JP2012255191A - Aluminum alloy - Google Patents

Aluminum alloy Download PDF

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JP2012255191A
JP2012255191A JP2011128722A JP2011128722A JP2012255191A JP 2012255191 A JP2012255191 A JP 2012255191A JP 2011128722 A JP2011128722 A JP 2011128722A JP 2011128722 A JP2011128722 A JP 2011128722A JP 2012255191 A JP2012255191 A JP 2012255191A
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extruded
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aluminum alloy
die
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Masayoshi Doi
正芳 土肥
Katsuzumi Tsuneki
克純 常木
Kazuo Miyahara
和男 宮原
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Sankyo Tateyama Inc
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Sankyo Tateyama Inc
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Abstract

PROBLEM TO BE SOLVED: To provide an aluminum alloy with which an extruded shape having low surface roughness and exhibiting excellent brightness without buffing is obtained.SOLUTION: The aluminum alloy contains 0.30-0.60 wt.% Si, 0.35-0.65 wt.% Mg, and 0.015-0.054 wt.% B.

Description

本発明は、表面粗度が小さく、バフ研磨無しでも光輝性に優れた押出形材が得られるアルミニウム合金に関する。   The present invention relates to an aluminum alloy having a small surface roughness and capable of obtaining an extruded profile excellent in glitter even without buffing.

A6063、A6061等の6000系のアルミニウム合金は、押出形材にして建材や家具、家電製品等に、広く用いられている。しかし従来のアルミ押出形材は、ダイスから押出したときにダイラインと呼ばれる細かいスジが表面に多数形成され、そのため表面が平滑ではなく、光輝性も低いものであった。オーディオパネル等の高い意匠性が求められるものでは、押出後にバフ研磨を行ってダイラインを無くしている。   6000 series aluminum alloys such as A6063 and A6061 are widely used for building materials, furniture, home appliances, etc., as extruded profiles. However, when a conventional aluminum extruded shape is extruded from a die, a large number of fine lines called die lines are formed on the surface, so that the surface is not smooth and has low gloss. In the case where a high design property such as an audio panel is required, the die line is eliminated by buffing after extrusion.

本発明は以上に述べた実情に鑑み、表面粗度が小さく、バフ研磨無しでも光輝性に優れた押出形材が得られるアルミニウム合金の提供を目的とする。   The present invention has been made in view of the above-described circumstances, and an object of the present invention is to provide an aluminum alloy having a small surface roughness and capable of obtaining an extruded profile excellent in glitter even without buffing.

上記の課題を達成するために請求項1記載の発明によるアルミニウム合金は、Siを0.30〜0.60wt%、Mgを0.35〜0.65wt%、Bを0.015〜0.054wt%含有することを特徴とする。   In order to achieve the above object, the aluminum alloy according to the first aspect of the present invention has an Si content of 0.30 to 0.60 wt%, Mg of 0.35 to 0.65 wt%, and B of 0.015 to 0.054 wt%. % Content.

従来のアルミ押出形材の表面にダイラインが形成されるのは、押出中にダイスのベアリングにアルミが厚く不均一にコーティングされ、このアルミコーティングが形材の表面に転写されるためと考えられる。請求項1記載の発明によるアルミニウム合金は、Bを0.015〜0.054wt%添加したことで、Bによって生成する化合物がダイスのベアリングをクリーニング(研磨)する作用があり、これによりベアリング上のアルミコーティングが薄く均一に形成されるため、ダイラインが抑制され、表面粗度が小さく光輝性に優れた押出形材が得られる。Siを0.30〜0.60wt%、Mgを0.35〜0.65wt%含有することで、機械的性質や押出性も概ね良好である。   The reason why the die line is formed on the surface of the conventional aluminum extruded profile is thought to be that aluminum is thickly and unevenly coated on the die bearing during extrusion, and this aluminum coating is transferred to the surface of the profile. In the aluminum alloy according to the first aspect of the present invention, 0.01 to 0.054 wt% of B is added, so that the compound formed by B has an action of cleaning (polishing) the bearing of the die. Since the aluminum coating is thinly and uniformly formed, the die line is suppressed, and an extruded shape having a small surface roughness and excellent glossiness can be obtained. By containing 0.30 to 0.60 wt% Si and 0.35 to 0.65 wt% Mg, mechanical properties and extrudability are generally good.

押出形材の断面形状の一例を示す図である。It is a figure which shows an example of the cross-sectional shape of an extrusion shape member. B含有量と表面粗さとの関係を示すグラフである。It is a graph which shows the relationship between B content and surface roughness. 実施例2と比較例1による押出形材の外観の写真である。2 is a photograph of the appearance of extruded profiles according to Example 2 and Comparative Example 1. (a)はダイスの模式図であり、(b)は実施例2と比較例1を押出したダイスのベアリングの写真である。(A) is a schematic diagram of a die, and (b) is a photograph of a die bearing in which Example 2 and Comparative Example 1 are extruded. 実施例1〜4及び比較例1による押出形材の断面組織観察写真である。It is a cross-sectional structure | tissue observation photograph of the extrusion shape material by Examples 1-4 and Comparative Example 1. FIG. 実施例4による押出形材の断面組織観察写真と、その中の粒子1,2の拡大写真である。It is the cross-sectional structure | tissue observation photograph of the extrusion shape material by Example 4, and the enlarged photograph of the particles 1 and 2 in it.

以下、本発明の実施の形態を説明する。本発明のアルミニウム合金は、Siを0.30〜0.60wt%、Mgを0.35〜0.65wt%、Bを0.015〜0.054wt%含有する。さらに不純物として、Fe、Mn、Ti、Cu等を含有する場合がある。以下、各成分の働きや成分範囲をこのように限定した理由について説明する。   Embodiments of the present invention will be described below. The aluminum alloy of the present invention contains 0.30 to 0.60 wt% Si, 0.35 to 0.65 wt% Mg, and 0.015 to 0.054 wt% B. Furthermore, Fe, Mn, Ti, Cu, etc. may be contained as impurities. Hereinafter, the reason why the function of each component and the component range are limited in this way will be described.

Siは、MgSiを析出させて材料に強度を付与するために添加されるものであり、含有量増とともに強度が向上する。Siが0.60wt%より多いと押出加工性及び表面性状が低下し、Siが0.30wt%より少ないと強度が低下する。よって、概ね良好な押出性と強度と表面性状を確保するため、Siは0.30〜0.60wt%とした。Siの含有量を0.40〜0.48wt%とすると、押出性と機械的性質をバランスよく向上させられるので、より好ましい。 Si is added to precipitate Mg 2 Si and impart strength to the material, and the strength increases as the content increases. When Si is more than 0.60 wt%, the extrusion processability and surface properties are lowered, and when Si is less than 0.30 wt%, the strength is lowered. Therefore, in order to ensure substantially good extrudability, strength, and surface properties, Si is set to 0.30 to 0.60 wt%. When the Si content is 0.40 to 0.48 wt%, the extrudability and the mechanical properties can be improved in a balanced manner, which is more preferable.

Mgは、MgSiを析出させて材料に強度を付与するために添加されるものであり、含有量増とともに強度が向上する。Mgが0.65wt%より多いと押出加工性及び表面性状が低下し、Mgが0.35wt%より少ないと強度が低下する。よって、概ね良好な押出性と強度と表面性状を確保するため、Mgは0.35〜0.65wt%とした。Mgの含有量を0.45〜0.53wt%とすると、押出性と機械的性質をバランスよく向上させられるので、より好ましい。 Mg is added to precipitate Mg 2 Si and impart strength to the material, and the strength increases as the content increases. When Mg is more than 0.65 wt%, the extrudability and surface properties are lowered, and when Mg is less than 0.35 wt%, the strength is lowered. Therefore, in order to ensure generally good extrudability, strength, and surface properties, Mg is set to 0.35 to 0.65 wt%. When the Mg content is 0.45 to 0.53 wt%, the extrudability and the mechanical properties can be improved in a balanced manner, which is more preferable.

Bは、JIS A6063合金に通常は添加されないが、Bを微量添加すると、Bによって生成する化合物によるダイスベアリングのクリーニング作用により、押出形材の表面が平滑化する効果が得られる。Bが0.054wt%より多いと、ビレットの鋳造が困難になり、Bが0.015wt%より少ないと表面平滑化効果が十分に得られない。よってBは、0.015〜0.054wt%とした。   B is not usually added to the JIS A6063 alloy, but if a small amount of B is added, an effect of smoothing the surface of the extruded profile is obtained by the cleaning action of the die bearing by the compound produced by B. When B is more than 0.054 wt%, billet casting becomes difficult, and when B is less than 0.015 wt%, the surface smoothing effect cannot be sufficiently obtained. Therefore, B is set to 0.015 to 0.054 wt%.

Feは、不純物として存在するものであり、多すぎると押出形材の表面性状、強度が低下する。Feの含有量は、おおむね0.07〜0.13wt%が好ましい。   Fe exists as an impurity, and if it is too much, the surface properties and strength of the extruded shape will be reduced. The content of Fe is preferably approximately 0.07 to 0.13 wt%.

Mnは、微量添加により強度、表面性状が向上する。多すぎると効果が無い。Mnの含有量は、おおむね0.02〜0.05wt%が好ましい。   Mn improves strength and surface properties when added in a small amount. If too much, there is no effect. The content of Mn is preferably about 0.02 to 0.05 wt%.

次に、本発明のアルミニウム合金より押出形材を製作する手順を説明する。まず、上述の元素が添加されたアルミニウム合金溶湯を用い、従前の連続鋳造方法によりビレットを製作する。次に、ビレットの組織を均質化するために、そのビレットを一般的な温度、時間にて均質化処理する。その後、ビレットを熱間押出加工して所定の断面形状に押出す。その後、押出した形材に対して人工時効硬化処理の後、必要に応じてアルマイト処理等の表面処理を行う。均質化処理、熱間押出加工、人工時効硬化処理は、A6063合金における通常の条件で行うことができる。   Next, a procedure for producing an extruded shape from the aluminum alloy of the present invention will be described. First, a billet is manufactured by a conventional continuous casting method using a molten aluminum alloy to which the above elements are added. Next, in order to homogenize the billet structure, the billet is homogenized at a general temperature and time. Thereafter, the billet is hot-extruded and extruded into a predetermined cross-sectional shape. Thereafter, the extruded shape material is subjected to a surface treatment such as an alumite treatment after an artificial age hardening treatment, if necessary. The homogenization treatment, hot extrusion processing, and artificial age hardening treatment can be performed under normal conditions in the A6063 alloy.

以下、本発明の実施例を比較例と対比して説明する。表1は、実施例、比較例の合金成分を示している。比較例1はBを含有しないもの、比較例2,3はBの含有量が請求項1の範囲から外れるもの、比較例4はSi,Mgの含有量が請求項1の範囲から外れるものである。表2は、実施例、比較例の合金を押出したときの押出状況と、押出後のダイス観察結果を示している。図1は、押出した形材の断面形状を示しており、オーディオパネルに用いられるものである。   Examples of the present invention will be described below in comparison with comparative examples. Table 1 shows alloy components of Examples and Comparative Examples. Comparative Example 1 does not contain B, Comparative Examples 2 and 3 have a B content outside the scope of Claim 1, and Comparative Example 4 has a Si and Mg content outside the scope of Claim 1. is there. Table 2 shows the extrusion situation when extruding the alloys of Examples and Comparative Examples, and the results of die observation after extrusion. FIG. 1 shows a cross-sectional shape of an extruded profile, which is used for an audio panel.

表2に示すとおり、実施例1〜5、比較例1〜3については押出状況は良好であり、押出後のダイスにも特に問題は無い。実施例6は、Si,Mgの含有量が多いため、実施例1〜5と比較すると押出性は若干悪くなるが、概ね良好である。比較例4は、実施例6よりもさらにSi,Mgの含有量が多いため、さらに押出性が悪くなる。   As shown in Table 2, the extruding situation is good for Examples 1 to 5 and Comparative Examples 1 to 3, and there is no particular problem with the dies after extrusion. In Example 6, since the contents of Si and Mg are large, the extrudability is slightly worse as compared with Examples 1 to 5, but is generally good. Since Comparative Example 4 has a higher Si and Mg content than Example 6, the extrudability is further deteriorated.

表3は、実施例と比較例の押出形材をT5熱処理したものの引張強さ、耐力、伸びを示している。   Table 3 shows the tensile strength, proof stress, and elongation of the extruded shapes of Examples and Comparative Examples that were T5 heat treated.

表3に示すように、Bを0.02〜0.05wt%含有する実施例1〜4と、Bを含有しない比較例1とを比較すると、引張強さ、耐力、伸びともにさほど違いはないことが確認された。実施例1〜6は、いずれもA6063T5の規格を十分に満足する高い強度を有する。特に実施例6は、Si,Mgの含有量が多いため、実施例1〜5よりも引張強さと耐力が高い。   As shown in Table 3, when Examples 1-4 containing 0.02 to 0.05 wt% of B and Comparative Example 1 containing no B are compared, there is not much difference in tensile strength, yield strength, and elongation. It was confirmed. Each of Examples 1 to 6 has high strength that sufficiently satisfies the standard of A6063T5. In particular, Example 6 has higher tensile strength and yield strength than Examples 1 to 5 because of the high Si and Mg contents.

表4は、実施例と比較例の押出形材の表面粗さRa,Rzと生地光沢度を示している。また、B含有量と表面粗さRaとの関係を図2に示す。図3は、実施例2と比較例1の合金より作成した押出形材の外観の写真である。   Table 4 shows the surface roughness Ra, Rz and the cloth glossiness of the extruded profiles of Examples and Comparative Examples. Moreover, the relationship between B content and surface roughness Ra is shown in FIG. FIG. 3 is a photograph of the appearance of an extruded profile made from the alloys of Example 2 and Comparative Example 1.

表4と図2に示すように、Bを含有しない比較例1では表面粗さRaが約0.3μmであるのに対して、Bを0.02〜0.05含有する実施例1〜6では、Raが約0.1μm以下と大幅に小さい。生地光沢度も、実施例1〜6は、Bを含有しない比較例1と比べて大幅に向上する。実施例1〜6の内では、B含有量の多少によって表面粗さ、光沢度ともに大きな違いはないが、Si,Mgの含有量の多い実施例6は、実施例1〜5と比較して若干表面粗さが大きい。図3に示すように、実施例1〜6の押出形材の表面は、ダイラインが目立たず、バフ研磨をしたような鏡面状になる。B含有量が0.015wt%より少ない比較例1と比較例2は、Bを含有しない比較例1よりは表面粗さが小さくなるものの、Raは0.1μmよりも大きいレベルで、ダイラインも目立つ状態となる。
以上の結果より明らかなように、Bを0.015〜0.054wt%添加することで、押出後にバフ研磨をしなくても、ダイラインが目立たない平滑な表面の押出形材を得ることができる。
As shown in Table 4 and FIG. 2, in Comparative Example 1 that does not contain B, the surface roughness Ra is about 0.3 μm, whereas Examples 1 to 6 that contain 0.02 to 0.05 B. Then, Ra is as small as about 0.1 μm or less. The fabric glossiness is also significantly improved in Examples 1 to 6 as compared with Comparative Example 1 containing no B. Among Examples 1-6, although there is no big difference in surface roughness and glossiness by some B content, Example 6 with much content of Si and Mg is compared with Examples 1-5. Slightly large surface roughness. As shown in FIG. 3, the surfaces of the extruded profiles of Examples 1 to 6 have a mirror-like shape in which the die line is not noticeable and buffed. Although Comparative Example 1 and Comparative Example 2 having a B content of less than 0.015 wt% have a smaller surface roughness than Comparative Example 1 that does not contain B, Ra is higher than 0.1 μm and the die line is also conspicuous. It becomes a state.
As is clear from the above results, by adding 0.015 to 0.054 wt% of B, it is possible to obtain an extruded shape having a smooth surface where the die line is not noticeable without buffing after extrusion. .

実施例2と比較例1の押出形材にアルマイト処理(シルバー、ダークブロンズ)を行い、表面外観を観察した。その結果を表5に示す。   The extruded shapes of Example 2 and Comparative Example 1 were alumite-treated (silver, dark bronze), and the surface appearance was observed. The results are shown in Table 5.

表5に示すとおり、実施例2、比較例1とも、アルマイトによる表面欠陥の発生は無く、Bを添加した本発明の実施例においても表面処理性が良好であることを確認した。   As shown in Table 5, it was confirmed that both Example 2 and Comparative Example 1 had no surface defects due to alumite, and the surface treatment property was good even in the examples of the present invention to which B was added.

Bを微量添加することにより押出形材の表面が平滑になる原因を調べるため、図4(a)に示すように、Bを0.03wt%含有する実施例2を押出したダイスと、Bを含有しない比較例1を押出したダイスを上下に分割し、そのベアリングを観察した。図4(b)はそのベアリングの拡大写真である。図4(b)に示すように、比較例1のもの(右側)は、ベアリングにアルミコーティングが厚く不均一に形成されているのに対して、実施例2のもの(左側)は、アルミコーティングが薄く均一に形成されている。アルミコーティングの表面粗さを測定したところ、実施例2のものはRa=0.05μm、比較例1のものではRa=0.24μmであった。押出形材の表面は、ダイスのベアリングのアルミコーティングが転写されて形成されるため、このようにアルミコーティングが薄く均一になったことで、押出形材の表面が平滑になるものと考えられる。   In order to investigate the cause of smoothing the surface of the extruded profile by adding a small amount of B, as shown in FIG. 4 (a), a die obtained by extruding Example 2 containing 0.03% by weight of B, and B A die obtained by extruding Comparative Example 1 not containing was divided into upper and lower parts, and the bearings were observed. FIG. 4B is an enlarged photograph of the bearing. As shown in FIG. 4 (b), the comparative example 1 (right side) has a thick and uneven aluminum coating on the bearing, whereas the example 2 (left side) has an aluminum coating. Is thin and uniform. When the surface roughness of the aluminum coating was measured, Ra of the example 2 was 0.05 μm, and Ra of the comparative example 1 was 0.24 μm. Since the surface of the extruded profile is formed by transferring the aluminum coating of the die bearing, it is considered that the surface of the extruded profile becomes smooth because the aluminum coating is thin and uniform.

図5は、実施例1〜4と比較例1による押出形材の断面組織の写真である。同図に示すように、Bの添加量が多くなるにつれて、比較的大きな黒い粒子が目立って増えていることが分かる。図6は、その粒子を拡大した写真である。これらの粒子は、添加されたBによって生成された化合物であり、これらの粒子がダイスのベアリングをクリーニング(研磨)することでベアリングのアルミコーティングが薄く均一になり、それに伴って押出形材の表面が平滑になるものと考えられる。   FIG. 5 is a photograph of the cross-sectional structure of extruded profiles according to Examples 1 to 4 and Comparative Example 1. As shown in the figure, it can be seen that relatively large black particles are conspicuously increasing as the amount of addition of B increases. FIG. 6 is an enlarged photograph of the particles. These particles are the compounds produced by the added B, and these particles clean (polish) the die bearings to make the bearing's aluminum coating thin and uniform, along with the surface of the extruded profile. Is thought to be smooth.

以上に述べたように、Bを0.015〜0.054wt%添加した本発明のアルミニウム合金は、Bによって生成する化合物がダイスのベアリングをクリーニング(研磨)する作用があり、これによりベアリング上のアルミコーティングが薄く均一に形成されるため、ダイラインが抑制され、バフ研磨をしなくても、表面粗度が小さく光輝性に優れた押出形材が得られる。Siを0.30〜0.60wt%、Mgを0.35〜0.65wt%含有することで、機械的性質や押出性も概ね良好である。特に、Siを0.40〜0.48wt%、Mgを0.45〜0.53wt%含有するものは、押出性と機械的性質をバランスよく向上させられるので、生産性、汎用性に優れ、表面性状も一層優れたものとなる。   As described above, the aluminum alloy of the present invention to which B is added in an amount of 0.015 to 0.054 wt% has an action of cleaning (polishing) the die bearing by the compound produced by B, thereby Since the aluminum coating is thinly and uniformly formed, the die line is suppressed, and an extruded profile having a low surface roughness and excellent glossiness can be obtained without buffing. By containing 0.30 to 0.60 wt% Si and 0.35 to 0.65 wt% Mg, mechanical properties and extrudability are generally good. In particular, those containing 0.40 to 0.48 wt% Si and 0.45 to 0.53 wt% Mg can be improved in a good balance between extrudability and mechanical properties. The surface properties are further improved.

本発明は以上に述べた実施形態に限定されない。合金成分は、特許請求の範囲に記載の範囲で適宜変更することができる。ビレットの均質化処理の条件、押出条件、押出形材の断面形状、押出後の時効処理の条件は任意である。本発明のアルミニウム合金の用途は任意であり、例えばサッシや手すり等の建材、家具、電気製品、自動車等の部品等に用いることができる。   The present invention is not limited to the embodiments described above. The alloy component can be changed as appropriate within the scope of the claims. The conditions for the homogenization treatment of the billet, the extrusion conditions, the cross-sectional shape of the extruded profile, and the conditions for the aging treatment after extrusion are arbitrary. The use of the aluminum alloy of the present invention is arbitrary, and for example, it can be used for building materials such as sashes and handrails, furniture, electrical products, parts of automobiles, and the like.

Claims (1)

Siを0.30〜0.60wt%、Mgを0.35〜0.65wt%、Bを0.015〜0.054wt%含有することを特徴とするアルミニウム合金。   An aluminum alloy containing 0.30 to 0.60 wt% of Si, 0.35 to 0.65 wt% of Mg, and 0.015 to 0.054 wt% of B.
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WO2020054847A1 (en) * 2018-09-14 2020-03-19 株式会社Lixil Aluminum alloy extruded material, fitting, and method for producing aluminum alloy extruded material

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JPS5263110A (en) * 1975-11-19 1977-05-25 Hokusei Aluminium Co Ltd Aluminium alloy for extrusion
JPS55131152A (en) * 1979-03-30 1980-10-11 Sumitomo Light Metal Ind Ltd Manufacture of a -mg-si type alloy with high extrudability and hardenability, and extruded material thereof
JPH11106856A (en) * 1997-10-03 1999-04-20 Kobe Steel Ltd Aluminum-magnesium-silicon series aluminum alloy sheet for forming

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JPS5263110A (en) * 1975-11-19 1977-05-25 Hokusei Aluminium Co Ltd Aluminium alloy for extrusion
JPS55131152A (en) * 1979-03-30 1980-10-11 Sumitomo Light Metal Ind Ltd Manufacture of a -mg-si type alloy with high extrudability and hardenability, and extruded material thereof
JPS6158546B2 (en) * 1979-03-30 1986-12-12 Sumitomo Light Metal Ind
JPH11106856A (en) * 1997-10-03 1999-04-20 Kobe Steel Ltd Aluminum-magnesium-silicon series aluminum alloy sheet for forming

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020054847A1 (en) * 2018-09-14 2020-03-19 株式会社Lixil Aluminum alloy extruded material, fitting, and method for producing aluminum alloy extruded material
JP2020045506A (en) * 2018-09-14 2020-03-26 株式会社Lixil Aluminum shape material, fitting and manufacturing method of aluminum shape material
JP7248399B2 (en) 2018-09-14 2023-03-29 株式会社Lixil Aluminum profile, fittings and method for manufacturing aluminum profile

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