JP2013183649A - Method for producing oil-in-water emulsion - Google Patents
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本発明は、プリン、ババロア、ゼリー等の練り込み用に使用される水中油型乳化物であるクリームや、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)としての使用である、風味に優れた水中油型乳化物の製造法に関する。 The present invention relates to a cream that is an oil-in-water emulsion used for kneading pudding, bavarois, jelly, and the like, and a foamable oil-in-water emulsion (whipped cream) used in decorations such as cakes and sand The present invention relates to a method for producing an oil-in-water emulsion excellent in flavor.
近年、食品に対する、品質(物性、生理活性、風味)、安全、安心への要求が高度になって来ている。水中油型乳化物においても例外ではなく、特に洋菓子、デザート類等の嗜好品に使用されているだけに風味への要求は顕著である。
具体的には、水中油型乳化物であるクリームはプリン、ゼリー等のデザート類の上に添加したり、プリン、ババロア、ゼリー等の練り込み用に使用されたり、更に水中油型乳化物を起泡してケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)が使用されたりしている。
水中油型乳化物には生クリーム、コンパウンドクリーム、植物性クリーム、生乳、濃縮乳、無脂乳固形分含有水中油型乳化物等がある。
これら水中油型乳化物は主として、油脂、乳蛋白質、乳化剤及び水を含む原料を混合して、予備乳化、殺菌又は滅菌処理し、均質化、冷却するか、又は油脂、乳蛋白質、乳化剤及び水を含む原料を混合して、予備乳化、均質化、殺菌又は滅菌処理し、再均質化、冷却する方法が一般的に採用されている。
特許文献1では、クリーム類に、不活性ガスを通気して液中溶存酸素を低下せしめたのちに、脱泡処理を行い、ついで加熱殺菌することを特徴とする、風味が良く、流通・保存時の乳化安定性にすぐれたクリーム類の製造法が提案されているが、不活性ガス通気装置や別途脱泡処理工程を必要とし作業が煩雑であるという問題を有している。
特許文献2では、ミセル状蛋白質を含有し、油滴のメジアン径が0.3〜5.0μmであり、油脂含量が20〜60重量%の水中油型乳化物の製造方法であって、原料となる水中油型乳化物に含まれる油滴のメジアン径を段階的に小さくしてゆき、該油滴の最終メジアン径を0.3〜5.0μmの範囲の所望の粒径とすることを特徴とする水中油型乳化物の製造方法が提案されているが、特定の蛋白質であるミセル状蛋白質を使用するものである。
特許文献3では、予備乳化工程に次ぐ均質化工程において、回転式乳化機を用いて、25m/s以上の高周速で均質化処理することを特徴とする水中油型乳化油脂組成物の製造方法が提案されているが、期待する風味が得られなかった。
特許文献4では、油脂原料を含む油相部と水相部とを、加温混合する工程、予備乳化する工程、殺菌する工程、均質化する工程、および冷却する工程からなる水中油型乳化組成物の製造方法において、油相部と水相部を加温混合する工程において第一のクリームを添加すること、および予備乳化する工程の後に第二のクリームを添加することを特徴とする水中油型乳化組成物の製造方法が提案されているが、これも期待する風味が得られなかった。
In recent years, demands for quality (physical properties, physiological activity, flavor), safety and security for foods have become higher. The oil-in-water emulsion is not an exception, and the demand for flavor is particularly remarkable only because it is used in luxury goods such as Western confectionery and desserts.
Specifically, creams that are oil-in-water emulsions can be added to desserts such as pudding and jelly, used for kneading pudding, bavalore, jelly, etc. Foaming oil-in-water emulsions (whipped creams) that are used to decorate cakes, sand and the like after foaming are used.
Oil-in-water emulsions include fresh creams, compound creams, vegetable creams, raw milk, concentrated milk, oil-in-water emulsions containing nonfat milk solids, and the like.
These oil-in-water emulsions are mainly mixed with raw materials containing fats and oils, milk proteins, emulsifiers and water, pre-emulsified, sterilized or sterilized, homogenized and cooled, or oils and fats, milk proteins, emulsifiers and water. Generally, a method of mixing raw materials containing, pre-emulsifying, homogenizing, sterilizing or sterilizing, re-homogenizing and cooling is generally employed.
Patent Document 1 is characterized by a good flavor, distribution and storage, characterized by deaeration treatment after aeration of inert gas in creams to lower dissolved oxygen in the liquid, followed by heat sterilization. Although a method for producing creams with excellent emulsification stability at the time has been proposed, there is a problem that an inert gas ventilation device and a separate defoaming treatment step are required, and the work is complicated.
In Patent Document 2, a method for producing an oil-in-water emulsion containing a micellar protein, having a median diameter of oil droplets of 0.3 to 5.0 μm and a fat content of 20 to 60% by weight, Gradually reducing the median diameter of the oil droplets contained in the oil-in-water emulsion to become the desired median diameter in the range of 0.3 to 5.0 μm. A characteristic method for producing an oil-in-water emulsion has been proposed, but a specific protein, a micellar protein, is used.
In patent document 3, in the homogenization process following the pre-emulsification process, using a rotary emulsifier, the homogenization process is performed at a high peripheral speed of 25 m / s or more. Although a method has been proposed, the expected flavor was not obtained.
In Patent Document 4, an oil-in-water emulsion composition comprising a step of heating and mixing an oil phase portion and an aqueous phase portion containing an oil raw material, a pre-emulsification step, a sterilization step, a homogenization step, and a cooling step. In a method for producing a product, an oil-in-water solution characterized by adding a first cream in a step of heating and mixing an oil phase part and an aqueous phase part, and adding a second cream after the step of pre-emulsifying Although the manufacturing method of the type | mold emulsion composition is proposed, the flavor which also anticipated this was not obtained.
本発明の目的は、幅広い乳原料が使用でき乳原料が少なくても、乳味、乳感に優れ、生クリームの様な程良い脂肪感を持った水中油型乳化物を提供することであり、起泡性水中油型乳化物の場合は粘度、ホイップした際の作業性、起泡性、保形性、外観に優れ、起泡物の口溶け、食感、乳味、程良い脂肪感、乳感に優れた水中油型乳化物を提供する事にある。 An object of the present invention is to provide an oil-in-water emulsion having excellent milk taste and milk feeling and having a moderate fat feeling like fresh cream even when a wide range of milk ingredients can be used and there are few milk ingredients. In the case of a foamable oil-in-water emulsion, it has excellent viscosity, workability when whipped, foamability, shape retention, appearance, melted foam mouthfeel, texture, milky taste, moderate fatiness, The object is to provide an oil-in-water emulsion excellent in milk feeling.
本発明の課題を達成するため、本発明者らは、水中油型乳化物を調製する予備乳化工程において、乳蛋白質と乳化剤を用いて乳化を安定化させるのに際して、これら界面活性物質の水中油型乳化物中での存在状態が当該乳化物の風味に大きく関連しているという知見に基づき本発明を完成するに至った。
即ち本発明の第1は、油脂、乳蛋白質、乳化剤及び水を原料とする水中油型乳化物の製造法であって、水中油型乳化物を調製するに際して、乳蛋白質と乳化剤を別途に用いる方法であり、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理する水中油型乳化物(B)の製造法である。第2は、乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製する際の品温が40〜95℃の範囲で実施する、第1記載の水中油型乳化物(B)の製造法である。第3は、乳化剤が水分散性乳化剤及び油分散性乳化剤から選択される1種以上のものである、第1記載の水中油型乳化物(B)の製造法である。第4は、乳蛋白質を用いる際の水中油型乳化物(A)の品温が40〜80℃の範囲である、第1記載の水中油型乳化物(B)の製造法である。第5は、殺菌又は滅菌処理前の水中油型乳化物(B)の油脂粒子のメジアン径が0.3〜100μmの範囲である、第1記載の水中油型乳化物(B)の製造法である。第6は、最終の水中油型乳化物(B)の油脂粒子のメジアン径が0.3〜5.0μmの範囲である、第1記載の水中油型乳化物(B)の製造法である。第7は、水中油型乳化物(B)が起泡性である、第1〜第6何れか1に記載の水中油型乳化物(B)の製造法である。第8は、第1〜第6何れか1に記載の方法によって製造された水中油型乳化物(B)に乳脂含有乳化物を混合してなる、乳脂・植脂含有水中油型乳化物である。第9は、乳脂・植脂含有水中油型乳化物が起泡性である、第8記載の乳脂・植脂含有水中油型乳化物である。
In order to achieve the object of the present invention, the inventors of the present invention, in the pre-emulsification step for preparing an oil-in-water emulsion, use a milk protein and an emulsifier to stabilize the emulsification. The present invention has been completed based on the knowledge that the state of presence in the mold emulsion is greatly related to the flavor of the emulsion.
That is, the first aspect of the present invention is a method for producing an oil-in-water emulsion using oil, fat, milk protein, emulsifier and water as raw materials. When preparing an oil-in-water emulsion, the milk protein and the emulsifier are separately used. This method comprises preparing an oil-in-water emulsion (A) using oils and fats, an emulsifier and water, excluding milk protein in advance, and then preparing an oil-in-water emulsion (B) using milk protein, and then sterilizing or This is a method for producing an oil-in-water emulsion (B) to be sterilized. Second, the oil-in-water type according to the first aspect, wherein the product temperature is 40 to 95 ° C. when the oil-in-water emulsion (A) is prepared using fats and oils, an emulsifier and water, excluding milk protein. It is a manufacturing method of an emulsion (B). The third is a method for producing the oil-in-water emulsion (B) according to the first aspect, wherein the emulsifier is at least one selected from a water-dispersible emulsifier and an oil-dispersible emulsifier. 4th is a manufacturing method of the oil-in-water type emulsion (B) of the 1st description whose product temperature of the oil-in-water type emulsion (A) at the time of using milk protein is the range of 40-80 degreeC. 5th is a manufacturing method of the oil-in-water emulsion (B) of 1st description whose median diameter of the oil-and-fat particle | grains of the oil-in-water emulsion (B) before sterilization or sterilization processing is the range of 0.3-100 micrometers. It is. 6th is the manufacturing method of the oil-in-water emulsion (B) of 1st aspect whose median diameter of the fats and oils particle | grains of the final oil-in-water emulsion (B) is 0.3-5.0 micrometers. . 7th is a manufacturing method of the oil-in-water type emulsion (B) of any one of 1st-6th whose oil-in-water type emulsion (B) is foamability. Eighth is an oil-in-water emulsion containing milk fat / vegetable fat mixed with an oil-in-water emulsion (B) produced by the method according to any one of the first to sixth, is there. The ninth is the oil-in-water emulsion containing milk fat / vegetable oil according to item 8, wherein the oil-in-water emulsion containing milk fat / vegetable oil is foamable.
幅広い乳原料が使用でき乳原料が少なくても、特に生クリームが少なくても、乳味、乳感に優れ、生クリームの様な程良い脂肪感を持った水中油型乳化物を提供することであり、起泡性水中油型乳化物の場合は粘度、ホイップした際の作業性、起泡性、保形性、外観に優れ、起泡物の口溶け、食感、乳味、程良い脂肪感、乳感に優れた水中油型乳化物を提供する事が可能になった。 To provide an oil-in-water emulsion that has excellent milk taste and milk feeling and has a good fat feeling like fresh cream, even if a wide range of milk ingredients can be used and there are few milk ingredients, especially fresh cream. In the case of foamable oil-in-water emulsions, it has excellent viscosity, workability when whipped, foamability, shape retention, appearance, melted foam mouthfeel, texture, milky taste, moderate fat It became possible to provide an oil-in-water emulsion excellent in feel and milkiness.
本発明の水中油型乳化物(B)の製造法は、油脂、乳蛋白質、乳化剤及び水を含む原料を混合して、予備乳化、殺菌又は滅菌処理し、均質化、冷却するか、又は油脂、蛋白質、乳化剤及び水を含む原料を混合して、予備乳化、均質化、殺菌又は滅菌処理し、再均質化、冷却する方法であり、水中油型乳化物を調製するに際して、乳蛋白質と乳化剤を別途に用いる方法であり、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理する水中油型乳化物(B)の製造法である。 The method for producing the oil-in-water emulsion (B) of the present invention comprises mixing raw materials containing fats and oils, milk proteins, emulsifiers and water, pre-emulsifying, sterilizing or sterilizing, homogenizing, cooling, or fats and oils , Protein, emulsifier and water-containing raw materials are mixed, pre-emulsified, homogenized, sterilized or sterilized, re-homogenized and cooled. When preparing an oil-in-water emulsion, milk protein and emulsifier The oil-in-water emulsion (A) is prepared using oils and fats, an emulsifier and water in advance, excluding milk protein, and then oil-in-water emulsion (B) using milk protein. Then, it is a manufacturing method of the oil-in-water emulsion (B) sterilized or sterilized.
本発明の水中油型乳化物(A)の製造法は、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製するのであるが、温水に水分散性乳化剤を分散・溶解し水相とし、別に融解した油脂に油分散性乳化剤を分散・溶解し油相とする。水相と油相を混合して水中油型乳化物(A)を得ることが出来る。
混合する方法として、バッチ攪拌と連続攪拌が例示できる。バッチ攪拌としては、4枚羽根(Fuji Electric Co..Ltd.)、TKホモミキサー(プライミクス株式会社)、ラボリューション(プライミクス株式会社)、クレアミックス(エム・テクニック(株))が例示できる。連続攪拌としては、インラインミキサー(Silverson Machines,Inc)、T.K.パイプラインホモミキサー(プライミックス株式会社)、 コロイドミル(株式会社イワキ)が例示できる。
攪拌以外の混合方法としての乳化・微粒化処理として、ホモゲナイザー(三和機械株式会社)、高圧ホモゲナイザーが例示できる。
水中油型乳化物(A)を調製する際の品温が40〜95℃の範囲で実施するのが好ましく、より好ましくは50〜80℃の範囲であり、更に好ましくは55〜70℃の範囲で実施する。品温が低すぎると油脂や乳化剤の結晶が析出して乳化が不安定になったり、次の段階での乳蛋白質の分散・溶解を妨げたりする。逆に品温が高すぎると、粒状又は粉末状の乳原料を使用する場合は、次の段階での乳蛋白質を分散・溶解する際にダマになり作業性が悪くなったり、乳蛋白質が熱変性を起こしたりすることで乳化が不安定になったりする。そして、次の段階での乳蛋白質を分散・溶解するに適度な品温に調整するのに時間を要し好ましくない。
In the method for producing an oil-in-water emulsion (A) of the present invention, an oil-in-water emulsion (A) is prepared using an oil, an emulsifier and water excluding milk protein in advance. An emulsifier is dispersed and dissolved into an aqueous phase, and an oil-dispersible emulsifier is dispersed and dissolved in a separately melted oil to obtain an oil phase. An oil-in-water emulsion (A) can be obtained by mixing an aqueous phase and an oil phase.
Examples of the mixing method include batch stirring and continuous stirring. Examples of batch agitation include four blades (Fuji Electric Co., Ltd.), TK homomixer (Primics Co., Ltd.), laboratory (Primics Co., Ltd.), and Claremix (M Technique Co., Ltd.). As continuous stirring, an in-line mixer (Silverson Machines, Inc), T.M. K. Examples include a pipeline homomixer (Plymix Co., Ltd.) and a colloid mill (Iwaki Co., Ltd.).
Examples of the emulsification and atomization treatment as a mixing method other than stirring include a homogenizer (Sanwa Machinery Co., Ltd.) and a high-pressure homogenizer.
It is preferable that the product temperature when preparing the oil-in-water emulsion (A) is in the range of 40 to 95 ° C, more preferably in the range of 50 to 80 ° C, still more preferably in the range of 55 to 70 ° C. To implement. If the product temperature is too low, oil and emulsifier crystals will precipitate, making the emulsification unstable, and preventing the milk protein from dispersing and dissolving in the next step. On the other hand, if the product temperature is too high, when using granular or powdered milk raw materials, the milk protein in the next stage becomes lumpy when it is dispersed and dissolved, resulting in poor workability or milk protein heat. Emulsification may become unstable due to denaturation. Further, it takes time to adjust the temperature to an appropriate product temperature to disperse and dissolve the milk protein in the next step, which is not preferable.
本発明では、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製するのであるが、乳化剤が水分散性乳化剤及び油分散性乳化剤から選択される1種以上のものであるのが好ましい。
水分散性乳化剤としては、酵素処理レシチン、モノグリセリド、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステルが挙げられ、水に分散したコロイド状態で使用するのが好ましい。
油分散性乳化剤としては、レシチン、ソルビタン脂肪酸エステル、モノグリセリド、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステルが挙げられ、油に分散したコロイド状態で使用するのが好ましい。
In the present invention, the oil-in-water emulsion (A) is prepared using an oil and fat, an emulsifier and water excluding milk protein in advance, and the emulsifier is selected from a water-dispersible emulsifier and an oil-dispersible emulsifier. The above is preferable.
Examples of the water-dispersible emulsifier include enzyme-treated lecithin, monoglyceride, organic acid monoglyceride, polyglycerin fatty acid ester, sucrose fatty acid ester, and polyoxyethylene sorbitan fatty acid ester, which are preferably used in a colloidal state dispersed in water.
Examples of the oil-dispersible emulsifier include lecithin, sorbitan fatty acid ester, monoglyceride, organic acid monoglyceride, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and are used in a colloidal state dispersed in oil. preferable.
本発明では、乳化剤が水分散性乳化剤及び油分散性乳化剤から選択される1種以上のものであるが、水分散性乳化剤及び油分散性乳化剤の使用量は、水中油型乳化物(B)全体に対して、0.05〜2重量%が好ましく、より好ましくは0.05〜1.5重量%であり、更に好ましくは0.05〜1.2重量%である。水分散性乳化剤及び油分散性乳化剤の使用量が少ないと水中油型乳化物(B)の乳化安定性が悪くなる。逆に多すぎると乳化剤の味を呈するようになり風味が悪くなる。 In the present invention, the emulsifier is at least one selected from a water-dispersible emulsifier and an oil-dispersible emulsifier. The amount of the water-dispersible emulsifier and the oil-dispersible emulsifier used is an oil-in-water emulsion (B). 0.05-2 weight% is preferable with respect to the whole, More preferably, it is 0.05-1.5 weight%, More preferably, it is 0.05-1.2 weight%. When there are few usage-amounts of a water dispersible emulsifier and an oil dispersible emulsifier, the emulsification stability of an oil-in-water emulsion (B) will worsen. On the other hand, if the amount is too large, the emulsifier taste is exhibited and the flavor is deteriorated.
本発明は、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理する水中油型乳化物(B)の製造法である。
そして、本発明では、調製された水中油型乳化物(A)の油脂粒子のメジアン径が0.3〜500μmの範囲であるのが好ましく、より好ましくは0.5〜50μmの範囲であり、更に好ましくは0.8〜10μmの範囲である。油脂粒子のメジアン径が小さ過ぎると、それ自体で不具合は起こらないが、小さくするのに多大なエネルギーを与える必要があるのにも係わらずそれに見合った効果は得られない。逆に油脂粒子のメジアン径が大き過ぎると油脂粒子同士が合一して油相と水相の相状態になり、水中油型乳化物(A)の状態が従来の調合方法である、乳蛋白質と乳化剤を同時に用いる方法の乳化状態に近い状態になるため、本願の発明の効果が得難くなる。
In the present invention, an oil-in-water emulsion (A) is prepared using an oil and fat, an emulsifier and water, excluding milk protein in advance, and then converted into an oil-in-water emulsion (B) using milk protein. This is a method for producing an oil-in-water emulsion (B) to be sterilized.
And in this invention, it is preferable that the median diameter of the oil-fat particle | grains of the prepared oil-in-water emulsion (A) is 0.3-500 micrometers, More preferably, it is the range of 0.5-50 micrometers, More preferably, it is the range of 0.8-10 micrometers. If the median diameter of the fat and oil particles is too small, there is no problem in itself, but an effect commensurate with it cannot be obtained even though a large amount of energy needs to be applied to make the particle small. Conversely, when the median diameter of the fat and oil particles is too large, the fat and oil particles are united to form a phase of an oil phase and an aqueous phase, and the state of the oil-in-water emulsion (A) is a conventional preparation method. Therefore, it is difficult to obtain the effect of the present invention.
本発明では、水中油型乳化物(A)を調製した後に、乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理する必要がある。
乳蛋白質を用いて水中油型乳化物(B)を得る方法としては、水中油型乳化物(A)と同様の混合・乳化方法が採用でき、バッチ攪拌、連続攪拌が例示できる。
使用する乳蛋白質としては、乳蛋白質が分散・溶解状態で存在している乳原料も、乳蛋白質が粒状又は粉末状の乳原料も何れも使用することが出来る。
乳蛋白質が分散・溶解状態で存在している乳原料としては、生乳、牛乳、脱脂乳、脱脂濃縮乳、生クリーム、濃縮乳、無糖練乳、加糖練乳が例示できる。
乳蛋白質が粒状又は粉末状の乳原料としては、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、酸カゼイン、レンネットカゼイン、若しくはカゼインナトリウム、カゼインカルシウム、カゼインカリウム等のカゼイン類、またはトータルミルクプロテインが例示できる。
これらの乳原料においては、乳脂肪が乳蛋白質に比して相対的に少ない原料が好ましい。乳脂肪を多く含む原料を使用した場合、新たな油脂粒子が形成されることによって、本願発明の効果が得難くなる。
乳蛋白質が分散・溶解状態で存在している乳原料としては、生乳、牛乳、脱脂乳、脱脂濃縮乳が好ましい。
乳蛋白質が粒状又は粉末状の乳原料としては、脱脂粉乳、バターミルクパウダー、ホエー蛋白、酸カゼイン、レンネットカゼイン、若しくはカゼインナトリウム、カゼインカルシウム、カゼインカリウム等のカゼイン類、またはトータルミルクプロテインが好ましい。
In this invention, after preparing an oil-in-water emulsion (A), it is necessary to use milk protein as an oil-in-water emulsion (B), and to sterilize or sterilize after that.
As a method for obtaining an oil-in-water emulsion (B) using milk protein, the same mixing and emulsification methods as in the oil-in-water emulsion (A) can be adopted, and batch stirring and continuous stirring can be exemplified.
As the milk protein to be used, both a milk raw material in which the milk protein is present in a dispersed / dissolved state and a milk raw material in which the milk protein is granular or powdery can be used.
Examples of the milk raw material in which the milk protein is present in a dispersed / dissolved state include raw milk, cow milk, skim milk, skim concentrated milk, fresh cream, concentrated milk, sugar-free condensed milk, and sweetened condensed milk.
Milk protein in the form of granular or powdered milk protein includes whole milk powder, skim milk powder, buttermilk powder, whey protein, acid casein, rennet casein, or caseins such as sodium caseinate, calcium caseinate, potassium casein, or total An example is milk protein.
In these milk raw materials, raw materials having relatively less milk fat than milk proteins are preferable. When a raw material containing a large amount of milk fat is used, it is difficult to obtain the effects of the present invention by forming new oil particles.
Raw milk, cow milk, skim milk, and skim concentrated milk are preferred as the milk raw material in which the milk protein is present in a dispersed / dissolved state.
As milk material in which the milk protein is granular or powdery, skim milk powder, buttermilk powder, whey protein, acid casein, rennet casein, casein such as sodium caseinate, calcium caseinate, potassium casein, or total milk protein is preferable. .
本発明では、乳蛋白質の含有量は、水中油型乳化物(B)全体に対して、0.2〜7重量%が好ましく、より好ましくは0.3〜6重量%であり、更に好ましくは0.3〜5重量%である。乳蛋白質の含有量が少ないと水中油型乳化物(B)の乳化安定性が悪くなる。逆に多すぎると殺菌又は滅菌処理で風味劣化を起こし易くなる。 In the present invention, the milk protein content is preferably 0.2 to 7% by weight, more preferably 0.3 to 6% by weight, and still more preferably, based on the entire oil-in-water emulsion (B). 0.3 to 5% by weight. When there is little content of milk protein, the emulsification stability of an oil-in-water emulsion (B) will worsen. On the other hand, if the amount is too large, flavor deterioration tends to occur during sterilization or sterilization.
本発明では、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理するのであるが、乳蛋白質を用いる際の水中油型乳化物(A)の品温が40〜80℃の範囲であるであるのが好ましく、より好ましくは50〜75℃の範囲であり、更に好ましくは55〜70℃の範囲である。品温が低すぎると乳蛋白質が分散・溶解しにくくなる。逆に品温が高すぎると添加した乳蛋白質が熱変性を起こし、最終製品での風味が劣るものになったり、最終製品の乳化安定性に悪影響を及ぼす。 In the present invention, an oil-in-water emulsion (A) is prepared using an oil and fat, an emulsifier and water, excluding milk protein in advance, and then converted into an oil-in-water emulsion (B) using milk protein. Although sterilization is performed, the product temperature of the oil-in-water emulsion (A) when using milk protein is preferably in the range of 40 to 80 ° C, more preferably in the range of 50 to 75 ° C. More preferably, it is the range of 55-70 degreeC. If the product temperature is too low, the milk protein is difficult to disperse and dissolve. On the other hand, if the product temperature is too high, the added milk protein will be thermally denatured, resulting in poor flavor in the final product, and adversely affecting the emulsion stability of the final product.
本発明に使用する油脂としては、食用として使用できるものを広く採用することができ、例えばナタネ油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、胡麻油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂並びに乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂が例示でき、上記油脂類の単独または混合油あるいはそれらの硬化、分別、エステル交換等を施した加工油脂(融点15〜40℃程度のもの)が例示できる。 本発明においては上記で例示した何れの油脂も使用できる。 As the fats and oils used in the present invention, those that can be used for food can be widely adopted, such as rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, Examples include vegetable oils such as kapok oil, sesame oil, evening primrose oil, palm oil, shea fat, monkey fat, cacao fat, palm oil, palm kernel oil, and animal fats such as milk fat, beef fat, pork fat, fish oil, whale oil, etc. Examples thereof include single or mixed oils of the above fats and oils or processed oils and fats (curing points of about 15 to 40 ° C.) subjected to curing, fractionation, transesterification and the like thereof. In the present invention, any of the oils and fats exemplified above can be used.
本発明の水中油型乳化物(B)の製造法としては、予備乳化工程において予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とする方法であり、その後、殺菌又は滅菌処理するのであるが、予備乳化工程以降の工程は一般的なクリーム類を製造する要領で行うことができる。
殺菌又は滅菌処理については、保存性の点で滅菌処理することが好ましい。
As a method for producing the oil-in-water emulsion (B) of the present invention, an oil-in-water emulsion (A) is prepared using an oil, an emulsifier and water, excluding milk protein in advance in the preliminary emulsification step, and then milk protein. In this method, an oil-in-water emulsion (B) is used and then sterilized or sterilized, but the steps after the preliminary emulsification step can be carried out in the same manner as for producing general creams.
The sterilization or sterilization treatment is preferably sterilization from the viewpoint of storage stability.
滅菌処理には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CP−UHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。 There are two types of sterilization treatment: indirect heating method and direct heating method. APV plate type UHT treatment device (manufactured by APV Co., Ltd.), CP-UHT sterilization device (Climati Package Co., Ltd.) Manufactured), Stork tubular type sterilizer (manufactured by STORK Co., Ltd.), Concer scraping type UHT sterilizer (manufactured by Tetra Pak Alpha Label Co., Ltd.), etc., but not particularly limited to these. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval Co., Ltd.). UHT sterilizers such as Ragia UHT sterilizer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash and Silkeborg Co., Ltd.), and any of these devices may be used.
本発明の殺菌又は滅菌処理前の水中油型乳化物(B)の油脂粒子のメジアン径が0.3〜100μmの範囲であるのが好ましく、より好ましくは0.5〜50μmの範囲であり、更に好ましくは0.7〜5.0μmの範囲である。油脂粒子のメジアン径が小さすぎるとそれ自体で不具合は起こらないが、小さくするのに多大なエネルギーを与える必要があるのにも関わらずそれに見合った効果は得られない。逆に油脂粒子のメジアン径が大き過ぎると殺菌又は滅菌処理時に油脂粒子同士の合一が起きやすくなり乳化が不安定になる。 It is preferable that the median diameter of the fat and oil particles of the oil-in-water emulsion (B) before sterilization or sterilization treatment of the present invention is in the range of 0.3 to 100 μm, more preferably in the range of 0.5 to 50 μm. More preferably, it is the range of 0.7-5.0 micrometers. If the median diameter of the fat and oil particles is too small, there is no problem in itself. However, although it is necessary to give a large amount of energy to reduce the oil particle, an effect commensurate with it cannot be obtained. Conversely, if the median diameter of the fat and oil particles is too large, coalescence between the fat and oil particles tends to occur during sterilization or sterilization treatment, and the emulsification becomes unstable.
本発明の殺菌又は滅菌処理後の最終製品の水中油型乳化物(B)の油脂粒子のメジアン径が0.3〜5.0μmの範囲であるのが好ましく、より好ましくは0.5〜3.5μmの範囲であり、更に好ましくは0.5〜3.0μmの範囲である。油脂粒子のメジアン径が小さすぎるとホイップする際、ホイップしにくくなったり、ホイップしたものの保形性が悪くなったり、逆にホイップしたものの硬さが硬くなり過ぎたりと、ホイップ後の物性の安定性に問題を生じやすくなる。逆に油脂粒子のメジアン径が大きすぎると保存中にクリーミングを発生したり、油脂粒子同士が合一しやすくなることでボテ(可塑化)が発生するなど、クリーム原液の安定性が悪くなる。 The median diameter of the fat particles of the oil-in-water emulsion (B) of the final product after sterilization or sterilization treatment of the present invention is preferably in the range of 0.3 to 5.0 μm, more preferably 0.5 to 3. The range is 0.5 μm, and more preferably 0.5 to 3.0 μm. If the median diameter of the fat and oil particles is too small, when whipping, it becomes difficult to whipped, the shape retention of the whipped product becomes worse, or conversely the hardness of the whipped product becomes too hard, the stability of the physical properties after whipping It tends to cause problems with sex. On the other hand, if the median diameter of the fat and oil particles is too large, creaming will occur during storage, and the fat and oil particles will easily coalesce with each other, resulting in poor stability of the cream stock solution.
本発明の水中油型乳化物又は起泡性水中油型乳化物の油脂分としては、10〜50重量%であり、好ましくは15〜48重量%であり、更に好ましくは20〜48重量%である。油脂分が多すぎると水中油型乳化物又は起泡性水中油型乳化物がボテ(可塑化状態)易くなり、少なすぎると、水中油型乳化物の場合は粘度が低くなり、流動性が乏しくなる。そして、起泡性水中油型乳化物の場合は起泡性、保形性が悪化する傾向になる。 The oil and fat content of the oil-in-water emulsion or foamable oil-in-water emulsion of the present invention is 10 to 50% by weight, preferably 15 to 48% by weight, and more preferably 20 to 48% by weight. is there. If the oil / fat content is too high, the oil-in-water emulsion or the foamable oil-in-water emulsion tends to be bottling (plasticized state), and if it is too low, the oil-in-water emulsion has low viscosity and fluidity. Become scarce. And in the case of a foamable oil-in-water emulsion, foamability and shape retention tend to deteriorate.
本発明の水中油型乳化物、又は起泡性水中油型乳化物に使用する糖類としては、ショ糖、果糖、ブドウ糖、乳糖、麦芽糖、転化糖、トレハロース、糖アルコール、コーンシロップ、水あめ、デキストリンが例示できる。糖アルコールとしてはエリスリトール、マンニトール、ソルビトール、キシリトール等の単糖アルコール、イソマルチトール、マルチトール、ラクチトール等の2糖アルコール、マルトトリイトール、イソマルトトリイトール、パニトール等の3糖アルコール、オリゴ糖アルコール等の4糖以上の糖アルコール、還元澱粉糖化物、還元澱粉分解物が例示できる。
そして、乳蛋白質と共存している乳糖は本発明の糖類に含まれる。
糖類の使用量は概ね0.5〜20重量%が好ましく、より好ましくは0.5〜10重量%、更に0.5〜6重量%が好まく、0.5〜4.5重量%が最も好ましい。
Examples of the saccharide used in the oil-in-water emulsion or foamable oil-in-water emulsion of the present invention include sucrose, fructose, glucose, lactose, maltose, invert sugar, trehalose, sugar alcohol, corn syrup, syrup, dextrin Can be illustrated. Sugar alcohols include monosaccharide alcohols such as erythritol, mannitol, sorbitol, and xylitol, disaccharide alcohols such as isomaltitol, maltitol, and lactitol, trisaccharide alcohols such as maltotriitol, isomaltolitol, and panitol, and oligosaccharide alcohols. Examples thereof include sugar alcohols having 4 or more sugars such as reduced starch saccharified product and reduced starch decomposed product.
And the lactose which coexists with milk protein is contained in the saccharide | sugar of this invention.
The amount of saccharide used is generally preferably 0.5 to 20% by weight, more preferably 0.5 to 10% by weight, further preferably 0.5 to 6% by weight, most preferably 0.5 to 4.5% by weight. preferable.
本発明の水中油型乳化物、又は起泡性水中油型乳化物については増粘多糖類を使用するのが好ましく、増粘多糖類としては、ジェランガム、キサンタンガム、ローカストビーンガム、プルラン、グァーガム、サイリウムシードガム、水溶性大豆多糖類、カラギーナン、タマリンド種子ガム及びタラガムから選択される1種又は2種以上の増粘多糖類が好ましく、更にジェランガム、キサンタンガム、プルラン、グァーガム、サイリウムシードガム、水溶性大豆多糖類、カラギーナン及びタマリンド種子ガムから選択される1種又は2種以上の増粘多糖類が好ましい。 For the oil-in-water emulsion or the foamable oil-in-water emulsion of the present invention, it is preferable to use a thickening polysaccharide. Examples of the thickening polysaccharide include gellan gum, xanthan gum, locust bean gum, pullulan, guar gum, One or more thickening polysaccharides selected from psyllium seed gum, water-soluble soybean polysaccharide, carrageenan, tamarind seed gum and tara gum are preferred, and gellan gum, xanthan gum, pullulan, guar gum, psyllium seed gum, water-soluble One or more thickening polysaccharides selected from soybean polysaccharides, carrageenan and tamarind seed gum are preferred.
本発明の水中油型乳化物、又は起泡性水中油型乳化物については、各種塩類を使用するのが好ましく、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが望ましい。
その他所望により香料、着色剤、保存料等を使用することができる。
For the oil-in-water emulsion or foamable oil-in-water emulsion of the present invention, it is preferable to use various salts, such as hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate, etc. These are preferably used alone or in combination of two or more.
In addition, a fragrance, a colorant, a preservative and the like can be used as desired.
更に、乳味を期待する場合は、本発明の水中油型乳化物(B)に、乳脂含有乳化物を混合して乳脂・植脂含有水中油型乳化物を得ることができる。
本発明の乳脂含有乳化物とは乳脂が含まれている乳化物であれば何れの乳化物でもよく、生クリーム、コンパウンドクリームが例示できる。又、牛乳、生クリーム、バター、バターオイル、動植物性油脂を使用し任意の油脂分に再構成した乳化物であっても良い。
本発明の水中油型乳化物(B)と乳脂含有乳化物の混合であるが、混合割合は任意であり、混合の時期は二つの乳化物が完成していれば何れの時期でも良いが、好ましくは、水中油型乳化物が均質化冷却された後に乳脂含有乳化物を混合するのが好ましい。
Furthermore, when expecting milky taste, milk fat containing emulsion can be mixed with the oil-in-water emulsion (B) of this invention, and milk fat and vegetation containing oil-in-water emulsion can be obtained.
The milk fat-containing emulsion of the present invention may be any emulsion as long as it contains milk fat, and examples thereof include fresh cream and compound cream. Moreover, the emulsion reconstituted in arbitrary fats and oils using milk, fresh cream, butter, butter oil, and animal and vegetable fats and oils may be used.
The oil-in-water emulsion (B) of the present invention and milk fat-containing emulsion are mixed, but the mixing ratio is arbitrary, and the timing of mixing may be any time as long as two emulsions are completed, Preferably, the milk fat-containing emulsion is mixed after the oil-in-water emulsion is homogenized and cooled.
本発明の水中油型乳化物(B)の製造法は、水中油型乳化物を調製するに際して、乳蛋白質と乳化剤を別途に用いる方法であり、予め乳蛋白質を除く、油脂、乳化剤及び水を用いて水中油型乳化物(A)を調製し、その後乳蛋白質を用いて水中油型乳化物(B)とし、その後、殺菌又は滅菌処理する製造法である。
従来の製造法は、乳蛋白質と乳化剤を同時に用いる方法であり、あくまで推測の域をでないが、本願発明の方法を採用することによって、従来の方法に比して水中油型乳化物においては、水相側に乳蛋白質が多く存在することになり、そのことによって、本願発明の効果である、水中油型乳化物に乳味、乳感、生クリームの様な程良い脂肪感を付与することが可能になったと考えている。
The method for producing an oil-in-water emulsion (B) of the present invention is a method in which a milk protein and an emulsifier are separately used when preparing an oil-in-water emulsion. The oil-in-water emulsion (A) is used to prepare an oil-in-water emulsion (B) using milk protein, and then sterilized or sterilized.
The conventional production method is a method that uses milk protein and an emulsifier at the same time, and it is not a speculative area, but by adopting the method of the present invention, in an oil-in-water emulsion compared to the conventional method, There will be a lot of milk protein on the water phase side, which gives the oil-in-water emulsion, which is the effect of the present invention, a moderate fat feeling such as milky taste, milky feeling, and fresh cream. I think that is possible.
以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。また、結果については以下の方法で評価した。 EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis. The results were evaluated by the following method.
水中油型乳化物の評価方法
水中油型乳化物の粘度、ボテテスト(水中油型乳化物の乳化状態の安定性)、油脂粒子径を評価した。方法は、
粘度:水中油型乳化物の粘度の測定は、B型粘度計(株式会社東京計器製)にて、2号ローター、30rpmの条件下で行った。
ボテテスト:水中油型乳化物を100ml容ビーカーに50g採り、20℃で2時間インキュベートし、その後5分間攪拌した時のボテの発生の有無を確認した。
油脂粒子径:レーザー回折式粒度分布測定装置(株式会社島津製作所製、SALD−2200)を用いて、水中油型乳化物を蒸留水で測定可能範囲に希釈し測定後、データとして出力される。油脂粒子径は積算50%径のメジアン径、積算25%径、積算75%径を求めた。
Evaluation Method of Oil-in-Water Emulsion Viscosity, bottom test (stability of emulsified state of oil-in-water emulsion) and oil particle size were evaluated. The method is
Viscosity: The viscosity of the oil-in-water emulsion was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd.) under the conditions of No. 2 rotor and 30 rpm.
Botte test: 50 g of an oil-in-water emulsion was taken in a 100 ml beaker, incubated at 20 ° C. for 2 hours, and then checked for the presence or absence of boiling when stirred for 5 minutes.
Fat and oil particle diameter: Using a laser diffraction particle size distribution measuring device (SALD-2200, manufactured by Shimadzu Corporation), the oil-in-water emulsion is diluted to a measurable range with distilled water, and is output as data after measurement. The oil and fat particle diameter was determined as a median diameter of 50% cumulative diameter, 25% cumulative diameter, and 75% cumulative diameter.
・水中油型乳化物を起泡させた場合の評価方法
ホイップ時間:水中油型乳化物1kgをホバートミキサー(HOBART CORPORATION製 MODEL N−5)3速(300rpm)にてホイップし、最適気泡状態に達するまでの時間。
オーバーラン(%):[(一定容積の水中油型乳化物の重量)−(一定容積の気泡後の水中油型乳化物重量)] ÷ (一定容量の気泡後の水中油型乳化物の重量)×100
保形性:造花した起泡物を15℃で24時間保存した場合の形の変化を評価する。「良好」「やや不良」「不良」の三段階で評価した。
風味の評価方法
起泡したクリームの口どけ、組織・食感、乳味、程良い脂肪感、乳感を評価
五段階評価 5;良好 4;やや良好 3;可
2;やや悪い 1;悪い
・ Evaluation method when foaming an oil-in-water emulsion: Whip time: 1 kg of an oil-in-water emulsion is whipped with a Hobart mixer (MODEL N-5, manufactured by HOBART CORPORATION) 3rd speed (300 rpm) to obtain an optimum bubble state Time to reach.
Overrun (%): [(weight of a fixed volume of oil-in-water emulsion) − (weight of oil-in-water emulsion after a fixed volume of bubbles)] ÷ (weight of oil-in-water emulsion after a fixed volume of bubbles) ) × 100
Shape retention: The change in shape when the artificial foam is stored at 15 ° C. for 24 hours is evaluated. Evaluation was made in three stages: “good”, “slightly bad”, and “bad”.
Flavor evaluation method Evaluate the mouth of foamed cream, texture, texture, milky taste, moderate fat feeling, milky feeling Five-step evaluation 5; Good 4; Slightly good 3;
2; Somewhat bad 1; Bad
・水中油型乳化物を添加又は練り込みを想定した評価方法
プリン、ゼリー等のデザート類の上に添加したり、プリン、ババロア、ゼリー等の練り込み用の使用を想定し水中油型乳化物のクリームを直接食して、乳味、程良い脂肪感、乳感を評価
五段階評価 5;良好 4;やや良好 3;可
2;やや悪い 1;悪い
・ Evaluation method assuming the addition or kneading of oil-in-water emulsions Oil-in-water emulsions that are added to desserts such as pudding and jelly, and are used for kneading pudding, bavaria, jelly, etc. Eat cream directly and evaluate milky taste, moderate fat feeling, milk feeling Five-point evaluation 5; Good 4; Slightly good 3;
2; Somewhat bad 1; Bad
実施例1
70℃の温水65.43部(100gの熱水にヘキサメタリン酸ナトリウム0.2部、重曹0.02部を溶解した熱水を含む)に水分散性乳化剤であるショ糖脂肪酸エステル(HLB5)を分散し水相(1)とする。
これとは別にパーム核油(融点28℃)30部を加熱融解し、そこに油分散性乳化剤であるレシチン0.2部を溶解・分散して油相(1)とする。
40Lタンクに水相(1)を仕込み、更に油相(1)を加えて、攪拌機としては4枚羽根(Fuji Electric Co..Ltd.)を使用し、回転数572rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
水相(1)及び油相(1)の配合を表1に纏めた。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表2に纏めた。
Example 1
Sucrose fatty acid ester (HLB5), a water-dispersible emulsifier, is added to 65.43 parts of hot water at 70 ° C. (including hot water in which 0.2 parts of sodium hexametaphosphate and 0.02 part of sodium bicarbonate are dissolved in 100 g of hot water). Disperse to form an aqueous phase (1).
Separately, 30 parts of palm kernel oil (melting point: 28 ° C.) is heated and melted, and 0.2 part of lecithin, which is an oil-dispersible emulsifier, is dissolved and dispersed therein to obtain an oil phase (1).
A water phase (1) is charged into a 40 L tank, an oil phase (1) is further added, a four-blade blade (Fuji Electric Co. Ltd.) is used as a stirrer, and a rotational speed of 572 rpm at 70 ° C. for 30 minutes. The mixture was stirred to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
The composition of the aqueous phase (1) and the oil phase (1) is summarized in Table 1.
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 2.
実施例1〜実施例13の水相(1,2,3)及び油相(1,2,3)の配合を表1に纏めた。
実施例2
実施例1と同様な水相(1)と油相(1)を準備し、40Lタンクに水相(1)を仕込み、更に油相(1)を加えて、攪拌機としては4枚羽根(Fuji Electric Co..Ltd.)を使用し、回転数572rpmで、70℃、30分間混合攪拌し、次にホモゲナイザー(三和機械株式会社)で4MPa の均質化圧力で均質化して、微粒化処理を行い、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表2に纏めた。
Example 2
The same water phase (1) and oil phase (1) as in Example 1 were prepared, the water phase (1) was charged into a 40 L tank, the oil phase (1) was further added, and the four-blade (Fuji) was used as a stirrer. Electric Co .. Ltd.), mixing and stirring at 70 ° C. for 30 minutes at a rotation speed of 572 rpm, and then homogenizing with a homogenizer (Sanwa Machinery Co., Ltd.) at a homogenization pressure of 4 MPa to carry out the atomization treatment. And an oil-in-water emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 2.
実施例3
実施例1と同様な水相(1)と油相(1)を準備し、20Lステンレス容器に水相(1)を仕込み、更に油相(1)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表2に纏めた。
Example 3
The same water phase (1) and oil phase (1) as in Example 1 were prepared, the water phase (1) was charged into a 20 L stainless steel container, the oil phase (1) was further added, and a TK homomixer ( Primix Co., Ltd.) was used and mixed and stirred at 8000 rpm for 30 minutes at 70 ° C. to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 2.
実施例4
実施例1と同様な水相(1)と油相(1)を準備し、20Lステンレス容器に水相(1)を仕込み、更に油相(1)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表2に纏めた。
Example 4
A water phase (1) and an oil phase (1) similar to those in Example 1 are prepared, and the water phase (1) is charged into a 20 L stainless steel container, and the oil phase (1) is further added. Co., Ltd.) was used and mixed and stirred at 22,000 rpm at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 2.
実施例1〜実施例4の結果を表2に纏めた。
実施例5
70℃の温水50.355部(100gの熱水にヘキサメタリン酸ナトリウム0.06部、重曹0.02部を溶解した熱水を含む)に水分散性乳化剤であるショ糖脂肪酸エステル(HLB5)0.2部を分散し水相(2)とする。
これとは別にパーム核油(融点28℃)10部、硬化油(パーム分別油)(融点36℃)15部、硬化油(菜種/パーム混合)(融点31℃)20部を加熱融解し、そこに油分散性乳化剤であるレシチン0.2部、ソルビタン脂肪酸エステル(HLB5.1)0.15部、ソルビタン脂肪酸エステル(HLB4.9)0.015部を溶解・分散して油相(2)とする。水相(2)及び油相(2)の配合については先にも述べたが表1に纏めた。
20Lステンレス容器に水相(2)を仕込み、更に油相(2)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表3に纏めた。
Example 5
Sucrose fatty acid ester (HLB5) 0 which is a water-dispersible emulsifier in 50.355 parts of hot water at 70 ° C. (including hot water in which 0.06 part of sodium hexametaphosphate and 0.02 part of sodium bicarbonate were dissolved in 100 g of hot water) Disperse 2 parts into the aqueous phase (2).
Separately, 10 parts of palm kernel oil (melting point 28 ° C.), 15 parts of hardened oil (palm fractionation oil) (melting point 36 ° C.), 20 parts of hardened oil (rapeseed / palm mixture) (melting point 31 ° C.) The oil dispersible emulsifier, 0.2 part of lecithin, 0.15 part of sorbitan fatty acid ester (HLB5.1), 0.015 part of sorbitan fatty acid ester (HLB4.9) was dissolved and dispersed in the oil phase (2). And The formulation of the water phase (2) and the oil phase (2) was described above but is summarized in Table 1.
A water phase (2) is charged into a 20 L stainless steel container, and an oil phase (2) is further added. A TK homomixer (Primics Co., Ltd.) is used as a stirrer, and the mixture is stirred at 70 ° C. for 30 minutes at a rotation speed of 8000 rpm. An oil-in-water emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 3.
実施例6
実施例5と同様な水相(2)と油相(2)を準備し、20Lステンレス容器に水相(2)を仕込み、更に油相(2)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、次にホモゲナイザー(三和機械株式会社)で4MPa の均質化圧力で均質化して、微粒化処理を行い、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表3に纏めた。
Example 6
The same aqueous phase (2) and oil phase (2) as in Example 5 were prepared, the aqueous phase (2) was charged into a 20 L stainless steel container, the oil phase (2) was further added, and a TK homomixer ( Primics Co., Ltd.), mixing and stirring at 8000 rpm for 30 minutes at 70 ° C., then homogenizing with a homogenizer (Sanwa Machinery Co., Ltd.) at a homogenization pressure of 4 MPa, An oil-type emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 3.
実施例7
実施例5と同様な水相(2)と油相(2)を準備し、20Lステンレス容器に水相(2)を仕込み、更に油相(2)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、次にホモゲナイザー(三和機械株式会社)で4MPa の均質化圧力で均質化して、微粒化処理を行い、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、その後ホモゲナイザー(三和機械株式会社)で2MPa の均質化圧力で均質化して水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表3に纏めた。
Example 7
The same aqueous phase (2) and oil phase (2) as in Example 5 were prepared, the aqueous phase (2) was charged into a 20 L stainless steel container, the oil phase (2) was further added, and a TK homomixer ( Primics Co., Ltd.), mixing and stirring at 8000 rpm for 30 minutes at 70 ° C., then homogenizing with a homogenizer (Sanwa Machinery Co., Ltd.) at a homogenization pressure of 4 MPa, An oil-type emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., add 4 parts of skim milk powder, and mix and stir for another 30 minutes. ) This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 3.
実施例8
実施例5と同様な水相(2)と油相(2)を準備し、20Lステンレス容器に水相(2)を仕込み、更に油相(2)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表3に纏めた。
Example 8
A water phase (2) and an oil phase (2) similar to those in Example 5 were prepared, the water phase (2) was charged into a 20 L stainless steel container, and the oil phase (2) was further added. Co., Ltd.) was used and mixed and stirred at 22,000 rpm at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 3.
実施例5〜実施例8の結果を表3に纏めた。
実施例9
70℃の温水50.355部(100gの熱水にヘキサメタリン酸ナトリウム0.06部、重曹0.02部を溶解した熱水を含む)に水分散性乳化剤であるショ糖脂肪酸エステル(HLB5)0.2部を分散し水相(3)とする。
これとは別にパーム核油(融点28℃)15部、硬化油(パーム分別油)(融点31℃)15部、硬化油(大豆/パーム混合)(融点31℃)15部を加熱融解し、そこに油分散性乳化剤であるレシチン0.2部、ソルビタン脂肪酸エステル(HLB5.1)0.15部、ソルビタン脂肪酸エステル(HLB4.9)0.015部を溶解・分散して油相(3)とする。水相(3)及び油相(3)の配合については先にも述べたが表1に纏めた。
20Lステンレス容器に水相(3)を仕込み、更に油相(3)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表4に纏めた。
Example 9
Sucrose fatty acid ester (HLB5) 0 which is a water-dispersible emulsifier in 50.355 parts of hot water at 70 ° C. (including hot water in which 0.06 part of sodium hexametaphosphate and 0.02 part of sodium bicarbonate were dissolved in 100 g of hot water) Disperse 2 parts to form aqueous phase (3).
Separately, 15 parts of palm kernel oil (melting point 28 ° C.), 15 parts of hardened oil (palm fractionation oil) (melting point 31 ° C.), 15 parts of hardened oil (soybean / palm mixture) (melting point 31 ° C.) The oil dispersible emulsifier, 0.2 part of lecithin, 0.15 part of sorbitan fatty acid ester (HLB5.1) and 0.015 part of sorbitan fatty acid ester (HLB4.9) are dissolved and dispersed in the oil phase (3). And The composition of the water phase (3) and the oil phase (3) was described above, but is summarized in Table 1.
A water phase (3) is charged into a 20 L stainless steel container, and an oil phase (3) is further added. Using a TK homomixer (Primics Co., Ltd.) as a stirrer, the mixture is stirred at 70 ° C. for 30 minutes at a rotation speed of 8000 rpm. An oil-in-water emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 4.
実施例10
実施例9と同様な水相(3)と油相(3)を準備し、20Lステンレス容器に水相(3)を仕込み、更に油相(3)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで、70℃、30分間混合攪拌し、次にホモゲナイザー(三和機械株式会社)で4MPa の均質化圧力で均質化して、微粒化処理を行い、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表4に纏めた。
Example 10
The same aqueous phase (3) and oil phase (3) as in Example 9 were prepared, the aqueous phase (3) was charged into a 20 L stainless steel container, the oil phase (3) was further added, and a TK homomixer ( Primics Co., Ltd.), mixing and stirring at 8000 rpm for 30 minutes at 70 ° C., then homogenizing with a homogenizer (Sanwa Machinery Co., Ltd.) at a homogenization pressure of 4 MPa, An oil-type emulsion (A) was obtained. After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 4.
実施例11
実施例9と同様な水相(3)と油相(3)を準備し、20Lステンレス容器に水相(3)を仕込み、更に油相(3)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を60℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表4に纏めた。
Example 11
The same aqueous phase (3) and oil phase (3) as in Example 9 were prepared, the aqueous phase (3) was charged into a 20 L stainless steel container, and the oil phase (3) was further added. Co., Ltd.) was used and mixed and stirred at 22,000 rpm at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 60 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 4.
実施例12
実施例9と同様な水相(3)と油相(3)を準備し、20Lステンレス容器に水相(3)を仕込み、更に油相(3)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を50℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表4に纏めた。
Example 12
The same aqueous phase (3) and oil phase (3) as in Example 9 were prepared, the aqueous phase (3) was charged into a 20 L stainless steel container, and the oil phase (3) was further added. Co., Ltd.) was used and mixed and stirred at 22,000 rpm at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 50 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 4.
実施例13
実施例9と同様な水相(3)と油相(3)を準備し、20Lステンレス容器に水相(3)を仕込み、更に油相(3)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで、70℃、30分間混合攪拌し、水中油型乳化物(A)を得た。品温を70℃に調整した上で脱脂粉乳を4部加えて更に30分間混合攪拌し、水中油型乳化物(B)を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物(B)得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表4に纏めた。
Example 13
The same aqueous phase (3) and oil phase (3) as in Example 9 were prepared, the aqueous phase (3) was charged into a 20 L stainless steel container, and the oil phase (3) was further added. Co., Ltd.) was used and mixed and stirred at 22,000 rpm at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion (A). After adjusting the product temperature to 70 ° C., 4 parts of skim milk powder was added and the mixture was further stirred for 30 minutes to obtain an oil-in-water emulsion (B). This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil emulsion (B) was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 4.
実施例9〜実施例13の結果を表4に纏めた。
比較例1
実施例1と同様な水相(1)と油相(1)を準備し、40Lタンクに水相(1)を仕込み、更に油相(1)を加えて、攪拌機としては4枚羽根(Fuji Electric Co..Ltd.)を使用し、回転数572rpmで混合攪拌し、攪拌開始と同時に脱脂粉乳を4部加えて、70℃、30分間混合攪拌し、水中油型乳化物を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表5に纏めた。
Comparative Example 1
The same water phase (1) and oil phase (1) as in Example 1 were prepared, the water phase (1) was charged into a 40 L tank, the oil phase (1) was further added, and the four-blade (Fuji) was used as a stirrer. Electric Co., Ltd.) was used and mixed and stirred at a rotational speed of 572 rpm. At the same time as stirring was started, 4 parts of skim milk powder was added and mixed and stirred at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion. This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 5.
比較例2
実施例1と同様な水相(1)と油相(1)を準備し、20Lステンレス容器に水相(1)を仕込み、更に油相(1)を加えて、攪拌機としてはTKホモミキサー(プライミクス株式会社)を使用し、回転数8000rpmで混合攪拌し、攪拌開始と同時に脱脂粉乳を4部加えて、70℃、30分間混合攪拌し、水中油型乳化物を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表5に纏めた。
Comparative Example 2
The same water phase (1) and oil phase (1) as in Example 1 were prepared, the water phase (1) was charged into a 20 L stainless steel container, the oil phase (1) was further added, and a TK homomixer ( Primix Co., Ltd.) was used and mixed and stirred at a rotational speed of 8000 rpm, and 4 parts of skimmed milk powder was added simultaneously with the start of stirring, followed by mixing and stirring at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion. This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 5.
比較例3
実施例1と同様な水相(1)と油相(1)を準備し、20Lステンレス容器に水相(1)を仕込み、更に油相(1)を加えて、攪拌機としてはラボリューション(プライミクス株式会社)を使用し、回転数22000rpmで混合攪拌し、攪拌開始と同時に脱脂粉乳を4部加えて、70℃、30分間混合攪拌し、水中油型乳化物を得た。これを岩井機械製殺菌装置で144℃4秒間直接蒸気殺菌処理し、78℃まで冷却後、5MPa の均質化圧力で均質化して、更に冷却後、5℃で24時間エージングして最終製品の水中油型乳化物を得た。各段階のサンプルの粒度分布を測定(島津製粒度分布計SALD2200)した。
24時間エージングした後の水中油型乳化物1kgに70gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表5に纏めた。
Comparative Example 3
A water phase (1) and an oil phase (1) similar to those in Example 1 are prepared, and the water phase (1) is charged into a 20 L stainless steel container, and the oil phase (1) is further added. Co., Ltd.), and mixed and stirred at a rotational speed of 22000 rpm. At the same time as starting stirring, 4 parts of skim milk powder was added and mixed and stirred at 70 ° C. for 30 minutes to obtain an oil-in-water emulsion. This was directly steam sterilized at 144 ° C. for 4 seconds with a sterilizer manufactured by Iwai Machine, cooled to 78 ° C., homogenized at a homogenization pressure of 5 MPa, further cooled, and then aged at 5 ° C. for 24 hours to obtain the final product in water. An oil-type emulsion was obtained. The particle size distribution of the sample at each stage was measured (Shimadzu particle size distribution analyzer SALD2200).
70 kg of granulated sugar was added to 1 kg of an oil-in-water emulsion after aging for 24 hours and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 5.
参考例1
乳脂肪分42%の生クリーム(商品名:タカナシ特選北海道純生クリーム42)を実施例1と同様に評価した。これらの評価を表5に纏めた。
Reference example 1
A fresh cream having a milk fat content of 42% (trade name: Takanashi Specialty Hokkaido Pure Fresh Cream 42) was evaluated in the same manner as in Example 1. These evaluations are summarized in Table 5.
比較例1〜比較例3及び参考例1の結果を表5に纏めた。
実施例1〜実施例13、比較例1〜比較例3及び参考例1の風味評価の総括
本発明は生クリーム及び水中油型乳化物の風味評価に際して、風味、口どけ、組織・食感を詳しく解析していく中で、従来の生クリームに対しての乳味、乳感の評価に加えて程良い脂肪感が乳味、乳感を誘発させているという風味評価項目を見い出した。
実施例1〜実施例13に示したように、油脂が植物性油脂のみの使用であっても本願発明の製造法を採用することによって、生クリームに近い程良い脂肪感と乳味、乳感を得ることが出来た。
風味評価を個別的に纏めと、口どけ;予備乳化方法の影響は少なく、使用油脂の種類と油脂分が影響する。組織・食感:予備乳化方法の影響を少なからず受け、油脂粒子径を小さくすれば良くなる。乳味:予備乳化方法の影響を大きく受け程良い脂肪感と連動する。程良い脂肪感:予備乳化方法の影響を大きく受け本願発明の新知見でもある。乳感:予備乳化方法の影響を大きく受け程良い脂肪感と連動する。
具体的な評価は先の表2〜表5に提示した通りである。
Summary of Flavor Evaluation of Examples 1 to 13 and Comparative Examples 1 to 3 and Reference Example 1 The present invention is to evaluate the flavor, mouthfeel, texture and texture of fresh cream and oil-in-water emulsion. In the detailed analysis, in addition to the conventional evaluation of milky taste and milky feeling for fresh cream, we found a flavor evaluation item that moderate fatness induces milky taste and milky feeling.
As shown in Examples 1 to 13, even when the fats and oils are only the use of vegetable oils and fats, by adopting the production method of the present invention, the fatness, milky taste, and milkiness that are closer to the cream are better. I was able to get.
Summarize the taste evaluation individually and speak; the effect of the pre-emulsification method is small, and the type and fat content of the oil used is affected. Tissue / texture: The effect of the pre-emulsification method is not a little, and the fat and oil particle size should be reduced. Milky taste: It is greatly influenced by the pre-emulsification method and is linked to a good fat feeling. Moderately good fat feeling: greatly influenced by the preliminary emulsification method, which is also a new finding of the present invention. Milky feeling: The influence of the pre-emulsification method is greatly affected, and it is linked with a good feeling of fat.
Specific evaluation is as presented in Tables 2 to 5 above.
プリン、ゼリー等のデザート類の上に添加したり、プリン、ババロア、ゼリー等の練り込み用の使用を想定した検討として、実施例3、実施例4及び比較例2及び比較例3の水中油型乳化物を直接食して、乳味、程良い脂肪感、乳感を評価した。
これらの結果を表6に纏めた。
These results are summarized in Table 6.
実施例14
5℃に冷却して24時間エージングした実施例3の水中油型乳化物80部と、同じく品温が5℃の乳脂肪分42%の生クリーム(商品名:タカナシ特選北海道純生クリーム42)20部を混合したもの1kgに70gのグラニュー糖を加えて、上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表7に纏めた。
実施例15
5℃に冷却して24時間エージングした実施例4の水中油型乳化物80部と、同じく品温が5℃の乳脂肪分42%の生クリーム(商品名:タカナシ特選北海道純生クリーム42)20部を混合したもの1kgに70gのグラニュー糖を加えて、上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表7に纏めた。
実施例16
5℃に冷却して24時間エージングした実施例3の水中油型乳化物30部と、同じく品温が5℃の乳脂肪分42%の生クリーム(商品名:タカナシ特選北海道純生クリーム42)70部を混合したもの1kgに70gのグラニュー糖を加えて、上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表7に纏めた。
実施例17
5℃に冷却して24時間エージングした実施例4の水中油型乳化物30部と、同じく品温が5℃の乳脂肪分42%の生クリーム(商品名:タカナシ特選北海道純生クリーム42)70部を混合したもの1kgに70gのグラニュー糖を加えて、上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性のホイップ分析を行った。またホイップしたクリームの風味の評価を行った。これらの結果を表7に纏めた。
これらの結果を表7に纏めた。
Example 14
80 parts of an oil-in-water emulsion of Example 3 cooled to 5 ° C. and aged for 24 hours, and a fresh cream with a milk fat content of 42% (product name: Takanashi Specialty Hokkaido Pure Fresh Cream 42) 20 70 kg of granulated sugar was added to 1 kg of the mixture, and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 7.
Example 15
80 parts of an oil-in-water emulsion of Example 4 cooled to 5 ° C. and aged for 24 hours, and a fresh cream (trade name: Takanashi Specialty Hokkaido Pure Fresh Cream 42) with a milk fat content of 42% and a product temperature of 5 ° C. 20 70 kg of granulated sugar was added to 1 kg of the mixture, and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 7.
Example 16
30 parts of the oil-in-water emulsion of Example 3 which was cooled to 5 ° C. and aged for 24 hours, and a fresh cream (trade name: Takanashi Specialty Hokkaido Pure Fresh Cream 42) with a milk fat content of 42% and a product temperature of 5 ° C. 70 70 kg of granulated sugar was added to 1 kg of the mixture, and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 7.
Example 17
30 parts of an oil-in-water emulsion of Example 4 cooled to 5 ° C. and aged for 24 hours, and a fresh cream (trade name: Takanashi Special Hokkaido Pure Fresh Cream 42) with a milk fat content of 42% and a product temperature of 5 ° C. 70 70 kg of granulated sugar was added to 1 kg of the mixture, and whipped by the above whipping method. Overrun and shape retention whipping analysis was performed according to the above method. The flavor of the whipped cream was evaluated. These results are summarized in Table 7.
These results are summarized in Table 7.
実施例14〜実施例17の結果を表7に纏めた。
本発明は、水中油型乳化物の製造法に関し更に詳しくはプリン、ババロア、ゼリー等の練り込み用に使用される水中油型乳化物であるクリームや、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)としての使用である、風味に優れた水中油型乳化物の製造法に関するものである。 The present invention relates to a method for producing an oil-in-water emulsion. More specifically, the present invention is used for creams that are oil-in-water emulsions used for kneading pudding, bavarois, jelly, etc., decorations such as cakes, sands, etc. The present invention relates to a method for producing an oil-in-water emulsion excellent in flavor, which is used as a foamable oil-in-water emulsion (whipped cream).
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