JP2012211248A - Antiadhesive agent for asphalt mixture - Google Patents
Antiadhesive agent for asphalt mixture Download PDFInfo
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- JP2012211248A JP2012211248A JP2011077229A JP2011077229A JP2012211248A JP 2012211248 A JP2012211248 A JP 2012211248A JP 2011077229 A JP2011077229 A JP 2011077229A JP 2011077229 A JP2011077229 A JP 2011077229A JP 2012211248 A JP2012211248 A JP 2012211248A
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- 239000010426 asphalt Substances 0.000 title claims abstract description 60
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 20
- 230000000181 anti-adherent effect Effects 0.000 title abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 59
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 12
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 11
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- 229920002614 Polyether block amide Polymers 0.000 claims abstract description 6
- 150000001413 amino acids Chemical class 0.000 claims abstract description 6
- 229960003237 betaine Drugs 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract 2
- 150000004676 glycans Chemical class 0.000 claims abstract 2
- 230000003405 preventing effect Effects 0.000 claims description 25
- 239000003112 inhibitor Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- -1 amide amino acid Chemical class 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 239000000306 component Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 239000002253 acid Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 12
- 230000002688 persistence Effects 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 150000004804 polysaccharides Chemical class 0.000 description 9
- 125000003342 alkenyl group Chemical group 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- 125000002252 acyl group Chemical group 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000010775 animal oil Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 235000019871 vegetable fat Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は、アスファルト合材が金属表面などに付着するのを防止するためのアスファルト合材付着防止剤に関し、金属表面などの塗工表面への残存性に優れ、アスファルト合材の付着防止効果が高く、付着防止効果が持続するアスファルト合材付着防止剤に関する。 The present invention relates to an asphalt mixture adhesion preventive agent for preventing asphalt mixture from adhering to a metal surface and the like, and is excellent in persistence on a coating surface such as a metal surface and has an effect of preventing asphalt mixture adhesion. The present invention relates to an asphalt mixture adhesion preventing agent that is high and has an adhesion preventing effect.
アスファルトと骨材を混ぜたアスファルト合材は、道路の舗装に使用されており、アスファルト合材工場で約110〜180℃の高温で製造され施工される。その施工に際しては、アスファルト合材を積載するホッパー、スキップエレベータ、ダンプ荷台等にアスファルト合材が付着する問題があった。 Asphalt composite material, which is a mixture of asphalt and aggregate, is used for road paving, and is manufactured and installed at a high temperature of about 110 to 180 ° C. in an asphalt composite plant. During the construction, there has been a problem that the asphalt composite material adheres to a hopper, a skip elevator, a dump carrier, etc. on which the asphalt composite material is loaded.
そこで従来は、軽油、重油等の鉱物油や動植物油脂をそのままもしくは水に乳化、分散させて、ダンプ荷台等に直接撒いたり、合材プラントではホッパー、スキップエレベータ等に噴霧装置を設置して定期的に吹き付けることでアスファルト合材の付着を防止していた(特許文献1、特許文献2)。しかしながら、この方法では軽油・重油等の鉱物油や動植物油脂が、アスファルトに溶解しアスファルト合材を軟化させるという問題点があった。 Therefore, conventionally, mineral oil such as light oil and heavy oil, and animal and vegetable oils and fats are directly or emulsified and dispersed in water, and they are spread directly on dump trucks. Asphalt mixture was prevented from adhering by spraying on the surface (Patent Document 1, Patent Document 2). However, this method has a problem that mineral oil such as light oil and heavy oil and animal and vegetable oils and fats dissolve in asphalt and soften the asphalt mixture.
この問題を解決する付着防止剤として、多価アルコールを使用するアスファルト合材付着防止剤が知られている。しかし多価アルコールを使用するアスファルト合材付着防止剤は、鉱物油や動植物油脂と比較して、金属表面への残存性が悪く、付着防止効果が低いという問題があった。また金属表面に残存した付着防止剤もアスファルト合材が降ろされると同時に表面より除去されてしまうことから付着防止効果を失い、再度アスファルト合材を積載する場合は、その都度付着防止剤を噴霧しなければならず、付着防止効果の持続性にも問題があった。これらの問題を解決するために、ポリビニルアルコール、ポリアルキルグリコール及び誘導体との併用やオレフィン・マレイン酸共重合物を併用するアスファルト合材付着防止剤が開示されているが、金属表面への残存性は改善されているものの付着防止効果および付着防止効果の持続性は十分でない(特許文献3、特許文献4、特許文献5)。 As an adhesion preventing agent for solving this problem, an asphalt mixture adhesion preventing agent using a polyhydric alcohol is known. However, the asphalt mixture adhesion inhibitor using polyhydric alcohol has a problem that it has poor persistence on the metal surface and has a low adhesion preventing effect as compared with mineral oils and animal and vegetable oils. In addition, the adhesion inhibitor remaining on the metal surface is also removed from the surface as soon as the asphalt mixture is lowered, so that the adhesion prevention effect is lost, and when loading asphalt mixture again, the adhesion inhibitor is sprayed each time. There was also a problem with the sustainability of the adhesion prevention effect. In order to solve these problems, an asphalt mixture adhesion preventive agent using a combination of polyvinyl alcohol, polyalkylglycol and a derivative or an olefin / maleic acid copolymer has been disclosed. However, the adhesion preventing effect and the persistence of the adhesion preventing effect are not sufficient (Patent Document 3, Patent Document 4, and Patent Document 5).
本発明は、上記従来の課題を解決するものであり、その目的は、塗工表面への残存性に優れ、アスファルト合材の付着防止効果が高く、付着防止効果が持続するアスファルト合材付着防止剤を提供することである。 The present invention solves the above-mentioned conventional problems, and its purpose is to prevent asphalt mixture adhesion that is excellent in persistence on the coating surface, has high anti-adhesion effect of asphalt mixture, and maintains the anti-adhesion effect. Is to provide an agent.
本発明者らは、上記課題を解決するために鋭意検討を行った結果、水溶性の多糖類と、ベタイン型界面活性剤、アミドアミノ酸型界面活性剤、アミノ酸型界面活性剤、アルキルポリエーテルアミン型界面活性剤、アルキルポリエーテルアミド型界面活性剤、アミンオキシド型界面活性剤から選ばれる1種または2種以上の界面活性剤と、炭素数2〜9の水溶性の多価アルコールを配合したアスファルト合材付着防止剤であって、上記界面活性剤が、界面活性剤、水、グリセリンを質量比5:15:80で調製した混合液が25℃で透明となる界面活性剤であるアスファルト合材付着防止剤が、塗工表面への残存性に優れ、アスファルト合材の付着防止効果が高く、付着防止効果が持続することを見出した。 As a result of intensive studies to solve the above problems, the present inventors have found that a water-soluble polysaccharide, a betaine surfactant, an amide amino acid surfactant, an amino acid surfactant, an alkyl polyether amine Type surfactant, alkyl polyetheramide type surfactant, amine oxide type surfactant selected from one or more surfactants and water-soluble polyhydric alcohol having 2 to 9 carbon atoms Asphalt composite anti-adhesive agent, wherein the surfactant is a surfactant prepared by mixing a surfactant, water, and glycerin at a mass ratio of 5:15:80 and becomes transparent at 25 ° C. It has been found that the material adhesion preventing agent has excellent persistence on the coating surface, has a high adhesion preventing effect on asphalt composites, and the adhesion preventing effect is sustained.
すなわち、本発明は、
(A)水溶性多糖類0.05〜1質量%、
(B)ベタイン型界面活性剤、アミドアミノ酸型界面活性剤、アミノ酸型界面活性剤、アルキルポリエーテルアミン型界面活性剤、アルキルポリエーテルアミド型界面活性剤、アミンオキシド型界面活性剤から選ばれる1種または2種以上の界面活性剤0.1〜5質量%、
(C)炭素数2〜9の水溶性の多価アルコール94〜99.85質量%からなるアスファルト合材付着防止剤であって、
前記(B)成分が、(B)成分と水とグリセリンの質量比が5:15:80である混合液が25℃で透明となる界面活性剤であるアスファルト合材付着防止剤に関する。
That is, the present invention
(A) 0.05 to 1% by mass of a water-soluble polysaccharide,
(B) 1 selected from betaine surfactants, amide amino acid surfactants, amino acid surfactants, alkyl polyether amine surfactants, alkyl polyether amide surfactants, amine oxide surfactants 0.1 to 5% by mass of seeds or two or more surfactants,
(C) an asphalt mixture adhesion inhibitor comprising 94 to 99.85% by mass of a water-soluble polyhydric alcohol having 2 to 9 carbon atoms,
The component (B) relates to an asphalt mixture adhesion preventive agent which is a surfactant in which a mixed solution in which the mass ratio of the component (B), water, and glycerin is 5:15:80 becomes transparent at 25 ° C.
本発明のアスファルト合材付着防止剤によれば、塗工表面への残存性に優れ、アスファルト合材の付着防止効果が高く、付着防止効果が持続するという効果を奏する。 According to the asphalt mixture adhesion preventive agent of the present invention, it is excellent in the persistence on the coating surface, has a high effect of preventing the adhesion of the asphalt mixture, and has an effect of maintaining the adhesion prevention effect.
以下、本発明をさらに詳細に説明する。本発明のアスファルト合材付着防止剤は、(A)水溶性多糖類、(B)界面活性剤、(C)多価アルコールからなる。まず、(A)水溶性多糖類について説明する。 Hereinafter, the present invention will be described in more detail. The asphalt mixture adhesion inhibitor of the present invention comprises (A) a water-soluble polysaccharide, (B) a surfactant, and (C) a polyhydric alcohol. First, (A) the water-soluble polysaccharide will be described.
〔(A)水溶性多糖類〕
本発明に用いる(A)成分は、水溶性の多糖類である。本発明に用いる多糖類は天然系と半合成系の化合物に分類される。天然系の化合物としては、デンプン、デキストリン、プルラン、アルギン酸、キサンタンガム、カラギーナン、アラビアガム、グアガム等が挙げられる。半合成系の化合物としては、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロースまたはその塩、カチオン化セルロース、カチオン化デンプン等が挙げられる。好ましくは、付着防止効果および付着防止効果の持続性の面から、キサンタンガムである。これらの多糖類は、好ましくは1%水溶液の粘度が100〜10,000mPa・sである。なお、粘度の測定はB型粘度計(東機産業(株)製、VISCOMETER TV−10)を使用し25℃、6rpmで行なうことができる。(A)成分の使用に際しては、単独若しくは2種以上の混合物として用いることができる。
[(A) Water-soluble polysaccharide]
The component (A) used in the present invention is a water-soluble polysaccharide. The polysaccharides used in the present invention are classified into natural and semisynthetic compounds. Examples of natural compounds include starch, dextrin, pullulan, alginic acid, xanthan gum, carrageenan, gum arabic, and guar gum. Examples of the semi-synthetic compound include methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose or a salt thereof, cationized cellulose, and cationized starch. Xanthan gum is preferable from the viewpoint of adhesion prevention effect and durability of adhesion prevention effect. These polysaccharides preferably have a 1% aqueous solution with a viscosity of 100 to 10,000 mPa · s. The viscosity can be measured at 25 ° C. and 6 rpm using a B-type viscometer (manufactured by Toki Sangyo Co., Ltd., VISCOMETER TV-10). When the component (A) is used, it can be used alone or as a mixture of two or more.
(A)成分は、アスファルト合材付着防止剤中、0.05〜1質量%の範囲であり、好ましくは0.1〜1質量%の範囲である。(A)成分が0.05質量%未満では、付着防止剤の残存性、付着防止効果および付着防止効果の持続性が悪くなることがあり、1質量%を越えるとハンドリングが悪くなり、使用が困難となることがある。 (A) A component is the range of 0.05-1 mass% in an asphalt mixture adhesion inhibitor, Preferably it is the range of 0.1-1 mass%. When the component (A) is less than 0.05% by mass, the persistence of the adhesion inhibitor, the adhesion preventing effect and the adhesion preventing effect may be deteriorated. It can be difficult.
〔(B)界面活性剤〕
本発明に用いる(B)成分は、ベタイン型界面活性剤、アミドアミノ酸型界面活性剤、アミノ酸型界面活性剤、アルキルポリエーテルアミン型界面活性剤、アルキルポリエーテルアミド型界面活性剤、アミンオキシド型界面活性剤から選ばれる1種または2種以上の界面活性剤である。例えば、ベタイン型界面活性剤としては式(1)に示す界面活性剤、アミドアミノ酸型界面活性剤およびアミノ酸型界面活性剤としては式(2)、(3)、(4)に示す界面活性剤、アルキルポリエーテルアミン型界面活性剤およびアルキルポリエーテルアミド型界面活性剤としては式(5)に示す界面活性剤、アミンオキシド型界面活性剤としては式(6)に示す界面活性剤が使用できる。なお、(B)成分として、上記6種の界面活性剤のそれぞれにおいて、単独若しくは2種以上の界面活性剤を使用することができる。
[(B) Surfactant]
Component (B) used in the present invention is a betaine type surfactant, an amide amino acid type surfactant, an amino acid type surfactant, an alkyl polyether amine type surfactant, an alkyl polyether amide type surfactant, an amine oxide type One or more surfactants selected from surfactants. For example, as the betaine type surfactant, the surfactant represented by the formula (1), the amide amino acid type surfactant and the amino acid type surfactant as the surfactant represented by the formulas (2), (3) and (4) The surfactant shown in Formula (5) can be used as the alkyl polyether amine surfactant and the alkyl polyether amide surfactant, and the surfactant shown in Formula (6) can be used as the amine oxide surfactant. . In addition, as (B) component, in each of said 6 types of surfactant, single or 2 or more types of surfactant can be used.
(式中R1は炭素数10〜18のアルキル基、アルケニル基、アシル基またはR4NH(CH2)l、R4は炭素数10〜18のアルキル基、アルケニル基またはアシル基、R2、R3は炭素数1〜3のアルキル基であり、X1は−(CH2)mCOO−、−CH2CH2(OH)CH2SO3 −または−(CH2)nPO4 −で、l、m、nは1〜3の整数である。) (Wherein R 1 is an alkyl group, alkenyl group, acyl group or R 4 NH (CH 2 ) 1 having 10 to 18 carbon atoms, R 4 is an alkyl group, alkenyl group or acyl group having 10 to 18 carbon atoms, R 2 , R 3 is an alkyl group having 1 to 3 carbon atoms, and X 1 is — (CH 2 ) m COO − , —CH 2 CH 2 (OH) CH 2 SO 3 — or — (CH 2 ) n PO 4 —. And l, m and n are integers of 1 to 3.)
(式中R5は炭素数10〜18のアルキル基、アルケニル基またはアシル基であり、X2は水素またはヒドロキシエチル基、Y1は水素、ヒドロキシエチル基または−(CH2)mCOOM1、Z1は−(CH2)nCOOM2であり、M1、M2は水素、アルカリ金属、アルカリ土類金属、アンモニウムまたは有機アンモニウムで、l、m、nは1〜3の整数である。) (Wherein R 5 is an alkyl group, alkenyl group or acyl group having 10 to 18 carbon atoms, X 2 is hydrogen or hydroxyethyl group, Y 1 is hydrogen, hydroxyethyl group or — (CH 2 ) m COOM 1 , Z 1 is — (CH 2 ) n COOM 2 , M 1 and M 2 are hydrogen, alkali metal, alkaline earth metal, ammonium or organic ammonium, and l, m and n are integers of 1 to 3. )
(式中R6は炭素数10〜18のアルキル基、アルケニル基またはアシル基であり、X3は水素、ヒドロキシエチル基または−(CH2)mCOOM3、Y2は−(CH2)nCOOM4であり、M3、M4は水素、アルカリ金属、アルカリ土類金属、アンモニウムまたは有機アンモニウムで、m、nは1〜3の整数である。) (Wherein R 6 is an alkyl group, alkenyl group or acyl group having 10 to 18 carbon atoms, X 3 is hydrogen, hydroxyethyl group or — (CH 2 ) m COOM 3 , Y 2 is — (CH 2 ) n. COOM 4 wherein M 3 and M 4 are hydrogen, alkali metal, alkaline earth metal, ammonium or organic ammonium, and m and n are integers of 1 to 3. )
(式中R7は炭素数10〜18のアルキル基、アルケニル基またはアシル基であり、M5は水素、アルカリ金属、アルカリ土類金属、アンモニウムまたは有機アンモニウムで、l、m、nは1〜3の整数である。) (Wherein R 7 is an alkyl group, alkenyl group or acyl group having 10 to 18 carbon atoms, M 5 is hydrogen, alkali metal, alkaline earth metal, ammonium or organic ammonium; It is an integer of 3.)
(式中R8は炭素数10〜18のアルキル基、アルケニル基またはアシル基であり、m≧0、n≧0の整数でm+nは1〜30である。) (In the formula, R 8 is an alkyl group, alkenyl group or acyl group having 10 to 18 carbon atoms, an integer of m ≧ 0 and n ≧ 0, and m + n is 1 to 30.)
(式中R9は炭素数10〜18のアルキル基、アルケニル基、脂肪族アシル基またはR12NH(CH2)n、R12は炭素数10〜18のアルキル基、アルケニル基または脂肪族アシル基、R10、R11は炭素数1〜3のアルキル基またはヒドロキシアルキル基であり、nは1〜3の整数である。) (Wherein R 9 is an alkyl group, alkenyl group, aliphatic acyl group or R 12 NH (CH 2 ) n having 10 to 18 carbon atoms, and R 12 is an alkyl group, alkenyl group or aliphatic acyl having 10 to 18 carbon atoms. The groups R 10 and R 11 are alkyl groups or hydroxyalkyl groups having 1 to 3 carbon atoms, and n is an integer of 1 to 3).
なお、上記式(2)〜(4)におけるアルカリ金属としては、リチウム、ナトリウム、カリウム等が挙げられ、好ましくは、ナトリウム、カリウムである。アルカリ土類金属としては、カルシウム、ストロンチウム、バリウム等が挙げられ、好ましくは、カルシウムである。有機アンモニウムにおける有機アミンとしては、例えばモノエタノールアミン、ジエタノールアミン、トリエタノールアミンなどのアルカノールアミン、ジエチルアミン、トリエチルアミンなどのアルキルアミンが挙げられる。 In addition, lithium, sodium, potassium etc. are mentioned as an alkali metal in said formula (2)-(4), Preferably, they are sodium and potassium. Examples of the alkaline earth metal include calcium, strontium, barium and the like, preferably calcium. Examples of organic amines in organic ammonium include alkanolamines such as monoethanolamine, diethanolamine and triethanolamine, and alkylamines such as diethylamine and triethylamine.
(B)成分としては(C)成分の多価アルコールに均一に溶解するものが好ましく、本発明における(B)成分の界面活性剤は、界面活性剤、水、グリセリンを質量比5:15:80で混合した場合に、その混合液が25℃で透明となるものである。上記混合液が白濁や分離をする界面活性剤では付着防止剤の残存性が悪くなることがある。
なお、透明か否かの判定は、上記混合液の調製を行なった後、外観を目視で観察することにより行なうことができる。
The component (B) is preferably one that is uniformly dissolved in the polyhydric alcohol of the component (C), and the surfactant of the component (B) in the present invention is a surfactant, water, and glycerin in a mass ratio of 5:15: When mixed at 80, the liquid mixture becomes transparent at 25 ° C. In the case of a surfactant in which the mixed solution becomes clouded or separated, the persistence of the anti-adhesive agent may be deteriorated.
The determination of whether or not it is transparent can be made by visually observing the appearance after preparing the mixed solution.
(B)成分は、アスファルト合材付着防止剤中、0.1〜5質量%の範囲であり、好ましくは0.5〜3質量%の範囲である。(B)成分が0.1質量%未満では、付着防止剤の残存性、付着防止効果および付着防止効果の持続性が悪くなることがあり、5質量%を越えても添加量に見合った効果が得られないことがある。 The component (B) is in the range of 0.1 to 5% by mass, and preferably in the range of 0.5 to 3% by mass in the asphalt mixture adhesion inhibitor. When the component (B) is less than 0.1% by mass, the persistence of the adhesion inhibitor, the adhesion preventing effect and the adhesion preventing effect may be deteriorated. May not be obtained.
〔(C)多価アルコール〕
本発明に用いる(C)成分は、炭素数2〜9の水溶性の多価アルコールである。本発明に使用する水溶性の多価アルコールは、常温で液体であり、水への溶解度が1,000g/L以上である。アスファルト合材付着防止剤は、使用用途上、土壌へ放出される可能性があるので、環境負荷が小さいものが好ましく、その観点から、好ましい(C)成分はグリセリンである。(C)成分は単独で、あるいは複数を組み合わせて使用することができる。
[(C) polyhydric alcohol]
(C) component used for this invention is a C2-C9 water-soluble polyhydric alcohol. The water-soluble polyhydric alcohol used in the present invention is liquid at room temperature and has a solubility in water of 1,000 g / L or more. Since the asphalt mixture adhesion inhibitor may be released to the soil for use, it is preferable that the environmental load is small, and from that viewpoint, the preferred component (C) is glycerin. Component (C) can be used alone or in combination.
(C)成分は、アスファルト合材付着防止剤中、94〜99.85質量%の範囲であり、好ましくは96〜99.4質量%の範囲である。(C)成分が94質量%未満では付着防止効果および付着防止効果の持続性が悪くなることがあり、99.85質量%を越えると付着防止剤の残存性、付着防止効果および付着防止効果の持続性が悪くなることがある。 The component (C) is in the range of 94 to 99.85% by mass, preferably in the range of 96 to 99.4% by mass, in the asphalt mixture adhesion inhibitor. If the component (C) is less than 94% by mass, the persistence of the adhesion preventing effect and the adhesion preventing effect may be deteriorated. Sustainability may worsen.
本発明のアスファルト合材付着防止剤は、公知の手法により各成分(A)〜(C)を混合することにより調製することができ、例えば、(C)多価アルコールに、(A)水溶性多糖類及び(B)界面活性剤に配合し、撹拌することにより、調製することができる。本発明のアスファルト合材付着防止剤は、通常、水で希釈して用いられ、例えば10倍程度に水で希釈して用いられる。 The asphalt mixture adhesion preventing agent of the present invention can be prepared by mixing the components (A) to (C) by a known method. For example, the (A) water-soluble (C) polyhydric alcohol can be prepared. It can prepare by mix | blending with polysaccharide and (B) surfactant, and stirring. The asphalt mixture adhesion preventive agent of the present invention is usually diluted with water and used, for example, diluted about 10 times with water.
本発明のアスファルト合材付着防止剤には、本発明の性能を損なわない範囲内で、色素、防錆剤、防腐剤などのその他の添加剤を組み合わせて用いてもよい。 The asphalt mixture adhesion preventive agent of the present invention may be used in combination with other additives such as pigments, rust preventives and preservatives within the range not impairing the performance of the present invention.
以下、実施例および比較例を挙げて本発明を更に具体的に説明する。
(B)成分およびその他成分については、表1に示すB1〜12およびB’1〜4の化合物を用いた。なお、表1中の各記号は、本明細書に記載の各式(1)〜(6)中の記号を表わす。また、表1中の混合液の外観は、B1〜12およびB’1〜4の化合物を用いて、該化合物、水、グリセリンを質量比5:15:80で混合した混合液を調製し、下記の基準で実施した透明性の評価である。すなわち、上記混合液を縦3cm×横3cm×高さ5cmのガラス容器に入れて、25℃恒温槽に3時間静置した後、そのガラス容器を横から見て、視点の反対側にある7ポイントの文字が目視で判別できるか否かで判定を行ない、次の3段階の基準で透明性を評価した。
Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.
(B) About the component and other components, the compound of B1-12 shown in Table 1 and B'1-4 was used. In addition, each symbol in Table 1 represents a symbol in each formula (1) to (6) described in this specification. Moreover, the external appearance of the liquid mixture in Table 1 prepared the liquid mixture which mixed this compound, water, and glycerin by mass ratio 5:15:80 using the compound of B1-12 and B'1-4, It is the evaluation of transparency conducted according to the following criteria. That is, the mixed solution is placed in a glass container having a length of 3 cm, a width of 3 cm, and a height of 5 cm, and left to stand in a thermostatic bath at 25 ° C. for 3 hours. Judgment was made based on whether or not the character of the point was visually distinguishable, and the transparency was evaluated according to the following three criteria.
(評価基準)
◎:均一かつ透明であり、文字が容易に判別できる。
○:わずかに白濁しているものの、均一で文字が判別できる。
×:白濁していて文字が判別できない。または混合液が分離している。
(Evaluation criteria)
A: Uniform and transparent, and characters can be easily distinguished.
○: Although it is slightly cloudy, the characters can be identified uniformly.
X: The characters are cloudy and cannot be distinguished. Or the mixture is separated.
表2〜5に示す割合で、アスファルト合材付着防止剤を調製し、以下の試験に供した。結果を表2〜5に示す。 Asphalt mixture adhesion inhibitors were prepared at the ratios shown in Tables 2 to 5, and were subjected to the following tests. The results are shown in Tables 2-5.
<アスファルト合材付着防止剤試験>
(1)アスファルト合材付着防止剤の残存性テスト
各アスファルト合材付着防止剤を水で10倍に希釈した液を、20cm×15cmのSS400鋼材に1gスプレーした後、鋼材を45度の角度に傾斜させ、10分後の希釈液の残留量を測定した。残存率(%)を以下の計算式で求め、残存率から以下のように判定した。
残存率(%)={(塗布量−10分後の残存量)/塗布量}×100
<Asphalt compound adhesion inhibitor test>
(1) Residuality test of asphalt mixture adhesion preventive agent After spraying 1 g of a solution obtained by diluting each asphalt mixture adhesion inhibitor 10 times with water onto SS400 steel material of 20 cm x 15 cm, the steel material at an angle of 45 degrees. It was tilted and the residual amount of the diluted solution after 10 minutes was measured. The residual rate (%) was determined by the following calculation formula, and judged from the residual rate as follows.
Residual rate (%) = {(application amount−remaining amount after 10 minutes) / application amount} × 100
(評価基準)
○:残存率が95%以上。
△:残存率が95%未満〜60%以上。
×:残存率が60%未満。
○の付着防止剤を合格とした。
(Evaluation criteria)
○: Remaining rate is 95% or more.
Δ: Residual rate is less than 95% to 60% or more.
X: Residual rate is less than 60%.
○ Adhesion preventive agent was accepted.
(2)付着防止効果テスト
各アスファルト合材付着防止剤を水で10倍に希釈した液を、20cm×15cmのSS400鋼材に1gスプレーした後、150℃に加熱したストレートアスファルト合材(密粒度アスファルト合材、ストレートアスファルト:6%、ストレートアスファルト針入度60〜80:JISK2207)を100g乗せ、さらにその上に20cm×15cmのSS400鋼材を3.0kg加重した状態で乗せて1分間常温で放置した。上のSS400鋼材を剥がし、鋼材を45度の角度に傾斜させ、ストレートアスファルト合材を落とした後、薬液を噴霧した下のSS400鋼材を秤量して、ストレートアスファルト合材の付着量を求めた。評価基準は、下記の評価基準に従い判定した。
(2) Adhesion prevention effect test 1 g of a solution obtained by diluting each asphalt mixture adhesion inhibitor 10 times with water is sprayed on 20 cm × 15 cm SS400 steel, and then heated to 150 ° C. Compound material, straight asphalt: 6%, straight asphalt penetration 60-80: JISK2207) is placed on top of it, further loaded with 3.0 cm of SS400 steel of 20 cm x 15 cm and left at room temperature for 1 minute. . The upper SS400 steel material was peeled off, the steel material was inclined at an angle of 45 degrees, and the straight asphalt composite material was dropped. Then, the SS400 steel material sprayed with the chemical solution was weighed to determine the adhesion amount of the straight asphalt composite material. Evaluation criteria were determined according to the following evaluation criteria.
(評価基準)
◎:ストレートアスファルト合材付着量が5g未満。
○:ストレートアスファルト合材付着量が5g以上〜10g 未満。
△:ストレートアスファルト合材付着量が10g以上〜20g未満。
×:ストレートアスファルト合材付着量が20g以上。
◎、○の付着防止剤を合格とした。
(Evaluation criteria)
A: The amount of adhering straight asphalt mixture is less than 5 g.
A: The amount of straight asphalt mixture adhering is 5 g or more and less than 10 g.
(Triangle | delta): The amount of straight asphalt compound material adhesion is 10g or more and less than 20g.
X: The amount of straight asphalt mixture adhering is 20 g or more.
◎, ○ anti-adhesive agent was accepted.
(3)付着防止効果の持続性テスト
各アスファルト合材付着防止剤を水で10倍に希釈した液を、20cm×15cmのSS400鋼材に1gスプレーした後、150℃に加熱したストレートアスファルト合材(密粒度アスファルト合材、ストレートアスファルト:6%、ストレートアスファルト針入度60〜80:JISK2207)を100g乗せ、さらにその上に20cm×15cmのSS400鋼材を3.0kg加重した状態で乗せて1分間常温で放置した。上のSS400鋼材を剥がし、鋼材を45度の角度に傾斜させ、ストレートアスファルト合材を落とした。この操作をストレートアスファルト合材の付着量が10gを越えるまで繰り返し行った。評価基準は、下記の評価基準に従い判定した。
(3) Sustainability test of anti-adhesion effect Straight asphalt compound (1 g) sprayed on a 20 cm x 15 cm SS400 steel solution diluted 10 times with each asphalt compound anti-adhesive agent with water, then heated to 150 ° C ( Dense grained asphalt mixture, straight asphalt: 6%, straight asphalt penetration 60-80: JISK2207) is placed on top of it, and further 20kg x 15cm SS400 steel is loaded with 3.0kg weight on it for 1 minute at room temperature Left alone. The upper SS400 steel was peeled off, the steel was tilted at a 45 degree angle, and the straight asphalt mixture was dropped. This operation was repeated until the adhesion amount of the straight asphalt mixture exceeded 10 g. Evaluation criteria were determined according to the following evaluation criteria.
(評価基準)
◎:5回繰り返しても合材の付着量は10gを越えなかった。
○:3〜5回で10gを越えた。
△:2回で10gを越えた。
×:1回で10gを越えた。
◎、○の付着防止剤を合格とした。
(Evaluation criteria)
(Double-circle): Even if it repeated 5 times, the adhesion amount of compound material did not exceed 10g.
○: 10 g exceeded 3 to 5 times.
(Triangle | delta): It exceeded 10g in 2 times.
X: Over 10 g at one time.
◎, ○ anti-adhesive agent was accepted.
表2,3に示すように、本発明に係る実施例の付着防止剤によれば、鋼材への残存性に優れ、アスファルト合材の付着防止効果が高く、また付着防止効果が持続することがわかる。
一方、表4,5に示すように、比較例の付着防止剤では、残存性、付着防止効果、持続性の全てが合格となるものがなかった。
As shown in Tables 2 and 3, according to the adhesion preventive agent of the embodiment according to the present invention, it is excellent in the persistence to the steel material, the adhesion preventing effect of the asphalt mixture is high, and the adhesion preventing effect is sustained. Recognize.
On the other hand, as shown in Tables 4 and 5, none of the adhesion preventing agents of Comparative Examples passed all of the persistence, the adhesion preventing effect, and the sustainability.
Claims (1)
(B)ベタイン型界面活性剤、アミドアミノ酸型界面活性剤、アミノ酸型界面活性剤、アルキルポリエーテルアミン型界面活性剤、アルキルポリエーテルアミド型界面活性剤、アミンオキシド型界面活性剤から選ばれる1種または2種以上の界面活性剤0.1〜5質量%、
(C)炭素数2〜9の水溶性の多価アルコール94〜99.85質量%からなるアスファルト合材付着防止剤であって、
前記(B)成分が、(B)成分と水とグリセリンの質量比が5:15:80である混合液が25℃で透明となる界面活性剤であるアスファルト合材付着防止剤。 (A) 0.05 to 1% by mass of a water-soluble polysaccharide,
(B) 1 selected from betaine surfactants, amide amino acid surfactants, amino acid surfactants, alkyl polyether amine surfactants, alkyl polyether amide surfactants, amine oxide surfactants 0.1 to 5% by mass of seeds or two or more surfactants,
(C) an asphalt mixture adhesion inhibitor comprising 94 to 99.85% by mass of a water-soluble polyhydric alcohol having 2 to 9 carbon atoms,
The asphalt mixture adhesion preventing agent whose said (B) component is surfactant which becomes transparent at 25 degreeC in the liquid mixture whose mass ratio of (B) component, water, and glycerol is 5:15:80.
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Cited By (3)
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JP2016513163A (en) * | 2013-02-22 | 2016-05-12 | バレロ,ラファエル,レオナルド バロエタ | Catalyst for asphalt mixture |
WO2020059885A1 (en) * | 2018-09-20 | 2020-03-26 | バイオ燃料技研工業株式会社 | Method and system for purifying glycerin, method for producing stripping agent, and stripping method |
CN113528015A (en) * | 2021-06-29 | 2021-10-22 | 山西工程科技职业大学 | Anti-sticking agent for trench oil-based rubber-tyred road roller and preparation method of anti-sticking agent |
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JP2006241409A (en) * | 2005-03-07 | 2006-09-14 | Nippon Eco Systems Kk | Deposition preventive agent for asphalt |
JP2007302710A (en) * | 2006-05-08 | 2007-11-22 | Nicca Chemical Co Ltd | Attach-preventing agent for asphalt-mixed material |
JP2010100731A (en) * | 2008-10-23 | 2010-05-06 | Nof Corp | Asphalt adhesion preventive agent |
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JP2004244548A (en) * | 2003-02-14 | 2004-09-02 | Toho Rika Kk | Asphalt adhesion-preventing agent |
JP2006241409A (en) * | 2005-03-07 | 2006-09-14 | Nippon Eco Systems Kk | Deposition preventive agent for asphalt |
JP2007302710A (en) * | 2006-05-08 | 2007-11-22 | Nicca Chemical Co Ltd | Attach-preventing agent for asphalt-mixed material |
JP2010100731A (en) * | 2008-10-23 | 2010-05-06 | Nof Corp | Asphalt adhesion preventive agent |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2016513163A (en) * | 2013-02-22 | 2016-05-12 | バレロ,ラファエル,レオナルド バロエタ | Catalyst for asphalt mixture |
WO2020059885A1 (en) * | 2018-09-20 | 2020-03-26 | バイオ燃料技研工業株式会社 | Method and system for purifying glycerin, method for producing stripping agent, and stripping method |
JPWO2020059885A1 (en) * | 2018-09-20 | 2021-08-30 | バイオ燃料技研工業株式会社 | Glycerin purification method and purification system, release agent manufacturing method and release method |
JP7325762B2 (en) | 2018-09-20 | 2023-08-15 | バイオ燃料技研工業株式会社 | Glycerin purification method and purification system, stripping agent manufacturing method and stripping method |
CN113528015A (en) * | 2021-06-29 | 2021-10-22 | 山西工程科技职业大学 | Anti-sticking agent for trench oil-based rubber-tyred road roller and preparation method of anti-sticking agent |
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