JP2012228350A - Cooker for removing nitrate nitrogen - Google Patents

Cooker for removing nitrate nitrogen Download PDF

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JP2012228350A
JP2012228350A JP2011098068A JP2011098068A JP2012228350A JP 2012228350 A JP2012228350 A JP 2012228350A JP 2011098068 A JP2011098068 A JP 2011098068A JP 2011098068 A JP2011098068 A JP 2011098068A JP 2012228350 A JP2012228350 A JP 2012228350A
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nitrate nitrogen
vegetables
pot
mineral
rice
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JP5957165B2 (en
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Masao Shimoda
政雄 霜田
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GLS KK
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Abstract

PROBLEM TO BE SOLVED: To remove nitrate nitrogen by not soil improvement of a field but by a cooker when cooking vegetables and rice containing nitrate nitrogen.SOLUTION: This cooker includes an earthen pot whose surface is coated with glaze including several % of mineral that contains silica of 70% or more, and a heating means for heating the earthen pot. The earthen pot is used for cooking rice or vegetables including nitrate nitrogen. Alternatively, this cooker includes a metal pot whose surface is coated with fluororesin including several % of mineral that contains silica of 70% or more, and a heating means for heating the metal pot. The metal pot is used for cooking rice and vegetables including nitrate nitrogen.

Description

本発明は、野菜や米等に含まれる硝酸態窒素を分解除去する調理器及び類似器具に関する。   The present invention relates to a cooker and similar appliances that decompose and remove nitrate nitrogen contained in vegetables, rice, and the like.

現在、田畑等の耕作地で米や野菜を栽培する場合、肥料に有機物が採用される場合が多く、この有機物から米や野菜は硝酸態窒素を吸収して成長するが、余剰の硝酸態窒素が残った場合、この野菜等を食べることによって、体内に硝酸態窒素が取り込まれる。この硝酸態窒素は体内で還元され、亜硝酸態窒素として体内たんぱく質と反応して発がん性のニトロソアミンとなり、細胞を傷つける。   Currently, when cultivating rice and vegetables on cultivated land such as fields, organic matter is often used for fertilizer, and rice and vegetables grow by absorbing nitrate nitrogen from this organic matter, but excess nitrate nitrogen If left over, nitrate nitrogen is taken into the body by eating these vegetables. This nitrate nitrogen is reduced in the body, reacts with protein in the body as nitrite nitrogen, and becomes carcinogenic nitrosamine, which damages cells.

現状の市販野菜、特に葉物野菜は数千ppmの残留硝酸態窒素を含む常態である。また、水中では、主としてたんぱく質などの分解によって生じたアンモニア性窒素が、更に生物化学的に酸化される。   Current commercial vegetables, especially leafy vegetables, are normal with thousands of ppm residual nitrate nitrogen. In water, ammoniacal nitrogen produced mainly by the decomposition of proteins and the like is further biochemically oxidized.

特許文献1は、畑などの土壌中に含まれるアンモニア態窒素や硝酸態窒素が農作物に吸収されることを防止するため、カルシウムとマグネシウムとの水酸化物に、鉄、マンガン、銅、亜鉛、ホウ素、及びモリブデンを原子状態で包含させ、複合水酸化物の粒体に形成した植物育成用ミネラル材を使用して土壌改良を行い、農作物に硝酸態窒素等が吸収されることを防止する発明である。   In Patent Document 1, in order to prevent ammonia nitrogen and nitrate nitrogen contained in soil such as fields from being absorbed by crops, calcium, magnesium hydroxide, iron, manganese, copper, zinc, An invention in which boron and molybdenum are included in an atomic state and the soil is improved by using a plant-growing mineral material formed into a composite hydroxide granule to prevent absorption of nitrate nitrogen and the like by agricultural crops. It is.

特開2006−306683号公報JP 2006-306683 A

しかしながら、上記特許文献1に係る発明は、土壌改良を行い硝酸態窒素等を除くものであるが、野菜や米を生産するための田畑の面積は膨大であり、全ての田畑の土壌改良を行うことはできない。また、その費用も膨大となる。   However, although the invention according to Patent Document 1 improves soil and removes nitrate nitrogen and the like, the area of the field for producing vegetables and rice is enormous, and soil improvement of all fields is performed. It is not possible. In addition, the cost is enormous.

そこで、本発明は田畑の土壌改良を行うのではなく、硝酸態窒素が含まれる野菜や米を調理する際、調理器によって硝酸態窒素を除去することを目的とする。   Therefore, the present invention aims at removing nitrate nitrogen with a cooking device when cooking vegetables and rice containing nitrate nitrogen, rather than improving soil in a field.

上記課題は第1の発明によれば、表面に珪素を少なくとも70%以上含有する鉱物を数%含む釉薬が塗布された土鍋と、該土鍋を加熱する加熱手段とを備える調理器具を提供することによって達成できる。   According to the first aspect of the present invention, there is provided a cooking utensil comprising a clay pot coated with a glaze containing several percent of a mineral containing at least 70% silicon on the surface, and heating means for heating the clay pot. Can be achieved.

また、上記課題は第2の発明によれば、表面に珪素を少なくとも70%含有する鉱物を数%含むフッ素樹脂が塗布された金属鍋と、該金属鍋を加熱する加熱手段とを備える調理器具を提供することによって達成できる。   According to a second aspect of the present invention, there is provided a cooking utensil comprising a metal pan having a surface coated with a fluororesin containing several percent of a mineral containing at least 70% silicon, and heating means for heating the metal pan. Can be achieved by providing.

また、上記課題は第3の発明によれば、前記土鍋、又は金属鍋は、硝酸態窒素を含む米又は野菜の煮炊きに使用する調理器具であることを特徴とする。   According to a third aspect of the present invention, the earthen pan or the metal pan is a cooking utensil used for cooking rice or vegetables containing nitrate nitrogen.

さらに、上記課題は第4の発明によれば、前記鉱物は、窒素(N)、リン(P)、カリウム(K)、水素(H)、炭素(C)、カルシウム(Ca)、マグネシウム(Mg)、イオウ(S)を含み、更に少量の銅(Cu)、亜鉛(Zn)、マンガン(Mn)、鉄(Fe)、及びホウ素(B)を含むことを特徴とする。   Further, according to a fourth aspect of the present invention, the mineral comprises nitrogen (N), phosphorus (P), potassium (K), hydrogen (H), carbon (C), calcium (Ca), magnesium (Mg ), Sulfur (S), and a small amount of copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), and boron (B).

本発明によれば、硝酸態窒素や亜硝酸態窒素を含む野菜やお米を煮炊きすることによって、容易に野菜やお米に含まれる亜硝酸態窒素等を分解、除去することができる調理器具を提供するものである。   ADVANTAGE OF THE INVENTION According to this invention, the cooking utensil which can decompose | disassemble and remove nitrite nitrogen etc. which are contained in vegetables and rice easily by boiling and cooking vegetables and rice containing nitrate nitrogen and nitrite nitrogen Is to provide.

本実施形態で使用する電磁誘導加熱調理器の構成を示す断面図である。It is sectional drawing which shows the structure of the electromagnetic induction heating cooking appliance used by this embodiment. 土鍋の構造を説明する図である。It is a figure explaining the structure of a clay pot. 土鍋の断面構成を示す図である。It is a figure which shows the cross-sectional structure of a clay pot. 本実施形態の硝酸態窒素の除去効果を示す測定結果の図である。It is a figure of the measurement result which shows the removal effect of nitrate nitrogen of this embodiment.

以下、本発明の実施の形態を図面を参照しながら説明する。
図1は、本実施形態で使用する電磁誘導加熱調理器の構成を示す断面図である。尚、本例は、電磁誘導加熱調理器として電磁誘導加熱炊飯器の例を使用して説明する。
電磁誘導加熱炊飯器1は、本体2と蓋部3で構成され、本体2内には土鍋4が設けられている。また、この土鍋4の下面には電磁誘導加熱用の加熱コイル5が配設されている。
Embodiments of the present invention will be described below with reference to the drawings.
FIG. 1 is a cross-sectional view showing a configuration of an electromagnetic induction heating cooker used in the present embodiment. In addition, this example demonstrates using the example of an electromagnetic induction heating rice cooker as an electromagnetic induction heating cooker.
The electromagnetic induction heating rice cooker 1 is composed of a main body 2 and a lid 3, and a clay pot 4 is provided in the main body 2. A heating coil 5 for electromagnetic induction heating is disposed on the lower surface of the earthenware pot 4.

加熱コイル5は、スパイラル状に旋回され直列に高周波電源に接続されており、加熱コイル5に高周波電流が供給される構成であり、不図示の制御部により駆動制御される。また、加熱コイル5に近接する土鍋4の位置には磁性体6が配設されている。この磁性体6としては、磁性を有する鉄系の材料、例えばステンレス(SUS430)等の材料が使用される。加熱コイル5に電流を流すと磁性体6に渦電流が発生し、発熱して土鍋4を加熱する。   The heating coil 5 is swirled in a spiral shape and connected in series to a high-frequency power source. A high-frequency current is supplied to the heating coil 5 and is driven and controlled by a control unit (not shown). In addition, a magnetic body 6 is disposed at the position of the earthenware pot 4 adjacent to the heating coil 5. As the magnetic body 6, an iron-based material having magnetism, for example, a material such as stainless steel (SUS430) is used. When a current is passed through the heating coil 5, an eddy current is generated in the magnetic body 6, generating heat and heating the earthenware pot 4.

また、図1において、磁性体6を帯状に示しているが、図1の紙面に対して垂直方向にも伸びた構成であり、磁性体6は土鍋4の底面に広く配設され、土鍋4を加熱する。   In FIG. 1, the magnetic body 6 is shown in a band shape, but the magnetic body 6 extends in a direction perpendicular to the paper surface of FIG. 1, and the magnetic body 6 is widely disposed on the bottom surface of the earthenware pot 4. Heat.

一方、図2は上記構成の電磁誘導加熱炊飯器1に使用される土鍋4の構成を示す図である。土鍋4は粘土材を成形した本体7で構成され、底壁7aと底壁7aの周囲に形成された周壁7bで構成されている。具体的には、粘土を本体7の型に成型し、底壁7aの外面(下面)に矩形の凹部8a、8b、8cを形成する。また、この凹部8a、8b、8cに嵌合する形状であって、凹部8a、8b、8cの深さと略同じ長さの厚みを備えた磁性体6を底壁7aの凹部8a、8b、8cに嵌合固着する。   On the other hand, FIG. 2 is a figure which shows the structure of the earthenware pot 4 used for the electromagnetic induction heating rice cooker 1 of the said structure. The earthenware pot 4 is comprised with the main body 7 which shape | molded the clay material, and is comprised by the surrounding wall 7b formed in the circumference | surroundings of the bottom wall 7a and the bottom wall 7a. Specifically, clay is molded into the mold of the main body 7, and rectangular recesses 8a, 8b, and 8c are formed on the outer surface (lower surface) of the bottom wall 7a. Further, the magnetic body 6 having a shape that fits into the recesses 8a, 8b, and 8c and has a thickness substantially the same as the depth of the recesses 8a, 8b, and 8c is used as the recesses 8a, 8b, and 8c of the bottom wall 7a. Fits and adheres to.

このようにして成型した粘土を焼いて素焼きを行う。この素焼きを行った土鍋4の本体7の内面9をサンドブラト等で粗面化し、内面9に釉薬10を塗布する。ここで、この釉薬10には、珪素(Si)を、例えば90%以上含有する鉱物11が混入しており、この鉱物11の粉末が釉薬10に含有されている。また、釉薬10に対する鉱物11の含有率は、例えば5%である。   The clay thus molded is baked to perform unglazing. The inner surface 9 of the main body 7 of the clay pot 4 subjected to the unglazed baking is roughened with sandburt or the like, and the glaze 10 is applied to the inner surface 9. Here, the glaze 10 is mixed with a mineral 11 containing, for example, 90% or more of silicon (Si), and the powder of the mineral 11 is contained in the glaze 10. Moreover, the content rate of the mineral 11 with respect to the glaze 10 is 5%, for example.

したがって、素焼きを行った土鍋4(本体7)の内面には上記Siを含有する釉薬10が塗布され、この状態で土鍋4を再度焼成する。
図3は、図2に示す土鍋4(7)のA−A’断面図である。同図に示すように、土鍋4(本体7)の表面12はサンドブラストで粗化され、その上に珪素(Si)を含有する釉薬10が塗布されている。
Accordingly, the glaze 10 containing Si is applied to the inner surface of the clay pot 4 (main body 7) that has been baked, and the clay pot 4 is fired again in this state.
FIG. 3 is a cross-sectional view taken along the line AA ′ of the clay pot 4 (7) shown in FIG. As shown in the figure, the surface 12 of the earthenware pot 4 (main body 7) is roughened by sandblasting, and a glaze 10 containing silicon (Si) is applied thereon.

このように処理することにより、その上面に珪素(Si)を含有する土鍋4を使用した電磁誘導加熱炊飯器1を提供することができる。したがって、例えばこの電磁誘導加熱炊飯器1を使用してお米を炊くことによって、例えば硝酸態窒素を含んでいるお米であっても、その量を元の1/3〜1/5程度まで減少させることができる。   By processing in this way, the electromagnetic induction heating rice cooker 1 which uses the earthenware pot 4 which contains silicon (Si) on the upper surface can be provided. Therefore, for example, by using this electromagnetic induction heating rice cooker 1 to cook rice, even if the rice contains nitrate nitrogen, the amount is reduced to about 1/3 to 1/5 of the original amount. Can be reduced.

また、上記実施形態の説明では、電磁誘導加熱炊飯器1について説明したが、電磁誘導加熱炊飯器1に限らず電磁誘導加熱方式を採用する調理器全てに適応できるものである。したがって、本例の土鍋4を使用した調理器を使用して野菜を調理する場合でも、上記と同様、硝酸態窒素を含んでいる野菜であっても、その量を元の1/3〜1/5程度まで減少させることができる。   Moreover, although the electromagnetic induction heating rice cooker 1 was demonstrated in description of the said embodiment, it can apply not only to the electromagnetic induction heating rice cooker 1 but all the cookers which employ | adopt an electromagnetic induction heating system. Therefore, even when cooking vegetables using the cooker using the earthenware pot 4 of this example, even if the vegetables contain nitrate nitrogen, the amount is reduced to 1/3 to 1 of the original. Can be reduced to about / 5.

したがって、本例によれば、例え硝酸態窒素を含む野菜や米であっても、上記土鍋4を使用する調理器を使用して野菜や米を煮炊きするだけで容易に安全な食品に変えることができる。   Therefore, according to this example, even vegetables and rice containing nitrate nitrogen can be easily changed to safe foods simply by boiling the vegetables and rice using the cooker using the clay pot 4. Can do.

また、野菜や米を生産するための土壌改良を行う場合に比べ、極めて容易に硝酸態窒素や亜硝酸態窒素の問題を解決することができ、費用の面でも格段有利である。   In addition, compared with the case of soil improvement for producing vegetables and rice, the problems of nitrate nitrogen and nitrite nitrogen can be solved very easily, which is advantageous in terms of cost.

また、土鍋4に限らず、例えば金属鍋であっても、同様に硝酸態窒素を除く調理器具を実現することができる。この場合、例えばアルミの基材にフッ素コーティングを行う際、珪素(Si)を、例えば70%以上含有する鉱物を、フッ素樹脂に混入させてコーティングを行うことによって、金属鍋においても同様の効果を得ることができる。   Moreover, it is not restricted to the earthenware pot 4, For example, even if it is a metal pot, the cooking appliance except nitrate nitrogen is realizable similarly. In this case, for example, when performing fluorine coating on an aluminum base material, the same effect can be obtained in a metal pan by coating silicon (Si), for example, a mineral containing 70% or more in a fluororesin. Can be obtained.

また、上記実施形態の説明では、土鍋4(本体7)の内面にSiを含有する鉱物11を含む釉薬10を塗布したが、土鍋4の本体7を粘土で作成する際、Siを含有する鉱物11を練り込み、素焼きする構成としてもよい。このように構成した土鍋4を使用し、野菜や米を煮炊きするだけで容易に安全な食品に変えることができる。   In the description of the above embodiment, the glaze 10 containing the Si-containing mineral 11 is applied to the inner surface of the earthenware pot 4 (main body 7). However, when the main body 7 of the earthenware pot 4 is made of clay, the mineral containing Si is used. 11 may be kneaded and unbaked. Using the earthenware pot 4 configured in this manner, it is possible to easily change to a safe food simply by boiling vegetables and rice.

また、土鍋4の本体7を粘土で作成する際、更に多くの凹部を形成し、当該凹部に上記鉱物11を嵌合固着し、土鍋4を作成してもよい。このように構成した土鍋4を使用しても、野菜や米を煮炊きするだけで容易に安全な食品に変えることができる。   Moreover, when making the main body 7 of the earthenware pot 4 with clay, many more recessed parts may be formed, the said mineral 11 may be fitted and fixed to the said recessed part, and the earthenware pot 4 may be produced. Even when the earthenware pot 4 configured in this way is used, it can be easily changed to a safe food simply by boiling vegetables and rice.

また、フッ素樹脂に代えて、シリカを使用する場合には、上記鉱物を1〜10%程度含むようにすればよく、セラミックの場合には、鉱物を1%程度含むようにすればよい。   In addition, when silica is used instead of the fluororesin, the mineral may be included in an amount of about 1 to 10%, and in the case of ceramic, the mineral may be included in an amount of about 1%.

さらに、上記鉱物11は、前述のように珪素(Si)を70%以上含有するものであるが、他の成分としては、例えば窒素(N)、リン(P)、カリウム(K)、水素(H)、炭素(C)、カルシウム(Ca)、マグネシウム(Mg)、イオウ(S)を含み、更に少量の銅(Cu)、亜鉛(Zn)、マンガン(Mn)、鉄(Fe)、及びホウ素(B)等、十数種類の元素を含む構成である。   Further, the mineral 11 contains 70% or more of silicon (Si) as described above. As other components, for example, nitrogen (N), phosphorus (P), potassium (K), hydrogen ( H), carbon (C), calcium (Ca), magnesium (Mg), sulfur (S) and further small amounts of copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), and boron (B) and the like, including a dozen elements.

最後に、本例の調理器を使用し、例えば小松菜を試験材料とした場合の本例の硝酸態窒素の除去試験の結果を図4に示す。同図に示すように、試験開始時6,700ppmであった硝酸態窒素は、30分後には4,500ppmに減少し、1時間後に3,500ppmには減少し、更に2時間後には2,900ppmに減少した。したがって、本例の土鍋4を使用した調理器の硝酸態窒素の除去効果が顕著に測定できた。
尚、小松菜に含まれる硝酸態窒素の測定は、それぞれの時間において、一定量の小松菜を調理器から取り出し、磨り潰して測定器で測定したものである。
Finally, FIG. 4 shows the result of the nitrate nitrogen removal test of this example when using the cooker of this example and using, for example, komatsuna as the test material. As shown in the figure, nitrate nitrogen, which was 6,700 ppm at the start of the test, decreased to 4,500 ppm after 30 minutes, decreased to 3,500 ppm after 1 hour, and further 2 hours after 2 hours. Reduced to 900 ppm. Therefore, the nitrate nitrogen removal effect of the cooker using the earthenware pot 4 of this example was remarkably measured.
In addition, the measurement of nitrate nitrogen contained in Komatsuna was measured by taking out a certain amount of Komatsuna from the cooker, grinding and measuring with a measuring instrument at each time.

1・・・電磁誘導加熱炊飯器
2・・・本体
3・・・蓋部
4・・・土鍋
5・・・加熱コイル
6・・・磁性体
7・・・本体
7a・・底壁
7b・・周壁
8a、8b、8c・・凹部
9・・・内面
10・・釉薬
11・・鉱物
12・・表面
DESCRIPTION OF SYMBOLS 1 ... Electromagnetic induction heating rice cooker 2 ... Main body 3 ... Cover part 4 ... Earthenware pot 5 ... Heating coil 6 ... Magnetic body 7 ... Main body 7a ... Bottom wall 7b ... Peripheral walls 8a, 8b, 8c ··· concave portion 9 · · · inner surface 10 · · glaze 11 · · mineral 12 · · surface

Claims (5)

表面に珪素を少なくとも70%以上含有する鉱物を数%含む釉薬が塗布された土鍋と、
該土鍋を加熱する加熱手段と、
を備える調理器具
A clay pot coated with a glaze containing several percent of a mineral containing at least 70% silicon on the surface;
Heating means for heating the clay pot;
Cooking utensils with
表面に珪素を少なくとも70%以上含有する鉱物を数%含むフッ素樹脂が塗布された金属鍋と、
該金属鍋を加熱する加熱手段と、
を備えることを特徴とする調理器具。
A metal pan coated with a fluororesin containing several percent of a mineral containing at least 70% silicon on the surface;
Heating means for heating the metal pan;
A cooking utensil comprising:
前記土鍋は、硝酸態窒素を含む米又は野菜の煮炊きに使用することを特徴とする請求項1に記載の調理器具。   The cooking utensil according to claim 1, wherein the clay pot is used for cooking rice or vegetables containing nitrate nitrogen. 前記金属鍋は、硝酸態窒素を含む米又は野菜の煮炊きに使用することを特徴とする請求項2に記載の調理器具。   The cooker according to claim 2, wherein the metal pan is used for cooking rice or vegetables containing nitrate nitrogen. 前記鉱物は、窒素、リン、カリウム、水素、炭素、カルシウム、マグネシウム、イオウを含み、更に少量の銅、亜鉛、マンガン、鉄、及びホウ素を含むことを特徴とする請求項1、2、3、又は4に記載した調理器具。   The said mineral contains nitrogen, phosphorus, potassium, hydrogen, carbon, calcium, magnesium, sulfur, and further contains a small amount of copper, zinc, manganese, iron, and boron. Or the cooking utensil described in 4.
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Publication number Priority date Publication date Assignee Title
CN104887087A (en) * 2015-05-12 2015-09-09 杨文举 Inner container of electromagnetic heating kettle
CN108523624A (en) * 2017-03-01 2018-09-14 佛山市顺德区美的电热电器制造有限公司 Pot and preparation method thereof and electric heating pot in a kind of energy-saving heat preserving

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JP3031741U (en) * 1996-05-28 1996-12-03 株式会社クレイツ Cookware
JPH1085766A (en) * 1996-09-16 1998-04-07 Mitsuo Wada Water quality improving material and method for improving water quality
JP3164085U (en) * 2010-09-01 2010-11-11 千陶 千賀陶器株式会社 Tableware with microwave oven

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JP3031741U (en) * 1996-05-28 1996-12-03 株式会社クレイツ Cookware
JPH1085766A (en) * 1996-09-16 1998-04-07 Mitsuo Wada Water quality improving material and method for improving water quality
JP3164085U (en) * 2010-09-01 2010-11-11 千陶 千賀陶器株式会社 Tableware with microwave oven

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104887087A (en) * 2015-05-12 2015-09-09 杨文举 Inner container of electromagnetic heating kettle
CN108523624A (en) * 2017-03-01 2018-09-14 佛山市顺德区美的电热电器制造有限公司 Pot and preparation method thereof and electric heating pot in a kind of energy-saving heat preserving
CN108523624B (en) * 2017-03-01 2024-03-26 佛山市顺德区美的电热电器制造有限公司 Energy-saving heat-preserving inner pot, preparation method thereof and electric heating pot

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