JP2013227310A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair cosmetic which has both a good setting force and a non-flaking property and is excellent in a hair-restyling performance and a non-sticky property.SOLUTION: A hair cosmetic is characterized by comprising the following components (A)-(D): (A) a (meth)acryl silicone-based graft copolymer; (B) one or more film-forming polymers selected from nonionic, amphoteric, and cationic polymers; (C) a monohydric lower alcohol; and (D) a polyalkylene glycol having a number-average molecular weight of 400-20,000.

Description

The present invention relates to a hairdressing cosmetic, and more specifically, a (meth) acryl silicone graft copolymer, a film-forming polymer, a monovalent lower alcohol, and a polyalkylene glycol having a number average molecular weight of 400 to 20000 are blended. The present invention relates to a hair styling cosmetic characterized in that it has excellent hair styling power, is less prone to flaking, is capable of re-hair styling, and is less sticky.

Conventionally, in hairdressing materials, a film-forming polymer or an oily component has been used as a hair setting agent in order to fix or hold a hairstyle. For example, in the case of a film-forming polymer, various polymers such as anionic, amphoteric, cationic, and nonionic are used, depending on the characteristics of the product such as hair spray, hair mousse, curler lotion, hair gel, and so on. Or have been used in combination. Such a film-forming polymer can impart an excellent setting force, but on the other hand, the formed film is hard, and there are cases where a feeling of stickiness or squeaking occurs. In addition, the oil component does not have the same setting power as a film-forming polymer, but does not form a film, so there is little hardness and stiffness, and there is also an effect of imparting gloss. Has been used for many things. Among these, solid oils have been widely used in emulsifier-type hair styling agents due to their ease of return when the hairstyle collapses and re-styling properties (see, for example, Patent Documents 1 to 3).

In recent years, in particular, a lot of studies have been made on a preparation technique that is excellent not only in setting power but also in re-styling. For example, there are techniques such as combining qualitative and quantitative characteristics of film-forming polymers (see, for example, Patent Documents 4 and 5).

On the other hand, not only combining the above existing components, but also developing components that give further added value. For example, since a (meth) acrylic polymer is transparent and forms a film and has good workability, it is widely used as a coating material, an adhesive material, an ink material, an external skin material, a cosmetic material, and the like. However, acrylic resins have many problems due to their high polarity, and various copolymers have been developed. Among them, an acrylic-silicone graft obtained by radical copolymerization of a dimethylpolysiloxane compound having a radical polymerizable group at one end of a molecular chain and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate. There are a copolymer (for example, see Patent Document 6), an amphiphilic block copolymer containing a polysiloxane block and a cationic block (for example, see Patent Document 7).

JP-A-10-45546 JP 11-124316 A JP 2004-67622 A JP 2004-182612 A JP 2010-229070 A Japanese Patent No. 2704730 Special table 2010-518190 gazette

However, when a film-forming polymer having a high film strength is used in order to realize a high setting force, there is a case where it feels stiff or flaking. In addition, a film forming agent having a low film strength has a problem that a sufficient setting force cannot be obtained, and it is difficult to achieve both the setting force and the lack of flaking.

Furthermore, although a preparation comprising a film-forming polymer and a polyalkylene glycol is excellent in re-styling, it cannot prevent flaking from the film-forming agent and is not satisfactory with respect to stickiness during use. It was.

Accordingly, an object of the present invention is to provide a hair styling cosmetic material that achieves both set power and lack of flaking, and is excellent in re-hair styling properties and non-stickiness.

In view of this situation, the present inventors have conducted extensive studies to solve the above-mentioned problems, and as a result, have conventionally used nonionic, amphoteric and cationic film-forming polymers and a hair styling using a polyalkylene glycol. Although the hair setting power can be improved to some extent and the setting power can be maintained by adjusting the amount of ingredients, flaking may occur. Therefore, as a result of investigating the control of setting force with another component, it is possible to achieve both good setting force and lack of flaking by using (meth) acryl silicone graft copolymer together. I found the knowledge. As a result of further investigations, by setting the number average molecular weight of the polyalkylene glycol to 400 to 20000, a hair styling cosmetic that achieves both good setting power and no flaking, has high styling properties, and is less sticky. As a result, the present invention was completed.

That is, the present invention provides the following components (A) to (D); (A) (meth) acryl silicone-based graft copolymer (B) one or more film-forming properties selected from nonionic, amphoteric, and cationic. The present invention provides a hair styling cosmetic characterized by blending a molecular (C) monovalent lower alcohol (D) polyalkylene glycol having a number average molecular weight of 400-20000.

The component (A) is a polymer obtained by reacting the following radically polymerizable monomers (a), (b), (c) and (d), and is 99.5% ethanol at 25 ° C. A (meth) acryl silicone graft copolymer that dissolves in an amount of 50 mass% or more. (A) The following general formula (I)
(In the formula, Me is a methyl group, R 1 is a hydrogen atom or a methyl group, R 2 is a linear or branched C 1-10 divalent divalent alkyl group which may contain 1 or 2 ether bonds. (B) a compound represented by the following formula (II): a saturated hydrocarbon group, R3 is a saturated hydrocarbon group having 1 to 10 carbon atoms, and m is an integer of 5 to 100.
(In the formula, R4 may be a hydrogen atom or a methyl group, R5, R6 and R7 may be the same or different, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X is -O-, -NH-, -O. —CH ₂ — or —O—CH ₂ CH (OH) —, Y is a linear or branched divalent saturated hydrocarbon group having 1 to 4 carbon atoms, and Z ⁻ represents a counter anion. A compound represented by the formula (III)
(In the formula, R8 and R9 may be the same or different, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R10 and R11 may be the same or different, and a hydrogen atom or an alkyl group having 1 to 18 carbon atoms. Group, Z ⁻ represents a counter anion.) (C) at least one selected from the compounds represented by formula (IV)
(Wherein R12 represents a hydrogen atom or a methyl group, R13 represents a hydrogen atom or a linear or branched alkyl group having 1 to 3 carbon atoms) (d) the following general formula (V )
(In the formula, R14 represents a hydrogen atom or a methyl group, and R15 represents a hydroxyalkyl group having 1 to 4 carbon atoms).

Provided is a hair styling cosmetic characterized in that the nonionic film-forming polymer of the component (B) is one or more selected from polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers. It is.

The amphoteric film-forming polymer of the component (B) is a hairstyling cosmetic characterized in that it is a hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer. .

The cationic film-forming polymer of the component (B) is polyquaternium-11, and provides a hair styling cosmetic.

Also provided is a hair styling cosmetic characterized in that the blending mass ratio of the component (A) and the component (B) is in the range of (A) :( B) = 1: 10 to 2: 1. Is.

The present invention also provides a hair styling cosmetic characterized by having a viscosity at 25 ° C. of 1000 mPa · s or less.

Furthermore, the present invention provides a hair styling cosmetic characterized by being housed in a container that can be used by spraying in a mist form.

The hairdressing cosmetic composition of the present invention has the advantages of achieving both good setting power and no flaking, high re-styling properties, and less stickiness.

Hereinafter, the present invention will be specifically described with a focus on preferred embodiments. In the present specification, “to” means a range including numerical values before and after.

The component (A) (meth) acryl silicone graft copolymer used in the hairdressing cosmetic composition of the present invention contains at least the following radically polymerizable monomers (a), (b), (c) and (d). It is a polymer obtained by reaction, and includes a polymer obtained by adding a copolymerizable monomer other than (a) to (d) and reacting. In the present invention, (meth) acryl means to include acrylic and methacrylic. The (meth) acryl silicone graft copolymer of the present invention dissolves in an amount of 50% by mass or more in 99.5% ethanol at 25 ° C. The charging ratio of each monomer is not limited as long as the effects of the present invention are exhibited, but (a) = 20 to 50% by mass, (b) = 0. It is 5-4 mass%, (c) and (d) = 46-79.5 mass%, and it is preferable that it is (c) / (d) = 0.5-1.5. When a copolymerizable monomer other than (a) to (d) is used, the total amount of the monomers (a) to (d) is preferably 66.5% by mass or more based on the total. In addition, in this invention, the preparation ratio of a monomer is substantially synonymous with those composition ratios in a copolymer. The (meth) acryl silicone graft copolymer of the present invention is a B-type rotational viscometer at 25 ° C. of an ethanol solution obtained by dissolving the copolymer in 99.5% ethanol so that the copolymer becomes 20% by mass. The viscosity (unit mPa · s = CS) measured by using is 50 to 250, preferably 70 to 150. The Tg of the (meth) acryl silicone graft copolymer of the present invention is preferably −10 to 40 ° C., more preferably 0 to 30 ° C. Here, Tg represents the value of Tg calculated by the following Fox equation. 1 / Tg = W ₁ / Tg ₁ + W ₂ / Tg ₂ +... + W _n / Tg _{n In the} above formula, W ₁ to W _n are n types of monomers used for the synthesis of a hair cosmetic base. It indicates each weight fraction of, Tg _n is from Tg _1, a glass transition temperature of the homopolymer where only the monomer is obtained by polymerizing. Furthermore, the (meth) acryl silicone graft copolymer of the present invention includes various forms such as a random copolymer and a block copolymer.

Below, the monomer which is a raw material of a copolymer is demonstrated. (A) Radical polymerizable monomer represented by general formula (I)

In the formula, Me represents a methyl group, and R1 represents a hydrogen atom or a methyl group. R2 represents a linear or branched divalent saturated hydrocarbon group having 1 to 10 carbon atoms, and may contain one or two ether bonds. Specifically, —CH ₂ —, — (CH ₂ ) ₂ , — (CH ₂ ) ₅ —, — (CH ₂ ) ₁₀ —, —CH ₂ —CH (CH ₃ ) —CH ₂ —, —CH ₂ CH ₂ OCH ₂ CH ₂ CH ₂ —, —CH ₂ CH ₂ OCH ₂ (CH ₃ ) CH ₂ —, —CH ₂ CH ₂ OCH ₂ CH ₂ CH ₂ OCH ₂ CH ₂ CH ₂ — and the like are exemplified. R3 has 1 carbon
Represents a saturated hydrocarbon group of 10 to 10, specifically, methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i-butyl group, t-butyl group , N-pentyl group, n-hexyl group, n-nonyl group, isononyl group, n-decyl group and other alkyl groups having 1 to 10 carbon atoms; cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cyclo C1-C10 cycloalkyl groups such as heptyl, cyclooctyl, and cyclododecyl; cyclopropylmethyl, 2-cyclopropylethyl, cyclobutylmethyl, cyclopentylmethyl, 3-cyclopentylpropyl, cyclo Cyclohexane having 1 to 10 carbon atoms such as hexylmethyl group, 2-cyclohexylethyl group, cycloheptylmethyl group, cyclooctylmethyl group, etc. An alkylalkyl group is mentioned. m represents an integer of 5 to 100.

The monomer represented by the formula (I) is, for example, the formula (1-a)

(Meth) acrylate substituted chlorosilane compound represented by the formula (1-b)

Can be obtained by dehydrochlorination reaction according to a conventional method, but the synthesis method is not limited thereto.

Specific examples of the monomer represented by the formula (I) include the following. In the following formulae, Me represents a methyl group, and n-Bu represents an n-butyl group.

(B) The radically polymerizable monomer (b) component represented by the formula (II) or the formula (III) is at least one selected from the cationic compounds represented by the following formula (II) or the formula (III). is there.

In formula (II), R4 represents a hydrogen atom or a methyl group. R5, R6 and R7 may be the same or different and each represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. Examples of the alkyl group having 1 to 4 carbon atoms include a methyl group, an ethyl group, an n-propyl group, Examples include i-propyl group, n-butyl group, s-butyl group, i-butyl group, and t-butyl group. X represents —O—, —NH—, —O—CH ₂ — or —O—CH ₂ CH (OH) —. Y represents a linear or branched divalent saturated hydrocarbon group having 1 to 4 carbon atoms, —CH ₂ —, — (CH ₂ ) ₂ , — (CH ₂ ) ₃ —, — (CH ₂ ) ₄ —, —CH ₂ —CH (CH ₃ ) —CH ₂ — and the like. Z ⁻ is a counter anion, and examples thereof include chlorine ion, bromine ion, hydrogen sulfate ion, nitrate ion, perchlorate ion, boron tetrafluoride ion, and phosphorus hexafluoride ion.

In formula (III), R8 and R9 may be the same or different and each represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. Examples of the alkyl group having 1 to 4 carbon atoms include a methyl group, an ethyl group, and n- Examples are propyl, i-propyl, n-butyl, s-butyl, i-butyl and t-butyl. R10 and R11 may be the same or different and each represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms. Examples of the alkyl group having 1 to 18 carbon atoms include a methyl group, an ethyl group, an n-propyl group, i- Propyl group, n-butyl group, s-butyl group, i-butyl group, t-butyl group, n-pentyl group, n-hexyl group, n-nonyl group, isononyl group, n-decyl group, lauryl group, tridecyl Group, myristyl group, n-pentadecyl group, palmityl group, heptadecyl group, stearyl group and the like.

(C) Radical polymerizable monomer represented by formula (IV)

In the formula, R12 represents a hydrogen atom or a methyl group. R13 represents a hydrogen atom or a linear or branched alkyl group having 1 to 3 carbon atoms, and examples of the linear or branched alkyl group having 1 to 3 carbon atoms include a methyl group, an ethyl group, and n -Propyl group and i-propyl group are exemplified.

(D) Radical polymerizable monomer represented by formula (V)

In the formula, R14 represents a hydrogen atom or a methyl group. R15 represents a hydroxyalkyl group having 1 to 4 carbon atoms, and examples thereof include a hydroxymethyl group, a 2-hydroxyethyl group, a 3-hydroxy-n-propyl group, and a 4-hydroxy-n-butyl group.

(E) Other copolymerizable monomers Examples of the other copolymerizable monomers include the following. ((Meth) acrylic monomer) (meth) acrylic acid n-butyl, (meth) acrylic acid isobutyl, (meth) acrylic acid t-butyl, (meth) acrylic acid 2-ethylhexyl, (meth) acrylic acid n -Hexyl, n-octyl (meth) acrylate, cyclohexyl (meth) acrylate, decyl (meth) acrylate, undecyl (meth) acrylate, lauryl (meth) acrylate, tridecyl (meth) acrylate, (Meth) acrylic acid myristyl, (meth) acrylic acid pentadecyl, (meth) acrylic acid palmityl, (meth) acrylic acid heptadecyl, (meth) acrylic acid stearyl, (meth) acrylic acid isostearyl, (meth) acrylic acid oleyl , Having (meth) acrylic acid behenyl, linear, branched or alicyclic hydrocarbon groups (meta Acrylates; Acrylonitrile; Acrylamide, diacetone acrylamide, N, N-dimethylacrylamide, Nt-butylacrylamide, N-octylacrylamide, Nt-octylacrylamide, etc. (meth) acrylamide; 2- (meth) acrylamide 2-methylpropanesulfonic acid and other sulfonic acid group-containing (meth) acrylamide; aminoethyl (meth) acrylate, t-butylaminoethyl methacrylate, alkylaminoalkyl (meth) acrylate such as methylaminoethyl (meth) acrylate; dimethyl Dialkylaminoalkyl (meth) acrylates such as aminoethyl (meth) acrylate and diethylaminoethyl (meth) acrylate; dimethylaminoethyl (meth) acrylamide, di Dialkylaminoalkyl (meth) methacrylamides such as tilaminoethyl (meth) acrylamide; cyclic compounds such as tetrahydrofurfuryl (meth) acrylate, isobornyl (meth) acrylate, glycidyl (meth) acrylate, and meth) acrylic Acid esters; (meth) acrylic acid alkoxyalkyl esters such as ethoxyethyl (meth) acrylate and methoxyethyl (meth) acrylate; polyalkylenes such as polyethylene glycol mono (meth) acrylate and polypropylene glycol mono (meth) acrylate Monoesters of glycol and (meth) acrylic acid; sulfonic acid group-containing (meth) acrylic esters; (meth) acryloyloxyalkyl phosphate monoesters such as (meth) acryloyloxyethyl phosphate; (Meth) acrylic acid glyceryl, 2-methacryloyloxyethyl succinic acid, 2- (meth) acryloyloxyethyl phthalic acid, β-carboxyethyl acrylate, acryloyloxyethyl succinate, 2- (meth) acryloyloxyethyl tetrahydrophthalic acid, 2- (meth) acryloyloxyethyl hexahydrophthalic acid; 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, polyethylene (n = 2) -50) Glycol di (meth) acrylate, propylene glycol di (meth) acrylate, polypropylene (n = 2-50) glycol di (meth) acrylate, butylene glycol di (meth) acrylate, dipentylglycol Di (meth) acrylate, neopentyl glycol di (meth) acrylate, trimethylolpropane di (meth) acrylate, methylenebisacrylamide, bisphenol F EO modified (n = 2-50) di (meth) acrylate, bisphenol A EO modified ( n = 2-50) diacrylate, bisphenol S EO modified (n = 2-50) di (meth) acrylate, trimethylolethane tri (meth) acrylate, trimethylolpropane tri (meth) acrylate, trimethylolpropane tricaprolacto Nate tri (meth) acrylate, trimethylolhexane tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, diglycerin tetra (meth) Acrylate, ditrimethylolpropane tetra (meth) acrylate, ditrimethylolpropane tetracaprolactonate, tetra (meth) acrylate, ditrimethylolethanetetra (meth) acrylate, ditrimethylolbutanetetra (meth) acrylate, ditrimethylolhexanetetra (meta) ) Ethylene such as acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, tripentaerythritol hexa (meth) acrylate, tripentaerythritol hepta (meth) acrylate, tripentaerythritol octa (meth) acrylate (Meth) acrylate etc. which have 2 or more of polyunsaturated double bonds are illustrated.

(Monomers other than (meth) acrylic) Unsaturated monocarboxylic acids such as crotonic acid; Aromatic vinyl compounds such as styrene; Unsaturated dicarboxylic acids such as itaconic acid, maleic acid, fumaric acid, maleic anhydride, citraconic acid; Monoalkyl esters of unsaturated dicarboxylic acids such as maleic acid monoalkyl esters, fumaric acid monoalkyl esters, itaconic acid monoalkyl esters; sulfonic acid group-containing monomers such as vinyl sulfonic acid, (meth) allyl sulfonic acid, etc. Alkene sulfonic acids of the above; aromatic vinyl group-containing sulfonic acids such as α-methylstyrene sulfonic acid; primary to tertiary amino group-containing unsaturated compounds such as (meth) allylamine; amino groups such as N, N-dimethylaminostyrene Aromatic vinyl compounds; divinylbenzene, diisopropenylbenzene, Compounds having 2 or more ethylenically unsaturated double bonds, such as livinylbenzene; Urethane oligomers having 2 or more ethylenically unsaturated double bonds; Silicone compounds having 2 or more ethylenically unsaturated double bonds; Acetic acid Examples include vinyl and vinyl pyrrolidone.

The blending amount of the component (A) in the hairdressing cosmetic composition of the present invention is not particularly limited, but is preferably 0.01 to 10% by mass (hereinafter simply referred to as “%”), more preferably 0, based on the total amount of the composition. 0.05 to 6%, which is suitable for effects such as no flaking and no stickiness.

The component (B) nonionic, amphoteric, and cationic film-forming polymer used in the present invention is a component that mainly contributes to setting power and the like, and is not particularly limited as long as it is usually used in cosmetics. However, the following can be illustrated.

Nonionic polymers include, for example, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, polyvinyl alcohol, and polyurethane. Rubiscol K (manufactured by BASF), PVP / VA (manufactured by ISP), Gohsenol series Commercial products such as (Nippon Gosei Co., Ltd.), Kuraray Poval Series (Kuraray), Acorn Series (Osaka Organic Chemical Industry Co., Ltd.) can be used.

As amphoteric polymers, N-methacryloylethyl N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide copolymer Examples include acrylic acid / dimethyldiallylammonium chloride / acrylamide copolymer, dimethyldiallylammonium chloride / acrylic acid copolymer, Yuka Former series (Mitsubishi Chemical Co., Ltd.), Amphomer series (National Starch) Commercial products such as Marquat Plus 3330 and Marquat 280 (Calgon) can be used.

As cationic polymers, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, diallyldimethylammonium chloride / hydroxyethylcellulose, glycidyltrimethylammonium chloride / hydroxyethylcellulose, dimethyldiallylammonium chloride polymer, dimethyl chloride Examples include diallylammonium acrylamide copolymer, Guffcoat 734, 755 (made by ISP), Katchinal series (made by Toho Chemical Industry), Cellcoat series (made by National Starch), Marcoat 100, 550 ( Calgon), H.C. C. Commercial products such as polymers (produced by Osaka Organic Chemical Industry Co., Ltd.) and Katchinal series (produced by Toho Chemical Industry Co., Ltd.) can be used.

Among the film-forming polymers selected from the component (B) nonionic, amphoteric, and cationic used in the present invention, nonionic film-forming polymers are polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, amphoteric The film-forming polymer is hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer, and the cationic film-forming polymer is one or more selected from polyquaternium-11 It is more preferable to exhibit the setting power.

The amount of the component (B) nonionic, amphoteric and cationic film-forming polymer used in the present invention is not particularly limited, but is preferably 0.1 to 30%, more preferably 1 to 20%. It is good. When the blending amount is in the range of 1 to 15%, it is suitable for realizing no flaking.

Further, by combining the component (A) and the component (B) at a specific mass ratio, the effect of suppressing the flaking and stickiness of the component (A) and the effect of the setting force by the component (B) are further enhanced. Is possible. Such a blending mass ratio is within the range of (A) :( B) = 1: 10 to 2: 1, more preferably (A) :( B) = 1: 5 to 1: 1. Suitable for achieving both set power and lack of flaking.

The component (C) monovalent lower alcohol used in the present invention is also blended as a solvent for the component (A), and is usually limited as long as it is usually used in hairdressing cosmetics. However, those having 1 to 3 carbon atoms are preferred. Specific examples include ethanol and isopropanol, and ethanol is particularly preferable.

Although the compounding quantity of the component (C) monovalent | monohydric lower alcohol used for this invention is not specifically limited, It can mix | blend in 10 to 99% of range in general. Moreover, a component (C) can also mix | blend 1 type or in combination of 2 or more types.

The polyalkylene glycol having a component (D) number average molecular weight of 400 to 20000 used in the present invention is blended in order to realize re-styling properties. Examples of the polyalkylene glycol include polypropylene glycol in which a propylene oxide structural unit is polymerized, polyethylene glycol in which an ethylene oxide structural unit is polymerized, polybutylene glycol in which a butylene oxide structural unit is polymerized, or a copolymer thereof. In addition, the number average molecular weight is measured by the end group quantification method, specifically, the hydroxyl value obtained by titration, by the average molecular weight test described in the Quasi-drug raw material standard. The polyalkylene glycol used in the present invention is not particularly limited, and commercially available products can be used. For example, PEG400, PEG600, PEG1000, PEG1500, PEG2000, PEG4000, PEG6000, PEG11000, PEG20000 (above, manufactured by NOF Corporation, Toho Chemical Co., Ltd. or Sanyo Chemical Industries), UNIOR D-1000, UNIOR D-2000 ( As mentioned above, NOF Corporation) can be exemplified.

The component (D) used in the present invention can be blended alone or in combination of two or more. By combining polyalkylene glycols having different molecular weights, it is possible to further improve the styling property. Is possible. In particular, when a polyalkylene glycol which is liquid at 25 ° C. and a polyalkylene glycol which is solid at 25 ° C. are combined, a particularly excellent effect is exhibited in terms of re-styling and non-stickiness.

The component (D) used in the present invention can be blended alone or in combination of two or more. The blending amount of the component (D) is preferably 0.1 to 20%, more preferably 2 to 10% in the hairdressing cosmetic composition.

The form of the hairdressing cosmetic composition of the present invention is not particularly limited, but a viscosity at 25 ° C. of 1000 mPa · s or less is preferable from the viewpoint of ease of application to hair. Furthermore, it is most preferable if it is accommodated in a container that can be used by spraying in a mist form because the amount applied to the hair becomes uniform and the application is easy. Here, the viscosity is measured with a single cylindrical rotational viscometer bismetron VS-A1 manufactured by Shibaura System.

In the hairdressing cosmetic composition of the present invention, in addition to the above-mentioned components, components that are usually used in preparations such as cosmetics and quasi-drugs, that is, water (in the qualitative and quantitative ranges that do not impair the effects of the present invention) Purified water, hot spring water, deep water, etc.), surfactant, oil agent, gelling agent, powder, polyhydric alcohol, resin, welding compound, moisturizer, antibacterial agent, fragrance, deodorant, salt, chelating agent , UV absorbers, pH adjusters, fresheners, plant extracts, vitamins, cosmetic ingredients, fragrances, and the like.

Examples of the surfactant include cationic, anionic, nonionic and amphoteric surfactants. Cationic surfactants include alkyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, tallow alkyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, behenyl trimethyl ammonium bromide. , Distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, dioctyldimethylammonium chloride, di (POE) oleylmethylammonium chloride (2EO), benzalkonium chloride, stearyldimethylbenzylammonium chloride, lanolin-derived quaternary ammonium salt , Stearic acid diethylaminoethylamide, stearic acid dimethylaminopropylamide De, ammonium chloride behenic acid amide propyl dimethyl hydroxypropyl, chloride stearoyl colaminoformyl methylpyridinium, cetylpyridinium chloride, tall oil alkyl benzyl hydroxyethyl imidazolinium chloride, and Zico coil hydroxyethylmonium methosulfate and the like. Anionic surfactants include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylates, alkyl sulfonates, alkene sulfonates, fatty acid ester sulfonates, fatty acid amide sulfonates, Sulfonates of alkyl sulfonates and their formalin condensates, alkyl sulfates, secondary higher alcohol sulfates, alkyl and allyl ether sulfates, fatty acid sulfates, fatty acid alkylolamide sulfates Salts, sulfate salts such as funnel oil, alkyl phosphates, alkyl ether phosphates, alkyl allyl ether phosphates, amide phosphates, N-acyl amino acid salts, acyl isethionate salts, N-acyl alkyl taurate salts, N Acyl polypeptide salts. Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene Alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor Oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene N-phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene / alkyl co-modified organopolysiloxane, alkanolamide, sugar ether, sugar Examples include amides. Amphoteric surfactants include betaines such as octyldimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, coconut oil fatty acid alkyldimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine Sulfobetaines such as lauryl sulfobetaine, N-coconut oil fatty acid acyl-N-carboxymethyl-N-hydroxyethylethylenediamine sodium, N-coconut oil fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine disodium, etc. And aminocarboxylic acid salts such as coconut oil alkyliminodicarboxylate. These surfactants can be used by appropriately selecting one or two or more thereof.

As the oil agent, oily components such as higher alcohols, hydrocarbon oils, ester oils, fats and oils, and the like can be used. For example, lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, cholesterol, phytosterol , Higher alcohols such as sitosterol, lanosterol, monostearyl glycerol ether (batyl alcohol), hydrocarbons such as ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, petrolatum, etc. , Diisobutyl adipate, 2-hexyldecyl adipate, adipic acid 2-heptylundecyl, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, tri-2-ethylhexanoic acid Trimethylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-succinate Ethylhexyl, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isopro palmitate , 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyl myristate Ester oils such as decyl, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, diisostearyl malate, waxes such as beeswax, carnauba wax, candelilla wax, whale wax, palm oil, palm Vegetable oils, beef tallow, beef leg fat, beef bone fat, beef tallow, hardened beef tallow, hardened oil, turtle oil, pork tallow, horse tallow, mink oil, liver oil, such as nuclear oil, olive oil, safflower oil, soybean oil, and cottonseed oil Animal oils such as egg yolk oil, lanolin, Lanolin derivatives such as liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid isopropyl, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethyl Cyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene-alkylmethylpolysiloxane-methylpolysiloxane copolymer, alkoxy-modified polysiloxane, alkyl-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane, amino-modified poly Siloxane, glycerin modified polysiloxane, higher alkoxy modified silicone, higher fatty acid modified silicone, silicone resin, silicone rubber, silicone Jin, and the like.

Gelling agents include amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, dextrins such as dextrin palmitate, dextrin stearate, dextrin 2-ethylhexanoate palmitate, etc. Fatty acid esters, sucrose palmitate, sucrose fatty acid esters such as sucrose stearate, monobenzylidene sorbitol, benzylidene derivatives of sorbitol such as dibenzylidene sorbitol, dimethylbenzyl dodecyl ammonium montmorillonite clay, dimethyl dioctadecyl ammonium montmorillonite clay, etc. Examples include organically modified clay minerals.

If the powder is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particle structure (porous) Any inorganic powder can be used, for example, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, synthetic mica. , Mica, kaolin, sericite, muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, aluminum magnesium silicate, calcium silicate, Barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, montmorillonite, z Light, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, etc .; organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, poly Methylbenzoguanamine powder, tetrafluoroethylene powder, polymethylmethacrylate powder, cellulose powder, silk powder, nylon powder, 12 nylon powder, 6 nylon powder, styrene / acrylic acid copolymer powder, divinylbenzene / styrene copolymer powder, vinyl Resin powder, urea resin powder, phenol resin powder, fluororesin powder, silicon resin powder Acrylic resin powder, melamine resin powder, epoxy resin powder, polycarbonate resin powder, microcrystalline fiber powder, lauroyl lysine, etc .; Colored pigments include iron oxide, iron hydroxide, inorganic red pigment of iron titanate, γ-iron oxide, etc. Inorganic brown pigments, inorganic yellow pigments such as yellow iron oxide and ocher, inorganic black pigments such as black iron oxide and carbon black, inorganic purple pigments such as manganese violet and cobalt violet, chromium hydroxide, chromium oxide and cobalt oxide Inorganic green pigments such as cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue, tar dyes raked, natural dyes raked, composite powders obtained by combining these powders, etc. Pearl pigments include titanium oxide coated mica, titanium oxide coated mica, bismuth oxychloride, titanium oxide coated Bismuth chloride, titanium oxide-coated talc, fish scale foil, titanium oxide-coated colored mica, etc .; metal powder pigments such as aluminum powder, copper powder, stainless steel powder, etc .; as tar dyes, red No. 3, red No. 104, red 106 No., Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 227, Red 228, Red 230, Red 401, Red 505, Yellow 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205 No., orange 201, orange 203, orange 204, orange 206, orange 207, etc .; natural pigments include carminic acid, laccaic acid, potassium The summing, brazilin, a powder selected from crocin, or composite of these powder, oil, silicone, or fluorine compounds at or in the powder was subjected to surface treatment.

Examples of the polyhydric alcohols include glycerin, diglycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene, in addition to the polyalkylene glycol having the number average molecular weight of 400 to 20000. Glycols, polyalkylene glycols having a number average molecular weight of less than 400, polyalkylene glycols having a number average molecular weight of more than 20000, and the like.

Antibacterial agents include benzoic acid, sodium benzoate, salicylic acid, coalic acid, sorbic acid, potassium sorbate, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, bis (2 -Pyridylthio-1-oxide) zinc, isopropylmethylphenol and the like, and examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol and the like.

Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, potassium carbonate, sodium bicarbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, triethanolamine, monoethanolamine, Examples of the refreshing agent include L-menthol and camphor.

Vitamins such as vitamin A and derivatives thereof, vitamin B and derivatives thereof, vitamin C and derivatives thereof, vitamin E and derivatives thereof, linolenic acid and derivatives thereof, and vitamins such as phytonadione, menaquinone, menadione, menadiol Ks; vitamin Ps such as eriocitrin and hesperidin; and biotin, carcinine, ferulic acid and the like.

As a refreshing agent, L-menthol, camphor, pyrrolidone carboxylate menthyl, menthyl lactate, etc., as vitamins, vitamin A and its derivatives, vitamin B and its derivatives, vitamin C and its derivatives, vitamin E and its derivatives, Examples include vitamin F of linolenic acid and its derivatives, vitamin Ks such as phytonadione, menaquinone, menadione and menadiol, vitamins P such as eriocitrin and hesperidin, and biotin, carcinine, ferulic acid and the like.

Examples of the cosmetic component include amino acids and amino acid derivatives, peptides, sterols, 2-methacryloyloxyethyl phosphorylcholine homopolymer, and a copolymer of 2-methacryloyloxyethyl phosphorylcholine and a hydrophobic monomer. Specifically, examples of amino acids include glycine, alanine, valine, isoleucine, serine, threonine, aspartic acid, glutamic acid, acetylglutamic acid, asparagine, glutamine, lysine, hydroxylysine, arginine, cystine, cysteine, acetylcysteine, methionine. , Phenylalanine, tyrosine, proline, hydroxyproline, ornithine, citrulline, theanine, trimethylglycine and the like. As amino acid derivatives, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl Octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), N-lauroylsarcosine isopropyl, N-lauroyl-L-glutamate dioctyldodecyl, and the like. Peptides may be derived from animals, fish, shellfish, plants and silk. Specifically, collagen and derivatives thereof or hydrolysates thereof, elastin and derivatives thereof or hydrolysates thereof, keratin and derivatives thereof Alternatively, a degradation product thereof, wheat protein and a derivative thereof or a hydrolyzate thereof, soybean protein and a derivative thereof or a hydrolyzate thereof, and the like can be given. Examples of sterols include cholesterol and phytosterol.

There is no restriction | limiting in particular in the manufacturing method of the hairdressing cosmetics of this invention, It prepares by a conventional method. That is, it can prepare by adding the said component (A)-(D) and the said arbitrary component as needed, and mixing this.

The hair styling cosmetic composition of the present invention thus obtained has both good setting power and no flaking, has high re-hair styling properties, and is less sticky, an aerosol container, a trigger container, an atomizer container, a bottle container, It can be used by putting it in a container such as a tube container or a pump container. In particular, by applying the hair cosmetic contained in a container that can be used by spraying in a mist form, the application to the hair is uniform. Therefore, it is preferable for obtaining the effects of the present invention. Moreover, it can be carried out in various forms such as liquid, emulsion, cream, gel, mousse, etc. by using in combination with other components. Among them, liquid water system, solubilization system, alcohol system, etc. It is preferable to obtain the effects of the present invention. In this case, it is excellent in usability that the hairdressing cosmetic has a viscosity of 1000 mPa · s or less. The viscosity in the present invention was measured using a bismetholone viscometer VDA2 (manufactured by Shibaura System Co., Ltd.). Measurements are measured at 25 ° C. unless otherwise specified.

EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited at all by these. 1 Production of (meth) acrylic silicone-based graft copolymer [Reference Production Example 1] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g at 70 to 80 ° C. with stirring, Dimethyl 2,2-azobis (2-methylpropionate) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate (EA) ^{(Note 4)} 31 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 27 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 4 g, isopropanol ^{(Note 1)} 50 g over 3-4 hours Added. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 87 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 2: 31: 27: 40 (Note 1) IPA Kanto Chemical Co., Ltd. (Note 2) V-601 Wako Pure Chemical Industries, Ltd. (Note 3) X-24 -8201 Shin-Etsu Chemical Co., Ltd. (Note 4) EA Kanto Chemical Co., Ltd. (Note 5) HEMA Kanto Chemical Co., Ltd. (Note 6) MAPTAC Evonik Degussa Japan Co., Ltd., 50% aqueous solution

[Reference Production Example 2] Isopropanol in a three-necked flask under nitrogen atmosphere
^{(Note 1)} 50 g under stirring at 70-80 ° C., dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-22-174DX) ^{(Note 7)} 40 g, ethyl acrylate ^{(Note 4)} 31 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 27 g, 3-trimethylammoniumpropylmethacrylamide chloride ^{(Note 6)} 4 g, isopropanol ^{(Note 1)} 170 g for 3 to 4 hours Added over time. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 90 g of a transparent rubber-like product. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-22-174DX = 2: 31: 27: 40 (Note 7) X-22-174DX Shin-Etsu Chemical Co., Ltd.

[Reference Production Example 3] In a three-necked flask, under a nitrogen atmosphere, 100 g of isopropanol ^{(Note 1)} was stirred at 70 to 80 ° C. with dimethyl 2,2-azobis (2-methylpropionate) ^(Note ) ²⁾ 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-22-174ASX) ^{(Note 8)} 40 g, ethyl acrylate ^{(Note 4)} 31 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 27 g, 3-trimethylammoniumpropylmethacrylamide 4 g of chloride ^{(Note 6)} and 50 g of isopropanol ^{(Note 1)} were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered and dried under reduced pressure at 80 ° C. to obtain 83 g of a transparent rubber-like product. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-22-174ASX = 2: 31: 27: 40 (Note 8) X-22-174ASX Shin-Etsu Chemical Co., Ltd.

[Reference Production Example 4] In a three-necked flask, under a nitrogen atmosphere, 100 g of isopropanol ^{(Note 1)} was stirred at 70 to 80 ° C. with dimethyl 2,2-azobis (2-methylpropionate) ^(Note ) ²⁾ 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40.4 g, ethyl acrylate ^{(Note 4)} 27.3 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 31.3 g, 3 -2 g of trimethylammoniumpropylmethacrylamide chloride ^{(Note 6)} and 50 g of isopropanol ^{(Note 1)} were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was separated by filtration and dried under reduced pressure at 80 ° C. to obtain 86 g of a transparent rubber-like material. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 1: 27.3: 31.3: 40.4

[Reference Production Example 5] In a three-necked flask, under a nitrogen atmosphere, 50 g of isopropanol ^{(Note 1)} was stirred at 70 to 80 ° C. with dimethyl 2,2-azobis (2-methylpropionate) ^(Note ) ²⁾ 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate ^{(Note 4)} 26 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 30 g, 3-trimethylammoniumpropyl methacrylamide 8 g of chloride ^{(Note 6)} and 120 g of isopropanol ^{(Note 1)} were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered and dried under reduced pressure at 80 ° C. to obtain 83 g of a transparent rubber-like product. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 4: 26: 30: 40

[Reference Production Example 6] In a three-necked flask, under a nitrogen atmosphere, 100 g of isopropanol ^{(Note 1)} was stirred at 70 to 80 ° C. with dimethyl 2,2-azobis (2-methylpropionate) ^(Note ) ²⁾ 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 20 g, ethyl acrylate ^{(Note 4)} 41.5 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 36.5 g, 3-trimethyl 4 g of ammonium propyl methacrylamide chloride ^{(Note 6)} and 50 g of isopropanol ^{(Note 1)} were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was separated by filtration and dried under reduced pressure at 80 ° C. to obtain 86 g of a transparent rubber-like material. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 2: 41.5: 36.5: 20

[Reference Production Example 7] In a three-necked flask, under a nitrogen atmosphere, 50 g of isopropanol ^{(Note 1)} was stirred at 70 to 80 ° C. with dimethyl 2,2-azobis (2-methylpropionate) ^(Note ) ²⁾ 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 50 g, ethyl acrylate ^{(Note 4)} 23 g, 2-hydroxyethyl methacrylate ^{(Note 5)} 25 g, 3-trimethylammoniumpropyl methacrylamide 4 g of chloride ^{(Note 6)} and 100 g of isopropanol ^{(Note 1)} were added over 3 to 4 hours. Subsequently, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in IPA was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 96 g of a transparent rubber-like material. From the infrared absorption spectrum, it was confirmed that the obtained rubber-like product was the intended (meth) acryl silicone graft copolymer. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 2: 23: 25: 50

[Reference Production Example 8] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70-80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate (EA) ^{(Note 4)} 31 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 27 g, dimethyldiallylammonium chloride (DADMAC) ^{(Note 9)} 3.34 g, isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 87 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The monomer charge ratio is as follows. DADMAC: EA: HEMA: X-24-8201 = 2: 31: 27: 40 (Note 9) DADMAC 60% aqueous solution manufactured by Tokyo Chemical Industry Co., Ltd.

[Reference Production Example 9] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of stirring at 70 to 80 ° C., dimethyl 2,2-azobis (2-methylpropionate) ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate (EA) ^{(Note 4)} 30 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 27 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 6 g, isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 89 g of a transparent rubber-like material. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 11 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 3: 30: 27: 40

[Reference Production Example 10] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70-80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 30 g, ethyl acrylate (EA) ^{(Note 4)} 35 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 32 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 6 g, isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 88 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 11 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 3: 35: 32: 30

[Reference Production Example 11] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70-80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 30 g, ethyl acrylate (EA) ^{(Note 4)} 36 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 32 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 4 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 88 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 11 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 2: 36: 32: 30

[Reference Production Example 12] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70-80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 30 g, ethyl acrylate (EA) ^{(Note 4)} 37 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 32 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 2 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 90 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 10 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 1: 37: 32: 30

[Reference Production Example 13] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70 to 80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-22-174DX) ^{(Note 7)} 30 g, ethyl acrylate (EA) ^{(Note 4)} 36 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 32 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 4 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was separated by filtration and dried under reduced pressure at 80 ° C. to obtain 86 g of a transparent rubber-like material. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 11 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-22-174DX = 2: 36: 32: 30

[Reference Production Example 14] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of stirring at 70 to 80 ° C., dimethyl 2,2-azobis (2-methylpropionate) ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate (EA) ^{(Note 4)} 16 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 42 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 2 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 91 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 30 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 1: 16.2: 42.4: 40.4

[Reference Production Example 15] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of stirred dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70 to 80 ° C. ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 40 g, ethyl acrylate (EA) ^{(Note 4)} 27 g, 2-hydroxyethyl methacrylate (HEMA) ^{(Note 5)} 31 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 2 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 88 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is 15 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 1: 27.3: 31.3: 40.4

[Reference Production Example 16] In a three-necked flask, under a nitrogen atmosphere, isopropanol (IPA) ^{(Note 1)} 100 g of dimethyl 2,2-azobis (2-methylpropionate ⁾ at 70-80 ° C. with stirring ) (V-601) ^{(Note 2)} 4 g, one-end methacrylate-substituted dimethylpolysiloxane (X-24-8201) ^{(Note 3)} 20.2 g, ethyl acrylate (EA) ^{(Note 4)} 65.7 g, 2-hydroxy Ethyl methacrylate (HEMA) ^{(Note 5)} 13.1 g, 3-trimethylammoniumpropylmethacrylamide chloride (MAPTAC) ^{(Note 6)} 2 g and isopropanol ^{(Note 1)} 50 g were added over 3 to 4 hours. Next, 1 g of dimethyl 2,2-azobis (2-methylpropionate) ^{(Note 2)} dissolved in isopropanol was added and reacted for 5 hours within a temperature range of 70 to 80 ° C. to obtain a viscous solution. . This solution was poured into purified water to precipitate the graft polymer, and then the precipitate was filtered off and dried under reduced pressure at 80 ° C. to obtain 87 g of a transparent rubber-like product. It was confirmed by infrared absorption spectrum that the obtained rubber-like product was the desired (meth) acryl silicone graft copolymer (this product was dimethylpolysiloxane, amide bond by infrared absorption spectrum. And a polymer having an ester bond, an alkyl group, and a hydroxyl group). The glass transition temperature (Tg) theoretically calculated from EA and HEMA is −10 ° C. The monomer charge ratio is as follows. MAPTAC: EA: HEMA: X-24-8201 = 1: 65.7: 13.1: 20.2

Example 1 Products 1 to 19 of the present invention and Comparative products 1 to 10: Hairdressing cosmetics Hairdressing cosmetics having the compositions shown in Tables 1 to 3 were prepared by the following production methods. ”,“ Re-hair styling ”, and“ No stickiness ”were evaluated by the following evaluation methods and criteria, and the results are shown in Tables 1 to 3.

(Production method)
(Invention products 1, 3-19, comparative products 1-10)
A: Components 1 to 23 are mixed uniformly.
B: A was filled in an atomizer container to obtain a hairdressing cosmetic.

(Invention product 2)
A: Components 1 to 23 are mixed uniformly.
B: The aerosol container was filled with A together with the components 24 and 25 to obtain a hairdressing cosmetic.
All of the products obtained here had a viscosity of 1000 mPa · s or less at 25 ° C.

[Evaluation method of evaluation items]
20 panelists specializing in cosmetics evaluation use the hair-styling cosmetics of the invention and comparative products, and each of “setting power”, “no flaking”, “re-hair-setting”, “no stickiness” Each item was evaluated on a five-point scale according to the following evaluation criteria, and the average score of all panels was further rounded to the first decimal place and rounded to the nearest 0.5.

Below, the evaluation criteria at the time of using the cosmetics for hairdressing of this invention are shown. The evaluation was performed by entering 5 grades, with 5 points when the effect was felt very much and 1 point when the effect was not felt at all.
<Evaluation criteria>: Setting ability [Evaluation results]: [Score]
Setting power is very high: 5-point setting power is available: 4-point setting power is slightly present: 3-point setting power is not so good: 2-point setting power is not good at all: 1 point

<Evaluation criteria>: No flaking [Evaluation result]: [Score]
There is no flaking: There is not much 5 point flaking: There is a little 4 point flaking: There is 3 point flaking: Very there is 2 point flaking: 1 point

<Evaluation criteria>: Hair styling [Evaluation result]: [Score]
Very good hair styling: 5 point hair styling: 4 point hair styling is a little: 3 point hair styling is not very good: 2 point hair styling is not good: 1 point

<Evaluation criteria>: No stickiness [Evaluation result]: [Score]
There is no stickiness at all: There is little stickiness at 5 points: There is a little stickiness at 4 points: There is stickiness at 3 points: There is very stickiness at 2 points: 1 point

Evaluation criteria
[Judgment]: Average score ◎: Score 4 or more ○: Score 3 or more and less than 4

As is apparent from the results in Tables 1 to 3, the hair styling cosmetics of the products 1 to 19 of the present invention have “setting power”, “no flaking”, “re-hair styling”, and “no stickiness”. It was an excellent hairdressing cosmetic for all items.
On the other hand, in the comparative product 1 produced without blending the component (A), “no flaking” was not good, and “no stickiness” was not satisfactory. In the comparative product 2 produced without blending the component (B), the “setting power” was not good, and “re-hair styling” and “non-stickiness” were not satisfactory. In Comparative product 3 produced without blending component (C), since there was no blending of ethanol, it was not possible to obtain a hair styling cosmetic in which component (A) was uniformly dissolved. Comparative product 4 produced without blending component (D) was not satisfactory in terms of “no flaking” and “re-styling”.
Moreover, the comparative products 5-7 could not obtain a uniform cosmetic for hairdressing. In comparative products 8 to 10 in which an anionic polymer is blended instead of the component (B), an anionic substance such as sodium alginate or carboxymethylcellulose Na reacts with the component (A) during production to produce an insoluble substance. separated.

Example 2 Hair Gel (Prescription) (%)
1 Polyvinylpyrrolidone 5.0
2 Polyurethane-14 2.0
3 (Meth) acrylic silicone graft copolymer of Reference Production Example 1 0.5
4 Polyoxyethylene hydrogenated castor oil isostearate 0.2
5 Fragrance 0.2
6 Hydroxypropyl methylcellulose 0.5
7 Glycerin 2.0
8 1,3-butylene glycol 2.0
9 Polyethylene glycol (number average molecular weight 6000) 2.0
10 Paraoxybenzoic acid ester 0.1
11 Phenoxyethanol 0.1
12 Hydrolyzed soy protein 0.5
13 Glycine 0.5
14 Ethanol 30.0
15 Remaining amount of purified water

(Production method)
A: Components 4, 5, and 14 are mixed uniformly.
B: Components other than A are heated and mixed uniformly.
C: A and B were mixed to obtain a hair gel.

  The hair gel of Example 2, which is an embodiment of the present invention, was compatible with both set power and lack of flaking, was able to re-hair, and was excellent in non-stickiness.

Example 3 Hair Spray (Prescription)
Stock solution (%)
1 Acrylamide / dimethylaminopropylacrylamide / methoxy PEG methacrylate copolymer 5.0
2 (Meth) acrylic silicone graft copolymer of Reference Production Example 1.0
3 Polyethylene glycol (number average molecular weight 20000) 3.0
4 Polyethylene glycol (number average molecular weight 400) 1.0
5 Ethylhexyl methoxycinnamate 1.0
6 Ethylhexyl salicylate 1.0
7 Dimethylpolysiloxane (10cs) 2.0
8 Lavender oil 1.0
9 Isopropanol 2.0
10 Ethanol remaining

Gas (%)
1 LPG 60.0
2 Dimethyl ether 40.0

(Production method)
A: Components 1 to 10 are mixed uniformly.
B: For 60 parts of the stock solution of A, 40 parts of gas was filled in an aerosol container to obtain a hair spray.

The hair spray of Example 3, which is an embodiment of the present invention, was compatible with both setting power and lack of flaking, was able to re-hair, and was excellent in non-stickiness. The hair spray of Example 3 had a viscosity of 1000 mPa · s or less at 25 ° C.

Example 4 Hair Mousse (Prescription)
Stock solution (%)
1 Vinylpyrrolidone / vinyl acetate copolymer 2.0
2 (Meth) acrylic silicone graft copolymer of Reference Production Example 1 2.0
3 Polyethylene glycol (number average molecular weight 1000) 2.0
4 Polyethylene glycol (number average molecular weight 2000000) 1.0
5 Propylene glycol 1.0
6 Polyoxyethylene sorbitan fatty acid ester 0.2
7 Methylphenylpolysiloxane 2.0
8 Stearyltrimethylammonium chloride 0.2
9 Sclerotium gum 0.2
10 Shea fat 1.0
11 Ethanol 2.0
12 Remaining amount of purified water

Gas (%)
LPG 100.0

(Production method)
A: Components 1 to 12 are mixed uniformly.
B: For 95 parts of the stock solution of A, 5 parts of gas was filled into an aerosol container to obtain a hair mousse.

  The hair mousse of Example 4, which is an embodiment of the present invention, was compatible with both set power and lack of flaking, was able to re-hair, and was excellent in non-stickiness. The viscosity of the hair mousse stock solution of Example 4 was 1000 mPa · s or less at 25 ° C.

Claims (9)

The following components (A) to (D); (A) (meth) acrylic silicone graft copolymer (B) one or more film-forming polymers (C) monovalent selected from nonionic, amphoteric and cationic A hair styling cosmetic comprising a polyalkylene glycol having a lower alcohol (D) number average molecular weight of 400 to 20000. The component (A) is a polymer obtained by reacting the following radically polymerizable monomers (a), (b), (c) and (d), and is 99.5% ethanol at 25 ° C. A (meth) acryl silicone graft copolymer that dissolves 50% by mass or more. (A) The following general formula (I)
(In the formula, Me is a methyl group, R 1 is a hydrogen atom or a methyl group, R 2 is a linear or branched C 1-10 divalent divalent alkyl group which may contain 1 or 2 ether bonds. A saturated hydrocarbon group, R3 is a saturated hydrocarbon group having 1 to 10 carbon atoms, and m is an integer of 5 to 100.) (b) The following general formula (II)
(In the formula, R4 may be a hydrogen atom or a methyl group, R5, R6 and R7 may be the same or different, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X is -O-, -NH-, -O. —CH ₂ — or —O—CH ₂ CH (OH) —, Y is a linear or branched divalent saturated hydrocarbon group having 1 to 4 carbon atoms, and Z ⁻ represents a counter anion. A compound represented by the formula (III)
(In the formula, R8 and R9 may be the same or different, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R10 and R11 may be the same or different, and a hydrogen atom or an alkyl group having 1 to 18 carbon atoms. Group, Z ⁻ represents a counter anion.) At least one selected from compounds represented by the following formula (IV):
(Wherein R12 represents a hydrogen atom or a methyl group, R13 represents a hydrogen atom or a linear or branched alkyl group having 1 to 3 carbon atoms) (d) the following general formula (V )
The hairdressing cosmetic composition according to claim 1, wherein R14 represents a hydrogen atom or a methyl group, and R15 represents a hydroxyalkyl group having 1 to 4 carbon atoms. The component (B) is one or more selected from polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer. The hairdressing cosmetic composition according to claim 1 or 2. The hair styling according to claim 1 or 2, wherein the nonionic film-forming polymer of the component (B) is one or more selected from polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymer. Cosmetics. The hair-styling makeup according to claim 1 or 2, wherein the amphoteric film-forming polymer of component (B) is a hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer. Fee. The cosmetic for hairdressing according to claim 1 or 2, wherein the cationic film-forming polymer of the component (B) is polyquaternium-11. The blending mass ratio of the component (A) and the component (B) is within the range of (A) :( B) = 1: 10 to 2: 1. Hairdressing cosmetics according to item. The hairdressing cosmetic composition according to any one of claims 1 to 7, wherein the viscosity at 25 ° C is 1000 mPa · s or less. The hairdressing cosmetic composition according to any one of claims 1 to 8, wherein the cosmetic composition is contained in a container that can be sprayed in a mist form.