JP2012210230A - Milk substitute and method for producing the same - Google Patents

Milk substitute and method for producing the same Download PDF

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JP2012210230A
JP2012210230A JP2012173718A JP2012173718A JP2012210230A JP 2012210230 A JP2012210230 A JP 2012210230A JP 2012173718 A JP2012173718 A JP 2012173718A JP 2012173718 A JP2012173718 A JP 2012173718A JP 2012210230 A JP2012210230 A JP 2012210230A
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oil
oils
fats
powdered
milk
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JP5926647B2 (en
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Yukio Sakai
幸男 酒井
Toshihiro Shintaku
敏博 新宅
Yoshihiro Kimura
良博 木村
Yoshio Tamura
佳生 田村
Junji Kawasaki
順二 川崎
Takayuki Ando
貴之 安藤
Yuji Dobashi
裕司 土橋
Akihiro Kishida
昭弘 岸田
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Nat Federation Of Dairy Coop Ass
NATIONAL FEDERATION OF DAIRY COOPERATIVE ASSOCIATIONS
Marubeni Nisshin Feed Co Ltd
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Nat Federation Of Dairy Coop Ass
NATIONAL FEDERATION OF DAIRY COOPERATIVE ASSOCIATIONS
Marubeni Nisshin Feed Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a milk substitute dispersing/dissolving well with water or warm water without developing a churning phenomenon, excellent in emulsion stability, and not solidifying during its preservation.SOLUTION: This milk substitute contains powdery oil-and-fat containing plant oil-and-fat having 10 to 20°C elevation melting point.

Description

本発明は、粉末油脂、それを用いた代用乳及びその製造方法に関する。   The present invention relates to powdered fats and oils, milk substitutes using the same, and methods for producing the same.

子牛、子豚、子山羊等の幼畜類の生産やその他の幼動物の飼育に当たっては、母乳の代わりに人工的に作られた代用乳を給与して飼育することが広く行われている。この代用乳は、脱脂粉乳、乾燥ホエー等の乳成分を主成分とし、これに油脂類、糖類、穀類等を配合して製造され、水や温水に溶解あるいは乳化分散させて給与されている。油脂類を多く配合した代用乳は、カロリーが高く、早期育成を促すことができるが、水や温水への溶解性・分散性が低く、脂肪球径が大きくなり、乳化安定性が悪くなって油脂の分離を起こしたり、消化吸収性が悪くなって下痢などを引き起こすという問題があった。また、保管中の温度差により油脂が溶融、固結を繰り返すため、油脂がしみ出したり、粉体が固結する問題もあった。   In the production of larvae such as calves, piglets, and goats, and the breeding of other larvae, it is widely practiced to feed artificial milk instead of breast milk. This milk substitute is made mainly of skim milk powder, dry whey and other milk components, and is blended with oils, sugars, cereals and the like, and is supplied after dissolved or emulsified and dispersed in water or hot water. Milk substitutes containing a large amount of fats and oils are high in calories and can promote early growth, but have low solubility and dispersibility in water and hot water, a large fat globule diameter, and poor emulsion stability. There have been problems of causing separation of oils and fats and poor digestibility and causing diarrhea. In addition, since the fats and oils are repeatedly melted and consolidated due to the temperature difference during storage, the fats and oils ooze out and the powders are solidified.

そこで、斯かる問題を解決するため、乳成分を主とする粉体原料に液体油脂を噴霧して造粒する代用乳の製造方法が報告されている(特許文献1)が、依然として乳化安定性が悪く、分散・溶解した時に油脂が分離してしまう。また、粉末油脂をその他の粉体原料と予め混合してから造粒する方法も知られている(特許文献2)が、水や温水への分散・溶解に時間がかかると共に、チャーニング現象(代用乳を水又は温水に加えて攪拌した時に乳化が破壊され、脂肪球等が凝集する現象)が生じてしまうのが実状であった。   Therefore, in order to solve such a problem, a method for producing a milk replacer in which liquid oil is sprayed on a powder raw material mainly containing a milk component and granulated has been reported (Patent Document 1), but still emulsification stability. The oils and fats are separated when dispersed and dissolved. In addition, a method of granulating powder oil and fat with other powder raw materials in advance is also known (Patent Document 2). However, it takes time to disperse and dissolve in water and warm water, and a charring phenomenon ( When the milk replacer was added to water or warm water and stirred, the emulsification was broken and a phenomenon in which fat globules and the like aggregated occurred.

特開2003−189799号公報JP 2003-189799 A 特開2006−94710号公報JP 2006-94710 A

本発明は、上記の如き従来の問題と実状に鑑みてなされたものであり、チャーニング現象を生じることなく水や温水に良好に分散・溶解し、乳化安定性に優れ、且つ保管中も固結しない代用乳を提供することを課題とする。   The present invention has been made in view of the above-described conventional problems and situations, and is well dispersed and dissolved in water and warm water without causing a charring phenomenon, excellent in emulsion stability, and solid even during storage. It is an object to provide milk replacer that does not tie.

本発明者は、当該課題を解決すべく鋭意研究を重ねた結果、代用乳に配合する油脂として上昇融点が10〜20℃の植物性油脂を含有する粉末油脂を用いれば、チャーニング現象を生じることなく水や温水に良好に分散・溶解し、乳化安定性に優れ、且つ保管中も固結することなく顆粒状を保つことを見出し、本発明を完成した。   As a result of intensive studies to solve the problem, the inventor of the present invention produces a charring phenomenon if a powdered fat containing a vegetable oil with an ascending melting point of 10 to 20 ° C. is used as the fat mixed in the milk substitute. The present invention was completed by discovering that it was well dispersed and dissolved in water and warm water without any problems, was excellent in emulsification stability, and kept in a granular form without being consolidated during storage.

すなわち、本発明は、上昇融点10〜20℃の植物性油脂を含有することを特徴とする粉末油脂により上記課題を解決したものである。   That is, this invention solves the said subject with the powdered fats and oils characterized by containing vegetable fats and oils with a raise melting | fusing point of 10-20 degreeC.

また、本発明は、上記粉末油脂を含有することを特徴とする代用乳により上記課題を解決したものである。   Moreover, this invention solves the said subject with the milk replacer characterized by containing the said powdered fats and oils.

さらに、本発明は、上記粉末油脂を含有する代用乳粉末組成物を流動層造粒することを特徴とする代用乳の製造方法により上記課題を解決したものである。   Furthermore, this invention solves the said subject with the manufacturing method of the milk replacer characterized by carrying out the fluidized-bed granulation of the replaceable milk powder composition containing the said powdered fats and oils.

本発明の粉末油脂を用いて代用乳を製造すれば、チャーニング現象を生じることなく水や温水に極めて良好に分散・溶解し、脂肪球径が小さく乳化安定性に優れた代用乳を得ることができる。しかもこの代用乳は、保管中も固結することなくサラサラとした顆粒状を呈する。   If milk substitutes are produced using the powdered fats and oils of the present invention, milk substitutes that are extremely well dispersed and dissolved in water and warm water without causing a charring phenomenon and that have a small fat globule diameter and excellent emulsion stability can be obtained. Can do. Moreover, this milk replacer exhibits a smooth granular shape without being consolidated during storage.

本発明で用いる植物性油脂の上昇融点は、10℃〜20℃であり、好ましくは15℃〜19℃である。植物性油脂としては、食用油脂として使用が認められているものであれば、その原料やその精製度等は問わないが、例えばパーム油、パーム核油、パームオレイン油等のパームヤシ由来の油脂、ヤシ油又はそれらの分画油、並びに中鎖脂肪酸トリグリセライド等を挙げることができる。中鎖脂肪酸トリグリセライドは、炭素数6〜12の脂肪酸をその構成脂肪酸とするトリグリセライド等が挙げられる。本発明においては、前記植物性油脂を単独で用いてもよく、融点が違う2種以上の植物性油脂を用いて上昇融点が10〜20℃の範囲になるように調整してもよい。また、上昇融点の調整のために、大豆油、その他の植物性油脂を用いることもできる。なお、本発明における上昇融点とは、試料を毛細管中で加熱した場合、軟化して上昇を始める温度を云い、下記に示す「基準油脂分析試験法」(1996年版)に記載の方法に従って、測定することができる。   The rising melting point of the vegetable oil used in the present invention is 10 ° C to 20 ° C, preferably 15 ° C to 19 ° C. As vegetable oils and fats, as long as their use is recognized as edible oils and fats, their raw materials and their purification levels are not limited, but for example, palm oils such as palm oil, palm kernel oil, palm olein oil, Mention may be made of coconut oil or fractionated oils thereof, and medium-chain fatty acid triglycerides. Examples of the medium-chain fatty acid triglyceride include triglycerides having a fatty acid having 6 to 12 carbon atoms as a constituent fatty acid. In this invention, you may use the said vegetable oil and fat independently, and you may adjust so that a raise melting | fusing point may be in the range of 10-20 degreeC using 2 or more types of vegetable oil and fat from which melting | fusing point differs. In addition, soybean oil and other vegetable oils can be used to adjust the rising melting point. The rising melting point in the present invention refers to the temperature at which a sample softens and begins to rise when the sample is heated in a capillary tube, and is measured according to the method described in “Standard Oil Analysis Test Method” (1996 version) shown below. can do.

上昇融点の測定法
1.試料の調製
(1)試料を融解し、乾燥濾紙で濾過する。
(2)毛細管(内径1mm、外径2mm以下、長さ50〜80mm、両端が開いているもの。)の一端を、完全に融解した試料(通常60℃)につけて約10mmの高さまで試料を満たし、速やかに氷片等で固化させる。
(3)10℃以下で24h、あるいは氷上で1h放置した後試験に供する。
2.方法
(1)試料調製した毛細管を温度計の下部にゴム輪または適当な方法で速やかに密着させ、それらの下端をそろえる。
(2)毛細管を密着させた温度計(長さ385〜390mm、水銀の長さ15〜25mm、0.2℃目盛)を、予想される融点より約20℃低い温度の水を満たしたビーカーの中に浸し、温度計の下端を水面下30mmの深さにおく。
(3)ビーカー(500〜1000mL)の中の水を適当な方法でかきまぜながら、最初は2℃/minずつ上昇するように加熱する。予測される融点の10℃下に達した後は、0.5℃/minとする。
(4)試料が毛細管中で上昇を始める温度を融点とする。
Measuring method of rising melting point Sample Preparation (1) Thaw the sample and filter with dry filter paper.
(2) Attach one end of a capillary tube (inner diameter: 1 mm, outer diameter: 2 mm or less, length: 50 to 80 mm, both ends open) to a completely melted sample (usually 60 ° C.), and put the sample to a height of about 10 mm. Fill and quickly solidify with ice pieces.
(3) Leave at 10 ° C. or lower for 24 hours, or leave on ice for 1 hour, and then test.
2. Method (1) The sample-prepared capillaries are quickly brought into close contact with the lower part of the thermometer by a rubber ring or an appropriate method, and their lower ends are aligned.
(2) A thermometer (length 385 to 390 mm, mercury length 15 to 25 mm, 0.2 ° C. scale) with a capillary in close contact with a beaker filled with water at a temperature about 20 ° C. lower than the expected melting point. Immerse it in and place the lower end of the thermometer at a depth of 30 mm below the water surface.
(3) While stirring the water in a beaker (500 to 1000 mL) by an appropriate method, heat the mixture so as to increase by 2 ° C./min at first. After reaching 10 ° C. below the predicted melting point, the temperature is set to 0.5 ° C./min.
(4) The temperature at which the sample begins to rise in the capillary is defined as the melting point.

植物性油脂の配合量は、粉末油脂原料の総質量中、40〜80質量%が好ましく、特に45〜65質量%が好ましい。40質量%より少ないと栄養設計上カロリーの充足が難しくなり、他方80質量%より多いと粉末油脂化が困難であり、さらに保存安定性が悪くなり易い。   The amount of the vegetable oil / fat is preferably 40 to 80% by mass and particularly preferably 45 to 65% by mass in the total mass of the powdered oil / fat raw material. If it is less than 40% by mass, it is difficult to satisfy calories for nutritional design, while if it is more than 80% by mass, it is difficult to make a powdered oil and fat, and storage stability tends to deteriorate.

本発明の粉末油脂には、乳化安定性の観点から、上記植物性油脂の他、例えばレシチン、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル等の乳化剤を配合するのが好ましい。また、必要に応じて、脱脂粉乳、全脂粉乳等の粉乳類;糖類、多糖類(デキストリン、ガム類)、シリカ、ケイ酸、カゼインナトリウム等を適宜配合することができる。   In addition to the above vegetable oils and fats, the powdered oils and fats of the present invention include, for example, lecithin, glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acids. It is preferable to incorporate an emulsifier such as an ester. Moreover, powdered milks such as skim milk powder and whole fat milk powder; sugars, polysaccharides (dextrin, gums), silica, silicic acid, sodium caseinate and the like can be appropriately blended as necessary.

粉末油脂の製造方法としては特に制限されない。例えば上記植物性油脂に必要により他の粉末油脂原料を混合して混合油組成物を得た後、これを高圧ホモジナイザー、コロイドミル、ホモミキサー等を用いて均質化処理し、次いで得られた混合乳化液を乾燥することにより粉末油脂を得ることができる。粉末油脂の乾燥方法としては、例えば熱風による噴霧乾燥法(スプレードライ法)、真空凍結乾燥法等が挙げられる。得られた粉末油脂は、特に代用乳用の粉末油脂として好適に用いることができる。
本発明の粉末油脂を調製するための混合乳化液は、混合乳化液中の脂肪球が乳化作用によって微細化されているため、得られる粉末油脂を水や温水に分散・溶解した際の脂肪球径は小さく且つ均一なものになる。従って、これを用いて製造した代用乳を水や温水に分散・溶解した際の脂肪球径も極めて微小なものになるため、乳化安定性に優れた代用乳が得られる。
It does not restrict | limit especially as a manufacturing method of powder oil. For example, after mixing the above vegetable oil and fat with other powder oil and fat raw materials as necessary to obtain a mixed oil composition, this is homogenized using a high-pressure homogenizer, colloid mill, homomixer, etc., and then the resulting mixture Powdered fats and oils can be obtained by drying the emulsion. Examples of the method for drying the powdered oil include a spray drying method (spray drying method) using hot air, a vacuum freeze drying method, and the like. The obtained powdered fats and oils can be suitably used particularly as powdered fats and oils for milk substitutes.
The mixed emulsion for preparing the powdered fats and oils of the present invention has the fat globules obtained by dispersing and dissolving the obtained powdered fats and oils in water or warm water because the fat globules in the mixed emulsion are refined by an emulsifying action. The diameter is small and uniform. Therefore, since the milk fat milk produced using this powder has a very small fat globule diameter when dispersed or dissolved in water or warm water, a milk substitute having excellent emulsification stability can be obtained.

本発明の代用乳は、上記粉末油脂を含有する代用乳粉末組成物を流動層造粒乾燥機等にて流動層造粒することにより製造することができる。なお、粉末油脂を除く代用乳原料を予め流動層造粒法により造粒した後、油脂類を添加する方法では、従来公知の方法で得られた代用乳に比べてチャーニング現象等の改善は認められるものの、満足する代用乳を得ることは難しい。   The milk substitute of the present invention can be produced by subjecting the milk powder composition containing the above-mentioned powdered fats and oils to fluidized bed granulation with a fluidized bed granulation dryer or the like. In addition, the method of adding fats and oils after granulating the milk substitute material excluding powdered fats and oils by the fluidized bed granulation method in advance, the improvement of the churn phenomenon etc. compared with the milk substitutes obtained by the conventionally known methods Although accepted, it is difficult to obtain a satisfactory milk substitute.

代用乳粉末組成物には、粉末油脂の他、例えば脱脂粉乳、全脂粉乳等の粉乳類やホエー蛋白質濃縮物(WPC)、乾燥ホエー等のホエー類等の乳成分;大豆ミール、濃縮大豆蛋白質、小麦蛋白、カゼイン、グルテン等の蛋白質又はその変性物並びにこれらの加水分解物;糖質、ビタミン、ミネラル、調味料、香辛料等の粉体原料を配合することができる。これらのうち、特に粉乳類やホエー類等の乳成分の1種又は2種以上を主成分として用いるのが、栄養面や嗜好性の観点から好ましい。
粉末油脂の配合量は、安定性や消化吸収性の観点から、代用乳粉末組成物の総質量中15〜70質量%が好ましく、特に20〜60質量%が好ましい。
In the milk powder substitute composition, in addition to powdered fats and oils, milk components such as powdered milk such as skim milk powder and whole milk powder, whey protein concentrate (WPC), whey such as dried whey, etc .; soybean meal, concentrated soybean protein Proteins such as wheat protein, casein, and gluten, or modified products thereof, and hydrolysates thereof; powder materials such as sugars, vitamins, minerals, seasonings, and spices can be blended. Among these, it is particularly preferable to use one or more milk components such as milk powder and whey as a main component from the viewpoints of nutrition and palatability.
The blending amount of the powdered fat is preferably 15 to 70% by mass, particularly preferably 20 to 60% by mass, based on the total mass of the milk powder substitute composition, from the viewpoints of stability and digestibility.

流動層造粒は、80℃〜120℃の熱風で上記代用乳粉末組成物を流動させながら水を噴霧して行うのが好ましい。この流動層造粒を行う際、水に代えて乳化剤溶液又はデキストリン等を含む粘結剤溶液を噴霧することもできる。
噴霧する水等の総量は、代用乳粉末組成物の総質量に対して、3〜20質量%が好ましく、特に5〜15質量%が好ましい。
The fluidized bed granulation is preferably carried out by spraying water while the above milk powder composition is fluidized with hot air at 80 ° C to 120 ° C. When performing the fluidized bed granulation, a binder solution containing an emulsifier solution or dextrin may be sprayed instead of water.
3-20 mass% is preferable with respect to the total mass of a milk powder substitute composition, and, as for total amount, such as water to spray, 5-15 mass% is especially preferable.

また、容器の容壁への付着防止、水又は温水への分散・溶解性の向上、消泡効果の観点から、流動層造粒の乾燥工程直前に、さらに乳化剤溶液を噴霧するのが好ましい。乳化剤溶液を噴霧する他の効果として乳化剤の使用量の削減等の効果も有する。
乳化剤溶液は、上記と同様の乳化剤を1〜50質量%含有させたものを、代用乳粉末組成物の総質量に対して、乳化剤として0.01〜2質量%、特に0.1〜1質量%噴霧するのが好ましい。
Moreover, it is preferable to spray an emulsifier solution immediately before the drying step of fluidized bed granulation from the viewpoint of preventing adhesion to the container wall, improving dispersion / solubility in water or warm water, and defoaming effect. As another effect of spraying the emulsifier solution, it also has an effect of reducing the amount of emulsifier used.
The emulsifier solution contains 1 to 50% by mass of the same emulsifier as described above, 0.01 to 2% by mass, especially 0.1 to 1% by mass as an emulsifier, based on the total mass of the milk powder substitute composition. % Spraying is preferred.

かくして得られる本発明の代用乳は、目開き105μm〜850μmの篩網を使用し、エアジェットシーブ(エアジェットシーブ200LS−N:ホソカワミクロン(株)製)で篩った時の通過重量百分率により算出された50%メジアン径が約190μmであり、サラサラとした顆粒状を呈している。   The milk replacer of the present invention thus obtained is calculated based on the percentage by weight passed when sieving with an air jet sieve (Air Jet sieve 200LS-N: manufactured by Hosokawa Micron Co., Ltd.) using a sieve mesh having an opening of 105 μm to 850 μm. The 50% median diameter is about 190 μm, and it has a smooth granular shape.

本発明の代用乳を給与する家畜の種類は特に限定されず、例えば子牛、子豚、子山羊、子馬等の幼畜類;子犬、子猫等のその他の幼動物を挙げることができ、特に幼畜類に好適である。   The type of livestock to which the milk replacer of the present invention is fed is not particularly limited, and examples thereof include larvae such as calves, piglets, goats, and foals; and other cubs such as puppies and kittens. Suitable for larvae.

実施例1
60℃の温水50質量部、60℃に加温したパームオレイン油−パーム核油混合油(上昇融点16.2℃)26.1質量部、ソルビタン脂肪酸エステルとショ糖脂肪酸エステル各々0.075質量部、レシチン0.05質量部、及び脱脂粉乳23.7質量部からなる混合乳化液を調製し、得られた混合乳化液を高圧ホモジナイザー(PANDA−2K型ホモジナイザー;NIRO SOAVI社製)によって均質化処理を行った。次いで均質化処理した混合乳化液をスプレードライヤー(FOC−20型スプレードライヤー;大川原化工機(株)製)によって140℃の熱風で噴霧乾燥して粉末油脂を調製した。
Example 1
50 parts by mass of hot water at 60 ° C., 26.1 parts by mass of palm olein oil-palm kernel oil mixture (rising melting point: 16.2 ° C.) heated to 60 ° C., 0.075 parts by mass for each of sorbitan fatty acid ester and sucrose fatty acid ester Part, lecithin 0.05 part by mass, and skim milk powder 23.7 parts by mass are prepared, and the resulting emulsion is homogenized with a high-pressure homogenizer (PANDA-2K type homogenizer; manufactured by NIRO SOAVI). Processed. Next, the homogenized mixed emulsion was spray-dried with hot air at 140 ° C. using a spray dryer (FOC-20 type spray dryer; manufactured by Okawahara Chemical Co., Ltd.) to prepare a powdered oil.

実施例2
実施例1で得られた粉末油脂46.0質量部、脱脂粉乳28.8質量部、濃縮ホエー2
0.0質量部、乾燥ホエー1.5質量部、及びビタミン・ミネラル類3.7質量部を攪拌混合機で均一になるまで混合して代用乳粉末組成物を調製した。
得られた代用乳粉末組成物100質量部を流動層造粒機(商品名「ミクスグラード」;株式会社大川原製作所製)に投入し、100℃の熱風で代用乳粉末組成物を流動させながら、60℃の温水を0.034質量部/秒の噴霧速度で噴霧し造粒した。噴霧した温水の総量は10質量部であり、代用乳粉末組成物の重量に対して10質量%となるまで噴霧した。温水の噴霧終了後、さらに5分間乾燥した後、流動層造粒機から取り出し代用乳を調製した。
Example 2
46.0 parts by weight of powdered oil obtained in Example 1, 28.8 parts by weight of skim milk powder, concentrated whey 2
A substitute milk powder composition was prepared by mixing 0.0 part by weight, 1.5 parts by weight of dry whey, and 3.7 parts by weight of vitamins and minerals with a stirring mixer until uniform.
100 parts by mass of the obtained milk powder composition was put into a fluidized bed granulator (trade name “Mixgrad” manufactured by Okawara Seisakusho Co., Ltd.), and the milk powder composition was made to flow with hot air at 100 ° C. 60 ° C. warm water was sprayed at a spray rate of 0.034 parts by mass / second and granulated. The total amount of sprayed warm water was 10 parts by mass, and sprayed until the mass of the milk powder composition was 10% by mass. After completion of spraying of warm water, it was further dried for 5 minutes, and then taken out from the fluidized bed granulator to prepare milk substitute.

実施例3
実施例1で得られた粉末油脂46.0質量部、脱脂粉乳28.8質量部、濃縮ホエー2
0.0質量部、乾燥ホエー1.5質量部、及びビタミン・ミネラル類3.7質量部を攪拌混合機で均一になるまで混合して代用乳粉末組成物を調製した。
得られた代用乳粉末組成物100質量部を流動層造粒機(商品名「ミクスグラード」;株式会社大川原製作所製)に投入し、100℃の熱風で代用乳粉末組成物を流動させながら、60℃の温水を0.034質量部/秒の噴霧速度で噴霧し造粒した。噴霧した温水の総量は10質量部で、代用乳粉末組成物の重量に対して10質量%となるまで噴霧した。温水の噴霧終了後、温水に代えて乳化剤(グリセリン脂肪酸エステル)溶液を乳化剤として代用乳粉末組成物の重量に対して0.5質量%となるように0.024質量部/秒の噴霧速度で噴霧した。乳化剤の噴霧終了後、さらに5分間乾燥した後、流動層造粒機から取り出し、代用乳を調製した。
Example 3
46.0 parts by weight of powdered oil obtained in Example 1, 28.8 parts by weight of skim milk powder, concentrated whey 2
A substitute milk powder composition was prepared by mixing 0.0 part by weight, 1.5 parts by weight of dry whey, and 3.7 parts by weight of vitamins and minerals with a stirring mixer until uniform.
100 parts by mass of the obtained milk powder composition was put into a fluidized bed granulator (trade name “Mixgrad” manufactured by Okawara Seisakusho Co., Ltd.), and the milk powder composition was made to flow with hot air at 100 ° C. 60 ° C. warm water was sprayed at a spray rate of 0.034 parts by mass / second and granulated. The total amount of sprayed hot water was 10 parts by mass, and sprayed until the mass of the milk powder composition was 10% by mass. After the spraying of warm water, instead of warm water, an emulsifier (glycerin fatty acid ester) solution is used as an emulsifier at a spray rate of 0.024 parts by mass / second so as to be 0.5% by weight with respect to the weight of the milk powder composition. Sprayed. After the spraying of the emulsifier, the mixture was further dried for 5 minutes and then taken out from the fluidized bed granulator to prepare a milk substitute.

実施例4
60℃の温水50質量部、60℃に加温したパームオレイン油−パーム核油−中鎖脂肪酸トリグリセライド混合油(上昇融点10℃)26.1質量部、ソルビタン脂肪酸エステルとショ糖脂肪酸エステル各々0.075質量部、レシチン0.05質量部、及び脱脂粉乳23.7質量部からなる混合乳化液を調製し、得られた混合乳化液を高圧ホモジナイザー(PANDA−2K型ホモジナイザー;NIRO SOAVI社製)によって均質化処理を行った。次いで均質化処理した混合乳化液をスプレードライヤー(FOC−20型スプレードライヤー;大川原化工機(株)製)によって140℃の熱風で噴霧乾燥して粉末油脂を調製した。
Example 4
50 parts by mass of warm water at 60 ° C., 26.1 parts by mass of palm olein oil-palm kernel oil-medium chain fatty acid triglyceride mixed oil (rising melting point 10 ° C.) heated to 60 ° C., 0 each for sorbitan fatty acid ester and sucrose fatty acid ester A mixed emulsion consisting of 0.075 parts by mass, lecithin 0.05 parts by mass and skim milk powder 23.7 parts by mass was prepared, and the resulting mixed emulsion was a high-pressure homogenizer (PANDA-2K type homogenizer; manufactured by NIRO SOAVI). The homogenization process was performed. Next, the homogenized mixed emulsion was spray-dried with hot air at 140 ° C. using a spray dryer (FOC-20 type spray dryer; manufactured by Okawahara Chemical Co., Ltd.) to prepare a powdered oil.

実施例5
60℃の温水50質量部、60℃に加温したパームオレイン油−パーム核油混合油(上昇融点20℃)26.1質量部、ソルビタン脂肪酸エステルとショ糖脂肪酸エステル各々0.075質量部、レシチン0.05質量部、及び脱脂粉乳23.7質量部からなる混合乳化液を調製し、得られた混合乳化液を高圧ホモジナイザー(PANDA−2K型ホモジナイザー;NIRO SOAVI社製)によって均質化処理を行った。次いで均質化処理した混合乳化液をスプレードライヤー(FOC−20型スプレードライヤー;大川原化工機(株)製)によって140℃の熱風で噴霧乾燥して粉末油脂を調製した。
Example 5
50 parts by weight of warm water of 60 ° C., 26.1 parts by weight of palm olein oil-palm kernel oil mixed oil (rising melting point 20 ° C.) heated to 60 ° C., 0.075 parts by weight of sorbitan fatty acid ester and sucrose fatty acid ester, A mixed emulsion comprising 0.05 part by weight of lecithin and 23.7 parts by weight of skim milk powder was prepared, and the resulting mixed emulsion was homogenized by a high pressure homogenizer (PANDA-2K type homogenizer; manufactured by NIRO SOAVI). went. Next, the homogenized mixed emulsion was spray-dried with hot air at 140 ° C. using a spray dryer (FOC-20 type spray dryer; manufactured by Okawahara Chemical Co., Ltd.) to prepare a powdered oil.

実施例6
実施例2において用いた粉末油脂に代えて実施例4で調製した粉末油脂を用いた以外実施例2と同様にして代用乳を調製した。
Example 6
A milk replacer was prepared in the same manner as in Example 2 except that the powdered fat prepared in Example 4 was used instead of the powdered fat used in Example 2.

実施例7
実施例2において用いた粉末油脂に代えて実施例5で調製した粉末油脂を用いた以外実施例2と同様にして代用乳を調製した。
Example 7
A milk replacer was prepared in the same manner as in Example 2 except that the powdered fat / oil prepared in Example 5 was used instead of the powdered fat / oil used in Example 2.

比較例1
60℃の温水50質量部、60℃に加温したパーム油−パーム核油混合油(上昇融点29.4℃)26.1質量部、ソルビタン脂肪酸エステルとショ糖脂肪酸エステル各々0.075質量部、レシチン0.05質量部、及び脱脂粉乳23.7質量部からなる混合乳化液を調製し、得られた混合乳化液を高圧ホモジナイザー(PANDA−2K型ホモジナイザー;NIRO SOAVI社製)によって均質化処理を行った。次いで均質化処理した混合乳化液をスプレードライヤー(FOC−20型スプレードライヤー;大川原化工機(株)製)によって140℃の熱風で噴霧乾燥して粉末油脂を調製した。
Comparative Example 1
50 parts by weight of warm water of 60 ° C., 26.1 parts by weight of palm oil-palm kernel oil mixture (rising melting point 29.4 ° C.) heated to 60 ° C., 0.075 parts by weight of sorbitan fatty acid ester and sucrose fatty acid ester, respectively A mixed emulsion comprising 0.05 part by weight of lecithin and 23.7 parts by weight of skim milk powder was prepared, and the resulting mixed emulsion was homogenized by a high-pressure homogenizer (PANDA-2K type homogenizer; manufactured by NIRO SOAVI). Went. Next, the homogenized mixed emulsion was spray-dried with hot air at 140 ° C. using a spray dryer (FOC-20 type spray dryer; manufactured by Okawahara Chemical Co., Ltd.) to prepare a powdered oil.

比較例2
比較例1で得られた粉末油脂46.0質量部、脱脂粉乳28.8質量部、濃縮ホエー20.0質量部、乾燥ホエー1.5質量部、及びビタミン・ミネラル類3.7質量部を攪拌混合機で均一になるまで混合して代用乳粉末組成物を調製した。
得られた代用乳粉末組成物100質量部を流動層造粒機(商品名「ミクスグラード」;株式会社大川原製作所製)に投入し、100℃の熱風で代用乳粉末組成物を流動させながら、60℃の温水を0.034質量部/秒の噴霧速度で噴霧し造粒した。噴霧した温水の総量は10質量部で、代用乳粉末組成物の重量に対して10質量%となるまで噴霧した。温水の噴霧終了後、さらに5分間乾燥した後、流動層造粒機から取り出し、代用乳を調製した。
Comparative Example 2
46.0 parts by mass of powdered fats and oils obtained in Comparative Example 1, 28.8 parts by mass of skim milk powder, 20.0 parts by mass of concentrated whey, 1.5 parts by mass of dried whey, and 3.7 parts by mass of vitamins and minerals The milk powder substitute composition was prepared by mixing with a stirring mixer until uniform.
100 parts by mass of the obtained milk powder composition was put into a fluidized bed granulator (trade name “Mixgrad” manufactured by Okawara Seisakusho Co., Ltd.), and the milk powder composition was made to flow with hot air at 100 ° C. 60 ° C. warm water was sprayed at a spray rate of 0.034 parts by mass / second and granulated. The total amount of sprayed hot water was 10 parts by mass, and sprayed until the mass of the milk powder composition was 10% by mass. After completion of spraying of hot water, the mixture was further dried for 5 minutes and then taken out from the fluidized bed granulator to prepare a milk substitute.

比較例3
比較例1で調製した粉末油脂46.0質量部、脱脂粉乳28.8質量部、濃縮ホエー20.0質量部、乾燥ホエー1.5質量部、及びビタミン・ミネラル類3.7質量部を攪拌混合機で均一になるまで混合して代用乳を調製した。
Comparative Example 3
46.0 parts by weight of powdered fats and oils prepared in Comparative Example 1, 28.8 parts by weight of skim milk powder, 20.0 parts by weight of concentrated whey, 1.5 parts by weight of dried whey, and 3.7 parts by weight of vitamins and minerals A milk replacer was prepared by mixing with a mixer until uniform.

試験例1
ミニ洗濯機(商品名Mini Mini Washer NA-33;National社製)に41℃の温水1Lを入れ、これに実施例3で調製した代用乳150gと、比較例2で調製した代用乳150gを各別に加えてそれぞれ1分間攪拌した後の分散・溶解状態を肉眼で評価確認した。
その結果、実施例3で調製した代用乳は分散・溶解し、チャーニング現象は認められなかったが、比較例2で調製した代用乳はチャーニング現象が生じ製品としては不適当であった。
Test example 1
Into a mini washing machine (trade name: Mini Mini Washer NA-33; manufactured by National), 1 L of warm water of 41 ° C. was added, and 150 g of the milk substitute prepared in Example 3 and 150 g of milk substitute prepared in Comparative Example 2 were each added. In addition to this, the dispersion and dissolution state after stirring for 1 minute each was evaluated and confirmed with the naked eye.
As a result, the milk replacer prepared in Example 3 was dispersed and dissolved, and no churning phenomenon was observed. However, the milk replacer prepared in Comparative Example 2 caused a churning phenomenon and was not suitable as a product.

試験例2
100Lのポリバケツに41℃の温水50Lを入れ、これに実施例3で調製した代用乳7kgと、比較例2で調製した代用乳7kgを各別に投入し、泡立て器(スーパー泡立て機#30)を用いてそれぞれ30秒間手攪拌(約60回転)を行った後の分散・溶解状態を調べた。
その結果、実施例3で調製した代用乳は分散・溶解し、チャーニング現象は認められなかったが、比較例2で調製した代用乳はチャーニング現象が生じ製品としては不適当であった。
Test example 2
Put 100 L of warm water of 41 ° C. in a 100 L plastic bucket, put 7 kg of milk substitute prepared in Example 3 and 7 kg of milk substitute prepared in Comparative Example 2 separately, and add a whisk (Super Whisk # 30) The dispersion / dissolved state after 30 minutes of manual stirring (about 60 revolutions) was used.
As a result, the milk replacer prepared in Example 3 was dispersed and dissolved, and no churning phenomenon was observed. However, the milk replacer prepared in Comparative Example 2 caused a churning phenomenon and was not suitable as a product.

試験例3
実施例1で調製した粉末油脂1kgと、比較例1で調製した粉末油脂1kgを、41℃の温水7Lの入ったビーカーに各別に入れ、それぞれ泡立て器を用いて手攪拌を行い投入後から分散・溶解する迄の時間を測定した。
その試験結果を示せば表1のとおりである。
Test example 3
1 kg of the powdered fats and oils prepared in Example 1 and 1 kg of the powdered fats and oils prepared in Comparative Example 1 were separately put into beakers containing 7 L of warm water of 41 ° C., and each was manually stirred using a whisk to disperse after charging. -The time until dissolution was measured.
The test results are shown in Table 1.

Figure 2012210230
Figure 2012210230

試験例4
実施例3で調製した代用乳1000質量部と、比較例3で調製した代用乳1000質量部を、ビーカーに入れた41℃の温水7000質量部に各別に投入し、それぞれ手攪拌により5秒間で9回転の速度で正・逆の攪拌を行い、溶解残渣が手に当たらなくなるまでの分散・溶解時間を比較したところ、実施例3の代用乳が比較例3の代用乳に対し明らかに短時間で分散・溶解した。このことから、流動層で造粒した代用乳は、温水への分散・溶解性が極めて良好であることが確認された。
Test example 4
1000 parts by weight of the milk replacer prepared in Example 3 and 1000 parts by weight of the milk replacer prepared in Comparative Example 3 were separately added to 7000 parts by weight of 41 ° C. warm water in a beaker, and each was manually stirred for 5 seconds. When the forward / reverse stirring was performed at a speed of 9 revolutions and the dispersion / dissolution time until the dissolved residue did not reach the hands was compared, the milk substitute in Example 3 was clearly shorter than the milk substitute in Comparative Example 3. Dispersed and dissolved. From this, it was confirmed that the milk replacer granulated in the fluidized bed has extremely good dispersion and solubility in warm water.

試験例5
実施例2で調製した代用乳3質量部と、実施例3で調製した代用乳3質量部と、比較例2で調製した代用乳3質量部を、ビーカーに入れた41℃の温水300質量部に各別に入れ、それぞれ完全に温水に沈み込むまでの時間を比較したところ、実施例2及び実施例3の代用乳は明らかに比較例2の代用乳に比べて短い時間で沈み込み、実施例2の代用乳と比較して実施例3の代用乳はさらに短い時間で沈み込むことが確認された。その結果を示せば、表2のとおりである。
Test Example 5
3 parts by weight of milk replacer prepared in Example 2, 3 parts by weight of milk replacer prepared in Example 3, and 3 parts by weight of milk replacer prepared in Comparative Example 2 300 parts by weight of 41 ° C. hot water in a beaker In each case, the time required to completely submerge in warm water was compared. The milk substitutes of Example 2 and Example 3 were clearly submerged in a shorter time than the milk substitute of Comparative Example 2, and Example It was confirmed that the milk substitute of Example 3 sinks in a shorter time compared to the milk substitute of No. 2. The results are shown in Table 2.

Figure 2012210230
Figure 2012210230

このことから、実施例1の粉末油脂(上昇融点16.2℃)を使用して得られた実施例2の代用乳は、比較例1の粉末油脂(上昇融点29.4℃)を使用して得られた比較例2の代用乳と比べて分散・溶解性が良好であることが確認された。また、実施例1の粉末油脂(上昇融点16.2℃)を使用して得られた実施例2の代用乳に、さらに乳化剤溶液を噴霧する工程を追加した実施例3の代用乳は、実施例2の代用乳と比べてさらに分散・溶解性が良好であることが確認された。
また、実施例6及び7で調製した代用乳を用いて、上記と同様に試験を行った結果、実施例3の代用乳とほぼ同様の試験結果が得られた。さらに、実施例3において用いた粉末油脂に代えて、上昇融点15℃と上昇融点19℃の植物性油脂を含有する粉末油脂を用いた代用乳について試験した結果、それぞれ実施例3の代用乳とほぼ同様の試験結果が得られた。
Therefore, the substitute milk of Example 2 obtained by using the powdered fats and oils of Example 1 (rising melting point 16.2 ° C.) uses the powdered fats and oils of Comparative Example 1 (rising melting point 29.4 ° C.). It was confirmed that the dispersibility and solubility were good as compared with the milk substitute of Comparative Example 2 obtained in the above. In addition, the milk substitute of Example 3 in which a step of spraying an emulsifier solution was further added to the milk substitute of Example 2 obtained using the powdered fats and oils of Example 1 (rising melting point 16.2 ° C.) was carried out. Compared with the milk substitute of Example 2, it was confirmed that the dispersibility and solubility were even better.
Moreover, as a result of performing the test in the same manner as described above using the milk substitutes prepared in Examples 6 and 7, the test results almost the same as those of the milk substitute in Example 3 were obtained. Furthermore, instead of the powdered fats and oils used in Example 3, as a result of testing on milk substitutes containing powdered oils and fats having a rising melting point of 15 ° C. and a rising melting point of 19 ° C., the milk substitutes of Example 3 and Almost similar test results were obtained.

試験例6
実施例3で得られた代用乳50質量部を41℃の温水350質量部に溶解して油脂含有率3%の代用乳溶液を調製した。この代用乳溶液の脂肪球サイズの球径をレーザー回折式粒度分布測定装置(SHIMADZUSALD−200V)を用いて測定したところ、最も大きいもので10μmであり、ほとんどの脂肪球が0.6〜10μmの範囲で、中心径が約2μmであった。このことから流動層で造粒した後、乳化剤溶液を噴霧した代用乳を水や温水に分散・溶解した場合にも脂肪球サイズが小さくなることが確認された。
Test Example 6
50 parts by mass of the milk substitute obtained in Example 3 was dissolved in 350 parts by mass of warm water at 41 ° C. to prepare a milk substitute solution with a fat content of 3%. The fat sphere size of this milk substitute solution was measured using a laser diffraction particle size distribution analyzer (SHIMADZUSALD-200V). The largest one was 10 μm, and most fat globules were 0.6 to 10 μm. In the range, the central diameter was about 2 μm. From this, it was confirmed that the fat globule size was reduced even when the milk replacer sprayed with the emulsifier solution was dispersed and dissolved in water or warm water after granulation in a fluidized bed.

試験例7
実施例3で得られた代用乳50質量部に、分離する油層を着色するための赤色色素0.01質量部を均一に混合した後、得られた混合物25質量部を50℃の温水180質量部に3分間攪拌溶解して油脂含有率3%の代用乳液を調製した。その代用乳液100質量部を100容量部メスシリンダーに入れ、50℃の乾燥機に30分放置した後、油脂分離状況を確認したところ、ほとんど分離は確認されなかった。このことから、流動層で造粒した後、乳化剤を添加した代用乳を温水に分散・溶解した場合にも、乳化安定性が良好であることが確認された。
Test Example 7
After 50 parts by mass of the milk substitute obtained in Example 3 is uniformly mixed with 0.01 part by mass of a red pigment for coloring the oil layer to be separated, 25 parts by mass of the resulting mixture is mixed with 180 parts by mass of hot water at 50 ° C. The mixture was stirred and dissolved for 3 minutes to prepare a milky milk substitute having a fat content of 3%. When 100 parts by mass of the milky substitute was placed in a 100-volume graduated cylinder and allowed to stand in a dryer at 50 ° C. for 30 minutes, the state of oil separation was confirmed. Almost no separation was confirmed. From this, it was confirmed that the emulsion stability was good even when the milk replacer to which the emulsifier was added was dispersed and dissolved in warm water after granulation in a fluidized bed.

試験例8
実施例3で得られた代用乳20kgを包装用紙袋に入れ、その上に20kgの製品9段を積み上げて加重をかけ、40℃、75%RHの恒温恒湿に保った部屋に1週間保管した後、最下段の紙袋を静かに開封し、代用乳の固結状況を確認したところ、全く固結は見られず、サラサラした顆粒の状態を保持していた。
Test Example 8
20 kg of milk substitute obtained in Example 3 is put in a wrapping paper bag, 9 kg of products of 20 kg are stacked on top of each other, weighted, and stored in a room kept at a constant temperature and humidity of 40 ° C. and 75% RH for 1 week. After that, the lowermost paper bag was gently opened, and the state of consolidation of the milk substitute was confirmed. As a result, no solidification was observed, and the state of the smooth granule was maintained.

実施例8
精製度の異なるパームオレイン油を使用して上昇融点が19℃になるようにパームオレイン油−パーム核油脂混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パームオレイン油−パーム核油脂混合油(上昇融点19℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Example 8
Palm olein oil-palm kernel fat mixed oil was prepared using palm olein oil having different degrees of purification so that the rising melting point was 19 ° C.
Next, in place of the palm olein oil-palm kernel oil / fat mixed oil (increased melting point 16.2 ° C.) used in Example 1, the palm olein oil-palm kernel oil / fat mixed oil (increased melting point 19 ° C.) was used. In the same manner as in No. 1, powdered fats and oils were prepared.

実施例9
パーム油とパームオレイン油を使用して上昇融点が20℃になるようにパーム油−パームオレイン油脂混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パーム油−パームオレイン油脂混合油(上昇融点20℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Example 9
A palm oil-palm olein oil / fat mixture was prepared using palm oil and palm olein oil so that the rising melting point was 20 ° C.
Next, in place of the palm olein oil-palm kernel oil / fat mixed oil (increased melting point 16.2 ° C.) used in Example 1, the palm oil-palm olein oil / fat mixed oil (increased melting point 20 ° C.) was used. A powdered oil was prepared in the same manner as above.

比較例4
パーム油とパームオレイン油を使用して上昇融点が21℃になるようにパーム油−パームオレイン油脂混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パーム油−パームオレイン油脂混合油(上昇融点21℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Comparative Example 4
A palm oil-palm olein oil / fat mixed oil was prepared using palm oil and palm olein oil so that the rising melting point was 21 ° C.
Next, in place of the palm olein oil-palm kernel oil / fat mixed oil (increased melting point 16.2 ° C.) used in Example 1, the palm oil-palm olein oil / fat mixed oil (increased melting point 21 ° C.) was used. In the same manner as above, powdered fats and oils were prepared.

実施例10
実施例2において用いた粉末油脂に代えて実施例8で調製した粉末油脂を用いた以外実施例2と同様にして代用乳を調製した。
Example 10
A milk replacer was prepared in the same manner as in Example 2 except that the powdered fat prepared in Example 8 was used instead of the powdered fat used in Example 2.

実施例11
実施例2において用いた粉末油脂に代えて実施例9で調製した粉末油脂を用いた以外実施例2と同様にして代用乳を調整した。
Example 11
Substitute milk was prepared in the same manner as in Example 2 except that the powdered fat / oil prepared in Example 9 was used instead of the powdered fat / oil used in Example 2.

比較例5
実施例2において用いた粉末油脂に代えて比較例4で調製した粉末油脂を用いた以外実施例2と同様にして代用乳を調整した。
Comparative Example 5
Substitute milk was prepared in the same manner as in Example 2 except that the powdered fats and oils prepared in Comparative Example 4 were used instead of the powdered fats and oils used in Example 2.

試験例9
試験例1において用いた代用乳に代えて実施例10で調製した代用乳、実施例11で調製した代用乳、比較例5で調製した代用乳を各別用い、また攪拌時間を15分とした以外試験例1と同様にして分散・溶解状態を評価確認した。
そのチャーニング現象の評価基準及び試験結果を示せば表3のとおりである。
Test Example 9
Instead of the milk replacer used in Test Example 1, the milk replacer prepared in Example 10, the milk replacer prepared in Example 11 and the milk replacer prepared in Comparative Example 5 were used separately, and the stirring time was 15 minutes. In the same manner as in Test Example 1 except for the above, the dispersion / dissolution state was evaluated and confirmed.
Table 3 shows the evaluation criteria and test results of the churning phenomenon.

Figure 2012210230
Figure 2012210230

表3から明らかな如く、実施例10及び実施例11で調製した代用乳は、15分間攪拌という過酷な条件において分散・溶解し、チャーニング現象がほとんど又は全く認められなかったが、比較例5で調製した代用乳はチャーニング現象が生じ製品としては不適当であった。
このことから、チャーニング現象が生じない代用乳を製造するためには、植物性油脂の上昇融点は少なくとも20℃以下である必要があり、好ましくは19℃以下であることが確認された。
As is apparent from Table 3, the milk substitutes prepared in Example 10 and Example 11 were dispersed and dissolved under the harsh conditions of stirring for 15 minutes, and little or no churning phenomenon was observed. Comparative Example 5 The milk replacer prepared in (3) was not suitable as a product due to the charring phenomenon.
From this fact, it was confirmed that the rising melting point of the vegetable oil / fat must be at least 20 ° C. or less, preferably 19 ° C. or less, in order to produce a milk replacer that does not cause the charring phenomenon.

実施例12
パームオレイン油と中鎖脂肪酸トリグリセライドを使用して上昇融点が10℃になるようにパームオレイン油−中鎖脂肪酸トリグリセライド混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パームオレイン油−中鎖脂肪酸トリグリセライド混合油(上昇融点10℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Example 12
Palm olein oil and medium chain fatty acid triglyceride mixed oil was prepared using palm olein oil and medium chain fatty acid triglyceride so that the rising melting point was 10 ° C.
Subsequently, in place of the palm olein oil-palm kernel fat / oil mixed oil (rising melting point 16.2 ° C.) used in Example 1 except that the palm olein oil-medium chain fatty acid triglyceride mixed oil (rising melting point 10 ° C.) was used. A powdered fat was prepared in the same manner as in Example 1.

実施例13
パームオレイン油と中鎖脂肪酸トリグリセライドを使用して上昇融点が15℃になるようにパームオレイン油−中鎖脂肪酸トリグリセライド混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パームオレイン油−中鎖脂肪酸トリグリセライド混合油(上昇融点15℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Example 13
Palm olein oil and medium chain fatty acid triglyceride mixed oil was prepared using palm olein oil and medium chain fatty acid triglyceride so that the rising melting point was 15 ° C.
Subsequently, in place of the palm olein oil-palm kernel fat / oil mixed oil (increased melting point 16.2 ° C.) used in Example 1, this palm olein oil-medium chain fatty acid triglyceride mixed oil (increased melting point 15 ° C.) was used. A powdered fat was prepared in the same manner as in Example 1.

実施例14
精製度の異なるパームオレイン油を使用して上昇融点が16.8℃になるようにパームオレイン油−パーム核油脂混合油を調製した。
次いで実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パームオレイン油−パーム核油脂混合油(上昇融点16.8℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Example 14
Palm olein oil-palm kernel fat mixed oil was prepared using palm olein oils having different purification degrees so that the rising melting point was 16.8 ° C.
Subsequently, in place of the palm olein oil-palm kernel oil / fat mixed oil (increased melting point 16.2 ° C.) used in Example 1, this palm olein oil-palm kernel oil / fat mixed oil (increased melting point 16.8 ° C.) was used. A powdered fat was prepared in the same manner as in Example 1.

比較例6
パームオレイン油と中鎖脂肪酸トリグリセライドを使用して上昇融点が5℃になるようにパームオレイン油−中鎖脂肪酸トリグリセライド混合油を調製した。
次いで、実施例1において用いたパームオレイン油−パーム核油脂混合油(上昇融点16.2℃)に代えて当該パームオレイン油−中鎖脂肪酸トリグリセライド混合油(上昇融点5℃)を用いた以外実施例1と同様にして粉末油脂を調製した。
Comparative Example 6
Palm olein oil and medium chain fatty acid triglyceride mixed oil was prepared using palm olein oil and medium chain fatty acid triglyceride so that the rising melting point was 5 ° C.
Subsequently, in place of the palm olein oil-palm kernel fat / oil mixed oil (increased melting point 16.2 ° C.) used in Example 1, this palm olein oil-medium chain fatty acid triglyceride mixed oil (increased melting point 5 ° C.) was used. A powdered fat was prepared in the same manner as in Example 1.

試験例10
実施例12で調製した粉末油脂5gと、実施例13で調製した粉末油脂5gと、実施例14で調製した粉末油脂5gと、比較例6で調製した粉末油脂5gを各別のろ紙(直径110mm、NO.5A:東洋濾紙株式会社製)上に直径約70mm程度の円形に広げ、それぞれ5kgで5分間、20kgで2分間室温で加圧し、100℃の乾燥機に1時間保管した後、ろ紙上の粉末油脂を取り除き、ろ紙に滲み出した油脂のろ紙全体に占める面積を評価確認した。
その評価基準及び試験結果を示せば表4のとおりである。
Test Example 10
5 g of the powdered fats and oils prepared in Example 12, 5 g of the powdered fats and oils prepared in Example 13, 5 g of the powdered fats and oils prepared in Example 14, and 5 g of the powdered fats and oils prepared in Comparative Example 6 (each with a diameter of 110 mm) , NO.5A: manufactured by Toyo Filter Paper Co., Ltd.), spread in a circle with a diameter of about 70 mm, pressurized at 5 kg for 5 minutes and 20 kg for 2 minutes at room temperature, stored in a dryer at 100 ° C. for 1 hour, and then filtered. The above powdered fats and oils were removed, and the area occupied by the fats and oils that exuded on the filter paper in the entire filter paper was evaluated and confirmed.
The evaluation criteria and test results are shown in Table 4.

Figure 2012210230
Figure 2012210230

表4から明らかな如く、実施例12で調製した粉末油脂はろ紙面積の40%未満の滲み出しが認められ、実施例13及び14で調製した粉末油脂は全く滲み出しが認められなかったが、比較例6で調製した粉末油脂は、ろ紙全体に滲み出しが認められた。
このことから、植物性油脂の融点が低くなるにつれ、油脂のコーティングが十分に行なわれなくなり、粉末油脂の安定性が悪くなることが判明したので、保管安定性に優れ、実用に耐えうる粉末油脂を製造するためには、植物性油脂の上昇融点は少なくとも10℃以上である必要があり、好ましくは15℃以上であることが確認された。
As is clear from Table 4, the powdered fats and oils prepared in Example 12 were found to exude less than 40% of the filter paper area, and the powdered oils and fats prepared in Examples 13 and 14 were not exuded at all. The powdered oil prepared in Comparative Example 6 oozed out throughout the filter paper.
From this, it became clear that as the melting point of vegetable fats and oils became lower, the coating of fats and oils was not sufficiently performed, and the stability of powdered fats and oils became worse. In order to produce, the rising melting point of the vegetable oil / fat needs to be at least 10 ° C. or higher, preferably 15 ° C. or higher.

以上の結果から、チャーニング現象を生じることなく水や温水に分散・溶解し、乳化安定性に優れ、且つ保管中も固結しない代用乳を提供するためには、植物性油脂の上昇融点は10〜20℃である必要があり、より好ましくは15℃〜19℃であることが確認された。   From the above results, in order to provide a milk substitute that is dispersed and dissolved in water or warm water without causing a charring phenomenon, has excellent emulsification stability, and does not solidify during storage, the rising melting point of vegetable oils and fats is It was confirmed that the temperature was 10 to 20 ° C, and more preferably 15 to 19 ° C.

Claims (4)

上昇融点が10〜20℃である植物性油脂を含む粉末油脂
(但し、以下の粉末油脂を除く:
中鎖脂肪酸トリグリセライドを水溶性液体原料と混合した後、他の油脂と混合し、次いで乳化剤と混合し、得られた混合物を均質化して得られる粉末油脂;ならびに
(イ)ヨウ素価が55.0〜67.0であるパーム油を50%以上用いた植物性混合油脂、(ロ)ヤシ油、パーム核油、あるいはそれらの混合油脂の含量が50%以上である植物性混合油脂、又は(ハ)パーム油の分画混合油脂を50%以上含有し、かつパーム核油、ヤシ油、あるいはそれらの混合油脂を50%以下含有する植物性混合油脂であって、パーム核油、ヤシ油、あるいはそれらの混合油脂の含量をA%としたとき、パーム油の分画混合油脂のヨウ素価が(55.0−0.05A)〜55.0となる植物性混合油脂からなる油脂を油脂成分として含有する粉末油脂)。
Powdered fats and oils containing vegetable fats and oils having an ascending melting point of 10 to 20 ° C. (excluding the following powdered fats and oils:
After mixing the medium chain fatty acid triglyceride with the water-soluble liquid raw material, it is mixed with other fats and oils, then mixed with an emulsifier, and the resulting mixture is homogenized to obtain powdered fats and oils; and (i) iodine value of 55.0 Vegetable oils and fats using 50% or more of palm oil of ˜67.0, (b) vegetable oils and fats whose content of palm oil, palm kernel oil, or oils and fats thereof is 50% or more, or (c ) A vegetable oil mixture containing 50% or more of a palm oil fractionated mixed oil and fat and containing 50% or less of palm kernel oil, coconut oil, or a mixed oil or fat thereof, wherein the palm kernel oil, coconut oil, or When the content of these mixed fats and oils is A%, the fats and oils which consist of vegetable mixed fats and oils whose palm oil fraction mixing fats and oils become (55.0-0.05A)-55.0 are used as fats and oils components. Contains powdered fats and oils) .
植物性油脂が、パームヤシ由来の油脂、ヤシ油及びそれらの分画油並びに中鎖脂肪酸トリグリセライドから選ばれる少なくとも1種の油脂である請求項1記載の粉末油脂。   The powdered oil according to claim 1, wherein the vegetable oil is at least one oil selected from oil and fat derived from palm palm, coconut oil and fractionated oils thereof, and medium-chain fatty acid triglycerides. 請求項1又は2記載の粉末油脂を含有することを特徴とする代用乳。   A milk replacer comprising the powdered fat according to claim 1 or 2. 請求項1又は2記載の粉末油脂を含有する代用乳粉末組成物を流動層造粒することを特徴とする代用乳の製造方法。   A method for producing milk substitute, comprising fluidized bed granulating the milk powder composition containing powdered fat according to claim 1 or 2.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019062748A (en) * 2017-09-28 2019-04-25 第一工業製薬株式会社 Substitute milk composition

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50135254A (en) * 1974-04-16 1975-10-27
JPS57159896A (en) * 1981-03-27 1982-10-02 Sankyo Shiyokuhin Kogyo Kk Powdery vegetable oil and manufacture
JPS6174538A (en) * 1984-09-17 1986-04-16 Ajinomoto Co Inc Fats and oils for fat-containing powder
JPH0227942A (en) * 1988-07-14 1990-01-30 Kanegafuchi Chem Ind Co Ltd Oil and fat composition containing powder of volatile component
JPH05219895A (en) * 1992-02-06 1993-08-31 Kao Corp Feed composition for baby domestic animal and method for raising baby domestic animal
JPH0880134A (en) * 1994-09-14 1996-03-26 Yukijirushi Shiyubiyou Kk Substitute for milk for calf and supply of artificial milk
JPH10271951A (en) * 1997-03-31 1998-10-13 Fuji Oil Co Ltd Oil and fat composition for batter and batter for fry using the same
JP2000279092A (en) * 1999-03-31 2000-10-10 Yoshihara Oil Mill Ltd Lecithin-containing edible oil and its use
JP2004350603A (en) * 2003-05-30 2004-12-16 Fuji Oil Co Ltd Oil-in-water type polishing agent
JP2005218307A (en) * 2004-02-03 2005-08-18 Meiji Shiryo Kk Method for producing milk substitute fed to livestock
JP2006094710A (en) * 2004-09-28 2006-04-13 Natl Fedelation Of Agricult Coop Assoc Method for producing milk substitute composition for young livestock
JP2006141207A (en) * 2004-11-16 2006-06-08 Q P Corp Emulsified cooking sauce, and method for producing the same
JP2007159522A (en) * 2005-12-16 2007-06-28 Natl Fedelation Of Agricult Coop Assoc Substitute milk composition for young livestock

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50135254A (en) * 1974-04-16 1975-10-27
JPS57159896A (en) * 1981-03-27 1982-10-02 Sankyo Shiyokuhin Kogyo Kk Powdery vegetable oil and manufacture
JPS6174538A (en) * 1984-09-17 1986-04-16 Ajinomoto Co Inc Fats and oils for fat-containing powder
JPH0227942A (en) * 1988-07-14 1990-01-30 Kanegafuchi Chem Ind Co Ltd Oil and fat composition containing powder of volatile component
JPH05219895A (en) * 1992-02-06 1993-08-31 Kao Corp Feed composition for baby domestic animal and method for raising baby domestic animal
JPH0880134A (en) * 1994-09-14 1996-03-26 Yukijirushi Shiyubiyou Kk Substitute for milk for calf and supply of artificial milk
JPH10271951A (en) * 1997-03-31 1998-10-13 Fuji Oil Co Ltd Oil and fat composition for batter and batter for fry using the same
JP2000279092A (en) * 1999-03-31 2000-10-10 Yoshihara Oil Mill Ltd Lecithin-containing edible oil and its use
JP2004350603A (en) * 2003-05-30 2004-12-16 Fuji Oil Co Ltd Oil-in-water type polishing agent
JP2005218307A (en) * 2004-02-03 2005-08-18 Meiji Shiryo Kk Method for producing milk substitute fed to livestock
JP2006094710A (en) * 2004-09-28 2006-04-13 Natl Fedelation Of Agricult Coop Assoc Method for producing milk substitute composition for young livestock
JP2006141207A (en) * 2004-11-16 2006-06-08 Q P Corp Emulsified cooking sauce, and method for producing the same
JP2007159522A (en) * 2005-12-16 2007-06-28 Natl Fedelation Of Agricult Coop Assoc Substitute milk composition for young livestock

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019062748A (en) * 2017-09-28 2019-04-25 第一工業製薬株式会社 Substitute milk composition

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