JP2013505832A5 - - Google Patents
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- JP2013505832A5 JP2013505832A5 JP2012532246A JP2012532246A JP2013505832A5 JP 2013505832 A5 JP2013505832 A5 JP 2013505832A5 JP 2012532246 A JP2012532246 A JP 2012532246A JP 2012532246 A JP2012532246 A JP 2012532246A JP 2013505832 A5 JP2013505832 A5 JP 2013505832A5
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- 239000000203 mixture Substances 0.000 claims description 82
- 238000000034 method Methods 0.000 claims description 51
- 239000003153 chemical reaction reagent Substances 0.000 claims description 49
- 229910052753 mercury Inorganic materials 0.000 claims description 36
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 35
- 239000003463 adsorbent Substances 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003546 flue gas Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 3
- -1 ammonium halides Chemical class 0.000 claims 17
- 239000002245 particle Substances 0.000 claims 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 10
- 239000007800 oxidant agent Substances 0.000 claims 9
- 230000002708 enhancing effect Effects 0.000 claims 5
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 230000002209 hydrophobic effect Effects 0.000 claims 5
- 229910052757 nitrogen Inorganic materials 0.000 claims 5
- 229910021536 Zeolite Inorganic materials 0.000 claims 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 4
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical group [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 4
- 239000000741 silica gel Substances 0.000 claims 4
- 229910002027 silica gel Inorganic materials 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- 239000010457 zeolite Substances 0.000 claims 4
- 150000001721 carbon Chemical class 0.000 claims 3
- 239000004927 clay Substances 0.000 claims 3
- 150000002366 halogen compounds Chemical class 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 238000007580 dry-mixing Methods 0.000 claims 2
- 150000004673 fluoride salts Chemical class 0.000 claims 2
- 229920002313 fluoropolymer Polymers 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 238000003801 milling Methods 0.000 claims 2
- 238000010298 pulverizing process Methods 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 230000000274 adsorptive effect Effects 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 150000002466 imines Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000012070 reactive reagent Substances 0.000 description 5
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 5
- 229910052815 sulfur oxide Inorganic materials 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000002594 sorbent Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011217 control strategy Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24640209P | 2009-09-28 | 2009-09-28 | |
| US24639809P | 2009-09-28 | 2009-09-28 | |
| US61/246,398 | 2009-09-28 | ||
| US61/246,402 | 2009-09-28 | ||
| US34933210P | 2010-05-28 | 2010-05-28 | |
| US61/349,332 | 2010-05-28 | ||
| PCT/US2010/050598 WO2011038415A2 (en) | 2009-09-28 | 2010-09-28 | Sorbent formulation for removal of mercury from flue gas |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013505832A JP2013505832A (ja) | 2013-02-21 |
| JP2013505832A5 true JP2013505832A5 (enExample) | 2013-10-24 |
| JP5740070B2 JP5740070B2 (ja) | 2015-06-24 |
Family
ID=43780615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012532246A Active JP5740070B2 (ja) | 2009-09-28 | 2010-09-28 | 燃焼排ガスから水銀を取り除く吸着剤 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US8216535B2 (enExample) |
| EP (1) | EP2482970B1 (enExample) |
| JP (1) | JP5740070B2 (enExample) |
| CA (1) | CA2755318C (enExample) |
| PL (1) | PL2482970T3 (enExample) |
| WO (1) | WO2011038415A2 (enExample) |
Families Citing this family (66)
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| EP2482970B1 (en) * | 2009-09-28 | 2018-08-08 | Calgon Carbon Corporation | Sorbent formulation for removal of mercury from flue gas |
| US11298657B2 (en) | 2010-10-25 | 2022-04-12 | ADA-ES, Inc. | Hot-side method and system |
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| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| US9682383B2 (en) | 2010-04-08 | 2017-06-20 | Nalco Company | Gas stream treatment process |
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-
2010
- 2010-09-28 EP EP10819662.7A patent/EP2482970B1/en active Active
- 2010-09-28 PL PL10819662T patent/PL2482970T3/pl unknown
- 2010-09-28 JP JP2012532246A patent/JP5740070B2/ja active Active
- 2010-09-28 WO PCT/US2010/050598 patent/WO2011038415A2/en not_active Ceased
- 2010-09-28 US US12/892,866 patent/US8216535B2/en active Active
- 2010-09-28 CA CA2755318A patent/CA2755318C/en active Active
-
2012
- 2012-06-06 US US13/490,088 patent/US8450238B2/en active Active
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2013
- 2013-03-13 US US13/801,942 patent/US8715599B2/en active Active
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