JP2013235034A5 - - Google Patents
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- JP2013235034A5 JP2013235034A5 JP2012105468A JP2012105468A JP2013235034A5 JP 2013235034 A5 JP2013235034 A5 JP 2013235034A5 JP 2012105468 A JP2012105468 A JP 2012105468A JP 2012105468 A JP2012105468 A JP 2012105468A JP 2013235034 A5 JP2013235034 A5 JP 2013235034A5
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- Prior art keywords
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- polymerization
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- 239000011347 resin Substances 0.000 claims 8
- 229920005989 resin Polymers 0.000 claims 8
- 238000004519 manufacturing process Methods 0.000 claims 6
- 239000000178 monomer Substances 0.000 claims 6
- 238000006116 polymerization reaction Methods 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- 229920001477 hydrophilic polymer Polymers 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 239000000758 substrate Substances 0.000 claims 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000003505 polymerization initiator Substances 0.000 claims 2
- AFXKUUDFKHVAGI-UHFFFAOYSA-N 1-methyl-3-methylidenepyrrolidin-2-one Chemical compound CN1CCC(=C)C1=O AFXKUUDFKHVAGI-UHFFFAOYSA-N 0.000 claims 1
- ZZDBHIVVDUTWJC-UHFFFAOYSA-N 1-methyl-5-methylidenepyrrolidin-2-one Chemical compound CN1C(=C)CCC1=O ZZDBHIVVDUTWJC-UHFFFAOYSA-N 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N 2-Pyrrolidone Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
- LWLHCZLCSDUDEL-UHFFFAOYSA-O C[N+](C)(C)CC(O)=P(=O)CCOC(=O)C=C Chemical compound C[N+](C)(C)CC(O)=P(=O)CCOC(=O)C=C LWLHCZLCSDUDEL-UHFFFAOYSA-O 0.000 claims 1
- 229940088644 N,N-dimethylacrylamide Drugs 0.000 claims 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N N,N-dimethylprop-2-enamide Chemical group CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinylpyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 230000000379 polymerizing Effects 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (6)
上記親水性モノマーを重合する工程
を有し、
上記接触が、溶液への基材の浸漬であり、
上記親水性モノマーが、Ｎ，Ｎ−ジメチルアクリルアミド、Ｎ−ビニルピロリドン、１−メチル−３−メチレン−２−ピロリドン、１−メチル−５−メチレン−２−ピロリドン、５−メチル−３−メチレン−２−ピロリドン、（メタ）アクリル酸、２−ヒドロキシエチル（メタ）アクリレート、２−（メタ）アクリルオキシエチルホスホリルコリン及びカルボキシベタイン構造含有（メタ）アクリレートからなる群より選ばれる少なくとも１種であり、
上記溶液における溶媒１００質量部に対する親水性モノマーの含有量が０．１質量部以上３０質量部以下であり、
上記溶液の溶媒が水を主成分として含有し、
上記溶液における溶媒１００質量部に対する重合開始剤の含有量が０．００００１質量部以上０．１質量部以下であり、
上記親水性モノマーの重合により得られる親水性重合体が、上記基材の少なくとも表面領域に侵入した状態で、基材を形成する樹脂と絡み合って固定される表面処理樹脂成形体の製造方法。 It possesses a resin base material, a hydrophilic monomer, the step of contacting a solution containing a polymerization initiator and a solvent, and a step of polymerizing the hydrophilic monomer,
The contact is immersion of the substrate in the solution;
The hydrophilic monomer is N, N-dimethylacrylamide, N-vinylpyrrolidone, 1-methyl-3-methylene-2-pyrrolidone, 1-methyl-5-methylene-2-pyrrolidone, 5-methyl-3-methylene- It is at least one selected from the group consisting of 2-pyrrolidone, (meth) acrylic acid, 2-hydroxyethyl (meth) acrylate, 2- (meth) acryloxyethyl phosphorylcholine and carboxybetaine structure-containing (meth) acrylate,
The content of the hydrophilic monomer with respect to 100 parts by mass of the solvent in the solution is 0.1 part by mass or more and 30 parts by mass or less,
The solvent of the solution contains water as a main component,
The content of the polymerization initiator with respect to 100 parts by mass of the solvent in the solution is 0.00001 parts by mass or more and 0.1 parts by mass or less,
A method for producing a surface-treated resin molded article, wherein a hydrophilic polymer obtained by polymerization of the hydrophilic monomer is intertwined with a resin forming a base material in a state where the hydrophilic polymer penetrates at least a surface region of the base material .
をさらに有し、
上記組成物が親水性重合体及び／又は有機溶媒を実質的に含まない請求項１から請求項５のいずれか１項に記載の表面処理樹脂成形体の製造方法。 Further comprising the step of forming the substrate using a composition containing a monomer for the substrate,
The method for producing a surface-treated resin molded article according to any one of claims 1 to 5, wherein the composition does not substantially contain a hydrophilic polymer and / or an organic solvent.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012105468A JP2013235034A (en) | 2012-05-02 | 2012-05-02 | Manufacturing method of surface treatment resin molding, and surface treatment resin molding |
| PCT/JP2013/062489 WO2013164989A1 (en) | 2012-05-02 | 2013-04-26 | Method for producing surface-treated resin molded body, and surface-treated resin molded body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012105468A JP2013235034A (en) | 2012-05-02 | 2012-05-02 | Manufacturing method of surface treatment resin molding, and surface treatment resin molding |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013235034A JP2013235034A (en) | 2013-11-21 |
| JP2013235034A5 true JP2013235034A5 (en) | 2015-06-11 |
Family
ID=49514388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012105468A Pending JP2013235034A (en) | 2012-05-02 | 2012-05-02 | Manufacturing method of surface treatment resin molding, and surface treatment resin molding |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2013235034A (en) |
| WO (1) | WO2013164989A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3141943B1 (en) * | 2014-05-09 | 2022-07-13 | Interojo Inc. | Hydrogel contact lens having wet surface, and manufacturing method therefor |
| WO2022044679A1 (en) * | 2020-08-27 | 2022-03-03 | 東京応化工業株式会社 | Surface treatment liquid and hydrophilization treatment method |
| CN113698653B (en) * | 2021-09-18 | 2022-08-23 | 江南大学 | Hydrophilic coating based on acrylic polymerization and photocuring and preparation method thereof |
| US20240168200A1 (en) * | 2021-11-12 | 2024-05-23 | Pegavision Corporation | Contact lens and manufacturing method thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4806382A (en) * | 1987-04-10 | 1989-02-21 | University Of Florida | Ocular implants and methods for their manufacture |
| US6011082A (en) * | 1997-06-02 | 2000-01-04 | Pharmacia & Upjohn Ab | Process for the modification of elastomers with surface interpreting polymer networks and elastomers formed therefrom |
| JP2001337298A (en) * | 2000-03-21 | 2001-12-07 | Menicon Co Ltd | Ocular lens material having hydrophilic surface and method for manufacturing the same |
| US6372815B1 (en) * | 2000-04-18 | 2002-04-16 | Ocular Sciences Inc | Ophthalmic lenses and compositions, and methods for producing same |
| MXPA02011857A (en) * | 2000-05-30 | 2003-04-10 | Novartis Ag | Coated articles. |
| JP3993097B2 (en) * | 2000-10-16 | 2007-10-17 | ノバルティス アクチエンゲゼルシャフト | Method of coating material surface |
| US6835410B2 (en) * | 2001-05-21 | 2004-12-28 | Novartis Ag | Bottle-brush type coatings with entangled hydrophilic polymer |
| JP3931089B2 (en) * | 2002-01-24 | 2007-06-13 | Ｈｏｙａヘルスケア株式会社 | Method for producing soft contact lens comprising silicone hydrogel having hydrophilic surface and soft contact lens |
| JP4631471B2 (en) * | 2004-03-08 | 2011-02-16 | 東レ株式会社 | Surface treatment method for plastic molded product and surface-treated plastic molded product |
-
2012
- 2012-05-02 JP JP2012105468A patent/JP2013235034A/en active Pending
-
2013
- 2013-04-26 WO PCT/JP2013/062489 patent/WO2013164989A1/en active Application Filing
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