JP2013227288A - Oily gelled cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily gelled cosmetic excellent in moisture retaining feeling and stability over time such as drain while achieving excellent spreading properties and no stickiness.SOLUTION: An oily gelled cosmetic includes following components (A)-(E): (A) a dextrin fatty acid ester and/or inulin fatty acid ester; (B) one or more selected from polyethylene glycols with an average molecular weight of 300-6,000; (C) an oil having a hydroxyl group in the molecule; (D) 40-95 mass% of an oil (except the component (C)) with a viscosity of ≤2,000 mPas at 30°C; and (E) a hydrophobized silicic anhydride.

Description

  The present invention relates to dextrin fatty acid ester and / or inulin fatty acid ester, polyethylene glycol having an average molecular weight of 300 to 6000, an oil agent having a hydroxyl group in the molecule, an oil agent having a viscosity at 30 ° C. of 2000 mPa · s or less (however, having a hydroxyl group in the molecule) 40 to 95% by mass (excluding oil agent), and an oily gel cosmetic containing hydrophobized silicic acid anhydride. More specifically, it has excellent moisturizing feeling while being excellent in spreading and stickiness, In particular, the present invention relates to an oily gel cosmetic having good temporal stability such as drainage at a high temperature.

  Conventionally, oily gel cosmetics containing various oils have been used to protect the skin from external stimuli and to provide an emollient effect by being applied to the skin and lips. In particular, in the dry season and environment, the skin and lips are protected from dryness, retain appropriate moisture, and have an excellent effect of enhancing the activity inside the skin by an occlusive effect. In order to obtain an oily gel-like cosmetic, a technique of blending a solid oil such as wax or an oily gelling agent such as dextrin fatty acid ester has been mainly used so far. Compared to the shape, the oily gelling agent was reduced, so that the stability over time was poor and problems such as drainage occurred.

  For this reason, oil-based gel cosmetics in recent years have been required to have good usability and excellent stability over time. For example, liquid hydrocarbons and hydrocarbon resins having a softening point of 40 ° C. or higher are required. Oil gel composition containing (for example, refer to Patent Document 1), oil gel cosmetics (for example, refer to Patent Document 2) in which gloss and stability are improved by combining dextrin fatty acid ester, 12-hydroxystearic acid and polybutene, There is a lip gloss composition in which stability or transparency is improved by combining diglyceryl isostearate polyglyceryl-2 and a specific silicon compound (for example, see Patent Document 3).

JP 2004-51850 A Japanese Patent Laid-Open No. 2002-3340 JP 2008-19200 A

However, the technique of Patent Document 1 is centered on hydrocarbon components, and the feeling of use such as stickiness is insufficient. In addition, 12-hydroxystearic acid used in the technique of Patent Document 2 has poor heat stability and storage stability, and has a drawback that coloration occurs due to overheating during production and precipitation occurs with time. In Patent Document 3, it is necessary to use diglyceryl isostearic acid polyglyceryl-2 in a large amount, and since it is limited to a specific silicon compound, a material having good usability such as weight and stickiness is obtained. It ’s difficult. Furthermore, in any case, when contacting with a resin container, the oil agent tends to drain from the contact surface due to the polarity of the container.
Therefore, there has been a demand for an oily gel cosmetic that is excellent in spreading at the time of application, less sticky to the skin, excellent in moisturizing feeling and excellent in stability over time.

  In view of such circumstances, the present inventors have conducted extensive studies to solve the above problems, and as a result, by blending polyethylene glycol having an average molecular weight of 300 to 6000 with high polarity into the oily gel cosmetic, It has been found to suppress drainage from the contact surface with the container. Furthermore, it discovered that the oil agent which has a hydroxyl group in a molecule | numerator was especially excellent as a component which can mix | blend this polyethylene glycol with oily gel cosmetics stably. That is, an oil agent having a hydroxyl group in the molecule improves the dissolution / dispersion of polyethylene glycol, dextrin fatty acid ester, an oil agent having a viscosity at 30 ° C. of 2000 mPa · s or less (except for an oil agent having a hydroxyl group), hydrophobized and anhydrous By mixing and dissolving in an oily gel cosmetic made of silicic acid, an oily gel cosmetic that is excellent in moisture retention while preventing drainage and being excellent in stability over time, in addition to being excellent in spreading and stickiness. As a result, the present invention was completed.

That is, the present invention includes the following components (A) to (E);
(A) Dextrin fatty acid ester and / or inulin fatty acid ester (B) One or more selected from polyethylene glycol having an average molecular weight of 300 to 6000 (C) Oil having hydroxyl group in molecule (D) Viscosity at 30 ° C Is less than 2000 mPa · s (excluding component (C))
40-95 mass%
(E) Provided is an oil-based gel cosmetic characterized by blending hydrophobized silicic anhydride.

  Moreover, the said component (B) contains the polyethylene glycol with an average molecular weight of 300-850 and the polyethylene glycol with an average molecular weight of 900-6000, The said oil-based gel cosmetics characterized by the above-mentioned are provided.

  Moreover, the compounding quantity of the said component (B) is 0.1-5 mass%, It provides the said oil-based gel cosmetics characterized by the above-mentioned.

  The component (C) is selected from polyglycerin fatty acid ester, citric acid alkyl ester, lactic acid alkyl ester, and malic acid alkyl ester.

  Moreover, the said component (D) is chosen from a liquid paraffin and a triglyceride, It provides the said oil-based gel cosmetics characterized by the above-mentioned.

  In addition, the oily gel-like cosmetic is characterized in that the viscosity of the oily gel-like cosmetic at 40 ° C. is 10,000 to 120,000 mPa · s.

  The oil-based gel cosmetic is characterized in that the oil-based gel cosmetic is for skin care.

  The oily gel-like cosmetic of the present invention is an oily gel-like cosmetic that is excellent in spreading and stickiness, but also has a good moisturizing feeling and has good stability over time, such as drainage at high temperatures.

Hereinafter, the present invention will be described in detail.
The dextrin fatty acid ester and / or inulin fatty acid ester of the component (A) used in the oily gel cosmetic of the present invention has an effect of gelling the oily component and imparting viscosity in a wide range, stability over time and makeup persistence. It is a component that improves the properties. The dextrin fatty acid ester of component (A) is an ester of dextrin and a fatty acid or a fatty acid derivative, preferably an ester of a higher fatty acid having 8 to 22 carbon atoms is used, and the average sugar polymerization degree of dextrin is 3 to 150. Preferably, the degree of substitution of fatty acids per glucose unit of dextrin is preferably 1.5 to 1.7. Specific examples include dextrin octoate, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, and the like. Examples of commercially available products of these dextrin fatty acid esters include “Leopard KL2”, “Leopard MKL2”, “Leopard TT2”, and “Leopard TL2” (manufactured by Chiba Flour Milling Co., Ltd.). Of these, dextrin palmitate is most preferable from the viewpoint of stability over time and usability.

  The inulin fatty acid ester of component (A) is an ester of inulin and a fatty acid or a fatty acid derivative, preferably an ester of a linear or branched saturated or unsaturated fatty acid having 8 to 32 carbon atoms and inulin, The average molecular weight of inulin is preferably in the range of 300 to 10,000. Specific examples include those described in JP-A-3-197409 and JP-A-2002-193732, and examples of commercially available products include “LEOPAL ISK2” (manufactured by Chiba Flour Mills).

  The blending amount of the component (A) used in the present invention is preferably 1 to 10% by mass (hereinafter simply referred to as “%”) because it is more excellent in stability with time and elongation, and is preferably 3 to 8%. It is preferable because the elongation spread is further excellent.

  One or more selected from polyethylene glycol having an average molecular weight of 300 to 6000 of the component (B) used in the present invention is a component that suppresses drainage. Specifically, PEG-6 (average molecular weight 300), PEG-8 (average molecular weight 400), PEG-32 (average molecular weight 1540), PEG-150 (average molecular weight 6000) (above, manufactured by Kimura Sangyo Co., Ltd.), etc. Among these, an average molecular weight of 500 to 3000 is preferable. The average molecular weight is measured by an average molecular weight test of polyethylene glycol 4000 described in the outer primordium. In addition, it is preferable to use polyethylene glycol having an average molecular weight of 300 to 850 and polyethylene glycol having an average molecular weight of 900 to 6000, and using such a combination is preferable because stability over time is more excellent.

  The amount of the component (B) used in the present invention is preferably 0.1 to 5%, more preferably 0.5 to 3%. This range is preferable because stability over time is more excellent.

  The oil agent having a hydroxyl group in the molecule of the component (C) used in the present invention is a component that improves the solubility of the component (B) in the oil agent in the present invention. For example, glycerin fatty acid ester, polyglycerin fatty acid ester, Citric acid alkyl ester, lactic acid alkyl ester, malic acid alkyl ester, glutamic acid alkyl ester, and the like can be used. Specifically, diglyceryl triisostearate, diglyceryl diisostearate, diglyceryl monoisostearate, diglyceryl trioctanoate, decaisostearate decaisostearate, diisostearyl malate, tri-2-ethylhexyl citrate, octyldodecyl lactate, etc. Is mentioned. Examples of commercially available products include “Cosmol 43V”, “Cosmol 42V”, “Cosmol 41V”, “Cosmol 222” (all manufactured by Nisshin Oillio Group), “IS-1009P” (manufactured by Sakamoto Pharmaceutical Co., Ltd.), and the like. . It is inferred that component (C) acts as a bridging agent that interacts with a highly polar polyethylene glycol (component (B)) by a hydroxyl group, thereby facilitating dissolution of component (B) in the oily base. Is done.

  The IOB value of the component (C) used in the present invention is preferably 0.25 or more because it is superior in stability over time. Here, IOB (Inorganic Organic Balance) means an inorganic value / organic value, and is based on the organic conceptual diagram of Satoshi Fujita (Satoshi Fujita, Masami Akatsuka, Systematic Organic Qualitative Analysis (mixture) 1974, Published by Kyoritsu Publishing). IOB represents the polarity of the organic compound. The higher the numerical value, the higher the polarity and the water becomes ∞. Examples of oils having an IOB value of 0.25 or more include diglyceryl triisostearate (IOB value 0.26), diglyceryl diisostearate (IOB value 0.41), and diisostearyl malate (IOB value 0.28). ) And the like.

  The blending amount of the component (C) used in the present invention is preferably 0.1 to 50% because stability over time and spread are more preferable, and if it is 5 to 40%, stability over time is further excellent. preferable.

  The oil agent (except for the component (C)) having a viscosity of 2000 mPa · s or less at 30 ° C. of the component (D) used in the present invention is a component that is excellent in non-stickiness and elongation spread, and is usually used in cosmetics. It is not particularly limited as long as it is. Specifically, hydrocarbons, fats and oils, ester oils, higher alcohols, silicone oils, fluorine, regardless of origin such as animal oil, vegetable oil, synthetic oil, and liquid oil, volatile oil, etc. Commonly used cosmetics such as oils and fatty acids are used. The viscosity is a value measured under the condition of 6 rotations with a No. 3 rotor and 60 seconds after using a single cylindrical rotational viscometer bismetron VS-A1 manufactured by Shibaura System.

  Among these, the component (D) is preferably a liquid hydrocarbon oil or one or more oil agents selected from triglycerides. It is preferable to select these oil agents because they are well-familiar with the skin and further improve the spread of elongation.

  Specific examples of the component (D) hydrocarbon oil include light isoparaffin, liquid paraffin, liquid isoparaffin, heavy liquid isoparaffin, hydrogenated polyisobutene, hydrogenated polydecene, squalane, isododecane, isohexadecane and the like. For example, it is possible to use commercially available products such as High Coal K-230, High Coal K-350, High Coal K-500 (above, manufactured by Kaneda), DRAKEOL 600 (manufactured by Penleco), Pearl Ream 6 (manufactured by NOF Corporation). One or two or more can be appropriately selected and used as necessary. Particularly preferred are liquid paraffin and heavy liquid isoparaffin, which are more preferred because they have a better moisturizing feeling.

  Specific examples of the triglyceride of component (D) include glyceryl triisostearate, glyceryl triisopalmitate, glyceryl tri-2-ethylhexanoate, glyceryl tri (capryl / capric acid), and one or two of these. The above can be appropriately selected and used. Among these, glyceryl tri-2-ethylhexanoate is preferable. It is preferable to select these oil agents because they are superior in terms of spreading and non-stickiness.

  The compounding quantity of the component (D) used for this invention is 40 to 95%, More preferably, it is 50 to 80%. If it is less than 40%, stickiness is felt and the spread of elongation becomes worse, and if it exceeds 95%, the stability over time becomes insufficient.

  The hydrophobized silicic acid anhydride of the component (E) used in the present invention is one in which silanol groups (hydroxyl groups) on the silicic acid surface are dimethylsilylated, trimethylsilylated, etc. AEROSILR972 manufactured by Nippon Aerosil Co., Ltd. R972V, R974, R976, R976S, R812, R812S, RX200, RX300 and the like.

  The average particle size of the hydrophobized silicic acid anhydride of component (E) used in the present invention is preferably 5 to 40 nm, more preferably 10 to 30 nm. This range is preferable because it is more excellent in stability with time and spread of elongation. The average particle diameter is obtained by measuring the specific surface area using the BET method and calculating the average particle diameter from the obtained specific surface area.

  The blending amount of the component (E) used in the present invention is preferably 0.1 to 3% because stability over time and spread are more excellent, and 0.5 to 2% is more excellent over time. Therefore, it is preferable.

  In addition to the above essential components, the oily gel cosmetic of the present invention generally contains components such as oils, surfactants, components (A) and components other than components (C) and (D). The present invention includes gelling agents excluding component (E), powders excluding component (E), preservatives, ultraviolet absorbers, dyes, fragrances, cosmetic ingredients, water-soluble ingredients, polyhydric alcohols excluding ingredient (B), etc. It can be used within a range that does not impair the effect.

  As a method for producing the oily gel cosmetic of the present invention, various methods can be used. As an example, the components (A) and (D) are mixed and dissolved at 90 ° C., and then the component (E). Can be obtained by adding the component (B) dissolved in the component (C). Moreover, you may mix | blend an arbitrary component in this case.

  The oily gel cosmetic of the present invention is preferably an oil-based one phase. In the present invention, water is preferably substantially not blended, and specifically, the blending amount of water is preferably 0.1% or less. In addition, the water here refers to ion-exchanged water, hot spring water, deep water, plant steam distilled water, etc. in addition to purified water usually used in cosmetics.

    The oily gel cosmetic of the present invention refers to one having a viscosity at 40 ° C. of 5,000 to 150,000 mPa · s as measured by a single cylindrical rotational viscometer bismetron VS-A1 manufactured by Shibaura System Co., Ltd. 10000 to 120,000 mPa · s. This range is preferable because the elongation spread is more excellent.

  Further, the oily gel cosmetic of the present invention can be used without particular limitation for makeup, skin care and the like, but from the viewpoint of feel, it is used for skin care such as cosmetic oil, massage material, cosmetic liquid, and oily cleansing material. It is preferable to use it for cleaning sebum remover and the like. Furthermore, since the stickiness peculiar to an oil agent is small and a moisturizing feeling is obtained, and it has a good elongation spread, application to a cosmetic oil is particularly suitable. In addition, cosmetic oil means cosmetic oil as a product, and is formed by blending various oils and the like instead of cosmetic raw materials themselves.

  The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

Examples 1 to 13 and Comparative Examples 1 to 9: Oily gel cosmetics (cosmetic oils)
The oily gel cosmetics having the compositions shown in Tables 1 and 2 below are produced according to the following production method, feeling of use (elongation, non-stickiness, moisturizing feeling), stability over time (room temperature, 5-45 ° C, 50 ° C ) Was evaluated. The results are also shown in Tables 1 and 2. In addition, the viscosity in 40 degreeC of Examples 1, 2, 5-11, Comparative Examples 2, 3, 6-9 is in the range of 15000-100,000 mPa * s, and the viscosity of Examples 3, 12, and Comparative Example 4 is It is in the range of 5000 to 40000 mPa · s, the viscosity of Examples 4 and 13 is in the range of 100,000 to 150,000 mPa · s, the viscosity of Comparative Example 5 is in the range of 100,000 to 1000000 mPa · s, and is a comparative example. The viscosity of No. 1 was in the range of 100 to 10,000 mPa · s. In addition, the viscosity value measured the viscosity value of 60 rotations after 60 rotations with a No. 4 rotor using the single cylinder type rotational viscometer bismetron VS-A1 by a Shibaura system company. However, the viscosity of Examples 4 and 13 and Comparative Example 5 is a viscosity value after 60 rotations and 60 seconds with a No. 4 rotor.

* 1 Leopard TL2 (Chiba Flour Mills)
* 2 Leo Pearl MKL2 (Chiba Flour Mills)
* 3 PERFORMALENE 500 (manufactured by New Phase Technology)
* 4 Drakeol 600 (Penreco)
* 5 Cosmol 168AR (viscosity at 30 ° C: 5500 mPa · s) (manufactured by Nisshin Oillio Group)
* 6 AEROSIL R-976S (Nippon Aerosil Co., Ltd.)
* 7 AEROSIL 300 (Nippon Aerosil Co., Ltd.)

(Production method)
A: Components (4) to (13) are heated to 80 ° C. and mixed uniformly.
B: Components (1) to (3) and (14) to (18) are heated to 90 ° C. and uniformly mixed.
C: A and B are mixed uniformly.
D: After dissolving C at 90 ° C., it was cooled to 70 ° C., filled in a resin container and molded to obtain an oily gel cosmetic.

(Evaluation method)
The following evaluation items were evaluated by the following evaluation methods.
a. Elongation b. No stickiness c. Moisturizing feeling a. About the extension spread, after washing face with a predetermined facial cleansing for 15 panelists specializing in cosmetics evaluation, the sensory sensation when 2 g of the test oily gel cosmetic was applied to both cheeks was evaluated. b. No stickiness, c. Regarding the moisturizing feeling, the state after 10 minutes from the application was subjected to sensory evaluation. The evaluation was performed in five stages using the following absolute evaluation criteria, and the average score of each sample was determined using a four-step criterion. As the facial cleanser used, Example 1 described in JP-A-2005-60298 was used.

Absolute Evaluation Criteria (Score): (Evaluation)
5 points: very good 4 points: good 3 points: normal 2 points: slightly bad 1 point: bad

4-level criteria (judgment): (average score)
◎: 4.5 points or more ○: 3.5 points or more and less than 4.5 points △: 2.5 points or more and less than 3.5 points ×: Less than 2.5 points

(Evaluation method)
The following evaluation items were evaluated by the following evaluation methods.
d. Stability over time Each sample is stored for 1 month at room temperature and 50 ° C. based on the state immediately after adjustment, and further 5 ° C. and 45 ° C. are stored in a thermostatic bath for 1 month in a 2-day cycle (5-45 ° C.), Each sample was determined using a four-step criterion by visual observation of the presence or absence of drainage.

4-step criteria (judgment): (evaluation)
◎: Drainage is not seen at all ○: Slight drainage is seen △: Drainage is seen ×: Drainage is seen considerably

  From Table 1 and Table 2, the oily gel cosmetics of the present invention products 1 to 13 have good stability over time, have little stickiness and excellent spread, and have a good moisturizing feeling. It was a fee. On the other hand, the comparative example 1 which does not mix | blend a component (A) was remarkably inferior in temporal stability. Comparative Example 2 in which component (B) is not blended, Comparative Example 3 in which component (C) is not blended, and Comparative Example 4 in which component (E) is not blended are both inferior in stability over time at 50 ° C. and drainage is remarkable. It was a thing. In Comparative Example 5 in which polyethylene wax was blended instead of component (A), the elongation and spread were poor, and the temporal stability was insufficient. The comparative example 6 which mix | blended polyethyleneglycol (molecular weight 200) with a small molecular weight instead of the component (B) was remarkably inferior in the temporal stability in 50 degreeC and 5-45 degreeC. The comparative example 7 which mix | blended polyethyleneglycol (molecular weight 20000) with a large molecular weight instead of a component (B) was notably inferior in temporal stability. The comparative product 8 in which the blending amount of the component (D) is less than 40% was remarkably inferior in elongation spread and non-stickiness. The comparative example 9 which mix | blended the silicic anhydride which has not hydrophobized instead of the component (E) was notably inferior in stability with time of 50 degreeC and 5-45 degreeC.

Example 14: Oily gel cleansing material (component) (%)
1. Liquid paraffin * 4 Residual amount PEG-32 0.2
3. PEG-6 0.2
4). Diglyceryl monoisostearate 3.0
5. Diglyceryl triisostearate 7.0
6). Dimethylpolysiloxane * 8 5.0
7). Polyoxyethylene isostearate (20 mol) glyceryl 20.0
8. Cetyl 2-ethylhexanoate 5.0
9. Dextrin palmitate * 1 3.0
10. Silylated silica anhydride * 9 1.0
11. Fragrance 0.1
* 8: KF-96A100CS (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 9: AEROSIL R-972 (Nippon Aerosil Co., Ltd.)

(Production method)
A: Components (1) to (7) are heated to 80 ° C. and uniformly mixed.
B: Components (8) and (9) are heated to 90 ° C. and mixed uniformly.
C: A, B and components (10) and (11) are uniformly mixed.
D: After dissolving C at 90 ° C., it was cooled to 70 ° C., filled in a container and molded to obtain an oily gel cleansing material.

  The oily gel cleansing material of Example 14 was an oily gel cleansing material having cleansing power, excellent stability over time, good spread to the skin, little stickiness, and good moisturizing effect. In addition, the viscosity in 40 degreeC was in the range of 15000-80000 mPa * s.

Example 15: Oily gel massage material (component) (%)
1. 1. Glyceryl tri-2-ethylhexanoate Residual amount Trimethylolpropane triisostearate 20.0
3. Meadow foam oil 20.0
4). Hydrogenated polyisobutene * 10 10.0
5. Diisostearyl malate 5.0
6). Diglyceryl diisostearate 5.0
7). PEG-150 0.1
8). PEG-8 0.4
9. Fragrance 0.1
10. Dibutylhydroxytoluene 0.1
11. Dextrin palmitate * 1 1.0
12 Silylated silica * 11 1.0
* 10: Pearl Dream 18 (Nippon Yushi Co., Ltd.)
* 11: AEROSIL R-974 (Nippon Aerosil Co., Ltd.)

(Production method)
A: Components (2) to (8) are heated to 80 ° C. and mixed uniformly.
B: Components (1) and (11) are heated to 90 ° C. and mixed uniformly.
C: A and B and components (9), (10) and (12) are mixed uniformly.
D: After dissolving C at 90 ° C., it was cooled to 70 ° C., filled into a container, and molded to obtain an oily gel massage material.

  The oily gel-like massage material of Example 15 was an oily gel-like massage material having excellent stability over time, good stretch spread on the skin, little stickiness, and good moisturizing effect. In addition, the viscosity in 40 degreeC was in the range of 5000-40000 mPa * s.

Example 16: Gelled cosmetic oil for removing sebum (component) (%)
1.2-cetyl ethyl hexanoate residual amount Polybutene * 12 5.0
3. Meadow Foam Oil 10.0
4). Diglyceryl diisostearate 8.0
5. Diglyceryl triisostearate 2.0
6). PEG-6 0.1
7). PEG-8 0.3
8). PEG-32 0.1
9. Fragrance 0.1
10. L-Menthol 0.02
11. Stearyl glycyrrhetinate 0.1
12 Dextrin palmitate * 1 6.0
13. Silylated Anhydrous Silicic Acid * 6 1.5
* 12: Nisseki Polybutene HV-1900F (manufactured by JX Nippon Mining & Energy Corporation)

(Production method)
A: Components (2) to (8) are heated to 80 ° C. and mixed uniformly.
B: Components (1) and (12) are heated to 90 ° C. and mixed uniformly.
C: A and B and components (9) to (11) and (13) are uniformly mixed.
D: After dissolving C at 90 ° C., it was cooled to 70 ° C., filled in a container and molded to obtain a gel cosmetic oil for removing sebum.

  The gel-like cosmetic oil for removing sebum of Example 16 is a gel-like cosmetic oil for removing sebum that has excellent sebum removal, excellent stability over time, good spread to the skin, little stickiness, and good moisturizing effect. Met. In addition, the viscosity in 40 degreeC was in the range of 15000-100,000 mPa * s.

Example 17: Oily gel eye color (component) (%)
1. Liquid paraffin * 4 Remaining amount PEG-6 0.2
3. PEG-32 0.2
4). PEG-150 0.05
5. Diglyceryl monoisostearate 5.0
6). Diglyceryl diisostearate 4.0
7. Cetyl 2-ethylhexanoate 30.0
8). Dextrin palmitate * 1 3.0
9. Silylated Anhydrous Silicic Acid * 13 1.0
10. Synthetic phlogopite * 14 10.0
11. Perfluorooctyltriethoxysilane 3% treatment Titanium oxide coated mica * 15 2.5
12 Perfluorooctyltriethoxysilane 2% treated Titanium oxide coated glass * 16 5.0
* 13: AEROSIL R-812 (Nippon Aerosil Co., Ltd.)
* 14: PDM-40L average particle size 35-45 μm (Topy)
* 15: FLAMENCO ULTRA SPARKLE 4500 with an average particle size of 50 μm (manufactured by BASF) treated with 3% perfluorooctyltriethoxysilane * 16: Metashine MC1080RC-S Fluorooctyltriethoxysilane 3% treated

(Production method)
A: Components (1) to (6) are heated to 80 ° C. and uniformly mixed.
B: Components (7) and (8) are heated to 90 ° C. and mixed uniformly.
C: A, B and components (9) to (12) are uniformly mixed.
D: After dissolving C at 90 ° C., it was cooled to 70 ° C., filled in a container and molded to obtain an oily gel eye color.

  The oily gel eye color of Example 17 was an oily gel eye color having excellent stability over time, good spread and spread on the skin, little stickiness, and good moisturizing effect. In addition, the viscosity in 40 degreeC was in the range of 15000-80000 mPa * s.

Claims (7)

The following components (A) to (E);
(A) Dextrin fatty acid ester and / or inulin fatty acid ester (B) One or more selected from polyethylene glycol having an average molecular weight of 300 to 6000 (C) Oil having hydroxyl group in molecule (D) Viscosity at 30 ° C Is less than 2000 mPa · s (excluding component (C))
40-95 mass%
(E) An oily gel cosmetic comprising a hydrophobized silicic acid anhydride.   The oily gel cosmetic according to claim 1, wherein the component (B) contains polyethylene glycol having an average molecular weight of 300 to 850 and polyethylene glycol having an average molecular weight of 900 to 6000.   The oily gel cosmetic according to claim 1 or 2, wherein the amount of the component (B) is 0.1 to 5% by mass.   The oily gel cosmetic according to any one of claims 1 to 3, wherein the component (C) is selected from polyglycerin fatty acid ester, citric acid alkyl ester, lactic acid alkyl ester, and malic acid alkyl ester.   The oily gel cosmetic according to any one of claims 1 to 4, wherein the component (D) is selected from liquid paraffin and triglyceride.   The oily gel-like cosmetic according to any one of claims 1 to 5, wherein the oily gel-like cosmetic has a viscosity at 40 ° C of 10,000 to 120,000 mPa · s.   The oily gel cosmetic according to any one of claims 1 to 6, wherein the oily gel cosmetic is for skin care.