JP2013242392A - Optical function member - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an optical function member which exhibits excellent image clarity when an optical function body is used for a polarization beam splitter or the like.SOLUTION: An optical function member includes an optical function body, and an adhesion layer which is provided on the optical function body and in which a ratio Tanδ (G"/G') of a loss modulus (G") to a storage modulus (G') is equal to or more than 0.3 and equal to or less than 1.0.

Description

  The present invention relates to an optical functional member having excellent image clarity.

  A wire grid polarizer, which is one of the optical functional bodies, regularly extends a linear metal wire (thin wire) on a substrate such as glass or film along a predetermined direction at a predetermined interval. A polarizer having an arrayed structure. In a wire grid polarizer, high polarization and light transmittance can be obtained by controlling the thickness and spacing of wires on a nanometer scale. For example, when producing a wire grid polarizer with sufficient polarization performance in the visible wavelength range, an ultrafine structure with a width (pitch) of 150 nm or less including the interval (gap) between the wires is required. It is known that

  Since the wire grid polarizer is composed of a metal wire as described above, it has a characteristic that the polarization property is expressed in the reflected light. It is known that it works well for applications such as a polarizing beam splitter as a reflective polarizer due to its ability to separate polarized light into both transmitted and reflected light, unlike the widely used absorption polarizer. ing.

  As a prior art of a polarizing beam splitter, a polarizing beam splitter using a cube prism is known. In addition, a wire grid polarizer directly formed on glass is known. Since all of these prior arts are formed on glass, the processability to a piece size is poor and applicable applications have been limited. Moreover, since it is very expensive, it is handled as a special optical component, and this is a factor that limits the applicable applications.

  Then, the wire grid polarizing plate formed on the film is known as a wire grid polarizing plate excellent in workability (patent document 1). Since these are generally manufactured by a roll process, they have a feature that they can be manufactured at a lower cost. However, since the wire grid polarizing plate is formed in a film shape and has flexibility, the self-supporting property is poor when the wire grid polarizing plate is used alone for a polarizing beam splitter or the like. For this reason, in order to give sufficient self-supporting property, it has been attempted to bond a wire grid polarizing plate to a different substrate with an adhesive layer. In this case, there has been a problem that the smoothness of the polarization reflection surface of the substrate is disturbed due to the deformation of the adhesive layer at the time of bonding, and the image clarity of the reflected image is lowered.

Japanese Patent No. 4275692

  This invention is made | formed in view of this point, and when using an optical function body for a polarization beam splitter etc., it aims at providing the optical function member which exhibits the outstanding image clarity.

  The optical functional member of the present invention is provided on the optical functional body and the optical functional body, and the ratio Tanδ (G ″ / G ′) between the loss elastic modulus (G ″) and the storage elastic modulus (G ′). And an adhesive layer having a value of 0.3 or more and 1.0 or less.

  In the optical functional member of the present invention, it is preferable that the adhesive strength of the adhesive constituting the adhesive layer is 8 (N / 25 mm) or more and 25 (N / 25 mm) or less with respect to the glass plate.

  In the optical function member of the present invention, the thickness of the optical function body is preferably 180 μm or more.

  In the optical functional member of the present invention, it is preferable that the adhesive layer has a thickness of 30 μm or more.

  In the optical function member of the present invention, the optical function body is preferably a wire grid polarizing plate.

  The composite optical member of the present invention is bonded to the optical functional member, the substrate bonded with the adhesive layer of the optical functional member on one main surface, and another adhesive layer on the other main surface of the substrate. And another optical functional member combined.

  According to the present invention, an adhesive layer having a ratio Tanδ (G ″ / G ′) of a loss elastic modulus (G ″) to a storage elastic modulus (G ′) of 0.3 to 1.0 is provided. Therefore, when the optical function body is used for a polarizing beam splitter or the like, excellent image clarity can be exhibited.

It is a side view which shows the wire grid polarizing plate which is an optical function body which concerns on embodiment of this invention. It is a schematic diagram of the jig | tool used when evaluating the self-supporting property of the wire grid polarizing plate which is an optical function body which concerns on embodiment of this invention. It is a side view which shows the other example of the wire grid polarizing plate which is an optical function body which concerns on embodiment of this invention.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
FIG. 1 is a side view showing an optical functional member according to an embodiment of the present invention. This optical functional member is mainly composed of a wire grid polarizing plate that is an optical functional body and an adhesive layer that bonds the wire grid polarizing plate to a rigid substrate. The wire grid polarizing plate is formed on the base material 101, the pattern layer 102 having a lattice-like uneven portion provided on one main surface of the base material 101, and the convex portions of the lattice-like uneven portion of the pattern layer 102. The metal layer 103 is formed.

  As described above, when an optical functional body formed in a film shape and having flexibility is used for a polarizing beam splitter or the like, when the self-supporting property is improved by being bonded to a rigid substrate, the substrate is deformed by deformation of the adhesive layer. Therefore, the smoothness of the polarizing reflection surface is disturbed, and the image clarity of the reflected image is deteriorated. As a result of intensive studies on this point, the present inventors have suppressed the deformation to such an extent that the smoothness of the polarization reflecting surface of the substrate is not disturbed, and can sufficiently adhere to a rigid substrate to improve the self-supporting property. The performance range was found. That is, when an optical function body formed in a film shape and having flexibility is used for a polarizing beam splitter or the like, the loss elastic modulus (G ″) and storage are used as an adhesive for bonding the optical function body to a rigid substrate. By using an adhesive whose elastic modulus (G ′) ratio Tanδ (= G ″ / G ′) is adjusted, the image clarity of the reflected image can be improved when the optical function body is used for a polarizing beam splitter or the like. As a result, the present invention has been made.

(0) Optical functional body The optical functional body refers to one having polarization separation characteristics, antireflection characteristics, and birefringence characteristics, and may have other optical characteristics incidentally. In other words, the optical functional body has one or a plurality of optical functions, for example, a polarizer having polarization separation characteristics, a polarizer with an antireflection layer having antireflection characteristics, and birefringence characteristics. A combination of a retardation plate and a reflective polarizer. Here, the optical function body preferably has a thickness of 180 μm or more in consideration of self-supporting properties. In this specification, the case where an optical function body is a wire grid polarizing plate is demonstrated. In addition, the description about a wire grid polarizing plate is mentioned later.

(1) Adhesive layer When the optical functional body is used alone, there is a use in which warpage occurs due to a temperature change and self-supporting property becomes a problem. In such a case, in order to hold the optical function body on a rigid substrate, both are bonded together via an adhesive layer. When holding the optical function body on a rigid substrate, from the viewpoint of maintaining image clarity, the physical properties of the adhesive (adhesive constituting the adhesive layer 201) used for bonding are loss elastic modulus (G ′ It is important that the ratio Tanδ (= G ″ / G ′) of “)” and the storage elastic modulus (G ′) is large. When Tan δ is large, stress on the substrate can be released as heat as a viscous component when the optical functional body is bonded. Thereby, deformation of the substrate can be suppressed and image clarity can be maintained.

  In general, since the bonding of the optical function body to the substrate is performed near room temperature, it is preferable to selectively use an adhesive having a Tan δ value at 25 ° C. of 0.3 or more. When Tan δ is 0.3 or more, the deformation of the adhesive when the optical function body is bonded to the substrate is small, the deformation of the polarization reflecting surface 103 is suppressed, and good image clarity can be obtained. Tan δ is preferably 0.35 or more, and more preferably 0.4 or more. Further, Tan δ is preferably 1.0 or less from the viewpoint of moldability of the adhesive layer of the optical function member. Tan δ is preferably 0.8 or less, more preferably 0.6 or less.

  Examples of the adhesive constituting the adhesive layer 201 include a rubber-based pressure-sensitive adhesive, an acrylic pressure-sensitive adhesive, a silicone-based pressure-sensitive adhesive, a urethane-based pressure-sensitive adhesive, a photocurable resin, and a thermosetting resin. In particular, an addition type silicone pressure sensitive adhesive or an acrylic pressure sensitive adhesive is preferable from the viewpoint of obtaining a high loss elastic modulus.

  Furthermore, it is desirable that the adhesive has a strong adhesive force with the object to be bonded (for example, a rigid substrate) during high-temperature heating. This is because, when used at a high temperature such as in-vehicle use, extremely fine bubbles present at the interface aggregate and expand, thereby reducing the flatness and image clarity of the substrate. As a range of such adhesive strength, it is preferable that the 180 ° peel adhesive strength is 8 (N / 25 mm) or more for the glass plate, and more preferably 180 ° peel adhesive strength is 10 (for the glass plate). N / 25 mm) or more. Moreover, the adhesive strength of the adhesive is preferably 180 ° peel-off adhesive strength with respect to a glass plate of 25 (N / 25 mm) or less, because when the separator is used, the peelability from the separator can be maintained. . The adhesive strength is preferably 180 ° peel-off adhesive strength with respect to a glass plate of 20 (N / 25 mm) or less. When an optical functional unit is bonded to a rigid substrate using an adhesive having an adhesive strength in this range, not only the adhesion to the substrate and the flatness of the optical functional unit are improved, but also more image clarity. Can be improved.

  When the thickness H2 of the adhesive layer 201 is equal to or less than a predetermined thickness, distortion and deformation generated when the optical function body and the substrate are bonded together are not sufficiently relieved, and the polarization reflecting surface of the optical function body is slightly deformed. This produces an orange peel pattern. This orange peel reduces the image clarity. In consideration of suppressing the deformation of the orange peel pattern, the thickness H2 of the adhesive layer 201 is preferably 30 μm or more, more preferably 40 μm or more.

(2) Wire grid polarizing plate (2-1) base material The base material 101 should just be a film which has a flexibility. As the base material 101, for example, an inorganic substrate, particularly a thin glass substrate or a resin substrate, or a combination thereof can be used. A substrate using a resin material is preferable because it has a merit such that a roll process can be performed and the wire grid polarizing plate can have flexibility (flexibility).

  The material of the flexible film includes polymethyl methacrylate resin, polycarbonate resin, polystyrene resin, cycloolefin resin (COP), crosslinked polyethylene resin, polyvinyl chloride resin, polyacrylate resin, polyphenylene ether resin, modified polyphenylene ether resin. Amorphous thermoplastic resins such as polyetherimide resin, polyether sulfone resin, polysulfone resin, polyether ketone resin, polyethylene terephthalate (PET) resin, polyethylene naphthalate resin, polyethylene resin, polypropylene resin, polybutylene terephthalate Crystalline thermoplastic resins such as resin, aromatic polyester resin, polyacetal resin, polyamide resin, and ultraviolet (UV) such as acrylic, epoxy, and urethane It includes resistance resin or thermosetting resin.

  Moreover, as the base material 101, a composite base material combining a base material made of an ultraviolet curable resin or a thermosetting resin and inorganic equipment, particularly a thin glass base material, the above thermoplastic resin, or a triacetate resin is used. May be.

  The thickness H1 of the substrate 101 is preferably 150 μm or more from the viewpoint of self-supporting properties. In addition, the thickness H1 of the substrate 101 is more preferably 500 μm or less from the viewpoint of stable production by a roll process. Further, when the thickness of the base material is 150 μm or more, the influence of distortion due to deformation of the adhesive layer is alleviated at the time of bonding to the substrate to be bonded, and as a result, good image clarity is obtained on the wire grid surface. . In addition, even if the thickness H1 of the base material 101 is less than 150 μm, the self-supporting property of the base material is exhibited to some extent if it is approximately 60 μm or more, and the image clarity is improved by using the adhesive used in the present invention. Can be made.

(2-2) Lattice-like uneven part The pattern layer 102 provided on the base material 101 is provided on the base material 101, and has a lattice-like uneven part 102a on the surface thereof. The convex portions of the lattice-shaped uneven portions 102a are provided at a predetermined interval and extend in a predetermined direction (a direction from the near side toward the far side in FIG. 1). The lattice-shaped uneven portion 102 a is formed by pressing and transferring a stamper having a lattice-shaped uneven shape to the pattern layer 102. Specifically, an ultraviolet curable resin is applied onto the base material 101, a stamper having a grid-like uneven shape is pressed and transferred to the ultraviolet curable resin, and then the ultraviolet curable resin is photocured to thereby form a grid-like unevenness. A pattern layer 102 having a portion 102a is formed.

  The cross-sectional shape of the recess in the plane perpendicular to the extending direction of the lattice-shaped uneven portion 102a (the paper surface in FIG. 1) is not a curve that changes gently like a parabola, but a relatively flat recess bottom and a small curvature. It is preferable that it is the substantially rectangular shape comprised from these corner | angular parts. Since the cross-sectional shape is a substantially rectangular shape, the side surface of the grid-like convex part is a substantially rectangular shape that is nearly perpendicular to the substrate surface, and the cross-sectional shape is a substantially rectangular shape, so that the metal wire described later However, it is formed in a shape close to the left-right symmetry with respect to the cross-sectional shape of the recess in the paper surface, and exhibits a high optical symmetry characteristically. By making the pitch of the convex portions 120 nm or less and making the convex cross-sectional shape substantially rectangular, it is possible to achieve both high degree of polarization and left-right symmetry of light transmittance.

In addition, in FIG. 1, the angle θ ₁ formed between the tangent to the side surface of the grid-like convex portion and the concave substrate surface is preferably 70 ° to 90 ° when viewed on the smaller angle side (acute angle side), and 80 ° More preferably, the angle is ˜90 °. By making the cross-sectional shape of the convex portion into a substantially rectangular shape, the direction perpendicular to the surface of the substrate 101 (up and down on the paper surface in FIG. 1) in the surface perpendicular to the extending direction of the lattice-shaped uneven portion 102a (the paper surface in FIG. The difference between the maximum values of light transmittances incident from the left and right symmetrical directions is 4% or less. Further, the value of the height of the convex portion of the grid-like convex portion / the half value width of the convex portion is preferably about 1.0 to 10, and the obtained optical performance, the ease of producing the convex shape, and the transfer performance In consideration of easiness, it is more preferably 2 to 5. Moreover, it is preferable that it is 0.2 times-0.7 times of pitch P, and, as for the half value width of a grid | lattice-like convex part, it is more preferable that it is 0.2 times-0.5 times.

(2-3) Dielectric In order to improve the adhesion between the material constituting the pattern layer 102 and the metal wire 103 in the present invention, it is preferable to deposit a dielectric material having a high adhesion between them. For example, silicon (Si) oxides, nitrides, halides, carbides or their composites (dielectrics in which other elements, simple substances, or compounds are mixed with dielectrics), aluminum (Al), chromium ( Cr), yttrium (Y), zirconia (Zr), tantalum (Ta), titanium (Ti), barium (Ba), indium (In), tin (Sn), zinc (Zn), magnesium (Mg), calcium ( A simple substance of a metal oxide such as Ca), cerium (Ce), copper (Cu), nitride, halide, carbide or a composite thereof can be used. The dielectric material only needs to be substantially transparent in the wavelength region where transmission polarization performance is to be obtained.

  The method for depositing the dielectric material is not particularly limited, and for example, a physical vapor deposition method such as a vacuum vapor deposition method, a sputtering method, or an ion plating method can be suitably used. In addition, when employ | adopting a roll process in a deposition process, a film feed speed is performed in the range of 0.1 m / min-100 m / min.

(2-4) Metal wire As a metal constituting the metal wire 103, in addition to aluminum and silver, copper, platinum, gold, or an alloy containing each of these metals as a main component according to the wavelength region of light of interest. Can also be used.

  The metal wire 103 is present at the upper side in the height direction from the side of the grid-like convex part and the top of the convex part, and the height of the metal wire 103 is 1.1 times or more and 10 times the height of the grid-like convex part In order to suppress absorption loss of transmitted light, a range of 1.3 times or more and 2.5 times or less is more preferable. The average value of the width of the metal wire 103 is preferably 0.2 times to 0.5 times the pitch P, and if it is 0.3 times to 0.4 times, both polarization characteristics and transmittance are compatible. It is most preferable to do.

  There is no particular limitation on the method for forming the metal wire 103 on the lattice-shaped convex portion, but the oblique deposition method under vacuum is preferable from the viewpoint of manufacturing cost and productivity. In the oblique deposition method, a metal is deposited while the deposition source has an incident angle α with respect to the normal of the base material in a plane (paper surface in FIG. 1) perpendicular to the extending direction of the lattice-shaped uneven portion 102a. It is a method of laminating. The preferable range of the incident angle α is determined from the cross-sectional shape of the grid-like convex portion and the metal wire 103 to be manufactured. In general, the incident angle α is preferably 5 ° to 40 °, more preferably 10 ° to 30 °. Furthermore, it is preferable to gradually reduce or increase the incident angle α while controlling the cross-sectional shape such as the height of the metal wire while considering the projection effect of the metal laminated during the vapor deposition. In addition, the extension direction of the grid | lattice-like uneven part 102a and the metal wire 103 becomes equal from such a manufacturing method.

  The amount of metal vapor deposition is determined by the shape of the grid-shaped convex portions, but is about 50 nm to 150 nm in average thickness. The average thickness here refers to the thickness of the deposited material on the assumption that the material is deposited on the smooth glass substrate from the direction perpendicular to the glass surface, and is used as a measure of the metal deposition amount. In addition, when employ | adopting a roll process in a vapor deposition process, a film feed rate is performed in the range of 0.1 m / min-100 m / min.

  From the viewpoint of optical characteristics, the metal laminated on the bottom of the concave portion of the concave and convex lattice is removed by etching as necessary. The etching method is not particularly limited as long as it can remove a necessary amount of metal without adversely affecting the base material and the dielectric layer, but from the viewpoint of productivity and equipment cost, a method of immersing in an aqueous solution of acid or alkali Is preferred.

(optical properties)
When an optical functional unit having polarization separation characteristics is used as a polarization beam splitter, the incident angle of transmitted and reflected light is freely designed by the optical system, but the transmission contrast is a polarization characteristic at the time of incidence at the angle used. If it is 5: 1 or more, or the reflection contrast is 5: 1 or more, it suitably acts on a display device or the like. The contrast of transmission or reflection is more preferably 10: 1 or more.

  Moreover, as an optical characteristic of an adhesive layer, it should just be transparent in a visible region, and it is more preferable to select a thing with a refractive index difference with an optical function body of 0.1 or less.

(Autonomy)
When an optical function body having polarization separation characteristics is used as a polarization beam splitter, it is used while being held in a mold or the like. It is assumed that sufficient self-supporting property is obtained if the condition that the reflected light is correctly specularly reflected is satisfied.

(Image clarity)
The image clarity is evaluated by a image clarity tester. The image clarity was evaluated by using a SUGA tester (ICM-1T) to evaluate the image clarity of the wire grid polarizer bonded with an adhesive.
The image clarity is evaluated by the following formula.
C (n) = (M−m) / (M + m) × 100
Here, n is the width of the slit, M is the amount of light transmitted through the light receiving side slit, and m is the amount of light leaked from the light receiving side slit light shielding part.

  In the case of an optical mirror capable of obtaining perfect image clarity, since light is completely shielded by the light-receiving side slit, m = 0, and the image clarity is 100%. The image clarity of the polarization reflecting surface of the wire grid polarizing plate was evaluated by the slit width (0.125 mm) on the light receiving side.

  There is a correlation between the deformation of the orange-peel-patterned polarization reflecting surface judged from the appearance and the image clarity value, and when the image clarity value is 85% or more, the deformation of the polarization reflecting surface is hardly visually recognized. It is not visually recognized that it is 90% or more. It is visually recognized as 80% or less, and clearly visible as 74% or less.

  In the above, as shown in FIG. 3, the optical function members 101 to 103 are provided with the adhesive layer 201 to form an optical function member, and the optical function body is bonded to the rigid substrate 401 via the adhesive layer 201. However, in the present invention, another optical function body is bonded via another adhesive layer to the optical function body 101 to 103 bonded to the rigid substrate 401 via the adhesive layer 201. The composite optical member formed is also included. That is, the composite optical member is bonded to the optical functional member, the adhesive layer of the optical functional member and the substrate bonded on one main surface, and the other main surface of the substrate via another adhesive layer. And another optical functional member.

  Next, examples performed for clarifying the effects of the present invention will be described. Here, a case where the optical function body is a wire grid polarizing plate will be described.

Example 1
<Preparation of a mold having a lattice-like uneven shape>
A transfer film having a grid-like uneven shape was produced using an ultraviolet curable resin. A Ni mold was used for the production of the lattice-shaped uneven transfer film. The Ni mold had a grid-like uneven shape with a pitch of 100 nm, and the cross-sectional shape of the grid-like uneven portion was a rectangle.

<Preparation of a grid-like convex transfer film roll>
About 0.01 mm of UV curable resin was continuously applied to a roll (film length 250 m) of ARTON (FEKP190 made by JSR) (hereinafter referred to as COP film) having a thickness of 190 μm, and the coated surface was covered with the above-mentioned fine concavo-convex lattice with a pitch of 100 nm. The film was brought into contact with the roll stamper, and irradiated with 1000 mJ / cm ^{2 of} ultraviolet rays using a UV lamp with a center wavelength of 365 nm from the film side, and the fine concavo-convex lattice of the roll stamper was continuously transferred, and then wound into a roll shape. . Hereinafter, this roll is referred to as an original roll.

  The obtained lattice-like convex transfer film was observed with an FE-SEM (Field Emission-Scanning Electron Microscope), and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch.

<Drying the raw roll>
In order to dry the water contained in the raw roll obtained as described above, the raw roll was transferred to a vacuum tank provided with three 200 W infrared heaters, and 2 m / It was run in minutes, and after heating, it was wound into a roll. The degree of vacuum when the film running was stopped was 0.03 Pa, and the degree of vacuum during film running (drying) was 0.15 Pa. Moreover, in order to know the surface temperature of the TAC film after passing through the heater, a thermo label was pasted on the TAC film in advance. The surface temperature of the TAC film after passing through the heater was between 60 ° C and 70 ° C.

<Formation of dielectric layer using sputtering method>
When the original fabric roll after drying was left in the vacuum chamber of the dryer for 12 hours, the film temperature dropped to 23 ° C. Thereafter, the grid-like convex portion transfer surface of the original fabric roll was transferred to a vacuum chamber for dielectric formation and metal wire formation. A reactive AC magnetron sputtering method was used for dielectric formation. Two silicon targets with a target size of 127 mm x 750 mm x 10 mmt are arranged, the distance from the substrate is 80 mm, the argon gas flow rate is 200 sccm, the nitrogen gas flow rate is 300 sccm, the output is 11 kW, the frequency is 37.5 kHz, and the traveling speed is 5 m / min. While unwinding, a silicon nitride layer was provided while being fed to the take-up roll side with a roll for film conveyance (main roller), and then taken up into a roll shape. The tension during sputtering was 30 N, the main roller temperature was 30 ° C., the background vacuum before starting sputtering was 0.005 Pa, and the vacuum during sputtering was 0.38 Pa. Silicon nitride was deposited on the Si chip under the same conditions, and the thickness of the silicon nitride layer was calculated using an ellipsometer.

<Aluminum deposition>
After forming silicon nitride as a dielectric layer on the grid-like convex transfer surface of the raw roll by sputtering, the film is fed by the main roller in the opposite direction to the sputtering, and grid-like convex is transferred by resistance heating vapor deposition A metal wire was formed on the surface and wound into a roll. In this embodiment, a case where aluminum (Al) is used as a metal will be described. At this time, the degree of vacuum before heating the vapor deposition boat was 0.005 Pa. In addition, an oblique vapor deposition method is used for the vapor deposition of aluminum, and the angle formed by the normal vapor deposition source on the substrate surface in a plane perpendicular to the vertical direction of the lattice starts from 32 ° (θs) and 15 ° (θd). A mask was placed so that it ended with.

  At this time, the mask opening width in the film conveyance direction was 60 mm, and the distance between the center of the mask opening and the vapor deposition boat was 400 mm. With the arrangement as described above, an aluminum wire having a purity of 99.9% or more and a wire diameter of 1.7 mm is placed on a heated boat while running the lattice-shaped convex transfer film at a film feed speed of 3.5 m / min. Vapor deposition was carried out at a feed rate of 200 mm / min. The total pressure during vapor deposition was 0.007 Pa. After vapor deposition, the raw roll was taken out of the vacuum chamber, and the aluminum film thickness was calculated from the emission intensity of fluorescent X-rays to be 110 nm. Therefore, the average film formation rate (v) of aluminum in this example was 126.4 nm / s as a value (130 / 1.03) obtained by dividing the film thickness of aluminum by the deposition time.

<Etching of aluminum>
The lattice-like convex transfer film roll formed with the silicon nitride and the aluminum film formed by the method described in the examples was placed in a 0.5 wt% NaOHaq bath at a temperature of 23 ° C. while unwinding the film. It was made to run for 2 seconds, and then this was washed with water and air-dried to obtain a roll of the intended wire grid film (hereinafter referred to as polarizing plate A).

<Independence evaluation>
An aluminum frame (formwork) 301 having a width of 5 mm and a thickness of 2 mm shown in FIG. 2A is prepared. Cut out the polarizing plate A into a 30 mm square, and sandwiched the polarizing plate A between a pair of aluminum frames 301 as shown in FIG. 2B, and then confirmed the 45-degree reflection position with the laser pointer irradiated from a position 200 mm away. did. Here, it was determined that the film having the center position shift of light within the range of 10 mm away from the polarizing plate A within 10 mm is self-supporting.

<Adhesive bonding>
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Nitto Denko Corporation adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was pasted together using HALTEC. For Tan δ of the adhesive, ARES (manufactured by TA Instruments) is used, the measurement temperature is 25 ° C., and the measurement mode is frequency dispersion (100 to 0.1 (rad / sec)), 25 mmφ parallel. Measurements were performed using plates. Here, a value with a frequency of 1.0 rad / sec was applied. At this time, the Tan δ value of HJ-9150W was 0.44. Moreover, adhesive force (vs. glass plate) was 12 N / 25 mm.

<Glass bonding>
Next, the wire grid polarizing plate having the adhesive and the glass plate (Schott B270) which is a rigid substrate were bonded together using an automatic bonding apparatus (HAL-650) (hereinafter, HALTECH) manufactured by Sankyo Corporation. .

<Image clarity evaluation>
Using a SUGA tester (ICM-1T), the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity was evaluated by the following formula.
C (n) = (M−m) / (M + m) × 100
Here, n is the width of the slit, M is the amount of light transmitted through the light receiving side slit, and m is the amount of light leaked from the light receiving side slit light shielding part.

  In the case of an optical mirror capable of obtaining perfect image clarity, since light is completely shielded by the light-receiving side slit, m = 0, and the image clarity is 100%. The image clarity of the reflective surface of the wire grid polarizer was evaluated by the slit width (0.125 mm) on the light receiving side. The image clarity of the wire grid polarizer of Example 1 was 95.6%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated. In addition, the case where almost no deformation was visually recognized by visual observation was marked with ◎, the case where it was slightly visually recognized was marked with ◯, the case where it was slightly visually recognized was marked with Δ, and the case where it was clearly visible was marked with ×.

(Example 2)
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Nichiei Kaken Kogyo Co., Ltd. adhesive (product name: SR30 38 μm) (Y) cut into a size of 80 mm × 80 mm was pasted together using HALTECH. For Tan δ of the adhesive, ARES (manufactured by TA Instruments) is used, the measurement temperature is 25 ° C., and the measurement mode is frequency dispersion (100 to 0.1 (rad / sec)), 25 mmφ parallel. Measurements were performed using plates. Here, a value with a frequency of 1.0 rad / sec was applied. At this time, the Tan δ value of SR30 was 0.32. Moreover, the adhesive force (vs. glass plate) was 10 N / 25 mm.

  Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 2 was 88%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Comparative Example 1)
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Sekisui Chemical Co., Ltd. adhesive (product name: WT # 5402A 25 μm) (Z) cut into a size of 80 mm × 80 mm was bonded using HALTEC. For Tan δ of the adhesive, ARES (manufactured by TA Instruments) is used, the measurement temperature is 25 ° C., and the measurement mode is frequency dispersion (100 to 0.1 (rad / sec)), 25 mmφ parallel. Measurements were performed using plates. Here, a value with a frequency of 1.0 rad / sec was applied. At this time, the value of Tan δ of WT # 5402A was 0.29. Moreover, adhesive force (vs. glass plate) was 8.4 N / 25 mm.

  Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 1 was 74%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 3)
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Nitto Denko Co., Ltd. adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was bonded using HALTEC.

  Next, the wire grid polarizing plate which has the said adhesive agent, and the acrylic board (Nitto resin Clarex) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 3 was 92%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

Example 4
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Nichiei Kaken Kogyo Co., Ltd. adhesive (product name: SR30 38 μm) (Y) cut into a size of 80 mm × 80 mm was bonded using HALTEC.

  Next, the wire grid polarizing plate which has the said adhesive agent, and the acrylic board (Nitto resin Clarex) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 3 was 86%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Comparative Example 2)
The polarizing plate A was cut into a size of 80 mm × 80 mm, and Sekisui Chemical Co., Ltd. adhesive (product name: WT # 5402A 25 μm) (Z) cut into a size of 80 mm × 80 mm was bonded using HALTEC.

  Next, the wire grid polarizing plate which has the said adhesive agent, and the acrylic board (Nitto resin Clarex) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 4 was 72%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 5)
Then, in the same procedure as in Example 1, about 0.01 mm of UV curable resin was continuously applied to a roll (film length 250 m) of PET (Toyobo A4300) (hereinafter COP film) having a thickness of 188 μm. Then, the coated surface is brought into contact with a roll stamper having a fine uneven grating with a pitch of 100 nm on the surface, and ultraviolet rays are irradiated from the film side with an ultraviolet lamp having a central wavelength of 365 nm at 1000 mJ / cm ² to form the fine uneven grating of the roll stamper. After continuously transferring, it was wound up into a roll. Hereinafter, this roll is referred to as an original roll. The obtained lattice-like convex transfer film was observed by FE-SEM, and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch. Aluminum deposition and etching were performed to obtain a target roll of wire grid film (hereinafter referred to as polarizing plate B).

  The polarizing plate B was cut into a size of 80 mm × 80 mm, and Nitto Denko Co., Ltd. adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 5 was 93%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 6)
The polarizing plate B was cut into a size of 80 mm × 80 mm, and Nichiei Kaken Kogyo Co., Ltd. adhesive (product name: SR30 38 μm) (Y) cut into a size of 80 mm × 80 mm was pasted together using HALTECH. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 6 was 85%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Comparative Example 3)
The polarizing plate B was cut into a size of 80 mm × 80 mm, and Sekisui Chemical Co., Ltd. adhesive (product name: WT # 5402A 25 μm) (Z) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 3 was 68%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 7)
Then, in the same procedure as in Example 1, about 0.01 mm of UV curable resin was applied to a PMMA plate (Nitto Resin Clarex) (hereinafter referred to as PMMA plate) having a thickness of 200 μm using a bar coater. The fine concavo-convex grid with 100 nm pitch was brought into contact with a stamper on the surface, and ultraviolet rays were irradiated from the film side using an ultraviolet lamp with a center wavelength of 365 nm at 1000 mJ / cm ² to transfer the fine concavo-convex grid of the stamper. The obtained lattice-like convex transfer film was observed by FE-SEM, and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch. Aluminum deposition and etching were performed to obtain a target wire grid film (hereinafter referred to as polarizing plate C).

  The polarizing plate C was cut into a size of 80 mm × 80 mm, and Nitto Denko Co., Ltd. adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 7 was 92%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 8)
The polarizing plate C was cut into a size of 80 mm × 80 mm, and Nichiei Kaken Kogyo Co., Ltd. adhesive (product name: SR30 38 μm) (Y) cut into a size of 80 mm × 80 mm was pasted together using HALTECH. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Example 8 was 88%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Comparative Example 4)
The polarizing plate C was cut into a size of 80 mm × 80 mm, and Sekisui Chemical Co., Ltd. adhesive (product name: WT # 5402A 25 μm) (Z) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 4 was 70%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

Example 9
Thereafter, in the same manner as in Example 1, about 0.01 mm of UV curable resin was continuously applied to a roll (film length 250 m) of a TAC film (Fuji Film Fujitac) (hereinafter referred to as TAC film) having a thickness of 80 μm. Then, the coated surface is brought into contact with the roll stamper having the fine irregularity grid of 100 nm pitch on the surface, and ultraviolet rays are irradiated from the film side with an ultraviolet lamp having a central wavelength of 365 nm at 1000 mJ / cm ² , Was continuously transferred and then wound into a roll. Hereinafter, this roll is referred to as an original roll. The obtained lattice-like convex transfer film was observed by FE-SEM, and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch. Aluminum deposition and etching were performed to obtain a target roll of wire grid film (hereinafter referred to as polarizing plate D).

  The polarizing plate D was cut into a size of 80 mm × 80 mm, and Nitto Denko Corporation adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was pasted together using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 5 was 81%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 10)
The polarizing plate D was cut into a size of 80 mm × 80 mm, and Nichiei Kaken Kogyo Co., Ltd. adhesive (product name: SR30 38 μm) (Y) cut into a size of 80 mm × 80 mm was pasted together using HALTECH. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 6 was 77%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Comparative Example 5)
The polarizing plate D was cut out to a size of 80 mm × 80 mm, and Sekisui Chemical Co., Ltd. adhesive (product name WT # 5402A 25 μm) (Z) cut out to a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 7 was 57%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

Example 11
Thereafter, in the same procedure as in Example 1, about 0.01 mm of UV curable resin was continuously applied to a roll (film length 250 m) of PET (Nitto Resin Clarex) (hereinafter COP film) having a thickness of 100 μm. Then, the coated surface is brought into contact with the roll stamper having the fine irregularity grid of 100 nm pitch on the surface, and ultraviolet rays are irradiated from the film side with an ultraviolet lamp having a central wavelength of 365 nm at 1000 mJ / cm ² , Was continuously transferred and then wound into a roll. Hereinafter, this roll is referred to as an original roll. The obtained lattice-like convex transfer film was observed by FE-SEM, and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch. Aluminum deposition and etching were performed to obtain a target roll of wire grid film (hereinafter referred to as polarizing plate E).

  The polarizing plate E was cut into a size of 80 mm × 80 mm, and Nitto Denko Co., Ltd. adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 8 was 78%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

(Example 12)
Thereafter, the UV curable resin was continuously applied to a roll (film length: 250 m) of a COP (JSR R-50) (hereinafter referred to as COP film) having a thickness of about 100 mm by the same procedure as Example 1. The coated surface is brought into contact with a roll stamper having a fine uneven grating with a pitch of 100 nm on the surface, and ultraviolet rays are irradiated from the film side with an ultraviolet lamp having a central wavelength of 365 nm at a wavelength of 1000 mJ / cm ^2. The lattice was continuously transferred and then wound into a roll. Hereinafter, this roll is referred to as an original roll. The obtained lattice-like convex transfer film was observed by FE-SEM, and it was confirmed that the cross-sectional shape was rectangular and the shape from the upper surface was a striped lattice. Moreover, the value of the convex part height / the half value width of the convex part of the lattice-like convex part was 2.9, and the half value width of the lattice-like convex part was 0.35 times the pitch. Aluminum deposition and etching were performed to obtain a target roll of wire grid film (hereinafter referred to as a polarizing plate F).

  The polarizing plate F was cut into a size of 80 mm × 80 mm, and Nitto Denko Co., Ltd. adhesive (product name: HJ-9150W 50 μm) (X) cut into a size of 80 mm × 80 mm was bonded using HALTEC. Next, the wire grid polarizing plate which has the said adhesive agent, and the glass plate (Schott B270) which is a board | substrate which has rigidity were bonded together using HALTECH. In the same procedure as in Example 1, the image clarity of the wire grid polarizer after bonding was evaluated. The image clarity of the wire grid polarizer of Comparative Example 9 was 75%. Further, the deformation of the orange-peel-patterned polarizing reflecting surface was visually evaluated.

  From Table 1 above, the self-supporting property can be imparted by holding the wire grid polarizer on a substrate having a specific thickness or more. Moreover, by using a specific adhesive, good image clarity was obtained and it was possible to act as a mirror surface.

  In addition, this invention is not limited to the said embodiment, It can implement variously. In the above-described embodiment, the size, shape, and the like illustrated in the accompanying drawings are not limited thereto, and can be appropriately changed within a range in which the effect of the present invention is exhibited. In addition, various modifications can be made without departing from the scope of the object of the present invention.

  The optical functional member of the present invention can be suitably used in a wide range of fields such as various optical devices, display devices, and light sources.

DESCRIPTION OF SYMBOLS 101 Base material 102 Pattern layer 103 Metal layer 201 Adhesive layer 301 Formwork 401 Rigid board | substrate H1 Base material thickness H2 Adhesive layer thickness

Claims (6)

  An optical function body, and a ratio Tanδ (G ″ / G ′) between a loss elastic modulus (G ″) and a storage elastic modulus (G ′) provided on the optical function body is 0.3 or more and 1 An optical functional member, comprising: an adhesive layer that is 0.0 or less.   The optical function member according to claim 1, wherein the adhesive force of the adhesive constituting the adhesive layer is 8 (N / 25 mm) or more and 25 (N / 25 mm) or less with respect to the glass plate.   The optical function member according to claim 1, wherein the optical function body has a thickness of 180 μm or more.   The optical functional member according to claim 1, wherein the adhesive layer has a thickness of 30 μm or more.   The optical functional member according to claim 1, wherein the optical functional body is a wire grid polarizing plate.   6. A composite optical member comprising: the optical functional member according to claim 1; and the substrate bonded to one of the main surfaces of the adhesive layer of the optical functional member.

Images