JP2013005878A - Cleaning sheet - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cleaning sheet which exhibits excellent collecting performance and retention performance for trash such as hairs and dirt regardless of a surface to be cleaned and a dried state of trash, and from which constituting fibers are hardly removed.SOLUTION: The cleaning sheet 1 has fiber aggregation 2 and a support 3 for supporting the fiber aggregation 2. The constituting fibers of the fiber aggregation 2 are tangled each other and are tangled with the support 3, and the fiber aggregation 2 and the support 3 form an integral tangled state. On the outside of a line BL connecting the contour of one surface 1a of the cleaning sheet 1 in a side view of the cleaning sheet 1, a fiber end 21 of the constituting fibers having lengths of 10 mm or more formed by raising treatment is present.

Description

  The present invention relates to a cleaning sheet that is suitably used for collecting and removing hair, dust, granular dust, and the like on the floor, shelves, walls, and the like.

  As a cleaning sheet, a nonwoven fabric such as spunlace nonwoven fabric is mainly used, and constituent fibers of the nonwoven fabric are raised (fluffed) by raising treatment (see, for example, Patent Documents 1 and 2). The raising process described in Patent Documents 1 and 2 is performed by applying a non-woven fabric to be processed to the peripheral surface of a roller (counterpile roller) having a large number of needles on the peripheral surface and rotating the roller. According to Patent Documents 1 and 2, by such raising process, the constituent fiber of the nonwoven fabric is caught on the needle of the roller, the hooked constituent fiber is cut, or the hooked constituent fiber is cut and entangled and loosened. It is said that a large number of fibers are produced, and such raising fibers improve the dust collection property.

JP-A-11-318791 JP 2007-190254 A

  The cleaning sheet may be used not only for cleaning a dry surface to be cleaned (or collecting dry dust) but also for cleaning a wet surface to be cleaned (or collecting wet dust). Therefore, the cleaning sheet has a high dust collection property that can easily wipe off dust such as hair and dust regardless of whether the surface to be cleaned or the dust on the surface to be cleaned is dry or wet. In addition, a high dust holding property capable of holding the collected garbage without dropping is required. However, the surface to be cleaned and the dry state of the dust have a considerable influence on the collection of dust by the cleaning sheet. Conventionally, the surface to be cleaned or the dust is wet, compared to the case where they are dry. As a result, the ability to collect dust by the cleaning sheet may be reduced. In addition, the cleaning sheet is required to have practically sufficient strength in addition to high dust collection ability and dust retention ability, and as little as possible to remove the constituent fibers. No cleaning sheet to fill has yet been provided.

  Accordingly, the present invention relates to a cleaning sheet that exhibits excellent collection and retention properties for dust such as hair and dust, and is less likely to cause removal of constituent fibers, regardless of the surface to be cleaned and the dry state of the dust. .

  The present invention has a fiber assembly and a support that supports the fiber assembly, and the constituent fibers of the fiber assembly are intertwined with the constituent fibers and intertwined with the support, The cleaning sheet in which the fiber assembly and the support body form an integral entangled state, the straight line connecting the contours of one surface of the cleaning sheet when the cleaning sheet is viewed from the side Further, the present invention provides a cleaning sheet having a fiber end portion of the constituent fiber having a length of 10 mm or more, which is formed on the outside by a raising process.

  The cleaning sheet of the present invention exhibits excellent catching and holding properties for dust such as hair and dust, regardless of whether the surface to be cleaned and the dust are dry or wet, and the constituent fibers can be removed. It is hard to wake up.

FIG. 1 is a perspective view schematically showing an example of the cleaning sheet of the present invention. FIG. 2 is a cross-sectional view schematically showing a cross section taken along line II of FIG. FIG. 3 is an enlarged side view schematically showing one surface (raised surface) of the cleaning sheet shown in FIG. FIG. 4 is an explanatory diagram of a method for measuring the protruding length of the fiber end portion from the fiber assembly. FIG. 5 is a plan view of a support in the cleaning sheet shown in FIG. FIG. 6A to FIG. 6C are plan views of other embodiments of the support according to the present invention, respectively. FIG. 7 is a schematic view of a manufacturing apparatus that can be used for manufacturing the cleaning sheet shown in FIG. 1. FIG. 8 is a schematic view of a manufacturing apparatus (raising apparatus) that can be used for manufacturing the cleaning sheet shown in FIG. 1.

  Hereinafter, the cleaning sheet of the present invention will be described based on preferred embodiments with reference to the drawings. As shown in FIGS. 1 and 2, the cleaning sheet 1 of the present embodiment has a fiber assembly 2 and a support 3 that supports the fiber assembly 2, and the constituent fibers of the fiber assembly 2 are constituent fibers. The fiber assembly 2 and the support body 3 form an integral entangled state by being intertwined with each other and also with the support body 3. The support 3 exists in the thickness direction of the cleaning sheet 1, and the upper and lower surfaces of the support 3 are covered with the fiber assembly 2 as shown in FIG. 2. One surface 1 a of the cleaning sheet 1 and the other surface 1 b located on the opposite side are each formed from a fiber assembly 2. The cleaning sheet 1 is a dry cleaning sheet that is not intentionally impregnated with a liquid such as an aqueous cleaning agent.

  The fiber assembly 2 is a nonwoven fabric formed by fiber entanglement of a fiber web mainly composed of fibers. As will be described later, the fiber assembly 2 according to the present embodiment is formed by hydroentangling a fiber web, and is a so-called spunlace nonwoven fabric. Since the fiber assembly 2 according to the present embodiment is formed only by entanglement of the constituent fibers, a fiber assembly (for example, an air-through nonwoven fabric or a spunbond nonwoven fabric) formed only by fusing or bonding the constituent fibers; The degree of freedom of the constituent fibers is greater than that. Therefore, it is excellent in the collection and retention of dust such as hair and fine dust due to the constituent fibers, is soft in touch and easily follows the surface to be cleaned, and does not easily scratch the surface to be cleaned.

  As one of the main features of the cleaning sheet 1 of the present embodiment, as shown in FIG. 3, the cleaning sheet 1 is outside of a straight line BL that connects the contours of the one surface 1 a of the cleaning sheet 1 when viewed from the side. On the other side (outside of the cleaning sheet 1 or the fiber assembly 2), there are fiber end portions (hereinafter also referred to as long fiber end portions) 21 of constituent fibers having a length of 10 mm or more. In other words, the length of the fiber end portion is the length of the portion (end portion) of the constituent fiber that protrudes outward from the fiber assembly 2, and is hereinafter also referred to as “the length of protrusion from the fiber assembly”. As will be described later, the long fiber end portion 21 is partially pulled out from the fiber assembly 2 without being cut by the raising treatment of the fiber assembly 2, and is outside the surface (contour) of the fiber assembly 2. It is located in the direction, and is the original fiber end part (fiber end part before raising treatment) of the constituent fiber, not the cut fiber end part produced by cutting the constituent fiber. The end of the constituent fiber having the long fiber end 21 opposite to the long fiber end 21 exists in the fiber assembly 2 and is intertwined with other constituent fibers or the support 3. In the present embodiment, the reason for the presence of the relatively long long fiber end portion 21 having a protruding length from the fiber assembly 2 of 10 mm or more employs napping treatment by pulling out the constituent fibers of the fiber assembly. Therefore, as described in Patent Documents 1 and 2, in brushing treatment using a roller (counterpile roller) having a large number of needles on the peripheral surface, as described in these Patent Documents, Since many of the constituent fibers caught are cut without being pulled out as they are, it is difficult to obtain a protruding length of 10 mm or more. In FIG. 3, the long fiber end portion 21 is described as extending from the one surface 1a of the cleaning sheet 1 in a direction substantially intersecting with the one surface 1a. 3, the long fiber end portion 21 does not necessarily have the form shown in FIG. 3. For example, the long fiber end portion 21 may be substantially along the one surface 1 a at an outer position than the straight line BL, and is not crimped. In addition to the shape extending generally in one direction, there may be a crimped shape.

  The straight line BL is a straight line that connects the contours of one surface (raised surface) 1a of the cleaning sheet 1 as described above. When the one surface 1a is a flat surface without unevenness, the straight line BL coincides with the contour line of the flat surface. In the method for measuring the length of protrusion from the fiber assembly at the fiber end, which will be described later, this also coincides with the fold line 90L (see FIG. 4) when the measurement sample (cleaning sheet) is folded in a mountain, but one side 1a. 1 is an uneven surface having unevenness as shown in FIGS. 1 to 3, it does not coincide with the contour line of the uneven surface and needs to be defined separately. Therefore, in the present invention, when the surface 1a is a concavo-convex surface, the tangent line at the top of the convex portion constituting the concavo-convex is a straight line BL, and when the heights of the plurality of convex portions constituting the concavo-convex are different, A tangent line at the top of the convex portion having the highest height is defined as a straight line BL. The straight line BL can be determined by observing the side surface (or the cross section along the thickness direction) of the cleaning sheet 1 with an optical microscope.

  The cleaning sheet 1 has one surface (raised surface) 1a on which the long fiber end portion 21 exists, so that the cleaning sheet 1 has a certain collection property and retention property for dust such as hair and dust, In addition, since the protruding length of the long fiber end portion 21 from the fiber assembly 2 is 10 mm or more, dust collection and dust retention are further improved, and a surface to be cleaned such as a floor surface is dried. If the surface to be cleaned is wet with water, etc. (or if the garbage to be collected is wet) Collectability and dust retention can be demonstrated. When the protruding length is less than 10 mm, the dust collecting property and dust holding property are insufficient, and particularly, the dust collecting property and dust holding property when the surface to be cleaned and the dust are wet are insufficient. From the viewpoint of more surely exhibiting such operational effects by the long fiber end portion 21, the protruding length of the long fiber end portion 21 is preferably 10 to 30 mm, and more preferably 10 to 25 mm. If the overhang length is too long, the entire constituent fibers are likely to come out of the fiber assembly 2 and the long fiber end portion 21 may not exist. The protruding length of the fiber end portion from the fiber assembly is measured as follows.

<Measurement method of fiber end length (length protruding from fiber assembly)>
FIG. 4 is an explanatory diagram of a method for measuring the length of the fiber end. A sheet having a brushed surface to be measured is cut into 20 cm × 20 cm to form a measurement sample 90, and the measurement sample 90 is folded in a mountain at a linear fold line 90L with the brushed surface side facing outward. The sheet is placed on the A4 size black mount 91 while maintaining the folded state. In FIG. 4, reference numeral 90 </ b> A is one end portion of the measurement sample 90 folded back to the mount 91 side by mountain folding, and reference numeral 90 </ b> B is the other end portion of the measurement sample 90. In addition, the bending direction when the measurement sample 90 is folded in a mountain is not particularly limited, and may be MD (Machine Direction) of the measurement sample 90 or CD (Cross machine Direction) orthogonal to MD, but is usually MD. To do. “Molding the folding direction as MD” means that the measurement sample 90 is folded so that the extending direction of the folding line 90L coincides with CD (direction perpendicular to MD). Double-sided tape along the fold line 90L on the entire area of the mount 91 on which the measurement sample 90 is placed extends from the fold line 90L to the outside in the direction perpendicular to the fold line 90L (longitudinal direction of the mount 91). 92 is affixed (the double-sided tape 92 does not overlap the fold line 90L). The length L92 of the double-sided tape 92 in the direction along the fold line 90L is 10 cm. Then, in the measurement sample 90 placed on the mount 91, a plan view of an area of 10 cm ² extending from the fold line 90L (the longitudinal side edge on the fold line 90L side of the double-sided tape 92) to the inner side in the longitudinal direction of the mount 91. A rectangular region (the hatched portion in FIG. 4) is a measurement target region 93, and the measurement target region 93 is a brush [manufactured by Komeri Co., Ltd., General Brush NO. 812, brush width (width of the entire portion where the bristles are arranged in the brush) 30 mm], and the fiber end portion 94 of the constituent fiber of the measurement sample 90 existing in the measurement target region 93 is orthogonal to the fold line 90L. The tape is attached to the double-sided tape 92 in a state of being straightened in the direction. In the wrinkle of the measurement target region 93 by the brush, the operation of moving the brush in the direction orthogonal to the fold line 90L from the inside of the measurement sample 90 toward the outside (double-sided tape 92) is performed 10 times, and Adjustment is performed so that the force applied to the measurement target region 93 during the stroke with the brush (the stroke force) falls within the range of 5 to 15 gf. The stroking force can be measured using a scale and can be adjusted with reference to the measured value. Thus, for each of a plurality of fiber ends 94 attached to the double-sided tape 92 in a state extending in a direction perpendicular to the fold line 90L as shown in FIG. 4, the straight line BL [measurement sample is measured from the free end of the fiber end 94. 90 (a straight line connecting the contours of the brushed surface of the measurement sample 90 when the cleaning sheet is viewed from the side)] is drawn, and the length of the perpendicular is determined from the fiber assembly of the fiber end portion 94. The protruding length is L0 (see FIG. 4). The straight line BL is as described above, and the straight line BL coincides with the folding line 90 when the raised surface of the measurement sample 90 is a flat surface without unevenness. For one measurement sample 90, the protrusion length L0 of each of the plurality of fiber end portions 94 is measured in the above-described procedure for each of three arbitrary measurement target regions 93, and the maximum value among the plurality of L0s Is the protruding length of the fiber end portion of the measurement sample 90 from the fiber assembly.

The long fiber end portion 21 having a protruding length of 10 mm or more from the fiber assembly 2 has a raised surface at any position on the raised surface 1a from the viewpoint of more reliably improving dust collection and dust retention. It is preferable that 10 or more exist per 10 cm ² (per measurement target region 93 having a rectangular shape in plan view shown in FIG. 4), and it is particularly preferable that 10 to 60 exist. That is, the number of long fiber ends in the cleaning sheet 1 is preferably 10 or more. The number of long fiber ends corresponds to the number of protruding end lengths L0 of 10 mm or more among the plurality of fiber end portions 94 attached to the double-sided tape 92 in the above-described protruding length measurement method (see FIG. 4). Specifically, for each of the three measurement target regions 93 for one measurement sample 90, the number of the fiber end portions 94 (that is, the long fiber end portions) having a protruding length L0 of 10 mm or more is counted. The average value thereof is defined as the number of long fiber ends in the measurement sample 90.

  In the present embodiment, as shown in FIGS. 1 and 2, one surface (raised surface) 1 a of the cleaning sheet 1 on which the long fiber end portion 21 exists has unevenness including a convex portion 11 and a concave portion 12. is doing. More specifically, the cleaning sheet 1 has one surface 1a and another surface 1b located on the opposite side, and has a large number of convex portions 11 formed to protrude from the other surface 1b side to the one surface 1a side. is doing. A concave portion 12 is formed between the adjacent convex portions 11, 11, and the entire sheet has an uneven shape due to the numerous convex portions 11 and the concave portions 12. As described above, the unevenness on the surface of the sheet makes it possible to collect and hold the dust with the unevenness itself, and the raising process roll and the raising process target sheet in the raising apparatus described later. In the raising treatment of the sheet by contact, since the convex portion 11 constituting the irregularities efficiently abuts on the peripheral surface of the raising roll, compared to the case where the surface of the sheet is a flat surface without irregularities, The constituent fibers of the sheet can be easily pulled out and the long fiber end portion 21 can be easily obtained, and the above-described operation and effect of the long fiber end portion 21 can be more reliably achieved.

  Further, in the present embodiment, the convex portion 11 has more long fiber end portions 21 than the concave portion 12. More specifically, the long fiber end portions 21 having a protruding length of 10 mm or more from the fiber assembly 2 are relatively large at the top portion of the convex portion 11 and the vicinity thereof, and relatively at the bottom portion of the concave portion 12 and the vicinity thereof. There are few. In relation to this, the length of protrusion of the fiber ends of the constituent fibers from the fiber assembly 2 at the top of the convex portion 11 and the vicinity thereof (average value of the length of protrusion of the plurality of fiber ends) is In addition, it is longer than the protruding length at the bottom of the concave portion 12 and in the vicinity thereof. Thus, the convex part 11 has many long fiber end parts 21 compared with the concave part 12, and the reason that the protrusion length is long is composed of the convex part 11 and the concave part 12 as described above. This is because, in the raising treatment of the uneven surface, the convex portion 11 has more contact opportunities with the raising roll than the concave portion 12. The “top portion of the convex portion 11 and its vicinity” means that the convex portion 11 is equally divided into three in the direction of its height h (see FIG. 2), and “upper layer”, “middle layer”, “ The “lower layer” corresponds to the “upper layer”, and the “bottom portion of the concave portion 12 and its vicinity” is a portion corresponding to the “lower layer”.

  In this way, there are relatively many long fiber end portions 21 in the convex portion 11, and the protruding length of the fiber end portion of the concave portion 12 is relatively short. The function is different from that of the section 12, whereby various kinds of dust can be efficiently collected and held as one surface (uneven surface) 1 a of the cleaning sheet 1. When the present inventors conducted a cleaning test of various kinds of dust on the cleaning sheet having the uneven surface as shown in FIG. 1 and FIG. 2, the ratio of the amount of sesame held for the sesame as granular trash. Concave portion: Convex portion = about 5: 1, and relatively many sesame was held in the concave portion, whereas hair as fibrous dust was held substantially uniformly throughout the sheet. From such a result, the convex portion 11 having a relatively large number of long fiber end portions 21 collects various shapes such as fibers and granules from the surface to be cleaned, and also removes the fibrous dust among the long fibers. The concave portion 12 which is preferentially held by being entangled at the end portion 21 and has relatively few long fiber end portions 21 is mainly particulate dust out of the dust collected via the convex portion 11. It is inferred that the long fiber end portion 21 that takes in and extends from the adjacent convex portion 11 plays a role of holding it.

  As shown in FIG. 1, the large number of convex portions 11 are approximately the same size, have a slightly elongated and narrow mountain shape, and are provided regularly. The interval between the convex portions 11, 11 adjacent to each other on one surface 1a of the cleaning sheet 1 is preferably 1 to 10 mm, more preferably 2 to the width direction of the sheet (X direction in FIG. 1, CD at the time of sheet manufacture). It is 8 mm, and preferably 3 to 20 mm, more preferably 4 to 15 mm in the longitudinal direction of the sheet (Y direction in FIG. 1, MD at the time of sheet production). The convex portion 11 may be partly connected to form a continuous body in the width direction and / or longitudinal direction of the sheet, or may be a continuous body throughout the sheet. By providing the convex portions 11 at such intervals, the flexibility of the cleaning sheet 1 can be improved and the surface to be cleaned can be prevented from being damaged. Moreover, it is excellent in the cleaning property of the stain | pollution | contamination with respect to the groove | channel and uneven | corrugated surface of a flooring, and is excellent in the collection property and the retention property of comparatively big stain | pollution | contamination, such as bread crumbs. Furthermore, since the three-dimensional shape of the convex portion 11 is clarified and the stability of the three-dimensional shape is increased, the unevenness becomes clear and is not easily crushed during use.

  The cleaning sheet 1 preferably has the same performance on both surfaces, and the shape and spacing of the convex portions 11 on the other surface 1b are preferably substantially the same as that of the one surface (raised surface) 1a. In particular, the total area of the convex portions 11 on the other surface 1b is preferably 20 to 100%, more preferably 35 to 100% of the total area of the convex portions 11 on the one surface 1a. From the viewpoint of dust collection or retention, the convex portion 11 existing on the one surface 1a of the cleaning sheet 1 is preferably in a front-back relationship with the concave portion 12 existing on the other surface 1b. Moreover, it is also preferable that the shape of the convex portion 11 is a reverse of the shape of the concave portion 12.

  The convex portion 11 and the concave portion 12 are composed of the fiber assembly 2 and are formed only by entanglement of the constituent fibers of the fiber assembly 2. Therefore, unlike the convex part and the concave part formed by fusing the fiber made of thermoplastic resin by partially heating and pressing by embossing or the like, the convex part 11 and the concave part 12 have a feel. It is soft and has a high degree of freedom in the constituent fibers due to the fact that the constituent fibers exist in an independent state without fusing, and it can efficiently collect dust such as hair and fine dust over the entire sheet. Therefore, it is excellent in collection property and retention.

  Moreover, since the convex-shaped part 11 and the concave-shaped part 12 are formed by the rearrangement and re-entanglement of the constituent fibers by hydroentanglement applied to the fiber assembly 2, as will be described later, the convex-shaped part 11 and The concave portion 12 retains its form by itself. Therefore, the convex portion 11 and the concave portion 12 are difficult to sag against the load. In this specification, “formed by re-arrangement / re-entanglement of fibers” means that the fiber aggregate once weakly entangled by hydroentanglement has a large number of irregularities or a large number of openings. It means that the fibers are rearranged along the concavo-convex portion and entangled again by being hydroentangled on the member. Due to the formation of the convex portion 11 and the concave portion 12, the apparent thickness of the cleaning sheet 1 is larger than the thickness of the fiber assembly 2 before the convex portion 11 and the concave portion 12 are applied. Become. The cleaning sheet 1 having the convex portion 11 and the concave portion 12 having a high form-retaining property is excellent in cleaning properties such as grooves and uneven surfaces on the surface to be cleaned, and in collecting dust and retaining properties such as bread crumbs.

  As described above, when the fiber assembly 2 is hydroentangled again on the patterning member, the constituent fiber located in the concave portion of the patterning member, that is, the constituent fiber located in the convex portion 11 of the cleaning sheet 1 Is stretched toward the concave portion of the patterning member, so that the entanglement between the constituent fibers is less than before patterning. On the other hand, since the fiber located in the convex part of the patterning member, that is, the constituent fiber located in the concave part 12 of the cleaning sheet 1 is struck toward the convex part of the patterning member by the water flow, the constituent fiber compared to before patterning Mutual confounding becomes stronger. As a result, in the cleaning sheet 1, the entanglement of the constituent fibers in the convex portion 11 has a weaker structure than that in the concave portion 12. Such a structure is excellent in the cleaning performance of grooves and uneven surfaces on the surface to be cleaned and the collection and retention of dust such as bread crumbs, and the constituent fibers of the convex portions 11 that are relatively weakly entangled are floors. Because it hits the surface strongly, it can efficiently entangle hair and dust. Moreover, since the constituent fibers of the concave portion 12 are relatively entangled, it is possible to prevent the constituent fibers from being removed during cleaning.

  Moreover, when the convex part 11 is weaker in the entanglement of the constituent fibers than the concave part 12 in this way, in the raising process of the concavo-convex surface composed of the convex part 11 and the concave part 12, the convex part 11 as described above. The portion of the constituent fibers of the convex portion 11 (the top portion of the convex portion 11 and the vicinity thereof) by the raised processing roll is coupled with the fact that there are many opportunities to contact the raised processing roll as compared with the concave portion 12. Pulling out easily occurs, and a long fiber end portion 21 is present in the convex portion 11.

  When the convex part 11 considers the range of 10 cm × 10 cm on the one surface (raised surface) 1 a or the other surface 1 b of the cleaning sheet 1, it is averaged in the range at any position on the surface. It is preferable that 50 to 850, particularly 100 to 600 are formed. Further, when the convex portion 11 is partly connected to form a continuous body with respect to the width direction and / or the longitudinal direction of the sheet, or when the convex portion 11 is a continuous body throughout the sheet, Alternatively, it is preferable that 10 to 50 rows, particularly 20 to 40 rows are formed on the average within a range of 10 cm in length in the longitudinal direction. By setting the number of the convex portions 11 within the above range, the convex portions 11 and the concave portions 12 are arranged in a well-balanced manner, so that the collection and retention of fine dust can be further improved, and breadcrumbs, etc. The collection and retention of relatively large garbage is further improved.

As shown in FIG. 2, the cleaning sheet 1 has an apparent thickness [thickness between the uppermost portion (excluding the long fiber end portion 21) of one surface (raised surface) 1a and the lowermost portion of the other surface 1b). T is thicker than the thickness of the fiber assembly 2 itself [thickness between the lowermost portion of the support 3 and the uppermost portion (excluding the long fiber end portion 21) of one surface (raised surface) 1a] t. It is in a bulky state. The apparent thickness T of the cleaning sheet 1 is 1 to 5 mm, particularly 1.3 to 4 mm, because a sufficient gap is formed in the cleaning sheet 1 and becomes bulky, which is suitable as a cleaning sheet. It is preferable because it can be used. Moreover, although the value itself of the thickness t of the fiber assembly 2 itself is determined by the basis weight, processing conditions, etc. of the fiber assembly 2, it is preferably 0.2 to 4 mm, more preferably 0.5 to 3 mm. . Moreover, as shown in FIG. 2, the height h of the convex-shaped part 11 becomes like this. Preferably it is 0.2-4 mm, More preferably, it is 0.5-4 mm. The apparent thickness T of the cleaning sheet 1, the thickness t of the fiber assembly 2 itself, and the height h of the convex portion 11 are 10 cm × 5 cm acrylic plate on the cleaning sheet 1 having the fiber assembly 2 to be measured. The weight of 30 gf / 50 cm ² (= 59 Pa) is applied to the cleaning sheet 1 in the thickness direction by placing a weight on top and a total weight of 30 g, and the cross section of the cleaning sheet 1 in that state. Is observed with an optical microscope.

  The fiber assembly 2 will be further described. As described above, the fiber assembly 2 according to this embodiment is a spunlace nonwoven fabric formed by hydroentangling a fiber web, and is formed only by entanglement of constituent fibers. However, the fiber assembly according to the present invention only needs to include a portion formed by entanglement of the constituent fibers, and partially includes a portion formed by fusion or adhesion of the constituent fibers. It does not matter. However, from the viewpoint of easily obtaining raised fibers having a raising length of 10 mm or more by raising treatment using a raising roll described later, the fiber assembly according to the present invention has a high degree of freedom of constituent fibers. More specifically, those formed only by entanglement of constituent fibers, such as spunlace nonwoven fabric, are preferably used. In addition to the spunlace nonwoven fabric, needle punch nonwoven fabrics, stitch bond nonwoven fabrics, and the like are also preferably used as the fiber assembly according to the present invention because of the high degree of freedom of the constituent fibers. In particular, spunlace nonwoven fabric is preferable because it has excellent dust collection performance.

  As the constituent fiber (long fiber end portion 21) of the fiber assembly 2, those usually used as constituent fibers of various nonwoven fabrics can be used, for example, polyolefins such as polyethylene (PE) and polypropylene (PP); Polyesters such as polyethylene terephthalate (PET) and polybutylene terephthalate (PBT); synthetic fibers (thermoplastic fibers) made from synthetic resins such as nylon (registered trademark) and polyamides such as nylon 6; regenerated cellulose fibers such as rayon; Examples thereof include biodegradable fibers such as polylactic acid. Further, the fiber configuration of the constituent fibers may be a single fiber made of one type of resin, or a composite fiber containing two or more types of resins having different melting points. As the composite fiber, a core-sheath type in which a resin having a relatively low melting point (low melting point resin) is a sheath and a resin having a relatively high melting point (high melting point resin) is a core; low melting point resin and high melting point resin Are side-by-side type in which are aligned in a predetermined direction.

  From the viewpoints of dust collection and dust retention, the fiber assembly 2 has a ratio of 50% by mass or more to the total constituent fibers of the constituent fibers having a fiber diameter (diameter) of 5 to 60 μm (hereinafter also referred to as specific fibers), In particular, it is preferably 70% by mass or more, particularly preferably 100% by mass. Further, regarding the fiber diameter of the specific fiber, from the viewpoint of reducing the frictional resistance when wiping the surface to be cleaned, the lower limit is preferably 8 μm, and particularly preferably 10 μm. Therefore, the upper limit is preferably 45 μm, particularly 40 μm. That the fiber diameter of the constituent fiber (the specific fiber) of the fiber assembly 2 is within the above range means that the fiber diameter of the long fiber end portion 21 is also within the above range. The fiber diameter of the constituent fibers is measured as follows.

<Measurement method of fiber diameter>
For the fibers to be measured (component fibers of the fiber assembly), the fiber diameter (diameter) of any 10 points is measured using a microscope, and the average value of the 10 measured values is determined as the fiber diameter of the fiber. To do. When the fiber assembly includes two or more kinds of fibers having different fiber diameters, the fiber diameters of any 10 points are measured according to the above procedure for each fiber, and the average value of the measured values of the 10 points is The fiber diameter of the fiber. In addition, when the fiber cross section is not a perfect circle but an ellipse or a flat structure (when the object to be measured is a non-round fiber), the equivalent diameter is simply obtained using the following method, The fiber diameter. That is, 10 points of relatively thick portions and 10 points of relatively thin portions of non-round fibers are arbitrarily selected, and the fiber diameter (diameter) is measured for each of these 20 points using a microscope. The average value of the 10 portions is a, the average value of the 10 thin portions is b, and the square root of the product of a and b is the fiber diameter of the non-round fiber.

  The fiber length of the constituent fibers of the fiber assembly 2 is the length of the fiber end portion (extruding from the fiber assembly 2) when the fiber end portion of the constituent fiber is pulled out of the fiber assembly 2 by the raising process described later. The length is preferably 10 mm or more, and is preferably 25 to 100 mm, and more preferably 35 to 70 mm, from the viewpoint of maintaining a practically sufficient strength as a cleaning sheet even after the raising treatment. The fiber length is measured as follows. That is, 10 fibers are drawn out from the fiber assembly to be measured, taking care not to break, and the length of each drawn fiber is measured, and the average value thereof is calculated as the fiber length of the constituent fibers of the fiber assembly. And If the drawn fiber is crimped, measure the length of the drawn fiber straight.

The basis weight of the fiber assembly ² is 15 to 100 g / m ² , particularly 20 to 80 g / m ² , so that when the cleaning sheet 1 is used, dust is pulled out to the back side of the sheet 1 or the sheet 1 is gripped. This is preferable in that the hands and the like can be prevented from becoming dirty, and the constituent fibers of the fiber assembly 2 and the fiber assembly 2 and the support 3 can be sufficiently entangled.

  In the present embodiment, the support 3 is made of a net-like sheet in which the constituent fibers of the fiber assembly 2 can be entangled. Specifically, as shown in FIG. 5, the support 3 is made of a lattice-like net 31 having many holes 30. Become. Since the support 3 is continuously present in the planar direction of the cleaning sheet 1, by using a net-like sheet as the support 3, the fiber assembly 2 has a low basis weight and weak entanglement, Even if the strength is insufficient, the cleaning sheet 1 as a whole can have a practically sufficient strength. In order to stably pull out the constituent fibers by the raising treatment, it is preferable that the degree of freedom of the constituent fibers is as high as possible, and the entangled state of the constituent fibers in the fiber assembly 2 is preferably weak. Generally, when the fiber entangled state is weak, the strength of the cleaning sheet 1 is low, and it is difficult to give practically sufficient strength. However, the use of the support 3 is sufficient for the cleaning sheet. Since strength can be given, even if the entangled state of the fiber assembly 2 is weakened, the strength of the cleaning sheet does not become so weak that it is difficult to use. Therefore, it is possible to effectively pull out the fiber by the raising process without cutting the fiber, and the cleaning sheet 1 having sufficient strength can be obtained.

  The dimensions of each part such as the wire diameter L1 and the distance L2 between the nets 31 are appropriately determined in consideration of the entanglement with the fiber assembly 2 and the like. The wire diameter L1 corresponds to the thickness of the net 31. The wire diameter L1 is preferably 50 to 600 μm, more preferably 100 to 400 μm, and the line distance L2 is preferably 2 to 30 mm, more preferably 4 to 20 mm. The wire diameter L1 may be partially different. In this case, the wire diameter of a relatively thick portion corresponds to the above value. Further, the distance L2 between the lines may be the same or different in the width direction of the sheet (X direction in FIG. 5, CD at the time of manufacturing the sheet) and the longitudinal direction of the sheet (Y direction in FIG. 5, MD at the time of manufacturing the sheet). May be.

  However, the support (mesh sheet) according to the present invention is not limited to such a lattice-like net 31, and for example, a perforated film having a large number of holes 30 as shown in FIGS. 6 (a) to 6 (c). 32 may be sufficient. In other words, the type of the reticulated sheet is not particularly limited as long as it has a hole through which fibers can pass and the fiber aggregate or the fiber web that is a material for forming the fiber aggregate can be integrated in an entangled state. For example, a woven fabric with a relatively large mesh space such as a gauze-like woven fabric, or a nonwoven fabric or paper having fiber voids that can be integrated in an entangled state by overlapping fiber webs on one or both sides, Alternatively, various non-woven fabrics and papers having holes are also used as the reticulated sheet as the support 3. 5 and 6, the plan view shape of the hole 30 can be changed as appropriate. For example, the perforated film 32 may have a star shape (cross shape) as shown in FIG. A circular shape as shown in FIG. Moreover, as shown in FIG.6 (c), you may combine the multiple types of hole 30 (two types of star shape and circular shape in the form of illustration) from which planar view shape differs.

  Examples of the material for forming the support 3 (network sheet) include polyolefin resins such as polyethylene, polypropylene, and polybutene; polyester resins such as polyethylene terephthalate and polybutylene terephthalate; polyamide resins such as nylon 6 and nylon 66; acrylonitrile -Based resins; vinyl resins such as polyvinyl chloride; vinylidene resins such as polyvinylidene chloride; cellulose-based regenerated fibers such as rayon; pulp materials and the like, modified materials, alloys or mixtures of these forming materials Can also be used.

The basis weight of the support 3 (network sheet) is preferably 3 to 60 g / m ² , more preferably 4 to 40 g / m ² . Moreover, the mass ratio which occupies for the whole sheet | seat 1 for cleaning of the support body 3 becomes like this. Preferably it is 5-70 mass%, More preferably, it is 8-60 mass%.

  The sheet elongation of the support 3 (net-like sheet) improves the attachment of the cleaning sheet 1 to the cleaning tool, and the operability deteriorates due to the cleaning sheet 1 extending and coming off the cleaning tool during cleaning. From the viewpoint of preventing the occurrence of the problem and further stably performing the raising treatment on the cleaning sheet 1, it is preferably less than 40%, more preferably less than 20%, and particularly preferably less than 10%. Sheet elongation is measured by the method described below.

The basis weight of the cleaning sheet 1 is adapted to impart appropriate thick feeling cleaning sheet 1, from the viewpoint of improving the processability, preferably 35~150g / m ^2, more preferably 45~100g / m ² It is.

  In the cleaning sheet 1, the confounding coefficient represented by the initial gradient of the fiber orientation and the stress-strain curve in the vertical direction in the fiber assembly 2 constituting the cleaning sheet 1 is 0.05 to 2 N · m / g, particularly It is preferably 0.2 to 1.2 N · m / g from the viewpoint of sufficient entanglement and sufficient fiber freedom for collecting dust. It can be said that the smaller the value of the entanglement coefficient, the weaker the entanglement between the fibers. The stress indicates a value obtained by dividing the tensile load value by the grip width (the width of the test piece at the time of measuring the tensile strength) and the basis weight of the non-woven fiber assembly 2, and the strain indicates the elongation. The degree of entanglement between fibers mainly depends on the entanglement energy applied to the fiber web during the entanglement process. For example, in hydroentanglement (water needling), the entangling energy applied to the fiber web can be controlled by conditions such as the type of fiber, the basis weight of the fiber web, the number of water jet nozzles, the water pressure, and the line speed.

  Next, an example of the manufacturing method of the cleaning sheet 1 of the present embodiment will be described with reference to FIGS. In the manufacturing method of the cleaning sheet 1 of the present embodiment, the polymerization step of superposing the upper fiber web 4a and the lower fiber web 4b on both surfaces of the support 3 (net 31) to form the polymer 5, and hydroentanglement In this way, the fiber webs 4a and 4b in the polymer 5 are entangled between the constituent fibers of the polymer 5 to form the fiber assembly 2, and the constituent fibers and the support 3 are entangled so that both are integrated. And the entanglement step of forming the composite 6 and the composite 6 is conveyed onto a patterning member having a large number of concave and convex portions, and a part of the fiber assembly 2 is protruded into the concave portion so as to correspond to the concave portions. The uneven | corrugated provision process which forms the part 11 (refer FIG.1 and FIG.2) in the composite body 6, and obtains the uneven | corrugated composite body 7, the drying process of drying the uneven | corrugated composite body 7, and the raising which performs a raising process to the uneven | corrugated composite body 7 The process proceeds in this order. In addition, the arrow shown by the code | symbol Y of FIG. 7, and the arrow shown by the code | symbol V1 of FIG. 8 are MD (Machine Direction) at the time of manufacture of the sheet | seat 1 for cleaning, respectively.

  As shown in FIG. 7, the manufacturing apparatus 50 includes a superposition part 50 </ b> A, an entanglement part 50 </ b> B, and an unevenness imparting part 50 </ b> C. 50 A of superposition | polymerization parts are the card machines 51A and 51B which manufacture the fiber webs 4a and 4b, respectively, the delivery rolls 52 and 52 of the fiber webs 4a and 4b, and the delivery of the support body 3 (net 31) wound in roll shape. And a roll 54. The entangled portion 50B includes a web support belt 55 made of an endless belt, and a first water jet nozzle 56. The unevenness imparting part 50C includes a patterning member 57 made of an endless belt and a second water jet nozzle 58. The patterning member 57 is rotated in the direction indicated by the arrow in FIG. The patterning member 57 is liquid-permeable and has a large number of irregularities on its surface.

  Moreover, the manufacturing apparatus 50 is provided with the raising process part 50D, as shown in FIG. The raised portion 50D is a portion for raising the constituent fibers of the uneven composite body 7 obtained through the unevenness imparting step, and in the manufacturing apparatus 50 of the present embodiment, the raised portions having a large number of convex portions 60A on the peripheral surface. A processing roll 60 is provided. The raising roll 60 has a metallic cylindrical shape such as an aluminum alloy or steel. The raising roll 60 is rotated by the driving force transmitted from the driving means (not shown) to the rotating shaft. The rotational speed (circumferential speed V2) of the raising roll 60 is controlled by a control unit (not shown) included in the manufacturing apparatus 50. Here, the circumferential speed V2 of the raising roll 60 means the speed on the surface of the raising roll 60. By adjusting the peripheral speed V2 of the raising roll 60, the raising height (the standing height of the long fiber end 21) and the number of raising (the number of long fiber ends) can be adjusted.

Each convex portion 60A on the circumferential surface of the raising roll 60 preferably has a height from the circumferential surface to the apex (top end) of the convex portion 60A of 0.01 to 5 mm, preferably 0.01 to 2 mm. More preferably it is. The distance (pitch) between the convex portions 60A adjacent in the circumferential direction and the distance (pitch) between the convex portions 60A adjacent in the rotation axis direction are each preferably 0.01 to 60 mm, and 0.01 to 5 mm, respectively. More preferably. The number of convex portions 60A per unit area is preferably 50 to 5000 / cm ² , since raising can be efficiently performed. In addition, the shape of the top of the convex portion 60A in plan view is not particularly limited, and can be, for example, a circle, an ellipse, a polygon, or the like. The area of the top end of the convex portion 60A is preferably 0.001 to 10 mm ² and more preferably 0.001 to ¹ mm ² from the viewpoint of increasing the ease of catching the fibers and causing efficient raising. preferable. As a roll having a concavo-convex surface comprising such a convex portion 60A, in addition to an embossing roll having a fine concavo-convex pattern on the peripheral surface, a roll in which sandpaper is wound around the peripheral surface, or concavo-convex processing on the peripheral surface by sandblasting Examples thereof include applied rolls (sandblast rolls).

  Further, as shown in FIG. 8, the raising unit 50 </ b> D includes conveyance rolls 61 and 62 that convey the napping object (uneven complex 7) on the upstream side and the downstream side of the raising roller 60. Yes. The conveyance speed V <b> 1 of the concavo-convex composite 7 is controlled by a control unit (not shown) included in the manufacturing apparatus 50. Here, the conveyance speed V <b> 1 of the concavo-convex composite 7 means a speed on the surface of the concavo-convex composite 7 supplied to the raising roll 60.

  From the viewpoint of raising the constituent fibers of the uneven composite body 7 more efficiently, as shown in FIG. 8, the position of the transport roll 61 on the downstream side of the raising roll 60 is set higher than the position of the raising roll 60. Is preferred. More specifically, it is preferable that the concavo-convex composite 7 is in contact with the contact surface (circumferential surface) with the raised roll 60 so that the holding angle α is 10 to 180 °, particularly 30 to 120 °. .

  In the manufacturing apparatus 50 of the cleaning sheet 1 having such a configuration, first, as shown in FIG. 7, the fiber webs 4a and 4b are continuously fed from the feeding rolls 52, from each of the card machines 51A and 51B in the superposition unit 50A. The roll-shaped support 3 (net 31) is fed out from the feed roll 54 while being fed out through 52 respectively. And the fiber webs 4a and 4b are each overlaid on both surfaces of the net | network 31 by the delivery rolls 52 and 52, and the polymer 5 is formed (polymerization process).

  Next, in the entangled portion 50B, as shown in FIG. 7, the polymer 5 is entangled by the high-pressure jet water flow ejected from the first water jet nozzle 56 while being transferred and transported onto the web support belt 55. Processed (entanglement process). Thus, the constituent fibers of the fiber webs 4a and 4b in the polymer 5 are intertwined to form the fiber assembly 2, and the constituent fibers and the support 3 are intertwined. An integrated composite 6 is obtained.

  Next, in the unevenness imparting section 50C, as shown in FIG. 7, the composite 6 is partially transferred by the high-pressure jet water stream ejected from the second water jet nozzle 58 while being transferred and transported onto the patterning member 57. Pressurized (unevenness imparting step). In that case, the part located on the recessed part of the patterning member 57 among the composites 6 is pressurized, and this pressurized part protrudes in this recessed part. As a result, the pressure portion becomes a concave portion 12 (see FIGS. 1 and 2) corresponding to the concave portion. On the other hand, a portion of the composite 6 that is located on the convex portion of the patterning member 57 does not protrude and becomes the convex portion 11. In this way, a large number of convex portions 11 and concave portions 12 are formed in the composite 6, and an uneven shape is imparted to the composite 6 as a whole, whereby the uneven composite 7 is obtained. The shape or the like of the convex portion 11 in the concavo-convex composite 7 is determined according to the type of the patterning member 57 and the entanglement energy applied to the fiber assembly by the high-pressure jet water flow in the entangled portion 50B and the concavo-convex imparting portion 50C. This entanglement energy is controlled by conditions such as the nozzle shape of the water jet nozzle, nozzle pitch, water pressure, number of nozzle stages (lines), and line speed. In addition, since the unevenness imparting step is a step of applying a high-pressure jet water stream to the fiber assembly (fiber web) and the support in the same manner as the entanglement step, these entanglements may be entangled in the unevenness imparting step, The entanglement process is not always completed in the entanglement process.

  The concavo-convex composite 7 obtained in this way is carried into a heating device (not shown) by the conveying belt 29, and is subjected to a heat treatment such as hot air blowing (drying process). In the next raising process, it is desirable that the surface 3a '(see FIG. 8) of the concavo-convex composite 7 is subjected to a raising process, and the support 3 is not exposed on the one surface 1a' before the raising process.

  Next, in the raising part 50D, as shown in FIG. 8, the concavo-convex composite 7 is conveyed in the direction Y on the circumferential surface of the raising roll 60 by the conveying rolls 61 and 62, and the fine irregularities on the circumferential surface Then, a raising process is performed on one surface 1a ′ of the concavo-convex composite body 7 (raising process). In the raising part 50D, the concavo-convex composite 7 is conveyed while being brought into contact with the peripheral surface of the raising roll 60, whereby the constituent fiber of the concavo-convex composite 7 is formed on the convex part 60A constituting the fine irregularities on the peripheral surface. Are entangled, and the constituent fiber entangled with the convex part is not completely pulled out from the concavo-convex composite 7 (without detaching from the concavo-convex composite 7), and is partially pulled out, so that the fiber end of the constituent fiber Protrudes from one surface 1a ′ of the concavo-convex composite 7, and a large number of long fiber end portions 21 (see FIG. 3) are formed. The end of the constituent fiber located on the opposite side of the fiber end (long fiber end 21) remains in the concavo-convex composite 7. The numerous raised portions 60A on the circumferential surface of the raised roll 60 have a shorter protruding length from the circumferential surface than the numerous needles on the circumferential surface of the counter pile roller described in Patent Documents 1 and 2. Since the number per unit area is large, it is difficult to cut the constituent fibers entangled in the raising treatment of the fiber assembly (nonwoven fabric), and it is easy to partially pull out the fiber assembly without cutting the constituent fibers. In the raising part 50D, from the viewpoint of promoting the drawing of the constituent fibers and efficiently forming the long fiber end part 21, as shown in FIG. It is preferable to rotate in the direction opposite to the direction. In this way, the cleaning sheet 1 having the raised treatment surface 1a in which many long fiber end portions 21 having a protruding length of 10 mm or more from the fiber assembly 2 exist is obtained.

  The present invention is not limited to the embodiment. For example, in the cleaning sheet 1, not only the one surface 1 a but also the other surface 1 b located on the opposite side may be a raised surface where the long fiber end portions 21 exist. Thus, when making both surfaces 1a and 1b of the sheet | seat 1 for cleaning into a raising process surface, the manufacturing apparatus 50 makes MD the raising | fluff processing part of the structure similar to the raising process part 50D shown in FIG. 2), the concavo-convex composite 7 may be sequentially passed through each raised portion and the raised portions may be sequentially subjected to raising treatment, or one configuration without changing the configuration of the manufacturing apparatus 50. The raising process part 50D may be used, and the concavo-convex composite body 7 may be reversed so that the raising process may be sequentially performed on both surfaces thereof.

  Moreover, in the said embodiment, although the high pressure jet water flow was applied to the single side | surface of the polymer 5 in the confounding process and the confounding process was performed, the high pressure jet water flow was applied to each of both surfaces of the polymer 5 simultaneously or sequentially. Processing may be performed. Moreover, the 1st surface 1a of the sheet | seat 1 for cleaning in which the long fiber edge part 21 exists does not need to have an unevenness | corrugation.

  EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to such examples.

[Example 1]
A cleaning sheet having the same configuration as the cleaning sheet 1 shown in FIGS. 1 and 2 was produced using a production apparatus as shown in FIGS. 7 and 8, and was used as a sample of Example 1. Specifically, first, a fiber web having a basis weight of 24 g / m ² was obtained using PET fiber (fiber diameter 11 μm, fiber length 38 mm) as a raw material and using a conventional card method. Next, using a lattice-like net made of polypropylene (wire diameter: 300 μm, distance between lines: 8 mm, basis weight: 5 g / m ² ) as a support (mesh sheet), the obtained fiber web was applied to each of the upper and lower surfaces of the support. Superposed to obtain a polymer (polymerization step), the polymer is entangled by jet water flow (water pressure 1 to 5 MPa) ejected from a plurality of nozzles and entangled and integrated, with an entanglement coefficient of 0.5 N · m / g A composite having a fiber assembly (spun lace nonwoven fabric) is obtained (entanglement step), and further, jet water flow ejected from a plurality of nozzles is applied to the composite on the patterning member under a water pressure of 1 to 5 MPa to form an uneven shape. The concavo-convex composite was obtained by applying (concavo-convex provision process), and the concavo-convex composite was dried with hot air (drying process). Then, only one surface of the obtained concavo-convex composite was subjected to raising treatment by a raising roll (raising step) to obtain a cleaning sheet having the desired irregularities. A sandblasting roll is used as the raising roll, the conveying speed V1 (see FIG. 8) of the uneven composite is 20 m / min, the peripheral speed V2 of the sandblast roll (see FIG. 8) is 200 m / min, and the sandblasting roll is used as the uneven composite. It was rotated in the opposite direction to the transport direction. The height of the convex portions on the circumferential surface of the sandblast roll is about 0.07 mm, and the distance (pitch) between the convex portions adjacent in the circumferential direction and the distance (pitch) between the convex portions adjacent in the rotation axis direction are about The area of the tip of the convex part was about 0.008 mm ² , and the number of convex parts per unit area was about 2000 / cm ² .

[Example 2]
A cleaning sheet having irregularities was produced in the same manner as in Example 1 except that the circumferential speed V2 of the sandblast roll was set to 20 m / min.

Example 3
Except for setting the circumferential speed V2 of the sandblast roll to 10 m / min, a cleaning sheet having irregularities was produced in the same manner as in Example 1, and this was designated as Example 3.

Example 4
PET fiber (fiber diameter 11 μm, fiber length 38 mm) and core-sheath type composite fiber (core part is PP, sheath part is PE, fiber diameter 48 μm, fiber length 51 mm) are used as the raw material of the fiber web, and the mixed mass of both fibers A cleaning sheet was prepared in the same manner as in Example 1 except that the ratio was PET fiber: core-sheath composite fiber = 45: 55, and the unevenness providing step was omitted. By omitting the unevenness providing step, the resulting cleaning sheet is substantially flat without unevenness.

Example 5
PET fiber (fiber diameter 11 μm, fiber length 38 mm) and core-sheath type composite fiber (core part is PP, sheath part is PE, fiber diameter 40 μm, fiber length 51 mm) are used as the raw material of the fiber web, and the mixed mass of both fibers A cleaning sheet having irregularities was produced in the same manner as in Example 1 except that the ratio was PET fiber: core-sheath type composite fiber = 45: 55.

Example 6
Two types of PET fibers having different fiber diameters and fiber lengths (first PET fibers (fiber diameter 11 μm, fiber length 38 mm), second PET fibers (fiber diameter 32 μm, fiber length 51 mm)) and both fibers are used as raw materials for the fiber web. A cleaning sheet having irregularities was prepared in the same manner as in Example 1 except that the mixing mass ratio of the first PET fiber: second PET fiber = 45: 55 was changed to Example 6.

Example 7
For cleaning with substantially no unevenness in the same manner as in Example 1 except that PET / nylon split fibers (fiber diameter after splitting: about 7 μm, fiber length: 51 mm) are used as the raw material of the fiber web, and the unevenness providing step is omitted. A sheet was prepared and used as Example 7.

Example 8
As a support (net-like sheet), a perforated spunlace nonwoven fabric composed of rayon fibers (rayon fineness 2.2 dtex, basis weight 40 g / m ² , perforation size (MD 1.5 mm, CD 0.5 mm), perforation rate 30%) A cleaning sheet having irregularities was produced in the same manner as in Example 1 except that was used as Example 8.

Example 9
In Example 1, except that the unevenness providing step was omitted, a cleaning sheet having substantially no unevenness was produced in the same manner as Example 1, and this was designated as Example 9.

[Comparative Example 1]
A cleaning sheet having irregularities was produced in the same manner as in Example 1 except that the raising step was omitted, and this was designated as Comparative Example 1.

[Comparative Example 2]
First, a fiber web having a basis weight of 30 g / m ² was obtained from a core-sheath type composite fiber (core part is PP, sheath part is PE, fiber diameter is 17 μm, fiber length is 51 mm) and a conventional card method is used. Next, the fiber web was heat treated at 135 ° C. to fuse the fibers together to obtain an air-through nonwoven fabric. The air-through nonwoven fabric thus obtained was subjected to a raising process by the same raising process as in Example 1 to produce a cleaning sheet having substantially no unevenness, and this was designated as Comparative Example 2.

[Comparative Example 3]
A cleaning sheet substantially free of irregularities by subjecting a spunbonded nonwoven fabric of PET fiber (fiber diameter 25 μm, continuous fiber) to a basis weight of 30 g / m ² with a raising process similar to that in Example 1 This was produced as Comparative Example 3.

[Comparative Example 4]
A cleaning sheet having substantially no unevenness was prepared in the same manner as in Example 1 except that the sheet was formed only with the fiber web without using the support (net-like sheet) and the convexity imparting step was omitted. Was referred to as Comparative Example 4.

[Comparative Example 5]
A cleaning sheet having substantially no unevenness was produced in the same manner as in Example 1 except that the unevenness providing step and the raising step were omitted, and this was designated as Comparative Example 5.

[Evaluation]
About each sample (sheet for cleaning) of an example and a comparative example, according to the above-mentioned method, while extruding length from the fiber aggregate of a fiber end part and the number of long fiber end parts, respectively, according to the following method, a dry cleaning surface In addition, the hair collection property, the fine dust collection property, the large granular dust collection property, the sheet elongation, the fiber dropout degree, and the wiping resistance on each of the wet cleaned surfaces were evaluated. The evaluation environment was a room temperature of 20 ° C. and a humidity of 60% RH. The results are shown in Table 1 below.

  Moreover, about each sample (cleaning sheet) of an Example and a comparative example, the fiber end part (including the fiber end part (long fiber end part) of 10 mm or more in length) protruded from the fiber assembly was visually observed. Then, about the cleaning sheet | seat (Examples 1-3, 5, 6 and 8 and the sample of the comparative example 1) which has an unevenness | corrugation, the said fiber end part is the convex part (top part of a convex part) which comprises an unevenness | corrugation. And in the vicinity thereof, and relatively small in the concave portion (the bottom portion of the concave portion and the vicinity thereof) constituting the unevenness. On the other hand, about the cleaning sheet (Examples 4, 7 and 9 and the samples of Comparative Examples 2 to 5) having substantially no unevenness, the fiber end portion is the entire surface (raised surface) of the cleaning sheet. Existed almost uniformly.

<Evaluation method of hair collection on dry surface to be cleaned>
The cleaning sheet was attached to the head part of Quickle Wiper (registered trademark), which is a cleaning tool manufactured by Kao Corporation. In evaluation, the surface (raised surface) which performed the raising process in the manufacturing process of the cleaning sheet was used as a cleaning surface. When there was no raised surface, any one surface of the cleaning sheet was used as the cleaning surface. Using a dry flooring surface (size 30 cm x 60 cm, manufactured by Matsushita Electric Works, Woody F) as the surface to be cleaned, 10 hairs of about 10 cm are spread on the flooring surface, and then the cleaning attached to the head unit on the surface. The entire surface of the flooring surface is wiped once with a certain stroke (60 cm) by placing the sheet for cleaning, and the hair is collected on the cleaning sheet. Thereafter, the head portion of the quick wiper was shaken 10 times with a stroke of 10 cm up and down to drop the hair not held on the cleaning sheet, and then the number of hairs held on the cleaning sheet was counted. The above operation was continuously performed for five types of cleaning sheets, and the total number of hairs collected by the five cleaning sheets (collected total number) was recorded. Then, divide the total number of collected hairs by 50 (the total number of scattered hairs), and multiply by 100 to obtain the retention rate (%) of the collected hair, and the retention rate is based on the following criteria: Based on this, it was evaluated as the hair collecting property on the dry surface to be cleaned.
A: Retention rate is 80% or more, and the hair collecting property on the dry surface to be cleaned is good.
○: Retention rate is 60% or more and less than 80%, and the hair collecting property on the dry surface to be cleaned is a practically sufficient level.
Δ: Retention rate is 40% or more and less than 60%, and is slightly inferior to the hair collecting property on the dry surface to be cleaned, but at a practical level.
X: Retention rate is less than 40%, and the ability to collect hair on the surface to be dried is not practical.

<Evaluation method of hair collection on wet surface to be cleaned>
In the above <Method for evaluating hair collection on dry surface to be cleaned>, after 10 hairs are sprayed on the surface to be cleaned, and further, 1 ml of ion-exchanged water is sprayed and applied to the hair. The retention rate (%) of the collected hair was determined by the same procedure as described above, and the retention rate was evaluated as the hair collecting property on the wet cleaned surface based on the following criteria.
A: Retention rate is 80% or more, and the hair collecting property on the wet surface to be cleaned is good.
○: Retention rate is 60% or more and less than 80%, and the hair collecting property on the wet cleaned surface is a practically sufficient level.
Δ: Retention rate is 40% or more and less than 60%, and is practically inferior to hair collecting property on a wet surface to be cleaned.
X: Retention rate is less than 40%, and the ability to collect hair on a wet surface to be cleaned is not practical.

<Evaluation method for collecting fine dust>
The cleaning sheet was attached to the head part of Quickle Wiper (registered trademark), which is a cleaning tool manufactured by Kao Corporation. Fine dust is used to evaluate dust collection. In evaluation, the surface (raised surface) which performed the raising process in the manufacturing process of the cleaning sheet was used as a cleaning surface. When there was no raised surface, any one surface of the cleaning sheet was used as the cleaning surface. Seven types of test dust (“JIS Z 8901”, “JIS Z 8901” test powder, manufactured on the surface of the flooring surface (size 90 cm × 90 cm, manufactured by Matsushita Electric Works, Woody F)) as a surface to be cleaned 7 types of test powder 1 specified in “Body and test particles”)) After 0.2 g (7 types total weight 0.2 g) is sprayed, the cleaning sheet attached to the head part is fixed. The entire area of the flooring surface is wiped twice with a stroke (60 cm), and the mass of dust attached to the cleaning sheet is measured. The mass of dust attached to the cleaning sheet is measured by subtracting the total mass of the cleaning sheet before wiping measured in advance from the total mass of the cleaning sheet after wiping. The above operation was carried out five times continuously for one type of cleaning sheet, and the total mass (collected total mass) of dust collected by the five cleaning sheets was recorded. Then, the total mass collected is divided by 1.0 (the total mass of dust dispersed), and further multiplied by 100 to obtain a fine dust collection rate (%). Based on the criteria, it was evaluated as a fine dust collecting property.
(Double-circle): The collection rate is 70% or more, and the collection property of fine dust is favorable.
◯: The collection rate is 50% or more and less than 70%, and the fine dust collection property is a practically sufficient level.
(Triangle | delta): The collection rate is 40% or more and less than 50%, and the level which is practically practical although it is somewhat inferior to the fine dust collection property.
X: The collection rate is less than 40%, and the collection property of fine dust is not practical.

<Evaluation method for collection of large granular waste>
The cleaning sheet was attached to the head part of Quickle Wiper (registered trademark), which is a cleaning tool manufactured by Kao Corporation. In evaluation, the surface (raised surface) which performed the raising process in the manufacturing process of the cleaning sheet was used as a cleaning surface. When there was no raised surface, any one surface of the cleaning sheet was used as the cleaning surface. Using a dry flooring surface (size: 30 cm x 60 cm, manufactured by Matsushita Electric Works, Woody F) as the surface to be cleaned, 0.5 g of bread crumb having a particle size of about 1.0 to 1.4 mm is sprayed on the flooring surface as large granular waste. After that, the cleaning sheet mounted on the head part is placed on the floor, and the entire flooring surface is wiped once and again with a certain stroke (60 cm) to collect the crumbs on the cleaning sheet. Measure the mass of the bread crumbs. The mass of the bread crumbs collected on the cleaning sheet is measured by subtracting the total mass of the cleaning sheet before wiping measured in advance from the total mass of the cleaning sheet after wiping. The above operation was carried out five times continuously for one type of cleaning sheet, and the total mass (collected total mass) of bread crumbs collected by the five cleaning sheets was recorded. Then, the total mass collected is divided by 2.5 (the total mass of the spread bread crumbs), and further multiplied by 100 to obtain a larger granular dust collection rate (%). Based on these criteria, it was evaluated as a large granular dust collecting property.
(Double-circle): The collection rate is 50% or more, and the collection property of large granular dust is good.
○: The collection rate is 30% or more and less than 50%, and the collection property of large granular dust is a practically sufficient level.
Δ: The collection rate is 15% or more and less than 30%, and is slightly inferior to the collection property of large granular dust, but at a practical level.
X: The collection rate is less than 15%, and the collection property of large granular dust is not practical.

<Evaluation method of sheet elongation>
From the cleaning sheet to be measured, a rectangular shape having a size of 100 mm for the CD and 30 mm for the MD that is perpendicular to the CD is cut out, and this cut out rectangular shape is used as a measurement sample. The measurement sample is attached to a chuck of a tensile tester so that the CD is in the pulling direction. The distance between chucks is 50 mm. Pull the measurement sample at 300 mm / min, use the length when the measurement sample is stretched when the load value is 5 N, obtain the sheet elongation at the time of 5 N / 25 mm load of the CD by the following formula, and evaluate it according to the following criteria did.
Sheet elongation (%) = [(Length when stretched−50) / 50] × 100
A: The sheet elongation is less than 10%, and the cleaning sheet does not stretch at all when the surface to be cleaned is wiped or attached to a cleaning tool, and is easy to use.
○: The sheet elongation is 10% or more and less than 20%, and the cleaning sheet hardly stretches when the surface to be cleaned is wiped or attached to a cleaning tool, and there is no practical problem.
Δ: Sheet elongation is 20% or more and less than 40%, and the cleaning sheet may be stretched when cleaning the surface to be cleaned or attached to a cleaning tool. The elongation is 40% or more, and the cleaning sheet is stretched when the surface to be cleaned is wiped or attached to a cleaning tool, which is not suitable for use.

<Evaluation method of fiber dropout degree>
The cleaning sheet was attached to the head part of Quickle Wiper (registered trademark), which is a cleaning tool manufactured by Kao Corporation. In evaluation, the surface (raised surface) which performed the raising process in the manufacturing process of the cleaning sheet was used as a cleaning surface. When there was no raised surface, any one surface of the cleaning sheet was used as the cleaning surface. Using the cleaning sheet attached to the head part, the entire area of the dry tatami mat as the surface to be cleaned is wiped 5 times. Thereafter, it was visually confirmed whether or not the constituent fibers of the cleaning sheet remained on the tatami mat and evaluated as the degree of fiber dropout based on the following criteria.
○: The number of constituent fibers remaining on the tatami is less than 10, and the degree of fiber dropping is low and highly evaluated.
Δ: There are 10 or more constituent fibers remaining on the tatami mat, and the degree of fiber dropping is slightly high, but at a practical level.
X: The cleaning sheet is torn by wiping and is not practical.

<Evaluation method of wiping resistance>
Five sheets of cleaning sheets cut into a circle with a diameter of 25 mm are prepared as samples. About the raising surface of this sample (if there is no raising surface, one surface of the cleaning sheet), the static friction coefficient μ was measured using HEIDON Tribogear Muse TYPE: 94i manufactured by Shinto Kagaku Co., Ltd. The average value of the static friction coefficient μ of the five samples was evaluated as the wiping resistance according to the following criteria.
○: The average value is less than 0.40 μm, the wiping resistance is small, and the wiping comfort is good.
(Triangle | delta): The said average value is 0.40 micrometer or more and less than 0.60 micrometer, The wiping resistance is large, and it is a little inferior to wiping comfort, but a practical level.
X: The said average value is 0.60 micrometer or more, wiping resistance is very large, and it is inferior to wiping comfort, and cannot be used practically.

  As is clear from the results shown in Table 1, each of Examples 1 to 9 includes a portion where the fiber assembly is formed by entanglement of the constituent fibers, and the fiber assembly and the support are integrated. An entangled state is formed, and the protruding length of the fiber end portion from the fiber assembly is 10 mm or more, and one surface of the cleaning sheet (raised surface, cleaning) when the cleaning sheet is viewed from the side The cleaning sheet has a fiber end portion (long fiber end portion) of a constituent fiber having a length of 10 mm or more outside the straight line BL (see FIG. 3) that connects the contours of the surface). It has excellent hair collection on the surface to be cleaned (dried surface to be cleaned), and has other brushing treatments for other cleaning performance (capability to collect hair on the surface to be cleaned, fine dust collection property, large particle dust collection property). It turns out that it is improving compared with the comparative example 1 which has not been given. Further, it can be seen that Examples 1 to 9 have low sheet elongation and are suitable for cleaning. Moreover, it can be seen from a comparison between Example 8 and other examples that even when a rayon-made hole-spun lace nonwoven fabric is used as the support, the sheet elongation is low and the structure is suitable as a cleaning sheet. On the other hand, Comparative Examples 1 and 5 mainly resulted in inferior cleaning performance because the raising process was not performed and the end portion of the long fiber did not exist on the cleaning surface. In Comparative Examples 2 and 3, although the end portion of the long fiber exists on the cleaning surface, the fiber aggregate is mainly formed by fusing or bonding the constituent fibers, resulting in poor cleaning performance. It was. Also, from the comparison between Example 9 and Comparative Example 4, if there is no support for supporting the fiber assembly, the sheet elongation increases and the cleaning sheet becomes easy to stretch, so that it is used as a cleaning sheet. It turns out that it becomes unsuitable.

In addition, when Examples 1, 2 and 3 are compared, Example 1 with the largest number of long fiber ends (the number of long fiber ends per 10 cm ^{2 of the} brushed surface) has the best cleaning performance. It can be seen that the greater the number of copies, the better the cleaning performance. In particular, from comparison between Example 2 and Example 3, it can be seen that when the number of long fiber ends exceeds 10, the ability to collect hair is improved.

  In addition, when Examples 4, 5, 6 and 7 are compared, all have good cleaning performance, but Example 7 mainly has a fiber assembly composed of constituent fibers having a fiber diameter of less than 8 μm. The result is that the wiping resistance is high and the wiping comfort is slightly inferior. In addition, since Example 4 mainly has a fiber assembly in which fibers having a fiber diameter exceeding 45 μm account for 50% by mass or more, the degree of fiber dropping is somewhat The result was high so-called fluff loss during cleaning. From this, regarding the fiber assembly, the proportion of the constituent fibers having a fiber diameter (diameter) of 8 to 45 μm (more preferably 10 to 40 μm) in all constituent fibers is 50% by mass or more. It turns out that it is preferable from a viewpoint of reduction of fluff loss. In addition, although Example 4 resulted in the appearance of fluff missing, and Example 7 resulted in slightly inferior wiping comfort, both Examples 4 and 7 are at a level that can be sufficiently used as a cleaning sheet.

  Moreover, when Example 1 and Example 9 are compared, although the cleaning performance is good in all cases, the example 1 having unevenness on the raised surface despite being manufactured through the same raised treatment is more preferable. Compared with Example 9 which does not have an unevenness | corrugation substantially, the number of long fiber ends was large, and as a result, it became a result with high hair collection property and large granular dust collection property. From this, it is understood that the raised surface is effective for increasing the number of long fiber ends and improving the cleaning performance.

  In addition, regarding the cleaning sheets (Examples 1 to 3, 5, 6 and 8 and Comparative Example 1 samples) having unevenness, in the evaluation of the large granular dust collection ability, The mass ratio was about concave portion: convex portion = 5: 1, and it was confirmed that the granular dust was preferentially collected in the concave portion. It was confirmed that was collected so as to be entangled with the convex portion.

1 Cleaning sheet 1a Brushed surface (one surface of cleaning sheet)
1b Other surface 11 of cleaning sheet Convex part 12 Concave part 2 Fiber aggregate 21 Long fiber end part 3 Support body 30 Hole 31 of support body Grid net (support body)
32 Perforated film (support)
4, 4a, 4b Fiber web 5 Polymer 6 Composite 7 Concave and convex composite 60 Brushed roll

Claims (5)

A fiber assembly and a support that supports the fiber assembly, and the constituent fibers of the fiber assembly are intertwined with each other and are also intertwined with the support. And a sheet for cleaning that forms an integral entangled state with the support,
There is a fiber end portion of the constituent fiber having a length of 10 mm or more, formed by raising the hair, outside the straight line connecting the outline of one surface of the cleaning sheet when the cleaning sheet is viewed from the side. Cleaning sheet. The cleaning sheet according to claim 1, wherein 10 or more fiber ends are present per 10 cm ² of one surface of the cleaning sheet.   The cleaning sheet according to claim 1 or 2, wherein the fiber assembly is formed by hydroentangling a fiber web.   The cleaning sheet according to any one of claims 1 to 3, wherein one surface of the cleaning sheet has unevenness including a convex portion and a concave portion.   The cleaning sheet according to claim 4, wherein the convex portion has more fiber end portions than the concave portion.

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