JP2013504640A - R−410aを代替する伝熱流体 - Google Patents
R−410aを代替する伝熱流体 Download PDFInfo
- Publication number
- JP2013504640A JP2013504640A JP2012528409A JP2012528409A JP2013504640A JP 2013504640 A JP2013504640 A JP 2013504640A JP 2012528409 A JP2012528409 A JP 2012528409A JP 2012528409 A JP2012528409 A JP 2012528409A JP 2013504640 A JP2013504640 A JP 2013504640A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- heat transfer
- tetrafluoropropene
- difluoromethane
- difluoroethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013529 heat transfer fluid Substances 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 56
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims abstract description 50
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims abstract description 22
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 13
- 230000006835 compression Effects 0.000 claims description 13
- 238000007906 compression Methods 0.000 claims description 13
- 230000002441 reversible effect Effects 0.000 claims description 13
- 238000005057 refrigeration Methods 0.000 claims description 6
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000003507 refrigerant Substances 0.000 description 16
- 239000012530 fluid Substances 0.000 description 12
- 238000004378 air conditioning Methods 0.000 description 8
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 henutafluoropropane Chemical compound 0.000 description 3
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical compound CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 1
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- HJEORQYOUWYAMR-UHFFFAOYSA-N 2-[(2-butylphenoxy)methyl]oxirane Chemical compound CCCCC1=CC=CC=C1OCC1OC1 HJEORQYOUWYAMR-UHFFFAOYSA-N 0.000 description 1
- HSDVRWZKEDRBAG-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COC(CCCCC)OCC1CO1 HSDVRWZKEDRBAG-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 210000005045 desmin Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 239000011555 saturated liquid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B45/00—Arrangements for charging or discharging refrigerant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/40—Replacement mixtures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/006—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
(1)二つの流体が平行に配置され、同じ方向に移動する:並流(アンチメソディック(antimethodic))モード、
(2)二つの流体が平行に配置され、逆方向に移動する:向流(メソディック(methodic))モード、
(3)二つの流体が直角に配置される交差流モード:この交差流モードは並流モードまたは向流モードの傾向にできる。
(4)二つの流体の一方が第2の流体が通る大径パイプ中でUターンする。この形状は長さの半分が向流交換器で他の半分が並流交換器であるものと等価:ピンヘッドモード。
計算ツール
密度、エンタルピー、エントロピーおよび混合物の液体/蒸気平衡データはRK-Soave式を用いて計算した。この式を使用するには該当混合物中の各純粋化合物の性質に関する知識と、各二成分混合物に対する相互作用係数とが必要である。
これらの化合物のデータは「ASHRAE Handbook 2005、第20章」に記載されており、また、Refrop(冷媒の性質を計算するためにNISTによって開発されたソフトウェア)から入手できる。
HFO-1234yfの温度-圧力曲線データは静的方法で測定できる。臨界温度および臨界圧力はSetaramから市販のC80カロリメータを使用して測定される。温度を関数とする飽和密度はパリのEcole des Mines研究所が開発した振動管デンシトメータ法を用いて測定される。
混合物中の各化合物の挙動を表すためにRK-Soave式では二元相互作用係数を使用する。この係数は液体−蒸気平衡の実験データの関数として計算される。
HFC-32/HFO-1234yf二成分混合物の液体/蒸気平衡の測定は-10℃、30℃、70℃で下記の等温式で求める。HFC-152a/HFO-1234yf二成分混合物の液体/蒸気平衡の測定は10℃で下記の等温式で求める。
HFC-152a/HFC-32二成分混合物の液体/蒸気平衡データはRefpropから入手にできる。この二元系の相互作用係数の計算には2つの等温式(-20℃と20℃)および2つの等圧曲線(1バールと25バール)を用いる。
スクリュー圧縮機と膨張弁とを有する、向流凝縮器および蒸発器を備えた圧縮システムを考える。この圧縮システムを15℃の過熱および5℃の過冷却で運転する。二次流体と冷媒との間の最少温度差は約5℃とみなされる。
冷却モードでは、圧縮システムを蒸発器の冷媒入口温度の-5℃と凝縮器の冷媒入口温度の50℃との間で運転する。システムは0℃で冷蔵する。
冷却運転条件下の本発明組成物の性能を[表1]に示す。各組成物の各成分(HF0-1234yf、HFC-32、HFC-152a)の値は重量百分率で与えられる。
加熱モードでは、圧縮システムを蒸発器の冷媒入口温度の-5℃と、凝縮器の冷媒入口温度の50℃との間の温度で運転する。システムは45℃で熱を供給する。
低温冷却モードでは、圧縮システムを蒸発器の冷媒入口温度の-30℃と凝縮器の冷媒入口温度の40℃との間で運転する。システムは-25℃の冷気を出す。
この冷却運転条件下の本発明組成物の性能を[表3]に示す。各組成物の各成分(HF0-1234yf、HFC-32、HFC-152a)の値は重量百分率で与えられる。
Claims (11)
- 2,3,3,3-テトラフルオロプロペンと、1,1-ジフルオロエタンと、ジフルオロメタンの三成分組成物の、混合物R-410Aを代替する冷却システムの熱媒体流体としての使用。
- 三成分組成物が基本的に5〜83重量%の2,3,3,3-テトラフルオロプロペンと、15〜75重量%のジフルオロメタンと、2〜40重量%のジフルオロエタンとを含む請求項1に記載の使用。
- 三成分組成物が基本的に5〜63重量%の2,3,3,3-テトラフルオロプロペンと、35〜70重量%のジフルオロメタンと、2〜25重量%のジフルオロエタンとを含む請求項1に記載の使用。
- 三成分組成物が基本的に40〜58重量%の2,3,3,3-テトラフルオロプロペンと、40〜50重量%のジフルオロメタンと、2〜10重量%のジフルオロエタンとを含む請求項1に記載の使用。
- 二成分組成物が安定化される請求項1〜4のいずれか一項に記載の使用。
- 冷却システムが圧縮タイプである請求項1〜5のいずれか一項に記載の使用。
- 上記システムを逆流モードまたは逆流傾向を有する交流モードの熱交換器で運転する請求項6に記載の使用。
- 2,3,3,3-テトラフルオロプロペンと、1,1-ジフルオロエタンと、ジフルオロメタンの三元組成物を混合物R-410Aを代替する冷凍システムの熱媒体流体として使用する伝熱方法。
- 冷却凍システムが、逆流モードまたは逆流傾向を有する交流モードの熱交換器で運転される圧縮タイプのシステムである請求項8に記載の方法。
- 三成分組成物が基本的に40〜58重量%の2,3,3,3-テトラフルオロプロペンと、40〜50重量%のジフルオロメタンと、2〜10重量%のジフルオロエタンとを含む、請求項8または9に記載の方法。
- 潤滑剤の存在下で実行される請求項6〜10のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0956245A FR2950067B1 (fr) | 2009-09-11 | 2009-09-11 | Fluide de transfert de chaleur en remplacement du r-410a |
FR0956245 | 2009-09-11 | ||
PCT/FR2010/051727 WO2011030028A1 (fr) | 2009-09-11 | 2010-08-17 | Fluide de transfert de chaleur en remplacement du r-410a |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013504640A true JP2013504640A (ja) | 2013-02-07 |
JP5657669B2 JP5657669B2 (ja) | 2015-01-21 |
Family
ID=42135950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012528409A Active JP5657669B2 (ja) | 2009-09-11 | 2010-08-17 | R−410aを代替する伝熱流体 |
Country Status (11)
Country | Link |
---|---|
US (2) | US9011711B2 (ja) |
EP (1) | EP2475736B1 (ja) |
JP (1) | JP5657669B2 (ja) |
CN (2) | CN102482560B (ja) |
BR (1) | BR112012005348B1 (ja) |
ES (1) | ES2562955T3 (ja) |
FR (1) | FR2950067B1 (ja) |
HK (1) | HK1211614A1 (ja) |
PL (1) | PL2475736T3 (ja) |
RU (1) | RU2544687C2 (ja) |
WO (1) | WO2011030028A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013504641A (ja) * | 2009-09-11 | 2013-02-07 | アルケマ フランス | 伝熱方法 |
JP2016513749A (ja) * | 2013-03-15 | 2016-05-16 | ハネウェル・インターナショナル・インコーポレーテッド | 低gwpの熱伝達組成物 |
JP2018501334A (ja) * | 2014-11-11 | 2018-01-18 | トレイン インターナショナル インク | 冷媒組成物及び使用方法 |
JP2023036561A (ja) * | 2021-09-02 | 2023-03-14 | ダイキン工業株式会社 | 冷媒を含む組成物、その使用、並びにそれを有する冷凍機及びその冷凍機の運転方法 |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2936806B1 (fr) | 2008-10-08 | 2012-08-31 | Arkema France | Fluide refrigerant |
FR2937328B1 (fr) | 2008-10-16 | 2010-11-12 | Arkema France | Procede de transfert de chaleur |
US20170080773A1 (en) | 2008-11-03 | 2017-03-23 | Arkema France | Vehicle Heating and/or Air Conditioning Method |
FR2950065B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Fluide refrigerant binaire |
FR2950066B1 (fr) * | 2009-09-11 | 2011-10-28 | Arkema France | Refrigeration basse et moyenne temperature |
FR2950070B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Compositions ternaires pour refrigeration haute capacite |
FR2950071B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Compositions ternaires pour refrigeration basse capacite |
US10035938B2 (en) | 2009-09-11 | 2018-07-31 | Arkema France | Heat transfer fluid replacing R-134a |
FR2950067B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Fluide de transfert de chaleur en remplacement du r-410a |
FR2950069B1 (fr) | 2009-09-11 | 2011-11-25 | Arkema France | Utilisation de compositions ternaires |
FR2954342B1 (fr) | 2009-12-18 | 2012-03-16 | Arkema France | Fluides de transfert de chaleur a inflammabilite reduite |
FR2959998B1 (fr) | 2010-05-11 | 2012-06-01 | Arkema France | Fluides de transfert de chaleur ternaires comprenant du difluoromethane, du pentafluoroethane et du tetrafluoropropene |
CN102947410B (zh) * | 2010-06-22 | 2016-11-09 | 阿科玛股份有限公司 | 具有多种氢氟烷和一种氢氟烯烃的热传递组合物 |
FR2962442B1 (fr) | 2010-07-09 | 2016-02-26 | Arkema France | Composition stable de 2,3,3,3-tetrafluoropropene |
FR2964975B1 (fr) | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
US20120119136A1 (en) * | 2010-11-12 | 2012-05-17 | Honeywell International Inc. | Low gwp heat transfer compositions |
FR2971512B1 (fr) | 2011-02-10 | 2013-01-18 | Arkema France | Compositions binaires de 2,3,3,3-tetrafluoropropene et d'ammoniac |
FR2974812B1 (fr) | 2011-05-04 | 2014-08-08 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
TWI585065B (zh) * | 2011-08-26 | 2017-06-01 | 杜邦股份有限公司 | 含四氟丙烯之組成物及其使用方法 |
CN102516946A (zh) * | 2011-12-20 | 2012-06-27 | 集美大学 | 绿色混合制冷剂 |
FR2986236B1 (fr) | 2012-01-26 | 2014-01-10 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
US9783721B2 (en) | 2012-08-20 | 2017-10-10 | Honeywell International Inc. | Low GWP heat transfer compositions |
BR112015011006A2 (pt) | 2012-11-16 | 2018-05-15 | Basf Se | composição lubrificante, e, método para lubrificar um sistema. |
FR2998302B1 (fr) | 2012-11-20 | 2015-01-23 | Arkema France | Composition refrigerante |
US8940180B2 (en) | 2012-11-21 | 2015-01-27 | Honeywell International Inc. | Low GWP heat transfer compositions |
FR3000095B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene et du 1,2-difluoroethylene |
FR3000093B1 (fr) | 2012-12-26 | 2015-07-17 | Arkema France | Composition azeotropique ou quasi-azeotropique de chloromethane |
FR3000096B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene |
US9982180B2 (en) | 2013-02-13 | 2018-05-29 | Honeywell International Inc. | Heat transfer compositions and methods |
FR3003565B1 (fr) | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
FR3008419B1 (fr) | 2013-07-11 | 2015-07-17 | Arkema France | Compositions a base de 2,3,3,3-tetrafluoropropene presentant une miscibilite amelioree |
FR3010415B1 (fr) | 2013-09-11 | 2015-08-21 | Arkema France | Fluides de transfert de chaleur comprenant du difluoromethane, du pentafluoroethane, du tetrafluoropropene et eventuellement du propane |
FR3033791B1 (fr) | 2015-03-18 | 2017-04-14 | Arkema France | Stabilisation du 1-chloro-3,3,3-trifluoropropene |
FR3057271B1 (fr) | 2016-10-10 | 2020-01-17 | Arkema France | Utilisation de compositions a base de tetrafluoropropene |
FR3057272B1 (fr) | 2016-10-10 | 2020-05-08 | Arkema France | Compositions azeotropiques a base de tetrafluoropropene |
FR3064275B1 (fr) | 2017-03-21 | 2019-06-07 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR3064264B1 (fr) | 2017-03-21 | 2019-04-05 | Arkema France | Composition a base de tetrafluoropropene |
FR3070982B1 (fr) | 2017-09-12 | 2019-08-30 | Arkema France | Composition a base d'hydrochlorofluoroolefine et d'huile minerale |
FR3077572B1 (fr) | 2018-02-05 | 2021-10-08 | Arkema France | Composition azeotropique ou quasi-azeotropique ternaire comprenant hf, 2,3,3,3-tetrafluoropropene et 1,1,1,2,2,-pentafluoropropane. |
FR3077822B1 (fr) | 2018-02-15 | 2020-07-24 | Arkema France | Compositions de transfert de chaleur en remplacement du r-134a |
JP6658948B2 (ja) * | 2018-08-09 | 2020-03-04 | ダイキン工業株式会社 | 冷媒を含有する組成物、並びに、その組成物を用いた冷凍方法、冷凍装置の運転方法及び冷凍装置 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008531836A (ja) * | 2005-03-04 | 2008-08-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロオレフィンを含む組成物 |
JP2010002074A (ja) * | 2008-06-18 | 2010-01-07 | Mitsubishi Electric Corp | 混合冷媒とそれを用いた冷凍サイクル装置 |
JP2010047754A (ja) * | 2008-07-30 | 2010-03-04 | Honeywell Internatl Inc | ジフルオロメタン及びフッ素置換オレフィンを含有する組成物 |
JP2010531927A (ja) * | 2008-03-07 | 2010-09-30 | アーケマ・インコーポレイテッド | 油リターンが改善されたハロゲン化アルケン伝熱組成物 |
JP2012505279A (ja) * | 2008-10-08 | 2012-03-01 | アルケマ フランス | 熱伝導流体 |
JP2013504641A (ja) * | 2009-09-11 | 2013-02-07 | アルケマ フランス | 伝熱方法 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH549772A (de) | 1972-04-29 | 1974-05-31 | Bertrams Ag Hch | Kreuzgegenstromwaermeaustauscher und verfahren zu seiner herstellung. |
FR2256381A1 (en) | 1973-12-27 | 1975-07-25 | Tour Agenturer Ab | Arrangement for heating or cooling a flow medium - part of air currents diverted to a circuit containing e.g. ammonia in a heat exchanger |
JPH04110388A (ja) | 1990-08-31 | 1992-04-10 | Daikin Ind Ltd | 熱伝達用流体 |
US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
EP2314653A3 (en) | 2002-10-25 | 2014-07-23 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US9005467B2 (en) | 2003-10-27 | 2015-04-14 | Honeywell International Inc. | Methods of replacing heat transfer fluids |
JP4110388B2 (ja) | 2003-01-10 | 2008-07-02 | 荒川化学工業株式会社 | 金めっき部品用洗浄剤およびすすぎ剤並びに洗浄方法およびすすぎ方法 |
CN113845884B (zh) * | 2005-03-04 | 2024-02-02 | 科慕埃弗西有限公司 | 包含氟代烯烃的组合物 |
ES2580080T3 (es) * | 2005-03-18 | 2016-08-19 | Carrier Commercial Refrigeration, Inc. | Intercambiador de calor de múltiples partes |
TWI657070B (zh) * | 2005-06-24 | 2019-04-21 | 美商哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物及其用途 |
GB0614080D0 (en) | 2006-07-17 | 2006-08-23 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
US8024937B2 (en) * | 2007-06-21 | 2011-09-27 | E. I. Du Pont De Nemours And Company | Method for leak detection in heat transfer systems |
FR2932493B1 (fr) * | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
FR2932492B1 (fr) | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
FR2937906B1 (fr) | 2008-11-03 | 2010-11-19 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule. |
FR2938551B1 (fr) | 2008-11-20 | 2010-11-12 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR2938550B1 (fr) | 2008-11-20 | 2010-11-12 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene procede de chauffage et/ou climatisation d'un vehicule |
FR2942237B1 (fr) | 2009-02-13 | 2013-01-04 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR2950067B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Fluide de transfert de chaleur en remplacement du r-410a |
FR2950069B1 (fr) | 2009-09-11 | 2011-11-25 | Arkema France | Utilisation de compositions ternaires |
FR2950065B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Fluide refrigerant binaire |
FR2950066B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Refrigeration basse et moyenne temperature |
FR2950071B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Compositions ternaires pour refrigeration basse capacite |
FR2950070B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Compositions ternaires pour refrigeration haute capacite |
FR2962442B1 (fr) | 2010-07-09 | 2016-02-26 | Arkema France | Composition stable de 2,3,3,3-tetrafluoropropene |
FR2964975B1 (fr) | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
FR2971512B1 (fr) | 2011-02-10 | 2013-01-18 | Arkema France | Compositions binaires de 2,3,3,3-tetrafluoropropene et d'ammoniac |
FR2974812B1 (fr) | 2011-05-04 | 2014-08-08 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
FR2986007B1 (fr) | 2012-01-25 | 2015-01-23 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
-
2009
- 2009-09-11 FR FR0956245A patent/FR2950067B1/fr not_active Expired - Fee Related
-
2010
- 2010-08-17 PL PL10762991T patent/PL2475736T3/pl unknown
- 2010-08-17 WO PCT/FR2010/051727 patent/WO2011030028A1/fr active Application Filing
- 2010-08-17 RU RU2012114165/05A patent/RU2544687C2/ru active
- 2010-08-17 CN CN201080040360.4A patent/CN102482560B/zh active Active
- 2010-08-17 BR BR112012005348-5A patent/BR112012005348B1/pt active IP Right Grant
- 2010-08-17 ES ES10762991.7T patent/ES2562955T3/es active Active
- 2010-08-17 JP JP2012528409A patent/JP5657669B2/ja active Active
- 2010-08-17 US US13/391,417 patent/US9011711B2/en active Active
- 2010-08-17 EP EP10762991.7A patent/EP2475736B1/fr active Active
- 2010-08-17 CN CN201510337319.8A patent/CN105018036B/zh active Active
-
2015
- 2015-02-06 US US14/615,741 patent/US20150152306A1/en not_active Abandoned
- 2015-12-18 HK HK15112509.2A patent/HK1211614A1/xx unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008531836A (ja) * | 2005-03-04 | 2008-08-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロオレフィンを含む組成物 |
JP2010531927A (ja) * | 2008-03-07 | 2010-09-30 | アーケマ・インコーポレイテッド | 油リターンが改善されたハロゲン化アルケン伝熱組成物 |
JP2010002074A (ja) * | 2008-06-18 | 2010-01-07 | Mitsubishi Electric Corp | 混合冷媒とそれを用いた冷凍サイクル装置 |
JP2010047754A (ja) * | 2008-07-30 | 2010-03-04 | Honeywell Internatl Inc | ジフルオロメタン及びフッ素置換オレフィンを含有する組成物 |
JP2012505279A (ja) * | 2008-10-08 | 2012-03-01 | アルケマ フランス | 熱伝導流体 |
JP2013504641A (ja) * | 2009-09-11 | 2013-02-07 | アルケマ フランス | 伝熱方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013504641A (ja) * | 2009-09-11 | 2013-02-07 | アルケマ フランス | 伝熱方法 |
JP2016513749A (ja) * | 2013-03-15 | 2016-05-16 | ハネウェル・インターナショナル・インコーポレーテッド | 低gwpの熱伝達組成物 |
JP2018501334A (ja) * | 2014-11-11 | 2018-01-18 | トレイン インターナショナル インク | 冷媒組成物及び使用方法 |
JP2021036041A (ja) * | 2014-11-11 | 2021-03-04 | トレイン インターナショナル インク | 冷媒組成物及び使用方法 |
US11198805B2 (en) | 2014-11-11 | 2021-12-14 | Trane International Inc. | Refrigerant compositions and methods of use |
JP7232227B2 (ja) | 2014-11-11 | 2023-03-02 | トレイン インターナショナル インク | 冷媒組成物及び使用方法 |
JP2023036561A (ja) * | 2021-09-02 | 2023-03-14 | ダイキン工業株式会社 | 冷媒を含む組成物、その使用、並びにそれを有する冷凍機及びその冷凍機の運転方法 |
Also Published As
Publication number | Publication date |
---|---|
BR112012005348B1 (pt) | 2020-02-27 |
CN105018036B (zh) | 2020-03-03 |
US9011711B2 (en) | 2015-04-21 |
FR2950067B1 (fr) | 2011-10-28 |
FR2950067A1 (fr) | 2011-03-18 |
CN105018036A (zh) | 2015-11-04 |
CN102482560A (zh) | 2012-05-30 |
WO2011030028A1 (fr) | 2011-03-17 |
US20150152306A1 (en) | 2015-06-04 |
JP5657669B2 (ja) | 2015-01-21 |
HK1211614A1 (en) | 2016-05-27 |
PL2475736T3 (pl) | 2016-07-29 |
EP2475736A1 (fr) | 2012-07-18 |
CN102482560B (zh) | 2015-07-22 |
BR112012005348A2 (pt) | 2016-03-29 |
ES2562955T3 (es) | 2016-03-09 |
RU2544687C2 (ru) | 2015-03-20 |
RU2012114165A (ru) | 2013-10-20 |
US20120161064A1 (en) | 2012-06-28 |
EP2475736B1 (fr) | 2016-01-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6781308B2 (ja) | 二元冷却流体 | |
JP5657669B2 (ja) | R−410aを代替する伝熱流体 | |
JP5657670B2 (ja) | 伝熱方法 | |
JP6138205B2 (ja) | ハイキャパシティー冷蔵用三元組成物 | |
JP6374835B2 (ja) | 三元組成物の使用 | |
JP5726193B2 (ja) | 低温および中温での冷却 | |
JP6546563B2 (ja) | 低キャパシティー冷却用三元組成物 | |
US10035938B2 (en) | Heat transfer fluid replacing R-134a |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130819 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140328 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140415 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140703 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141118 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141126 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5657669 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |