JP2013213016A - Method for producing bacteriostatic sterilization deodorizing composition, and bacteriostatic sterilization deodorizing composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To propose a method for producing a bacteriostatic sterilization deodorizing composition for rubble containing industrial waste for example, and to provide a bacteriostatic sterilization deodorizing composition.SOLUTION: A method for producing a bacteriostatic sterilization deodorizing composition includes; a silver ion aqueous solution generation step of generating a silver ion aqueous solution by bringing raw water into mineral status by electrolysis, and mixing a silver ion into the raw water in the mineral status; a mineral aqueous solution generation step for generating a mineral aqueous solution by bringing purified water or spring water into a predetermined state of temperature by heat treatment, and fusing at least two or more minerals and vitamin C by using a stirring means; a mixing step of mixing the mineral aqueous solution obtained by the mineral aqueous solution generation step and the silver ion aqueous solution obtained by the silver ion aqueous solution generation step; and a standing step of bringing a fusion solution through the mixing step into a stationary state for a predetermined time.

Description

  The present invention relates to a method for producing a bacteriostatic bactericidal deodorant composition and a bacteriostatic bactericidal deodorant composition which are used to suppress the growth of bacteria and remove malodors.

  The object of the invention of Patent Document 1 is for the purpose of removing a trace amount of malodorous components present in daily living space, and particularly against malodorous gases such as hydrogen sulfide, ammonia, mercaptans, amines and aldehydes which are problematic. An object of the present invention is to provide a malodorous gas adsorbent having a new composition that has an excellent deodorizing effect, is highly safe, and is easy to handle (paragraph 0009).

As technical means for achieving the object of the present invention, the characteristic technical means of Patent Document 1 is “silicate, silver, aluminum, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, tin, copper, zinc. An aqueous solution containing one or two or more metal salts selected from the group consisting of metal salts of cadmium and lead is adjusted to a pH of 9 to 11 and maintained at 45 to 70 ° C. to obtain a silicate and a metal salt. This is a malodorous gas adsorbent in which a sol containing is formed, neutralized with an acid, and a metal salt is included inside a silicic acid gel structure having a specific surface area of 500 m ² / g or more.

Therefore, in Patent Document 1, for example, an aqueous solution containing one kind of silver ions or two or more kinds of metal salts of silver ions and manganese is adjusted to a predetermined range and maintained at a predetermined temperature, and silicate and A malodorous gas adsorbent is disclosed in which a sol containing a metal salt is generated, then neutralized with an acid, and the metal salt is included inside a silicic acid gel structure having a specific surface area of 500 m ² / g or more. Become.

  However, since the malodorous gas adsorbent is an aqueous solution mainly containing a metal salt (chlorine), it has an advantage that it can be used on a daily basis, but it can sufficiently suppress so-called residual effects and bacteria. There was a problem that the use was limited.

  Further, the problem of the invention of Patent Document 2 is a deodorant that exhibits a deodorizing effect extremely effectively against both bad odors of industrial waste N and S, and has good stability even at high temperatures. As a technical means for achieving the object of the invention, the present invention provides: “The liquid deodorant composition comprises a zinc compound such as zinc gluconate and zinc sulfate, a nonionic surfactant and a fragrance. It is characterized by including. " In other words, “fragrance” is added to suppress the deodorizing effect.

  By the way, as a well-known fact, the “Great East Japan Earthquake” occurred last year, and now one of the national issues is how to deal with a lot of rubble in the affected areas. The reason is that bad odor, bad odor and sterilization caused by rubble mixed with various filth, sludge, strange odor, foreign matter, chemicals, wood chips and iron scraps contaminate people's living environment, and as a result This is because there is a risk of harming people's health, and it may also adversely affect the natural flora and fauna ecosystem and the natural environment.

  The chemical substances assumed to be contained in the rubble as well as industrial waste generated in daily life include, for example, plastic materials, petroleum and coal products, transportation equipment, iron and non-metals, ceramics, stones and clays. Products, processed paper and pulp, industrial waste, vehicles, metal plating, ship manufacturing and maintenance, port transportation, landfill chemicals, acetonitrile, acrylonitrile, acrylic acid, acrylamide, antimony and its compounds, asbestos, benzene, bisphenol A Epoxy resin, boric acid and compounds, n-butyl methacrylate, chloroform, chromium and trivalent chromium compounds, cobalt compounds, water-soluble copper salts, cyclohexylamine, dioxins, ethylbenzene, ethylene glycol, ethylenediaminetetraacetic acid, formaldehyde, hydrazine , Fluoride water Water and its water solubility, lead and its compounds, manganese and its compounds, methacrylic acid, methyl methacrylate, molybdenum and its compounds, monomethyl ether, nickel and its compounds, nonylphenol, phenol, toluene, 1.3.5 trimethylbenzene, xylene, This is because it can be said that a water-soluble zinc compound and the like are contained.

Therefore, the advent of a bacteriostatic bactericidal deodorant composition for rubble including industrial waste is currently demanded.
The inventor uses the term “bacteriostatic” herein, and “bacteriostatic action” is a concept that is contrary to sterilization. Instead of killing and reducing the bacteria, it is to reduce the bacteria by suppressing the growth of the bacteria. Sterilization is an important function in human life, but the civilization to make use of (biological and inanimate circulation) creates a balance that suppresses the abnormal growth of specific forces, thus balancing a dynamic space that is not necessarily neutral. The balance between “bacteriostatic” and “sterilization” is the principle of maintaining the pulsation of natural circulation, and it is considered to be fundamental to produce a composition that conforms to this principle.

  In addition, inventions worthy of protecting ecosystems are not limited to chemical substances and technological innovations, and it is necessary to ensure that the balance between neutral “bacteriostatic” and “sterilization” does not break. Just sterilization and sterilization is not possible.

The debris generated from the extraordinary and unforeseen events of the Great East Japan Earthquake has been a major issue in public health failure, the generation of hazardous waste, and the response to spoilage. A full defense. It is said that maggots were generated from the debris and later flies were generated in large quantities. As is well known, maggots are fly larvae, occur in corrosives and filth, and are recognized as sanitary pests with adult flies. In particular, the flies include house flies, moss flies, yellow flies, mistletoe, black flies. These flies immediately appear in septic, animal carcasses, fermented animals and plants, odorous foreign matter, feces, toilet bowls and toilet bowls that have not been washed, and the parent flies produce larvae directly. It takes no time for eggs to hatch.
Therefore, the emergence of a novel bacteriostatic bactericidal and deodorant composition for rubble corresponding to the odor and foul odor of rubble generated by these maggots and flies is desired.

  Although the patent document 2 pointed out in this specification takes into account artificial fragrances, deodorization and sterilization of rubble is virtually impossible simply by concealing the odor element with artificial fragrances, and neutral " It is not a deodorant composition for industrial waste considering the natural environment so that the balance between “bacteriostatic” and “sterilization” is not lost.

  Therefore, in view of the problems of Patent Document 1, Patent Document 2, etc., the present inventor mainly represents an effect on bacteriostatic sterilization and deodorization of organic compounds generated in rubble, and contributes to environmental and sanitary maintenance of human life. Provided is a bacteriostatic bactericidal deodorant composition capable of exerting the maximum effect.

  The subject of the invention of Patent Document 3 is “deodorant / deodorant with high practicality effective against unpleasant odors such as human body odor, bad breath, urine odor, pet animal odor, manure odor, and cigarette odor. By providing an agent, the specific constitution is “an oxidant containing a phytic acid metal complex compound formed by phytic acid and metal ions such as iron, copper, zinc, aluminum, manganese, calcium, magnesium, cobalt, etc. In particular, although the phytic acid metal complex compound has the effect of reducing various unpleasant odors, it is used as a bacteriostatic bactericidal deodorant composition for rubble including industrial waste. It is not something.

JP-A-4-290546 JP 2001-321427 A JP-A-9-202721

  The intended purpose of the present invention is to provide a method for producing a bacteriostatic bactericidal and deodorant composition for rubble including industrial waste, in consideration of the application problems of Patent Document 1, Patent Document 2 and Patent Document 3. It is to propose a fungicidal and deodorant composition. The second object of the present invention is, for example, effective in bacteriostatic sterilization and deodorization of organic compounds generated in rubble, and is effective in improving the environment and hygiene of human life. Proposing a composition. In other words, the bacteriostatic bactericidal deodorant composition exhibits an antibacterial effect against a wide variety of bacteria and is difficult to produce resistant bacteria due to its bacteriostatic effect. In addition, it is extremely safe for humans and animals. The manufacturing method of this invention and a bacteriostatic bactericidal deodorant composition are proposed.

  The method for producing a bacteriostatic bactericidal deodorant composition of the present invention comprises a step of producing a silver ion aqueous solution, wherein raw water is made into an inorganic state by electrolysis, and silver ions are mixed into the raw raw water to produce a silver ion aqueous solution. Alternatively, fresh water is heat-treated to a required temperature state, and at least two kinds of inorganic substances and vitamin C are fused using a stirring means to generate an inorganic aqueous solution generation process, and the inorganic aqueous solution generation process is obtained. It includes a mixing step of mixing the inorganic aqueous solution and the silver ion aqueous solution obtained in the silver ion aqueous solution generating step, and a standing step of allowing the fusion liquid that has passed through the mixing step to stand for a required time. 1).

  In the above structure, the two or more inorganic substances are citric acid and manganese. In addition, the temperature condition of the inorganic aqueous solution generation step is 40 to 60 degrees, while the mass of the two or more inorganic substances and vitamin C is 15% to 25% of citric acid with respect to the silver ion aqueous solution. Before and after, manganese is around 15% to 25%, and vitamin C is around 15% to 25%. In addition, the bacteriostatic bactericidal deodorant composition is characterized in that it is either a liquid material, an ice making body that further incorporates a freezing step, or a powder body that further includes a drying step. In addition, the bacteriostatic bactericidal deodorant composition is characterized in that it is used for any of rubble, edible seafood, frozen vegetables, frozen fruits, meat products, and processed marine products. Furthermore, the bacteriostatic bactericidal deodorant composition obtained by mixing volcanic ash with the liquid bacteriostatic bactericidal deodorant composition obtained in claim 1 is a powder, and the powder is It contains volcanic ash called silicon.

  In addition, the bacteriostatic bactericidal deodorant composition is characterized in that at least citric acid, manganese, and vitamin C are fused with an aqueous silver ion solution. Here, “bacteriostatic” is a concept that is contrary to sterilization, and is not to kill and reduce bacteria, but to reduce bacteria by suppressing the growth of bacteria.

(A) The invention described in claim 1 activates so-called bacteriostatic action against harmful microorganisms and bacteria because citric acid, manganese and vitamin C are combined with the bactericidal action of the silver ion aqueous solution. Can be made. In addition, since the bactericidal action of the present invention works in a balanced manner with respect to the object, it is possible to substantially kill cells / bacteria that are the source of odors and odors of rubble, for example. In addition, since raw water (purified water or fresh water) is a mineral of low molecular weight minus active water that becomes an inorganic state by electrolysis, the raw water in the inorganic state and silver ions are combined as much as possible to form a “silver ion aqueous solution”. As a result, the adsorption power to the target becomes strong (improves molecular cohesion), and the silver ion aqueous solution is further stirred with at least two inorganic substances and vitamin C via a heating means. Since the bacteriostatic bactericidal deodorant composition obtained by fusing with no toxic compounds does not contain any harmful compounds, it is safe for the ecosystem and the global environment and harmless to the human body. In addition, since it is not necessary to add an artificial fragrance | flavor like patent document 2, a target object can be obtained cheaply.
(B) In Claim 2, the temperature condition of the predetermined range is 40 to 80 degrees, while the mass of the predetermined range is 15% citric acid with respect to the primary aqueous solution. Since about 25%, about 15% to 25% manganese, and about 15% to 25% vitamin C, a bacteriostatic bactericidal deodorant composition can be obtained. As a desirable experiment or verification example of a bacteriostatic bactericidal deodorant composition, the temperature condition is around 55 ° C., citric acid is around 20%, manganese is around 18%, vitamin C is 16% (where “around” means plus / minus (Including errors up to minus 1%), mixing time of 10 liters for about 15 minutes, and standing time of 10 hours to 12 hours, citric acid, manganese and vitamin C are “colorless and odorless. Fusion to "state". On the other hand, when the temperature condition and the blending amount of each substance are different, the solution is fused to a “light pink and odorless state”. In addition, depending on the temperature condition and the amount of each substance, the substances do not fuse, so that a precipitation phenomenon occurs, or even if each substance fuses, a vitamin smell is obtained.
(C) The invention described in claim 4 can be used not only for spraying the object, but also for seafood, for example, for maintaining freshness in an ice state. Moreover, it can also be mixed and used for the crushed debris. In addition, various usage modes are possible.
(D) The invention described in claim 5 can be used for any of rubble, edible fish and shellfish, frozen vegetables, frozen fruits, meat products, and processed marine products. In view of the problems in application 2 and Patent Document 3, the bacteria can be suppressed by the bacteriostatic sterilization method and the residual effect is improved, so that the bacteriostatic sterilization for rubble also includes industrial waste. Effective for deodorant compositions.
(E) In the invention described in claim 6, the bacteriostatic bactericidal deodorant composition obtained by mixing volcanic ash with the liquid bacteriostatic bactericidal deodorant composition obtained in claim 1 is a powder. Since the powdery body contains volcanic ash called solarizable silicon, the industrial application field of the bacteriostatic bactericidal deodorant composition is expanded, for example, the powdery body is sprayed on the object. Therefore, it can be used not only in daily life but also in the civil engineering and architectural fields.
(F) The bacteriostatic bactericidal deodorant composition according to claim 7 has the same effect as the invention according to claim 1.

Process drawing which shows 1st Embodiment of this invention. Schematic explanatory drawing which shows a silver ion aqueous solution production | generation process. Schematic explanatory drawing which shows an inorganic substance aqueous solution production | generation process. Schematic explanatory drawing which shows a mixing process and a stationary process. Process drawing which shows 2nd Embodiment of this invention.

  FIG. 1 is a process diagram showing a first embodiment of the present invention. In this figure, A is a silver ion aqueous solution generation step, B is an inorganic aqueous solution generation step, C is a silver ion aqueous solution a obtained in the silver ion aqueous solution generation step, and an inorganic aqueous solution b obtained in the inorganic aqueous solution generation step. A mixing step D for fusing, and a stationary step D for allowing the fusion liquid c that has undergone the mixing step to stand for a required time.

  FIG. 2 is a schematic explanatory view showing a silver ion aqueous solution generation step A. In this figure, first, 1 is a first container, and raw water 3 is introduced into the first container 1 from, for example, a faucet 2. Therefore, this raw water 3 is so-called tap water. The tap water 3 contains chlorine and organic substances as is well known. Of course, the raw water 3 may be lake water, spring water, or the like, but is preferably purified water (including fresh water) 3. Next, 4 is an electrolytic vessel, and the raw water 3 is put into the electrolytic vessel 4 for electrolysis. When raw water (electrolyte aqueous solution) 3 is placed in the electrolytic vessel 4 and a current is passed through, the raw water 3 containing chlorine and organic matter becomes an aqueous solution 5 in an inorganic state. Next, 6 is a primary production container, and the aqueous solution 5 in the inorganic state is put into the primary production container 6, for example, silver ions 8 are mixed through a spoon means 7, and “silver ion aqueous solution a” is prepared. Generate.

  FIG. 3 is a schematic explanatory view showing an inorganic aqueous solution generation step B. In this figure, first, 1A is a second container, and purified water (including fresh water) 3A is put into the second container as in the case of the first container 1 in the silver ion aqueous solution generation step A. Reference numeral 10 denotes a heating means having a heating coil 10b inside the support 10a. On the support 10a of the heating means 10, a heating container 11 containing purified water 3A is placed. Thus, the purified water 3A is heated via the heating means 10 and reaches an appropriate temperature state at a required temperature, for example, a temperature within 40 to 80 degrees. Desirably, the purified water 3A is maintained in a state of around 55 degrees. Two or more kinds of inorganic substances 12, preferably at least citric acid and manganese are added under the appropriate temperature condition. In this embodiment, vitamin C is further added. Then, using the stirring means 13, the warm purified water 3A, the citric acid, manganese, and vitamin C are fused at the atomic / molecular level to obtain an “inorganic aqueous solution b”. Once this inorganic aqueous solution b is obtained, it is left to stand at room temperature, for example, around 18 to 20 degrees.

  FIG. 4 is a schematic explanatory view showing the mixing step C and the standing step D. In the mixing step C, the inorganic aqueous solution b obtained in the inorganic aqueous solution production step B is fused with the silver ion aqueous solution a obtained in the silver ion aqueous solution production step A as described above. Reference numeral 15 denotes a mixing container. The mixing container 15 contains a fusion product c in which a silver ion aqueous solution a and an inorganic aqueous solution b are fused. This fusion product c is subjected to a standing step D in which it is left as it is for 10 hours to 12 hours, for example, and becomes the final target product (bacteriostatic bactericidal deodorant composition) d. In other words, the standing step D corresponds to an aging step for aging the fusion product c.

  Incidentally, the chlorine-based disinfectant used in Patent Document 1 and the like has a disinfecting effect against bacteria and is a commonly used disinfectant. However, the chlorine-based disinfectant has no residual effect, and has a disadvantage that it cannot suppress the growth when microorganisms fly from the outside after the treatment, and the treatment must be repeated frequently. Don't be. On the other hand, those containing heavy metal ions such as zinc, silver, and copper are generally used as antibacterial agents that have long-lasting antibacterial effects against bacteria. It has been recognized that heavy metal ions have a broad bactericidal spectrum and have characteristics such as a high bactericidal effect on bacteria, a long-lasting antibacterial effect, and resistance to resistant bacteria.

  However, silver ions are insufficient in terms of sterilizing power and deodorizing power immediately after processing as compared with oxidizing agents such as chlorinated fungicides, and are used for bacteria to develop fungicidal performance. A higher concentration of silver ions is required. Furthermore, when sulfides coexist in the object to be treated (the object to be treated), silver ions change to sulfides that are insoluble in water, and thereafter, there is a problem that the antibacterial effect is significantly reduced.

  Therefore, the present inventor considers the above-mentioned problems of silver ions, and mixes two kinds, preferably two or three or more kinds of substances in residual silver ions, and is mainly an organic system generated in rubble. Research was conducted to show the effect of bacteriostatic bactericidal deodorization of compounds. As a result, the bacteriostatic bactericidal deodorant composition d was successfully obtained by the production method shown in FIG.

In the research of the present inventor, for example, when silver ions are combined with citric acid, which is an example of an inorganic group, it is desirable that the silver ions be in the form of an aqueous solution such as a required electrolyte and temperature (appropriate temperature condition).
Therefore, the present inventor makes a bacteriostatic bactericidal effect by adsorbing to the surface of microorganisms by zeta potential, decomposes using an oxidation-reduction reaction to detoxify the organic system, Decided to do.

  If it adds, the bacteriostatic bactericidal deodorant composition d obtained by the manufacturing method of this invention fuse | melts silver ion (Ag +) and a mineral (shimizu) to make aqueous solution (silver ion aqueous solution), and is contained in the rubble which is a target object. A large amount of chemicals (including dangerous materials and explosives), iron in automobiles (corrosive liquid), gasoline, dead carcasses (septic odor), bacteria from soil, salt from fish or sea rot, wood chips, spoiled crops, fire Incineration ash, large amounts of various bacteria, foul odors, odors, bad odors, sludge, various chemicals, goods, foodstuffs used in daily life, etc. The purpose is to restore or restore the safe and secure environment necessary for industrial recovery.

  For example, as shown in FIG. 1, the production method for obtaining such a “bacteriostatic bactericidal deodorant composition” is made by bringing raw water 3 into an inorganic state by electrolysis and mixing silver ions 8 into the raw water 5 in the inorganic state. A silver ion aqueous solution generation step A for generating a silver ion aqueous solution a and purified water or fresh water 3A are heat-treated to a required temperature state, and at least two kinds of inorganic substances 12 and vitamin C are fused using a stirring means 13. An inorganic aqueous solution generation step B for generating an inorganic aqueous solution b, a mixing step C for mixing the inorganic aqueous solution b obtained in the inorganic aqueous solution generation step and the silver ion aqueous solution a obtained in the silver ion aqueous solution generation step, and this mixing It includes a standing step D in which the fusion liquid c that has undergone the step is allowed to stand for a required time.

  The bacteriostatic bactericidal deodorant composition having the above-described configuration is sprayed and mixed with, for example, an unimaginable acidic / alkaline malodorous odor substance that is a component of rubble.

  In this section, some practical examples will be described.

(1) Example of liquid: object is rubble As a verification example, the temperature range of the predetermined range is 40 to 80 degrees, while the mass of the predetermined range is relative to the primary aqueous solution (silver ion aqueous solution) a. Citric acid is about 15% to 25%, manganese is about 15% to about 25%, and vitamin C is about 15% to 25%. Thus, as a desirable experiment or verification example that can obtain a bacteriostatic bactericidal deodorant composition d, “temperature conditions are around 55 ° C., citric acid is around 20%, manganese is around 18%, vitamin C is 16% (here In addition, “before and after” includes an error of plus or minus 1%), the mixing time is about 15 minutes at 10 liters, and the standing time is 10 to 12 hours. In this way, citric acid, manganese, and vitamin C are fused into a “colorless and odorless state” in the silver ion aqueous solution. On the other hand, when the temperature condition and the blending amount of each substance are different, the solution is fused to a “light pink and odorless state”. In addition, depending on the temperature condition and the amount of each substance, the substances do not fuse, so that a precipitation phenomenon occurs, or even if each substance fuses, a vitamin smell is obtained.

  The liquid bacteriostatic bactericidal deodorant composition d was sprayed on “10 liters” of, for example, “rubble on Kesennuma coast” which is an example of an object. The measuring device is, for example, a high-sensitivity tin oxide-based heat-wire sintered semiconductor sensor, which is a product (Smell Sensor XP329) of Shin Cosmos Electric Co., Ltd. Before spraying the liquid bacteriostatic bactericidal deodorant composition d onto the rubble, the start of measuring the rubble with the measuring instrument is “673 (a state that can not be tolerated unless the nose is removed)”. Therefore, after spraying “10 liters” of the liquid bacteriostatic bactericidal deodorant composition d onto the rubble, the rubble odor is given in one hour units, such as 1 hour, 2 hours, 3 hours, 4 hours, and 5 hours. It was measured. As a result, 1 hour / 673 (the state where the nose is picked), 2 hours / 563, 3 hours / 276 (decrease to the odor of manure), 4 hours / 115, 5 hours / 66 (feels some odor) The bad odor decreased over time. In addition to bacteriostatic bactericidal deodorization against rubble, fire resistance and flame retardancy were enhanced.

  By the way, I will add here about the “zeta potential”. As is well known, the zeta potential is defined as zero in a region that is sufficiently neutral from the particle and is electrically neutral, and fine particles are increasingly used as a material, so its function is improved. Then, the surface is improved, and a polymer compound, a surfactant, foreign particles, etc. are adsorbed on the surface, or the surface is chemically treated to obtain a composition agent. From such zeta potential characteristics, the silver ion aqueous solution a obtained in the silver ion aqueous solution generation step A of the present invention is combined with at least two kinds of inorganic substances 12 such as citric acid and manganese, and further, vitamin C as molecules / atoms. The bacteriostatic bactericidal deodorant composition d in a state of fusion of not only the immediate effect, the so-called residual effect by bacteriostatic sterilization, but also the effects described below (heat resistance / difficulty) It was confirmed by experimental results that it has flammability and adsorptivity.

(2) Example of an individual: an example in which a freezing step is taken into account Freezing is performed by storing the bacteriostatic bactericidal deodorant composition (for example, liquid) according to claim 1 in a -5 to -10 degree refrigeration system. The resulting solid (ice making) was obtained. That is, the bacteriostatic bactericidal deodorant composition was solidified by refrigeration equipment for about 3 to 5 hours, for example, to obtain a so-called “ice-making”.

  The ice making was used for any of edible seafood, frozen vegetables, frozen fruits, meat products, processed marine products, for example. Although the use conditions differed slightly, for example, in edible fish and shellfish, it was possible to maintain the freshness as desired. Therefore, by solidifying the present invention, the bacteriostatic sterilization and sterilization can be performed in industries that require freezing preservation, freezing transportation, and freezing preservation of fresh food in the fishery industry, fishery processing industry, and fresh food in the food industry. Enables effects including odor and selective deodorization.

  In addition, the solid bacteriostatic bactericidal deodorant that has been made into ice can be solidified in, for example, an ice making factory for business use. Since no chemicals are used in the ingredients, it can be used safely and with peace of mind. The solid ice produced with normal tap water and the ice making and thawing times remain the same. It is a solid ice making of only this composition, which can have fungicidal effect, selective deodorization and freshness maintenance, and does not use any chemicals.

(3) Example of pulverization The bacteriostatic bactericidal deodorant composition (for example, liquid) according to claim 1 is pulverized by freeze drying or vacuum freeze drying. For example, when performing bacteriostatic bactericidal sterilization and deodorizing treatment, the present powdered composition is mixed into the soil or sprayed on the ground surface, such as existing farmland, livestock, and barns where movement is impossible.

  In the above powdering, the bacteriostatic bactericidal deodorant composition d obtained by mixing volcanic ash with the liquid bacteriostatic bactericidal deodorant composition d obtained in claim 1 is a powder, The body contains volcanic ash called solar silicon. Specifically, the liquid bacteriostatic bactericidal deodorant composition d according to claim 1 and volcanic ash are mixed and powdered. By mixing this powder with soluble silicon as volcanic ash, unlike ordinary soil, it becomes a powder with adsorptive power, including rubble, nasty smell, offensive odor, manure, vomit, chemical substances, etc. The powder is adsorbed by applying it to the object, and rubble and filth can be treated. The blending ratio of the powder body is desirably 20% for the liquid bacteriostatic bactericidal deodorant composition d, 60% for ordinary ordinary volcanic ash, and 20% for soluble silicon as special volcanic ash.

(4) Production method of the second embodiment In the second embodiment of the present invention, purified water or fresh water is heat-treated to a required temperature state, and at least two kinds of inorganic substances and vitamin C are fused using a stirring means. The inorganic aqueous solution generation step B for generating the inorganic aqueous solution exists, but the inorganic aqueous solution generation step B does not exist in the manufacturing method of the second embodiment. That is, the mixing step C is different in that the fusion product c is obtained by directly mixing the silver ion aqueous solution a obtained in the silver ion aqueous solution generation step A with at least two kinds of inorganic substances and vitamin C. . Therefore, the bacteriostatic bactericidal deodorant composition d of the present invention is obtained by fusing at least citric acid, manganese, and vitamin C to the silver ion aqueous solution a.

  The present invention is mainly used as a bacteriostatic bactericidal deodorant composition for rubble including industrial waste.

A ... Silver ion aqueous solution production process,
B: Inorganic aqueous solution generation step,
C ... mixing process,
D ... Standing process,
a ... silver ion aqueous solution,
b: inorganic aqueous solution,
c: Fusion,
d: Bacteriostatic bactericidal deodorant composition.
12: Two or more inorganic substances.

Claims (7)

The raw water is converted into an inorganic state by electrolysis, and a silver ion aqueous solution generating step for generating silver ion aqueous solution by mixing silver ions into the raw raw water in the inorganic state, and heat treatment of purified water or fresh water to a required temperature state, at least two kinds An inorganic aqueous solution generation step for fusing the above inorganic material and vitamin C using a stirring means to generate an inorganic aqueous solution, an inorganic aqueous solution obtained in the inorganic aqueous solution generation step, and a silver ion aqueous solution obtained in the silver ion aqueous solution generation step A method for producing a bacteriostatic bactericidal deodorant composition, comprising: a mixing step of mixing the mixture, and a step of allowing the fusion liquid that has undergone the mixing step to stand for a required time. 2. The method for producing a bacteriostatic bactericidal deodorant composition according to claim 1, wherein the two or more inorganic substances are citric acid and manganese. In Claim 1, The temperature conditions of the said inorganic aqueous solution production | generation process are 40 to 60 degree | times, On the other hand, the mass of the said 2 or more types of inorganic substance and vitamin C is citric acid with respect to silver ion aqueous solution. A method for producing a bacteriostatic bactericidal deodorant composition, characterized in that it is about 15% to 25%, manganese is about 15% to about 25%, and vitamin C is about 15% to about 25%. 2. The static bacteriostatic bactericidal deodorant composition according to claim 1, wherein the bacteriostatic bactericidal deodorant composition is any one of a liquid, an ice-making body added with a freezing step, and a powdered product added with a drying step. A method for producing a fungicidal and deodorant composition. 2. The bacteriostatic bactericidal deodorant composition according to claim 1, wherein the bacteriostatic bactericidal deodorant composition is used for any of rubble, edible seafood, frozen vegetables, frozen fruits, meat products, and processed marine products. A method for producing a deodorant composition. The bacteriostatic bactericidal deodorant composition obtained by mixing volcanic ash with the liquid bacteriostatic bactericidal deodorant composition obtained in claim 1 is a powder, and the powder includes soluble silicon and A bacteriostatic bactericidal deodorant composition characterized by containing volcanic ash. A bacteriostatic bactericidal deodorant composition in which at least citric acid, manganese, and vitamin C are fused with an aqueous silver ion solution.

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