JP2013047037A - Pneumatic tire - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a pneumatic tire with an inner liner, configured to prevent separation of the inner liner, while improving bending fatigue strength, air permeation resistance and crack resistance.SOLUTION: The pneumatic tire has an inner liner formed on the inside of the tire. The inner liner is formed of a polymer sheet of thermoplastic elastomer composition containing 0.1-100 pts.wt. of tackifier with respect to 100 pts.wt. of styrene-isobutylene-styrene triblock copolymer. In the inner liner, the ratio (Gs/Gb) between an average thickness Gs of a buttress region Rs formed from a tire maximum width position to a corresponding position Lu of a belt layer end and an average thickness Gb of a bead region Rb formed from the tire maximum width position to a bead toe is 0.30-0.75.

Description

  The present invention relates to a pneumatic tire provided with an inner liner.

  In recent years, tires have been made lighter due to the strong social demand for low fuel consumption of vehicles, and an inner liner that is disposed inside the tire and has a function of preventing air leakage from the inside of the pneumatic tire to the outside. There is also a demand for weight reduction.

  At present, the rubber composition for an inner liner improves the air permeation resistance of a tire by using a rubber compound mainly composed of butyl rubber including, for example, 70 to 100% by mass of butyl rubber and 30 to 0% by mass of natural rubber. Has been done. In addition to butylene, the rubber compound mainly composed of butyl rubber contains about 1% by mass of isoprene, which, when combined with sulfur, vulcanization accelerator, and zinc white, enables co-crosslinking between adjacent rubber layers. I have to. The butyl rubber usually requires a thickness of about 0.6 to 1.0 mm for passenger car tires and about 1.0 to 2.0 mm for truck and bus tires. In order to achieve this, there is a demand for a polymer that has better air permeation resistance than butyl rubber and that can reduce the thickness of the inner liner layer.

  Conventionally, it has been proposed to use a thermoplastic elastomer in order to reduce the weight of the inner liner. However, when the thickness of the thermoplastic elastomer is made thinner than that of butyl rubber, the air permeability and strength are lowered, and the inner liner may be broken by the heat and pressure of the bladder during vulcanization of the tire. Further, a thermoplastic elastomer having a low strength is likely to crack in the inner liner in a buttress portion that undergoes large repeated shear deformation during tire running.

  Patent Document 1 discloses a laminate for improving the adhesion between the inner liner layer and the rubber layer. By providing an adhesive layer on both sides of the inner liner layer, the adhesive layers come into contact with each other at the overlapping portion of the inner liner layer, and are firmly bonded by heating, so that air pressure retention is improved. . However, the adhesive layer for overlaying the inner liner layer comes into contact with the bladder in a heated state in the vulcanization process, and there is a problem that it adheres to and adheres to the bladder.

  In Patent Document 2, a mixture of an air permeation-resistant nylon resin and butyl rubber is prepared by dynamic cross-linking to produce an inner liner layer having a thickness of 100 μm. However, nylon resin is hard at room temperature and unsuitable as an inner liner for tires. In addition, the vulcanization adhesion to the rubber layer is not performed only with the mixture obtained by the dynamic crosslinking. Therefore, the adhesion layer for vulcanization is required in addition to the inner liner layer. Therefore, the inner liner member has a complicated structure and many processes. This is disadvantageous from the viewpoint of productivity.

  Prior Document 3 disperses maleic anhydride-modified hydrogenated styrene-ethylene-butadiene-styrene block copolymer in an air-permeable ethylene-vinyl alcohol copolymer to produce a flexible gas barrier layer. In addition, the thermoplastic polyurethane layer has an sandwich sandwich structure, and rubber paste (70/30 of butyl rubber / natural rubber is dissolved in toluene) is applied to the surface to be bonded to the tire rubber to produce an inner liner layer. However, the modified ethylene-vinyl alcohol copolymer dispersed in a flexible resin has low adhesive strength and may be peeled off from the thermoplastic polyurethane layer. In the modified ethylene-vinyl alcohol copolymer dispersed with a flexible resin, the flexible resin is dispersed, but the EVOH of the matrix is poor in bending fatigue and breaks during running of the tire. Furthermore, although rubber paste is applied to the surface to be bonded to the tire rubber, a process different from the normal inner liner process is required, resulting in poor productivity.

JP-A-9-19987 Japanese Patent No. 2999188 JP 2008-24219 A

  An object of the present invention is to prevent peeling of an inner liner in a pneumatic tire provided with an inner liner, and to further improve bending fatigue resistance, air permeation resistance and crack resistance of the pneumatic tire.

  The present invention is a pneumatic tire provided with an inner liner on the inner side of the tire, and the inner liner has a tackifier of 0.1 to 100 parts per 100 parts by mass of a styrene-isobutylene-styrene triblock copolymer. The inner liner includes an average thickness Gs of the buttress region Rs from the tire maximum width position to the corresponding position Lu at the belt layer end, and a bead toe from the tire maximum width position. This relates to a pneumatic tire in which the ratio (Gs / Gb) of the average thickness Gb of the bead region Rb is 0.30 to 0.75.

The styrene-isobutylene-styrene triblock copolymer preferably has a styrene component content of 10 to 30% by mass and a weight average molecular weight of 50,000 to 400,000. The tackifier preferably has a weight average molecular weight Mw of 1 × 10 ² to 1 × 10 ⁶ and a softening point of 50 ° C. to 150 ° C.

  In the pneumatic tire according to another embodiment of the present invention, the average thickness Gs of the buttress region Rs of the inner liner is 0.05 to 0.45 mm.

  In the present invention, a thermoplastic elastomer composition containing a tackifier is used for an inner liner, and the ratio of the average thickness Gb of the bead region Rb and the average thickness Gs of the buttress region Rs of the inner liner is set within a certain range. Thus, the thickness can be reduced while improving the air permeation resistance, and the adhesive strength with the adjacent rubber layer can be improved. And the stress accompanying the repeated deformation | transformation of the tire at the time of driving | running | working can be relieve | moderated effectively, and bending fatigue property and crack resistance can be improved.

It is a schematic sectional drawing which shows the right half of the pneumatic tire of this invention.

  An embodiment of a pneumatic tire according to the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view of the right half of a pneumatic tire for passenger cars. The pneumatic tire 1 has a tread portion 2 and sidewall portions 3 and bead portions 4 so as to form a toroid shape from both ends of the tread portion. Further, a bead core 5 is embedded in the bead portion 4. Also, a carcass ply 6 provided from one bead portion 4 to the other bead portion, with both ends folded back and locked around the bead core 5, and at least two sheets on the outer side of the crown portion of the carcass ply 6 A belt layer 7 made of a ply is arranged.

  The belt layer 7 usually intersects two plies made of steel cords or cords such as aramid fibers with respect to the tire circumferential direction so that the cords are usually at an angle of 5 to 30 °. Are arranged as follows. In addition, a topping rubber layer can be provided on both outer sides of the belt layer to reduce peeling at both ends of the belt layer. In the carcass ply, organic fiber cords such as polyester, nylon, and aramid are arranged at approximately 90 ° in the tire circumferential direction. In the region surrounded by the carcass ply and the folded portion, the bead core 5 extends from the upper end to the sidewall direction. An extending bead apex 8 is arranged. Further, an inner liner 9 extending from one bead portion 4 to the other bead portion 4 is disposed inside the carcass ply 6 in the tire radial direction.

  Here, the inner liner is made of a styrene-isobutylene-styrene triblock copolymer (SIBS), and the thickness is adjusted to a range of 0.05 mm to 1.0 mm, preferably 0.05 mm to 0.6 mm.

<Configuration of inner liner>
In the present invention, from the average thickness Gb of the inner liner 9 in the bead area Rb extending from the tire maximum width position Le to the bead toe Lt, the inner liner 9 in the buttress area Rs extending from the tire maximum width position Le to the corresponding position Lu at the belt layer end. The average thickness Gs is made thin.

  By reducing the thickness Gs of the inner liner in the buttress region Rs, even if shear deformation occurs due to repeated bending deformation in this region during tire running, the stress can be relieved and cracks can be generated. Can be prevented.

  In order to effectively relieve the stress due to bending deformation, the ratio (Gs / Gb) of the average thickness Gs of the buttress region Rs of the inner liner to the average thickness Gb of the bead region Rb is 0.3-0. 75. Further, in order to maintain the air pressure holding performance and also have the effect of relaxing the stress in the buttress region, it is desirable that the average thickness Gs of the buttress region Rs of the inner liner is 0.05 to 0.45 mm.

<Composition for inner liner>
In the present invention, the inner liner is composed of a thermoplastic elastomer composition comprising a mixture of at least 80% by mass of a styrene-isobutylene-styrene triblock copolymer (SIBS) and 20% by mass or less of a rubber component or a thermoplastic elastomer.

  Since the styrene-isobutylene-styrene triblock copolymer (SIBS) is derived from the isobutylene block, the polymer film made of SIBS has excellent air permeation resistance. Therefore, when a polymer film made of SIBS is used for the inner liner, a pneumatic tire having excellent air permeation resistance can be obtained.

  Further, SIBS has excellent durability because its molecular structure other than aromatic is completely saturated, thereby preventing deterioration and hardening. Therefore, when a polymer film made of SIBS is used for the inner liner, a pneumatic tire having excellent durability can be obtained.

  The molecular weight of SIBS is not particularly limited, but the weight average molecular weight by GPC measurement is preferably 50,000 to 400,000 from the viewpoints of fluidity, molding process, rubber elasticity and the like. If the weight average molecular weight is less than 50,000, the tensile strength and the tensile elongation may be lowered, and if it exceeds 400,000, the extrusion processability may be deteriorated. Since SIBS improves air permeation resistance and durability, the content of the styrene component in SIBS is 10 to 30% by mass, preferably 14 to 25% by mass.

  In SIBS, the degree of polymerization of each block is preferably about 10,000 to 150,000 for an isobutylene block and about 5,000 to 30,000 for a styrene block from the viewpoint of rubber elasticity and workability.

  SIBS can be obtained by a living cationic polymerization method of a general vinyl compound. For example, JP-A-62-48704 and JP-A-64-62308 disclose that living cationic polymerization of isobutylene and other vinyl compounds is possible. By using isobutylene and other compounds as vinyl compounds, It is disclosed that a polyisobutylene-based block copolymer can be produced.

  Since SIBS does not have double bonds other than aromatics in the molecule, it is more stable to ultraviolet rays than a polymer having double bonds in the molecule, such as polybutadiene, and therefore has weather resistance. It is good.

  As the thermoplastic synthetic elastomer mixed with the SIBS, for example, a styrene thermoplastic elastomer is preferable. Styrenic thermoplastic elastomer refers to a copolymer containing a styrene block as a hard segment. For example, styrene-isoprene-styrene block copolymer (SIS), styrene-isobutylene block copolymer (SIB), styrene-butadiene-styrene block copolymer (SBS), styrene-isobutylene-styrene block copolymer (SIBS). ), Styrene-ethylene-butene-styrene block copolymer (SEBS), styrene-ethylene-propylene-styrene block copolymer (SEPS), styrene-ethylene-ethylene-propylene-styrene block copolymer (SEEPS), styrene There is a butadiene-butylene-styrene block copolymer (SBBS).

  The styrenic thermoplastic elastomer may have an epoxy group in its molecular structure. For example, Epofriend A1020 manufactured by Daicel Chemical Industries, Ltd. (weight average molecular weight is 100,000, epoxy equivalent is 500). An epoxy-modified styrene-butadiene-styrene copolymer (epoxidized SBS) can be used.

  In addition, rubber components such as natural rubber, IR, BR, and SBR can be blended with SIBS. The rubber component can be used in combination with the thermoplastic elastomer.

<Tackifier>
The said tackifier is mix | blended in 0.1-100 mass parts with respect to 100 mass parts of thermoplastic elastomers, Preferably, it is 1-50 mass parts. When the tackifier is less than 0.1 parts by mass, the vulcanization adhesive strength with the second layer is not sufficient, while when it exceeds 100 parts by mass, the tackiness becomes too high, and the workability and productivity are reduced. The gas barrier property is further lowered.

Here, the “tackifier” refers to an additive for enhancing the tackiness of the thermoplastic elastomer composition, and examples thereof include the following tackifiers. The tackifier preferably has a weight average molecular weight Mw of 1 × 10 ² to 1 × 10 ⁶ and a softening point in the range of 50 ° C. to 150 ° C. When the weight average molecular weight is less than 1 × 10 ² , the viscosity is low, and the formability of the sheet is not preferable. On the other hand, when it exceeds 1 × 10 ⁶ , the adhesiveness of the inner liner becomes insufficient.

The tackifiers used in the present invention are listed below.
[C9 petroleum resin]
C9 petroleum resin is obtained by thermally decomposing naphtha to obtain useful compounds such as ethylene, propylene, butadiene, etc., but the remaining C5-C9 fraction (mainly C9 fraction) from which they have been removed is in a mixed state. It is an aromatic petroleum resin obtained by polymerization as it is. For example, as trade names, Alcon P70, P90, P100, P125, P140, M90, M100, M115, and M135 (all manufactured by Arakawa Chemical Industries, Ltd., softening point 70 to 145 ° C.), and Imabe S100 and S110 , P100, P125, P140 (all manufactured by Idemitsu Petrochemical Co., Ltd., aromatic copolymer hydrogenated petroleum resin, softening point 100-140 ° C., weight average molecular weight 700-900, bromine number 2.0-6.0 g) / 100 g) and Petcoal XL (manufactured by Tosoh Corporation).

[C5 petroleum resin]
C5 petroleum resin is obtained by thermally decomposing naphtha to obtain useful compounds such as ethylene, propylene and butadiene, but the remaining C4 to C5 fractions (mainly C5 fractions) from which they have been removed are mixed. It is an aliphatic petroleum resin obtained by polymerization as it is. Product names include Highletz G100 (Mitsui Petrochemical Co., Ltd., softening point 100 ° C.), Marcarez T100AS (Maruzen Oil Co., Ltd., softening point 100 ° C.), and Escorez 1102 (Tonex Corp., softening) The point is 110 ° C.).

[Terpene resin]
As product names, YS Resin PX800N, PX1000, PX1150, PX1250, PXN1150N, Clearon P85, P105, P115, P125, P135, P150, M105, M115, K100 (all manufactured by Yashara Chemical Co., Ltd., softening point 75-160 ° C) )

[Aromatic modified terpene resin]
As product names, there are YS resins TO85, TO105, TO115, and TO125 (all manufactured by Yashara Chemical Co., Ltd., softening point: 75 to 165 ° C.).

[Terpene phenol resin]
Tamanor 803L, 901 (made by Arakawa Chemical Industry Co., Ltd., softening point 120 ° C to 160 ° C) as product names, and YS polystar U115, U130, T80, T100, T115, T145, T160 (all manufactured by Yasuhara Chemical Co., Ltd., Softening point 75-165 ° C).

[Coumarone resin]
There is a coumarone resin (manufactured by Kobe Oil Chemical Co., Ltd.) having a softening point of 90 ° C.

[Coumaron Inden Oil]
As a trade name, there is 15E (manufactured by Kobe Oil Chemical Co., Ltd., pour point 15 ° C.).

[Rosin ester]
As product names, Ester gum AAL, A, AAV, 105, AT, H, HP, HD (all manufactured by Arakawa Chemical Industries, softening point 68 ° C. to 110 ° C.), and Harrier Star TF, S, C, There are DS70L, DS90, and DS130 (all manufactured by Harima Kasei Co., Ltd., softening point 68 ° C to 138 ° C).

[Hydrogenated rosin ester]
As trade names, there are Superesters A75, A100, A115, and A125 (all manufactured by Arakawa Chemical Industries, Ltd., softening point 70 ° C to 130 ° C).

[Alkylphenol resin]
As a trade name, there is Tamanoru 510 (manufactured by Arakawa Chemical Industries, Ltd., softening point 75 ° C. to 95 ° C.).

[DCPD]
As a trade name, there is Escoretz 5300 (manufactured by Tonex Co., Ltd., softening point 105 ° C.)

  The inner liner can be produced by a conventional method for forming a thermoplastic resin or a thermoplastic elastomer into a sheet, for example, extrusion molding, calendar molding, or the like.

<Pneumatic tire manufacturing method>
A general manufacturing method can be used for the pneumatic tire of the present invention. The inner liner can be manufactured by being placed in contact with the carcass ply inside the green tire and vulcanized together with other members. The vulcanized pneumatic tire has excellent air permeation resistance and durability because the inner liner and the rubber layer of the carcass ply are well bonded.

  In order to adjust the thickness of the inner liner in the bead region Rb and the buttress region Rs, for example, a profile is attached to the extrusion opening of the polymer sheet, and an integrated sheet having a thin buttress region thickness Gs is prepared. This is arranged on the inner surface of the tire as an inner liner.

  The rubber layer of the carcass ply used in the pneumatic tire of the present invention is composed of generally used rubber components such as natural rubber, polyisoprene, styrene-butadiene rubber, polybutadiene rubber, and fillers such as carbon black and silica. Can be used.

  The pneumatic tires of Examples and Comparative Examples were manufactured according to the specifications shown in Table 1 and Table 2, and the performance was evaluated. The compounding components used for the inner liner are as follows.

(Note 1) SIBS used Shibstar SIBSTAR 102T (Shore A hardness: 25, styrene component content: 25 mass%, weight average molecular weight: 100,000) manufactured by Kaneka Corporation.
(Note 2) As the tackifier A, C9 petroleum resin, Alcon P140 (Arakawa Chemical Industries, Ltd., softening point 140 ° C., weight average molecular weight Mw: 900) was used.
(Note 3) As the tackifier B, a terpene resin, YS resin PX1250 (manufactured by Yashara Chemical Co., Ltd., softening point: 125 ° C., weight average molecular weight Mw: 700) was used.
(Note 4) As the tackifier C, hydrogenated rosin ester, super ester A125 (Arakawa Chemical Industries, softening point 125 ° C., weight average molecular weight Mw: 700) was used.

<Manufacture of inner liner>
The thermoplastic elastomer composition was pelletized with a twin screw extruder (screw diameter: φ50 mm, L / D: 30, cylinder temperature: 220 ° C.) according to the formulation shown in Tables 1 and 2. Thereafter, an inner liner was produced with a T-die extruder (screw diameter: φ80 mm, L / D: 50, die lip width: 500 mm, cylinder temperature: 220 ° C.).

<Manufacture of pneumatic tires>
Pneumatic tires are manufactured in 195 / 65R15 size having the basic structure shown in FIG. 1, using the above inner liner to produce raw tires, and then press molding at 170 ° C. for 20 minutes in the vulcanization process. did. After the vulcanized tire was cooled at 100 ° C. for 3 minutes, the vulcanized tire was taken out of the mold to produce a pneumatic tire.

  Here, in order to adjust the thickness in the bead region Rb and the buttress region Rs of the inner liner, a profile is attached to the extrusion port of the polymer sheet, and an integrated sheet in which the thickness Gs of the buttress region is reduced is created. This was disposed on the inner surface of the tire as an inner liner.

  In Tables 1 and 2, the thickness of the inner liner indicates the thickness of the Gb region. Except for Comparative Example 1, Gb is 0.6 mm in all Examples and Comparative Examples.

  In addition, in the inner liner of Comparative Example 1, the following blending components were mixed with a Banbury mixer and formed into a sheet with a calendar roll to obtain a polymer film having a thickness of 1.0 mm. The value of Gs / Gb is 1.

IIR (Note 5) 80 parts by mass Natural rubber (Note 6) 20 parts by mass Filler (Note 7) 60 parts by mass (Note 5) “Exon Chlorobutyl 1068” manufactured by ExxonMobil Co., Ltd. was used.
(Note 6) Natural rubber used was TSR20.
(Note 7) “Seast V” (N660, nitrogen adsorption specific surface area: 27 m ² / g) manufactured by Tokai Carbon Co., Ltd. was used as the filler.

<Performance test>
Pneumatic tires were manufactured using the inner liners of Examples and Comparative Examples, and the following performance tests were performed.

<Peel test>
A test piece was prepared according to JIS-K-6256 “How to determine adhesion between vulcanized rubber and thermoplastic rubber”. A thermoplastic elastomer sheet and a rubber sheet are bonded and vulcanized. After vulcanization, the peel force is measured at the bonding interface. The peel strength of Comparative Example 1 was set to 100, and index evaluation was performed using relative values. It shows that peeling force is so large that an index | exponent is large.

<Bending fatigue test>
A predetermined test piece having a groove in the center was prepared according to JIS-K-6260 “Testing method for demature bending cracking of vulcanized rubber and thermoplastic rubber”. As the inner liner, a sheet having a thickness of 0.3 mm was attached to rubber and vulcanized to prepare a predetermined test piece. An incision was made in advance at the center of the groove of the test piece, and a test was conducted to measure crack growth by repeatedly bending and deforming. The crack length was measured at an ambient temperature of 23 ° C., a strain of 30%, and a period of 5 Hz, and the number of repetitions of bending deformation required for the crack to grow by 1 mm was calculated. Using the value of Comparative Example 1 as a reference (100), the flexural fatigue properties of the polymer laminates of Examples and Comparative Examples were expressed as indices. It can be said that the larger the numerical value, the better the cracks are less likely to grow. For example, the index of Example 1 is obtained by the following formula.

(Bending fatigue index) = (Number of repetitions of bending deformation of Example 1) / (Number of repetitions of bending deformation of Comparative Example 1) × 100
<Static air pressure drop rate test>
The 195 / 65R15 steel radial PC tire manufactured by the above method was assembled into a JIS standard rim 15 × 6 JJ, sealed with an initial air pressure of 300 Kpa, left at room temperature for 90 days, and the rate of decrease in air pressure was calculated.

<Measurement of average thickness>
A 195 / 65R15 steel radial PC tire was divided into 8 equal parts in the circumferential direction, and 8 cut samples cut along the tire radial direction with a width of 20 mm were created at each location, and each of these 8 cut samples was The thickness of the inner liner layer was measured at five points equally divided into five in the buttress region Rs and the bead region Rb. The arithmetic average values of the total 40 measured values were Gs and Gb.

<Crack resistance>
195 / 65R15 steel radial PC tire is assembled to JIS standard rim 15 × 6JJ, filled with regular air pressure, and the maximum load corresponding to this air pressure is applied from the air pressure-addition capacity correspondence table with JATMA YEAR BOOK, speed 80km / The vehicle traveled on the drum at h, and when the damage that could be visually confirmed was generated, the vehicle was stopped and the travel distance was determined. The travel distance of Comparative Example 1 is taken as 100 and is shown as an index. The larger the index, the better the crack resistance.

<Performance evaluation results>
<Comparative Example 1>
It is a specification of a conventional inner liner and is used as a standard for performance evaluation.

<Comparative example 2>
This is an example in which a SIBS layer is used as an inner liner. The value of Gs / Gb is 1. Although the peel force is inferior, the static air drop rate is improved.

<Comparative Examples 3-8>
It is an example (Comparative Examples 3 to 5) in which 1 part of the tackifier was mixed with SIBS and mixed with 100 parts (Comparative Examples 6 to 8) in which 100 parts of the tackifier was mixed with SIBS. The value of Gs / Gb is 1 for all. In both cases, the static air drop rate is improved.

<Comparative Examples 9 and 10>
Comparative Example 9 is an example in which a thermoplastic elastomer composition in which 0.05 part by weight of a tackifier is mixed with SIBS is used as an inner liner, and Comparative Example 10 is a thermoplastic elastomer in which 110 parts by weight of a tackifier is mixed with SIBS. This is an example in which the composition is used for an inner liner. The value of Gs / Gb is 0.75 for both. In Comparative Example 9, the static air drop rate is improved. In Comparative Example 10, the static air drop rate is improved, but the crack resistance is inferior.

<Comparative Example 11>
This is an example in which a thermoplastic elastomer composition in which 1 part by mass of a tackifier is mixed with SIBS is used as an inner liner. The value of Gs / Gb is 0.25. In Comparative Example 11, the static air reduction rate is improved, but the crack resistance is inferior.

<Examples 1-6>
Examples 1 to 3 are examples in which a thermoplastic elastomer composition obtained by mixing 1 part by mass of a tackifier with SIBS was used as an inner liner. Examples 4 to 6 are examples in which a thermoplastic elastomer composition obtained by mixing 100 parts by mass of a tackifier with SIBS was used for an inner liner. The value of Gs / Gb is 0.75 for both. In all of Examples 1 to 6, peeling force, bending fatigue, static air reduction rate, and crack resistance are comprehensively improved.

<Examples 7 to 9>
Examples 7 to 9 are examples in which a thermoplastic elastomer composition in which 1 part by mass of a tackifier is mixed with SIBS is used as an inner liner. The value of Gs / Gb is the highest at 0.75 in Example 1, and the lowest at 0.33 in Example 9. In all of Examples 7 to 9, the peel force, bending fatigue, static air drop rate, and crack resistance are comprehensively improved.

  The pneumatic tire of the present invention can be used as a pneumatic tire for trucks and buses, heavy machinery, etc. in addition to a pneumatic tire for passenger cars.

  1 Pneumatic tire, 2 tread part, 3 side wall part, 4 bead part, 5 bead core, 6 carcass ply, 7 belt layer, 8 bead apex, 9 inner liner, Rb bead area, Rs buttress area, Le tire maximum width position , Lt Bead toe, Lu Corresponding position of belt layer end.

Claims (4)

  A pneumatic tire provided with an inner liner on the inner side of the tire, wherein the inner liner is a heat containing 0.1 to 100 parts by mass of a tackifier with respect to 100 parts by mass of a styrene-isobutylene-styrene triblock copolymer. The inner liner is composed of a polymer sheet of a plastic elastomer composition, and the inner liner has an average thickness Gs of a buttress region Rs extending from a tire maximum width position to a corresponding position Lu at the belt layer end, and a bead region extending from the tire maximum width position to a bead toe. A pneumatic tire having a ratio (Gs / Gb) of an average thickness Gb of Rb of 0.30 to 0.75.   The pneumatic tire according to claim 1, wherein the styrene-isobutylene-styrene triblock copolymer has a styrene component content of 10 to 30% by mass and a weight average molecular weight of 50,000 to 400,000. 3. The pneumatic tire according to claim 1, wherein the tackifier has a weight average molecular weight Mw of 1 × 10 ² to 1 × 10 ⁶ and a softening point in a range of 50 ° C. to 150 ° C. 3.   The pneumatic tire according to any one of claims 1 to 3, wherein an average thickness Gs of the buttress region Rs of the inner liner is 0.05 to 0.45 mm.

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