JP2013218827A - Power storage device, and vehicle - Google Patents

Power storage device, and vehicle Download PDF

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JP2013218827A
JP2013218827A JP2012086748A JP2012086748A JP2013218827A JP 2013218827 A JP2013218827 A JP 2013218827A JP 2012086748 A JP2012086748 A JP 2012086748A JP 2012086748 A JP2012086748 A JP 2012086748A JP 2013218827 A JP2013218827 A JP 2013218827A
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protrusion
end surface
positive electrode
storage device
power storage
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JP5772690B2 (en
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Atsushi Minamigata
厚志 南形
Motoaki Okuda
元章 奥田
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Toyota Industries Corp
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

PROBLEM TO BE SOLVED: To provide a power storage device in which a collector portion and a collector member can be easily coupled to each other, and a vehicle.SOLUTION: A first protrusion portion 42 and a second protrusion portion 43 are formed on a first terminal member 40 constituting a collector terminal 30, and a third protrusion portion 52 and a fourth protrusion portion 53 are formed on a second terminal member 50. Then, a second inclined portion 43d inclined on a rear end side from a tip side toward a base end side is formed on the second protrusion portion 43 of the first terminal member 40, while a fourth inclined portion 53d inclined on a front end side from the tip side toward the base end side is formed on the fourth protrusion portion 53 of the second terminal member 50. In a lamination direction of an electrode body 25, the second inclined portion 43d is formed to exceed a half of the width of the second protrusion portion 43, and the fourth inclined portion 53d is formed to exceed a half of the width of the fourth protrusion portion 53.

Description

本発明は、蓄電装置、及び車両に関する。   The present invention relates to a power storage device and a vehicle.

従来から、蓄電装置の一種である二次電池としては、リチウムイオン二次電池や、ニッケル水素二次電池などが知られている。例えば、リチウムイオン二次電池では、電極シートが層状をなす電極体をケースに収容するとともに、電極体の縁部に形成された集電部と、ケースの外部に突出される電極端子とを集電部材により電気的に接続している(例えば特許文献1)。なお、集電部では、電極シートにおいて活物質が塗布されていない未塗工部(所謂リード部)が複数重なって層状の構造をなしている。   Conventionally, lithium ion secondary batteries, nickel hydride secondary batteries, and the like are known as secondary batteries that are a type of power storage device. For example, in a lithium ion secondary battery, an electrode body having a layered electrode sheet is accommodated in a case, and a current collector formed at the edge of the electrode body and an electrode terminal protruding outside the case are collected. It is electrically connected by an electric member (for example, Patent Document 1). Note that the current collector has a layered structure in which a plurality of uncoated portions (so-called lead portions) on which no active material is applied are overlapped on the electrode sheet.

特許文献1では、集電部をなす未塗工部を2つの束(所謂リード群)に分割し、分割した未塗工部の間に金属ブロックを挿入するとともに、集電部(未塗工部)、集電部材、及び金属ブロックを抵抗溶接用の電極で挟持しつつ通電することにより、集電部(未塗工部)と集電部材とを溶接して電気的に接続している。   In Patent Document 1, an uncoated part that forms a current collector is divided into two bundles (so-called lead groups), and a metal block is inserted between the divided uncoated parts, and a current collector (uncoated) Part), the current collecting member, and the metal block are energized while being sandwiched between the electrodes for resistance welding, thereby welding and electrically connecting the current collecting part (uncoated part) and the current collecting member. .

特開2011−92995号公報JP 2011-92995 A

特許文献1のように、集電部において層状をなす未塗工部を予め2つに分割する方法としては、例えば未塗工部の間に分割用の冶具を挿入することが考えられる。しかしながら、集電部では、金属薄板からなる未塗工部が層状の構造をなしていることから、未塗工部の間に上記冶具を挿入することが困難であるばかりか、冶具の挿入時に当該冶具と未塗工部(金属薄板)の縁部とが当接することにより、未塗工部が破損してしまう虞もある。このように、従来では、層状の構造をなす未塗工部を複数に分割し、集電部と集電部材とを連結することが難しかった。   As in Patent Document 1, as a method of previously dividing the uncoated portion that forms a layer in the current collecting portion into two, for example, it is conceivable to insert a dividing jig between the uncoated portions. However, in the current collector, the uncoated part made of a thin metal plate has a layered structure, so that it is difficult to insert the jig between the uncoated parts. When the jig and the edge of the uncoated part (metal thin plate) come into contact with each other, the uncoated part may be damaged. As described above, conventionally, it has been difficult to divide an uncoated part having a layered structure into a plurality of parts and connect the current collecting part and the current collecting member.

この発明は、上記従来技術に存在する問題点に着目してなされたものであり、その目的は、集電部と集電部材とを容易に連結できる蓄電装置、及び車両を提供することにある。   The present invention has been made paying attention to the problems existing in the above prior art, and an object thereof is to provide a power storage device and a vehicle that can easily connect a current collector and a current collector. .

請求項1に記載の発明は、金属薄板、前記金属薄板の表面に活物質が塗布された塗工部、及び前記活物質が塗布されていない未塗工部を有する電極シートが複数重なって層状の構造をなす電極体と、前記電極体の一方の縁部から延出形成され、かつ各前記電極シートの未塗工部が複数重なって層状の構造をなす集電部と、前記電極体から電力を取り出すための電極端子と、前記集電部と前記電極端子とを電気的に接続した集電部材とを有する蓄電装置であって、前記電極体における積層方向の両端部には、前記積層方向に沿って延びる端面がそれぞれ形成されており、前記集電部材は、前記両端部の一方の端面上に、かつ前記電極体の積層方向に直交する方向に並んで配置される第1部材、及び第2部材を有し、前記第1部材には、前記電極体における層と平行する側面である第1側面と、前記第1側面とは反対側の側面である第2側面とがそれぞれ形成され、前記第1部材は、前記電極端子と電気的に接続され、前記第1部材には、前記第2部材側に突出する第1突起部、及び少なくとも一つの第2突起部とが形成され、前記第1突起部は、少なくとも、前記第1側面と連続し、かつ前記第1側面と平行な第1端面と、前記第1端面とは反対側の端面である第2端面と、前記第1端面と前記第2端面における前記第1突起部の先端側の端部同士を繋ぐ第1連接部によって構成され、前記第1連接部は第1傾斜部を有し、前記第1傾斜部は、前記第1端面と鋭角をなし、前記第2突起部は、少なくとも、前記第1端面側に形成され、かつ前記第1端面と平行する第3端面と、前記第3端面とは反対側の端面である第4端面と、前記第3端面と前記第4端面における前記第2突起部の先端側の端部同士を繋ぐ第2連接部によって構成され、前記第2連接部は、第2傾斜部を有し、前記第2傾斜部は、前記第4端面と鋭角をなし、前記第2部材は、前記電極体における層と平行する側面である第3側面と、前記第3側面とは反対側の側面である第4側面とがそれぞれ形成され、前記第3側面は前記第1側面と同じ側に、前記第4側面は、前記第2側面と同じ側に、それぞれ形成され、前記第2部材は、前記第1部材と直接、又は前記集電部をなす前記未塗工部を介して連続し、前記第2部材には、前記第1部材側に突出する第3突起部、及び少なくとも一つの第4突起部とが形成され、前記第3突起部は、少なくとも、前記第4側面と連続し、かつ前記第4側面と平行な第5端面と、前記第5端面とは反対側の端面である第6端面と、前記第5端面と前記第6端面における前記第3突起部の先端側の端部同士を繋ぐ第3連接部によって構成され、前記第3連接部は第3傾斜部を有し、前記第3傾斜部は、前記第5端面と鋭角をなし、前記第4突起部は、少なくとも、前記第5端面側に形成され、かつ前記第5端面と平行する第7端面と、前記第7端面とは反対側の端面である第8端面と、前記第7端面と前記第8端面における前記第2突起部の先端側の端部同士を繋ぐ第4連接部によって構成され、前記第4連接部は、第4傾斜部を有し、前記第4傾斜部は、前記第8端面と鋭角をなし、前記積層方向において、前記第1端面側から、前記第1突起部、前記第4突起部、及び前記第2突起部が順に配置され、前記積層方向において、前記第2端面側から、前記第3突起部、前記第2突起部、及び前記第4突起部が順に配置され、記第1突起部と前記第4突起部との間、前記第2突起部と前記第4突起部との間、及び前記第2突起部と前記第3突起部との間には、前記集電部をなす前記未塗工部がそれぞれ複数の束に分割して配置されており、前記第2傾斜部、及び前記4傾斜部の、それぞれ前記第2突起部、及び前記第4突起部における前記積層方向の幅は、それぞれ前記第2突起部、及び前記第4突起部の前記積層方向の幅の半分を超えて形成されていることを要旨とする。   The invention according to claim 1 is a layered structure in which a plurality of electrode sheets having a thin metal plate, a coated portion where an active material is applied to the surface of the thin metal plate, and an uncoated portion where the active material is not applied are stacked. From the electrode body, a current collector portion extending from one edge of the electrode body, and a plurality of uncoated portions of the electrode sheets overlapping to form a layered structure, and the electrode body A power storage device having an electrode terminal for taking out electric power, and a current collecting member that electrically connects the current collecting part and the electrode terminal, wherein both ends of the electrode body in the laminating direction have the laminated layer End surfaces extending along the direction are respectively formed, and the current collecting members are arranged on one end surface of the both end portions and aligned in a direction perpendicular to the stacking direction of the electrode bodies, And the second member, and the first member includes the electrode A first side surface that is a side surface parallel to the layer and a second side surface that is a side surface opposite to the first side surface, and the first member is electrically connected to the electrode terminal, The first member is formed with a first protrusion that protrudes toward the second member and at least one second protrusion, and the first protrusion is at least continuous with the first side surface. And a first end surface parallel to the first side surface, a second end surface which is an end surface opposite to the first end surface, and an end on the tip side of the first protrusion on the first end surface and the second end surface. The first connecting part has a first inclined part, the first inclined part forms an acute angle with the first end surface, and the second projecting part is at least A third end surface formed on the first end surface side and parallel to the first end surface; A fourth end surface that is the end surface opposite to the end surface; and a second connecting portion that connects the third end surface and the end portions of the second projecting portion on the tip end side of the fourth end surface, and the second connecting portion. The portion has a second inclined portion, the second inclined portion forms an acute angle with the fourth end surface, and the second member is a third side surface that is a side surface parallel to the layer in the electrode body, A fourth side surface, which is a side surface opposite to the third side surface, is formed, the third side surface is on the same side as the first side surface, and the fourth side surface is on the same side as the second side surface, respectively. The second member is formed continuously with the first member or through the uncoated portion forming the current collector, and the second member protrudes toward the first member. 3 protrusions and at least one fourth protrusion are formed, and the third protrusion includes at least the fourth protrusion. A fifth end surface that is continuous with the side surface and parallel to the fourth side surface; a sixth end surface that is an end surface opposite to the fifth end surface; and the third protrusion on the fifth end surface and the sixth end surface. The third connecting portion has a third inclined portion, and the third inclined portion forms an acute angle with the fifth end surface, and the fourth connecting portion connects the end portions on the distal end side of the third connecting portion. The protrusion is at least a seventh end surface formed on the fifth end surface side and parallel to the fifth end surface, an eighth end surface that is an end surface opposite to the seventh end surface, and the seventh end surface. The fourth end portion includes a fourth connecting portion that connects end portions of the second projecting portions on the eighth end surface, and the fourth connecting portion includes a fourth inclined portion, and the fourth inclined portion includes: An acute angle with the eighth end surface, and in the stacking direction, from the first end surface side, the first protrusion and the fourth protrusion And the second protrusion, the third protrusion, the second protrusion, and the fourth protrusion are sequentially disposed from the second end surface side in the stacking direction. The current collector is formed between the first projection and the fourth projection, between the second projection and the fourth projection, and between the second projection and the third projection. The uncoated portions are each divided and arranged in a plurality of bundles, and the second inclined portion and the fourth inclined portion of the second protruding portion and the fourth protruding portion, respectively, in the stacking direction. The gist of the present invention is that the width is formed to exceed half of the width of the second protrusion and the fourth protrusion in the stacking direction.

これによれば、集電部における積層方向と直交する方向から当該集電部を挟むように第1部材及び第2部材を配置する。そして、集電部における積層方向の外側に、第1部材に形成された第1突起部、及び第2部材に形成された第2突起部をそれぞれ配置させるとともに、集電部をなす各電極シートの未塗工部の間に、第1部材に形成された第2突起部、及び第2部材に形成された第4突起部をそれぞれ挿入させる。   According to this, a 1st member and a 2nd member are arrange | positioned so that the said current collection part may be pinched | interposed from the direction orthogonal to the lamination direction in a current collection part. And each 1st projection part formed in the 1st member and the 2nd projection part formed in the 2nd member are arranged outside the lamination direction in a current collection part, and each electrode sheet which makes a current collection part The second protrusion formed on the first member and the fourth protrusion formed on the second member are inserted between the uncoated portions.

ここで、第2突起部の第2連接部に形成された第2傾斜部は第4端面と鋭角をなし、第4突起部の第4連接部に形成された第4傾斜部は第8端面と鋭角をなしていることから、第2傾斜部と第4傾斜部とは、同一方向側に傾斜している。そして、第2傾斜部と第4傾斜部同士を相互に沿わせつつ、第1部材の第2突起部を第2部材の第3突起部と第4突起部との間に挿入させる一方で、第2部材の第4突起部を第1部材の第1突起部と第2突起部との間に挿入させる。これにより、第1部材及び第2部材が、第1突起部と第3突起部が相互に近接する方向へ相対的に移動(斜行)される。   Here, the second inclined portion formed at the second connecting portion of the second projecting portion forms an acute angle with the fourth end surface, and the fourth inclined portion formed at the fourth connecting portion of the fourth projecting portion is the eighth end surface. Therefore, the second inclined portion and the fourth inclined portion are inclined in the same direction side. And while the second inclined portion and the fourth inclined portion are along each other, the second protruding portion of the first member is inserted between the third protruding portion and the fourth protruding portion of the second member, The fourth protrusion of the second member is inserted between the first protrusion and the second protrusion of the first member. Accordingly, the first member and the second member are relatively moved (skewed) in the direction in which the first protrusion and the third protrusion are close to each other.

このため、第1突起部と第4突起部との間、第2突起部と第4突起部との間、及び第2突起部と第3突起部との間には、集電部をなす未塗工部がそれぞれ複数の束に分割して配置され、これにより集電部材と集電部とが連結され、電気的に接続される。特に、請求項1に記載の発明によれば、第2傾斜部における積層方向の幅は、第2突起部の積層方向の幅の半分を超えて形成されているとともに、第4傾斜部における積層方向の幅は、第4突起部の積層方向の幅の半分を超えて形成されている。このため、仮に集電部が、第1部材及び第2部材における前記積層方向の長さより大きい場合であっても、前記積層方向において第2傾斜部及び第4傾斜部の形成範囲分だけ、第1部材と第2部材との間により多数の未塗工部を挟み込むように配置できる。したがって、集電部と集電部材とを容易に連結できる。   Therefore, a current collector is formed between the first protrusion and the fourth protrusion, between the second protrusion and the fourth protrusion, and between the second protrusion and the third protrusion. The uncoated portion is divided into a plurality of bundles, and the current collecting member and the current collecting portion are thereby connected and electrically connected. In particular, according to the first aspect of the present invention, the width in the stacking direction of the second inclined portion is formed to exceed half the width of the second projecting portion in the stacking direction, and the stack in the fourth inclined portion. The width in the direction is formed to exceed half of the width in the stacking direction of the fourth protrusions. For this reason, even if the current collector is larger than the length in the stacking direction of the first member and the second member, the second inclined portion and the fourth tilted portion are formed in the stacking direction by the formation range. It can arrange | position so that many uncoated parts may be inserted | pinched between 1 member and 2nd member. Therefore, the current collector and the current collector can be easily connected.

請求項2に記載の発明は、請求項1に記載の蓄電装置において、前記第1傾斜部、前記第2傾斜部、前記第3傾斜部、及び前記第4傾斜部は、それぞれ前記第1突起部、前記第2突起部、前記第3突起部、及び前記第4突起部の先端に形成されていることを要旨とする。   According to a second aspect of the present invention, in the power storage device according to the first aspect, each of the first inclined portion, the second inclined portion, the third inclined portion, and the fourth inclined portion is the first protrusion. And the second protrusion, the third protrusion, and the fourth protrusion.

これによれば、各第1〜第4傾斜部は、それぞれ第1〜第4突起部の先端に形成されている。このため、各第1〜第4傾斜部の先端にそれぞれ傾斜部を設けない構成と比較して、集電部をなす未塗工部(金属薄板)の間に第2,第4突起部を挿入する際に、各第1〜第4突起部の先端が未塗工部の縁部に当接することによって未塗工部(金属薄板)が損傷することを抑制できる。   According to this, each 1st-4th inclination part is formed in the front-end | tip of the 1st-4th projection part, respectively. For this reason, compared with the structure which does not provide an inclination part at the front-end | tip of each 1st-4th inclination part, a 2nd, 4th protrusion part is provided between the uncoated parts (metal thin plate) which make a current collection part. When inserting, it can suppress that an uncoated part (metal thin plate) is damaged by the front-end | tip of each 1st-4th projection part contacting the edge part of an uncoated part.

請求項3に記載の発明は、請求項1または2に記載の蓄電装置において、前記第3突起部の先端及び前記第4突起部の先端と、前記第1部材における前記第1突起部及び前記第2突起部の基端部である第1基端部と、は離間しており、前記第1突起部の先端及び前記第2突起部の先端と、前記第2部材における前記第3突起部及び前記第4突起部の基端部である第2基端部と、は離間していることを要旨とする。   The invention according to claim 3 is the power storage device according to claim 1 or 2, wherein the tip of the third protrusion and the tip of the fourth protrusion, the first protrusion of the first member, and the The first protrusion, which is the base end of the second protrusion, is spaced apart from the first protrusion and the second protrusion, and the third protrusion of the second member. And it makes it a summary to have separated from the 2nd base end part which is a base end part of the said 4th projection part.

これによれば、第3突起部及び第4突起部の先端と第1基端部とが離間しているとともに、第1突起部及び第2突起部の先端と第2基端部とが離間している。このため、第1〜第4突起部の弾性を利用し、各突起部の間に電極シートにおける未塗工部を確実に挟み込むように配置できる。   According to this, while the front-end | tip and 1st base end part of a 3rd projection part and a 4th projection part are spaced apart, the front-end | tip and 2nd base end part of a 1st projection part and a 2nd projection part are spaced apart. doing. For this reason, it can arrange | position so that the uncoated part in an electrode sheet may be pinched | interposed reliably between each projection part using the elasticity of a 1st-4th projection part.

請求項4に記載の発明は、請求項1〜3のいずれか1項に記載の蓄電装置において、前記積層方向と直交する方向において、前記集電部をなす前記未塗工部の縁部のうち前記第1基端部側に配置される第1縁部は、前記第2基端部側に傾斜しているとともに、前記未塗工部の縁部のうち、前記第2基端部側に配置される第2縁部は、前記第1基端部側に傾斜していることを要旨とする。   Invention of Claim 4 is an electrical storage apparatus of any one of Claims 1-3. WHEREIN: In the direction orthogonal to the said lamination direction, the edge part of the said uncoated part which makes the said current collection part Of these, the first edge disposed on the first base end side is inclined toward the second base end side, and among the edges of the uncoated part, the second base end side The gist is that the second edge portion arranged on the side is inclined toward the first base end side.

これによれば、第1部材に形成された第2突起部の先端部を未塗工部の間に挿入する際に、当該先端部が未塗工部の第1縁部と当接する面積を小さくすることができるとともに、第2部材に形成された第4突起部の先端部を未塗工部の間に挿入する際に、当該先端部が未塗工部の第2縁部と当接する面積を小さくできる。したがって、第2突起部、及び第4突起部を未塗工部の間に挿入する際に、未塗工部(金属薄板)が破損することを抑制できる。   According to this, when inserting the front-end | tip part of the 2nd projection part formed in the 1st member between uncoated parts, the area which the said front-end | tip part contact | abuts with the 1st edge part of an uncoated part. While being able to be reduced, when the tip of the fourth protrusion formed on the second member is inserted between the uncoated portions, the tip contacts the second edge of the uncoated portion. The area can be reduced. Therefore, when inserting the 2nd projection part and the 4th projection part between uncoated parts, it can control that an uncoated part (metal thin plate) is damaged.

請求項5に記載の発明は、請求項1〜4のいずれか1項に記載の蓄電装置において、前記第1突起部と前記第3突起部、及び前記第2突起部と前記第4突起部とは、それぞれ同一形状をなしていることを要旨とする。   According to a fifth aspect of the present invention, in the power storage device according to any one of the first to fourth aspects, the first projecting portion and the third projecting portion, and the second projecting portion and the fourth projecting portion. The gist is that each has the same shape.

これによれば、集電部をなす未塗工部との接触領域の形状を第1,第2部材とで異なる形状に形成する場合と比較して、第1,第2部材を簡便に形成できる。
請求項6に記載の発明は、請求項1〜5のいずれか1項に記載の蓄電装置において、前記第2突起部、及び前記第4突起部は、それぞれの基端部側における前記積層方向に沿う断面積よりも、それぞれの先端部側における前記積層方向に沿う断面積が小さい先細り形状をなしていることを要旨とする。
According to this, compared with the case where the shape of a contact area with the uncoated part which makes a current collection part is formed in a different shape with the first and second members, the first and second members are simply formed. it can.
The invention according to claim 6 is the power storage device according to any one of claims 1 to 5, wherein the second protrusion and the fourth protrusion are in the stacking direction on the base end side. The gist is that the cross-sectional area along the laminating direction on each tip side is smaller than the cross-sectional area along the direction.

これによれば、第2,第4突起部は、積層方向に沿う断面積が基端部側よりも先端部側のほうが小さい先細り形状をなしていることから、第2,第4突起部を未塗工部(金属薄板)の間に挿入する際に、第2,第4突起部の先端が未塗工部の各縁部と当接する面積を小さくできる。したがって、第2,第4突起部を未塗工部の間に挿入する際に、未塗工部が破損することを抑制できる。   According to this, since the second and fourth projecting portions have a tapered shape in which the cross-sectional area along the stacking direction is smaller on the distal end side than on the proximal end side, the second and fourth projecting portions are When inserting between uncoated parts (thin metal plates), the area where the tips of the second and fourth protrusions abut against each edge of the uncoated part can be reduced. Therefore, when inserting the 2nd, 4th projection part between uncoated parts, it can control that an uncoated part is damaged.

請求項7に記載の発明は、請求項1〜6のいずれか1項に記載の蓄電装置において、前記第1部材及び前記第2部材は、前記金属薄板と同一の金属から形成されていることを要旨とする。   The invention according to claim 7 is the power storage device according to any one of claims 1 to 6, wherein the first member and the second member are formed of the same metal as the metal thin plate. Is the gist.

これによれば、第1部材及び第2部材は、金属薄板と同一の金属から形成されていることから、第1,第2部材の間に集電部をなす未塗工部を配置した状態で抵抗溶接を行うことにより、第1,第2部材と未塗工部とを容易に接合できる。   According to this, since the 1st member and the 2nd member are formed from the same metal as a metal thin plate, the state which has arrange | positioned the uncoated part which makes a current collection part between the 1st, 2nd members By performing resistance welding in step 1, the first and second members and the uncoated portion can be easily joined.

請求項8に記載の発明は、金属薄板、前記金属薄板の表面に活物質が塗布された塗工部、及び前記活物質が塗布されていない未塗工部を有する電極シートが複数重なって層状の構造をなす電極体と、前記電極体の一方の縁部から延出形成され、かつ各前記電極シートの未塗工部が複数重なって層状の構造をなす集電部と、前記電極体から電力を取り出すための電極端子と、前記集電部と前記電極端子とを電気的に接続した集電部材とを有する蓄電装置であって、前記電極体における積層方向の両端部には、前記積層方向に沿って延びる端面がそれぞれ形成されており、前記集電部材は、前記両端部の一方の端面上に、かつ前記電極体の積層方向に直交する方向に並んで配置される第1部材、及び第2部材を有し、前記第1部材には、前記電極体における層と平行する側面である第1側面と、前記第1側面とは反対側の側面である第2側面とがそれぞれ形成され、前記第1部材は、前記電極端子と電気的に接続され、前記第1部材には、前記第2部材側に突出する第1突起部、及び少なくとも一つの第2突起部とが形成され、前記第1突起部は、少なくとも、前記第1側面と連続し、かつ前記第1側面と平行な第1端面と、前記第1端面とは反対側の端面である第2端面と、前記第1端面と前記第2端面における前記第1突起部の先端側の端部同士を繋ぐ第1連接部によって構成され、前記第1連接部は第1傾斜部を有し、前記第1傾斜部は、前記第1端面と鋭角をなし、前記第2突起部は、少なくとも、前記第1端面側に形成され、かつ前記第1端面と平行する第3端面と、前記第3端面とは反対側の端面である第4端面と、前記第3端面と前記第4端面における前記第2突起部の先端側の端部同士を繋ぐ第2連接部によって構成され、前記第2連接部は、第2傾斜部を有し、前記第2傾斜部は、前記第4端面と鋭角をなし、前記第2部材は、前記電極体における層と平行する側面である第3側面と、前記第3側面とは反対側の側面である第4側面とがそれぞれ形成され、前記第3側面は前記第1側面と同じ側に、前記第4側面は、前記第2側面と同じ側に、それぞれ形成され、前記第2部材は、前記第1部材と直接、又は前記集電部をなす前記未塗工部を介して連続し、前記第2部材には、前記第1部材側に突出する第3突起部、及び少なくとも一つの第4突起部とが形成され、前記第3突起部は、少なくとも、前記第4側面と連続し、かつ前記第4側面と平行な第5端面と、前記第5端面とは反対側の端面である第6端面と、前記第5端面と前記第6端面における前記第3突起部の先端側の端部同士を繋ぐ第3連接部によって構成され、前記第3連接部は第3傾斜部を有し、前記第3傾斜部は、前記第5端面と鋭角をなし、前記第4突起部は、少なくとも、前記第5端面側に形成され、かつ前記第5端面と平行する第7端面と、前記第7端面とは反対側の端面である第8端面と、前記第7端面と前記第8端面における前記第2突起部の先端側の端部同士を繋ぐ第4連接部によって構成され、前記第4連接部は、第4傾斜部を有し、前記第4傾斜部は、前記第8端面と鋭角をなし、前記積層方向において、前記第1端面側から、前記第1突起部、前記第4突起部、及び前記第2突起部が順に配置され、前記積層方向において、前記第2端面側から、前記第3突起部、前記第2突起部、及び前記第4突起部が順に配置され、記第1突起部と前記第4突起部との間、前記第2突起部と前記第4突起部との間、及び前記第2突起部と前記第3突起部との間には、前記集電部をなす前記未塗工部がそれぞれ複数の束に分割して配置されており、前記積層方向と直交する方向において、前記集電部をなす前記未塗工部の縁部のうち前記第1突起部及び前記第2突起部の基端部である第1基端部側に配置される第1縁部は、前記第3突起部及び前記第4突起部の基端部である第2基端部側に傾斜しているとともに、前記未塗工部の縁部のうち、前記第2基端部側に配置される第2縁部は、前記第1基端部側に傾斜していることを要旨とする。   The invention according to claim 8 is a layered structure in which a plurality of electrode sheets having a thin metal plate, a coated portion in which an active material is applied to the surface of the thin metal plate, and an uncoated portion in which the active material is not applied are overlapped. From the electrode body, a current collector portion extending from one edge of the electrode body, and a plurality of uncoated portions of the electrode sheets overlapping to form a layered structure, and the electrode body A power storage device having an electrode terminal for taking out electric power, and a current collecting member that electrically connects the current collecting part and the electrode terminal, wherein both ends of the electrode body in the laminating direction have the laminated layer End surfaces extending along the direction are respectively formed, and the current collecting members are arranged on one end surface of the both end portions and aligned in a direction perpendicular to the stacking direction of the electrode bodies, And the second member, and the first member includes the electrode A first side surface that is a side surface parallel to the layer and a second side surface that is a side surface opposite to the first side surface, and the first member is electrically connected to the electrode terminal, The first member is formed with a first protrusion that protrudes toward the second member and at least one second protrusion, and the first protrusion is at least continuous with the first side surface. And a first end surface parallel to the first side surface, a second end surface which is an end surface opposite to the first end surface, and an end on the tip side of the first protrusion on the first end surface and the second end surface. The first connecting part has a first inclined part, the first inclined part forms an acute angle with the first end surface, and the second projecting part is at least A third end surface formed on the first end surface side and parallel to the first end surface; A fourth end surface that is the end surface opposite to the end surface; and a second connecting portion that connects the third end surface and the end portions of the second projecting portion on the tip end side of the fourth end surface, and the second connecting portion. The portion has a second inclined portion, the second inclined portion forms an acute angle with the fourth end surface, and the second member is a third side surface that is a side surface parallel to the layer in the electrode body, A fourth side surface, which is a side surface opposite to the third side surface, is formed, the third side surface is on the same side as the first side surface, and the fourth side surface is on the same side as the second side surface, respectively. The second member is formed continuously with the first member or through the uncoated portion forming the current collector, and the second member protrudes toward the first member. 3 protrusions and at least one fourth protrusion are formed, and the third protrusion includes at least the fourth protrusion. A fifth end surface that is continuous with the side surface and parallel to the fourth side surface; a sixth end surface that is an end surface opposite to the fifth end surface; and the third protrusion on the fifth end surface and the sixth end surface. The third connecting portion has a third inclined portion, and the third inclined portion forms an acute angle with the fifth end surface, and the fourth connecting portion connects the end portions on the distal end side of the third connecting portion. The protrusion is at least a seventh end surface formed on the fifth end surface side and parallel to the fifth end surface, an eighth end surface that is an end surface opposite to the seventh end surface, and the seventh end surface. The fourth end portion includes a fourth connecting portion that connects end portions of the second projecting portions on the eighth end surface, and the fourth connecting portion includes a fourth inclined portion, and the fourth inclined portion includes: An acute angle with the eighth end surface, and in the stacking direction, from the first end surface side, the first protrusion and the fourth protrusion And the second protrusion, the third protrusion, the second protrusion, and the fourth protrusion are sequentially disposed from the second end surface side in the stacking direction. The current collector is formed between the first projection and the fourth projection, between the second projection and the fourth projection, and between the second projection and the third projection. The uncoated portions are each divided and arranged in a plurality of bundles, and in the direction orthogonal to the stacking direction, the first protrusions and the first protrusions of the uncoated portions that form the current collector The first edge portion disposed on the first base end side which is the base end portion of the second projection portion is the second base end side which is the base end portion of the third projection portion and the fourth projection portion. Of the uncoated portion, the second edge disposed on the second base end side is inclined toward the first base end side. The gist that you are.

これによれば、請求項1に記載の発明と同様にして、第1突起部と第4突起部との間、第2突起部と第4突起部との間、及び第2突起部と第3突起部との間に、集電部をなす未塗工部をそれぞれ複数の束に分割して配置させ、これにより集電部材と集電部とを連結し、電気的に接続することができる。そして、請求項8に記載の発明では、積層方向と直交する方向において、集電部をなす未塗工部の縁部のうち第1部材の第1基端部側に配置される第1縁部は、第2部材の第2基端部側に傾斜しているとともに、未塗工部の縁部のうち第2部材の第2基端部側に配置される第2縁部は、第1基端部側に傾斜している。このため、第1部材に形成された第2突起部の先端部を未塗工部の間に挿入する際に、当該先端部が未塗工部の第1縁部と当接する面積を小さくすることができるとともに、第2部材に形成された第4突起部の先端部を未塗工部の間に挿入する際に、当該先端部が未塗工部の第2縁部と当接する面積を小さくできる。したがって、第2突起部、及び第4突起部を未塗工部の間に挿入する際に、未塗工部(金属薄板)が破損することを抑制できる。したがって、集電部と集電部材とを容易に連結できる。   According to this, similarly to the first aspect of the invention, between the first protrusion and the fourth protrusion, between the second protrusion and the fourth protrusion, and between the second protrusion and the first protrusion. Between the three protrusions, the uncoated part forming the current collector is divided and arranged in a plurality of bundles, whereby the current collector and the current collector are connected and electrically connected. it can. And in invention of Claim 8, in the direction orthogonal to the lamination direction, the 1st edge arrange | positioned in the 1st base end part side of the 1st member among the edge parts of the uncoated part which makes a current collection part. The portion is inclined to the second base end side of the second member, and the second edge disposed on the second base end side of the second member among the edges of the uncoated portion is It inclines to the 1 base end part side. For this reason, when inserting the front-end | tip part of the 2nd projection part formed in the 1st member between uncoated parts, the area which the said front-end | tip part contacts the 1st edge part of an uncoated part is made small. In addition, when the tip of the fourth protrusion formed on the second member is inserted between the uncoated parts, the area where the tip contacts the second edge of the uncoated part Can be small. Therefore, when inserting the 2nd projection part and the 4th projection part between uncoated parts, it can control that an uncoated part (metal thin plate) is damaged. Therefore, the current collector and the current collector can be easily connected.

請求項9に記載の発明は、請求項8に記載の蓄電装置において、前記第2突起部には、前記第3端面と前記第4端面とを繋ぎ、かつ前記電極体側に形成される第1下面と、前記第1下面とは反対側の第1上面が形成され、前記第2突起部の先端部には、前記第1下面と前記第1上面とを連続する第5傾斜面が形成され、前記第5傾斜面は、前記第1下面又は前記第1上面となす角度が鋭角であり、前記第4突起部には、前記第7端面と前記第8端面とを繋ぎ、かつ前記電極体側に形成される第2下面と、前記第2下面とは反対側の第2上面が形成され、前記第4突起部の先端部には、前記第2下面と前記第2上面とを連続する第6傾斜面が形成され、前記第6傾斜面は、前記第2下面又は前記第2上面となす角度が鋭角であることを要旨とする。   According to a ninth aspect of the present invention, in the power storage device according to the eighth aspect, the second protrusion is connected to the third end surface and the fourth end surface and is formed on the electrode body side. A lower surface and a first upper surface opposite to the first lower surface are formed, and a fifth inclined surface that continues the first lower surface and the first upper surface is formed at a tip portion of the second protrusion. The fifth inclined surface has an acute angle with the first lower surface or the first upper surface, and the fourth protrusion is connected to the seventh end surface and the eighth end surface, and is on the electrode body side. And a second upper surface opposite to the second lower surface is formed, and a distal end portion of the fourth projecting portion has a second continuous with the second lower surface and the second upper surface. 6 inclined surfaces are formed, and the sixth inclined surface is characterized in that an angle formed with the second lower surface or the second upper surface is an acute angle. .

これによれば、第2突起部の先端部には、第5傾斜面が形成されているとともに、この第5傾斜面は、第2突起部の第1下面又は第1上面となす角度が鋭角である。また、第4突起部の先端部には、第6傾斜面が形成されているとともに、この第6傾斜面は、第1突起部の第2下面又は第2上面となす角度が鋭角である。このため、第2,第4突起部の先端部は、所謂先細り形状をなすことから、第2,第4突起部を未塗工部の間に挿入する際に、第2,第4突起部の先端部が未塗工部の各縁部と当接する面積を小さくできる。したがって、第2,第4突起部を未塗工部の間に挿入する際に、未塗工部(金属薄板)が破損することを抑制できる。   According to this, the 5th inclined surface is formed in the front-end | tip part of a 2nd projection part, and the angle which this 5th inclined surface makes with the 1st lower surface or 1st upper surface of a 2nd projection part is an acute angle. It is. In addition, a sixth inclined surface is formed at the tip portion of the fourth protrusion, and the angle formed between the sixth inclined surface and the second lower surface or the second upper surface of the first protrusion is an acute angle. For this reason, since the tip part of the 2nd and 4th projection part makes what is called a taper shape, when inserting the 2nd and 4th projection part between uncoated parts, the 2nd and 4th projection part It is possible to reduce the area in which the tip of each of the two contacts the respective edges of the uncoated portion. Therefore, when inserting a 2nd, 4th projection part between uncoated parts, it can suppress that an uncoated part (metal thin plate) breaks.

請求項10に記載の発明は、請求項1〜請求項9に記載の蓄電装置において、前記蓄電装置は、二次電池であることを要旨とする。これによれば、二次電池において集電部と集電部材とを容易に連結できる。   The gist of the power storage device according to any one of claims 1 to 9 is that the power storage device is a secondary battery. According to this, a current collection part and a current collection member can be easily connected in a secondary battery.

請求項11に記載の発明は、車両において、請求項1〜10のいずれか1項に記載の蓄電装置を搭載したことを要旨とする。
これによれば、蓄電装置として、集電部をなす未塗工部が破損することを抑制して集電部と集電部材とを容易に連結できることから、蓄電装置を含む車両の製造に要する時間を短縮できる。
The gist of the invention described in claim 11 is that the power storage device according to any one of claims 1 to 10 is mounted in a vehicle.
According to this, as the power storage device, it is possible to easily connect the current collector and the current collecting member while preventing the uncoated portion forming the current collector from being damaged, and thus it is necessary to manufacture a vehicle including the power storage device. You can save time.

本発明によれば、集電部と集電部材とを容易に連結できる。   ADVANTAGE OF THE INVENTION According to this invention, a current collection part and a current collection member can be connected easily.

二次電池を模式的に示す断面図。Sectional drawing which shows a secondary battery typically. 分解した電極体を模式的に示す斜視図。The perspective view which shows typically the decomposed | disassembled electrode body. (a)は、図1の部分拡大図、(b)は、(a)に示すA−A線断面図。(A) is the elements on larger scale of FIG. 1, (b) is the sectional view on the AA line shown to (a). (a)及び(b)は、二次電池の製造方法を説明するための模式図。(A) And (b) is a schematic diagram for demonstrating the manufacturing method of a secondary battery. (a)及び(b)は、二次電池の製造方法を説明するための模式図。(A) And (b) is a schematic diagram for demonstrating the manufacturing method of a secondary battery. (a)は、第2の実施形態における二次電池を模式的に示す断面図、(b)は、(a)に示すB−B線断面図。(A) is sectional drawing which shows typically the secondary battery in 2nd Embodiment, (b) is the BB sectional drawing shown to (a). 別の実施形態における電極体を模式的に示す正面図。The front view which shows the electrode body in another embodiment typically. (a)は、別の実施形態における第2突起部及び第4突起部を模式的に示す平面図、(b)は、同じく正面図。(A) is a top view which shows typically the 2nd projection part and 4th projection part in another embodiment, (b) is a front view similarly.

(第1の実施形態)
以下、本発明を具体化した第1の実施形態を図1〜図5にしたがって説明する。
図1に示すように、車両(例えば産業車両や乗用車両)に搭載される蓄電装置としての二次電池10は、全体として扁平な略直方体状をなすケース11を備えている。ケース11は、有底筒状(本実施形態では四角筒状)に形成された本体部材12、及び本体部材12の開口部12aを密閉するように、本体部材12に組み付けられる平板状(本実施形態では矩形平板状)をなす蓋部材13から形成されている。本体部材12、及び蓋部材13は、何れも金属(例えばステンレスやアルミニウムなど)から形成されている。以下の説明では、矢印Y1に示すケース11の長手方向を左右方向と示し、矢印Y2に示すケース11の高さ方向を上下方向と示し、図3で矢印Y3に示すケース11の短手方向を前後方向と示す。なお、図1では、紙面に対して垂直な方向が前後方向となる。
(First embodiment)
A first embodiment of the present invention will be described below with reference to FIGS.
As shown in FIG. 1, a secondary battery 10 as a power storage device mounted on a vehicle (for example, an industrial vehicle or a passenger vehicle) includes a case 11 having a flat and substantially rectangular parallelepiped shape as a whole. The case 11 has a flat plate shape (this embodiment) assembled to the main body member 12 so as to seal the main body member 12 formed in a bottomed cylindrical shape (square tube shape in the present embodiment) and the opening 12a of the main body member 12. It is formed from a lid member 13 having a rectangular flat plate shape. The main body member 12 and the lid member 13 are both made of metal (for example, stainless steel or aluminum). In the following description, the longitudinal direction of the case 11 indicated by the arrow Y1 is indicated as the left-right direction, the height direction of the case 11 indicated by the arrow Y2 is indicated as the vertical direction, and the short direction of the case 11 indicated by the arrow Y3 in FIG. This is indicated as the front-rear direction. In FIG. 1, the direction perpendicular to the paper surface is the front-rear direction.

蓋部材13の外面(上面)には、円柱状(略円柱状)をなし、二次電池10(後述する電極体25)から電力を外部に取り出すための電極端子(外部端子)としての正極端子15、及び電極端子としての負極端子16が突出するように設けられている。本実施形態の二次電池10では、正極端子15及び負極端子16を介して充電及び放電が行われる。なお、正極端子15及び負極端子16は、ケース11(本体部材12及び蓋部材13)と絶縁された状態とされている。   The outer surface (upper surface) of the lid member 13 has a cylindrical shape (substantially cylindrical shape), and a positive electrode terminal as an electrode terminal (external terminal) for taking out electric power from the secondary battery 10 (electrode body 25 described later) to the outside. 15 and a negative electrode terminal 16 as an electrode terminal are provided so as to protrude. In the secondary battery 10 of the present embodiment, charging and discharging are performed via the positive terminal 15 and the negative terminal 16. The positive terminal 15 and the negative terminal 16 are insulated from the case 11 (the main body member 12 and the lid member 13).

また、ケース11には、シート状のセパレータ23を間に挟んだ状態(介在させた状態)で、電極シートとしての正電極シート21及び電極シートとしての負電極シート22が複数重なって層状の構造(積層構造)をなす電極体25が収容(収納)されている。電極体25は、全体として上下方向及び左右方向に扁平な直方体状(略直方体状)をなしている。なお、電極体25は、絶縁材料からなる絶縁袋11aに覆われた状態でケース11に収容されているとともに、ケース11内には、例えばリチウムイオン二次電池や、ニッケル水素二次電池というように、二次電池10の種類に応じた電解質が充填されている。   The case 11 has a layered structure in which a plurality of positive electrode sheets 21 as electrode sheets and negative electrode sheets 22 as electrode sheets overlap each other with a sheet-like separator 23 sandwiched therebetween (intervened state). An electrode body 25 having a (laminated structure) is accommodated (accommodated). The electrode body 25 has a rectangular parallelepiped shape (substantially rectangular parallelepiped shape) that is flat in the vertical direction and the horizontal direction as a whole. The electrode body 25 is accommodated in the case 11 in a state of being covered with an insulating bag 11a made of an insulating material, and in the case 11, for example, a lithium ion secondary battery or a nickel hydride secondary battery is used. Further, an electrolyte corresponding to the type of the secondary battery 10 is filled.

図2に示すように、正電極シート21及び負電極シート22は、四角形(矩形)のシート状をなす金属薄板(金属シート)としての金属箔26を備えている。金属箔26は、例えばリチウムイオン二次電池や、ニッケル水素二次電池というように、二次電池10の種類に応じた金属により形成される。また、金属箔26に用いられる金属は、正電極シート21と、負電極シート22とでも異なる。本実施形態において、正電極シート21の金属箔26は、アルミニウムからなる一方で、負電極シート22の金属箔26は、銅からなる。   As shown in FIG. 2, the positive electrode sheet 21 and the negative electrode sheet 22 include a metal foil 26 as a thin metal plate (metal sheet) having a rectangular (rectangular) sheet shape. The metal foil 26 is formed of a metal corresponding to the type of the secondary battery 10 such as a lithium ion secondary battery or a nickel hydride secondary battery. The metal used for the metal foil 26 is different between the positive electrode sheet 21 and the negative electrode sheet 22. In the present embodiment, the metal foil 26 of the positive electrode sheet 21 is made of aluminum, while the metal foil 26 of the negative electrode sheet 22 is made of copper.

各金属箔26の両表面(前面及び後面)には、各金属箔26の1辺となる上縁部26aから左右方向の全幅にわたって一定幅で設定された非塗布領域26bを除き、その全面に活物質が塗布され、活物質層27が形成されている。即ち、非塗布領域26bは、金属箔26の上縁部26aに沿って延設されている。なお、金属箔26には、二次電池10の種類に応じた活物質が塗布される。また、金属箔26に塗布される活物質は、正電極シート21と、負電極シート22とでも異なる。正電極シート21及び負電極シート22において、活物質層27が形成された領域は、活物質が塗布された塗工部27aとなる。   On both surfaces (front surface and rear surface) of each metal foil 26, except for the non-application region 26 b set with a constant width from the upper edge portion 26 a serving as one side of each metal foil 26 over the entire width in the left-right direction, An active material is applied to form an active material layer 27. That is, the non-application area 26 b extends along the upper edge portion 26 a of the metal foil 26. Note that an active material corresponding to the type of the secondary battery 10 is applied to the metal foil 26. The active material applied to the metal foil 26 is different between the positive electrode sheet 21 and the negative electrode sheet 22. In the positive electrode sheet 21 and the negative electrode sheet 22, a region where the active material layer 27 is formed becomes a coating portion 27a to which the active material is applied.

各正電極シート21の上縁部26aにおいて左右方向の中央より左側には、非塗布領域26bを打ち抜き加工することにより、四角形(略四角形)をなす正電極リード21aが上方に向かって延出形成されている。また、各負電極シート22の上縁部26aにおいて左右方向の中央より右側には、非塗布領域26bを打ち抜き加工することにより、四角形(略四角形)をなす負電極リード22aが上方に向かって延出形成されている。このため、正電極リード21a及び負電極リード22aは、表面に活物質層27が形成されていない。即ち本実施形態において、正電極リード21a及び負電極リード22aは、金属箔26の表面に活物質が塗布されていない未塗工部となる。また、セパレータ23は、絶縁性を有する樹脂材料からなり、極めて微細な空孔構造をなす矩形の多孔性シートとされている。セパレータ23は、正電極シート21と負電極シート22との間に介在して正電極シート21と負電極シート22とを絶縁する。   By punching the non-coating region 26b on the left side of the upper edge portion 26a of each positive electrode sheet 21 in the left-right direction, a square (substantially square) positive electrode lead 21a is formed to extend upward. Has been. In addition, by punching the non-application area 26b on the right side of the center in the left-right direction at the upper edge portion 26a of each negative electrode sheet 22, the negative electrode lead 22a having a square shape (substantially square shape) extends upward. Has been formed. For this reason, the active material layer 27 is not formed on the surfaces of the positive electrode lead 21a and the negative electrode lead 22a. That is, in the present embodiment, the positive electrode lead 21a and the negative electrode lead 22a are uncoated portions where the active material is not applied to the surface of the metal foil 26. The separator 23 is made of an insulating resin material and is a rectangular porous sheet having an extremely fine pore structure. The separator 23 is interposed between the positive electrode sheet 21 and the negative electrode sheet 22 to insulate the positive electrode sheet 21 and the negative electrode sheet 22.

そして、電極体25は、正電極シート21及び負電極シート22の間にセパレータ23を挟んだ状態で、正電極シート21及び負電極シート22を前後方向(厚さ方向)に複数、積層して層状に形成されてなる。詳しく言えば、電極体25において、正電極シート21及び負電極シート22は、…→正電極シート21→負電極シート22→正電極シート21…のように、交互に配置されている。   The electrode body 25 is formed by laminating a plurality of positive electrode sheets 21 and negative electrode sheets 22 in the front-rear direction (thickness direction) with the separator 23 sandwiched between the positive electrode sheet 21 and the negative electrode sheet 22. It is formed in layers. Specifically, in the electrode body 25, the positive electrode sheets 21 and the negative electrode sheets 22 are alternately arranged in the order of... → positive electrode sheet 21.fwdarw.negative electrode sheet 22.fwdarw.positive electrode sheet 21.

本実施形態では、矢印Y1に示す左右方向、及びY2に示す上下方向が正電極シート21(正電極リード21a)、負電極シート22(負電極リード22a)、及びセパレータ23の面方向となり、矢印Y3に示す前後方向が電極体25における正電極シート21及び負電極シート22の積層方向(層方向)となる。なお、電極体25の積層方向は、正電極シート21、負電極シート22及びセパレータ23の面方向と直交する方向と一致する。また、本実施形態では、上方へ向かう方向が正電極リード21a及び負電極リード22aの延出方向となる。   In the present embodiment, the horizontal direction indicated by the arrow Y1 and the vertical direction indicated by Y2 are the surface directions of the positive electrode sheet 21 (positive electrode lead 21a), the negative electrode sheet 22 (negative electrode lead 22a), and the separator 23. The front-rear direction indicated by Y3 is the stacking direction (layer direction) of the positive electrode sheet 21 and the negative electrode sheet 22 in the electrode body 25. Note that the stacking direction of the electrode bodies 25 coincides with the direction orthogonal to the surface directions of the positive electrode sheet 21, the negative electrode sheet 22, and the separator 23. In the present embodiment, the upward direction is the extending direction of the positive electrode lead 21a and the negative electrode lead 22a.

そして、図1に示すように、電極体25における積層方向の両端部には、当該積層方向に沿って延びる上端面(上端部)25a及び下端面(下端部)25bがそれぞれ形成されている。そして、電極体25の上端面25aにおいて、左右方向の中央より左側には、正電極リード21aがセパレータ23を間に挟まない状態で前記積層方向に複数重なって層状の構造をなす集電部としての正極集電部28が形成されている。また、電極体25の上端面25aにおいて左右方向の中央より右側には、負電極リード22aがセパレータ23を間に挟まない状態で前記積層方向に複数重なって層状の構造をなす集電部としての負極集電部29が形成されている。即ち、正極集電部28及び負極集電部29は、電極体25の上端面25aにおいて、非塗布領域26bの延設方向に沿って相互に離間した状態で、当該延設方向(左右方向)の中央(略中央)に形成されている。このように、本実施形態の電極体25では、正電極シート21(正電極リード21a)及び負電極シート22(負電極リード22a)が層となる。   As shown in FIG. 1, an upper end surface (upper end portion) 25a and a lower end surface (lower end portion) 25b extending along the stacking direction are formed at both ends of the electrode body 25 in the stacking direction. On the upper end surface 25a of the electrode body 25, on the left side of the center in the left-right direction, a current collector that forms a layered structure in which a plurality of positive electrode leads 21a are stacked in the stacking direction with no separator 23 interposed therebetween. The positive electrode current collector 28 is formed. Further, on the right side of the center in the left-right direction on the upper end surface 25a of the electrode body 25, a plurality of negative electrode leads 22a are stacked in the laminating direction with a separator 23 interposed therebetween, and serve as a current collector that forms a layered structure A negative electrode current collector 29 is formed. That is, the positive electrode current collector 28 and the negative electrode current collector 29 are arranged in the extending direction (left-right direction) in a state of being separated from each other along the extending direction of the non-application region 26 b on the upper end surface 25 a of the electrode body 25. Is formed at the center (substantially the center). Thus, in the electrode body 25 of this embodiment, the positive electrode sheet 21 (positive electrode lead 21a) and the negative electrode sheet 22 (negative electrode lead 22a) are layers.

そして、図1に示すように、本実施形態の二次電池10において、正極集電部28(正電極リード21a)と、正極端子15とは、集電部材としての集電端子30によって電気的に接続されている。また、負極用の負極集電部29(負電極リード22a)と、負極端子16とは、集電部材としての集電端子31によって電気的に接続されている。以下、集電端子30,31による連結構造(接合構造)について詳しく説明する。   As shown in FIG. 1, in the secondary battery 10 of the present embodiment, the positive electrode current collector 28 (positive electrode lead 21a) and the positive electrode terminal 15 are electrically connected by a current collecting terminal 30 as a current collecting member. It is connected to the. The negative electrode current collector 29 (negative electrode lead 22a) for the negative electrode and the negative electrode terminal 16 are electrically connected by a current collector terminal 31 as a current collector. Hereinafter, the connection structure (joint structure) by the current collecting terminals 30 and 31 will be described in detail.

なお、本実施形態の集電端子31は、集電端子30と同一構成(形状)であるとともに、集電端子31と負極集電部29(負電極リード22a)との接続構造は、集電端子30と正極集電部28(正電極リード21a)との接続構造と点対称である。したがって、以下の説明では、主に集電端子30の構成、及び集電端子30と正極集電部28(正電極リード21a)との接続構造について詳しく説明し、集電端子31の構成、及び集電端子31と負極集電部29(負電極リード22a)との連結構造については、同一符号を付すなどしてその説明を省略又は簡略する。   In addition, the current collection terminal 31 of this embodiment is the same structure (shape) as the current collection terminal 30, and the connection structure of the current collection terminal 31 and the negative electrode current collection part 29 (negative electrode lead 22a) is current collection. This is point-symmetric with the connection structure between the terminal 30 and the positive electrode current collector 28 (positive electrode lead 21a). Therefore, in the following description, the configuration of the current collector terminal 30 and the connection structure between the current collector terminal 30 and the positive electrode current collector 28 (positive electrode lead 21a) will be described in detail, and the configuration of the current collector terminal 31 and About the connection structure of the current collection terminal 31 and the negative electrode current collection part 29 (negative electrode lead 22a), the description is abbreviate | omitted or simplified by attaching | subjecting the same code | symbol.

図3(a)及び図3(b)に示すように、集電端子30は、正電極シート21の金属箔26と同一の金属(本実施形態ではアルミニウム)から形成され、全体として櫛歯状(櫛状)をなす第1部材としての第1端子部材40と、第2部材としての第2端子部材50とから構成されている。第1端子部材40と、第2端子部材50とは、電極体25の上端面25a上に、かつ電極体25の積層方向に直交する方向(図3における左右方向)に並んで配置される。また、第1端子部材40及び第2端子部材50は、電極体25における積層方向に沿った長さ(幅)が電極体25の積層方向の長さ(厚さ)よりも小さく形成されている。なお、集電端子31を構成する第1端子部材40及び第2端子部材50は、負電極シート22の金属箔26と同一の金属(本実施形態では銅)から形成されている。   As shown in FIGS. 3A and 3B, the current collecting terminal 30 is made of the same metal (aluminum in the present embodiment) as the metal foil 26 of the positive electrode sheet 21, and has a comb-like shape as a whole. It is comprised from the 1st terminal member 40 as a 1st member which makes | forms (comb shape), and the 2nd terminal member 50 as a 2nd member. The first terminal member 40 and the second terminal member 50 are arranged side by side on the upper end surface 25a of the electrode body 25 and in a direction orthogonal to the stacking direction of the electrode body 25 (the left-right direction in FIG. 3). The first terminal member 40 and the second terminal member 50 are formed such that the length (width) along the stacking direction of the electrode body 25 is smaller than the length (thickness) of the electrode body 25 in the stacking direction. . In addition, the 1st terminal member 40 and the 2nd terminal member 50 which comprise the current collection terminal 31 are formed from the same metal (copper in this embodiment) as the metal foil 26 of the negative electrode sheet 22.

第1端子部材40は、電極体25の上端面25aに沿って配置された略四角形の平板状をなし、正極端子15と接合されて電気的に接続された本体部41を備えている。この本体部41には、電極体25における積層方向の両端に位置し、電極体25における層(正電極シート21及び負電極シート22)と平行する側面(後端面)である第1側面41aと、第1側面41aとは反対側の側面(前端面)である第2側面41bとが形成されている。   The first terminal member 40 has a substantially rectangular flat plate disposed along the upper end surface 25 a of the electrode body 25, and includes a main body 41 that is joined to and electrically connected to the positive electrode terminal 15. The main body 41 has first side surfaces 41a that are located at both ends of the electrode body 25 in the stacking direction and are parallel to the layers (the positive electrode sheet 21 and the negative electrode sheet 22) in the electrode body 25 (rear end surface). A second side surface 41b which is a side surface (front end surface) opposite to the first side surface 41a is formed.

また、本体部41の外周端面のうち、第2端子部材50側に配置される側面である第1基端部41cには、第2端子部材50に向かって、正電極リード21a(正電極シート21)の面方向に沿って延びる1つの第1突起部42、及び2つの第2突起部43が形成されている。第1突起部42及び第2突起部43は、何れも四角棒状に形成されているとともに、相互に平行をなしている。第1端子部材40において第1突起部42は、本体部41のうち、電極体25における積層方向の一方の端部となる後端部に形成されている。   Further, of the outer peripheral end surface of the main body 41, the first base end portion 41 c which is a side surface disposed on the second terminal member 50 side is directed to the positive electrode lead 21 a (positive electrode sheet) toward the second terminal member 50. One first protrusion 42 and two second protrusions 43 extending along the surface direction 21) are formed. The first protrusion 42 and the second protrusion 43 are both formed in a square bar shape and are parallel to each other. In the first terminal member 40, the first projecting portion 42 is formed at the rear end portion of the main body portion 41 that is one end portion in the stacking direction of the electrode body 25.

第1突起部42は、第1突起部42の後端面となる第1端面42aと、当該第1端面42aとは反対側の端面(前端面)である第2端面42bと、第1端面42a及び第2端面42bにおける第1突起部42の先端側の端部同士を繋ぐ第1連接部42cによって構成されている。第1突起部42の先端に形成された第1連接部42cは、第1突起部42の先端側から基端部側に向かって、本体部41の第2側面41b側へ向かって傾斜する第1傾斜部42dをなしている。第1傾斜部42dは、第1端面42aとでなす角度が鋭角である。   The first protrusion 42 includes a first end face 42a that is a rear end face of the first protrusion 42, a second end face 42b that is an end face (front end face) opposite to the first end face 42a, and a first end face 42a. And the 1st connection part 42c which connects the edge parts of the front end side of the 1st projection part 42 in the 2nd end surface 42b is comprised. The first connecting portion 42c formed at the distal end of the first projecting portion 42 inclines toward the second side surface 41b side of the main body portion 41 from the distal end side of the first projecting portion 42 toward the proximal end portion side. One inclined portion 42d is formed. The first inclined portion 42d has an acute angle with the first end surface 42a.

第1突起部42に形成された第1傾斜部42dは、電極体25での積層方向において、第1突起部42の全幅にわたって形成されている。また、第1突起部42に形成された第1傾斜部42dは、正電極リード21a(正極集電部28)の延出方向において、第1突起部42の全幅(全厚)にわたって形成されている。したがって、第1突起部42の先端(先端部)は、正電極リード21aの延出方向に沿って延びる線状をなしている。   The first inclined portion 42 d formed on the first protrusion 42 is formed across the entire width of the first protrusion 42 in the stacking direction of the electrode body 25. The first inclined portion 42d formed on the first protrusion 42 is formed over the entire width (total thickness) of the first protrusion 42 in the extending direction of the positive electrode lead 21a (positive electrode current collector 28). Yes. Therefore, the tip (tip) of the first protrusion 42 has a linear shape extending along the extending direction of the positive electrode lead 21a.

また、第1端子部材40において、本体部41の第1側面41aと、第1突起部42の後端面となる第1端面42aとは、面一に形成されている。即ち、本体部41の第1側面41aと、第1突起部42の第1端面42aとは、連続し、かつ平行している。   In the first terminal member 40, the first side surface 41 a of the main body 41 and the first end surface 42 a serving as the rear end surface of the first protrusion 42 are formed flush with each other. That is, the first side surface 41a of the main body 41 and the first end surface 42a of the first protrusion 42 are continuous and parallel.

また、各第2突起部43は、第1端面42a(第1突起部42)側に形成され、且つ第1端面42aと平行する後端面である第3端面43aと、当該第3端面とは反対側の端面(前端面)である第4端面43bと、第3端面43a及び第4端面43bにおける第2突起部43の先端側の端部同士を繋ぐ第2連接部43cによって構成されている。   Each second protrusion 43 is formed on the first end face 42a (first protrusion 42) side, and the third end face 43a, which is a rear end face parallel to the first end face 42a, and the third end face The fourth end surface 43b, which is the opposite end surface (front end surface), and the second connecting portion 43c that connects the end portions of the third end surface 43a and the fourth end surface 43b on the tip end side of the second protrusion 43 are connected to each other. .

第3端面43aは、本体部41の第1側面41aと同じ側に、第4端面43bは、第2側面41bと同じ側にそれぞれ形成されている。また、各第2突起部43の先端に形成された第2連接部43cは、第2突起部43の先端側から基端部側に向かって、本体部41の第1側面41a側へ向かって傾斜する第2傾斜部43dをなしている。第2傾斜部43dは、第4端面43bとでなす角度が鋭角である。   The third end surface 43a is formed on the same side as the first side surface 41a of the main body 41, and the fourth end surface 43b is formed on the same side as the second side surface 41b. Further, the second connecting portion 43 c formed at the distal end of each second projecting portion 43 is directed from the distal end side of the second projecting portion 43 toward the proximal end portion side toward the first side surface 41 a side of the main body portion 41. An inclined second inclined portion 43d is formed. The second inclined portion 43d has an acute angle with the fourth end surface 43b.

そして、各第2突起部43に形成された第2傾斜部43dは、電極体25での積層方向において、第2突起部43の全幅にわたって形成されている。即ち、第2傾斜部43dにおける電極体25の積層方向の幅は、第2突起部43おける前記積層方向の長さの半分を超えて形成されている。また、第2突起部43に形成された第2傾斜部43dは、正電極リード21aの延出方向において、第2突起部43の全幅(全厚)にわたって形成されている。したがって、第2突起部43の先端(先端部)は、正電極リード21aの延出方向に沿って延びる線状をなしている。   The second inclined portion 43 d formed on each second protrusion 43 is formed across the entire width of the second protrusion 43 in the stacking direction of the electrode body 25. That is, the width in the stacking direction of the electrode body 25 in the second inclined portion 43d is formed to exceed half of the length in the stacking direction of the second protrusion 43. Further, the second inclined portion 43d formed on the second protrusion 43 is formed over the entire width (total thickness) of the second protrusion 43 in the extending direction of the positive electrode lead 21a. Therefore, the tip (tip portion) of the second protrusion 43 has a linear shape extending along the extending direction of the positive electrode lead 21a.

また、第2端子部材50は、電極体25の上端面25aに沿って配置された略四角形の平板状をなす本体部51を備えている。この本体部51には、電極体25における積層方向の両端に位置し、電極体25における層(正電極シート21及び負電極シート22)と平行する側面(後端面)である第3側面51aと、第3側面51aとは反対側の側面(前端面)である第4側面51bとが形成されている。第3側面51aは、本体部41における第1側面41aと同じ側に、第4側面51bは、本体部41における第2側面41bと同じ側にそれぞれ形成されている。   The second terminal member 50 includes a main body 51 having a substantially rectangular flat plate shape arranged along the upper end surface 25 a of the electrode body 25. The main body 51 has third side surfaces 51a that are side surfaces (rear end surfaces) located at both ends of the electrode body 25 in the stacking direction and parallel to the layers (the positive electrode sheet 21 and the negative electrode sheet 22) in the electrode body 25. The fourth side surface 51b, which is the side surface (front end surface) opposite to the third side surface 51a, is formed. The third side surface 51 a is formed on the same side as the first side surface 41 a in the main body portion 41, and the fourth side surface 51 b is formed on the same side as the second side surface 41 b in the main body portion 41.

また、本体部51の外周端面のうち、第1端子部材40側に配置される側面である第2基端部51cには、第1端子部材40に向かって正電極リード21a(正電極シート21)の面方向に沿って延びる1つの第3突起部52、及び2つの第4突起部53が形成されている。第3突起部52及び第4突起部53は、何れも四角棒状に形成されているとともに、相互に平行をなしている。第2端子部材50において第3突起部52は、本体部51のうち、電極体25における積層方向の他方の端部となる前端部に形成されている。   In addition, a positive electrode lead 21 a (positive electrode sheet 21) toward the first terminal member 40 is formed on the second base end portion 51 c which is a side surface arranged on the first terminal member 40 side among the outer peripheral end surfaces of the main body 51. ) One third projecting portion 52 and two fourth projecting portions 53 extending along the surface direction. The third protrusions 52 and the fourth protrusions 53 are both formed in a square bar shape and are parallel to each other. In the second terminal member 50, the third protrusion 52 is formed at the front end of the main body 51 that is the other end of the electrode body 25 in the stacking direction.

第3突起部52は、第3突起部52の前端面となる第5端面52a、当該第5端面52aとは反対側の端面(後端面)である第6端面52bと、第5端面52a及び第6端面52bにおける第3突起部52の先端側の端部同士を繋ぐ第3連接部52cによって構成されている。第3突起部52の先端に形成された第3連接部52cは、第3突起部52の先端側から基端部側に向かって、本体部51の第3側面51a側へ向かって傾斜する第3傾斜部52dをなしている。第3傾斜部52dは、第5端面52aとでなす角度が鋭角である。   The third projecting portion 52 includes a fifth end surface 52a serving as a front end surface of the third projecting portion 52, a sixth end surface 52b serving as an end surface (rear end surface) opposite to the fifth end surface 52a, a fifth end surface 52a, and It is comprised by the 3rd connection part 52c which connects the edge parts by the side of the tip of the 3rd projection part 52 in the 6th end surface 52b. The third connecting portion 52c formed at the distal end of the third projection 52 is inclined toward the third side surface 51a of the main body 51 from the distal end side to the proximal end side of the third projection portion 52. Three inclined portions 52d are formed. The third inclined portion 52d has an acute angle with the fifth end surface 52a.

第3突起部52に形成された第3傾斜部52dは、電極体25での積層方向において、第3突起部52の全幅にわたって形成されている。また、第3突起部52に形成された第3傾斜部52dは、正電極リード21a(正極集電部28)の延出方向において、第3突起部52の全幅(全厚)にわたって形成されている。したがって、第3突起部52の先端(先端部)は、正電極リード21aの延出方向に沿って延びる線状をなしている。   The third inclined portion 52 d formed on the third protrusion 52 is formed over the entire width of the third protrusion 52 in the stacking direction of the electrode body 25. Further, the third inclined portion 52d formed in the third protrusion 52 is formed over the entire width (total thickness) of the third protrusion 52 in the extending direction of the positive electrode lead 21a (positive electrode current collector 28). Yes. Therefore, the tip (tip) of the third protrusion 52 has a linear shape extending along the extending direction of the positive electrode lead 21a.

また、第2端子部材50において、本体部51の第4側面51bと、第3突起部52の前端面となる第5端面52aとは、面一に形成されている。即ち、本体部51の第4側面51bと、第3突起部52の第5端面52aとは、連続し、かつ平行している。   In the second terminal member 50, the fourth side surface 51 b of the main body 51 and the fifth end surface 52 a serving as the front end surface of the third protrusion 52 are formed flush with each other. That is, the fourth side surface 51b of the main body 51 and the fifth end surface 52a of the third protrusion 52 are continuous and parallel.

各第4突起部53は、第5端面52a(第3突起部52)側に形成され、且つ第5端面52aと平行する前端面である第7端面53aと、当該第7端面53aとは反対側の端面(後端面)である第8端面53bと、第7端面53a及び第8端面53bにおける第4突起部53の先端側の端部同士を繋ぐ第4連接部53cによって構成されている。   Each fourth projection 53 is formed on the fifth end surface 52a (third projection 52) side, and is a seventh end surface 53a that is a front end surface parallel to the fifth end surface 52a, and is opposite to the seventh end surface 53a. 8th end surface 53b which is a side end surface (rear end surface), and the 4th connection part 53c which connects the edge part of the front end side of the 4th projection part 53 in the 7th end surface 53a and the 8th end surface 53b.

第7端面53aは、本体部51の第4側面51bと同じ側に、第8端面53bは、第3側面51aと同じ側にそれぞれ形成されている。また、各第4突起部53の先端に形成された第4連接部53cは、第4突起部53の先端側から基端部側に向かって、本体部51の第4側面51b側へ向かって傾斜する第4傾斜部53dをなしている。第4傾斜部53dは、第8端面53bとでなす角度が鋭角である。したがって、本実施形態において、第2傾斜部43dと第4傾斜部53dとは同一方向側に傾斜している。より詳しく言えば、本実施形態の第2傾斜部43dと第4傾斜部53dとは平行に形成されている。   The seventh end surface 53a is formed on the same side as the fourth side surface 51b of the main body 51, and the eighth end surface 53b is formed on the same side as the third side surface 51a. Further, the fourth connecting portion 53 c formed at the distal end of each fourth projecting portion 53 is directed from the distal end side of the fourth projecting portion 53 toward the proximal end portion side toward the fourth side surface 51 b side of the main body portion 51. An inclined fourth inclined portion 53d is formed. The fourth inclined portion 53d has an acute angle with the eighth end surface 53b. Therefore, in the present embodiment, the second inclined portion 43d and the fourth inclined portion 53d are inclined in the same direction. More specifically, the second inclined portion 43d and the fourth inclined portion 53d of the present embodiment are formed in parallel.

そして、各第4突起部53に形成された第4傾斜部53dは、電極体25での積層方向において、第4突起部53の全幅にわたってそれぞれ形成されている。即ち、第4傾斜部53dの、電極体25における積層方向の幅は、第4突起部53における前記積層方向の長さの半分を超えて形成されている。また、第4突起部53に形成された第4傾斜部53dは、正電極リード21aの延出方向において、第4突起部53の全幅(全厚)にわたって形成されている。したがって、第4突起部53の先端(先端部)は、正電極リード21aの延出方向に沿って延びる線状をなしている。   And the 4th inclination part 53d formed in each 4th projection part 53 is formed over the full width of the 4th projection part 53 in the lamination direction in the electrode body 25, respectively. In other words, the width of the fourth inclined portion 53d in the stacking direction in the electrode body 25 is formed to exceed half the length of the fourth protrusion 53 in the stacking direction. Further, the fourth inclined portion 53d formed on the fourth protrusion 53 is formed over the entire width (total thickness) of the fourth protrusion 53 in the extending direction of the positive electrode lead 21a. Therefore, the tip (tip) of the fourth protrusion 53 has a linear shape extending along the extending direction of the positive electrode lead 21a.

また、本実施形態において、第1端子部材40に形成された第1基端部41c、第1突起部42、及び第2突起部43は、第2端子部材50に形成された第2基端部51c、第3突起部52、及び第4突起部53とそれぞれ同一形状をなしている。   In the present embodiment, the first base end 41 c, the first protrusion 42, and the second protrusion 43 formed on the first terminal member 40 are the second base end formed on the second terminal member 50. The portion 51c, the third protrusion 52, and the fourth protrusion 53 have the same shape.

また、隣り合う第1突起部42と第2突起部43、第2突起部43と第2突起部43、第3突起部52と第4突起部53、及び第4突起部53と第4突起部53における前後方向の離間距離は、第2突起部43及び第4突起部53における前後方向の幅よりも僅かに大きく形成されている。   Also, adjacent first and second protrusions 42 and 43, second and fourth protrusions 43 and 43, third and fifth protrusions 52 and 53, and fourth and fourth protrusions 53 and 43, respectively. The separation distance in the front-rear direction of the portion 53 is slightly larger than the width of the second protrusion 43 and the fourth protrusion 53 in the front-rear direction.

また、各端子部材40,50を組み合わせた状態において、第2端子部材50に形成された第3突起部52の先端(第3傾斜部52d)及び第4突起部53の先端(第4傾斜部53d)と、第1端子部材40において第1突起部42及び第2突起部43が形成された第1基端部41cと、は離間している。また、第1端子部材40に形成された第1突起部42の先端(第1傾斜部42d)及び第2突起部43の先端(第2傾斜部43d)と、第2端子部材50において第3突起部52及び第4突起部53が形成された第2基端部51cと、は離間している。   Further, in a state where the terminal members 40 and 50 are combined, the tip of the third protrusion 52 (third inclined portion 52d) and the tip of the fourth protrusion 53 (fourth inclined portion) formed on the second terminal member 50. 53d) is separated from the first base end portion 41c in which the first protrusion 42 and the second protrusion 43 are formed in the first terminal member 40. Further, the tip of the first protrusion 42 (first inclined portion 42 d) and the tip of the second protrusion 43 (second inclined portion 43 d) formed on the first terminal member 40 and the second terminal member 50 are third. The second base end portion 51c on which the protrusion 52 and the fourth protrusion 53 are formed is separated.

そして、各端子部材40,50は、電極体25の積層方向において、第1端面42a側(第1側面41a、及び第3側面51a)から、第1突起部42、第4突起部53、及び第2突起部43が順に配置されている。さらに、前記積層方向において、第5端面52a側(第2側面41b側、及び第4側面51b側)から、第3突起部52、第2突起部43、及び第4突起部53が順に配置されている。   And each terminal member 40,50 is the 1st projection part 42, the 4th projection part 53, and the 1st end surface 42a side (1st side surface 41a and 3rd side surface 51a) in the lamination direction of the electrode body 25, and The 2nd protrusion part 43 is arrange | positioned in order. Further, in the stacking direction, the third protrusion 52, the second protrusion 43, and the fourth protrusion 53 are sequentially arranged from the fifth end face 52a side (the second side face 41b side and the fourth side face 51b side). ing.

このため、第1端子部材40と第2端子部材50とを組み合わせた状態において、第1突起部42と第4突起部53との間、第2突起部43と第4突起部53との間、及び第2突起部43と第3突起部52との間には、隙間(クリアランス)が形成される。そして、これらの各隙間には、正極集電部28を構成する各正電極リード21a(層)が、その積層方向において複数枚(複数層)ごとに複数の束(本実施形態では5つ)に分割された状態で、それぞれ各隙間を正電極リード21aの延出方向(上下方向)に挿通するように配置されている。なお、本実施形態において、相手方の端子部材の隣り合う突起部との間に形成される各隙間は、当該各隙間にそれぞれ挟み込まれる各正電極リード21a(金属箔26)の厚さの合計よりも僅かに広く形成されている。   For this reason, in the state which combined the 1st terminal member 40 and the 2nd terminal member 50, between the 1st projection part 42 and the 4th projection part 53, between the 2nd projection part 43 and the 4th projection part 53 A gap (clearance) is formed between the second protrusion 43 and the third protrusion 52. In each of these gaps, each positive electrode lead 21a (layer) constituting the positive electrode current collector 28 has a plurality of bundles (five in this embodiment) for each of a plurality (a plurality of layers) in the stacking direction. In such a state, each gap is arranged so as to be inserted in the extending direction (vertical direction) of the positive electrode lead 21a. In the present embodiment, each gap formed between adjacent projecting portions of the counterpart terminal member is based on the total thickness of each positive electrode lead 21a (metal foil 26) sandwiched in each gap. Is also slightly wider.

また、第1端子部材40に形成された第1突起部42(第2端面42b)は、正極集電部28における積層方向の端面のうち、第1端子部材40において第1突起部42が形成された端部側(後端部側)の端面36aに接している。第2端子部材50に形成された第4突起部53(第6端面52b)は、正極集電部28における積層方向の端面のうち、第2端子部材50において第4突起部53が形成された端部側(前端部側)の端面36bに接している。以上のように、本実施形態の第2端子部材50は、正電極リード21aを介して第1端子部材40と接触している(連続している)。   The first protrusion 42 (second end face 42 b) formed on the first terminal member 40 is formed by the first protrusion 42 on the first terminal member 40 among the end faces in the stacking direction of the positive electrode current collector 28. It is in contact with the end face 36a on the end part side (rear end part side). The fourth protrusion 53 (sixth end surface 52 b) formed on the second terminal member 50 is the end of the positive electrode current collector 28 in the stacking direction, and the fourth protrusion 53 is formed on the second terminal member 50. It is in contact with the end surface 36b on the end side (front end side). As described above, the second terminal member 50 of the present embodiment is in contact (continuous) with the first terminal member 40 via the positive electrode lead 21a.

本実施形態では、第1突起部42及び第2突起部43の基端部である第1基端部41cと、第1突起部42と、第2突起部43とが正電極リード21aと接触する接触領域37をなしている。同様に、本実施形態では、第2端子部材50に形成された第3突起部52及び第4突起部53の基端部である第2基端部51cと、第3突起部52、及び第4突起部53が正電極リード21aと接触する接触領域37をなしている。本実施形態では、接触領域37の形状が第1端子部材40と第2端子部材50とで同一形状をなしている。   In the present embodiment, the first base end 41c, which is the base end of the first protrusion 42 and the second protrusion 43, the first protrusion 42, and the second protrusion 43 are in contact with the positive electrode lead 21a. The contact area 37 is formed. Similarly, in the present embodiment, the second base end portion 51c, which is the base end portion of the third protrusion portion 52 and the fourth protrusion portion 53 formed on the second terminal member 50, the third protrusion portion 52, and the The four protrusions 53 form a contact region 37 in contact with the positive electrode lead 21a. In the present embodiment, the shape of the contact region 37 is the same for the first terminal member 40 and the second terminal member 50.

そして、本実施形態において、第1端子部材40、第2端子部材50、及び正極集電部28(正電極リード21a)は、抵抗溶接によって相互に接合(溶接)されている。より詳しく説明すると、正電極リード21aは、電極体25における積層方向から見た場合において、第1突起部42、第2突起部43、第3突起部52、及び第4突起部53と重なり合う(重合する)領域において溶接されている(図中に墨色で示す)。   In the present embodiment, the first terminal member 40, the second terminal member 50, and the positive electrode current collector 28 (positive electrode lead 21a) are joined (welded) to each other by resistance welding. More specifically, the positive electrode lead 21a overlaps the first protrusion 42, the second protrusion 43, the third protrusion 52, and the fourth protrusion 53 when viewed from the stacking direction of the electrode body 25 ( It is welded in the area where it is polymerized (shown in black in the figure).

次に、二次電池10の製造方法について、その作用とともに図4及び図5にしたがって説明する。なお、以下の説明では、集電端子30の製造方法、及び集電端子30と正極集電部28(正電極リード21a)との連結方法について詳しく説明し、銅からなる点でのみ集電端子30と相違する集電端子31の製造方法、及び集電端子31と負極集電部29との連結方法についてはその説明を簡略化又は省略する。   Next, a method for manufacturing the secondary battery 10 will be described with reference to FIGS. In the following description, a method for manufacturing the current collector terminal 30 and a method for connecting the current collector terminal 30 and the positive electrode current collector 28 (positive electrode lead 21a) will be described in detail, and the current collector terminal only in terms of copper. Description of the manufacturing method of the current collecting terminal 31 different from 30 and the method of connecting the current collecting terminal 31 and the negative electrode current collecting portion 29 are simplified or omitted.

図4に示すように、集電端子30を構成するための第1端子部材40及び第2端子部材50は、1枚の長方形の金属板(本実施形態ではアルミニウム板)をレーザ加工機によって切断(レーザカット)して形成される。このとき本実施形態では、図4(a)に示すように、1枚の金属板を、連続する1本の切断線L(破線で示す)に沿って切断することにより、図4(b)に示すように、接触領域37における形状を同一形状とした各端子部材40,50を形成する。   As shown in FIG. 4, the first terminal member 40 and the second terminal member 50 for constituting the current collecting terminal 30 are formed by cutting one rectangular metal plate (in this embodiment, an aluminum plate) with a laser processing machine. (Laser cut). At this time, in the present embodiment, as shown in FIG. 4A, a single metal plate is cut along a continuous cutting line L (shown by a broken line) to obtain FIG. As shown in FIG. 3, the terminal members 40 and 50 having the same shape in the contact region 37 are formed.

したがって、本実施形態では、各端子部材40,50を個々に形成(製造)する場合と比較して、各端子部材40,50を簡便に形成できるとともに、材料にロスが生じることを抑制できる。ここで、金属板の切断に用いるレーザ光の出力は、挟み込む正電極リード21a(金属箔26)の厚さの合計よりも僅かに広い隙間が、第1突起部42と第4突起部53、第2突起部43と第3突起部52、及び第2突起部43と第4突起部53の間に形成される出力に設定される。   Therefore, in this embodiment, compared with the case where each terminal member 40 and 50 is formed (manufactured) individually, each terminal member 40 and 50 can be easily formed, and loss of material can be suppressed. Here, the output of the laser beam used for cutting the metal plate has a gap slightly wider than the total thickness of the sandwiched positive electrode lead 21a (metal foil 26), and the first protrusion 42 and the fourth protrusion 53, The output is formed between the second protrusion 43 and the third protrusion 52 and between the second protrusion 43 and the fourth protrusion 53.

そして、第1端子部材40の本体部41に対して正極端子15を溶接などにより接合する。また同様に、負極用の集電端子31についても、長方形の金属板(本実施形態では銅板)をレーザ加工機によって切断し、各端子部材40,50を形成するとともに、第1端子部材40の本体部41に対して負極端子16を溶接などにより接合する。   Then, the positive terminal 15 is joined to the main body 41 of the first terminal member 40 by welding or the like. Similarly, for the current collecting terminal 31 for the negative electrode, a rectangular metal plate (a copper plate in the present embodiment) is cut by a laser processing machine to form the terminal members 40 and 50, and the first terminal member 40. The negative terminal 16 is joined to the main body 41 by welding or the like.

また、間にセパレータ23を挟んだ状態で、正電極シート21及び負電極シート22を前後方向(厚さ方向)に積層し、電極体25を形成する。図5(a)に示すように、正電極シート21及び負電極シート22を積層した状態において、正極集電部28をなす正電極リード21aは、電極体25における積層方向に分割されていない状態とされている。   In addition, the positive electrode sheet 21 and the negative electrode sheet 22 are laminated in the front-rear direction (thickness direction) with the separator 23 sandwiched therebetween to form the electrode body 25. As shown in FIG. 5A, in a state in which the positive electrode sheet 21 and the negative electrode sheet 22 are laminated, the positive electrode lead 21a forming the positive electrode current collector 28 is not divided in the lamination direction in the electrode body 25. It is said that.

次に、正極集電部28をなす正電極リード21a(正電極シート21)の面方向のうち、正電極リード21aの延出方向と直交する方向(ここでは左右方向)から、第1基端部41cと第2基端部51cとを向かい合わせた状態で、正極集電部28を挟むように各端子部材40,50を配置する。このとき、各端子部材40,50に形成した第1突起部42、及び第3突起部52は、それぞれ電極体25での積層方向における正極集電部28の外側に配置させた状態とする。そして、各端子部材40,50を相互に近接する方向へ移動させ、正電極リード21aの間に第2突起部43、及び第4突起部53を挿入させる(二点鎖線で示す)。   Next, in the surface direction of the positive electrode lead 21a (positive electrode sheet 21) forming the positive electrode current collector 28, the first base end from the direction (here, the left-right direction) orthogonal to the extending direction of the positive electrode lead 21a. With the portion 41c and the second base end portion 51c facing each other, the terminal members 40 and 50 are disposed so as to sandwich the positive electrode current collector 28. At this time, the first protrusions 42 and the third protrusions 52 formed on the terminal members 40 and 50 are arranged outside the positive electrode current collector 28 in the stacking direction of the electrode body 25, respectively. Then, the respective terminal members 40 and 50 are moved in directions close to each other, and the second projecting portion 43 and the fourth projecting portion 53 are inserted between the positive electrode leads 21a (indicated by a two-dot chain line).

このとき、図5(b)に示すように、各端子部材40,50は、第2突起部43に形成した第2傾斜部43d、及び第4突起部53に形成した第4傾斜部53d同士を相互に沿わせつつ、相互に近接する方向へ移動させる。そして、第1端子部材40において、第1突起部42に隣り合わせて形成した第2突起部43を、他方の第2端子部材50に形成した第3突起部52と第4突起部53との間に挿入させる。換言すれば、第2端子部材50において、第3突起部52に隣り合わせて形成した第4突起部53を、他方の第1端子部材40に形成した第1突起部42と第2突起部43との間に挿入させる。これにより、各端子部材40,50は、第1突起部42及び第3突起部52が前後方向において相互に近接する方向へ相対的に移動(斜行)される(矢印Y4に示す)。   At this time, as shown in FIG. 5 (b), each of the terminal members 40 and 50 includes the second inclined portion 43 d formed on the second protruding portion 43 and the fourth inclined portion 53 d formed on the fourth protruding portion 53. Are moved in directions close to each other while being moved along each other. In the first terminal member 40, the second protrusion 43 formed adjacent to the first protrusion 42 is formed between the third protrusion 52 and the fourth protrusion 53 formed on the other second terminal member 50. To insert. In other words, in the second terminal member 50, the fourth protrusion 53 formed adjacent to the third protrusion 52 is replaced with the first protrusion 42 and the second protrusion 43 formed on the other first terminal member 40. Insert between. Thereby, each terminal member 40 and 50 is relatively moved (skewed) in the direction in which the first protrusion 42 and the third protrusion 52 are close to each other in the front-rear direction (indicated by an arrow Y4).

このため、第1突起部42と第4突起部53との間、第3突起部52と第2突起部43との間、及び第2突起部43と第4突起部53の間には、正電極リード21aが分割されつつ挟み込まれるように配置される。したがって、正極集電部28を構成する正電極リード21aを複数の束に分割する作業と、正極集電部28に対して集電端子31(各端子部材40,50)を組み付ける(配置する)作業と、を同時に行うことができるため、工程を簡略化することができる。   Therefore, between the first protrusion 42 and the fourth protrusion 53, between the third protrusion 52 and the second protrusion 43, and between the second protrusion 43 and the fourth protrusion 53, The positive electrode lead 21a is arranged so as to be sandwiched while being divided. Therefore, the work of dividing the positive electrode lead 21a constituting the positive electrode current collector 28 into a plurality of bundles, and the current collector terminals 31 (terminal members 40, 50) are assembled (arranged) to the positive electrode current collector 28. Since the operation can be performed at the same time, the process can be simplified.

特に本実施形態の第2傾斜部43dは、当該第2傾斜部43dが形成された第2突起部43において、電極体25での積層方向における長さの半分を超えて形成されている。また、第4傾斜部53dは、当該第4傾斜部53dが形成された第4突起部53において、電極体25での積層方向における長さの半分を超えて形成されている。このため、本実施形態のように、正極集電部28(電極体25)における積層方向の長さ(厚さ)が、第1端子部材40及び第2端子部材50における前記積層方向の長さ(幅)より大きい場合であっても、電極体25における積層方向において第2傾斜部43d及び第4傾斜部53dの形成範囲分だけ、各端子部材40,50の間により多層(多数)の正電極リード21aを挟み込むことができる。   In particular, the second inclined portion 43d of the present embodiment is formed in the second protrusion 43 where the second inclined portion 43d is formed so as to exceed half the length in the stacking direction of the electrode body 25. Further, the fourth inclined portion 53d is formed in the fourth protruding portion 53 where the fourth inclined portion 53d is formed so as to exceed half the length in the stacking direction of the electrode body 25. Therefore, as in the present embodiment, the length (thickness) in the stacking direction of the positive electrode current collector 28 (electrode body 25) is the length in the stacking direction of the first terminal member 40 and the second terminal member 50. Even in the case where the width is larger than the width, the number of positive (multiple) layers between the terminal members 40 and 50 is increased by the formation range of the second inclined portion 43d and the fourth inclined portion 53d in the stacking direction of the electrode body 25. The electrode lead 21a can be sandwiched.

ここで、二次電池10におけるエネルギ密度(体積エネルギ密度及び重量エネルギ密度)を向上させる観点からは、各集電端子30,31を出来る限り小型化することが好ましいといえる。例えば、各端子部材40,50における前後方向(電極体25における積層方向)の幅を小さく形成することで各集電端子30,31を小型化し、二次電池10のエネルギ密度を向上させることも可能と考えられる。しかしながら、単に各端子部材40,50における前後方向の幅を小さく形成した場合には、当該各端子部材40,50における前後方向の幅を超える厚みの正極集電部28を挟み込むことができないという問題がある。   Here, from the viewpoint of improving the energy density (volume energy density and weight energy density) in the secondary battery 10, it can be said that it is preferable to make each of the current collecting terminals 30 and 31 as small as possible. For example, the current collecting terminals 30 and 31 can be downsized and the energy density of the secondary battery 10 can be improved by reducing the width of each terminal member 40 and 50 in the front-rear direction (stacking direction in the electrode body 25). It seems possible. However, when the width in the front-rear direction of each terminal member 40, 50 is simply formed small, the positive electrode current collector 28 having a thickness exceeding the width in the front-rear direction of each terminal member 40, 50 cannot be sandwiched. There is.

これに対して、本実施形態では、第2突起部43及び第4突起部53における前後方向の幅の半分をそれぞれ超えて第2傾斜部43d及び第4傾斜部53dが形成されている。このため、第2傾斜部43dと第4傾斜部53dとを相互に沿わせつつ、各端子部材40,50を相互に近接する方向へ移動させることにより、各傾斜部43d,53dにおける前後方向の幅分だけ、第1突起部42と第3突起部52とが相互の接近する方向(前後方向)へ各端子部材40,50を移動させることができる。この際、第1突起部42と第3突起部52とによって、正極集電部28を構成する正電極リード21aを前後方向に寄せ集めることができる。このように、本実施形態では、各突起部43,53における前後方向の幅の半分を超えて、より詳しくは各傾斜部43d,53dにおける前後方向の幅分だけ、各端子部材40,50における前後方向の幅よりも厚みのある正極集電部28を挟み込むことができる。   On the other hand, in this embodiment, the 2nd inclination part 43d and the 4th inclination part 53d are formed exceeding the half of the width | variety of the front-back direction in the 2nd protrusion part 43 and the 4th protrusion part 53, respectively. For this reason, by moving the terminal members 40 and 50 in directions close to each other while keeping the second inclined portion 43d and the fourth inclined portion 53d along each other, the front and rear direction of each inclined portion 43d and 53d is increased. Each terminal member 40, 50 can be moved in the direction (front-rear direction) in which the first protrusion 42 and the third protrusion 52 approach each other by the width. At this time, the first electrode portion 42 and the third protrusion portion 52 can gather the positive electrode leads 21a constituting the positive electrode current collector 28 in the front-rear direction. As described above, in the present embodiment, more than half of the width in the front-rear direction of each protrusion 43, 53, more specifically, the width of each of the inclined members 43d, 53d is equal to the width in the front-rear direction. The positive electrode current collector 28 having a thickness larger than the width in the front-rear direction can be sandwiched.

また、各傾斜部42d,43d,52d,53dは、それぞれ各突起部42,43,52,53の先端に形成されている。このため、各突起部42,43,52,53の先端に傾斜部を設けない構成と比較して、第2突起部43及び第4突起部53を正電極リード21aの間に挿入する際に、各突起部43,53の先端(先端部)が正電極リード21aの縁部に当接することによって正電極リード21aが損傷することを抑制できる。   The inclined portions 42d, 43d, 52d, and 53d are formed at the tips of the protruding portions 42, 43, 52, and 53, respectively. For this reason, when inserting the 2nd protrusion part 43 and the 4th protrusion part 53 between the positive electrode leads 21a compared with the structure which does not provide an inclination part at the front-end | tip of each protrusion part 42,43,52,53. Further, the positive electrode lead 21a can be prevented from being damaged by the tips (tips) of the projections 43 and 53 coming into contact with the edge of the positive electrode lead 21a.

また、本実施形態では、第1突起部42の第1傾斜部42d、及び第2突起部43の第2傾斜部43dを、第2基端部51cから離間させる。同様に、本実施形態では、第3突起部52の第3傾斜部52d、及び第4突起部53の第4傾斜部53dを、第1端子部材40の第1基端部41cから離間させるようにする。これにより、各突起部42,43,52,53の弾性(たわみ)によって正電極リード21aを挟み込み易くさせることができる。したがって、各突起部42,43,52,53の間に正電極リード21aを確実に挟み込むように配置させることができる。   In the present embodiment, the first inclined portion 42d of the first protruding portion 42 and the second inclined portion 43d of the second protruding portion 43 are separated from the second base end portion 51c. Similarly, in the present embodiment, the third inclined portion 52d of the third protruding portion 52 and the fourth inclined portion 53d of the fourth protruding portion 53 are separated from the first base end portion 41c of the first terminal member 40. To. Accordingly, the positive electrode lead 21a can be easily sandwiched by the elasticity (deflection) of the protrusions 42, 43, 52, 53. Therefore, the positive electrode lead 21a can be disposed so as to be securely sandwiched between the protrusions 42, 43, 52, 53.

次に、各突起部42,43,52,53の間に正電極リード21aを挟み込んだ状態において、各突起部42,43,52,53(各端子部材40,50)を、棒状に形成された一対の電極38によって、電極体25における積層方向(前後方向)の両側から所定荷重で挟持し、各突起部42,43,52,53と正電極リード21aとを密着させる。そして、各突起部42,43,52,53と正電極リード21aとを密着させた状態のまま、各電極38の間で通電させて各突起部42,43,52,53及び正電極リード21aを溶接し、接合させる。以上により、正極集電部28と集電端子30とが電気的に接続される。   Next, in a state where the positive electrode lead 21a is sandwiched between the protrusions 42, 43, 52, and 53, the protrusions 42, 43, 52, and 53 (terminal members 40 and 50) are formed in a rod shape. The pair of electrodes 38 is sandwiched with a predetermined load from both sides of the electrode body 25 in the stacking direction (front-rear direction), and the protrusions 42, 43, 52, 53 and the positive electrode lead 21a are brought into close contact with each other. Then, with the projections 42, 43, 52, 53 and the positive electrode lead 21a being in close contact with each other, current is passed between the electrodes 38 to provide the projections 42, 43, 52, 53 and the positive electrode lead 21a. Are welded and joined. As described above, the positive electrode current collector 28 and the current collector terminal 30 are electrically connected.

本実施形態では、正電極リード21a(金属箔26)、第1端子部材40、及び第2端子部材50が何れも同一の金属(アルミニウム)により形成されている。このため、各端子部材40,50によって正電極リード21aを挟み込んだ状態で抵抗溶接を行うことにより、各端子部材40,50と正電極リード21aとを容易に接合することができる。負極集電部29と集電端子31(各端子部材40,50)との接合についても同様である。   In the present embodiment, the positive electrode lead 21a (metal foil 26), the first terminal member 40, and the second terminal member 50 are all formed of the same metal (aluminum). For this reason, each terminal member 40 and 50 and the positive electrode lead 21a can be easily joined by performing resistance welding in a state where the positive electrode lead 21a is sandwiched between the terminal members 40 and 50. The same applies to the joining of the negative electrode current collector 29 and the current collector terminal 31 (the terminal members 40 and 50).

そして、電極体25を絶縁袋11aに収容した状態で本体部材12に収納するとともに、この本体部材12には、正極端子15及び負極端子16を上面から突出させつつ蓋部材13が組み付けられる。そして、最終的に電解質(電解液)が充填されて二次電池10が完成される。   The electrode body 25 is housed in the main body member 12 in a state of being housed in the insulating bag 11a, and the lid member 13 is assembled to the main body member 12 with the positive electrode terminal 15 and the negative electrode terminal 16 protruding from the upper surface. Finally, the secondary battery 10 is completed by being filled with an electrolyte (electrolytic solution).

したがって、本実施形態によれば、以下のような効果を得ることができる。
(1)第2傾斜部43d及び第4傾斜部53dは、各突起部43,53において、それぞれ電極体25での積層方向における長さ(幅)の半分を超えて形成されている。このため、本実施形態のように、電極体25における積層方向の長さ(厚さ)が、各端子部材40,50における前記積層方向の長さ(幅)より大きい場合であっても、電極体25の積層方向において各傾斜部43d,53dの形成範囲分だけ、各端子部材40,50の間により多層の正電極リード21aを挟み込むことができる。したがって、正極集電部28と集電端子30とを容易に連結できる。負極集電部29と集電端子31との連結(接合)についても同様である。
Therefore, according to the present embodiment, the following effects can be obtained.
(1) The second inclined portion 43d and the fourth inclined portion 53d are formed in each protrusion 43, 53 so as to exceed half of the length (width) in the stacking direction of the electrode body 25. For this reason, even when the length (thickness) in the stacking direction of the electrode body 25 is larger than the length (width) of the terminal members 40 and 50 in the stacking direction as in the present embodiment, the electrode The multilayer positive electrode lead 21a can be sandwiched between the terminal members 40 and 50 by the formation range of the inclined portions 43d and 53d in the stacking direction of the body 25. Therefore, the positive electrode current collector 28 and the current collector terminal 30 can be easily connected. The same applies to the connection (bonding) between the negative electrode current collector 29 and the current collector terminal 31.

(2)各傾斜部42d,43d,52d,53dは、それぞれ対応する突起部の先端に形成されている。このため、各突起部42,43,52,53の先端部に傾斜部を設けない構成と比較して、第2突起部43及び第4突起部53を正電極リード21aの間に挿入する際に、第2突起部43及び第4突起部53の先端部が正電極リード21aの縁部に当接することによって正電極リード21aが損傷することを抑制できる。負極集電部29と集電端子31との連結についても同様である。   (2) Each inclined part 42d, 43d, 52d, 53d is formed at the tip of the corresponding protrusion. For this reason, when inserting the 2nd protrusion part 43 and the 4th protrusion part 53 between the positive electrode leads 21a compared with the structure which does not provide an inclination part in the front-end | tip part of each protrusion part 42,43,52,53. In addition, it is possible to prevent the positive electrode lead 21a from being damaged by the tips of the second protrusion 43 and the fourth protrusion 53 coming into contact with the edge of the positive electrode lead 21a. The same applies to the connection between the negative electrode current collector 29 and the current collector terminal 31.

(3)第1端子部材40に形成された各突起部42,43の先端を、第2端子部材50の第2基端部51cから離間させるとともに、第2端子部材50に形成された各突起部52,53の先端を第1端子部材40の第1基端部41cから離間させている。このため、各突起部42,43,52,53の弾性によって正電極リード21aを挟み込み易くさせることができる。したがって、各突起部42,43,52,53の間に正電極リード21aを確実に挟み込むように配置させることができる。負極集電部29と集電端子31との連結についても同様である。   (3) The tips of the projections 42 and 43 formed on the first terminal member 40 are separated from the second base end portion 51 c of the second terminal member 50 and the projections formed on the second terminal member 50. The distal ends of the portions 52 and 53 are separated from the first base end portion 41 c of the first terminal member 40. For this reason, the positive electrode lead 21a can be easily sandwiched by the elasticity of the protrusions 42, 43, 52, and 53. Therefore, the positive electrode lead 21a can be disposed so as to be securely sandwiched between the protrusions 42, 43, 52, 53. The same applies to the connection between the negative electrode current collector 29 and the current collector terminal 31.

(4)正電極シート21と接する接触領域37の形状は、第1端子部材40と第2端子部材50とで同一形状とした。このため、正電極リード21aとの接触領域37の形状を各端子部材40,50とで異なる形状に形成する場合と比較して、各端子部材40,50を簡便に形成することができる。   (4) The shape of the contact region 37 in contact with the positive electrode sheet 21 is the same for the first terminal member 40 and the second terminal member 50. For this reason, each terminal member 40 and 50 can be simply formed compared with the case where the shape of the contact region 37 with the positive electrode lead 21a is formed in a shape different from each terminal member 40 and 50.

(5)正電極リード21a(金属箔26)、第1端子部材40、及び第2端子部材50を何れも同一の金属(アルミニウム)により形成している。このため、各端子部材40,50によって正電極リード21aを挟み込んだ状態で抵抗溶接を行うことにより、各端子部材40,50と正電極リード21aとを容易に接合することができる。負極集電部29と集電端子31との連結についても同様である。
(第2の実施形態)
次に、本発明を具体化した第2の実施形態を図6にしたがって説明する。なお、以下の説明では、既に説明した実施形態と同一構成について同一符号を付すなどし、その重複する説明を省略又は簡略する。
(5) The positive electrode lead 21a (metal foil 26), the first terminal member 40, and the second terminal member 50 are all formed of the same metal (aluminum). For this reason, each terminal member 40 and 50 and the positive electrode lead 21a can be easily joined by performing resistance welding in a state where the positive electrode lead 21a is sandwiched between the terminal members 40 and 50. The same applies to the connection between the negative electrode current collector 29 and the current collector terminal 31.
(Second Embodiment)
Next, a second embodiment of the present invention will be described with reference to FIG. In the following description, the same reference numerals are given to the same configurations as those of the already described embodiments, and the overlapping description is omitted or simplified.

図6(a)及び図6(b)に示すように、本実施形態の二次電池10では、正極集電部28を構成する各正電極リード21a、及び負極集電部29を構成する各負電極リード22aの形状が正面視台形状(略台形状)をなしている点で第1の実施形態と相違している。なお、以下の説明では、正極集電部28について詳しく説明し、正極集電部28と左右対称に構成された負極集電部29についてはその説明を省略する。   As shown in FIG. 6A and FIG. 6B, in the secondary battery 10 of the present embodiment, each positive electrode lead 21 a constituting the positive electrode current collector 28 and each constituting the negative electrode current collector 29. The negative electrode lead 22a is different from the first embodiment in that the shape of the negative electrode lead 22a is a trapezoidal shape (substantially trapezoidal). In the following description, the positive electrode current collector 28 will be described in detail, and the description of the negative electrode current collector 29 configured symmetrically with the positive electrode current collector 28 will be omitted.

正極集電部28を構成する各正電極リード21aは、当該正電極リード21aが延出形成された上縁部26aから上方に向かって、正電極シート21(正電極リード21a)の面方向のうち正電極リード21aの延出方向と直交する方向(左右方向)の長さ(幅)が徐々に小さくなるように、左右方向の第1縁部39a及び第2縁部39bが斜状に形成されている。   Each positive electrode lead 21a constituting the positive electrode current collector 28 is formed in the surface direction of the positive electrode sheet 21 (positive electrode lead 21a) from the upper edge portion 26a on which the positive electrode lead 21a is extended and formed upward. The first edge 39a and the second edge 39b in the left-right direction are slanted so that the length (width) in the direction (left-right direction) orthogonal to the extending direction of the positive electrode lead 21a is gradually reduced. Has been.

前述のように、各突起部42,43,52,53の先端は、正電極リード21aの延出方向(上下方向)に沿って延びる線状に形成されている。このため、各突起部42,43,52,53が延びる方向において、正電極リード21aの縁部のうち、第1端子部材40に形成された各突起部42,43の第1基端部41c側に配置される第1縁部39aは、第2突起部43の先端部(先端)に対して傾斜している。同様に、正電極リード21aの縁部のうち、第2端子部材50に形成された各突起部52,53の第2基端部51c側に配置される第2縁部39bは、第4突起部53の先端部(先端)に対して傾斜している。   As described above, the tips of the protrusions 42, 43, 52, and 53 are formed in a linear shape extending along the extending direction (vertical direction) of the positive electrode lead 21a. Therefore, in the direction in which the protrusions 42, 43, 52, 53 extend, the first base end portion 41c of the protrusions 42, 43 formed on the first terminal member 40, of the edge of the positive electrode lead 21a. The first edge 39 a disposed on the side is inclined with respect to the tip (tip) of the second protrusion 43. Similarly, the second edge 39b disposed on the second base end 51c side of each of the protrusions 52 and 53 formed on the second terminal member 50 among the edges of the positive electrode lead 21a is a fourth protrusion. The portion 53 is inclined with respect to the tip (tip).

次に、上記のように構成した二次電池10の作用について説明する。
本実施形態において、各正電極リード21aの第1縁部39aは、第1端子部材40に形成された第2突起部43の先端部に対して傾斜しているとともに、第2縁部39bは、第2端子部材50に形成された第4突起部53の先端部に対して傾斜している。したがって、第2突起部43の先端部を正電極リード21aの間に挿入する際に、当該先端部が正電極リード21aの第1縁部39aと当接する面積を小さくすることができる。同様に、第4突起部53の先端部を正電極リード21aの間に挿入する際に、当該先端部が正電極リード21aの第2縁部39bと当接する面積を小さくできる。即ち、本実施形態では、第2突起部43及び第4突起部53の先端部と各縁部39a,39bとがそれぞれ点接触した状態から、第2突起部43、及び第4突起部53を正電極リード21aの間に挿入させることができる。
Next, the operation of the secondary battery 10 configured as described above will be described.
In the present embodiment, the first edge 39a of each positive electrode lead 21a is inclined with respect to the tip of the second protrusion 43 formed on the first terminal member 40, and the second edge 39b is The second terminal member 50 is inclined with respect to the distal end portion of the fourth protrusion 53 formed on the second terminal member 50. Therefore, when the tip of the second protrusion 43 is inserted between the positive electrode leads 21a, the area where the tip contacts the first edge 39a of the positive electrode lead 21a can be reduced. Similarly, when the tip of the fourth protrusion 53 is inserted between the positive electrode leads 21a, the area where the tip contacts the second edge 39b of the positive electrode lead 21a can be reduced. That is, in the present embodiment, the second projecting portion 43 and the fourth projecting portion 53 are moved from the state where the tip portions of the second projecting portion 43 and the fourth projecting portion 53 are in point contact with the respective edge portions 39a and 39b. It can be inserted between the positive electrode leads 21a.

例えば、正電極リード21aの縁部と、第2突起部43及び第4突起部53の先端部とが平行をなしている場合には、正電極リード21aの縁部と各突起部43,53の先端部とが交差するように接触することがあり、各突起部43,53を正電極リード21aの間に挿入する際に正電極リード21aに損傷を与える虞がある。これに対して本実施形態では、正電極リード21aの第1縁部39a及び第2縁部39bを各突起部43,53の先端部に対してそれぞれ傾斜させることにより、各突起部43,53を正電極リード21aの間に挿入する際の、正電極リード21aの破損を好適に抑制できる。   For example, when the edge of the positive electrode lead 21a and the tip of the second protrusion 43 and the fourth protrusion 53 are parallel, the edge of the positive electrode lead 21a and the protrusions 43 and 53 are provided. There is a possibility that the leading end of the lead electrode 21a may be damaged when the projections 43 and 53 are inserted between the positive electrode leads 21a. On the other hand, in the present embodiment, the first edge portion 39a and the second edge portion 39b of the positive electrode lead 21a are inclined with respect to the distal end portions of the protrusion portions 43 and 53, respectively, thereby causing the protrusion portions 43 and 53 to be inclined. Can be suitably prevented from being damaged when the electrode is inserted between the positive electrode leads 21a.

したがって、本実施形態によれば、第1の実施形態の効果(1)〜(5)に加えて、以下のような効果を得ることができる。
(6)各正電極リード21aの第1縁部39aは、第1端子部材40に形成された第2突起部43の先端部に対して傾斜しているとともに、第2縁部39bは、第2端子部材50に形成された第4突起部53の先端部に対して傾斜している。このため、第2突起部43の先端部を正電極リード21aの間に挿入する際に、当該先端部が正電極リード21aの第1縁部39aと当接する面積を小さくすることができる。同様に、第2端子部材50に形成された第4突起部53の先端部を正電極リード21aの間に挿入する際に、当該先端部が正電極リード21aの第2縁部39bと当接する面積を小さくできる。したがって、第2突起部43及び第4突起部53を正電極リード21aの間に挿入する際の、正電極リード21aの破損を抑制できる。
Therefore, according to this embodiment, in addition to the effects (1) to (5) of the first embodiment, the following effects can be obtained.
(6) The first edge 39a of each positive electrode lead 21a is inclined with respect to the tip of the second protrusion 43 formed on the first terminal member 40, and the second edge 39b is It is inclined with respect to the tip end portion of the fourth protrusion 53 formed on the two-terminal member 50. For this reason, when inserting the front-end | tip part of the 2nd projection part 43 between the positive electrode leads 21a, the area which the said front-end | tip part contact | abuts with the 1st edge part 39a of the positive electrode lead 21a can be made small. Similarly, when the distal end portion of the fourth protrusion 53 formed on the second terminal member 50 is inserted between the positive electrode leads 21a, the distal end portion comes into contact with the second edge 39b of the positive electrode lead 21a. The area can be reduced. Therefore, damage to the positive electrode lead 21a when the second protrusion 43 and the fourth protrusion 53 are inserted between the positive electrode leads 21a can be suppressed.

実施形態は上記のように限定されるものではなく、例えば以下のように具体化してもよい。
○ 図7に示すように、正電極リード21a及び負電極リード22aは、第1縁部39a及び第2縁部39bが平行をなす平行四辺形状に形成してもよい。即ち、各正電極リード21aの第1縁部39aは、第1端子部材40に形成された第2突起部43の先端部に対して傾斜しているとともに、第2縁部39bは、第2端子部材50に形成された第4突起部53の先端部に対して傾斜しておればよい。負極集電部29についても同様である。
The embodiment is not limited as described above, and may be embodied as follows, for example.
As shown in FIG. 7, the positive electrode lead 21a and the negative electrode lead 22a may be formed in a parallelogram shape in which the first edge portion 39a and the second edge portion 39b are parallel to each other. That is, the first edge 39a of each positive electrode lead 21a is inclined with respect to the tip of the second protrusion 43 formed on the first terminal member 40, and the second edge 39b is the second edge 39b. What is necessary is just to incline with respect to the front-end | tip part of the 4th projection part 53 formed in the terminal member 50. FIG. The same applies to the negative electrode current collector 29.

○ 図7に示すように、第2縁部39bの基端部にR部39cを設けて補強をしてもよい。また同様に、第1縁部39aの基端部にR部39cを設けてもよい。
○ 図8(a)及び図8(b)に示すように、各第2突起部43は、その先端部に第2傾斜部43dに加えて、さらに正電極リード21a(又は負電極リード22a)の延出方向(上下方向)に傾斜する面状をなす第5傾斜面43eを設けて先細り形状に形成してもよい。なお、図8では、1つの第2突起部43、及び1つの第4突起部53のみを図示し、その他の部材の図示を省略している。詳述すると、各第2突起部43には、第3端面43aと第4端面43bとを繋ぎ、かつ電極体25側に形成される第1下面43fと、当該第1下面43fとは反対側の第1上面43gが形成される。そして、第2突起部43の先端には、第1下面43fと第1上面43gとを連続する第5傾斜面43eが形成される。この第5傾斜面43eは、第1下面43f又は第1上面43gとなす角度が鋭角であるとよい。
O As shown in FIG. 7, you may reinforce by providing the R part 39c in the base end part of the 2nd edge part 39b. Similarly, an R portion 39c may be provided at the proximal end portion of the first edge portion 39a.
As shown in FIGS. 8A and 8B, each of the second protrusions 43 has a positive electrode lead 21a (or a negative electrode lead 22a) in addition to the second inclined portion 43d at the tip. A fifth inclined surface 43e having a surface inclined in the extending direction (vertical direction) may be provided to form a tapered shape. In FIG. 8, only one second protrusion 43 and one fourth protrusion 53 are shown, and other members are not shown. More specifically, each second protrusion 43 connects the third end surface 43a and the fourth end surface 43b, and the first lower surface 43f formed on the electrode body 25 side is opposite to the first lower surface 43f. The first upper surface 43g is formed. A fifth inclined surface 43e is formed at the tip of the second protrusion 43 so as to continue the first lower surface 43f and the first upper surface 43g. The fifth inclined surface 43e may have an acute angle with the first lower surface 43f or the first upper surface 43g.

また、各第4突起部53は、その先端部に第4傾斜部53dに加えて、さらに正電極リード21a(又は負電極リード22a)の延出方向(上下方向)に傾斜する面状をなす第6傾斜面53eを設けて先細り形状に形成してもよい。詳述すると、各第4突起部53には、第7端面53aと第8端面53bとを繋ぎ、かつ電極体25側に形成される第2下面53fと、当該第2下面53fとは反対側の第2上面53gが形成される。そして、第4突起部53の先端部には、第2下面53fと第2上面53gとを連続する第6傾斜面53eが形成される。この第6傾斜面53eは、第2下面53f又は第2上面53gとなす角度が鋭角であるとよい。   In addition to the fourth inclined portion 53d, each fourth protruding portion 53 has a planar shape inclined further in the extending direction (vertical direction) of the positive electrode lead 21a (or the negative electrode lead 22a). A sixth inclined surface 53e may be provided to form a tapered shape. More specifically, each fourth projection 53 is connected to the seventh end surface 53a and the eighth end surface 53b, and the second lower surface 53f formed on the electrode body 25 side is opposite to the second lower surface 53f. The second upper surface 53g is formed. A sixth inclined surface 53e is formed at the distal end portion of the fourth protrusion 53 so as to continue the second lower surface 53f and the second upper surface 53g. The sixth inclined surface 53e may have an acute angle with the second lower surface 53f or the second upper surface 53g.

また、第2突起部43、及び第4突起部53の先端部を円錐状に形成し、第2傾斜部43dと第5傾斜面43e、及び第4傾斜部53dと第6傾斜面53eが連続するように形成してもよい。なお、第1突起部42、及び第3突起部52についても同様に変更できる。これにより、各突起部42,43,52,53は、基端部から先端部にかけて、電極体25における積層方向に沿った断面積が小さくなっていく形状にできる。   Further, the tip portions of the second protrusion 43 and the fourth protrusion 53 are formed in a conical shape, and the second inclined portion 43d and the fifth inclined surface 43e, and the fourth inclined portion 53d and the sixth inclined surface 53e are continuous. You may form so that it may do. The first protrusion 42 and the third protrusion 52 can be similarly changed. Thereby, each protrusion part 42,43,52,53 can be made into the shape where the cross-sectional area along the lamination direction in the electrode body 25 becomes small from a base end part to a front-end | tip part.

○ 集電端子30において、さらに第2端子部材50の本体部51と正極端子15とを直接、溶接してもよく、集電端子31において、さらに本体部51と負極端子16とを直接、溶接してもよい。   In the current collecting terminal 30, the main body 51 and the positive terminal 15 of the second terminal member 50 may be directly welded. In the current collecting terminal 31, the main body 51 and the negative terminal 16 are directly welded. May be.

○ 各端子部材40,50のうち、一方に突起部を設けるとともに他方に凹部を設け、突起部と凹部とを係合させることにより各端子部材40,50を相互に固定するようにしてもよい。   ○ Of each terminal member 40, 50, a protrusion may be provided on one side, a recess may be provided on the other, and the terminal members 40, 50 may be fixed to each other by engaging the protrusion and the recess. .

○ 各傾斜部42d,43d,52d,53dは、それぞれ対応する突起部の基端部側に形成されていてもよい。
○ 第1の実施形態において、第2傾斜部43d及び第4傾斜部53dは、それぞれ各突起部43,53における電極体25での積層方向の長さの半分を超える範囲にわたって形成されておれば、その形成範囲を変更してもよい。例えば、第2突起部43、及び第4突起部53における前記積層方向の長さ(幅)の4分の3の範囲にわたって形成されていてもよい。
Each inclined part 42d, 43d, 52d, 53d may be formed on the base end side of the corresponding protrusion.
In the first embodiment, if the second inclined portion 43d and the fourth inclined portion 53d are formed over a range that exceeds half of the length in the stacking direction of the electrode body 25 in each of the protruding portions 43 and 53, respectively. The formation range may be changed. For example, the second protrusion 43 and the fourth protrusion 53 may be formed over a range of three quarters of the length (width) in the stacking direction.

○ 第2の実施形態において、第2傾斜部43d及び第4傾斜部53dは、それぞれ各突起部43,53における電極体25での積層方向の長さの半分以下の範囲にわたって形成されていてもよい。但し、正極集電部28と集電端子30や、負極集電部29と集電端子31を容易に連結させる観点からは、上記実施形態のように構成することが好ましい。   In the second embodiment, the second inclined portion 43d and the fourth inclined portion 53d may be formed over a range that is half or less of the length in the stacking direction of the electrode body 25 in each of the protrusions 43 and 53, respectively. Good. However, from the viewpoint of easily connecting the positive electrode current collector 28 and the current collector terminal 30 and the negative electrode current collector 29 and the current collector terminal 31, it is preferable to configure as in the above embodiment.

○ 各端子部材40,50は、プレス加工などにより形成してもよい。
○ 各端子部材40,50は、それぞれ別の金属板から形成してもよい。
○ 各端子部材40,50は、接触領域37において同一形状に形成されていなくてもよい。即ち、各端子部材40,50は、正電極リード21aや負電極リード22aを挟み込める形状であれば、各突起部42,43,52,53、及び本体部41,51の形状を適宜変更してもよい。負極集電部29と集電端子31との連結(接合)についても同様に変更できる。
Each terminal member 40, 50 may be formed by press working or the like.
Each terminal member 40, 50 may be formed from a separate metal plate.
Each terminal member 40 and 50 does not need to be formed in the same shape in the contact region 37. That is, if each terminal member 40,50 is a shape which can pinch | interpose the positive electrode lead 21a and the negative electrode lead 22a, it changes suitably the shape of each projection part 42,43,52,53 and the main-body parts 41,51. May be. The connection (bonding) between the negative electrode current collector 29 and the current collector terminal 31 can be similarly changed.

○ 第1端子部材40には、第2突起部43を1つ、又は3つ以上形成してもよく、第2端子部材50には、第4突起部53を1つ、又は3つ以上形成してもよい。この場合、各端子部材40,50の間に形成される隙間の数に応じて正極集電部28を構成する正電極リード21aを分割し、挟み込むようにすればよい。負極集電部29と集電端子31との連結(接合)についても同様に変更できる。   ○ The first terminal member 40 may be formed with one or three or more second protrusions 43, and the second terminal member 50 may be formed with one or three or more fourth protrusions 53. May be. In this case, the positive electrode lead 21a constituting the positive electrode current collector 28 may be divided and sandwiched according to the number of gaps formed between the terminal members 40 and 50. The connection (bonding) between the negative electrode current collector 29 and the current collector terminal 31 can be similarly changed.

○ 各端子部材40,50の間に形成される隙間のうち、一部の隙間に正電極リード21aを配置しない構成としてもよい。この場合、正電極リード21aが配置されない隙間は、正電極シート21を介することなく各端子部材40,50が接触(連続)し、接合される。負極集電部29と集電端子31との連結(接合)についても同様に変更できる。   O It is good also as a structure which does not arrange | position the positive electrode lead 21a in some clearance gaps among the clearance gaps formed between each terminal members 40 and 50. FIG. In this case, in the gap where the positive electrode lead 21a is not disposed, the terminal members 40 and 50 are brought into contact (continuous) and joined without the positive electrode sheet 21 interposed therebetween. The connection (bonding) between the negative electrode current collector 29 and the current collector terminal 31 can be similarly changed.

○ 各端子部材40,50及び正極集電部28(正電極リード21a)は、抵抗溶接とは異なる溶接方法により接合してもよい。また、各端子部材40,50の間に正極集電部28(正電極リード21a)を挟み込んだだけの状態としてもよい。負極集電部29と集電端子31との接合についても同様に変更できる。   Each terminal member 40, 50 and the positive electrode current collector 28 (positive electrode lead 21a) may be joined by a welding method different from resistance welding. Alternatively, the positive electrode current collector 28 (positive electrode lead 21a) may be simply sandwiched between the terminal members 40 and 50. The junction between the negative electrode current collector 29 and the current collector terminal 31 can be similarly changed.

○ 集電端子30を構成する各端子部材40,50は、正電極リード21aを構成する金属箔26とは異なる金属により形成されていてもよい。また、集電端子30を構成する各端子部材40,50は、それぞれ異なる金属から形成されていてもよく、さらに第2端子部材50は、樹脂などの絶縁材料により形成されていてもよい。集電端子31についても同様に変更できる。   Each terminal member 40 and 50 which comprises the current collection terminal 30 may be formed with the metal different from the metal foil 26 which comprises the positive electrode lead 21a. Moreover, each terminal member 40 and 50 which comprises the current collection terminal 30 may be formed from a respectively different metal, and also the 2nd terminal member 50 may be formed with insulating materials, such as resin. The current collecting terminal 31 can be similarly changed.

○ 電極体25は、正電極シート21、負電極シート22、及びセパレータ23を長尺のシート状(帯状)に形成するとともに、セパレータ23を間に挟んだ状態で、正電極シート21及び負電極シート22を渦まき状に捲回し、正電極シート21及び負電極シート22が層状の構造(積層構造)をなすように形成してもよい。この場合、正電極シート21において幅方向(左右方向)の一方の端部(本別例では左端部)には、正電極シート21の長さ方向に沿って所定間隔で延びるように、幅方向の外側(左側)へ突出する正電極リード21aを設ける。その一方で、負電極シート22において幅方向の他方の端部(本別例では右端部)には、負電極シート22の長さ方向に沿って所定間隔で延びるように、幅方向の外側(右側)へ突出する負電極リード22aを設ける。そして、正電極シート21及び負電極シート22を捲回することで、電極体25の左端部に複数の正電極リード21aが層状をなす正極集電部28を形成する一方で、電極体25の右端部に複数の負電極リード22aが層状をなす負極集電部29を形成するとよい。   The electrode body 25 is formed by forming the positive electrode sheet 21, the negative electrode sheet 22, and the separator 23 into a long sheet shape (band shape) and sandwiching the separator 23 therebetween, and the positive electrode sheet 21 and the negative electrode The sheet 22 may be wound in a spiral shape so that the positive electrode sheet 21 and the negative electrode sheet 22 have a layered structure (laminated structure). In this case, in the positive electrode sheet 21, one end portion (left end portion in this example) in the width direction (left-right direction) extends in the width direction so as to extend at a predetermined interval along the length direction of the positive electrode sheet 21. A positive electrode lead 21a that protrudes to the outside (left side) is provided. On the other hand, in the negative electrode sheet 22, the other end in the width direction (the right end in the present example) extends outside in the width direction so as to extend at a predetermined interval along the length direction of the negative electrode sheet 22 ( A negative electrode lead 22a protruding to the right) is provided. Then, by winding the positive electrode sheet 21 and the negative electrode sheet 22, the positive electrode current collector portion 28 in which a plurality of positive electrode leads 21 a form a layer shape is formed on the left end portion of the electrode body 25. A negative electrode current collector 29 in which a plurality of negative electrode leads 22a form a layer shape may be formed at the right end.

○ 電極体25は、セパレータ23を介在させて、正電極シート21及び負電極シート22を蛇腹状に折り曲げて積層してもよい。
○ 金属薄板(金属シート)として金属箔26としたが、電池の容量の低下や電池作製時に影響しない程度の厚みのある薄板であってもよい。
The electrode body 25 may be laminated by folding the positive electrode sheet 21 and the negative electrode sheet 22 in a bellows shape with the separator 23 interposed therebetween.
Although the metal foil 26 is used as the metal thin plate (metal sheet), it may be a thin plate having a thickness that does not affect the battery capacity reduction or the battery production.

○ ケース11(本体部材12)の形状は、円柱状や、左右方向に扁平な楕円柱状に形成してもよい。
○ 上記実施形態における、平行や直交は、必ずしも完全な平行や直交を意味せず、平行や直交の位置関係から、電極体25や金属箔26、又は各突起部42,43,52,53を弾性変形させた程度の範囲は、これらに含むものとする。
The shape of the case 11 (main body member 12) may be formed in a columnar shape or an elliptical column shape that is flat in the left-right direction.
In the above embodiment, the parallel or orthogonal does not necessarily mean completely parallel or orthogonal, and the electrode body 25, the metal foil 26, or the protrusions 42, 43, 52, and 53 are determined from the parallel or orthogonal positional relationship. The range of the degree of elastic deformation is included in these.

○ 上記実施形態の二次電池10を車両(例えば産業車両や乗用車両など)に搭載し、車両に装備された発電機により充電する一方で、二次電池10から供給する電力によりエアコン用のコンプレッサや、車輪を駆動するための電動モータ、或いはカーナビゲーションシステムなどの電装品を駆動してもよい。これによれば、二次電池10として、正電極リード21aや負電極リード22aの破損を抑制し、正極集電部28と集電端子30、及び負極集電部29と集電端子31を容易に連結できることから、二次電池10を含む車両の製造に要する時間を短縮できる。   ○ The secondary battery 10 of the above embodiment is mounted on a vehicle (for example, an industrial vehicle or a passenger vehicle), and is charged by a generator mounted on the vehicle, while the compressor for an air conditioner is supplied with electric power supplied from the secondary battery 10 Alternatively, an electric motor for driving the wheels or an electrical component such as a car navigation system may be driven. According to this, as the secondary battery 10, the positive electrode lead 21a and the negative electrode lead 22a are prevented from being damaged, and the positive electrode current collector 28 and the current collector terminal 30 and the negative electrode current collector 29 and the current collector terminal 31 are easily provided. Therefore, the time required for manufacturing the vehicle including the secondary battery 10 can be shortened.

○ 本発明は、蓄電装置としての電気二重層キャパシタとして具体化してもよい。   The present invention may be embodied as an electric double layer capacitor as a power storage device.

10…二次電池(蓄電装置)、15…正極端子(電極端子)、16…負極端子(電極端子)、21…正電極シート(電極シート)、21a…正電極リード(未塗工部)、22…負電極シート(電極シート)、22a…負電極リード(未塗工部)、25…電極体、25a…上端面(端面)、25b…下端面(端面)、26…金属箔、27a…塗工部、28…正極集電部(集電部)、29…負極集電部(集電部)、30…集電端子(集電部材)、31…集電端子(集電部材)、39a…第1縁部、39b…第2縁部、40…第1端子部材(第1部材)、41a…第1側面、41b…第2側面、41c…第1基端部、42…第1突起部、42a…第1端面、42b…第2端面、42c…第1連接部、42d…第1傾斜部、43…第2突起部、43a…第3端面、43b…第4端面、43c…第2連接部、43d…第2傾斜部、43e…第5傾斜面、43f…第1下面、43g…第1上面、50…第2端子部材(第2部材)、51a…第3側面、51b…第4側面、51c…第2基端部、52…第3突起部、52a…第5端面、52b…第6端面、52c…第3連接部、52d…第3傾斜部、53…第4突起部、53a…第7端面、53b…第8端面、53c…第4連接部、53d…第4傾斜部、53e…第6傾斜面、53f…第2下面、53g…第2上面。   DESCRIPTION OF SYMBOLS 10 ... Secondary battery (electric storage apparatus), 15 ... Positive electrode terminal (electrode terminal), 16 ... Negative electrode terminal (electrode terminal), 21 ... Positive electrode sheet (electrode sheet), 21a ... Positive electrode lead (uncoated part), 22 ... Negative electrode sheet (electrode sheet), 22a ... Negative electrode lead (uncoated part), 25 ... Electrode body, 25a ... Upper end surface (end surface), 25b ... Lower end surface (end surface), 26 ... Metal foil, 27a ... Coating part, 28 ... Positive current collecting part (current collecting part), 29 ... Negative electrode current collecting part (current collecting part), 30 ... Current collecting terminal (current collecting member), 31 ... Current collecting terminal (current collecting member), 39a ... 1st edge part, 39b ... 2nd edge part, 40 ... 1st terminal member (1st member), 41a ... 1st side surface, 41b ... 2nd side surface, 41c ... 1st base end part, 42 ... 1st Projection, 42a ... first end surface, 42b ... second end surface, 42c ... first connecting portion, 42d ... first inclined portion, 43 ... second projection, 43a 3rd end surface, 43b ... 4th end surface, 43c ... 2nd connection part, 43d ... 2nd inclined part, 43e ... 5th inclined surface, 43f ... 1st lower surface, 43g ... 1st upper surface, 50 ... 2nd terminal member ( 2nd member), 51a ... 3rd side surface, 51b ... 4th side surface, 51c ... 2nd base end part, 52 ... 3rd projection part, 52a ... 5th end surface, 52b ... 6th end surface, 52c ... 3rd connection part , 52d ... third inclined portion, 53 ... fourth protrusion, 53a ... seventh end surface, 53b ... eighth end surface, 53c ... fourth connecting portion, 53d ... fourth inclined portion, 53e ... sixth inclined surface, 53f ... 2nd lower surface, 53g ... 2nd upper surface.

Claims (11)

金属薄板、前記金属薄板の表面に活物質が塗布された塗工部、及び前記活物質が塗布されていない未塗工部を有する電極シートが複数重なって層状の構造をなす電極体と、
前記電極体の一方の縁部から延出形成され、かつ各前記電極シートの未塗工部が複数重なって層状の構造をなす集電部と、
前記電極体から電力を取り出すための電極端子と、
前記集電部と前記電極端子とを電気的に接続した集電部材とを有する蓄電装置であって、
前記電極体における積層方向の両端部には、前記積層方向に沿って延びる端面がそれぞれ形成されており、
前記集電部材は、前記両端部の一方の端面上に、かつ前記電極体の積層方向に直交する方向に並んで配置される第1部材、及び第2部材を有し、
前記第1部材には、前記電極体における層と平行する側面である第1側面と、前記第1側面とは反対側の側面である第2側面とがそれぞれ形成され、
前記第1部材は、前記電極端子と電気的に接続され、
前記第1部材には、前記第2部材側に突出する第1突起部、及び少なくとも一つの第2突起部とが形成され、
前記第1突起部は、少なくとも、
前記第1側面と連続し、かつ前記第1側面と平行な第1端面と、
前記第1端面とは反対側の端面である第2端面と、
前記第1端面と前記第2端面における前記第1突起部の先端側の端部同士を繋ぐ第1連接部によって構成され、
前記第1連接部は第1傾斜部を有し、
前記第1傾斜部は、前記第1端面と鋭角をなし、
前記第2突起部は、少なくとも、
前記第1端面側に形成され、かつ前記第1端面と平行する第3端面と、
前記第3端面とは反対側の端面である第4端面と、
前記第3端面と前記第4端面における前記第2突起部の先端側の端部同士を繋ぐ第2連接部によって構成され、
前記第2連接部は、第2傾斜部を有し、
前記第2傾斜部は、前記第4端面と鋭角をなし、
前記第2部材は、前記電極体における層と平行する側面である第3側面と、前記第3側面とは反対側の側面である第4側面とがそれぞれ形成され、
前記第3側面は前記第1側面と同じ側に、前記第4側面は、前記第2側面と同じ側に、それぞれ形成され、
前記第2部材は、前記第1部材と直接、又は前記集電部をなす前記未塗工部を介して連続し、
前記第2部材には、前記第1部材側に突出する第3突起部、及び少なくとも一つの第4突起部とが形成され、
前記第3突起部は、少なくとも、
前記第4側面と連続し、かつ前記第4側面と平行な第5端面と、
前記第5端面とは反対側の端面である第6端面と、
前記第5端面と前記第6端面における前記第3突起部の先端側の端部同士を繋ぐ第3連接部によって構成され、
前記第3連接部は第3傾斜部を有し、
前記第3傾斜部は、前記第5端面と鋭角をなし、
前記第4突起部は、少なくとも、
前記第5端面側に形成され、かつ前記第5端面と平行する第7端面と、
前記第7端面とは反対側の端面である第8端面と、
前記第7端面と前記第8端面における前記第2突起部の先端側の端部同士を繋ぐ第4連接部によって構成され、
前記第4連接部は、第4傾斜部を有し、
前記第4傾斜部は、前記第8端面と鋭角をなし、
前記積層方向において、前記第1端面側から、前記第1突起部、前記第4突起部、及び前記第2突起部が順に配置され、
前記積層方向において、前記第2端面側から、前記第3突起部、前記第2突起部、及び前記第4突起部が順に配置され、
前記第1突起部と前記第4突起部との間、前記第2突起部と前記第4突起部との間、及び前記第2突起部と前記第3突起部との間には、前記集電部をなす前記未塗工部がそれぞれ複数の束に分割して配置されており、
前記第2傾斜部、及び前記4傾斜部の、それぞれ前記第2突起部、及び前記第4突起部における前記積層方向の幅は、それぞれ前記第2突起部、及び前記第4突起部の前記積層方向の幅の半分を超えて形成されていることを特徴とする蓄電装置。
An electrode body having a layered structure in which a plurality of electrode sheets each having a metal thin plate, a coated portion where an active material is applied to the surface of the metal thin plate, and an uncoated portion where the active material is not applied;
A current collector formed extending from one edge of the electrode body, and a plurality of uncoated portions of the electrode sheets are stacked to form a layered structure;
An electrode terminal for extracting power from the electrode body;
A power storage device having a current collecting member that electrically connects the current collecting part and the electrode terminal,
End faces extending along the laminating direction are formed at both ends of the electrode body in the laminating direction, respectively.
The current collecting member has a first member and a second member arranged on one end face of the both end portions and arranged in a direction orthogonal to the stacking direction of the electrode body,
In the first member, a first side surface that is a side surface parallel to the layer in the electrode body and a second side surface that is a side surface opposite to the first side surface are formed, respectively.
The first member is electrically connected to the electrode terminal;
The first member is formed with a first protrusion protruding toward the second member and at least one second protrusion,
The first protrusion is at least
A first end surface continuous with the first side surface and parallel to the first side surface;
A second end surface which is an end surface opposite to the first end surface;
The first end surface and the second end surface are configured by a first connecting portion that connects end portions on the distal end side of the first projecting portion,
The first connecting portion has a first inclined portion;
The first inclined portion forms an acute angle with the first end surface;
The second protrusion is at least
A third end face formed on the first end face side and parallel to the first end face;
A fourth end surface that is an end surface opposite to the third end surface;
The third end surface and the fourth end surface are configured by a second connecting portion that connects end portions on the distal end side of the second projecting portion,
The second connecting part has a second inclined part,
The second inclined portion forms an acute angle with the fourth end surface;
The second member has a third side surface that is a side surface parallel to the layer in the electrode body, and a fourth side surface that is a side surface opposite to the third side surface, respectively.
The third side surface is formed on the same side as the first side surface, and the fourth side surface is formed on the same side as the second side surface,
The second member is continuous with the first member directly or through the uncoated portion forming the current collector,
The second member is formed with a third protrusion that protrudes toward the first member, and at least one fourth protrusion.
The third protrusion is at least
A fifth end surface that is continuous with the fourth side surface and parallel to the fourth side surface;
A sixth end surface which is an end surface opposite to the fifth end surface;
The fifth end surface and the sixth end surface are configured by a third connecting portion that connects end portions on the distal end side of the third projecting portion,
The third connecting portion has a third inclined portion;
The third inclined portion forms an acute angle with the fifth end surface;
The fourth protrusion is at least
A seventh end surface formed on the fifth end surface side and parallel to the fifth end surface;
An eighth end surface which is an end surface opposite to the seventh end surface;
The seventh end surface and the eighth end surface are constituted by a fourth connecting portion that connects end portions on the distal end side of the second projecting portion,
The fourth connecting portion has a fourth inclined portion,
The fourth inclined portion forms an acute angle with the eighth end surface;
In the stacking direction, the first protrusion, the fourth protrusion, and the second protrusion are sequentially disposed from the first end face side.
In the stacking direction, the third protrusion, the second protrusion, and the fourth protrusion are sequentially arranged from the second end face side,
Between the first protrusion and the fourth protrusion, between the second protrusion and the fourth protrusion, and between the second protrusion and the third protrusion, The uncoated parts constituting the electrical parts are each divided and arranged in a plurality of bundles,
The width of the second inclined portion and the fourth inclined portion in the stacking direction of the second protruding portion and the fourth protruding portion, respectively, is the stack of the second protruding portion and the fourth protruding portion, respectively. A power storage device, wherein the power storage device is formed to exceed half of a width in a direction.
前記第1傾斜部、前記第2傾斜部、前記第3傾斜部、及び前記第4傾斜部は、それぞれ前記第1突起部、前記第2突起部、前記第3突起部、及び前記第4突起部の先端に形成されていることを特徴とする請求項1に記載の蓄電装置。   The first inclined portion, the second inclined portion, the third inclined portion, and the fourth inclined portion are respectively the first protruding portion, the second protruding portion, the third protruding portion, and the fourth protruding portion. The power storage device according to claim 1, wherein the power storage device is formed at a tip of the portion. 前記第3突起部の先端及び前記第4突起部の先端と、前記第1部材における前記第1突起部及び前記第2突起部の基端部である第1基端部と、は離間しており、
前記第1突起部の先端及び前記第2突起部の先端と、前記第2部材における前記第3突起部及び前記第4突起部の基端部である第2基端部と、は離間していることを特徴とする請求項1または2に記載の蓄電装置。
The distal end of the third projecting portion and the distal end of the fourth projecting portion are separated from the first proximal end portion that is the proximal end portion of the first projecting portion and the second projecting portion of the first member. And
The distal end of the first projecting portion and the distal end of the second projecting portion are separated from the second proximal end portion that is the proximal end portion of the third projecting portion and the fourth projecting portion of the second member. The power storage device according to claim 1, wherein the power storage device is provided.
前記積層方向と直交する方向において、前記集電部をなす前記未塗工部の縁部のうち前記第1基端部側に配置される第1縁部は、前記第2基端部側に傾斜しているとともに、前記未塗工部の縁部のうち、前記第2基端部側に配置される第2縁部は、前記第1基端部側に傾斜していることを特徴とする請求項3に記載の蓄電装置。   In a direction orthogonal to the stacking direction, a first edge disposed on the first base end side of the uncoated part forming the current collector is on the second base end side. The second edge portion, which is inclined and arranged on the second base end side among the edges of the uncoated portion, is inclined toward the first base end side. The power storage device according to claim 3. 前記第1突起部と前記第3突起部、及び前記第2突起部と前記第4突起部とは、それぞれ同一形状をなしていることを特徴とする請求項1〜4のいずれか1項に記載の蓄電装置。   The said 1st projection part and the said 3rd projection part, and the said 2nd projection part and the said 4th projection part have each comprised the same shape, The any one of Claims 1-4 characterized by the above-mentioned. The power storage device described. 前記第2突起部、及び前記第4突起部は、それぞれの基端部側における前記積層方向に沿う断面積よりも、それぞれの先端部側における前記積層方向に沿う断面積が小さい先細り形状をなしていることを特徴とする請求項1〜5のいずれか1項に記載の蓄電装置。   The second projecting portion and the fourth projecting portion have a tapered shape in which the cross-sectional area along the stacking direction on the distal end side is smaller than the cross-sectional area along the stacking direction on the base end side. The power storage device according to claim 1, wherein the power storage device is provided. 前記第1部材及び前記第2部材は、前記金属薄板と同一の金属から形成されていることを特徴とする請求項1〜6のいずれか1項に記載の蓄電装置。   The power storage device according to claim 1, wherein the first member and the second member are made of the same metal as the thin metal plate. 金属薄板、前記金属薄板の表面に活物質が塗布された塗工部、及び前記活物質が塗布されていない未塗工部を有する電極シートが複数重なって層状の構造をなす電極体と、
前記電極体の一方の縁部から延出形成され、かつ各前記電極シートの未塗工部が複数重なって層状の構造をなす集電部と、
前記電極体から電力を取り出すための電極端子と、
前記集電部と前記電極端子とを電気的に接続した集電部材とを有する蓄電装置であって、
前記電極体における積層方向の両端部には、前記積層方向に沿って延びる端面がそれぞれ形成されており、
前記集電部材は、前記両端部の一方の端面上に、かつ前記電極体の積層方向に直交する方向に並んで配置される第1部材、及び第2部材を有し、
前記第1部材には、前記電極体における層と平行する側面である第1側面と、前記第1側面とは反対側の側面である第2側面とがそれぞれ形成され、
前記第1部材は、前記電極端子と電気的に接続され、
前記第1部材には、前記第2部材側に突出する第1突起部、及び少なくとも一つの第2突起部とが形成され、
前記第1突起部は、少なくとも、
前記第1側面と連続し、かつ前記第1側面と平行な第1端面と、
前記第1端面とは反対側の端面である第2端面と、
前記第1端面と前記第2端面における前記第1突起部の先端側の端部同士を繋ぐ第1連接部によって構成され、
前記第1連接部は第1傾斜部を有し、
前記第1傾斜部は、前記第1端面と鋭角をなし、
前記第2突起部は、少なくとも、
前記第1端面側に形成され、かつ前記第1端面と平行する第3端面と、
前記第3端面とは反対側の端面である第4端面と、
前記第3端面と前記第4端面における前記第2突起部の先端側の端部同士を繋ぐ第2連接部によって構成され、
前記第2連接部は、第2傾斜部を有し、
前記第2傾斜部は、前記第4端面と鋭角をなし、
前記第2部材は、前記電極体における層と平行する側面である第3側面と、前記第3側面とは反対側の側面である第4側面とがそれぞれ形成され、
前記第3側面は前記第1側面と同じ側に、前記第4側面は、前記第2側面と同じ側に、それぞれ形成され、
前記第2部材は、前記第1部材と直接、又は前記集電部をなす前記未塗工部を介して連続し、
前記第2部材には、前記第1部材側に突出する第3突起部、及び少なくとも一つの第4突起部とが形成され、
前記第3突起部は、少なくとも、
前記第4側面と連続し、かつ前記第4側面と平行な第5端面と、
前記第5端面とは反対側の端面である第6端面と、
前記第5端面と前記第6端面における前記第3突起部の先端側の端部同士を繋ぐ第3連接部によって構成され、
前記第3連接部は第3傾斜部を有し、
前記第3傾斜部は、前記第5端面と鋭角をなし、
前記第4突起部は、少なくとも、
前記第5端面側に形成され、かつ前記第5端面と平行する第7端面と、
前記第7端面とは反対側の端面である第8端面と、
前記第7端面と前記第8端面における前記第2突起部の先端側の端部同士を繋ぐ第4連接部によって構成され、
前記第4連接部は、第4傾斜部を有し、
前記第4傾斜部は、前記第8端面と鋭角をなし、
前記積層方向において、前記第1端面側から、前記第1突起部、前記第4突起部、及び前記第2突起部が順に配置され、
前記積層方向において、前記第2端面側から、前記第3突起部、前記第2突起部、及び前記第4突起部が順に配置され、
前記第1突起部と前記第4突起部との間、前記第2突起部と前記第4突起部との間、及び前記第2突起部と前記第3突起部との間には、前記集電部をなす前記未塗工部がそれぞれ複数の束に分割して配置されており、
前記積層方向と直交する方向において、前記集電部をなす前記未塗工部の縁部のうち前記第1突起部及び前記第2突起部の基端部である第1基端部側に配置される第1縁部は、前記第3突起部及び前記第4突起部の基端部である第2基端部側に傾斜しているとともに、前記未塗工部の縁部のうち、前記第2基端部側に配置される第2縁部は、前記第1基端部側に傾斜していることを特徴とする蓄電装置。
An electrode body having a layered structure in which a plurality of electrode sheets each having a metal thin plate, a coated portion where an active material is applied to the surface of the metal thin plate, and an uncoated portion where the active material is not applied;
A current collector formed extending from one edge of the electrode body, and a plurality of uncoated portions of the electrode sheets are stacked to form a layered structure;
An electrode terminal for extracting power from the electrode body;
A power storage device having a current collecting member that electrically connects the current collecting part and the electrode terminal,
End faces extending along the laminating direction are formed at both ends of the electrode body in the laminating direction, respectively.
The current collecting member has a first member and a second member arranged on one end face of the both end portions and arranged in a direction orthogonal to the stacking direction of the electrode body,
In the first member, a first side surface that is a side surface parallel to the layer in the electrode body and a second side surface that is a side surface opposite to the first side surface are formed, respectively.
The first member is electrically connected to the electrode terminal;
The first member is formed with a first protrusion protruding toward the second member and at least one second protrusion,
The first protrusion is at least
A first end surface continuous with the first side surface and parallel to the first side surface;
A second end surface which is an end surface opposite to the first end surface;
The first end surface and the second end surface are configured by a first connecting portion that connects end portions on the distal end side of the first projecting portion,
The first connecting portion has a first inclined portion;
The first inclined portion forms an acute angle with the first end surface;
The second protrusion is at least
A third end face formed on the first end face side and parallel to the first end face;
A fourth end surface that is an end surface opposite to the third end surface;
The third end surface and the fourth end surface are configured by a second connecting portion that connects end portions on the distal end side of the second projecting portion,
The second connecting part has a second inclined part,
The second inclined portion forms an acute angle with the fourth end surface;
The second member has a third side surface that is a side surface parallel to the layer in the electrode body, and a fourth side surface that is a side surface opposite to the third side surface, respectively.
The third side surface is formed on the same side as the first side surface, and the fourth side surface is formed on the same side as the second side surface,
The second member is continuous with the first member directly or through the uncoated portion forming the current collector,
The second member is formed with a third protrusion that protrudes toward the first member, and at least one fourth protrusion.
The third protrusion is at least
A fifth end surface that is continuous with the fourth side surface and parallel to the fourth side surface;
A sixth end surface which is an end surface opposite to the fifth end surface;
The fifth end surface and the sixth end surface are configured by a third connecting portion that connects end portions on the distal end side of the third projecting portion,
The third connecting portion has a third inclined portion;
The third inclined portion forms an acute angle with the fifth end surface;
The fourth protrusion is at least
A seventh end surface formed on the fifth end surface side and parallel to the fifth end surface;
An eighth end surface which is an end surface opposite to the seventh end surface;
The seventh end surface and the eighth end surface are constituted by a fourth connecting portion that connects end portions on the distal end side of the second projecting portion,
The fourth connecting portion has a fourth inclined portion,
The fourth inclined portion forms an acute angle with the eighth end surface;
In the stacking direction, the first protrusion, the fourth protrusion, and the second protrusion are sequentially disposed from the first end face side.
In the stacking direction, the third protrusion, the second protrusion, and the fourth protrusion are sequentially arranged from the second end face side,
Between the first protrusion and the fourth protrusion, between the second protrusion and the fourth protrusion, and between the second protrusion and the third protrusion, The uncoated parts constituting the electrical parts are each divided and arranged in a plurality of bundles,
Arranged on the first base end side, which is the base end of the first protrusion and the second protrusion, of the edge of the uncoated part forming the current collector in the direction perpendicular to the stacking direction The first edge portion is inclined toward the second base end portion side which is the base end portion of the third protrusion portion and the fourth protrusion portion, and among the edge portions of the uncoated portion, The power storage device, wherein a second edge portion arranged on the second base end side is inclined toward the first base end side.
前記第2突起部には、前記第3端面と前記第4端面とを繋ぎ、かつ前記電極体側に形成される第1下面と、前記第1下面とは反対側の第1上面が形成され、
前記第2突起部の先端部には、前記第1下面と前記第1上面とを連続する第5傾斜面が形成され、
前記第5傾斜面は、前記第1下面又は前記第1上面となす角度が鋭角であり、
前記第4突起部には、前記第7端面と前記第8端面とを繋ぎ、かつ前記電極体側に形成される第2下面と、前記第2下面とは反対側の第2上面が形成され、
前記第4突起部の先端部には、前記第2下面と前記第2上面とを連続する第6傾斜面が形成され、
前記第6傾斜面は、前記第2下面又は前記第2上面となす角度が鋭角であることを特徴とする請求項8に記載の蓄電装置。
The second protrusion is formed with a first lower surface that connects the third end surface and the fourth end surface and is formed on the electrode body side, and a first upper surface opposite to the first lower surface,
A fifth inclined surface that continues the first lower surface and the first upper surface is formed at the tip of the second protrusion,
The fifth inclined surface has an acute angle with the first lower surface or the first upper surface,
The fourth protrusion is formed with a second lower surface that connects the seventh end surface and the eighth end surface and is formed on the electrode body side, and a second upper surface opposite to the second lower surface,
A sixth inclined surface that is continuous with the second lower surface and the second upper surface is formed at the tip of the fourth protrusion,
The power storage device according to claim 8, wherein an angle formed between the sixth inclined surface and the second lower surface or the second upper surface is an acute angle.
前記蓄電装置は、二次電池であることを特徴とする請求項1〜請求項9のいずれか1項に記載の蓄電装置。   The power storage device according to claim 1, wherein the power storage device is a secondary battery. 請求項1〜10のいずれか1項に記載の蓄電装置を搭載したことを特徴とする車両。   A vehicle comprising the power storage device according to any one of claims 1 to 10.
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