JP2013216639A - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
- Publication number
- JP2013216639A JP2013216639A JP2012090926A JP2012090926A JP2013216639A JP 2013216639 A JP2013216639 A JP 2013216639A JP 2012090926 A JP2012090926 A JP 2012090926A JP 2012090926 A JP2012090926 A JP 2012090926A JP 2013216639 A JP2013216639 A JP 2013216639A
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- shampoo composition
- mass ratio
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000002453 shampoo Substances 0.000 title claims abstract description 38
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 29
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 13
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 12
- 125000005702 oxyalkylene group Chemical group 0.000 claims abstract description 11
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 10
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 10
- 125000006353 oxyethylene group Chemical group 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 4
- 150000004665 fatty acids Chemical group 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 125000002252 acyl group Chemical group 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 7
- 238000005886 esterification reaction Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 abstract description 22
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 210000002374 sebum Anatomy 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 3
- 150000005846 sugar alcohols Polymers 0.000 abstract description 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 125000005313 fatty acid group Chemical group 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 38
- -1 polyoxyethylene Polymers 0.000 description 25
- 230000003750 conditioning effect Effects 0.000 description 20
- 235000014113 dietary fatty acids Nutrition 0.000 description 20
- 239000000194 fatty acid Substances 0.000 description 20
- 229930195729 fatty acid Natural products 0.000 description 20
- 239000003921 oil Substances 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 238000005354 coacervation Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 229920001223 polyethylene glycol Polymers 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- 235000001014 amino acid Nutrition 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000003240 coconut oil Substances 0.000 description 7
- 235000019864 coconut oil Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000010696 ester oil Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 241000282320 Panthera leo Species 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 239000000213 tara gum Substances 0.000 description 3
- 235000010491 tara gum Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- SIOLDWZBFABPJU-UHFFFAOYSA-N isotridecanoic acid Chemical compound CC(C)CCCCCCCCCC(O)=O SIOLDWZBFABPJU-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- ISYWECDDZWTKFF-UHFFFAOYSA-N nonadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(O)=O ISYWECDDZWTKFF-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 230000003381 solubilizing effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
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- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
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- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、皮脂や整髪料に由来する汚れを効果的に除去することができ、洗髪時の泡質に優れ、すすぎ時および乾燥後の滑らかさが良好なシャンプー組成物に関する。 The present invention relates to a shampoo composition that can effectively remove dirt derived from sebum and hair dressing, is excellent in foam quality at the time of shampooing, and has good smoothness after rinsing and after drying.
シャンプーには、皮脂や整髪料を除去する洗浄力のほか、きめ細かな泡を形成させて摩擦による毛髪損傷を低減させることや、すすぎ時および乾燥後の感触を改善させるコンディショニング効果が求められる。近年、消費者のヘアスタイルに対するニーズの多様化により、皮膜性ポリマーやロウ類などの親油性の高い油剤を配合した整髪料の使用が増えており、シャンプーによる洗髪ではこれら油剤を除去し難いという問題点がある。シャンプーの洗浄力を向上させて、これら油剤を除去するために、界面活性剤を高濃度に配合することも考えられるが、この場合、すすぎ時にきしみが生じたり、乾燥後にパサつく場合がある。そこで、従来のシャンプーでは、コンディショニング成分としてカチオン性高分子を配合し、これとアニオン性界面活性剤、両性界面活性剤から形成される複合体が析出するコアセルベーション現象によって、すすぎ時および乾燥後の滑らかさを付与している。そのため、シャンプー処方ではこの複合体の生成量や生成領域を制御することが重要となる。 The shampoo is required to have a cleaning effect for removing sebum and hair dressing, as well as a conditioning effect to form fine bubbles to reduce hair damage due to friction and to improve the feel after rinsing and after drying. In recent years, with the diversification of consumer needs for hairstyles, the use of hair styling that contains highly lipophilic oils such as film polymers and waxes has increased, and it is difficult to remove these oils by washing with shampoo. There is a problem. In order to improve the detergency of the shampoo and remove these oils, it is conceivable to add a surfactant at a high concentration. In this case, however, squeaking may occur during rinsing or it may become dry after drying. Therefore, in conventional shampoos, a cationic polymer is blended as a conditioning component, and a coacervation phenomenon in which a complex formed from this, an anionic surfactant, and an amphoteric surfactant precipitates. Of smoothness. Therefore, in the shampoo formulation, it is important to control the production amount and production area of this complex.
非特許文献1では、無機塩を添加することによってコアセルベーション形成領域が拡大することが記載されているが、無機塩を配合すると泡量が減少したり、泡質が悪化するといった問題点があった。 Non-Patent Document 1 describes that the coacervation forming region is expanded by adding an inorganic salt. However, when an inorganic salt is added, there is a problem that the amount of foam decreases or the foam quality deteriorates. there were.
こうした状況を鑑み、特許文献1には、イオン性界面活性剤、カチオン化タラガム、ポリオキシエチレン(7)ヤシ油脂肪酸グリセリンを配合することで、すすぎ時の希釈された領域でもコアセルベーション現象により多量の複合体を生成し、すすぎ時の指通り性に優れ、乾燥後もパサつかず、まとまりが良好なシャンプー組成物が開示されている。しかしながら、この組成物は、親油性の高い油剤を配合した整髪料に対する洗浄力が十分ではなく、洗髪時の泡質についても十分満足できるものではなかった。 In view of such a situation, Patent Document 1 includes an ionic surfactant, cationized tara gum, polyoxyethylene (7) coconut oil fatty acid glycerin, and even in a diluted region at the time of rinsing, due to the coacervation phenomenon. Disclosed is a shampoo composition that produces a large amount of a complex, is excellent in fingering properties during rinsing, does not feel dry even after drying, and has a good unity. However, this composition does not have sufficient detergency for a hair styling compounded with a highly lipophilic oil agent, and the foam quality during shampooing is not satisfactory.
また、特許文献2には、両性界面活性剤、アニオン性界面活性剤、カチオン性ポリマー、多価アルコール、ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン、テトラオレイン酸ポリオキシエチレン(60)ソルビットを配合し、泡質が良好で、洗浄後の毛髪にハリ、コシを付与できるシャンプー組成物が開示されている。しかしながら、この組成物は、洗髪時およびすすぎ時の感触が不十分で、洗浄力も十分満足できるものではなかった。
このように、親油性の高い油剤を配合した整髪料を効果的に除去することができ、洗髪時の泡質に優れ、コンディショニング効果が良好な、言い換えれば、すすぎ時および乾燥後の滑らかさが良好なシャンプー組成物の開発には至っていなかった。
Patent Document 2 contains amphoteric surfactant, anionic surfactant, cationic polymer, polyhydric alcohol, polyoxyethylene (7) coconut oil fatty acid glycerin, tetraoleic acid polyoxyethylene (60) sorbit However, a shampoo composition having good foam quality and capable of imparting firmness and stiffness to the washed hair is disclosed. However, this composition has an insufficient feel during shampooing and rinsing, and the cleaning power is not sufficiently satisfactory.
In this way, it is possible to effectively remove hair styling blended with a highly lipophilic oil agent, excellent foam quality at the time of shampooing, good conditioning effect, in other words, smoothness after rinsing and after drying A good shampoo composition has not been developed.
本発明は、上記事情に鑑み、皮脂や整髪料に由来する汚れを効果的に除去することができ、洗髪時の泡質に優れ、すすぎ時および乾燥後の滑らかさが良好なシャンプー組成物を提供することを目的とする。 In view of the above circumstances, the present invention is a shampoo composition that can effectively remove dirt derived from sebum and hair dressing, has excellent foam quality during shampooing, and has good smoothness after rinsing and after drying. The purpose is to provide.
本発明者らは、上記課題を解決するために鋭意検討した結果、シャンプー組成物に特定のアルキレンオキシド誘導体を所定の割合で配合することにより、コアセルベーション形成が促進され、良好なコンディショニング効果が得られると共に、洗浄力、泡質も向上できることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have promoted the formation of coacervation by adding a specific alkylene oxide derivative to the shampoo composition at a predetermined ratio, and have a good conditioning effect. As a result, it was found that the detergency and foam quality could be improved, and the present invention was completed.
すなわち、本発明は以下に示されるシャンプー組成物である。
下記の成分(A)を3〜30質量%、成分(B)を0.5〜20質量%、成分(C)を0.05〜5質量%、成分(D)を0.5〜15質量%、成分(E)を0.1〜10質量%含有し、成分(D)/成分(A)の質量比が0.08〜0.9であり、成分(D)/成分(E)の質量比が0.5〜8であることを特徴とするシャンプー組成物;
(A)アニオン性界面活性剤、
(B)両性界面活性剤、
(C)カチオン性高分子、
(D)下記一般式(1)で示されるアルキレンオキシド誘導体、
(E)アルカリ金属の無機塩。
That is, this invention is a shampoo composition shown below.
The following component (A) is 3 to 30% by mass, component (B) is 0.5 to 20% by mass, component (C) is 0.05 to 5% by mass, and component (D) is 0.5 to 15% by mass. %, Component (E) is contained in an amount of 0.1 to 10% by mass, the mass ratio of component (D) / component (A) is 0.08 to 0.9, and component (D) / component (E) A shampoo composition having a mass ratio of 0.5 to 8;
(A) an anionic surfactant,
(B) an amphoteric surfactant,
(C) a cationic polymer,
(D) an alkylene oxide derivative represented by the following general formula (1):
(E) An inorganic salt of an alkali metal.
一般式(1)においてオキシアルキレン基の合計に占めるオキシエチレン基の質量比率が100質量%であることが好ましく、成分(A)が、アシル基の炭素数が8〜18であるN−アシルアミノ酸型のアニオン性界面活性剤であることが好ましい。 In the general formula (1), the mass ratio of the oxyethylene group to the total of the oxyalkylene groups is preferably 100% by mass, and the component (A) is an N-acylamino acid whose acyl group has 8 to 18 carbon atoms. The anionic surfactant of the type is preferred.
本発明のシャンプー組成物によれば、皮脂や整髪料に由来する汚れを効果的に除去することができ、洗髪時の泡質に優れ、すすぎ時および乾燥後の滑らかさが良好であるという効果が得られる。 According to the shampoo composition of the present invention, dirt derived from sebum and hair conditioner can be effectively removed, the foam quality during hair washing is excellent, and the smoothness after rinsing and after drying is good. Is obtained.
以下、本発明の実施形態について説明する。本発明のシャンプー組成物は下記の成分(A)〜(E)を含有する。以下、各成分について説明する。 Hereinafter, embodiments of the present invention will be described. The shampoo composition of the present invention contains the following components (A) to (E). Hereinafter, each component will be described.
〔(A)アニオン性界面活性剤〕
成分(A)は、アニオン性界面活性剤であり、シャンプー組成物に起泡力や洗浄力を付与するために配合される。
アニオン性界面活性剤としては、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、アルキルアミドエーテル硫酸塩、ポリオキシエチレンアミドエーテル硫酸塩、ポリオキシエチレンアルキルエーテル酢酸塩、アルキル燐酸塩、ポリオキシエチレンアルキルエーテルリン酸塩、α−オレフィンスルホン酸塩、高級脂肪酸塩、N−アシルアミノ酸塩、N−アシルイセチオン酸塩、N−アシルメチルタウリン塩、N−アシルポリペプチド塩、アルキルスルホコハク酸塩等が挙げられる。これらの中でも、アルキル硫酸エステル塩、ポリオキシエチレンアルキルエーテル硫酸塩、N−アシルアミノ酸塩が好ましく、更に好ましくはN−アシルアミノ酸塩である。これらの塩を構成する対イオンとしては、アルカリ金属イオン、アルカリ土類金属イオン、アンモニウムイオン、アルカノールアミンイオン、アミノ酸イオン等が挙げられる。これらアニオン性界面活性剤におけるアルキル基またはアシル基は、洗浄力や起泡力の観点から、炭素数が10〜18であることが好ましく、更に好ましくは12〜14である。
[(A) Anionic surfactant]
Component (A) is an anionic surfactant and is blended to impart foaming power and detergency to the shampoo composition.
Anionic surfactants include alkyl sulfates, polyoxyethylene alkyl ether sulfates, alkyl amide ether sulfates, polyoxyethylene amide ether sulfates, polyoxyethylene alkyl ether acetates, alkyl phosphates, polyoxyethylene alkyls. Examples include ether phosphate, α-olefin sulfonate, higher fatty acid salt, N-acyl amino acid salt, N-acyl isethionate, N-acylmethyl taurate, N-acyl polypeptide salt, alkylsulfosuccinate. . Among these, alkyl sulfate ester salts, polyoxyethylene alkyl ether sulfates, and N-acyl amino acid salts are preferable, and N-acyl amino acid salts are more preferable. Examples of counter ions constituting these salts include alkali metal ions, alkaline earth metal ions, ammonium ions, alkanolamine ions, and amino acid ions. The alkyl group or acyl group in these anionic surfactants preferably has 10 to 18 carbon atoms, more preferably 12 to 14 carbon atoms from the viewpoint of detergency and foaming power.
更に、(A)成分として、N−アシルアミノ酸型のアニオン性界面活性剤を使用することで、すすぎ時の指通りや乾燥後の滑らかさを更に改善することができる。N−アシルアミノ酸型界面活性剤としては、例えば、グリシン、アラニン、N−メチルアラニン、サルコシン、グルタミン酸、アスパラギン酸のアシル化物の塩を用いることができる。これらの塩を構成する対イオンとしては、アルカリ金属イオン、アルカリ土類金属イオン、アンモニウムイオン、アルカノールアミンイオン、アミノ酸イオン等が挙げられる。アシル基の炭素数は8〜18であることが好ましく、洗浄力や起泡力の観点から12〜18であることが特に好ましく、更に好ましくは12〜14である。また、混合脂肪酸由来のアシル基を用いることができ、混合脂肪酸としては、ヤシ油脂肪酸、パーム核油脂肪酸などが挙げられる。アシル基として好ましくは、ラウロイル基、ミリストイル基、ヤシ油脂肪酸アシル基、パーム核油脂肪酸アシル基などが挙げられる。N−アシルアミノ酸型のアニオン性界面活性剤の具体例としては、PEG(2)ウラリルエーテル硫酸ナトリウム、ラウロイルメチル−β−アラニンナトリウムなどが挙げられる。なお、PEG(2)ウラリルエーテル硫酸ナトリウムにおけるPEGはポリエチレングリコールを表わし、(2)はオキシエチレン基の平均付加モル数が2であることを表わす(以下、同様)。 Further, by using an N-acylamino acid type anionic surfactant as the component (A), the smoothness after rinsing and after drying can be further improved. As an N-acyl amino acid type surfactant, for example, a salt of an acylated product of glycine, alanine, N-methylalanine, sarcosine, glutamic acid, or aspartic acid can be used. Examples of counter ions constituting these salts include alkali metal ions, alkaline earth metal ions, ammonium ions, alkanolamine ions, and amino acid ions. The acyl group preferably has 8 to 18 carbon atoms, particularly preferably 12 to 18 carbon atoms, and more preferably 12 to 14 carbon atoms from the viewpoint of detergency and foaming power. Moreover, the acyl group derived from a mixed fatty acid can be used, and examples of the mixed fatty acid include coconut oil fatty acid and palm kernel oil fatty acid. Preferred examples of the acyl group include lauroyl group, myristoyl group, coconut oil fatty acid acyl group, and palm kernel oil fatty acid acyl group. Specific examples of the N-acyl amino acid type anionic surfactant include PEG (2) sodium lauryl ether sulfate, sodium lauroylmethyl-β-alanine, and the like. In addition, PEG in PEG (2) lauryl ether sodium sulfate represents polyethylene glycol, and (2) represents that the average number of added moles of oxyethylene groups is 2 (the same applies hereinafter).
成分(A)は、シャンプー組成物全量に対して、3〜30質量%、好ましくは5〜20質量%、更に好ましくは7〜15質量%の割合で含まれる。3質量%未満の場合は、洗浄力や泡質、すすぎ時および乾燥後の感触が不十分となり、30質量%を超えると、すすぎ時および乾燥後の感触が悪化することがある。(A)成分は1種単独で用いてもよいし、または2種以上を併用してもよい。 The component (A) is contained in a proportion of 3 to 30% by mass, preferably 5 to 20% by mass, and more preferably 7 to 15% by mass with respect to the total amount of the shampoo composition. When the amount is less than 3% by mass, the detergency and foam quality, and the feeling after rinsing and after drying become insufficient. When the amount exceeds 30% by mass, the feeling after rinsing and after drying may be deteriorated. (A) A component may be used individually by 1 type or may use 2 or more types together.
〔(B)両性界面活性剤〕
成分(B)は、両性界面活性剤であり、成分(A)と併用することで洗浄力や泡質を向上させる効果がある。
両性界面活性剤としては、アルキルベタイン、アルキルアミドベタイン、アルキルヒドロシキシスルホベタイン、アルキルアミドヒドロキシスルホベタイン、アルキルカルボキシメチルヒドロキシエチルイミダゾリニウムベタイン、アルキルアミドヒドロキシエチルアミノ酸型両性界面活性剤、アルキルイミノジ酢酸塩等が挙げられる。アルキル基またはアシル基の炭素数は、洗浄力や起泡力の観点から、10〜18であることが好ましく、更に好ましくは12〜14である。また、アシル基として、ヤシ油脂肪酸などの混合脂肪酸由来のアシル基を用いることができる。両性界面活性剤の具体例としては、ラウリルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、パーム核油脂肪酸アミドプロピルベタイン、ラウリルヒドロキシスルホベタインなどが挙げられる。
[(B) Amphoteric surfactant]
Component (B) is an amphoteric surfactant and has the effect of improving detergency and foam quality when used in combination with component (A).
Amphoteric surfactants include alkylbetaines, alkylamidobetaines, alkylhydroxysulfobetaines, alkylamidohydroxysulfobetaines, alkylcarboxymethylhydroxyethylimidazolinium betaines, alkylamidohydroxyethyl amino acid type amphoteric surfactants, alkyliminos. Examples thereof include diacetate. The number of carbon atoms of the alkyl group or acyl group is preferably 10-18, more preferably 12-14, from the viewpoints of detergency and foaming power. Further, as the acyl group, an acyl group derived from a mixed fatty acid such as coconut oil fatty acid can be used. Specific examples of the amphoteric surfactant include lauryl betaine, coconut oil fatty acid amidopropyl betaine, palm kernel oil fatty acid amidopropyl betaine, and lauryl hydroxysulfobetaine.
成分(B)は、シャンプー組成物全量に対して、0.5〜20質量%、好ましくは1〜15質量%、更に好ましくは2〜10質量%の割合で含まれる。0.5質量%未満の場合は、洗浄力や泡質が不十分であり、20質量%を越えると、すすぎ時の指通りが低下することがある。成分(B)は1種単独で用いてもよいし、または2種以上を併用してもよい。 Component (B) is included in a proportion of 0.5 to 20% by mass, preferably 1 to 15% by mass, and more preferably 2 to 10% by mass, based on the total amount of the shampoo composition. When the amount is less than 0.5% by mass, the detergency and foam quality are insufficient, and when it exceeds 20% by mass, the fingering during rinsing may decrease. A component (B) may be used individually by 1 type, or may use 2 or more types together.
〔(C)カチオン性高分子〕
成分(C)は、カチオン性高分子であり、すすぎ時の指通りや乾燥後の滑らかさを向上させるために配合される。成分(C)は、成分(A)および(B)の混合ミセルと複合体を形成し、すすぎ時の希釈によって系内から析出(コアセルベーション現象)し、これが毛髪に吸着することで、すすぎ時の指通りや乾燥後の滑らかさを向上させるコンディショニング効果を付与する。
[(C) Cationic polymer]
Ingredient (C) is a cationic polymer, and is blended in order to improve the smoothness after fingering and after rinsing. Component (C) forms a complex with the mixed micelles of components (A) and (B), and precipitates from the system (coacervation phenomenon) due to dilution during rinsing, and this is adsorbed to the hair, thereby rinsing Gives a conditioning effect that improves smoothness after fingering and drying.
カチオン性高分子としては、例えば、ジアルキルジアリルアンモニウムクロリドのホモポリマー、ジアルキルジアリルアンモニウムクロリドと(メタ)アクリレートとの共重合体、ジアルキルジアリルアンモニウムクロリドと(メタ)アクリレートエステルとの共重合体、ジアルキルジアリルアンモニウムクロリドと(メタ)アクリルアミドとの共重合体、ポリ塩化メタクリロイルオキシエチルトリメチルアンモニウムクロリド、カチオン化セルロース、カチオン化澱粉、カチオン化グアーガム、カチオン化タラガム、カチオン化ローカストビーンガム、カチオン化キサンタンガム、カチオン化フェヌグリークガム、カチオン化キサンタンガム、ビニルイミダゾリニウムトリクロリドとビニルピロリドンとの共重合体、ヒドロキシエチエルセルロースとジメチルジアリルアンモニウムクロリドとの共重合体、ビニルピロリドンとジメチルアミノエチルメタクリレートとの共重合体、ポリビニルピロリドンとアルキルアミノアクリレートとビニルカプロラクタムとの共重合体、ビニルピロリドンとメタクリロイルアミドプロピルトリメチルアンモニウムクロリドとの共重合体、アルキルアクリルアミドとアクリレートとアルキルアミノアルキルアクリルアミドとポリエチレングリコールメタクリレートとの共重合体、アジピン酸とジメチルアミノヒドロキシプロピルエチレントリアミンとの共重合体等が挙げられ、特にカチオン化セルロース、カチオン化グアーガム、カチオン化タラガム、ジアルキルジアリルアンモニウムクロリドのホモポリマー、ジアルキルジアリルアンモニウムクロリドと(メタ)アクリルアミドとの共重合体が好ましい。なお、(メタ)アクリレートはメタクリレートまたはアクリレートを表わし、(メタ)アクリルはメタクリルまたはアクリルを表わす。 Examples of the cationic polymer include a homopolymer of dialkyl diallylammonium chloride, a copolymer of dialkyl diallylammonium chloride and (meth) acrylate, a copolymer of dialkyl diallylammonium chloride and (meth) acrylate ester, and dialkyl diallyl. Copolymer of ammonium chloride and (meth) acrylamide, polychlorinated methacryloyloxyethyltrimethylammonium chloride, cationized cellulose, cationized starch, cationized guar gum, cationized tara gum, cationized locust bean gum, cationized xanthan gum, cationized Fenugreek gum, cationized xanthan gum, copolymer of vinyl imidazolinium trichloride and vinyl pyrrolidone, hydroxyethyl Copolymers of rose and dimethyldiallylammonium chloride, copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, copolymers of polyvinylpyrrolidone, alkylaminoacrylate and vinylcaprolactam, vinylpyrrolidone and methacryloylamidopropyltrimethylammonium chloride Copolymer of alkylacrylamide, acrylate, alkylaminoalkylacrylamide and polyethylene glycol methacrylate, copolymer of adipic acid and dimethylaminohydroxypropylethylenetriamine, etc., especially cationized cellulose, cationized Guar gum, cationized tara gum, homopolymer of dialkyl diallylammonium chloride, dialkyl diallylammonium Copolymers of Rorido and (meth) acrylamide is preferable. (Meth) acrylate represents methacrylate or acrylate, and (meth) acryl represents methacryl or acryl.
カチオン性高分子のカチオン化度は、例えばケルダール法等の窒素含有率の測定値から計算することができ、0.2〜3質量%であることが好ましく、更に好ましくは0.5〜2質量%である。カチオン性高分子の重量平均分子量は、ゲル浸透クロマトグラフィー(GPC)を用いて測定することができ、10万〜300万の範囲が好ましく、より好ましくは40万〜200万の範囲である。 The degree of cationization of the cationic polymer can be calculated from a measured value of nitrogen content such as Kjeldahl method, and is preferably 0.2 to 3% by mass, more preferably 0.5 to 2% by mass. %. The weight average molecular weight of the cationic polymer can be measured using gel permeation chromatography (GPC), preferably in the range of 100,000 to 3,000,000, more preferably in the range of 400,000 to 2,000,000.
このようなカチオン性高分子の具体例としては、レオガードLP・GP・MGP(ライオン(株)製)、UCARELR−30M・JR−400・JR−30M(ダウケミカル(株)製)、ラボールガムCG−M・CG−M7・CG−M8M(大日本住友製薬(株)製)、N−Hance3000(ハーキュレス・ジャパン(株)製)などが挙げられる。成分(C)は1種単独で用いてもよいし、または2種以上を併用してもよい。 Specific examples of such a cationic polymer include Leogard LP • GP • MGP (manufactured by Lion Corporation), UCARERL-30M • JR-400 • JR-30M (manufactured by Dow Chemical Co., Ltd.), Labor Gum CG- M-CG-M7 / CG-M8M (Dainippon Sumitomo Pharma Co., Ltd.), N-Hance 3000 (Hercules Japan Co., Ltd.), etc. are mentioned. A component (C) may be used individually by 1 type, or may use 2 or more types together.
成分(C)は、シャンプー組成物全量に対して、0.05〜5質量%、好ましくは0.1〜2質量%、更に好ましくは0.2〜1質量%の割合で含まれる。0.05質量%未満であると、コアセルベーション現象が生じず、コンディショニング効果が得られないことがあり、5質量%を超えると、ごわつく場合がある。 Component (C) is included in a proportion of 0.05 to 5% by mass, preferably 0.1 to 2% by mass, more preferably 0.2 to 1% by mass, based on the total amount of the shampoo composition. If it is less than 0.05% by mass, the coacervation phenomenon does not occur, and the conditioning effect may not be obtained. If it exceeds 5% by mass, it may be stiff.
〔(D)アルキレンオキシド誘導体〕
成分(D)は、下記一般式(1)で示されるアルキレンオキシド誘導体であり、成分(A)のアニオン性界面活性剤と成分(C)のカチオン性高分子の凝集を促進し、コアセルベーション現象を促進することで、すすぎ時の指どおりや乾燥後の滑らかさを向上させる。また、成分(D)を配合することで、泡立て時に泡膜からの水の排液を抑制し、泡量や泡質を改善する。更に、成分(D)は油性成分に対する乳化や可溶化力が高く、洗浄力を向上させる効果がある。
[(D) alkylene oxide derivative]
Component (D) is an alkylene oxide derivative represented by the following general formula (1), which promotes aggregation of the anionic surfactant of component (A) and the cationic polymer of component (C), and provides coacervation. By promoting the phenomenon, smoothness after rinsing and after drying is improved. Moreover, by mix | blending a component (D), the drainage of the water from a foam film is suppressed at the time of foaming, and the amount of foams and foam quality are improved. Furthermore, the component (D) has a high emulsification and solubilizing power with respect to the oil component, and has an effect of improving the cleaning power.
式(1)中、Zは炭素数が2以上であり、2〜9個の水酸基を有する化合物の全ての水酸基を除いた残基である。炭素数が2以上であり、2〜9個の水酸基を有する化合物(以下、水酸基含有化合物ともいう。)としては、水酸基の数が2であればジエチレングリコール、水酸基の数が3であればグリセリン、トリメチロールプロパン、ヘキシレングリコール、水酸基の数が4であればエリスリトール、ペンタエリスリトール、ソルビタン、アルキルグリコシド、水酸基の数が5であればキシリトール、水酸基の数が6であればジペンタエリスリトール、ソルビトール、イノシトール、水酸基の数が8であればショ糖、トレハロース、水酸基の数が9であればマルチトールが挙げられる。一般式(1)で示されるアルキレンオキシド誘導体を調製するに際しては、上記の水酸基含有化合物を1種単独で用いてもよいし、または2種以上を含む混合物を用いてもよい。 In the formula (1), Z is a residue having 2 or more carbon atoms and excluding all hydroxyl groups of the compound having 2 to 9 hydroxyl groups. A compound having 2 or more carbon atoms and having 2 to 9 hydroxyl groups (hereinafter also referred to as a hydroxyl group-containing compound) is diethylene glycol if the number of hydroxyl groups is 2, and glycerin if the number of hydroxyl groups is 3. Trimethylolpropane, hexylene glycol, erythritol, pentaerythritol, sorbitan, alkylglycoside if the number of hydroxyl groups is 4, xylitol if the number of hydroxyl groups is 5, dipentaerythritol, sorbitol, if the number of hydroxyl groups is 6, Inositol, if the number of hydroxyl groups is 8, sucrose, trehalose, if the number of hydroxyl groups is 9, maltitol is mentioned. In preparing the alkylene oxide derivative represented by the general formula (1), the above hydroxyl group-containing compound may be used alone, or a mixture containing two or more kinds may be used.
xはZを構成する水酸基含有化合物の水酸基の数であり、2〜9であり、好ましくは3〜7、更に好ましくは5〜7である。xが1では、泡質改善や良好なコンディショニング効果が得られず、xが10以上ではべたつき感が生じることがある。 x is the number of hydroxyl groups of the hydroxyl group-containing compound constituting Z, and is 2 to 9, preferably 3 to 7, and more preferably 5 to 7. When x is 1, foam quality improvement and good conditioning effect cannot be obtained, and when x is 10 or more, stickiness may occur.
AOは炭素数2または3のオキシアルキレン基であり、オキシエチレン(EO)基、オキシプロピレン(PO)基が挙げられる。AOが2種の場合、AOの付加形態はブロック状が好ましい。また、Zに対してEO−POの順に付加したZ−O−EO−PO−の形態でも、PO−EOの順に付加したZ−O−PO−EO−の形態でもよいが、Z−O−EO−PO−の形態が好ましい。 AO is an oxyalkylene group having 2 or 3 carbon atoms, and examples thereof include an oxyethylene (EO) group and an oxypropylene (PO) group. When two kinds of AO are used, the addition form of AO is preferably a block form. Moreover, the form of Z—O—EO—PO— added to Z in the order of EO—PO or the form of Z—O—PO—EO— added in the order of PO—EO may be used. The form of EO-PO- is preferred.
オキシアルキレン基の合計に占めるオキシエチレン基の質量比率は50〜100質量%であり、好ましくは80〜100質量%である。50質量%以下であると泡質改善効果やコンディショニング効果が低下する。かかる質量比率は100質量%であることが更に好ましく、この場合、コアセルベーション促進効果が最も高くなり、すすぎ時の指通りや乾燥後の滑らかさが更に向上する。 The mass ratio of the oxyethylene group to the total of the oxyalkylene groups is 50 to 100% by mass, preferably 80 to 100% by mass. When it is 50% by mass or less, the foam quality improving effect and the conditioning effect are lowered. The mass ratio is more preferably 100% by mass. In this case, the coacervation promoting effect is the highest, and the smoothness after fingering and drying after rinsing is further improved.
mはオキシアルキレン基の平均付加モル数であり、水酸基当たりのオキシアルキレン基の平均付加モル数m/xが5〜20であり、好ましくは5〜15であり、更に好ましくは7〜12である。m/xが5未満であると泡質が低下し、十分なコンディショニング効果も得られず、m/xが20を超えるとコンディショニング効果が低下することがある。 m is the average addition mole number of the oxyalkylene group, and the average addition mole number m / x of the oxyalkylene group per hydroxyl group is 5 to 20, preferably 5 to 15 and more preferably 7 to 12. . When m / x is less than 5, the foam quality is deteriorated and a sufficient conditioning effect cannot be obtained. When m / x exceeds 20, the conditioning effect may be lowered.
Rは炭素数8〜22の脂肪酸残基または水素原子である。Rを構成する脂肪酸の炭素数は8〜22であり、飽和脂肪酸、不飽和脂肪酸、分岐脂肪酸およびヒドロキシル基置換脂肪酸などが用いられる。
脂肪酸としては、例えば、カプリル酸、ノナン酸、デカン酸、ラウリン酸、トリデカン酸、イソトリデカン酸、ミリスチン酸、ペンタデカン酸、パルミチン酸、ヘプタデカン酸、ステアリン酸、ノナデカン酸、ベヘン酸、ドデセン酸、テトラデセン酸、ヘキサデセン酸、パルミトオレイン酸、オレイン酸、バクセン酸、リノール酸、リノレン酸、アラキドン酸、イソステアリン酸、ヒドロキシステアリン酸などが挙げられ、なかでもラウリン酸、イソステアリン酸、オレイン酸が好ましい。一般式(1)で示されるアルキレンオキシド誘導体を調製するに際しては、これら脂肪酸を1種単独で用いてもよいし、または2種以上を用いてもよい。
R is a fatty acid residue having 8 to 22 carbon atoms or a hydrogen atom. The fatty acid constituting R has 8 to 22 carbon atoms, and saturated fatty acid, unsaturated fatty acid, branched fatty acid, hydroxyl group-substituted fatty acid and the like are used.
Examples of fatty acids include caprylic acid, nonanoic acid, decanoic acid, lauric acid, tridecanoic acid, isotridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, heptadecanoic acid, stearic acid, nonadecanoic acid, behenic acid, dodecenoic acid, tetradecenoic acid Hexadecenoic acid, palmitooleic acid, oleic acid, vaccenic acid, linoleic acid, linolenic acid, arachidonic acid, isostearic acid, hydroxystearic acid and the like, among which lauric acid, isostearic acid and oleic acid are preferred. In preparing the alkylene oxide derivative represented by the general formula (1), these fatty acids may be used alone or in combination of two or more.
このようなアルキレンオキシド誘導体としては、テトラオレイン酸PEG(60)ソルビット、テトラオレイン酸PEG(40)ソルビット、トリラウリン酸PEG(40)ソルビット、トリイソステアリン酸PEG(30)グリセリル、ジオレイン酸PEG(23)などが挙げられる。成分(D)は1種単独で用いてもよいし、または2種以上を併用してもよい。 Examples of such alkylene oxide derivatives include tetraoleate PEG (60) sorbite, tetraoleate PEG (40) sorbite, trilaurate PEG (40) sorbite, triisostearate PEG (30) glyceryl, and dioleate PEG (23). Etc. A component (D) may be used individually by 1 type, or may use 2 or more types together.
一般式(1)で示されるアルキレンオキシド誘導体のエステル化率は40〜90%であり、好ましくは50〜85%、更に好ましくは60〜80%である。40%未満であると十分な洗浄力が得られず、90%を超えてもコンディショニング効果が低下する場合がある。 The esterification rate of the alkylene oxide derivative represented by the general formula (1) is 40 to 90%, preferably 50 to 85%, more preferably 60 to 80%. If it is less than 40%, sufficient detergency cannot be obtained, and if it exceeds 90%, the conditioning effect may be reduced.
ここでエステル化率とは、一般式(1)中のZを構成する水酸基含有化合物の水酸基の総数のうち脂肪酸がエステル結合している水酸基の数の割合を表し、成分(D)の鹸化価(SV)、水酸基価(OHV)、酸価(AV)を測定し、以下に示す方法にて算出することができる。
エステル化率=[(SV−AV) /(SV−AV+OHV)] ×100
なお、SV、AV、OHVはいずれも日本工業規格(JIS)記載の方法に準拠して測定することができる。
SV; JIS K −0070 4. 1
AV; JIS K −0070 3. 1
OHV; JIS K−1557 1
Here, the esterification rate represents the ratio of the number of hydroxyl groups in which fatty acids are ester-bonded out of the total number of hydroxyl groups of the hydroxyl group-containing compound constituting Z in the general formula (1), and the saponification value of component (D) (SV), hydroxyl value (OHV), and acid value (AV) can be measured and calculated by the following method.
Esterification rate = [(SV-AV) / (SV-AV + OHV)] × 100
SV, AV, and OHV can all be measured according to the method described in Japanese Industrial Standard (JIS).
SV; JIS K-0070 4.1
AV; JIS K-0070 3.1
OHV; JIS K-1557 1
成分(D)は、シャンプー組成物全量に対して、0.5〜15質量%、好ましくは0.5〜10質量%、更に好ましくは0.8〜6質量%の割合で含まれる。0.5質量%未満であると十分な洗浄力、泡質、コンディショニング効果が得られず、15質量%を超えてもコンディショニング効果が低下する場合がある。 Component (D) is included in a proportion of 0.5 to 15% by mass, preferably 0.5 to 10% by mass, and more preferably 0.8 to 6% by mass, based on the total amount of the shampoo composition. If it is less than 0.5% by mass, sufficient detergency, foam quality, and conditioning effect cannot be obtained, and if it exceeds 15% by mass, the conditioning effect may be reduced.
成分(A)と成分(D)の質量比(D)/(A)は、0.08〜0.9であり、好ましくは0.2〜0.8である。質量比がこの範囲内であれば、成分(D)のアルキレンオキシド誘導体のポリオキシアルキレン鎖が系内の電荷を遮蔽することで、コアセルベーション形成を促進し、すすぎ時の指通り、乾燥後の滑らかさを改善し、良好なコンディショニング効果を得ることができる。質量比(D)/(A)が0.08未満であったり、0.9を超えたりしてもコアセルベーション促進能が低下し、コンディショニング効果が低下することがある。 The mass ratio (D) / (A) of the component (A) to the component (D) is 0.08 to 0.9, preferably 0.2 to 0.8. If the mass ratio is within this range, the polyoxyalkylene chain of the alkylene oxide derivative of the component (D) shields the charge in the system, thereby promoting the formation of coacervation. Can improve the smoothness of the film and obtain a good conditioning effect. If the mass ratio (D) / (A) is less than 0.08 or exceeds 0.9, the coacervation promoting ability may be reduced, and the conditioning effect may be reduced.
〔(E)アルカリ金属の無機塩〕
成分(E)は、アルカリ金属の無機塩であり、上記成分(A)、(B)、(C)と組み合わせることでコアセルベーション現象を促進し、すすぎ時の指通りを改善する。
アルカリ金属の無機塩としては、アルカリ金属の塩化物塩、硫酸塩、硝酸塩、およびリン酸塩等が挙げられる。アルカリ金属としては、ナトリウム、カリウム、およびリチウムが挙げられる。具体的には、塩化ナトリウム、塩化カリウム、硫酸ナトリウム、および硫酸カリウムが挙げられる。成分(E)は1種単独で用いてもよいし、または2種以上を併用してもよい。
[(E) Inorganic salt of alkali metal]
Component (E) is an inorganic salt of an alkali metal, and in combination with the components (A), (B), and (C), promotes the coacervation phenomenon and improves fingering during rinsing.
Examples of the alkali metal inorganic salt include alkali metal chloride salts, sulfate salts, nitrate salts, and phosphate salts. Alkali metals include sodium, potassium, and lithium. Specific examples include sodium chloride, potassium chloride, sodium sulfate, and potassium sulfate. A component (E) may be used individually by 1 type, or may use 2 or more types together.
成分(E)は、シャンプー組成物全量に対して、0.1〜10質量%、好ましくは0.2〜5質量%、更に好ましくは0.5〜2質量%の割合で含まれる。0.1質量%未満であるとすすぎ時の指通りが低下し、10質量%を超えると泡質が悪化することがある。 Component (E) is contained in a proportion of 0.1 to 10% by mass, preferably 0.2 to 5% by mass, and more preferably 0.5 to 2% by mass, based on the total amount of the shampoo composition. When the amount is less than 0.1% by mass, the fingering at the time of rinsing decreases, and when it exceeds 10% by mass, the foam quality may deteriorate.
成分(D)と成分(E)の質量比(D)/(E)は、0.5〜8であり、好ましくは0.5〜5、更に好ましくは1.0〜4である。一般的に、成分(E)のような無機塩を配合すると泡量や泡質が低下するが、質量比(D)/(E)がこの範囲内であれば無機塩の存在下でも、成分(D)が泡膜中の水を増粘することで良好な泡量、泡質を得ることができる。(D)/(E)が0.5未満であると泡質が低下し、8を超えると泡量が低下することがある。 The mass ratio (D) / (E) of the component (D) and the component (E) is 0.5 to 8, preferably 0.5 to 5, and more preferably 1.0 to 4. Generally, when an inorganic salt such as component (E) is blended, the amount of foam and the foam quality are lowered. However, if the mass ratio (D) / (E) is within this range, the component can be obtained even in the presence of the inorganic salt. (D) can obtain a good foam amount and foam quality by thickening water in the foam film. If (D) / (E) is less than 0.5, the foam quality may be reduced, and if it exceeds 8, the amount of foam may be reduced.
〔(F)炭化水素油など〕
本発明のシャンプー組成物は、更に成分(F)として炭化水素油またはエステル油を含有していてもよく、これらをシャンプー組成物に配合することで、乾燥後の滑らかさを向上させることができる。成分(F)は、成分(A)、(B)、(C)、(D)と組み合わせることで毛髪への吸着が促進され、乾燥後の滑らかさが向上する。特に、成分(D)の乳化、可溶化力が高いので、成分(F)を安定配合することができる。
[(F) Hydrocarbon oil, etc.]
The shampoo composition of the present invention may further contain a hydrocarbon oil or an ester oil as the component (F), and by blending these into the shampoo composition, the smoothness after drying can be improved. . The component (F) is combined with the components (A), (B), (C), and (D) to promote the adsorption to the hair, and the smoothness after drying is improved. In particular, since the emulsification and solubilizing power of component (D) is high, component (F) can be stably blended.
炭化水素油としては、例えば、流動パラフィン、流動イソパラフィン、スクワラン、スクワレン、ポリイソブテン、水添ポリイソブテンなどが挙げられる。エステル油としては、例えば、ミリスチン酸イソプロピル、オクタン酸セチル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ラウリン酸ヘキシル、乳酸ミリスチル、トリ−2−エチルヘキサン酸グリセリル、セバシン酸ジイソプロピル、パルミチン酸2−エチルヘキシル等の合成エステル油や、アボガド油、亜麻仁油、大豆油、ツバキ油、マカデミアナッツ油、ココナッツ油、トウモロコシ油、ミンク油、オリーブ油、サフラワー油、パーム油、ナタネ油、綿実油、落花生油、茶実油、コメヌカ油、ホホバ油等の天然エステル油が挙げられる。成分(F)は、炭化水素油であることがより好ましく、更に好ましくは流動イソパラフィン、ポリイソブテン、水添ポリイソブテンである。成分(F)は1種単独で用いてもよいし、または2種以上を併用してもよい。 Examples of the hydrocarbon oil include liquid paraffin, liquid isoparaffin, squalane, squalene, polyisobutene, and hydrogenated polyisobutene. Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, hexyl laurate, myristyl lactate, glyceryl tri-2-ethylhexanoate, diisopropyl sebacate, 2-ethylhexyl palmitate, etc. Synthetic ester oils, avocado oil, linseed oil, soybean oil, camellia oil, macadamia nut oil, coconut oil, corn oil, mink oil, olive oil, safflower oil, palm oil, rapeseed oil, cottonseed oil, peanut oil, teaseed oil Natural ester oils such as rice bran oil and jojoba oil. Component (F) is more preferably a hydrocarbon oil, and still more preferably liquid isoparaffin, polyisobutene, and hydrogenated polyisobutene. A component (F) may be used individually by 1 type, or may use 2 or more types together.
成分(F)は、シャンプー組成物全量に対して、好ましくは0.05〜1質量%、更に好ましくは0.1〜0.5質量%の割合で含まれる。0.05質量%未満であると乾燥後の滑らかさが向上しない場合があり、1質量%を超えると安定性が低下する場合がある。 The component (F) is preferably contained in a proportion of 0.05 to 1% by mass, more preferably 0.1 to 0.5% by mass, based on the total amount of the shampoo composition. If it is less than 0.05% by mass, the smoothness after drying may not be improved, and if it exceeds 1% by mass, the stability may be lowered.
本発明のシャンプー組成物は、更に必要に応じて、本発明の効果を損なわない範囲内で、シャンプーに一般的に用いられている各種成分を含有していてもよい。例えば、高級脂肪酸、高級アルコール、シリコーン油等の油分、グリセリン、プロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール等の保湿剤、パラオキシ安息香酸エステル、安息香酸ナトリウム、フェノキシエタノール等の防腐剤、エチレンジアミン四酢酸塩、エデト酸等のキレート剤、ジステアリン酸エチレングリコール等のパール化剤、パラメトキシケイ皮酸エステル、メトキシジベンゾイルメタン等の紫外線吸収剤、増粘剤、酸化防止剤、pH調整剤、植物抽出物、アミノ酸、ビタミン類、色素、香料を適宜配合することができる。 The shampoo composition of the present invention may further contain various components generally used in shampoos, as necessary, within a range not impairing the effects of the present invention. For example, oils such as higher fatty acids, higher alcohols, silicone oils, humectants such as glycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol, preservatives such as paraoxybenzoate, sodium benzoate, phenoxyethanol, ethylenediamine Chelating agents such as acetate and edetic acid, pearlizing agents such as ethylene glycol distearate, UV absorbers such as paramethoxycinnamic acid ester and methoxydibenzoylmethane, thickeners, antioxidants, pH adjusters, plants Extracts, amino acids, vitamins, pigments, and fragrances can be appropriately blended.
本発明のシャンプー組成物は常法に従って製造できる。また、その剤型は任意であり、透明系液体状、パール系液体状、ペースト状、クリーム状、ゲル状、固形状、粉末状等にすることができるが、特に透明系やパール系の液体状が好ましい。 The shampoo composition of this invention can be manufactured in accordance with a conventional method. Moreover, the dosage form is arbitrary and can be made into a transparent liquid form, a pearl liquid form, a paste form, a cream form, a gel form, a solid form, a powder form, etc. The shape is preferred.
以下、実施例および比較例を挙げて本発明を更に具体的に説明する。 Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.
<実施例1〜11および比較例1〜7>
表2および表3に示した成分を所定の比率で配合し、更に共通添加成分として表1に示す成分を配合したシャンプー組成物を下記の方法で調製した。なお、表2および表3中の配合量の数値は、シャンプー組成物全量に対する質量%を表わす。
<Examples 1-11 and Comparative Examples 1-7>
The shampoo composition which mix | blended the component shown in Table 2 and Table 3 by the predetermined | prescribed ratio, and also mix | blended the component shown in Table 1 as a common addition component was prepared with the following method. In addition, the numerical value of the compounding amount in Table 2 and Table 3 represents mass% with respect to the total amount of the shampoo composition.
*1:レオガードMGP(ライオン(株)製、カチオン化度1.8質量%、重量平均分子量170万)
*2:パールリームEX(日油(株)製)
* 1: Leogard MGP (manufactured by Lion Corporation, cationization degree 1.8% by mass, weight average molecular weight 1.7 million)
* 2: Pearl Ream EX (manufactured by NOF Corporation)
*1:レオガードMGP(ライオン(株)製、カチオン化度1.8質量%、重量平均分子量170万)
*2:パールリームEX(日油(株)製)
* 1: Leogard MGP (manufactured by Lion Corporation, cationization degree 1.8% by mass, weight average molecular weight 1.7 million)
* 2: Pearl Ream EX (manufactured by NOF Corporation)
<調製法>
成分(A)〜(F)、共通添加成分および水を表1〜3に示した比率となるように80℃にて均一になるまで混合し、室温まで冷却し、液状のシャンプー組成物を得た。
<Preparation method>
Ingredients (A) to (F), common additive ingredients, and water are mixed at 80 ° C. so as to have the ratios shown in Tables 1 to 3 until uniform, and cooled to room temperature to obtain a liquid shampoo composition. It was.
<評価法>
(a)洗浄力
パネラー10名が市販のヘアワックスを毛髪に適量塗布した後、実施例および比較例のシャンプー組成物を使用して洗髪を行った際の洗浄力をパネラー各人が下記評価基準にて評価し、評点をつけた。10名のパネラーの評価の平均値が3.0以上を「◎」、2.0以上3.0未満を「○」、1.0以上2.0未満を「△」、1.0未満を「×」とした。ただし、平均値に関わらず、2名以上のパネラーが0点の評点をつけた場合は「×」とした。
4:すすぎ後に全く整髪料が残っていないと判断。
3:すすぎ後にほとんど整髪料が残っていないと判断。
2:すすぎ後にやや整髪料が残っていると判断。
1:すすぎ後にも整髪料が残存しており、ややごわつく感触であると判断。
0:すすぎ後にもほとんど整髪量が除去できておらず、ごわつく感触であると判断。
<Evaluation method>
(A) Detergency After 10 panelists applied an appropriate amount of commercially available hair wax to their hair, each panelist evaluated the detergency when the hair was washed using the shampoo compositions of Examples and Comparative Examples. And scored. The average value of the evaluation of 10 panelists is 3.0 or more “◎”, 2.0 or more and less than 3.0 “◯”, 1.0 or more and less than 2.0 “△”, and less than 1.0 It was set as “x”. However, regardless of the average value, when two or more panelists gave a score of 0, it was marked “x”.
4: Determined that no hairstyling material remains after rinsing.
3: Judged that almost no hairstyling material remains after rinsing.
2: Judged that some hairstyling material remained after rinsing.
1: The hair-styling material remains even after rinsing, and it is judged that the touch is somewhat stiff.
0: Almost no hair styling was removed even after rinsing, and it was determined that the feel was stiff.
(b)泡質
上記(a)の評価を行う際、洗髪時の泡量、泡質をパネラー各人が下記評価基準で評価し、評点をつけた。10名のパネラーの評価の平均値が3.0以上を「◎」、2.0以上3.0未満を「○」、1.0以上2.0未満を「△」、1.0未満を「×」とした。ただし、平均値に関わらず、2名以上のパネラーが0点の評点をつけた場合は「×」とした。
4:非常にきめ細かな泡が多量に形成されていると判断。
3:泡量が適切で、きめ細かな泡が形成されていると判断。
2:泡量がやや少ないが、きめ細かな泡が形成されていると判断。
1:泡量が適切であるが、やや粗い泡が形成されていると判断。
0:泡量が少なく、粗い泡が形成されていると判断。
(B) Foam quality When the above (a) was evaluated, each panelist evaluated the amount of foam and the foam quality at the time of shampooing according to the following evaluation criteria, and given a score. The average value of the evaluation of 10 panelists is 3.0 or more “◎”, 2.0 or more and less than 3.0 “◯”, 1.0 or more and less than 2.0 “△”, and less than 1.0 It was set as “x”. However, regardless of the average value, when two or more panelists gave a score of 0, it was marked “x”.
4: Judged that a lot of very fine bubbles were formed.
3: Judged that the amount of bubbles was appropriate and fine bubbles were formed.
2: Although the amount of bubbles is slightly small, it is determined that fine bubbles are formed.
1: Although the amount of foam is appropriate, it is determined that a slightly coarse foam is formed.
0: It is judged that the amount of bubbles is small and coarse bubbles are formed.
(c)すすぎ時の指通り
上記(a)の評価を行う際、すすぎ時の指通りをパネラー各人が下記評価基準で評価し、評点をつけた。10名のパネラーの評価の平均値が3.0以上を「◎」、2.0以上3.0未満を「○」、1.0以上2.0未満を「△」、1.0未満を「×」とした。ただし、平均値に関わらず、2名以上のパネラーが0点の評点をつけた場合は「×」とした。
4:非常に指通りが滑らかであると判断。
3:指通りが滑らかであると判断。
2:指通りが滑らかであるが、ややぬるつくと判断。
1:ややきしむ感触であると判断。
0:指通りが悪く、きしむ感触であると判断。
(C) Fingering at the time of rinsing When performing the evaluation of (a) above, each panelist evaluated the fingering at the time of rinsing according to the following evaluation criteria, and gave a score. The average value of the evaluation of 10 panelists is 3.0 or more “◎”, 2.0 or more and less than 3.0 “◯”, 1.0 or more and less than 2.0 “△”, and less than 1.0 It was set as “x”. However, regardless of the average value, when two or more panelists gave a score of 0, it was marked “x”.
4: Judged that the finger is very smooth.
3: It is determined that the finger passage is smooth.
2: The finger is smooth, but it is judged to be slightly slim.
1: Judged to have a slightly crisp feel.
0: Judgment is bad due to bad fingering and a crisp feel.
(d)乾燥後の滑らかさ
上記(a)の評価を行った後、ドライヤーにて毛髪を乾燥させた直後の状態をパネラー各人が下記評価基準で評価し、評点をつけた。10名のパネラーの評価の平均値が3.0以上を「◎」、2.0以上3.0未満を「○」、1.0以上2.0未満を「△」、1.0未満を「×」とした。ただし、平均値に関わらず、2名以上のパネラーが0点の評点をつけた場合は「×」とした。
4:非常に指通りが滑らかであると判断。
3:指通りが滑らかであると判断。
2:指通りが滑らかであるが、ややごわつくと判断。
1:ややごわつく感触であると判断。
0:指通りが悪く、ごわつく感触であると判断。
(D) Smoothness after drying After the evaluation of (a) above, each panelist evaluated the condition immediately after drying the hair with a dryer according to the following evaluation criteria, and gave a score. The average value of the evaluation of 10 panelists is 3.0 or more “◎”, 2.0 or more and less than 3.0 “◯”, 1.0 or more and less than 2.0 “△”, and less than 1.0 It was set as “x”. However, regardless of the average value, when two or more panelists gave a score of 0, it was marked “x”.
4: Judged that the finger is very smooth.
3: It is determined that the finger passage is smooth.
2: The finger is smooth, but judged to be a little stiff.
1: Judged to have a slightly stiff feel.
0: The finger feels bad and it is judged to be stiff.
本発明に係る実施例1〜11のシャンプー組成物は、いずれも整髪料に由来する汚れを効果的に除去することができ、泡質に優れ、すすぎ時および乾燥後の滑らかさが良好であった。 Each of the shampoo compositions of Examples 1 to 11 according to the present invention can effectively remove stains derived from the hair styling agent, is excellent in foam quality, and has good smoothness during rinsing and after drying. It was.
一方、比較例1〜7では十分な効果が得られていない。比較例1では、成分(D)の配合量が0.5質量%未満であり、成分(A)と成分(D)の質量比(D)/(A)が0.08未満であるので、十分な洗浄力、泡質、コンディショニング効果が得られていない。比較例2では、質量比(D)/(A)が0.08未満であり、質量比(D)/(E)が0.5未満であるので、洗浄力、泡質が不十分で、コンディショニング効果も十分ではなかった。比較例3では、成分(E)が配合されていないので、コンディショニング効果が不十分であった。比較例4では、成分(D)に代えて、一般式(1)における水酸基当たりのAO付加モル数m/xが5未満であり、エステル化率も40未満である成分(D‘)を用いているので、洗浄力、泡質、乾燥後の滑らかさも十分ではなかった。 On the other hand, in Comparative Examples 1-7, sufficient effect is not acquired. In Comparative Example 1, the blending amount of component (D) is less than 0.5% by mass, and the mass ratio (D) / (A) of component (A) to component (D) is less than 0.08. Insufficient detergency, foam quality and conditioning effect. In Comparative Example 2, since the mass ratio (D) / (A) is less than 0.08 and the mass ratio (D) / (E) is less than 0.5, the cleaning power and foam quality are insufficient. The conditioning effect was not sufficient. In Comparative Example 3, since the component (E) was not blended, the conditioning effect was insufficient. In Comparative Example 4, a component (D ′) having an AO addition mole number per hydroxyl group m / x in the general formula (1) of less than 5 and an esterification rate of less than 40 in place of the component (D) is used. Therefore, detergency, foam quality, and smoothness after drying were not sufficient.
比較例5では、成分(D)に代えて、一般式(1)における水酸基当たりのAO付加モル数m/xが5未満である成分(D‘)を用いているので、泡質とコンディショニング効果が不十分であった。比較例6では、成分(D)に代えて、エステル化率が40未満である成分(D‘)を用いているので、洗浄力が不十分で、乾燥後の滑らかさも十分ではなかった。比較例7では、成分(D)に代えて、一般式(1)におけるm/xが20を超えている成分(D‘)を用いているので、泡質には優れるものの、洗浄力、コンディショニング効果は不十分であった。 In Comparative Example 5, since the component (D ′) in which the number of moles of AO added per hydroxyl group m / x in the general formula (1) is less than 5 in the general formula (1) is used instead of the component (D), the foam quality and the conditioning effect Was insufficient. In Comparative Example 6, since the component (D ′) having an esterification rate of less than 40 was used instead of the component (D), the cleaning power was insufficient and the smoothness after drying was not sufficient. In Comparative Example 7, since component (D ′) in which m / x in general formula (1) exceeds 20 is used instead of component (D), the foam quality is excellent, but the cleaning power and conditioning The effect was insufficient.
Claims (3)
(A)アニオン性界面活性剤、
(B)両性界面活性剤、
(C)カチオン性高分子、
(D)下記一般式(1)で示されるアルキレンオキシド誘導体、
(E)アルカリ金属の無機塩。 The following component (A) is 3 to 30% by mass, component (B) is 0.5 to 20% by mass, component (C) is 0.05 to 5% by mass, and component (D) is 0.5 to 15% by mass. %, Component (E) is contained in an amount of 0.1 to 10% by mass, the mass ratio of component (D) / component (A) is 0.08 to 0.9, and component (D) / component (E) A shampoo composition having a mass ratio of 0.5 to 8;
(A) an anionic surfactant,
(B) an amphoteric surfactant,
(C) a cationic polymer,
(D) an alkylene oxide derivative represented by the following general formula (1):
(E) An inorganic salt of an alkali metal.
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JP2016023173A (en) * | 2014-07-23 | 2016-02-08 | 日油株式会社 | Shampoo composition |
JP2018043980A (en) * | 2016-09-13 | 2018-03-22 | 日油株式会社 | Transparent shampoo composition |
CN109745246A (en) * | 2017-11-01 | 2019-05-14 | 日油株式会社 | Hair shampoo composition |
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US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
US11980679B2 (en) | 2019-12-06 | 2024-05-14 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
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US11980679B2 (en) | 2019-12-06 | 2024-05-14 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
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