、エマルジョンの破壊、脱油、凝集及び沈降分離を起こさない。コーヒー、茶、ココア又は他の液体製品に加える場合には、この液体クリーマーは、高い白色化能、良好な口当たり、十分なこく、滑らかな質感及びさらには、貯蔵期間中に異臭(off flavor note)を発することがない良好な風味を提供できる。この液体クリーマーは、シリアルなどの他の種々の食品と共に、ベリー用のクリームとして、スープ用のクリーマーとして、及び多くの調理用途において使用できる。 [0026] The stable liquid creamer of embodiments of the present disclosure is also easily dispersible in coffee and stable in hot and cold acidic environments, causing feathering, emulsion breakage, deoiling, flocculation and sedimentation separation. Absent. When added to coffee, tea, cocoa or other liquid products, this liquid creamer has a high whitening ability, good mouthfeel, full mouthfeel, smooth texture and even off flavour notes during storage. ) Can be provided. This liquid creamer can be used with a variety of other food products such as cereal, as a cream for berries, as a creamer for soups, and in many cooking applications.
[0027]一般の実施形態において、本開示は、κ−カラギーナンとι−カラギーナンの重量比約1:2〜約1:6のブレンドを含むガム成分、約0.5〜約2.5重量%の範囲のタンパク質、少なくとも2種の乳化剤のブレンドを含む、約0.2〜約0.7重量%の範囲の乳化剤系及び約8〜約20重量%の範囲の油を含む液体クリーマーを提供する。乳化剤系:タンパク質:ガム成分の重量比はそれぞれ、(2〜14):(5〜50):1であることができる。 [0027] In a general embodiment, the present disclosure provides a gum component comprising a blend of kappa-carrageenan and iota-carrageenan in a weight ratio of about 1: 2 to about 1: 6, about 0.5 to about 2.5% by weight. A cream creamer comprising a range of protein, a blend of at least two emulsifiers, an emulsifier system in the range of about 0.2 to about 0.7% by weight and an oil in the range of about 8 to about 20% by weight. . The weight ratio of emulsifier system: protein: gum component can be (2-14) :( 5-50): 1, respectively.
[0028]一実施形態において、ガム成分は、κ−カラギーナンとι−カラギーナンの重量比約1:2.5〜約1:4のブレンドを含む。別の実施形態において、乳化剤系は、少なくとも2種の乳化剤のブレンドを含み、液体クリーマーの約0.3〜約0.6重量%の範囲である。 [0028] In one embodiment, the gum component comprises a blend of kappa-carrageenan and iota-carrageenan in a weight ratio of about 1: 2.5 to about 1: 4. In another embodiment, the emulsifier system comprises a blend of at least two emulsifiers and ranges from about 0.3 to about 0.6% by weight of the liquid creamer.
[0029]一実施形態において、ガム成分は、約0.05〜約0.10重量%の範囲である。タンパク質は、カゼイン、カゼイン酸ナトリウム、カゼイン酸カリウム、カゼイン酸カルシウム、大豆タンパク質、エンドウ豆タンパク質、ホエータンパク質又はそれらの組み合わせであることができる。 [0029] In one embodiment, the gum component ranges from about 0.05 to about 0.10% by weight. The protein can be casein, sodium caseinate, potassium caseinate, calcium caseinate, soy protein, pea protein, whey protein, or combinations thereof.
[0030]乳化剤系は、特定の重量比の少なくとも2種の低分子量の乳化剤の組み合わせを含むことができる。エマルジョンの型は乳化剤によって制御でき、乳化剤は連続相中に可溶でなければならない。安定な水中油型エマルジョンの場合には、典型的には、高い親水性・親油性バランス(「HLB」)値を有する乳化剤が最良の安定性を提供するはずである。しかし、意外なことに、低HLB値を有する低分子量乳化剤と中HLB値を有する低分子量乳化剤との組み合わせが、それらの特定の重量比において、液体クリーマーの最良の乳化安定性を提供することが判明した。 [0030] The emulsifier system may comprise a combination of at least two low molecular weight emulsifiers in a specific weight ratio. The type of emulsion can be controlled by an emulsifier, which must be soluble in the continuous phase. In the case of a stable oil-in-water emulsion, typically an emulsifier with a high hydrophilic / lipophilic balance (“HLB”) value should provide the best stability. Surprisingly, however, the combination of a low molecular weight emulsifier having a low HLB value and a low molecular weight emulsifier having a medium HLB value may provide the best emulsification stability of the liquid creamer at their particular weight ratio. found.
[0031]親水性及び親油性は乳化剤間で異なり、親水性と親油性のバランスをHLB値と称する。HLB値は、分子の種々の領域の親水性値又は親油性値を算出することによって求める。種々の参考文献が、HLB値について記載している。例は、Griffin WC:「Classification of Surface−Active Agents by ‘HLB’」、Journal of the Society of Cosmetic Chemists 1(1949):311、又はGriffin WC:「Calculation of HLB Values of Non−Ionic Surfactants」、Journal of the Society of Cosmetic Chemists 5(1954):259であり、これらを参照することによって本明細書中に組み入れる。乳化剤のHLB値は典型的には0〜20の範囲である。 [0031] Hydrophilicity and lipophilicity differ between emulsifiers, and the balance between hydrophilicity and lipophilicity is referred to as the HLB value. The HLB value is determined by calculating the hydrophilicity value or lipophilicity value of various regions of the molecule. Various references describe HLB values. Examples are: Griffin WC: “Classification of Surface-Active Agents by 'HLB'”, Journal of the Society of Cosmetic Chems 1 (1949), 311, or Gulfin WC: “Classic of Surface-Active Agents by 'HLB'”, Journal of the Society of Co. of the Society of Cosmetic Chemists 5 (1954): 259, which are incorporated herein by reference. The HLB value of the emulsifier is typically in the range of 0-20.
[0032]低HLB値は、約1〜約5の範囲である。中HLB値は、約5〜約10の範囲である。低HLB値を有する低分子量乳化剤としては、モノグリセリド、ジグリセリド、アセチル化モノグリセリド、ソルビタントリオレエート、グリセロールジオレエート、ソルビタントリステアレート、プロピレングリコールモノステアレート、グリセロールモノオレエート及びモノステアレートを、単独で又は組み合わせとして挙げることができるが、これらに限定するものではない。中HLB値を有する低分子量乳化剤としては、ソルビタンモノオレエート、プロピレングリコールモノラウレート、ソルビタンモノステアレート、カルシウムステアロキシル−2−ラクチレート、グリセロールソルビタンモノパルミテート、大豆レシチン及びモノグリセリドのジアセチル化酒石酸エステルを、単独で又は組み合わせとして挙げることができるが、これらに限定するものではない。 [0032] Low HLB values range from about 1 to about 5. Medium HLB values range from about 5 to about 10. Low molecular weight emulsifiers having low HLB values include monoglycerides, diglycerides, acetylated monoglycerides, sorbitan trioleate, glycerol dioleate, sorbitan tristearate, propylene glycol monostearate, glycerol monooleate and monostearate alone However, the present invention is not limited to these examples. Low molecular weight emulsifiers with medium HLB values include sorbitan monooleate, propylene glycol monolaurate, sorbitan monostearate, calcium stearoxyl-2-lactyrate, glycerol sorbitan monopalmitate, soy lecithin and monoacetylated tartaric acid Esters may be mentioned alone or in combination, but are not limited thereto.
[0033]一実施形態において、乳化剤は、モノグリセリド(「MG」)、ジグリセリド(「DG」)、モノグリセリドのジアセチル酒石酸エステル(「TMG」)又は特定の低HLB値若しくは中HLB値を有するそれらの組み合わせである。乳化剤の特定の重量比が、優れた安定性を達成することが、さらに判明した。一実施形態において、MBとDGの重量比はそれぞれ、約7:1〜約9.5:1であることができる。別の実施形態において、MGとTMGの重量比はそれぞれ、約1:2.5〜約1:4.5であることができる。 [0033] In one embodiment, the emulsifier is a monoglyceride ("MG"), diglyceride ("DG"), diacetyl tartaric acid ester of monoglyceride ("TMG") or a combination thereof having a specific low or medium HLB value. It is. It has further been found that certain weight ratios of emulsifiers achieve excellent stability. In one embodiment, the weight ratio of MB and DG can each be about 7: 1 to about 9.5: 1. In another embodiment, the weight ratio of MG and TMG can each be about 1: 2.5 to about 1: 4.5.
[0034]一実施形態において、油は、1種又は複数の植物油を含む。油は、クリーム性(creaminess)と口当たりをクリーマーに与えることができる。油は、クリーマーの白色化効果に関与することもできる。1種又は複数の植物油としては、部分水素化油又は完全水素化油を、単独で又は組み合わせとして挙げることができる。例えば、植物油としては、大豆油、ココナッツ油、パーム油、パーム分別油、綿実油、カノーラ油、オリーブ油、ヒマワリ油、ベニハナ油又はそれらの組み合わせを挙げることができるが、これらに限定するものではない。ヒマワリ油は、高オレイン酸ヒマワリ油であってもよい。油は、任意の適当な量及び方法で混合して、最大の酸化安定性を確実にできる。例えば、油は、65%以下の飽和脂肪酸を含む植物油のブレンドなどであることができる。一実施形態において、植物油のブレンドは、1%以下のトランス脂肪酸を含む。 [0034] In one embodiment, the oil comprises one or more vegetable oils. Oils can provide creamers with creaminess and mouthfeel. The oil can also contribute to the whitening effect of the creamer. One or more vegetable oils may include partially or fully hydrogenated oils, either alone or in combination. For example, the vegetable oil can include, but is not limited to, soybean oil, coconut oil, palm oil, palm fractionation oil, cottonseed oil, canola oil, olive oil, sunflower oil, safflower oil, or combinations thereof. The sunflower oil may be a high oleic sunflower oil. The oil can be mixed in any suitable amount and manner to ensure maximum oxidative stability. For example, the oil can be a blend of vegetable oils containing up to 65% saturated fatty acids. In one embodiment, the vegetable oil blend contains no more than 1% trans fatty acids.
[0035]油は、エマルジョンの分散相の主成分である。一実施形態において、油滴の平均直径は0.6ミクロン未満である。好ましくは、油滴は、約0.25ミクロン〜0.45ミクロンの範囲の直径を有する。この範囲の粒径(particle size)のエマルジョンの油滴が、最適の白色化効果を生じる。 [0035] Oil is the major component of the dispersed phase of the emulsion. In one embodiment, the average diameter of the oil droplets is less than 0.6 microns. Preferably, the oil droplets have a diameter in the range of about 0.25 microns to 0.45 microns. Oil droplets of an emulsion with a particle size in this range produce an optimal whitening effect.
[0036]一実施形態において、液体クリーマーは、セルロースを含まない。例えば、液体クリーマーは、微結晶セルロース及びカルボキシメチルセルロースなどのセルロース成分を用いずに製造できる。 [0036] In one embodiment, the liquid creamer does not include cellulose. For example, liquid creamers can be produced without the use of cellulose components such as microcrystalline cellulose and carboxymethylcellulose.
[0037]一実施形態において、液体クリーマーは緩衝剤を含む。緩衝剤は、コーヒーなどの高温の酸性環境中への添加時に、クリーマーの不所望なクリーム分離又は沈殿を防止できる。緩衝剤は、例えば、一リン酸塩、二リン酸塩、炭酸ナトリウム(sodium monocarbonate)及び炭酸水素ナトリウム、炭酸カリウム(potassium monocarbonate)及び炭酸水素カリウム又はそれらの組み合わせであることができる。より詳しくは、適当な緩衝剤の非限定的な例は、塩、例えば、リン酸カリウム、リン酸水素二カリウム、リン酸二水素カリウム、炭酸水素ナトリウム、炭酸水素ナトリウム、クエン酸ナトリウム、リン酸ナトリウム、リン酸水素二ナトリウム、リン二水素ナトリウムム及びトリポリリン酸ナトリウムである。緩衝剤は、液体クリーマーの総重量に基づき、約0.5〜約1%の量に存在できる。 [0037] In one embodiment, the liquid creamer includes a buffer. The buffer can prevent unwanted cream separation or precipitation of the creamer when added to a hot acidic environment such as coffee. The buffering agent can be, for example, monophosphate, diphosphate, sodium carbonate and sodium bicarbonate, potassium carbonate and potassium bicarbonate, or combinations thereof. More particularly, non-limiting examples of suitable buffering agents include salts such as potassium phosphate, dipotassium hydrogen phosphate, potassium dihydrogen phosphate, sodium bicarbonate, sodium bicarbonate, sodium citrate, phosphoric acid. Sodium, disodium hydrogen phosphate, sodium dihydrogen phosphate and sodium tripolyphosphate. The buffer may be present in an amount of about 0.5 to about 1%, based on the total weight of the liquid creamer.
[0038]一実施形態において、液体クリーマーは、液体クリーマーを添加する水性媒体をさらに白色化するのに十分な量で白色化剤を含んでいてもよい。例えば、白色化剤はTiO2であってもよく、TiO2は液体クリーマーの重量に基づき、約0.1〜約1重量%の量で存在できる。TiO2は、約0.1〜約0.7ミクロンの範囲の粒径を有することができ、好ましい実施形態は0.4ミクロンの粒径を有する。TiO2を補足的なホワイトナーとして用いる場合には、TiO2は、液体クリーマーの保存寿命全体にわたって完全に分散した状態に保持できる。炭酸カルシウム、硫酸カルシウム及び酸化アルミニウムなどの他の適当な白色化剤を使用してもよい。 [0038] In one embodiment, the liquid creamer may include a whitening agent in an amount sufficient to further whiten the aqueous medium to which the liquid creamer is added. For example, whitening agents may be a TiO 2, TiO 2, based on the weight of the liquid creamer, it can be present in an amount of from about 0.1 to about 1 wt%. The TiO 2 can have a particle size in the range of about 0.1 to about 0.7 microns, with a preferred embodiment having a particle size of 0.4 microns. When TiO 2 is used as a supplemental whitener, the TiO 2 can be kept fully dispersed throughout the shelf life of the liquid creamer. Other suitable whitening agents such as calcium carbonate, calcium sulfate and aluminum oxide may be used.
[0039]別の実施形態において、白色化剤の粒子径(particulate size)は、0.3〜0.5ミクロンの範囲である。白色化剤の最適粒子径は、光散乱が最も濃い白色を発する場合に得られる。白色化剤の最適粒子径は、考慮する波長に関係し、全可視スペクトルについては、最適粒子径は平均波長の1/2又は約0.30ミクロンであろう。白色化剤の粒子径が小さいほど液体クリーマー自体は青味がかり、白色化剤の粒子径が大きいほど白色化力が低下していくと予想できる。平均約0.30ミクロンの粒径の使用は、少なくとも2つの理由で有益なはずである。白色化力の増加は、同じ最終的な色に必要な白色化成分の減少につながり、コスト削減を可能にする。粒子は小さいほど懸濁が容易であり、懸濁状態が保持される。一般的に言えば、懸濁粒子は、沈降傾向をもたらす重力に関して、ストークスの法則の終端速度によって支配される。しかし、粒径約2.0ミクロン未満では、他の力がかなり大きくなり、それが沈降又は懸濁も制御する。粒径2.0ミクロン未満では、ブラウン運動が支配的であり、粒径の減少につれて、重力が次第に重要性を失っていき、その結果、小粒子の懸濁に有利となり、沈降もそれほど起こらないことは、よく知られている。 [0039] In another embodiment, the particle size of the whitening agent ranges from 0.3 to 0.5 microns. The optimum particle size of the whitening agent is obtained when a white color with the strongest light scattering is emitted. The optimum particle size of the whitening agent is related to the wavelength considered, and for the entire visible spectrum, the optimum particle size will be 1/2 the average wavelength or about 0.30 microns. It can be expected that the liquid creamer itself becomes bluish as the particle size of the whitening agent decreases, and that the whitening power decreases as the particle size of the whitening agent increases. The use of an average particle size of about 0.30 microns should be beneficial for at least two reasons. An increase in whitening power leads to a reduction in whitening components required for the same final color, enabling cost savings. The smaller the particle, the easier it is to suspend and the suspended state is maintained. Generally speaking, suspended particles are governed by the Stokes Law termination velocity with respect to the gravity that causes the settling tendency. However, below a particle size of less than about 2.0 microns, other forces are quite large, which also controls sedimentation or suspension. Below the 2.0 micron particle size, the Brownian motion is dominant, and as the particle size decreases, gravity gradually loses its importance, resulting in favor of small particle suspension and less sedimentation. That is well known.
[0040]液体クリーマーは、香味料、甘味料、着色剤又はそれらの組み合わせなどの1種又は複数の成分を含むこともできる。甘味料としては、例えば、スクロース、フルクトース、デキストロース、マルトース、デキストリン、レブロース、タガトース、ガラクトース、コーンシロップ固体及び他の天然甘味料又は人工甘味料を挙げることができる。シュガーレス甘味料としては、糖アルコール、例えば、マルチトール、キシリトール、ソルビトール、エリスリトール、マンニトール、イソマルト、ラクチトール、水素化澱粉加水分解物などを、単独で又は組み合わせとして挙げることができるが、これらに限定するものではない。 [0040] The liquid creamer may also include one or more ingredients such as flavorings, sweeteners, colorants, or combinations thereof. Sweeteners can include, for example, sucrose, fructose, dextrose, maltose, dextrin, levulose, tagatose, galactose, corn syrup solids and other natural or artificial sweeteners. Sugarless sweeteners can include, but are not limited to, sugar alcohols such as maltitol, xylitol, sorbitol, erythritol, mannitol, isomalt, lactitol, hydrogenated starch hydrolysates, and the like. Not what you want.
[0041]香味料、甘味料及び着色剤の使用レベルは大きく変化し、甘味料の強さ、目的とする、製品の甘味度、使用する香味料のレベル及び種類並びにコストの事情によって異なるであろう。糖及び/又はシュガーレス甘味料の組み合わせを、液体クリーマー中に使用してもよい。一実施形態において、甘味料は、液体クリーマー中に約20〜約50重量%の範囲の濃度で存在する。別の実施形態において、甘味料は、約25〜約35重量%の範囲である。 [0041] The use levels of flavors, sweeteners and colorants vary widely and depend on the strength of the sweetener, the intended sweetness of the product, the level and type of flavoring used and the cost circumstances. Let's go. A combination of sugar and / or sugarless sweetener may be used in the liquid creamer. In one embodiment, the sweetener is present in the liquid creamer at a concentration ranging from about 20 to about 50% by weight. In another embodiment, the sweetener ranges from about 25 to about 35% by weight.
[0042]別の実施形態において、本開示は、安定な液体クリーマーの製造方法を提供する。
有利には、他の実施形態において、安定な液体クリーマーは、20℃で少なくとも9ヶ月間、30℃で少なくとも3ヶ月間及び38℃で少なくとも1ヶ月間、望ましい性質を低下させることなく、物理化学的安定性を有することができる。
[0042] In another embodiment, the present disclosure provides a method for producing a stable liquid creamer.
Advantageously, in other embodiments, the stable liquid creamer is a physicochemical compound that does not degrade desirable properties at 20 ° C. for at least 9 months, 30 ° C. for at least 3 months, and 38 ° C. for at least 1 month. Stability.
[0043]この方法は、κ−カラギーナンとι−カラギーナンの重量比約1:2〜約1:6のブレンドを含むガム成分、約0.5〜約2.5重量%の範囲のタンパク質、少なくとも2種の低分子量乳化剤のブレンドを含む、約0.2〜約0.7重量%の範囲の乳化剤系及び約8〜約20重量%の範囲の油の組み合わせを水和させて、液体クリーマーを形成するステップと、液体クリーマーを均質化するステップと、容器に液体クリーマーを無菌充填するステップとを含む。水和は、水又は任意の他の適当な液体を用いて実施できる。乳化剤系:タンパク質:ガム成分の重量比はそれぞれ、(2〜14):(5〜50):1であることができる。 [0043] The method comprises a gum component comprising a blend of κ-carrageenan and ι-carrageenan in a weight ratio of about 1: 2 to about 1: 6, a protein in the range of about 0.5 to about 2.5% by weight, at least Hydrating a combination of an emulsifier system in the range of about 0.2 to about 0.7% by weight and an oil in the range of about 8 to about 20% by weight comprising a blend of two low molecular weight emulsifiers to form a liquid creamer Forming, homogenizing the liquid creamer, and aseptically filling the container with the liquid creamer. Hydration can be performed using water or any other suitable liquid. The weight ratio of emulsifier system: protein: gum component can be (2-14) :( 5-50): 1, respectively.
[0044]ガム、乳化剤、タンパク質、1種又は複数の緩衝剤、1種又は複数の甘味料及び1種又は複数の香味料の水中での水和を、撹拌しながら融解油脂を添加して実施し、続いて熱処理、均質化、冷却及び無菌条件下での無菌容器への充填を行うことができる。無菌熱処理は、直接的又は間接的な超高温(「UHT」)法を使用できる。UHT法は、当業界で知られている。UHT法の例には、UHT殺菌及びUHT低温殺菌が含まれる。 [0044] Hydration of gums, emulsifiers, proteins, one or more buffering agents, one or more sweeteners and one or more flavorings in water is performed with the addition of melted fats and oils with stirring. Subsequently, heat treatment, homogenization, cooling and filling into sterile containers under aseptic conditions can be performed. Aseptic heat treatment can use direct or indirect ultra high temperature ("UHT") methods. The UHT method is known in the art. Examples of UHT methods include UHT sterilization and UHT pasteurization.
[0045]直接的な熱処理は、エマルジョン中への水蒸気(steam water)の注入によって実施する。この場合には、フラッシュ蒸発による過剰な水の除去が必要なことがある。間接的な熱処理は、熱伝達界面をエマルジョンと接触させて実施する。均質化は、熱処理の前及び/又は後に実施できるであろう。エマルジョン中における熱伝達を改善することによって熱処理を改善するために、熱処理の前に均質化を行うことが魅力的な場合がある。熱処理後の均質化の実施は通常、エマルジョン中の油滴が確実に望ましい寸法を有するようにする。無菌充填は種々の出版物、例えば、L,Grimmによる論文、「Beverage Aseptic Cold Filling」(Fruit Processing, July 1998、262〜265頁)、R.Nicolasによる論文、「Aseptic Filling of UHT Dairy Products in HDPE Bottles」(Food Tech. Europe、March/April 1995、52〜58頁)、又は米国特許第6,536,188号(Taggart)に記載されており、これらを参照することによって本明細書中に組み入れる。 [0045] The direct heat treatment is carried out by injection of steam water into the emulsion. In this case, excess water may need to be removed by flash evaporation. Indirect heat treatment is performed with the heat transfer interface in contact with the emulsion. Homogenization could be performed before and / or after heat treatment. In order to improve heat treatment by improving heat transfer in the emulsion, it may be attractive to perform homogenization prior to heat treatment. Performing homogenization after heat treatment usually ensures that the oil droplets in the emulsion have the desired dimensions. Aseptic filling has been described in various publications, for example, the paper by L, Grimm, “Beverage Aseptic Cold Filling” (Fruit Processing, July 1998, pp. 262-265). Published by Nicolas, described in “Aeptic Filling of UHT Daily Products in HDPE Bottles” (Food Tech. Europe, March / April 1995, pages 52-58), or US Pat. No. 6,536,188t. Which are hereby incorporated by reference.
[0046]無菌液体クリーマーは、飲料に加えると、良好な口当たり、及びこく、滑らかな質感、並びに悪臭のない心地良い味を有する、物理的に安定な均質の白色化ドリンクを生じる。液体クリーマーの使用は、コーヒーへの適用にのみ限定しない。例えば、クリーマーは、他の飲料、例えば、茶若しくはココアにも使用でき、又はシリアル若しくはベリーと共に、スープ用クリーマーとして、及び多くの調理用途においても使用できる。 [0046] Sterile liquid creamers, when added to beverages, yield a physically stable, homogeneous whitened drink with a good mouthfeel and a rich, smooth texture and a pleasant taste without odor. The use of liquid creamers is not limited to coffee applications. For example, creamers can be used in other beverages, such as tea or cocoa, or as a soup creamer with cereals or berries, and in many cooking applications.
[0047]以下の例は、限定ではなく実例として、本開示の種々の実施形態の説明に役立つ。
例1
[0047] The following examples serve to illustrate various embodiments of the present disclosure by way of illustration and not limitation.
Example 1
[0048]スクロース500gとκーカラギーナン20g及びι−カラギーナン50gとを混ぜ合わせることによって、カラギーナンとスクロースとのドライブレンドを調製した。タンク中で高撹拌下において、約75℃の熱水58kgにドライブレンドを加えた。次いで、リン酸水素二カリウム400gを、連続撹拌下でタンクに加えた。 [0048] A dry blend of carrageenan and sucrose was prepared by combining 500 g of sucrose with 20 g of κ-carrageenan and 50 g of ι-carrageenan. The dry blend was added to 58 kg of hot water at about 75 ° C. under high stirring in a tank. Then 400 g of dipotassium hydrogen phosphate was added to the tank under continuous stirring.
[0049]次に、カゼイン酸ナトリウム900g、二酸化チタン300g、香味料330g及びスクロース2.5kgを混ぜ合わせることによって、ドライブレンドを調製した。ドライブレンドを、高撹拌下でタンクに加えた。約10分間の混合後、乳化剤(Dimodan 100g及びPanodan 300g)を、連続高撹拌下でタンクに加えた。さらに、高撹拌下で約60℃の融解油8.4kgを加え、続いてスクロース27kgを加えた。少量の追加の水を加えて、総生成物重量を100kgに調整した。 [0049] Next, a dry blend was prepared by combining 900 g sodium caseinate, 300 g titanium dioxide, 330 g flavor, and 2.5 kg sucrose. The dry blend was added to the tank under high agitation. After about 10 minutes of mixing, emulsifiers (Dimodan 100 g and Panodane 300 g) were added to the tank under continuous high agitation. Further, 8.4 kg of melted oil at about 60 ° C. was added under high stirring, followed by 27 kg of sucrose. A small amount of additional water was added to adjust the total product weight to 100 kg.
[0050]得られた液体を予熱し、143℃で5秒間UHT処理し、180/40バールで均質化し、冷却し、液体クリーマーをボトルに無菌充填した。液体クリーマーは、任意の無菌容器、例えば、ジャー、ジャグ又はパウチ中に無菌充填してもよい。 [0050] The resulting liquid was preheated, UHT treated at 143 ° C. for 5 seconds, homogenized at 180/40 bar, cooled, and the liquid creamer was aseptically filled into bottles. The liquid creamer may be aseptically filled into any sterile container, such as a jar, jug or pouch.
[0051]液体クリーマーを含有する3セットのボトルを、下記条件下で貯蔵した:
−38℃で1ヶ月
−30℃で3ヶ月
−室温(約20℃)で9ヶ月。
[0051] Three sets of bottles containing liquid creamers were stored under the following conditions:
-1 month at -38 ° C-3 months at 30 ° C-9 months at room temperature (about 20 ° C).
[0052]クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。貯蔵中に、相分離(クリーム分離、脱油、マーブリングなど)、ゲル化、沈降分離及び実質的な粘度変化は認められなかった。 [0052] The physicochemical stability and sensory profile of coffee beverages with added creamers and liquid creamers were determined by an untrained panelist. During storage, no phase separation (cream separation, deoiling, marbling, etc.), gelation, sedimentation separation and substantial viscosity change were not observed.
[0053]液体クリーマーは、良好な外観、口当たり、滑らかな質感及び「異」味のない良好な風味を有することが判明した。さらに、クリーマーは、コーヒーに加えた場合に、高い白色化能を示した。
例2
[0053] The liquid creamer has been found to have a good appearance, mouthfeel, smooth texture and good flavor without "bad" taste. In addition, the creamer showed high whitening ability when added to coffee.
Example 2
[0054]スクロース500gとκーカラギーナン10g及びι−カラギーナン30gとを混ぜ合わせることによって、カラギーナンとスクロースとのドライブレンドを調製した。タンク中で高撹拌下において、約75℃の熱水58kgにドライブレンドを加えた。次いで、リン酸水素二カリウム400gを、連続撹拌下でタンクに加えた。 [0054] A dry blend of carrageenan and sucrose was prepared by combining 500 g of sucrose with 10 g of κ-carrageenan and 30 g of ι-carrageenan. The dry blend was added to 58 kg of hot water at about 75 ° C. under high stirring in a tank. Then 400 g of dipotassium hydrogen phosphate was added to the tank under continuous stirring.
[0055]次に、カゼイン酸ナトリウム1.0kg、二酸化チタン300g、香味料330g及びスクロース2.5kgを混ぜ合わせることによって、ドライブレンドを調製した。ドライブレンドを、高撹拌下でタンクに加えた。約10分間の混合後、乳化剤(Dimodan 100g及びPanodan 300g)を、連続高撹拌下でタンクに加えた。さらに、高撹拌下で約60℃の融解油8.4kgを加え、続いてスクロース27kgを加えた。少量の追加の水を加えて、総生成物重量を100kgに調整した。 [0055] Next, a dry blend was prepared by combining 1.0 kg of sodium caseinate, 300 g of titanium dioxide, 330 g of flavoring agent and 2.5 kg of sucrose. The dry blend was added to the tank under high agitation. After about 10 minutes of mixing, emulsifiers (Dimodan 100 g and Panodane 300 g) were added to the tank under continuous high agitation. Further, 8.4 kg of melted oil at about 60 ° C. was added under high stirring, followed by 27 kg of sucrose. A small amount of additional water was added to adjust the total product weight to 100 kg.
[0056]得られた液体を予熱し、143℃で5秒間UHT処理し、180/40バールで均質化し、冷却し、液体クリーマーをボトルに無菌充填した。 [0056] The resulting liquid was preheated, UHT treated at 143 ° C. for 5 seconds, homogenized at 180/40 bar, cooled, and the liquid creamer was aseptically filled into bottles.
[0057]液体クリーマーを含有する3セットのボトルを、下記条件下で貯蔵した:
38℃で1ヶ月
30℃で3ヶ月
室温(約20℃)で9ヶ月。
[0057] Three sets of bottles containing liquid creamers were stored under the following conditions:
1 month at 38 ° C. 3 months at 30 ° C. 9 months at room temperature (about 20 ° C.).
[0058]クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。貯蔵中に、相分離(クリーム分離、脱油、マーブリングなど)、ゲル化、沈降分離及び実質的な粘度変化は認められなかった。 [0058] Untrained panelists determined the physicochemical stability and sensory profile of coffee drinks with added creamers and liquid creamers. During storage, no phase separation (cream separation, deoiling, marbling, etc.), gelation, sedimentation separation and substantial viscosity change were not observed.
[0059]液体クリーマーは、良好な外観、口当たり、滑らかな質感及び「異」味のない良好な風味を有することが判明した。さらに、クリーマーは、コーヒーに加えた場合に、高い白色化能を示した。
例3
[0059] The liquid creamer has been found to have a good appearance, mouthfeel, smooth texture and good flavor without "bad" taste. In addition, the creamer showed high whitening ability when added to coffee.
Example 3
[0060]スクロース500gとκーカラギーナン10g及びι−カラギーナン30gとを混ぜ合わせることによって、カラギーナンとスクロースとのドライブレンドを調製した。タンク中で高撹拌下において、約75℃の熱水58kgにドライブレンドを加えた。次いで、リン酸水素二カリウム400gを、連続撹拌下でタンクに加えた。 [0060] A dry blend of carrageenan and sucrose was prepared by combining 500 g of sucrose with 10 g of κ-carrageenan and 30 g of ι-carrageenan. The dry blend was added to 58 kg of hot water at about 75 ° C. under high stirring in a tank. Then 400 g of dipotassium hydrogen phosphate was added to the tank under continuous stirring.
[0061]次に、カゼイン酸ナトリウム1.0kg、二酸化チタン300g、香味料330g及びスクロース2.5kgを混ぜ合わせることによって、ドライブレンドを調製した。ドライブレンドを、高撹拌下でタンクに加えた。約10分間の混合後、乳化剤(Dimodan 130g及びPanodan 380g)を、連続高撹拌下でタンクに加えた。さらに、高撹拌下で約60℃の融解油8.4kgを加え、続いてスクロース27kgを加えた。少量の追加の水を加えて、総生成物重量を100kgに調整した。 [0061] Next, a dry blend was prepared by combining 1.0 kg of sodium caseinate, 300 g of titanium dioxide, 330 g of flavoring agent and 2.5 kg of sucrose. The dry blend was added to the tank under high agitation. After about 10 minutes of mixing, emulsifiers (Dimodan 130 g and Pandan 380 g) were added to the tank under continuous high agitation. Further, 8.4 kg of melted oil at about 60 ° C. was added under high stirring, followed by 27 kg of sucrose. A small amount of additional water was added to adjust the total product weight to 100 kg.
[0062]得られた液体を予熱し、143℃で5秒間UHT処理し、180/40バールで均質化し、冷却した。次いで、液体クリーマーを、ボトルに無菌充填した。 [0062] The resulting liquid was preheated, UHT treated at 143 ° C. for 5 seconds, homogenized at 180/40 bar, and cooled. The liquid creamer was then aseptically filled into bottles.
[0063]液体クリーマーを含有する3セットのボトルを、下記条件下で貯蔵した:
38℃で1ヶ月
30℃で3ヶ月
室温(約20℃)で9ヶ月。
[0063] Three sets of bottles containing liquid creamers were stored under the following conditions:
1 month at 38 ° C. 3 months at 30 ° C. 9 months at room temperature (about 20 ° C.).
[0064]クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。貯蔵中に、相分離(クリーム分離、脱油、マーブリングなど)、ゲル化、沈降分離及び実質的な粘度変化は認められなかった。 [0064] Untrained panelists determined the physicochemical stability and sensory profile of coffee drinks with added creamers and liquid creamers. During storage, no phase separation (cream separation, deoiling, marbling, etc.), gelation, sedimentation separation and substantial viscosity change were not observed.
[0065]液体クリーマーは、良好な外観、口当たり、滑らかな質感及び「異」味のない良好な風味を有することが判明した。さらに、クリーマーは、コーヒーに加えた場合に、高い白色化能を示した。
例4
[0065] The liquid creamer has been found to have a good appearance, mouthfeel, smooth texture and good flavor with no "bad" taste. In addition, the creamer showed high whitening ability when added to coffee.
Example 4
[0066]例1と同様にして、コーヒーホワイトナーを調製した。但し、κーカラギーナンとι−カラギーナンのブレンドの代わりにκ−カラギーナンのみを用いた。液体クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。 [0066] A coffee whitener was prepared as in Example 1. However, only κ-carrageenan was used in place of the blend of κ-carrageenan and ι-carrageenan. An untrained panelist determined the physicochemical stability and sensory profile of liquid creamers and coffee beverages with added liquid creamers.
[0067]20℃において4ヶ月間の貯蔵後、官能評価はボトル中のクリーム分離を示した。
さらに、ボトル中の液体クリーマーの著しい沈降分離を観察した。コーヒーに加えた場合には、作りたての液体コーヒークリーマーに比較して、白色化能の著しい減少が観察された。
例5
[0067] After storage for 4 months at 20 ° C, sensory evaluation showed cream separation in the bottle.
In addition, significant sedimentation of the liquid creamer in the bottle was observed. When added to coffee, a significant decrease in whitening ability was observed compared to freshly made liquid coffee creamer.
Example 5
[0068]例1と同様にして、コーヒーホワイトナーを調製した。但し、2種の乳化剤の総使用量を、70gではなく900gとした。液体クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。 [0068] A coffee whitener was prepared as in Example 1. However, the total amount of the two emulsifiers was 900 g instead of 70 g. An untrained panelist determined the physicochemical stability and sensory profile of liquid creamers and coffee beverages with added liquid creamers.
[0069]20℃において3ヶ月間の貯蔵後、官能評価はボトル中の著しいクリーム分離を示した。コーヒーに加えた場合には、作りたての液体コーヒークリーマーに比較して、白色化能の著しい減少が観察された。
例6
[0069] After storage for 3 months at 20 ° C., sensory evaluation showed significant cream separation in the bottle. When added to coffee, a significant decrease in whitening ability was observed compared to freshly made liquid coffee creamer.
Example 6
[0070]例1と同様にして、コーヒーホワイトナーを調製した。但し、カゼイン酸ナトリウムを3.0kg用いた。液体クリーマー及び液体クリーマーを添加したコーヒー飲料の物理化学的安定性及び官能プロフィールを、訓練を受けていないパネリストが判定した。 [0070] A coffee whitener was prepared as in Example 1. However, 3.0 kg of sodium caseinate was used. An untrained panelist determined the physicochemical stability and sensory profile of liquid creamers and coffee beverages with added liquid creamers.
[0071]38℃で3週間の貯蔵の後、官能検査はボトル中の凝集を示した。さらに、液体クリーマーの著しい粘度増加を観察した。 [0071] After storage for 3 weeks at 38 ° C., sensory tests showed agglomeration in the bottle. In addition, a significant increase in viscosity of the liquid creamer was observed.
[0072]本発明の好ましい実施形態の種々の変更及び修正は、当業者には明白であることを理解すべきである。このような変更及び修正は、本発明の主題の精神及び範囲から逸脱することなく、また、所期の利点を損なうことなく、実施できる。したがって、このような変更及び修正は添付の特許請求の範囲によって網羅されるよう意図する。
[0072] It should be understood that various changes and modifications to the preferred embodiments of the present invention will be apparent to those skilled in the art. Such changes and modifications can be made without departing from the spirit and scope of the present inventive subject matter and without diminishing its intended advantages. Accordingly, such changes and modifications are intended to be covered by the appended claims.
Claims (13)
約0.5〜約2.5重量%の範囲のタンパク質と、
少なくとも2種の乳化剤のブレンドを含む約0.2〜約0.7重量%の範囲の乳化剤系であって、乳化剤系:タンパク質:ガム成分の重量比は、(2〜14):(5〜50):1である乳化剤系と、
約8〜約20重量%の範囲の油と
を含む液体クリーマー。 a gum component comprising a blend of κ-carrageenan and ι-carrageenan in a weight ratio of about 1: 2 to about 1: 6;
A protein in the range of about 0.5 to about 2.5% by weight;
An emulsifier system in the range of about 0.2 to about 0.7 weight percent comprising a blend of at least two emulsifiers, wherein the weight ratio of emulsifier system: protein: gum component is (2-14) :( 5 50): an emulsifier system which is 1:
A liquid creamer comprising about 8 to about 20 weight percent of oil.
液体クリーマーを均質化するステップと、
容器に液体クリーマーを無菌充填するステップと
を含む、安定な液体クリーマーの製造方法。 a gum component comprising a blend of κ-carrageenan and ι-carrageenan in a weight ratio of about 1: 2 to about 1: 6, a protein in the range of about 0.5 to about 2.5% by weight, and at least two low molecular weight emulsifiers. Hydrating a combination of an emulsifier system in the range of about 0.2 to about 0.7% by weight containing the blend and an oil in the range of about 8 to about 20% by weight to form a liquid creamer;
Homogenizing the liquid creamer;
Aseptically filling the container with the liquid creamer.
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USPCT/US2009/065946 | 2009-11-25 | ||
US2009065946 | 2009-11-25 | ||
PCT/EP2010/067161 WO2011064093A1 (en) | 2009-11-25 | 2010-11-10 | Liquid creamers and methods of making same |
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EP (1) | EP2503896A1 (en) |
JP (1) | JP2013511963A (en) |
CN (1) | CN102711492A (en) |
CA (1) | CA2781844A1 (en) |
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JPWO2017065284A1 (en) * | 2015-10-16 | 2017-10-12 | 不二製油株式会社 | Oil composition for coffee cream |
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US20140044854A1 (en) * | 2011-04-29 | 2014-02-13 | Nestec S.A. | Creamers and methods of making same |
RU2014130108A (en) * | 2011-12-22 | 2016-02-10 | Нестек С.А. | LIQUID CHLAMINS AND METHODS FOR PRODUCING THEM |
CN104137885B (en) * | 2013-05-10 | 2016-04-20 | 南阳乳业株式会社 | Stablize containing former milk or defatted milk, emergence and the preparation method of coffee creamer that is improved of milk local flavor |
ES2946171T3 (en) | 2016-05-04 | 2023-07-13 | Cj Cheiljedang Corp | Nutraceutical food to inhibit the increase in blood sugar containing coffee and tagatose |
CN110769695A (en) * | 2017-06-30 | 2020-02-07 | 雀巢产品有限公司 | Creamers with improved texture/mouthfeel and methods of making the same |
ES2975065T3 (en) * | 2017-12-01 | 2024-07-03 | Nestle Sa | Cream substitutes with improved texture/mouthfeel and methods of preparation thereof |
EP3879990B1 (en) * | 2018-11-14 | 2024-02-28 | Société des Produits Nestlé S.A. | Liquid creamer |
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US4857341A (en) * | 1985-08-19 | 1989-08-15 | Nestec S.A. | Protein-free coffee whitener and method of making same |
US6020017A (en) * | 1998-06-25 | 2000-02-01 | Mingione; Armand | Non-dairy drink mixture |
US6536188B1 (en) | 1999-02-02 | 2003-03-25 | Steuben Foods, Inc. | Method and apparatus for aseptic packaging |
MXPA06014738A (en) * | 2004-06-15 | 2007-03-26 | Nestec Sa | Aerated creamers and processes. |
EP1900292A1 (en) * | 2006-09-15 | 2008-03-19 | Nestec S.A. | Beverage creamer |
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- 2010-11-10 CA CA2781844A patent/CA2781844A1/en not_active Abandoned
- 2010-11-10 JP JP2012540353A patent/JP2013511963A/en active Pending
- 2010-11-10 PH PH1/2012/501044A patent/PH12012501044A1/en unknown
- 2010-11-10 WO PCT/EP2010/067161 patent/WO2011064093A1/en active Application Filing
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JPWO2017065284A1 (en) * | 2015-10-16 | 2017-10-12 | 不二製油株式会社 | Oil composition for coffee cream |
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CN102711492A (en) | 2012-10-03 |
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