JP2007159522A - Substitute milk composition for young livestock - Google Patents

Substitute milk composition for young livestock Download PDF

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JP2007159522A
JP2007159522A JP2005362916A JP2005362916A JP2007159522A JP 2007159522 A JP2007159522 A JP 2007159522A JP 2005362916 A JP2005362916 A JP 2005362916A JP 2005362916 A JP2005362916 A JP 2005362916A JP 2007159522 A JP2007159522 A JP 2007159522A
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oil
fat
mixed
palm
vegetable
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JP4693621B2 (en
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Maki Korogi
牧 興梠
Keiji Fukamachi
啓次 深町
Takeshi Akusawa
猛 阿久沢
Toshiyuki Abe
敏行 阿部
Hiromoto Ishikawa
博基 石川
Minoru Shimizu
実 清水
Kazufumi Takahashi
一史 高橋
Hiroaki Takamura
弘明 高村
Ryuji Maeda
竜治 前田
Hiroshi Tanabe
博 田辺
Michio Jinbo
通夫 神保
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KAGAKU SHIRYO KENKYUSHO KK
National Federation of Agricultural Cooperative Associations
Scientific Feed Laboratory Co Ltd
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KAGAKU SHIRYO KENKYUSHO KK
National Federation of Agricultural Cooperative Associations
Scientific Feed Laboratory Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To obtain a substitute milk composition for young livestock, using vegetable oil and fat, preventing insoluble aggregate from sticking to a nursing instrument when melting in hot water, facilitating washing instruments, and extremely excellent in meltability. <P>SOLUTION: This substitute milk composition for young livestock is obtained by using vegetable oil and fat which contains ≥50 wt.% of palm oil with an iodine value of 55.0-67.0, or vegetable mixed oil and fat which contains ≥50 wt.% of coconut oil, palm kernel oil or their mixed oil and fat, or vegetable mixed oil and fat which contains ≥50 wt.% of fractional mixed oil and fat of palm oil, and ≤50 wt.% of palm kernel oil, coconut oil, or their mixed oil and fat, and which has an iodine value of (55.0-0.05A) to 55.0 of fractional mixed oil and fat of palm oil when setting the content of palm kernel oil, coconut oil or their mixed oil and fat to (A)%. The composition prevents water insoluble aggregate from sticking to an instrument, facilitates washing instruments, and has excellent meltability. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この方法は、幼畜のための代用乳組成物の製造方法に関する。さらに詳しくは、子牛、子豚、小羊、その他の幼動物に給与される代用乳組成物に関するものであり、温水で溶解する際に難溶性の凝集物が器具に付着せず、器具洗浄が容易となる、溶解性の非常に優れた幼畜用のための代用乳組成物に関する。 This method relates to a method for producing a milk replacer composition for young animals. More specifically, it relates to a milk substitute composition to be fed to calves, piglets, lambs, and other young animals. When dissolved in warm water, hardly soluble aggregates do not adhere to the device, and the device is washed. The present invention relates to a milk replacer composition for use in juveniles having excellent solubility.

子牛、子豚、子山羊等の幼畜類の生産やその他の幼動物の飼育に当っては、母乳の代替に人工的に造られた代用乳組成物を給与して飼育することが広く行われている。
この代用乳組成物は、脱脂粉乳、乾燥ホエー、ホエー蛋白質濃縮物(WPC)等の乳成分を主原料とし、これに油脂類、糖類、穀類、ミネラル、ビタミン、抗生物質などを配合した粉末或いは顆粒状の固形物であり、実際に使用する際には、水又は温水に溶解或いは乳化分散させて給与されている。
In the production of larvae such as calves, piglets, and goats, and the breeding of other larvae, it is widely practiced to feed milk substitutes that are artificially created to replace breast milk. It has been broken.
This milk substitute composition is mainly composed of milk components such as skim milk powder, dried whey, whey protein concentrate (WPC), etc., and powders or fats, sugars, grains, minerals, vitamins, antibiotics, etc. It is a granular solid, and when actually used, it is fed after being dissolved or emulsified and dispersed in water or warm water.

この代用乳組成物は、油脂原料として30〜80%の油脂を脱脂粉乳、ホエー類、カゼイン、必要によりデキストリンやコーンシロップなどの糖質基材、乳化剤及びその他の助剤、及び安定剤などでコーティングした粉末油脂を混合する、或いは油脂以外の原料に液体油脂や乳化油脂を噴霧して製造されている。   This substitute milk composition uses 30 to 80% fat as fat raw material, skim milk powder, whey, casein, if necessary, sugar base materials such as dextrin and corn syrup, emulsifiers and other auxiliaries, and stabilizers. It is manufactured by mixing coated powdered fats or oils or spraying liquid oils or emulsified oils and fats on raw materials other than fats and oils.

このような代用乳組成物に求められる品質特性は、サラサラして流動性に優れ、保存時に固結しない、また温水に速やかに溶解することなどが挙げられるが、加えて重要なことは、代用乳組成物を温水に溶解した後の代用乳溶液が安定であり、哺乳器具に油脂などの汚れが付着しないことである。 The quality characteristics required of such a milk substitute composition are smooth and excellent in fluidity, do not solidify during storage, and dissolve quickly in warm water, but the important thing is that The milk substitute solution after dissolving the milk composition in warm water is stable, and dirt such as fats and oils does not adhere to the feeding apparatus.

しかし、従来の代用乳組成物は、液体油脂を噴霧して製造されるものの場合、水や温水に溶解したときしばしば油脂が分離したり、難溶性の浮遊物を生じることが有る。また、粉末油脂を使用して製造される代用乳組成物の場合でも、近年使用が拡大している自動哺乳機に付属するミキサーや、大型農場で代用乳を大量溶解するために用いられる大型の電動ミキサーなどを用いて強い攪拌力で溶解しようとすると、油脂が析出して難溶性の凝集物を生じ、バケツや自動哺乳機または哺乳ビンなどに付着して洗浄を著しく困難にさせる。これらの現象は、植物性油脂を使用した場合に顕著であり、特に外気温度が高い春から夏に製造あるいは保管した代用乳組成物で顕著に現れる。 However, when the conventional milk substitute composition is produced by spraying liquid fats and oils, the fats and oils are often separated when dissolved in water or warm water, or hardly soluble suspended matters may be generated. In addition, even in the case of a milk substitute composition manufactured using powdered fats and oils, a mixer attached to an automatic feeding machine that has been increasingly used in recent years, and a large-scale milk used for dissolving a large amount of milk substitute on a large farm When an electric mixer or the like is used to dissolve with a strong stirring force, fats and oils precipitate to form hardly soluble aggregates, which adhere to a bucket, an automatic baby machine, a baby bottle, or the like, making cleaning extremely difficult. These phenomena are remarkable when vegetable oils and fats are used, and are particularly noticeable in milk substitute compositions produced or stored in spring and summer when the outside air temperature is high.

このような代用乳組成物の物性上の問題に関しては、従来から様々な方法で解決が図られてきた。例えば、特許文献1(特開2005−218307)では、エステル交換した植物油脂を用いて抗固結性と溶解性ともに良好な代用乳製造方法を提案している。しかし、この文献で述べられているのはあくまで代用乳組成物の温水に対する分散溶解性であり、代用乳組成物を強攪拌した際の油脂汚れや凝集物防止についてはあまり対策がとられておらず、解決策は提示されていないのが現状である。
特開2005−218307
Such problems in physical properties of the milk substitute composition have been conventionally solved by various methods. For example, Patent Document 1 (Japanese Patent Application Laid-Open No. 2005-218307) proposes a milk substitute production method that has good anti-caking property and solubility using a transesterified vegetable oil. However, what is described in this document is only the dispersibility of the milk substitute composition in warm water, and there are not so many measures taken to prevent oil stains and aggregates when the milk substitute composition is vigorously stirred. In fact, no solution has been proposed.
JP 2005-218307 A

本発明は、植物性油脂を使用し、抗固結性や流動性が優れるとともに、温水で溶解する際に難溶性の凝集物が器具に付着せず、器具洗浄が容易となる、溶解性の非常に優れた幼畜用代用乳組成物を提供することを課題とする。   The present invention uses vegetable fats and oils, has excellent anti-caking property and fluidity, and hardly soluble aggregates do not adhere to the device when dissolved in warm water, facilitating device cleaning. It is an object of the present invention to provide a very good milk composition for larvae.

本発明者らは、上記課題を解決すべく鋭意検討の結果、油脂成分として、(イ)ヨウ素価が55.0〜67.0であるパーム油を50%以上用いた植物性混合油脂、(ロ)ヤシ油、パーム核油、あるいはそれらの混合油脂の含量が50%以上である植物性混合油脂又は(ハ)パーム油の分画混合油脂を50%以上含有し、かつパーム核油、ヤシ油、あるいはそれらの混合油脂を50%以下含有する植物性混合油脂であり、パーム核油、ヤシ油、あるいはそれらの混合油脂の含量をA%としたとき、パーム油の分画混合油脂のヨウ素価が(55.0−0.05A)〜55.0となるような植物性混合油脂の何れか1種を含有してなる幼畜用代用乳組成物が、抗固結性や流動性が優れるとともに、温水で溶解する際に難溶性の凝集物が器具に付着せず、器具洗浄が容易となる、溶解性の非常に優れた幼畜用代用乳組成物であることを見出し、これらの知見に基づいて本発明を完成した。 As a result of intensive studies to solve the above-mentioned problems, the present inventors, as an oil and fat component, (i) a vegetable mixed oil and fat using 50% or more of palm oil having an iodine value of 55.0 to 67.0, ( (B) containing 50% or more of vegetable oil or fat mixed with palm oil, palm kernel oil, or mixed oil or fat thereof, or (c) fractionated oil or fat of palm oil, and palm kernel oil or palm Oil, or vegetable mixed oil containing 50% or less of those mixed fats and oils, when the content of palm kernel oil, coconut oil, or mixed oils thereof is A%, The dairy substitute milk composition containing any one of the vegetable mixed fats and oils having a value of (55.0-0.05A) to 55.0 has anti-caking property and fluidity. Excellent and hardly soluble aggregates adhere to the device when dissolved in warm water Not, it is easy instrument cleaning, found to be very good young 畜用 milk substitute composition solubility, the present invention has been completed based on these findings.

本発明によれば、植物性油脂を使用し、溶解時に強攪拌しても難溶性の凝集物が析出せず、しかも温水で溶解する際に難溶性の凝集物が哺乳器具に付着しないので、器具洗浄が容易となる、溶解性の非常に優れた幼畜用代用乳組成物を得ることができる。 According to the present invention, vegetable oils and fats are used, so that hardly soluble aggregates do not precipitate even when strongly stirred during dissolution, and hardly soluble aggregates do not adhere to feeding devices when dissolved in warm water. It is possible to obtain a dairy substitute milk composition having excellent solubility and facilitating instrument cleaning.

本願の発明は、油脂成分として、(イ)ヨウ素価が55.0〜67.0であるパーム油を50%以上用いた植物性混合油脂、(ロ)ヤシ油、パーム核油、あるいはそれらの混合油脂の含量が50%以上である植物性混合油脂又は(ハ)パーム油の分画混合油脂を50%以上含有し、かつパーム核油、ヤシ油、あるいはそれらの混合油脂を50%以下含有する植物性混合油脂であり、パーム核油、ヤシ油、あるいはそれらの混合油脂の含量をA%としたとき、パーム油の分画混合油脂のヨウ素価が(55.0−0.05A)〜55.0となるような植物性混合油脂の何れか1種を含有してなる幼畜用代用乳組成物である。 The invention of the present application is as follows: (i) Vegetable mixed oil or fat using 50% or more of palm oil having an iodine value of 55.0 to 67.0, (b) palm oil, palm kernel oil, or those Contains 50% or more of vegetable mixed fats or oils that contain 50% or more of mixed fats and oils, and contains 50% or less of palm kernel oil, coconut oil, or mixed fats and oils thereof. When the content of palm kernel oil, coconut oil, or the mixed fats and oils thereof is A%, the iodine value of the mixed fats and oils of palm oil is (55.0-0.05A) to It is a milk composition for larvae containing any one of the vegetable mixed fats and oils of 55.0.

本発明に於いては、パーム油から植物油脂中のトリパルミトイルグリセロール(PPP)を多く含む高融点のステアリン分画を除いた低融点分画油脂、特に、ヨウ素価が55.0〜67.0となるようなパーム油の低融点分画混合油脂を使用した植物性混合油脂から調製した幼畜用代用乳が、溶解時に強攪拌しても難溶性の凝集物が析出せず、しかも温水で溶解する際に難溶性の凝集物が哺乳器具に付着せず、器具洗浄が容易となる、溶解性の非常に優れている。 In the present invention, low melting point fraction oils and fats obtained by removing a high melting point stearin fraction containing a large amount of tripalmitoylglycerol (PPP) in vegetable oils and fats from palm oil, in particular, iodine value is 55.0 to 67.0. Milky milk substitute prepared from vegetable oils and fats using a low melting fraction oil mixture of palm oil that does not form difficult-to-aggregate aggregates even when stirred strongly during dissolution, and with warm water When dissolving, the hardly soluble aggregate does not adhere to the feeding device, and the device can be easily cleaned, and the solubility is very excellent.

又、使用するパーム分画油のヨウ素価が55.0以下であっても、その量が全体の油脂量に対して十分に少なければ溶解時の凝集物発生を防止することが可能である。特に、もともとトリパルミトイルグリセロール含量が非常に低いパーム核油やヤシ油を50%以下使用してパーム分画油を薄めた植物性油脂の場合、パーム核油やヤシ油の混合比率をA%とすれば、ヨウ素価が(55.0−0.05×A)〜55.0であるようなパーム分画油脂であれば凝集物の発生は起こらない。また、パーム核油やヤシ油を50%以上使用してパーム分画油脂を薄めてしまえば、そのパーム分画油のヨウ素価に関わらず溶解後の凝集物は発生しない。 Moreover, even if the iodine fraction of the palm fraction oil to be used is 55.0 or less, if the amount is sufficiently small relative to the total amount of fats and oils, it is possible to prevent the generation of aggregates during dissolution. In particular, in the case of vegetable fats and oils in which palm fraction oil has been diluted by using 50% or less of palm kernel oil or palm oil, which originally has a very low tripalmitoylglycerol content, the mixing ratio of palm kernel oil or palm oil is A%. If it is a palm fraction oil and fat whose iodine value is (55.0-0.05 * A)-55.0, generation | occurrence | production of the aggregate will not occur. Moreover, if palm kernel oil and palm oil are used 50% or more and palm fraction fats and oils are diluted, the aggregate after melt | dissolution will not generate | occur | produce irrespective of the iodine number of the palm fraction oil.

本発明における幼畜用代用乳組成物は粉末油脂を10〜60%、好ましくは30〜60%含み且つその粉末油脂の成分の内植物性油脂を30〜80%含むものが有利に用いられる。
本発明における植物性油脂としては、ヨウ素価が55.0〜67.0のパーム分画油脂を50%以上使用することが望ましい。このパーム分画油脂を得る方法は、原料のパーム油から一般的な方法で分別処理を受けた分画油、あるいは精製パーム油そのものを単独または2種以上混合すればよい。パーム油以外に使用する植物油脂としては、大豆油、菜種油、サフラワー油、ひまわり油、米油、コーンオイル、綿実油、カカオ脂、パーム核油、ヤシ油、それらの分画油等の油脂原料の内の1種又は2種以上であればよいが、幼畜用代用乳組成物として栄養成分や価格を考慮すると、この目的のためには、パーム核油、ヤシ油、およびそれらの分画油を適宜選択することが有利である。
The dairy substitute milk composition in the present invention is advantageously one containing 10 to 60%, preferably 30 to 60%, of powdered oil and fat and 30 to 80% of endophyte oil or fat as a component of the powdered fat.
As the vegetable oil and fat in the present invention, it is desirable to use 50% or more of a palm fraction oil or fat having an iodine value of 55.0 to 67.0. The method for obtaining the palm fraction oil may be a single fraction or a mixture of two or more of the fraction oil that has been subjected to a fractionation process from the raw palm oil by a general method, or the refined palm oil itself. Vegetable oils and fats used in addition to palm oil include oils such as soybean oil, rapeseed oil, safflower oil, sunflower oil, rice oil, corn oil, cottonseed oil, cocoa butter, palm kernel oil, coconut oil, and fractionated oils thereof. One or more of them may be used, but considering the nutritional components and price as a milk substitute composition for larva, for this purpose, palm kernel oil, coconut oil, and their fractions are used. It is advantageous to select the oil accordingly.

さらに、使用するパーム分画油脂のヨウ素価が55.0以下である場合は、トリパルミトイルグリセロール含量の低いパーム核油やヤシ油を加えてパーム分画油脂を希釈するとよい。例えばパーム核油やヤシ油、あるいはその混合油脂を50%以下使用する場合は、その全体の油脂に対する混合比率をA%とすれば、ヨウ素価が(55.0−0.05×A)〜55.0であるようなパーム分画油脂を選択すればよい。また、パーム分画油脂のヨウ素価に関わらず、パーム核油やヤシ油が50%以上含まれる植物性混合油脂であれば、溶解後の凝集物は発生せず、好適に用いることができる。   Furthermore, when the iodine value of the palm fraction oil to be used is 55.0 or less, the palm fraction oil may be diluted by adding palm kernel oil or palm oil having a low tripalmitoylglycerol content. For example, when using 50% or less of palm kernel oil or palm oil, or a mixed fat / oil thereof, the iodine value is (55.0−0.05 × A) —if the mixing ratio to the total fat / oil is A%. A palm fraction oil such as 55.0 may be selected. Regardless of the iodine value of the palm fraction oil and fat, if it is a vegetable mixed oil and fat containing 50% or more of palm kernel oil or palm oil, aggregates after dissolution do not occur and can be suitably used.

また、パーム油とパーム油以外の油脂をあらかじめ混合してから分別処理を行う場合でも、その混合分画油脂について、ヨウ素価が55.0〜67.0であるパーム油の分画を50%以上含有するか、あるいはパーム核油かヤシ油を50%以上含有する、あるいはパーム核油やヤシ油が50%以下であっても、その含有量をA%としたときにパーム分画油脂のヨウ素価が(55.0−0.05A)〜55.0となるような油脂構成であると見なせるものが望ましい。 Moreover, even when performing a fractionation process after mixing fats and oils other than palm oil and palm oil beforehand, 50% of the fraction of palm oil whose iodine value is 55.0 to 67.0 is obtained for the mixed fractionated fats and oils. Or more than 50% of palm kernel oil or coconut oil, or even if palm kernel oil or coconut oil is 50% or less, What can be considered that it is an oil-and-fat structure from which an iodine value is set to (55.0-0.05A)-55.0 is desirable.

本発明において用いられる粉末油脂は、これまでに説明した植物性混合油脂を90%以上含有した油脂を用いて、一般に通常の方法によって製造されたものが用いられる。例えば、脱脂粉乳、ホエー、カゼイン、糖類、多糖類(デキストリン、ガム類)、及び乳化剤を水に溶解し、その後乳化剤を溶解した植物性油脂を混合、乳化し、次いでホモジナイザーによって均質化処理し、これを噴霧乾燥して粉末化調製されたものである。又、上記組成の植物性油脂を通常の方法で代用乳原料に噴霧造粒し、顆粒状を呈するものであってもよい。 As the powdered fats and oils used in the present invention, oils and fats containing 90% or more of the vegetable mixed fats and oils described so far are generally used which are produced by a usual method. For example, skim milk powder, whey, casein, sugars, polysaccharides (dextrin, gums), and an emulsifier are dissolved in water, and then the vegetable oil and fat in which the emulsifier is dissolved are mixed, emulsified, and then homogenized by a homogenizer. This was spray-dried to prepare a powder. Moreover, the vegetable oil and fat of the said composition may be spray-granulated by the normal method to the milk substitute material, and a granular form may be shown.

本発明の幼畜用代用乳組成物はその他に、幼畜用代用乳に通常用いられる代用乳用原料として脱脂粉乳、ホエー蛋白質濃縮物(WPC)、乾燥ホエー、糖質、ミネラル、ビタミン類及び賦形材、乳化剤等が用いられ、その使用量も通常のものと変わりはない。 The dairy substitute milk composition of the present invention also includes skim milk powder, whey protein concentrate (WPC), dried whey, sugars, minerals, vitamins and the like as a milk substitute ingredient normally used for larval milk substitutes. A shaping material, an emulsifier and the like are used, and the amount used is not different from that of a normal one.

以下、本発明の幼畜用代用乳組成物を実施例を用いて更に詳細に説明するが、本発明は、これらに限定されるものではない。
実施例1
表1に各実施例および比較例の植物性混合油脂の混合比率およびヨウ素価を示す。また、表2に粉末油脂配合を、表3に代用乳配合を示す。
Hereinafter, although the milk composition for larvae of the present invention will be described in more detail using examples, the present invention is not limited to these.
Example 1
Table 1 shows the mixing ratios and iodine values of the vegetable mixed fats of each Example and Comparative Example. Table 2 shows the powdered fat composition, and Table 3 shows the milk substitute composition.

Figure 2007159522
Figure 2007159522

Figure 2007159522
Figure 2007159522

実施例1の植物性混合油脂の混合比率は、ヨウ素価52.5である精製パーム油(ニチユソリューション(株))が30重量%、ヨウ素価56.3であるパームオレイン油(ニチユソリューション(株))が70重量%とした。また、粉末油脂配合は、表2に示すとおり、乳化剤は粗レシチン(ADM社製)、ソルビタン脂肪酸エステル(第一工業製薬(株))およびポリオキシエチレンソルビタン脂肪酸エステル(第一工業製薬(株))を用意した。また粉末油脂のコーティング基剤として脱脂粉乳(雪印乳業(株))を使用した。 The mixing ratio of the vegetable oil mixture of Example 1 was 30% by weight of refined palm oil (Nichiyu Solution Co., Ltd.) having an iodine value of 52.5 and palm olein oil (Nichiyu Solution Co., Ltd.) having an iodine value of 56.3. )) Was 70% by weight. In addition, as shown in Table 2, the powdered fats and oils blended were crude lecithin (manufactured by ADM), sorbitan fatty acid ester (Daiichi Kogyo Seiyaku Co., Ltd.) and polyoxyethylene sorbitan fatty acid ester (Daiichi Kogyo Seiyaku Co., Ltd.). ) Was prepared. Moreover, skim milk powder (Snow Brand Milk Products Co., Ltd.) was used as a coating base for powdered oils and fats.

上記の植物性混合油脂を粉末油脂重量に対して48.5重量%用意し、60℃に加熱した後、レシチン1.0重量%、ソルビタン脂肪酸エステル0.5重量%、ポリオキシエチレンソルビタン脂肪酸エステル0.1重量%を加熱した植物性混合油脂に加え、よく混和し、レシチンと乳化剤を含む油脂混合物を調製した。
一方、上記の脱脂粉乳50重量部を60℃の温水100重量部に混合溶解し、さらに上に調製した60℃の植物性混合油脂組成物を加え、60℃に保持しながらモーター攪拌機にて均一になるまで混合し、O/W混合乳化溶液を調製した。
48.5% by weight of the above vegetable mixed fat / oil is prepared with respect to the weight of the powdered fat / oil, heated to 60 ° C., then lecithin 1.0% by weight, sorbitan fatty acid ester 0.5% by weight, polyoxyethylene sorbitan fatty acid ester 0.1 wt% was added to the heated vegetable mixed fat and oil, and mixed well to prepare a fat and oil mixture containing lecithin and an emulsifier.
On the other hand, 50 parts by weight of the above skim milk powder is mixed and dissolved in 100 parts by weight of warm water at 60 ° C., and the 60 ° C. vegetable mixed oil / fat composition prepared above is further added. And mixed to prepare an O / W mixed emulsion solution.

得られた混合乳化溶液を高圧ホモジナイザー15MR−8TA(APV GAULIN Inc)によって200kg/cm2の圧力をかけ、均質化処理(ホモジナイズ)を行った。この均質化処理した混合乳化液の脂肪球の球径を光学顕微鏡を用いて測定したところ、1μm〜5μmと非常に小さく、均質化処理によって乳化液中の脂肪球が微細化されたことが確認された。
均質化処理した混合乳化液は、ニロ社製(デンマーク)スプレードライヤーモバイル・マイナー(NiroCo.Ltd.Mobile Minor)を用いて180℃の熱風にて噴霧乾燥処理を行った。
噴霧乾燥後に得られた粉体はバットに薄く広げ、室温で一晩放冷し、粗蛋白質含有率が15.5%、脂肪含有率が49%である粉末油脂組成物を製造した。
The obtained mixed emulsion solution was subjected to homogenization by applying a pressure of 200 kg / cm 2 with a high-pressure homogenizer 15MR-8TA (APV GAULIN Inc). The diameter of the fat globules in the homogenized mixed emulsion was measured using an optical microscope, and it was confirmed that the fat globules in the emulsion were refined by the homogenization. It was.
The homogenized mixed emulsion was spray-dried with hot air at 180 ° C. using a Niro Co. Ltd. Mobile Minor (Niro Co. Ltd.).
The powder obtained after spray drying was spread thinly on a vat and allowed to cool overnight at room temperature to produce a powdered fat composition having a crude protein content of 15.5% and a fat content of 49%.

上記方法によって得られた粉末油脂組成物を用いて、表3に示す代用乳組成物配合を用意した。 Using the powdered oil / fat composition obtained by the above method, the milk composition for milk substitute shown in Table 3 was prepared.

Figure 2007159522
Figure 2007159522

表3に示した各原料を万能混合機にて均一になるまで十分混合し、粗蛋白質含有率25%、脂肪含有率21%の混合粉末を調製した。
調製した混合粉末6kgを、流動層造粒機(MGD−0.5、株式会社大川原製作所製)に投入し、90℃の熱風で混合粉末を流動させながら、常温(約25℃)の水を50g/秒の噴霧速度で噴霧し造粒を行った。噴霧した水の総量は450g、すなわち混合粉末の重量に対して7.5%となるまで噴霧した。水噴霧終了後、10分間追加乾燥した後流動層から排出した。
得られた造粒物はバットに薄く広げ、4℃の冷蔵庫にて1時間冷却した後、目開き1.4mmのふるいにて篩分し、篩下したものを代用乳組成物とした。代用乳組成物の外観性状はサラサラした顆粒状を呈していた。
Each raw material shown in Table 3 was sufficiently mixed with a universal mixer until uniform, and a mixed powder having a crude protein content of 25% and a fat content of 21% was prepared.
6 kg of the prepared mixed powder is put into a fluidized bed granulator (MGD-0.5, manufactured by Okawara Seisakusho Co., Ltd.), and water at room temperature (about 25 ° C) is added while flowing the mixed powder with hot air of 90 ° C. Spray granulation was carried out at a spraying speed of 50 g / sec. Spraying was performed until the total amount of water sprayed was 450 g, that is, 7.5% based on the weight of the mixed powder. After completion of water spraying, the mixture was further dried for 10 minutes and then discharged from the fluidized bed.
The obtained granulated material was spread thinly on a vat, cooled in a refrigerator at 4 ° C. for 1 hour, sieved with a sieve having an aperture of 1.4 mm, and sieved to obtain a milk substitute composition. The appearance of the milk substitute composition was smooth and granular.

この代用乳組成物65gを、溶解性評価のために温度変化による劣化処理を行った。プログラム付き恒温槽に試作した代用乳組成物65gを入れ、35度で3時間加熱、次いで5℃で3時間冷却するサイクルを8回繰り返した後、サンプルを取り出した。
劣化処理を行った代用乳組成物は、自動哺乳機(型式TAP5−SA2−30−P、株式会社ロールクリエート)で溶解性の評価を行った。まず自動哺乳機の溶解ポットに43℃の温水500mlを入れ、次に劣化処理を行った代用乳組成物65gをその中に投じ、ミキサーを回転させて2分間強攪拌し代用乳を溶解した。攪拌した後、溶解した代用乳溶液を目開き0.5mmのふるいに空けて残渣を確認したところ、図1に示す如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
The milk substitute composition 65 g was subjected to a deterioration treatment due to temperature change for solubility evaluation. A prototype milk composition 65 g was placed in a thermostat with a program, heated at 35 ° C. for 3 hours, and then cooled at 5 ° C. for 3 hours, and the sample was taken out 8 times.
The substitute milk composition subjected to the deterioration treatment was evaluated for solubility with an automatic baby machine (model TAP5-SA2-30-P, Roll Create Co., Ltd.). First, 500 ml of 43 ° C. warm water was put in a dissolving pot of an automatic baby machine, and then 65 g of the milk substitute composition that had been subjected to deterioration treatment was poured therein, and the mixer was rotated to vigorously stir for 2 minutes to dissolve the milk substitute. After stirring, the dissolved milk substitute solution was poured into a 0.5 mm sieve and the residue was confirmed. As shown in FIG. 1, no agglomerates were observed on the sieve, and the fat and oil to the dissolution pot There was no contamination.

実施例2
実施例2の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油が18重量%、同じくパームオレイン油が42重量%、および精製パーム核油(ニチユソリューション株式会社)を40%とした。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、実施例1と同様、図1に示す如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
Example 2
The mixing ratio of the vegetable oil mixture of Example 2 was 18% by weight of refined palm oil similar to that used in Example 1, 42% by weight of palm olein oil, and refined palm kernel oil (Nichiyu Solution Co., Ltd.). ) Was 40%. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment with a temperature difference in the same manner as in Example 1, and then stirred strongly with an automatic baby machine, as in Example 1, as shown in FIG. Etc. were not confirmed at all, and there was no adhesion of fat and oil stains to the dissolution pot.

実施例3
実施例3の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油を20%、またヨウ素価67.0のパーム低融点分画油であるパームエース10(不二製油(株))を80%使用した。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、実施例1と同様、図1に示した如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
Example 3
The mixing ratio of the vegetable oil mixture of Example 3 was 20% of refined palm oil similar to that used in Example 1, and Palm Ace 10 (non-refining fraction oil having a iodine low value of 67.0) Nichi Oil Co., Ltd.) was used 80%. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, it was agitated with an automatic baby machine, and as in Example 1, as shown in FIG. Nothing was confirmed, and there was no oily dirt adhered to the melting pot.

実施例1〜3の結果から、パーム油、パームオレイン、パームエース10などを混合したパーム分画油脂の構成をヨウ素価が55.0以上に調整した植物性混合油脂を50%以上使用すれば、凝集物やポットへの汚れつきを起こすことなく、溶解性の非常に優れた代用乳組成物となることがわかる。また、この時、パーム分画油脂以外の油脂、例えば実施例2のようにパーム核油(ヨウ素価18.6)を混合した場合から分かるように、パーム分画油脂以外の油脂のヨウ素価が非常に低いために植物性混合油脂全体のヨウ素価が55.0を下回ることもある。しかし、本実施例は植物性混合油脂全体のヨウ素価に関わらず、パーム分画油脂のヨウ素価が55.0以上となるものを使用することで、図1に示した如く、凝集物の発生のない代用乳組成物が得られることを示している。 From the results of Examples 1 to 3, if 50% or more of the vegetable oil mixture is used, the composition of the palm fraction oil and fat mixed with palm oil, palm olein, palm ace 10 and the like is adjusted to an iodine value of 55.0 or more. It can be seen that the milk replacer composition has excellent solubility without causing agglomerates and dirt on the pot. At this time, as can be seen from the case of mixing fat and oil other than palm fraction fat and oil, for example, palm kernel oil (iodine number 18.6) as in Example 2, the iodine value of fat and oil other than palm fraction fat and oil is Since it is very low, the iodine value of the whole vegetable mixed fat may be less than 55.0. However, in this example, regardless of the iodine value of the whole vegetable mixed fat and oil, by using the palm fraction fat and oil having an iodine value of 55.0 or more, as shown in FIG. It is shown that a milk replacer composition without odor is obtained.

実施例4
実施例4の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油を40%、また精製ヤシ油(不二製油(株))を60%使用した。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、実施例1と同様、図1に示した如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
Example 4
As for the mixing ratio of the vegetable mixed fat of Example 4, 40% of refined palm oil similar to that used in Example 1 and 60% of refined palm oil (Fuji Oil Co., Ltd.) were used. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, it was agitated with an automatic baby machine, and as in Example 1, as shown in FIG. Nothing was confirmed, and there was no oily dirt adhered to the melting pot.

実施例5
実施例5の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油を30%、また実施例2で使用したものと同様の精製パーム核油を70%使用した。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、実施例1と同様、図1に示した如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
Example 5
The mixing ratio of the vegetable oil mixture of Example 5 was 30% of refined palm oil similar to that used in Example 1, and 70% of refined palm kernel oil similar to that used in Example 2. . Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, it was agitated with an automatic baby machine, and as in Example 1, as shown in FIG. Nothing was confirmed, and there was no oily dirt adhered to the melting pot.

実施例6
実施例6の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油を42%、パームオレイン油を28%、また実施例4で使用したものと同様の精製ヤシ油を30%使用した。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、実施例1と同様、図1に示した如く、ふるい上に凝集物などは一切確認されず、また溶解ポットへの油脂汚れの付着もなかった。
実施例4、5の結果から、ヨウ素価が55.0を下回るパーム分画油脂を使用した場合でも、パーム核油やヤシ油などを50%以上使用し、パーム分画油脂を十分希釈すれば、溶解時に凝集物の付着などは生ぜず、自動哺乳機の溶解ポットを油脂で汚すことはないことがわかる。
Example 6
The mixing ratio of the vegetable mixed fat of Example 6 is 42% of refined palm oil similar to that used in Example 1, 28% of palm olein oil, and the same refined palm as used in Example 4 30% oil was used. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, it was agitated with an automatic baby machine, and as in Example 1, as shown in FIG. Nothing was confirmed, and there was no oily dirt adhered to the melting pot.
From the results of Examples 4 and 5, even when palm fraction fats and oils having an iodine value of less than 55.0 are used, if palm kernel oil or palm oil is used by 50% or more and the palm fraction fats and oils are sufficiently diluted, It can be seen that there is no adhesion of agglomerates at the time of dissolution, and the dissolution pot of the automatic feeding machine is not soiled with fats and oils.

また、実施例6では、ヤシ油の使用比率を30%としたが、この場合凝集物発生を起こさないパーム分画油脂のヨウ素価は、発明者らの提案する式から計算すると、
55.0−0.05×30=53.5 〜 55.0
の範囲内にあることが条件となる。一方精製パーム油とパームオレインの混合比率から計算したパーム分画油脂としてのヨウ素価は54.0となり、実際に凝集物発生も起こらなかった。このようにヤシ油などのパーム分画油以外の油脂含量が50%以下であっても、パーム分画油脂のヨウ素価が発明者らの提案する数式上の範囲にあれば、代用乳溶解時に凝集物の発生は起こらないのである。
In Example 6, the use ratio of coconut oil was set to 30%. In this case, the iodine value of the palm fraction oil that does not cause agglomerate generation was calculated from the formula proposed by the inventors,
55.0−0.05 × 30 = 53.5 to 55.0
It must be within the range. On the other hand, the iodine value as a palm fraction fat calculated from the mixing ratio of refined palm oil and palm olein was 54.0, and no aggregates were actually generated. Thus, even if the fat content other than the palm fraction oil such as palm oil is 50% or less, if the iodine value of the palm fraction fat is within the range of the mathematical formula proposed by the inventors, when the substitute milk is dissolved Aggregation does not occur.

比較例1
比較例1の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油を100%使用した。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、図2に示すようにふるい上に白色の凝集物が大量に回収された。成分を分析した結果、90%が油脂であり、上昇融点は50℃であった。またガスクロマトグラフィーでトリグリセリドを分析した結果、ほとんどのトリグリセリド組成に原料油脂との違いはなかったものの、トリパルミトイルグリセロール(PPP)を示すC48のピークが原料油脂の約3倍と突出していることがわかった。このため、凝集物は、トリパルミトイルグリセロールを主体とする高融点のトリグリセリドが凝集し、代用乳溶解液中に析出したものであると推定された。
Comparative Example 1
100% of refined palm oil similar to that used in Example 1 was used as the mixing ratio of the vegetable mixed fat of Comparative Example 1. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.
When this milk replacer composition was subjected to deterioration treatment in the same manner as in Example 1 with a temperature difference, it was vigorously stirred with an automatic baby machine. As shown in FIG. 2, a large amount of white agglomerates were collected on the sieve. It was done. As a result of analyzing the components, 90% were fats and oils, and the rising melting point was 50 ° C. As a result of analysis of triglycerides by gas chromatography, the C48 peak indicating tripalmitoylglycerol (PPP) protruded about 3 times that of the raw oils and fats, although most of the triglyceride compositions were not different from those of the raw oils and fats. all right. For this reason, it was presumed that the aggregates were aggregates of high melting point triglycerides mainly composed of tripalmitoylglycerol and precipitated in the milk substitute solution.

比較例2
比較例2の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油が40重量%、およびパームオレインを60%とした。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
Comparative Example 2
The mixing ratio of the vegetable oil mixture of Comparative Example 2 was 40% by weight of refined palm oil similar to that used in Example 1, and 60% of palm olein. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk composition for milk substitute were produced by the same mixing ratio and method as in Example 1.

この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、図2に示すように、ふるい上に大きさ約3〜10mmの白色凝集物の粒が多数残った。また自動哺乳機の溶解ポット壁面やミキサー部分にも多数の凝集物が付着していた。 When this milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, it was vigorously stirred with an automatic baby machine. As shown in FIG. 2, the size of the milk composition was about 3 to 10 mm on the sieve. Many grains of white aggregate remained. In addition, a large number of agglomerates adhered to the melting pot wall and mixer portion of the automatic feeding machine.

実施例1と比較例1、2を比較すると、実施例1で使用したパーム分画油脂のヨウ素価が55.2であったのに対し、比較例1のパーム油のヨウ素価が52.5であり、また比較例2で使用したパーム分画油脂のヨウ素価は54.8であった。このように、パーム分画油脂のヨウ素価が55.0を下回ると、凝集物が発生することがわかった。 When Example 1 and Comparative Examples 1 and 2 were compared, the iodine value of the palm fraction fat used in Example 1 was 55.2, whereas the iodine value of the palm oil of Comparative Example 1 was 52.5. Moreover, the iodine value of the palm fraction fat used in Comparative Example 2 was 54.8. Thus, when the iodine value of the palm fraction fat was less than 55.0, it was found that aggregates were generated.

比較例3
比較例3の植物性混合油脂の混合比率は、実施例1で用いたものと同様の精製パーム油が55%、パームオレイン油を5%、および実施例2で使用したものと同様の精製パーム核油を40%とした。この植物性混合油脂を用いて、実施例1と同様の配合比率、方法にて粉末油脂および代用乳組成物を試作した。
この代用乳組成物を実施例1と同様の方法で温度差をかけて劣化処理した後、自動哺乳機で強攪拌したところ、比較例1、2と同様、図2に示すようにふるい上に少量の白色凝集物が認められた。また自動哺乳機の溶解ポット壁面やミキサー部分にもわずかに凝集物が付着していた。
Comparative Example 3
The mixing ratio of the vegetable mixed fat of Comparative Example 3 is 55% of refined palm oil similar to that used in Example 1, 5% of palm olein oil, and refined palm similar to that used in Example 2 The core oil was 40%. Using this vegetable mixed oil and fat, a powdered oil and fat and a milk substitute composition were prototyped by the same mixing ratio and method as in Example 1.
This milk replacer composition was subjected to deterioration treatment by applying a temperature difference in the same manner as in Example 1, and then stirred vigorously with an automatic baby machine. As in Comparative Examples 1 and 2, as shown in FIG. A small amount of white aggregate was observed. Further, a slight amount of agglomerates adhered to the melting pot wall and mixer part of the automatic feeding machine.

比較例3では、精製パーム油とパームオレイン油の混合比率から、そのパーム分画油としてのヨウ素価は52.8と計算される。一方、実施例5で示したように、パーム核油の使用比率は40%であるので、この場合凝集物発生を起こさないパーム分画油脂のヨウ素価は、発明者らの提案する式から計算すると、
55.0−0.05×40=53.0 〜 55.0
の範囲内にあることが望ましいが、比較例3のパーム分画油脂のヨウ素価はこの範囲を逸脱している。そのため、実際に代用乳溶解後に凝集物が発生し、溶解ポットを汚す結果となってしまったのである。
In Comparative Example 3, the iodine value as the palm fraction oil is calculated to be 52.8 from the mixing ratio of refined palm oil and palm olein oil. On the other hand, as shown in Example 5, the use ratio of palm kernel oil is 40%. In this case, the iodine value of the palm fraction oil that does not cause the generation of aggregates is calculated from the formula proposed by the inventors. Then
55.0−0.05 × 40 = 53.0 to 55.0
However, the iodine value of the palm fraction fat of Comparative Example 3 deviates from this range. Therefore, agglomerates were actually generated after the milk substitute was melted, and the melting pot was soiled.

本発明による各生産物のろ過試験結果を示す図である。It is a figure which shows the filtration test result of each product by this invention. 比較例の各生産物のろ過試験結果を示す図である。It is a figure which shows the filtration test result of each product of a comparative example.

Claims (6)

油脂成分として、(イ)ヨウ素価が55.0〜67.0であるパーム油を50%以上用いた植物性混合油脂、(ロ)ヤシ油、パーム核油、あるいはそれらの混合油脂の含量が50%以上である植物性混合油脂又は(ハ)パーム油の分画混合油脂を50%以上含有し、かつパーム核油、ヤシ油、あるいはそれらの混合油脂を50%以下含有する植物性混合油脂であり、パーム核油、ヤシ油、あるいはそれらの混合油脂の含量をA%としたとき、パーム油の分画混合油脂のヨウ素価が(55.0−0.05A)〜55.0となるような植物性混合油脂の何れか1種を含有してなる幼畜用代用乳組成物。 As the fat and oil component, (i) a vegetable mixed fat or oil using 50% or more of palm oil having an iodine value of 55.0 to 67.0, (b) coconut oil, palm kernel oil, or a mixed fat or oil content thereof 50% or more of vegetable mixed oil or fat or (c) Palm oil fractioned mixed oil or fat containing 50% or more and vegetable kernel oil, coconut oil, or mixed oil or fat thereof containing 50% or less When the content of palm kernel oil, coconut oil, or a mixed fat / oil thereof is A%, the iodine value of the fractionated mixed fat / oil of palm oil is (55.0-0.05A) to 55.0. A dairy substitute milk composition comprising any one of such vegetable mixed fats and oils. 油脂成分として、(イ)ヨウ素価が55.0〜67.0であるパーム油を50%以上用いた植物性混合油脂、(ロ)ヤシ油、パーム核油、あるいはそれらの混合油脂の含量が50%以上である植物性混合油脂又は(ハ)パーム油の分画混合油脂を50%以上含有し、かつパーム核油、ヤシ油、あるいはそれらの混合油脂を50%以下含有する植物性混合油脂であり、パーム核油、ヤシ油、あるいはそれらの混合油脂の含量をA%としたとき、パーム油の分画混合油脂のヨウ素価が(55.0−0.05A)〜55.0となるような植物性混合油脂の何れか1種を90%以上含有してなる請求項1に記載の幼畜用代用乳組成物。 As the fat and oil component, (i) a vegetable mixed fat or oil using 50% or more of palm oil having an iodine value of 55.0 to 67.0, (b) coconut oil, palm kernel oil, or a mixed fat or oil content thereof 50% or more of vegetable mixed oil or fat or (c) Palm oil fractioned mixed oil or fat containing 50% or more and vegetable kernel oil, coconut oil, or mixed oil or fat thereof containing 50% or less When the content of palm kernel oil, coconut oil, or a mixed fat / oil thereof is A%, the iodine value of the fractionated mixed fat / oil of palm oil is (55.0-0.05A) to 55.0. The substitute milk composition for juveniles according to claim 1, comprising 90% or more of any one of such vegetable mixed fats and oils. 温水で溶解する際に難溶性の凝集物が器具に付着せず、器具洗浄が容易であり、溶解性にも優れた請求項1又は2に記載の幼畜用代用乳組成物。 The milk composition for larvae according to claim 1 or 2, wherein hardly soluble agglomerates do not adhere to the instrument when dissolved with warm water, and the instrument can be easily washed and has excellent solubility. 粉末状又は顆粒状の油脂を30%〜80%含む請求項1、2、3又は4に記載の幼畜用代用乳組成物。 The milk composition for juvenile use according to claim 1, comprising 30% to 80% of a powdered or granular oil or fat. 請求項1、2、3に記載の油脂を30〜80%含有し、噴霧乾燥法を用いて製造された粉末油脂を含有することを特徴とする幼畜用代用乳組成物。 A dairy substitute milk composition comprising 30 to 80% of the oil and fat according to claim 1, 2 and 3, and containing a powdered oil and fat produced using a spray drying method. 粉末油脂の添加量が、幼畜用代用乳組成物の30%〜60%である請求項4に記載の幼畜用代用乳組成物。 The dairy substitute milk composition according to claim 4, wherein the amount of powdered oil / fat is 30% to 60% of the dairy substitute milk composition.
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JP2012005447A (en) * 2010-06-28 2012-01-12 National Federation Of Dairy Cooperative Associations Milk substitute composition
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