JP2012162466A - Hair dye - Google Patents
Hair dye Download PDFInfo
- Publication number
- JP2012162466A JP2012162466A JP2011022164A JP2011022164A JP2012162466A JP 2012162466 A JP2012162466 A JP 2012162466A JP 2011022164 A JP2011022164 A JP 2011022164A JP 2011022164 A JP2011022164 A JP 2011022164A JP 2012162466 A JP2012162466 A JP 2012162466A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- component
- dye
- hair dye
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000118 hair dye Substances 0.000 title claims abstract description 123
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 34
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 29
- 229940008099 dimethicone Drugs 0.000 claims abstract description 26
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 26
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 26
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 239000000981 basic dye Substances 0.000 claims abstract description 13
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 60
- 230000000694 effects Effects 0.000 abstract description 33
- 238000004043 dyeing Methods 0.000 abstract description 28
- 230000003766 combability Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 37
- 238000011156 evaluation Methods 0.000 description 28
- 239000000975 dye Substances 0.000 description 24
- 239000000203 mixture Substances 0.000 description 19
- 230000014759 maintenance of location Effects 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- -1 aromatic alcohols Chemical class 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- 238000005406 washing Methods 0.000 description 11
- 238000000926 separation method Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000013256 coordination polymer Substances 0.000 description 8
- 238000004945 emulsification Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000002459 sustained effect Effects 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 4
- 239000002552 dosage form Substances 0.000 description 4
- 238000005562 fading Methods 0.000 description 4
- 230000002688 persistence Effects 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- WLKAMFOFXYCYDK-UHFFFAOYSA-N [5-amino-4-[[3-[(2-amino-4-azaniumyl-5-methylphenyl)diazenyl]-4-methylphenyl]diazenyl]-2-methylphenyl]azanium;dichloride Chemical compound [Cl-].[Cl-].CC1=CC=C(N=NC=2C(=CC([NH3+])=C(C)C=2)N)C=C1N=NC1=CC(C)=C([NH3+])C=C1N WLKAMFOFXYCYDK-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229960002788 cetrimonium chloride Drugs 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 230000003699 hair surface Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000005722 itchiness Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- MCTQNEBFZMBRSQ-UHFFFAOYSA-N (3-amino-4-phenyldiazenylphenyl)azanium;chloride Chemical compound Cl.NC1=CC(N)=CC=C1N=NC1=CC=CC=C1 MCTQNEBFZMBRSQ-UHFFFAOYSA-N 0.000 description 1
- AQNZDXHBYRTSHA-UHFFFAOYSA-N 1,4-bis(2,3-dihydroxypropylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCC(O)CO)=CC=C2NCC(O)CO AQNZDXHBYRTSHA-UHFFFAOYSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- NLXFWUZKOOWWFD-UHFFFAOYSA-N 1-(2-hydroxyethylamino)-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCO)=CC=C2NC NLXFWUZKOOWWFD-UHFFFAOYSA-N 0.000 description 1
- BQYHUHIVBWYROK-UHFFFAOYSA-N 1-(3-aminopropylamino)-4-(methylamino)anthracene-9,10-dione;hydrochloride Chemical compound Cl.O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCN)=CC=C2NC BQYHUHIVBWYROK-UHFFFAOYSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 1
- WAPNOHKVXSQRPX-UHFFFAOYSA-N 1-phenylethanol Chemical compound CC(O)C1=CC=CC=C1 WAPNOHKVXSQRPX-UHFFFAOYSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
- QAMCXJOYXRSXDU-UHFFFAOYSA-N 2,4-dimethoxy-n-[2-(1,3,3-trimethylindol-1-ium-2-yl)ethenyl]aniline;chloride Chemical compound [Cl-].COC1=CC(OC)=CC=C1NC=CC1=[N+](C)C2=CC=CC=C2C1(C)C QAMCXJOYXRSXDU-UHFFFAOYSA-N 0.000 description 1
- OWMQBFHMJVSJSA-UHFFFAOYSA-N 2-(2-amino-4-nitroanilino)ethanol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1NCCO OWMQBFHMJVSJSA-UHFFFAOYSA-N 0.000 description 1
- JXVSZMLWYMMWAL-UHFFFAOYSA-N 2-(2-aminoethylamino)anthracene-9,10-dione;hydrochloride Chemical compound Cl.C1=CC=C2C(=O)C3=CC(NCCN)=CC=C3C(=O)C2=C1 JXVSZMLWYMMWAL-UHFFFAOYSA-N 0.000 description 1
- AZLWQVJVINEILY-UHFFFAOYSA-N 2-(2-dodecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCOCCOCCO AZLWQVJVINEILY-UHFFFAOYSA-N 0.000 description 1
- YUNHBAIHRNIODP-UHFFFAOYSA-N 2-(2-hydroxyethylamino)-5-nitrophenol Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1O YUNHBAIHRNIODP-UHFFFAOYSA-N 0.000 description 1
- ILCOCZBHMDEIAI-UHFFFAOYSA-N 2-(2-octadecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCOCCO ILCOCZBHMDEIAI-UHFFFAOYSA-N 0.000 description 1
- ZUAURMBNZUCEAF-UHFFFAOYSA-N 2-(2-phenoxyethoxy)ethanol Chemical compound OCCOCCOC1=CC=CC=C1 ZUAURMBNZUCEAF-UHFFFAOYSA-N 0.000 description 1
- LGZSBRSLVPLNTM-UHFFFAOYSA-N 2-(4-amino-2-methyl-5-nitroanilino)ethanol Chemical compound CC1=CC(N)=C([N+]([O-])=O)C=C1NCCO LGZSBRSLVPLNTM-UHFFFAOYSA-N 0.000 description 1
- LGGKGPQFSCBUOR-UHFFFAOYSA-N 2-(4-chloro-2-nitroanilino)ethanol Chemical compound OCCNC1=CC=C(Cl)C=C1[N+]([O-])=O LGGKGPQFSCBUOR-UHFFFAOYSA-N 0.000 description 1
- AUGYVRQAFGDGQV-UHFFFAOYSA-N 2-(chloromethyl)oxirane;2-(2-hydroxyethylamino)ethanol;2-nitrobenzene-1,4-diamine Chemical compound ClCC1CO1.OCCNCCO.NC1=CC=C(N)C([N+]([O-])=O)=C1 AUGYVRQAFGDGQV-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 1
- MGYUQZIGNZFZJS-KTKRTIGZSA-N 2-[2-[(z)-octadec-9-enoxy]ethoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCOCCO MGYUQZIGNZFZJS-KTKRTIGZSA-N 0.000 description 1
- AKWFJQNBHYVIPY-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO AKWFJQNBHYVIPY-UHFFFAOYSA-N 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- NJZCRXQWPNNJNB-UHFFFAOYSA-N 2-[2-nitro-4-(trifluoromethyl)anilino]ethanol Chemical compound OCCNC1=CC=C(C(F)(F)F)C=C1[N+]([O-])=O NJZCRXQWPNNJNB-UHFFFAOYSA-N 0.000 description 1
- WXGKXLXGYOYZMX-UHFFFAOYSA-N 2-[4-(2-aminoethylamino)-3-nitrophenoxy]ethanol Chemical compound NCCNC1=CC=C(OCCO)C=C1[N+]([O-])=O WXGKXLXGYOYZMX-UHFFFAOYSA-N 0.000 description 1
- WZYPIHOBHDXNJL-UHFFFAOYSA-N 2-[4-[(2-bromo-6-chloro-4-nitrophenyl)diazenyl]-3-chloro-n-(2-hydroxyethyl)anilino]ethanol Chemical compound ClC1=CC(N(CCO)CCO)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Br WZYPIHOBHDXNJL-UHFFFAOYSA-N 0.000 description 1
- YSVKKVUAUKQDBY-UHFFFAOYSA-N 2-[4-[(4-aminophenyl)diazenyl]-n-(2-hydroxyethyl)-3-methylanilino]ethanol Chemical compound CC1=CC(N(CCO)CCO)=CC=C1N=NC1=CC=C(N)C=C1 YSVKKVUAUKQDBY-UHFFFAOYSA-N 0.000 description 1
- NZKTVPCPQIEVQT-UHFFFAOYSA-N 2-[4-[(4-aminophenyl)diazenyl]-n-(2-hydroxyethyl)anilino]ethanol Chemical compound C1=CC(N)=CC=C1N=NC1=CC=C(N(CCO)CCO)C=C1 NZKTVPCPQIEVQT-UHFFFAOYSA-N 0.000 description 1
- BZYZOJIGZUACMS-UHFFFAOYSA-N 2-[4-[bis(2-hydroxyethyl)amino]anilino]-5-(2-hydroxyethylamino)cyclohexa-2,5-diene-1,4-dione Chemical compound O=C1C(NCCO)=CC(=O)C(NC=2C=CC(=CC=2)N(CCO)CCO)=C1 BZYZOJIGZUACMS-UHFFFAOYSA-N 0.000 description 1
- LXKQJEXWFGAMMW-UHFFFAOYSA-N 2-[4-[ethyl(2-hydroxyethyl)amino]-2-nitroanilino]ethanol;hydrochloride Chemical compound Cl.OCCN(CC)C1=CC=C(NCCO)C([N+]([O-])=O)=C1 LXKQJEXWFGAMMW-UHFFFAOYSA-N 0.000 description 1
- ASAQRGCLIPUSEK-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-3-nitroanilino]ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(N(CCO)CCO)C=C1[N+]([O-])=O ASAQRGCLIPUSEK-UHFFFAOYSA-N 0.000 description 1
- ZEARLPPIUCBHRP-UHFFFAOYSA-N 2-[4-chloro-5-(2-hydroxyethylamino)-2-nitroanilino]ethanol Chemical compound OCCNC1=CC(NCCO)=C([N+]([O-])=O)C=C1Cl ZEARLPPIUCBHRP-UHFFFAOYSA-N 0.000 description 1
- ADCWDMYESTYBBN-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-3-methyl-4-[(4-nitrophenyl)diazenyl]anilino]ethanol Chemical compound CC1=CC(N(CCO)CCO)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 ADCWDMYESTYBBN-UHFFFAOYSA-N 0.000 description 1
- GTMWPZKEYRLDJV-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-(2-methoxyethylamino)-3-nitroanilino]ethanol;hydrochloride Chemical compound Cl.COCCNC1=CC=C(N(CCO)CCO)C=C1[N+]([O-])=O GTMWPZKEYRLDJV-UHFFFAOYSA-N 0.000 description 1
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- PCGDWIWUQDHQLK-UHFFFAOYSA-N 2-morpholin-4-yl-5-nitrobenzaldehyde Chemical compound O=CC1=CC([N+](=O)[O-])=CC=C1N1CCOCC1 PCGDWIWUQDHQLK-UHFFFAOYSA-N 0.000 description 1
- WHJNKCNHEVCICH-UHFFFAOYSA-N 2-nitro-1-n-phenylbenzene-1,4-diamine Chemical compound [O-][N+](=O)C1=CC(N)=CC=C1NC1=CC=CC=C1 WHJNKCNHEVCICH-UHFFFAOYSA-N 0.000 description 1
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 1
- YFKNIPGAJBJZQT-UHFFFAOYSA-N 3-(4-amino-2-chloro-5-nitroanilino)propane-1,2-diol Chemical compound NC1=CC(Cl)=C(NCC(O)CO)C=C1[N+]([O-])=O YFKNIPGAJBJZQT-UHFFFAOYSA-N 0.000 description 1
- IJBOVPNSQXXDJB-UHFFFAOYSA-N 3-[2-chloro-4-(2,3-dihydroxypropylamino)-5-nitroanilino]propane-1,2-diol Chemical compound OCC(O)CNC1=CC([N+]([O-])=O)=C(NCC(O)CO)C=C1Cl IJBOVPNSQXXDJB-UHFFFAOYSA-N 0.000 description 1
- XDHQHBSDKYPJRG-UHFFFAOYSA-N 3-[2-nitro-4-(trifluoromethyl)anilino]propane-1,2-diol Chemical compound OCC(O)CNC1=CC=C(C(F)(F)F)C=C1[N+]([O-])=O XDHQHBSDKYPJRG-UHFFFAOYSA-N 0.000 description 1
- SZWQTBKBBNGUAB-UHFFFAOYSA-N 3-[4-(2-hydroxyethylamino)-3-nitrophenoxy]propane-1,2-diol Chemical compound OCCNC1=CC=C(OCC(O)CO)C=C1[N+]([O-])=O SZWQTBKBBNGUAB-UHFFFAOYSA-N 0.000 description 1
- YHSOWKGIYXECIF-UHFFFAOYSA-N 3-[4-[bis(2-hydroxyethyl)amino]-2-nitroanilino]propan-1-ol Chemical compound OCCCNC1=CC=C(N(CCO)CCO)C=C1[N+]([O-])=O YHSOWKGIYXECIF-UHFFFAOYSA-N 0.000 description 1
- XSUKBLJKLXZDPN-UHFFFAOYSA-N 3-[n-methyl-4-(methylamino)-3-nitroanilino]propane-1,2-diol;hydrochloride Chemical compound Cl.CNC1=CC=C(N(C)CC(O)CO)C=C1[N+]([O-])=O XSUKBLJKLXZDPN-UHFFFAOYSA-N 0.000 description 1
- HWIFOTHJSSDGGC-UHFFFAOYSA-N 4-(2-hydroxyethylamino)-3-nitrobenzamide Chemical compound NC(=O)C1=CC=C(NCCO)C([N+]([O-])=O)=C1 HWIFOTHJSSDGGC-UHFFFAOYSA-N 0.000 description 1
- PWOSOZQHIRPPHP-UHFFFAOYSA-N 4-(2-hydroxyethylamino)-3-nitrobenzonitrile Chemical compound OCCNC1=CC=C(C#N)C=C1[N+]([O-])=O PWOSOZQHIRPPHP-UHFFFAOYSA-N 0.000 description 1
- HSDSBIUUVWRHTM-UHFFFAOYSA-N 4-(2-nitroanilino)phenol Chemical compound C1=CC(O)=CC=C1NC1=CC=CC=C1[N+]([O-])=O HSDSBIUUVWRHTM-UHFFFAOYSA-N 0.000 description 1
- UNBOSJFEZZJZLR-UHFFFAOYSA-N 4-(4-nitrophenylazo)aniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 UNBOSJFEZZJZLR-UHFFFAOYSA-N 0.000 description 1
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 description 1
- ZRVPOURSNDQODC-UHFFFAOYSA-M 4-[(2,4-dimethyl-1,2,4-triazol-4-ium-3-yl)diazenyl]-n,n-dimethylaniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=NN1C ZRVPOURSNDQODC-UHFFFAOYSA-M 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- SEVMQEIGENUPIE-UHFFFAOYSA-N 4-bromo-1-fluoro-2-methoxybenzene Chemical compound COC1=CC(Br)=CC=C1F SEVMQEIGENUPIE-UHFFFAOYSA-N 0.000 description 1
- SPWPAFQLIZTXFN-UHFFFAOYSA-M 4-methoxy-n-methyl-n-[(1,3,3-trimethylindol-1-ium-2-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(OC)=CC=C1N(C)\N=C\C1=[N+](C)C2=CC=CC=C2C1(C)C SPWPAFQLIZTXFN-UHFFFAOYSA-M 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- 244000020518 Carthamus tinctorius Species 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、染毛料に関し、より特定的には、染料を毛髪に浸透・吸着させて所望の色に毛髪を染める、いわゆるヘアマニキュアに関する。 The present invention relates to a hair dye, and more particularly to a so-called hair nail polish that dyes hair into a desired color by penetrating and adsorbing the dye into the hair.
従来、毛髪の色を気軽に好みの色に染めることのできる、頭髪用の染料（染毛料、染毛剤、カラーリング剤、ヘアカラーリング剤などと称すこともある、以下、単に染毛料と称す）が数々開発されてきている。一般的な染毛料として、ヘアダイ、ヘアマニキュアが知られている。 Conventionally, hair dyes that can be easily dyed into the color of your hair (sometimes called hair dyes, hair dyes, coloring agents, hair coloring agents, etc. Many have been developed. Hair dyes and hair manicures are known as common hair dyes.
ヘアダイとは、毛髪内部のメラニン色素を分解し毛髪の色を明るくしたり、毛髪の色を脱色すると同時に所望の色の染料で毛髪を染め上げたりするものであり、いわゆるブリーチ、ブリーチカラーなどと称されるもののことである。一方、ヘアマニキュアとは、メラニン色素を分解せずに、染料を毛髪表面に吸着、さらには毛髪内部に染料を浸透させて所望の色に毛髪を染めるものである。 A hair dye is one that decomposes the melanin pigment in the hair to lighten the color of the hair, or decolorizes the hair and simultaneously dyes the hair with a dye of the desired color. It is what is done. On the other hand, hair manicure is a method in which a dye is adsorbed on the hair surface without decomposing the melanin pigment, and further, the dye is penetrated into the hair to dye the hair to a desired color.
一般的に、ヘアダイは染色力が強く、色持ちが良いといった特徴がある一方で、塩基性成分や、酸化剤などが含有されているため毛髪を傷めてしまうといった欠点がある。一方、ヘアマニキュアは塩基性成分や、酸化剤などが含有されていないものが多く、ヘアダイと比較して毛髪を傷めるといったことはないといった利点がある。 In general, hair dyes are characterized by strong dyeing power and good color retention, but have the disadvantage of damaging hair because they contain basic components, oxidizing agents, and the like. On the other hand, many hair manicures do not contain basic components, oxidizing agents, etc., and have the advantage that they do not damage hair compared to hair dies.
ところで、多くのヘアマニキュアは、アニオン性もしくはノニオン性の増粘剤を多く含有したジェル剤（ジェル状）とするものが多く、施術後（ヘアマニキュアを塗布し洗い流した後）の毛髪に上記増粘剤が残留することがある。つまり、上述したように、ヘアマニキュアは、施術後の毛髪に、ハリや硬さが出てしまうといった欠点がある（毛髪に、いわゆる被膜感が出ると表現することもある）。 By the way, many hair nail polishes are often made into gels (gels) containing a large amount of anionic or nonionic thickeners, and the above-mentioned increase is applied to the hair after treatment (after applying hair nail polish and washing away). Sticky agent may remain. In other words, as described above, hair nail polish has a drawback that the hair after treatment is firm and firm (it may be expressed that the hair has a so-called coating feeling).
また、上述したように、ヘアマニキュアは、毛髪表面に染料を塗布することにより毛髪を染色するものであり、例えば、ヘアダイと比べて色の持続（色持ち）が劣る。また、一般的なヘアマニキュアの染料は、酸性染料を用いているものが多く、施術中、頭皮に染料が染着した場合、施術後に洗髪しても当該染料が頭皮から落ちにくいといったこともある。 In addition, as described above, the hair nail polish dyes hair by applying a dye to the hair surface, and has, for example, inferior color persistence (color retention) as compared to a hair dye. In addition, many dyes for general hair manicure use acid dyes, and if the dye is dyed on the scalp during the treatment, it may be difficult to remove the dye from the scalp even if the hair is washed after the treatment. .
このようなヘアマニキュアの欠点を解消するために、例えば、特許文献１に開示されている毛髪料組成物がある。 In order to eliminate such drawbacks of hair manicure, for example, there is a hair composition disclosed in Patent Document 1.
上記特許文献１に開示されている毛髪料組成物は、染料、芳香族アルコール、ノニオン界面活性剤が配合されたものである。これにより、ヘアマニキュアの問題点である、色の持続（色持ち）が劣るといったことを解消し、高い染毛力（色の持続、色持ち）を維持できるようにしたものである。 The hair composition disclosed in Patent Document 1 is a mixture of a dye, an aromatic alcohol, and a nonionic surfactant. As a result, the problem of hair manicure, which is inferior in color persistence (color retention), is solved, and high hair dyeing power (color persistence, color retention) can be maintained.
なお、ヘアマニキュアにおいては、一般的に、染料を毛髪に、より付着、浸透させるために（染色力を高めるために）、当該染料とともに芳香族アルコールを添加する。しかしながら、染料とともに芳香族アルコールを添加した場合、ヘアマニキュアの剤型が安定しない、つまり保存安定性が劣ることが知られている。そのため、上記特許文献１を含む従来のヘアマニキュアには、染料、芳香族アルコールに加えて、水溶性高分子化合物（アニオン性もしくはノニオン性の増粘剤）が添加されている、剤型がジェル状のヘアマニキュアが多い。 In hair manicure, generally, an aromatic alcohol is added together with the dye in order to make the dye adhere to and penetrate into the hair (in order to increase the dyeing power). However, it is known that when an aromatic alcohol is added together with the dye, the dosage form of the hair nail polish is not stable, that is, the storage stability is poor. Therefore, the conventional hair manicure including the above-mentioned Patent Document 1 contains a water-soluble polymer compound (an anionic or nonionic thickener) in addition to a dye and an aromatic alcohol. Many hair-like manicures.
しかしながら、ジェル状のヘアマニキュアは、施術後の毛髪に、増粘剤が残り、ハリや硬さや、被膜感が出るといった問題点がある。 However, gel-like hair nail polish has a problem in that a thickener remains on the hair after treatment, resulting in a firmness, hardness, and a coating feeling.
本発明は、上記事情に鑑みてなされたものであり、その目的とするところは、染色力を維持しつつ、かつ、施術後においても、毛髪に柔軟性や指通りの良さ（毛髪の滑り性）を与えるといったトリートメント効果を有する染毛料を提供することにある。 The present invention has been made in view of the above circumstances, and the object of the present invention is to maintain the dyeing power and to provide flexibility and good fingering to the hair even after the treatment (hair slipperiness). ) To provide a hair dye having a treatment effect.
上記のような目的を達成するために、本発明は以下の特徴を有している。すなわち、第１の発明は、乳化物であることを特徴とする染毛料である。なお、当該染毛料は、（Ａ）成分：塩基性染料、（Ｂ）成分：芳香族アルコール、（Ｃ）成分：カチオン界面活性剤、（Ｄ）成分：ノニオン界面活性剤、（Ｅ）成分：ジメチコンもしくはジメチコノールを含有する。 In order to achieve the above object, the present invention has the following features. That is, the first invention is a hair dye characterized by being an emulsion. The hair dye contains (A) component: basic dye, (B) component: aromatic alcohol, (C) component: cationic surfactant, (D) component: nonionic surfactant, and (E) component: Contains dimethicone or dimethiconol.
第２の発明は、上記第１の発明において、（Ｆ）成分：アミノ変性シリコーンをさらに含有する。 A second invention further comprises (F) component: amino-modified silicone in the first invention.
第３の発明は、上記第２の発明において、染毛料における（Ｆ）成分：アミノ変性シリコーンの重量の値は、（Ｅ）成分：ジメチコンもしくはジメチコノールの重量の値を下回ることを特徴とする。 The third invention is characterized in that, in the second invention, the weight value of the component (F): amino-modified silicone in the hair dye is lower than the weight value of the component (E): dimethicone or dimethiconol.
第４の発明は、上記第１乃至３の何れか１の発明において、（Ｇ）成分：ＨＬＢ（Hydrophile-Lipophile Balance）の値が７未満のポリエーテル変性シリコーンをさらに含有する。 According to a fourth invention, in any one of the first to third inventions, the invention further comprises a polyether-modified silicone having a component (G): HLB (Hydrophile-Lipophile Balance) value of less than 7.
第５の発明は、上記第１乃至４の何れか１の発明において、（Ｄ）成分のＨＬＢ（Hydrophile-Lipophile Balance）の値は５〜１５である。 5th invention WHEREIN: The value of HLB (Hydrophile-Lipophile Balance) of (D) component is 5-15 in any one invention of the said 1st thru | or 4.
第６の発明は、上記第１乃至５の何れか１の発明に係る染毛料のｐＨは６〜８．５である。 In the sixth aspect, the hair dye according to any one of the first to fifth aspects has a pH of 6 to 8.5.
第７の発明は、第１剤と第２剤とからなる染毛料である。ここで、上記第１剤とは、上記第１、２、４の何れか１の発明に係る染毛料である。一方、上記第２剤とは、（Ｃ）成分：カチオン界面活性剤、（Ｅ）成分：ジメチコンもしくはジメチコノール、（Ｆ）成分：アミノ変性シリコーンを含有する処理剤である。なお、当該第２剤は、上記第１剤を毛髪に塗布した後に塗布されるものである。 7th invention is the hair dye which consists of a 1st agent and a 2nd agent. Here, the first agent is a hair dye according to any one of the first, second, and fourth inventions. On the other hand, the second agent is a treatment agent containing (C) component: cationic surfactant, (E) component: dimethicone or dimethiconol, and (F) component: amino-modified silicone. The second agent is applied after the first agent is applied to the hair.
本発明によれば、染色力を維持しつつ、かつ、施術後においても、毛髪に柔軟性や指通りの良さ（毛髪の滑り性）を与えるといったトリートメント効果を有する染毛料を提供することができる。また、多剤式、例えば、主に毛髪を染色するための成分、主にトリートメント効果を与える成分を含有する第１剤と、トリートメント効果を与える成分を含有する第２剤とした場合、上記第１剤を毛髪に塗布した後、当該第２剤を毛髪に塗布することにより、トリートメント効果を持続させることもできる。 ADVANTAGE OF THE INVENTION According to this invention, the hair dye which has the treatment effect of giving the softness | flexibility and the goodness | strength of a finger (slipperiness of hair) to hair, even after a treatment, can be provided, maintaining dyeing power. . In addition, when a multi-agent type, for example, a first agent containing mainly a component for dyeing hair, a component that mainly gives a treatment effect, and a second agent that contains a component that gives a treatment effect, After applying one agent to the hair, the treatment effect can be maintained by applying the second agent to the hair.
本発明に係る染毛料は、（Ａ）塩基性染料、（Ｂ）芳香族アルコール、（Ｃ）カチオン界面活性剤、（Ｄ）ノニオン界面活性剤、（Ｅ）ジメチコンもしくはジメチコノールを必須含有成分とする。なお、本発明に係る染毛料は、上記各必須成分を含む（例えば、溶媒は水とする）乳化状態の染毛料である。 The hair dye according to the present invention contains (A) a basic dye, (B) an aromatic alcohol, (C) a cationic surfactant, (D) a nonionic surfactant, (E) dimethicone or dimethiconol as an essential component. . In addition, the hair dye which concerns on this invention is a hair dye of the emulsified state containing each said essential component (for example, a solvent shall be water).
また、本発明に係る染毛料は、上記（Ａ）〜（Ｅ）の各必須成分に加えて、（Ｆ）アミノ変性シリコーン、（Ｇ）ポリエーテル変性シリコーン、（Ｈ）高級アルコールを配合してもよい。つまり、上記（Ａ）〜（Ｅ）の各必須成分に加えて、上記成分（Ｆ）、（Ｇ）、（Ｈ）を１種類単独、または２種類以上を適宜組み合わせて配合してもよい。 Moreover, the hair dye which concerns on this invention mix | blends (F) amino modified silicone, (G) polyether modified silicone, and (H) higher alcohol in addition to each essential component of said (A)-(E). Also good. That is, in addition to the essential components (A) to (E), the components (F), (G), and (H) may be used alone or in combination of two or more.
一般的に、ジェル状の毛髪料が多く知られているが、特にヘアマニキュアにおいては、高粘度の増粘剤が使用されているところ、施術後の毛髪に当該増粘剤が残り、ハリや硬さや、被膜感が出るといった問題点があった。そのため、粘度の低い、例えば、乳化系の染毛料（ヘアマニキュア）が望まれていた。 In general, many gel-like hair preparations are known. Particularly in hair manicure, a thickener is used. There were problems such as hardness and a feeling of coating. Therefore, for example, an emulsified hair dye (hair manicure) having a low viscosity has been desired.
また、染毛料の主たる目的は毛髪を染色するものであるところ、毛髪に対して染料を効果的に浸透させるために、一般的には、ベンジルアルコールに代表される芳香族アルコールが、当該染毛料に配合されている。なお、染毛料に配合されている芳香族アルコールは、効果的に染料を毛髪へ浸透させることができるものの、乳化系の染毛料とした場合、乳化状態を不安定にすることが知られている。従って、乳化系の染毛料を得る場合、当該芳香族アルコールを配合しない方が好ましい。しかしながら、上述したように、芳香族アルコールは、染料を毛髪へ浸透させる効果に寄与しているので、染毛料において、芳香族アルコールを配合しない場合、染毛料の主たる目的を達成することができない虞がある。 The main purpose of hair dyes is to dye hair. In order to effectively permeate dyes into hair, generally aromatic alcohols typified by benzyl alcohol are used. It is blended. In addition, although the aromatic alcohol mix | blended with hair dye can permeate | transmit a dye effectively to hair, when it is set as an emulsification type hair dye, it is known that an emulsified state will become unstable. . Therefore, when obtaining an emulsified hair dye, it is preferable not to mix the aromatic alcohol. However, as described above, the aromatic alcohol contributes to the effect of allowing the dye to penetrate into the hair. Therefore, if the aromatic alcohol is not blended in the hair dye, the main purpose of the hair dye may not be achieved. There is.
本出願人は、鋭意検討した結果、上述した成分（Ａ）〜（Ｅ）を必須成分とする染毛料とすることにより染色力を維持しつつ、かつ、剤型を乳化物としたことにより施術後においても、毛髪に柔軟性や指通りの良さ（毛髪の滑り性）を与えるといったトリートメント効果を有する染毛料を得るに至った。 As a result of diligent study, the applicant of the present invention maintains the dyeing power by using the above-described components (A) to (E) as essential components and maintains the dyeing power, and makes the dosage form an emulsion. Later, the present inventors have obtained a hair dye having a treatment effect such as imparting flexibility and good fingering (sliding property of hair) to the hair.
以下、本発明を詳細に説明するが、これらの説明は本発明を限定するものではない。従って、本発明の範囲を逸脱することなく種々の改良や変形を行うことができることは言うまでもない。 Hereinafter, the present invention will be described in detail, but these descriptions do not limit the present invention. Accordingly, it goes without saying that various improvements and modifications can be made without departing from the scope of the present invention.
（Ａ）塩基性染料
上記塩基性染料は、分子内にアミノ基、または置換アミノ基をもった色素、もしくはその塩類の構造をした染料であり、一般にその色調は、あざやかで、染色性、堅牢性も良い。なお、上記塩基性染料としては、例えば、赤色２１３号、赤色２１４号、Basic Blue 3、Basic Blue 6、Basic Blue 7、Basic Blue 9、Basic Blue 26、Basic Blue 41、Basic Blue 99、Basic Brown 4、Basic Brown 16、Basic Brown 17、Basic Brown 1、Basic Brown 4、Basic Orange 1、Basic Orange 2、Basic Red 1、Basic Red 2、Basic Red 22、Basic Red 46、Basic Red 76、Basic Red 118、Basic Violet 1、Basic Violet 3、Basic Violet 4、Basic Violet 10、Basic Violet 11:1、Basic Violet 14、Basic Violet 16、Basic Yellow 11、Basic Yellow 28、Basic Yellow 57などを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。
(A) Basic dye The basic dye is a dye having an amino group or substituted amino group in the molecule, or a salt thereof, and generally has a vivid color tone, dyeability and fastness. Good nature. Examples of the basic dye include Red No. 213, Red No. 214, Basic Blue 3, Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41, Basic Blue 99, Basic Brown 4 , Basic Brown 16, Basic Brown 17, Basic Brown 1, Basic Brown 4, Basic Orange 1, Basic Orange 2, Basic Red 1, Basic Red 2, Basic Red 22, Basic Red 46, Basic Red 76, Basic Red 118, Basic Violet 1, Basic Violet 3, Basic Violet 4, Basic Violet 10, Basic Violet 11: 1, Basic Violet 14, Basic Violet 16, Basic Yellow 11, Basic Yellow 28, Basic Yellow 57, etc. Or you may mix | blend combining 2 or more types suitably.
なお、上記塩基性染料に加えて、以下の直接染料、分散染料、天然色素を１種類単独、または２種類以上を適宜組み合わせて配合してもよい。 In addition to the above basic dye, the following direct dyes, disperse dyes, and natural pigments may be used alone or in combination of two or more.
上記直接染料としては、例えば、４−ニトロ−ｏ−フェニレンジアミン、２−ニトロ−ｐ−フェニレンジアミン、２−アミノ−４−ニトロフェノール、２−アミノ−５−ニトロフェノール、ピクラミン酸、ピクリン酸、およびそれらの塩類、HC Blue No.2、HC Blue No.4、HC Blue No.5、HC Blue No.6、HC Blue No.8、HC Blue No.9、HC Blue No.10、HC Blue No.11、HC Blue No.12、HC Blue No.13、HC Blue No.14、HC Brown No.1、HC Brown No.2、HC Green No.1、HC Orange No.1、HC Orange No.2、HC Orange No.3、HC Orange No.5、HC Red No.1、HC Red No.3、HC Red No.7、HC Red No.8、HC Red No.9、HC Red No.10、HC Red No.11、HC Red No.13、HC Red No.14、HC Violet No.1、HC Violet No.2、HC Yellow No.4、HC Yellow No.5、HC Yellow No.6、HC Yellow No.7、HC Yellow No.8、HC Yellow No.9、HC Yellow No.10、HC Yellow No.11、HC Yellow No.12、HC Yellow No.13、HC Yellow No.14、HC Yellow No.15などを挙げることができ、上記塩基性染料とともに、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。 Examples of the direct dye include 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, picramic acid, picric acid, And their salts, HC Blue No.2, HC Blue No.4, HC Blue No.5, HC Blue No.6, HC Blue No.8, HC Blue No.9, HC Blue No.10, HC Blue No .11, HC Blue No.12, HC Blue No.13, HC Blue No.14, HC Brown No.1, HC Brown No.2, HC Green No.1, HC Orange No.1, HC Orange No.2 , HC Orange No.3, HC Orange No.5, HC Red No.1, HC Red No.3, HC Red No.7, HC Red No.8, HC Red No.9, HC Red No.10, HC Red No. 11, HC Red No. 13, HC Red No. 14, HC Violet No. 1, HC Violet No. 2, HC Yellow No. 4, HC Yellow No. 5, HC Yellow No. 6, HC Yellow No .7, HC Yellow No. 8, HC Yellow No. 9, HC Yellow No. 10, HC Yellow No. 11, HC Yellow No. 12, HC Yellow No. 13, HC Yellow No. 14, HC Yellow No. 15 Etc. Bets can be, together with the basic dye may be formulated in combination singly, or two or more types as appropriate.
上記分散染料としては、例えば、Disperse Black 9、Disperse Blue 1、Disperse Blue 3、Disperse Blue 7、Disperse Brown 4、Disperse Orange 3、Disperse Red 11、Disperse Red 15、Disperse Red 17、Disperse Violet 1、Disperse Violet 4、Disperse Violet 15などを挙げることができ、上記塩基性染料とともに、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。 Examples of the disperse dye include Disperse Black 9, Disperse Blue 1, Disperse Blue 3, Disperse Blue 7, Disperse Brown 4, Disperse Orange 3, Disperse Red 11, Disperse Red 15, Disperse Red 17, Disperse Violet 1, Disperse Violet 4, Disperse Violet 15 and the like, and together with the basic dye, one kind may be used alone, or two or more kinds may be used in appropriate combination.
上記天然色素としては、例えば、クチナシ色素、ウコン色素、ベニバナ色素、コチニール色素、シソ色素、ラック色素、銅クロロフィリンナトリウムなどを挙げることができ、上記塩基性染料とともに、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。 Examples of the natural pigments include gardenia pigments, turmeric pigments, safflower pigments, cochineal pigments, perilla pigments, lac pigments, and copper chlorophyllin sodium, and together with the basic dye, one type alone or two or more types. May be combined as appropriate.
（Ｂ）芳香族アルコール
上記芳香族アルコールは、ベンゼン環に直接置換しないヒドロキシ基を持つアルコール類のことであり、上記塩基性染料の毛髪への浸透を促進し、染色性を高める効果がある。なお、上記芳香族アルコールとしては、例えば、ベンジルアルコール、２−フェニルエチルアルコール、シンナミルアルコール、フェニルプロパノール、１−フェノキシ−２−プロパノール、フェニルジグリコール、α−メチルベンジルアルコール、ジメチルベンジルカルビノール、ベンジルオキシエタノール、フェノキシエタノール、フェノキシイソプロパノール、ｐ−アニシルアルコールなどを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。
(B) Aromatic alcohol The aromatic alcohol is an alcohol having a hydroxy group that is not directly substituted on the benzene ring, and has the effect of promoting the penetration of the basic dye into the hair and enhancing the dyeability. Examples of the aromatic alcohol include benzyl alcohol, 2-phenylethyl alcohol, cinnamyl alcohol, phenylpropanol, 1-phenoxy-2-propanol, phenyl diglycol, α-methylbenzyl alcohol, dimethylbenzyl carbinol, Benzyloxyethanol, phenoxyethanol, phenoxyisopropanol, p-anisyl alcohol and the like can be mentioned, and one kind alone or two or more kinds may be appropriately combined.
なお、上記染毛料中の芳香族アルコールの濃度（上記染毛料における配合量）は、０．１重量％以上、好ましくは０．５重量％〜６重量％、より好ましくは２重量％〜５重量％である。 The concentration of the aromatic alcohol in the hair dye (the blending amount in the hair dye) is 0.1% by weight or more, preferably 0.5% by weight to 6% by weight, more preferably 2% by weight to 5% by weight. %.
（Ｃ）カチオン界面活性剤
上記カチオン界面活性剤は、施術後（ヘアマニキュアを塗布し洗い流した後）の毛髪に対するごわつき、軋みを解消する効果、言い換えると、毛髪に特に柔軟性を付与できるといった効果がある。なお、上記カチオン界面活性剤としては、例えば、セトリモニウムクロリド、ステアリルトリモニウムクロリド、ベヘントリモニウムクロリド、ジココジモニウムクロリド、ジステアリウムジモニウムクロリド、セトリモニウムブロミド、ステアリルトリモニウムブロミド、ベヘントリモニウムブロミドなどを挙げることができる。なお、上述したカチオン界面活性剤を、１種類単独、または２種類以上を適宜組み合わせて配合してもよいが、毛髪に柔軟性を与える効果においては、上述した中でも、セトリモニウムクロリドおよび／またはステアリルトリモニウムクロリドを配合するのが好ましい。
(C) Cationic surfactant The cationic surfactant has the effect of eliminating stiffness and itchiness on the hair after treatment (after applying hair nail polish and washing away), in other words, the effect of being able to impart particularly flexibility to the hair. There is. Examples of the cationic surfactant include cetrimonium chloride, stearyltrimonium chloride, behentrimonium chloride, dicocodimonium chloride, distearium dimonium chloride, cetrimonium bromide, stearyltrimonium bromide, behentrimonium. A bromide etc. can be mentioned. The above-mentioned cationic surfactant may be blended alone or in combination of two or more, but in the effect of imparting flexibility to the hair, among the above, cetrimonium chloride and / or stearyl Trimonium chloride is preferably blended.
（Ｄ）ノニオン界面活性剤
上記ノニオン界面活性剤は、上記染毛料が乳化物の場合、乳化状態の安定化に効果がある。なお、上記ノニオン界面活性剤としては、例えば、ラウレス−２〜４０、セテス−２〜４０、ステアレス−２〜４０、ベヘネス−２〜４０、オレス-２〜４０、ＰＥＧ−(５〜１０)水添ヒマシ油、脂肪酸グリセリル、ポリグリセリン脂肪酸エステルなどを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。
(D) Nonionic surfactant The said nonionic surfactant is effective in stabilization of an emulsified state, when the said hair dye is an emulsion. Examples of the nonionic surfactant include laureth-2 to 40, ceteth-2 to 40, steareth-2 to 40, behenez-2 to 40, oleth-2 to 40, PEG- (5 to 10) water. Examples thereof include added castor oil, fatty acid glyceryl, polyglycerin fatty acid ester, and the like. One kind alone or two or more kinds may be blended as appropriate.
なお、上記染毛料に配合するノニオン界面活性剤は、ＨＬＢ（Hydrophile-Lipophile Balance、以下単にＨＬＢと記す）の値が５〜１５程度のものを用いるのが好ましい。また、上記染毛料に配合するノニオン界面活性剤は、特に、ポリオキシエチレンアルキルエーテルが好ましい。 In addition, it is preferable to use the nonionic surfactant with which the value of HLB (Hydrophile-Lipophile Balance, hereinafter abbreviated as HLB) is about 5 to 15 as the nonionic surfactant to be blended in the hair dye. The nonionic surfactant to be blended in the hair dye is particularly preferably polyoxyethylene alkyl ether.
（Ｅ）ジメチコン、ジメチコノール
上記ジメチコン、ジメチコノールとは、ポリシロキサン誘導体のことであり、毛髪の滑り性（指通り性）を良好にする効果がある。なお、上記ジメチコン、ジメチコノールの粘度については特に限定されるものでは無いが、髪の滑り性（指通り性）を良好にする観点から、粘度が１００００ＣＰ〜２０００００００ＣＰ（１×１０4ＣＰ〜２×１０7ＣＰ）程度、好ましくは１０００００ＣＰ〜２０００００００ＣＰ（１×１０5ＣＰ〜２×１０7ＣＰ）程度の高重合ジメチコン、高重合ジメチコノールを配合するのが好ましい。また、上記染毛料には、単独または複数、つまりジメチコンのみ、ジメチコノールのみ、ジメチコンおよびジメチコノールが配合されてもよく、エマルションタイプのジメチコン、ジメチコノールを使用しても良い。なお、上記ジメチコンおよびジメチコノールはノニオン性増粘剤を含まないものが好ましい。
(E) Dimethicone and dimethiconol The above-mentioned dimethicone and dimethiconol are polysiloxane derivatives and have an effect of improving the slipperiness (handing property) of hair. The viscosity of the dimethicone and dimethiconol is not particularly limited, but the viscosity is 10,000 CP to 20000000 CP (1 × 10 4 CP to 2 × 10) from the viewpoint of improving the slipperiness (handing property) of the hair. 7 CP), preferably about 100000 CP to 20000000 CP (1 × 10 5 CP to 2 × 10 7 CP) of highly polymerized dimethicone and highly polymerized dimethiconol. The hair dye may contain one or more, that is, only dimethicone, only dimethiconol, dimethicone and dimethiconol, or may use emulsion type dimethicone or dimethiconol. The dimethicone and dimethiconol preferably do not contain a nonionic thickener.
（Ｆ）アミノ変性シリコーン
上記アミノ変性シリコーンとは、ジメチコン骨格の一部がアミノ化されたものを指し、毛髪の滑り性、特に毛髪に柔軟性を付与するのに効果がある。なお、上記アミノ変性シリコーンとしては、例えば、アモジメチコン、ビス（ヒドロキシ／メトキシ）アモジメチコン、（ビスイソブチルＰＥＧ−１４／アモジメチコン）コポリマー、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーなどを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。
(F) Amino-modified silicone The above-mentioned amino-modified silicone refers to a part of the dimethicone skeleton that is aminated, and is effective in imparting slidability of hair, in particular, flexibility to hair. Examples of the amino-modified silicone include amodimethicone, bis (hydroxy / methoxy) amodimethicone, (bisisobutyl PEG-14 / amodimethicone) copolymer, and (alkyl acrylate / diacetone acrylamide) copolymer. It can be used alone or in combination of two or more.
（Ｇ）ポリエーテル変性シリコーン
上記ポリエーテル変性シリコーンは、ジメチコンの主鎖および側鎖にポリオキシエチレンが導入されたシリコーン重合体を指す。なお、ポリエーテル変性シリコーンとしては、具体的には、ＰＥＧ３〜２５ジメチコン、ＰＥＧ／ＰＰＧ−３〜２５／３〜２５ジメチコン、ポリオキシシリコーン−１３、ＰＥＧ−３〜２５メチルエーテルジメチコンなどを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。なお、上記染毛料に配合するポリエーテル変性シリコーンは、主鎖中にポリエーテル基を含むものを用いるのが好ましい。
(G) Polyether-modified silicone The polyether-modified silicone refers to a silicone polymer in which polyoxyethylene is introduced into the main chain and side chain of dimethicone. Specific examples of the polyether-modified silicone include PEG 3-25 dimethicone, PEG / PPG-3-25 / 3-25 dimethicone, polyoxysilicone-13, PEG-3-25 methyl ether dimethicone, and the like. One kind alone or two or more kinds may be blended as appropriate. In addition, it is preferable to use what contains a polyether group in a principal chain for the polyether modified silicone mix | blended with the said hair dye.
また、上記染毛料に配合するポリエーテル変性シリコーンは、ＨＬＢの値が７未満のものを用いるのが好ましい。 Moreover, it is preferable to use a polyether-modified silicone blended in the hair dye having an HLB value of less than 7.
（Ｈ）高級アルコール
上記高級アルコールとは、分子量の大きなアルコール類であり、通常、炭素数１０以上のものを指し、上記染毛料が乳化物の場合、乳化状態の安定化に効果がある。なお、上記高級アルコールとしては、例えば、セタノール、ステアリルアルコール、ミリスチルアルコール、ベヘニルアルコールなどを挙げることができ、１種類単独、または２種類以上を適宜組み合わせて配合してもよい。また、染毛料中の高級アルコールの好ましい濃度（染毛料における配合量）は、３質量％〜１５質量％である。
(H) Higher alcohol The higher alcohol is an alcohol having a large molecular weight, and usually refers to those having 10 or more carbon atoms. When the hair dye is an emulsion, it is effective in stabilizing the emulsified state. Examples of the higher alcohol include cetanol, stearyl alcohol, myristyl alcohol, behenyl alcohol, and the like. One kind alone or two or more kinds may be blended as appropriate. Moreover, the preferable density | concentration (blending amount in hair dye) of the higher alcohol in hair dye is 3 mass%-15 mass%.
また、上記染毛料には、上述した必須成分（Ａ）〜（Ｅ）、また当該必須成分に加えて配合される、成分（Ｆ）、（Ｇ）、（Ｈ）の他、必要に応じて保湿剤、ＰＰＴ類、植物抽出エキス、防腐剤、酸化防止剤、紫外線吸収剤、キレート剤、溶剤、ｐＨ調整剤、消臭剤、色素や香料等を適宜配合してもよい。 In addition to the above-described essential components (A) to (E) and components (F), (G), and (H) that are blended in addition to the essential components, the hair dye as necessary. Moisturizers, PPTs, plant extracts, preservatives, antioxidants, ultraviolet absorbers, chelating agents, solvents, pH adjusters, deodorants, pigments and fragrances may be appropriately blended.
このように、本発明に係る染毛料は、（Ａ）塩基性染料、（Ｂ）芳香族アルコール、（Ｃ）カチオン界面活性剤、（Ｄ）ノニオン界面活性剤、（Ｅ）ジメチコンもしくはジメチコノールを必須含有成分とする。なお、本発明に係る染毛料は、上記各必須成分を含む（例えば、溶媒は水とする）乳化状態の染毛料、つまり、当該毛髪料は乳化物である。また、必要に応じて上記（Ａ）〜（Ｅ）の各必須成分に加えて、（Ｆ）アミノ変性シリコーン、（Ｇ）ポリエーテル変性シリコーン、（Ｈ）高級アルコールを配合されてなるものである。 As described above, the hair dye according to the present invention must contain (A) a basic dye, (B) an aromatic alcohol, (C) a cationic surfactant, (D) a nonionic surfactant, (E) dimethicone or dimethiconol. Contains. In addition, the hair dye which concerns on this invention contains the said each essential component (for example, a solvent shall be water) in the emulsified state, ie, the said hair dye is an emulsion. In addition to the essential components (A) to (E), (F) amino-modified silicone, (G) polyether-modified silicone, and (H) higher alcohol are blended as necessary. .
なお、本発明に係る染毛料は、上記必須成分をすべて含ませた単剤式の染毛料である形態に限らず、多剤式の染毛料としてもよい。例えば、本発明に係る染毛料を第１剤と第２剤とからなる多剤式の染毛料とすることも可能である。 The hair dye according to the present invention is not limited to a single-component hair dye containing all the essential components, and may be a multi-component hair dye. For example, the hair dye according to the present invention may be a multi-component hair dye composed of a first agent and a second agent.
例えば、第１剤には、上記成分（Ａ）〜（Ｅ）が配合され、第２剤には上記成分（Ｃ）および（Ｅ）に加えて、（Ｆ）アミノ変性シリコーンが配合されてもよい。また、第１剤には、上記成分（Ａ）〜（Ｅ）および、（Ｆ）アミノ変性シリコーンが配合され、第２剤には上記成分（Ｃ）および（Ｅ）に加えて、（Ｆ）アミノ変性シリコーンが配合されてもよい。さらに、第１剤には、上記成分（Ａ）〜（Ｅ）および、（Ｆ）アミノ変性シリコーン、（Ｇ）ポリエーテル変性シリコーンが配合され、第２剤には上記成分（Ｃ）および（Ｅ）に加えて、（Ｆ）アミノ変性シリコーンが配合されてもよい。なお、上述した剤型の態様は一例であり、剤型の態様をまとめると以下のようになる。 For example, the first agent contains the components (A) to (E), and the second agent may contain (F) an amino-modified silicone in addition to the components (C) and (E). Good. The first agent contains the components (A) to (E) and (F) amino-modified silicone, and the second agent contains (F) in addition to the components (C) and (E). An amino-modified silicone may be blended. Furthermore, the above-mentioned components (A) to (E) and (F) amino-modified silicone and (G) polyether-modified silicone are blended in the first agent, and the above-mentioned components (C) and (E) are blended in the second agent. In addition, (F) amino-modified silicone may be blended. In addition, the aspect of the dosage form mentioned above is an example, and it is as follows when the aspect of a dosage form is put together.
つまり、第１剤には、主に毛髪を染色するための成分、主にトリートメント効果を与える成分（必要に応じて乳化を安定化する成分、例えば（Ｈ）高級アルコールなど）が含まれていればよく、第２剤には、主にトリートメント効果を与える成分（必要に応じて乳化を安定化する成分、例えば（Ｈ）高級アルコールなど）が含まれていればよい。なお、第１剤と第２剤とに限られるものではなく、主に毛髪を染色するための成分、主にトリートメント効果を与える成分（必要に応じて乳化を安定化する成分）が含まれている染毛料とする第１剤に加えて、トリートメント効果を与える成分が含有されている処理剤とする第２剤および第３剤としても良く、つまり実際のヘアサロン等で許容される範囲でトリートメント効果を与える成分が含有されている処理剤を複数（第２剤、第３剤、さらには第４剤）備えてもよい。 In other words, the first agent mainly contains a component for dyeing hair, and a component that mainly gives a treatment effect (a component that stabilizes emulsification as necessary, for example, (H) a higher alcohol). What is necessary is just to contain the component (The component which stabilizes emulsification as needed, for example, (H) higher alcohol etc.) which mainly gives the treatment effect in the 2nd agent. In addition, it is not restricted to 1st agent and 2nd agent, The component for dyeing hair mainly and the component (component which stabilizes emulsification as needed) mainly containing the treatment effect are included. In addition to the first agent used as a hair dye, the second agent and the third agent used as treatment agents containing a treatment effect component may be used. In other words, the treatment effect is within the range allowed in an actual hair salon. A plurality of treatment agents (second agent, third agent, and further fourth agent) containing a component that provides the above may be provided.
なお、本発明に係る染毛料を多剤式、例えば２剤式とした場合の施術例としては、第１剤を毛髪に塗布した後、次いで、第２剤を毛髪に塗布する。また、第１剤を毛髪に塗布した後、第２剤を毛髪に塗布する前の処置としては、プレーンリンスまたはシャンプー後プレーンリンスが好ましい。 In addition, as an example of treatment when the hair dye according to the present invention is a multi-component type, for example, a two-component type, after the first agent is applied to the hair, the second agent is then applied to the hair. In addition, as a treatment after applying the first agent to the hair and before applying the second agent to the hair, plain rinse or plain rinse after shampooing is preferable.
以下、本発明を実施例および比較例に基づき更に詳細に説明するが、本発明の実施例のみに限定されるのではなく、本発明の効果を損なわない量的質的範囲で、各含有成分の組成の組み合わせや配合量を変更してもよい。 Hereinafter, the present invention will be described in more detail based on examples and comparative examples. However, the present invention is not limited only to the examples of the present invention, and each component contained in a quantitative and qualitative range that does not impair the effects of the present invention. You may change the combination and compounding quantity of these.
〈試料の調製〉
表１〜表８に記載した組成に従い、実施例１〜実施例３６、および比較例１〜１２の各染毛料を調製し、以下の評価に供した。なお、評価結果は、表１〜表８にそれぞれ併記した。また、特に断らない限り、表１〜８の数値は重量％である。
<Preparation of sample>
Each hair dye of Examples 1 to 36 and Comparative Examples 1 to 12 was prepared according to the composition described in Tables 1 to 8 and subjected to the following evaluation. In addition, the evaluation result was written together in Table 1-Table 8, respectively. Moreover, unless otherwise indicated, the numerical value of Tables 1-8 is weight%.
〈試験例１：染色力（染色性についての評価）〉
染毛処理用白色ヤク毛束１ｇに対し各実施例および比較例にそれぞれに係る染毛料２ｇを、当該毛束に均一に塗布し、４０℃の条件下で１０分間放置した。その後、毛束をよく水洗し、乾燥した毛束の染色性を評価した。なお、染色性についての評価は、パネラー１０名が標準光源下で目視にて染色度合い（染色力）を下記の評点に基づいて４段階で評価した。具体的には、各パネラーが下記の基準で採点した。
<Test Example 1: Dyeing power (evaluation of dyeability)>
2 g of the hair dye according to each of the examples and comparative examples was uniformly applied to 1 g of the white yak hair bundle for hair dyeing treatment and allowed to stand at 40 ° C. for 10 minutes. Thereafter, the hair bundle was washed thoroughly with water, and the dyeability of the dried hair bundle was evaluated. In addition, evaluation about dyeing | staining property evaluated the dyeing | staining degree (dyeing power) in four steps based on the following ratings visually by 10 panelists under a standard light source. Specifically, each panel scored according to the following criteria.
３点：しっかり染まっている
２点：染まっている
１点：やや染まっている
０点：殆ど染まっていない
3 points: Stained well 2 points: Stained 1 point: Slightly stained 0 point: Almost unstained
そして、表１〜表８には、上記評価項目についてのパネラー１０名の合計点を集計し、評価項目の総合評価（評価結果）として下記のように示した。 And in Table 1-Table 8, the total score of 10 panelists about the said evaluation item was totaled, and it showed as follows as comprehensive evaluation (evaluation result) of an evaluation item.
◎：合計点数が２３〜３０点
○：合計点数が１５〜２２点
△：合計点数が７〜１４点
×：合計点数が０〜６点
◎: Total score is 23-30 points ○: Total score is 15-22 points △: Total score is 7-14 points ×: Total score is 0-6 points
〈試験例２：色持ち（色の持続性についての評価）〉
染毛処理用白色ヤク毛束１ｇに対し各実施例および比較例にそれぞれに係る染毛料２ｇを、当該毛束に均一に塗布し、４０℃の条件下で１０分間放置した。その後、当該各毛束を１％のラウリル硫酸ナトリウム水溶液で洗浄し、さらに水洗するといった工程を１０回繰り返した。なお、毛束を１％のラウリル硫酸ナトリウム水溶液で洗浄し、さらに水洗するといった工程を以下では仮に洗浄工程と称す。そして、当該各毛束を乾燥させ、色持ちを評価した。なお、色持ちについての評価は、パネラー１０名が標準光源下で目視にて、処理前後の色の差（染毛料を塗布する前の各毛束色と洗浄工程を経た後の各毛束の色の差）を下記の評点に基づいて４段階で評価した。具体的には、各パネラーが下記の基準で採点した。
<Test Example 2: Color retention (evaluation of color persistence)>
2 g of the hair dye according to each of the examples and comparative examples was uniformly applied to 1 g of the white yak hair bundle for hair dyeing treatment and allowed to stand at 40 ° C. for 10 minutes. Then, the process of washing each hair bundle with a 1% sodium lauryl sulfate aqueous solution and further washing with water was repeated 10 times. In addition, the process of washing the hair bundle with 1% sodium lauryl sulfate aqueous solution and further washing with water is hereinafter referred to as a washing process. And each said hair | bristle bundle was dried and the color last was evaluated. In addition, the evaluation about the color durability was performed by visually comparing 10 panelists under a standard light source with a difference in color before and after the treatment (each hair bundle color before applying the hair dye and each hair bundle after passing through the washing step). The color difference was evaluated in four stages based on the following scores. Specifically, each panel scored according to the following criteria.
３点：殆ど褪色していない
２点：やや褪色している
１点：褪色している
０点：殆ど褪色した
3 points: Almost fading 2 points: Slightly fading 1 point: Fading 0 points: Almost fading
そして、表１〜表８には、上記評価項目についてのパネラー１０名の合計点を集計し、評価項目の総合評価（評価結果）として下記のように示した。 And in Table 1-Table 8, the total score of 10 panelists about the said evaluation item was totaled, and it showed as follows as comprehensive evaluation (evaluation result) of an evaluation item.
◎：合計点数が２３〜３０点
○：合計点数が１５〜２２点
△：合計点数が７〜１４点
×：合計点数が０〜６点
◎: Total score is 23-30 points ○: Total score is 15-22 points △: Total score is 7-14 points ×: Total score is 0-6 points
〈試験例３：（施術後の毛髪の）感触〉
ヘアカラーリングをしている２０代〜３０代の女性１０名（毛髪の長さ：セミロングヘア〜ロングヘア）をパネラーとして、各パネラーがシャンプー（洗髪）処理を行った後、各実施例および比較例にそれぞれに係る染毛料を毛髪全体に塗布した。そして、塗布後、１０分放置した後、毛髪を良く水洗、乾燥させ、施術後の毛髪の感触について評価した。具体的には、下記の評点に基づいて、トリートメント効果（「毛髪の柔軟性」、「毛髪の滑り性」）について４段階で評価し、下記の基準で採点した。
<Test Example 3: Feel of hair after treatment>
Each panelist performed shampooing (hair washing) treatment with 10 females in their 20s to 30s doing hair coloring (hair length: semi-long hair to long hair), and then each example and comparative example. The hair dye according to each was applied to the entire hair. And after leaving for 10 minutes after application | coating, the hair was washed with water well and dried, and the touch of the hair after treatment was evaluated. Specifically, based on the following scores, treatment effects (“hair flexibility”, “hair slipperiness”) were evaluated in four stages, and scored according to the following criteria.
３点：非常に良い
２点：やや良い
１点：やや悪い
０点：非常に悪い
3 points: Very good 2 points: Somewhat good 1 point: Somewhat bad 0 point: Very bad
そして、表１〜表８には、上記評価項目についてのパネラー１０名の合計点を集計し、評価項目の総合評価（評価結果）として下記のように示した。 And in Table 1-Table 8, the total score of 10 panelists about the said evaluation item was totaled, and it showed as follows as comprehensive evaluation (evaluation result) of an evaluation item.
◎：合計点数が２３〜３０点
○：合計点数が１５〜２２点
△：合計点数が７〜１４点
×：合計点数が０〜６点
◎: Total score is 23-30 points ○: Total score is 15-22 points △: Total score is 7-14 points ×: Total score is 0-6 points
〈試験例４：乳化状態の安定性〉
各実施例および比較例にそれぞれ係る染毛料の乳化状態の安定性は、各実施例および比較例にそれぞれ係る染毛料を透明なガラス容器に入れ、５０℃、２週間の条件下で放置した後、目視にて分離状態を確認し判断した。そして、下記の評点に基づいて４段階で評価した。
<Test Example 4: Stability of emulsified state>
The stability of the emulsified state of the hair dyes according to the respective examples and comparative examples is determined by placing the hair dyes according to the respective examples and comparative examples in transparent glass containers and leaving them at 50 ° C. for 2 weeks. The separation state was visually confirmed and judged. And it evaluated in four steps based on the following score.
◎：分離が全く見られない
○：僅かに分離が見られる
△：分離が見られる
×：大部分に分離が見られる
◎: No separation observed ○: Slight separation observed △: Separation observed ×: Mostly separated
〈試験例５：持続性（施術後のトリートメント効果の持続性）〉
ヘアカラーリングをしている２０代〜３０代の女性１０名（毛髪の長さ：セミロングヘア〜ロングヘア）をパネラーとして、各パネラーがシャンプー（洗髪）処理を行った後、実施例１に係る染毛料（第１剤と称す）を毛髪全体に塗布した。そして、塗布後、１０分放置した後、毛髪を水洗し、実施例３５〜３６および比較例１１にそれぞれ係る染毛料の何れか１の染毛料（第２剤と称す）を毛髪全体に塗布し水洗した後に評価を行った。具体的には、当該施術直後の感触（柔軟性、滑り性）と、１週間後の感触（柔軟性、滑り性）とを比較し、トリートメント効果（「毛髪の柔軟性」、「毛髪の滑り性」）が持続しているか否かで４段階で評価し、下記の基準で採点した。
<Test Example 5: Sustainability (sustainability of treatment effect after treatment)>
After the panelists were 10 women in their 20s to 30s who are doing hair coloring (hair length: semi-long hair to long hair), each paneler performed a shampoo treatment, and then the dyeing according to Example 1 Hair (referred to as the first agent) was applied to the entire hair. And after leaving for 10 minutes after application | coating, the hair is washed with water and the hair dye (referred to as the second agent) of any one of the hair dyes according to Examples 35 to 36 and Comparative Example 11 is applied to the entire hair. Evaluation was performed after washing with water. Specifically, the feeling immediately after the treatment (flexibility, slipperiness) was compared with the feel after one week (flexibility, slipperiness), and the treatment effects (“hair flexibility”, “hair slippage” The evaluation was made on a four-point scale based on whether or not “sex” was sustained, and was scored according to the following criteria.
３点：施術直後の感触が持続している
２点：施術直後の感触がやや持続している
１点：施術直後の感触があまり持続していない
０点：施術直後の感触が持続していない
3 points: Feeling immediately after the treatment is sustained 2 points: Feeling immediately after the treatment is slightly sustained 1 point: Feeling immediately after the treatment is not so persistent 0 point: Feeling immediately after the treatment is not sustained
そして、表８には、上記評価項目についてのパネラー１０名の合計点を集計し、評価項目の総合評価（評価結果）として下記のように示した。 And in Table 8, the total score of 10 panelists about the said evaluation item was totaled, and it showed as follows as comprehensive evaluation (evaluation result) of an evaluation item.
◎：合計点数が２３〜３０点
○：合計点数が１５〜２２点
△：合計点数が７〜１４点
×：合計点数が０〜６点
◎: Total score is 23-30 points ○: Total score is 15-22 points △: Total score is 7-14 points ×: Total score is 0-6 points
なお、商品価値の観点からは各項目（試験例１〜試験例５）の総合評価がいずれも○以上の評価であることが望まれる。 In addition, from the viewpoint of commercial value, it is desired that the overall evaluation of each item (Test Example 1 to Test Example 5) is an evaluation of ◯ or more.
（実施例１〜実施例４、比較例１〜４）
表１に記載した組成に従い、実施例１〜実施例４および比較例１〜４にそれぞれに係る染毛料を調整し、上述の試験例１〜３に従って各染毛料を評価した。具体的には、実施例１〜実施例４および比較例１〜３にそれぞれに係る染毛料は、主に当該各染毛料のｐＨの値がそれぞれ異なる。
(Examples 1 to 4 and Comparative Examples 1 to 4)
According to the composition described in Table 1, hair dyes according to Examples 1 to 4 and Comparative Examples 1 to 4 were adjusted, and each hair dye was evaluated according to Test Examples 1 to 3 described above. Specifically, the hair dyes according to each of Examples 1 to 4 and Comparative Examples 1 to 3 mainly have different pH values for the respective hair dyes.
表１の実施例１〜実施例４にみられるように、何れも「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」についてそれぞれ良好な効果が得られた。一方、表１の比較例１〜比較例４にみられるように、何れも「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」についてそれぞれ良好な効果が得られなかった。 As can be seen from Examples 1 to 4 in Table 1, all have good effects on “dyeing power”, “color retention”, “feel (flexibility)”, and “feel (slidability)”. It was. On the other hand, as seen in Comparative Examples 1 to 4 in Table 1, all have good effects on “dyeing power”, “color retention”, “feel (flexibility)”, and “feel (slidability)”. Was not obtained.
つまり、染毛料のｐＨの値は６以上、９未満程度が好ましく、特に中性付近（ｐＨ＝７）がより好ましいことが分かった。言い換えると、染毛料のｐＨの値が９を超えると（塩基になるに従い）、毛髪に柔軟性や指通りの良さ（毛髪の滑り性）を与えるといったトリートメント効果について良好な結果は得られず、染毛料のｐＨの値が６未満であると、染毛料の主たる目的（染色力、色持ち）を達成できないことが分かった。 That is, it was found that the pH value of the hair dye is preferably about 6 or more and less than 9, and more preferably near neutrality (pH = 7). In other words, if the pH value of the hair dye exceeds 9 (as it becomes a base), good results cannot be obtained with respect to the treatment effect such as giving the hair flexibility or good fingering (hair slipperiness), It was found that the main purpose (dyeing power, color retention) of the hair dye could not be achieved when the pH value of the hair dye was less than 6.
なお、上述の試験例４に従って実施例１〜実施例４それぞれに係る染毛料を評価した結果、実施例１〜実施例４の何れも、「乳化状態の安定性」について分離が全く見られず、優れた結果が得られた。 In addition, as a result of evaluating the hair dye which concerns on each of Example 1-Example 4 according to the above-mentioned Test Example 4, as for any of Example 1-Example 4, separation is not seen at all about "stability of an emulsification state". Excellent results were obtained.
（実施例５〜実施例１７、比較例５〜６）
表２および表３に記載した組成に従い、実施例５〜実施例１７および比較例５〜６にそれぞれに係る染毛料を調整し、上述の試験例１〜４に従って各染毛料を評価した。具体的には、実施例５〜実施例１７および比較例５〜６にそれぞれに係る染毛料は、主に当該各染毛料に含有されている、ジメチコン、ジメチコノール（それぞれ粘度の違いを含む）、アミノ変性シリコーンがそれぞれ異なる。
(Examples 5 to 17 and Comparative Examples 5 to 6)
According to the compositions described in Table 2 and Table 3, hair dyes according to Examples 5 to 17 and Comparative Examples 5 to 6 were prepared, and each hair dye was evaluated according to Test Examples 1 to 4 described above. Specifically, the hair dyes according to Examples 5 to 17 and Comparative Examples 5 to 6, respectively, are mainly contained in the respective hair dyes, dimethicone, dimethiconol (each including a difference in viscosity), Each amino-modified silicone is different.
表２および表３の実施例５〜実施例１７にみられるように、何れも「染色力」、「色持ち」についてそれぞれ良好な効果が得られた。 As can be seen in Examples 5 to 17 of Table 2 and Table 3, good effects were obtained for both “dyeing power” and “color retention”.
また、表２および表３の実施例５〜実施例１７それぞれに係る染毛料と、比較例５〜６それぞれに係る染毛料とを比較すると、染毛料にジメチコンおよびジメチコノールの何れも配合されていない場合、特に「感触（柔軟性）」（つまり毛髪の柔軟性）について良好な結果を得ることができなかった。 Moreover, when the hair dye which concerns on each of Example 5-Example 17 of Table 2 and Table 3 and the hair dye which concerns on each of Comparative Examples 5-6 are compared, neither dimethicone nor dimethiconol is mix | blended with the hair dye. In particular, good results could not be obtained especially for “feel (flexibility)” (that is, flexibility of hair).
なお、表２および表３の実施例１２〜１７にみられるように、何れも「感触（柔軟性）」、「感触（滑り性）」ともに優れた効果が得られた。つまり、この結果より、染毛料にジメチコンやジメチコノールとともに、アミノ変性シリコーンが配合されているのが好ましいことが分かる。より具体的には、染毛料におけるジメチコンとジメチコノールとの重量の和（ジメチコンおよびジメチコノールの少なくとも何れか一方が含まれていればよい）の値が、アミノ変性シリコーンの重量の値を超えるのが好ましい。 As can be seen from Examples 12 to 17 in Table 2 and Table 3, both “feel (flexibility)” and “feel (slidability)” were excellent. That is, it can be seen from this result that amino-modified silicone is preferably blended with the hair dye together with dimethicone and dimethiconol. More specifically, it is preferable that the sum of the weights of dimethicone and dimethiconol in the hair dye (which should contain at least one of dimethicone and dimethiconol) exceeds the weight value of the amino-modified silicone. .
なお、上述の試験例４に従って実施例５〜実施例１７それぞれに係る染毛料を評価した結果、実施例５〜実施例１７の何れも、「乳化状態の安定性」について分離が全く見られないか、僅かに分離が見られる程度であり、良好な結果が得られた。 In addition, as a result of evaluating the hair dye which concerns on each of Example 5-Example 17 according to the above-mentioned Test example 4, as for any of Example 5- Example 17, separation is not seen at all about "stability of an emulsified state". In addition, only a slight separation was observed, and good results were obtained.
さらには、実施例１５〜１７にみられるように、染毛料にポリエーテル変性シリコーンが配合され、当該ポリエーテル変性シリコーンのＨＬＢの値が７未満のものを用いると、「乳化状態の安定性」について分離が全く見られず、優れた結果が得られた。 Furthermore, as seen in Examples 15 to 17, when a polyether-modified silicone is blended in the hair dye, and the HLB value of the polyether-modified silicone is less than 7, “emulsification stability” No separation was observed with respect to and excellent results were obtained.
（実施例１８〜実施例２２、比較例７）
表４に記載した組成に従い、実施例１８〜実施例２２および比較例７にそれぞれに係る染毛料を調整し、上述の試験例１〜４に従って各染毛料を評価した。具体的には、実施例１８〜実施例２２および比較例７にそれぞれに係る染毛料は、主に当該各染毛料に含有されている、ノニオン界面活性剤（ＨＬＢの値の違いを含む）がそれぞれ異なる。
(Examples 18 to 22, Comparative Example 7)
According to the compositions described in Table 4, hair dyes according to Examples 18 to 22 and Comparative Example 7 were prepared, and each hair dye was evaluated according to Test Examples 1 to 4 described above. Specifically, the hair dyes according to Examples 18 to 22 and Comparative Example 7 are nonionic surfactants (including differences in HLB values) mainly contained in the respective hair dyes. Each is different.
表４の実施例１８〜実施例２２にみられるように、「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」、についてそれぞれ良好な結果が得られ、「乳化状態の安定性」についても良好な結果が得られた。一方、表４の比較例７の「乳化状態の安定性」については、大部分に分離が見られ、良好な結果は得られなかった。 As can be seen from Example 18 to Example 22 in Table 4, good results were obtained for “dyeing power”, “color retention”, “feel (flexibility)”, and “feel (slidability)”. Also, good results were obtained for "stability of emulsified state". On the other hand, with regard to “stability in the emulsified state” of Comparative Example 7 in Table 4, most of the separation was observed, and good results were not obtained.
なお、例えば、実施例１９と、実施例２０〜２２とを比較すると、実施例１９の方が「乳化状態の安定性」について、優れた結果が得られた。つまり、上記染毛料の乳化安定化の観点から当該染毛料に配合するノニオン界面活性剤のＨＬＢの値は、５〜１５程度のものを用いるのが好ましい。また、実施例１８についても「乳化状態の安定性」について、優れた結果は得られ、ＨＬＢの値が５〜１５程度のノニオン界面活性剤が配合され、より好ましくは、ＨＬＢの値が５〜１５程度のノニオン界面活性剤とともに、比較的ＨＬＢの値が高い（１６以上、２０程度）ノニオン界面活性剤を配合するのが好ましい。 For example, when Example 19 was compared with Examples 20 to 22, Example 19 was superior in terms of “stability in the emulsified state”. That is, from the viewpoint of stabilizing the emulsification of the hair dye, it is preferable to use an HLB value of about 5 to 15 for the nonionic surfactant added to the hair dye. Moreover, about Example 18, the excellent result was acquired about "stability of an emulsified state", the nonionic surfactant whose HLB value is about 5-15 is mix | blended, More preferably, the value of HLB is 5-5. It is preferable to blend a nonionic surfactant having a relatively high HLB value (16 or more, about 20) with a nonionic surfactant of about 15.
（実施例２３〜実施例２４、比較例８）
表５に記載した組成に従い、実施例２３〜実施例２４および比較例８にそれぞれに係る染毛料を調整し、上述の試験例１〜４に従って各染毛料を評価した。具体的には、実施例２３〜実施例２４および比較例８にそれぞれに係る染毛料は、主に当該各染毛料に含有されている、高級アルコールがそれぞれ異なる。
(Example 23 to Example 24, Comparative Example 8)
According to the composition described in Table 5, hair dyes according to Examples 23 to 24 and Comparative Example 8 were prepared, and each hair dye was evaluated according to Test Examples 1 to 4 described above. Specifically, the hair dyes according to each of Examples 23 to 24 and Comparative Example 8 are different in higher alcohols mainly contained in the respective hair dyes.
表５の実施例２３〜実施例２４にみられるように、「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」、についてそれぞれ良好な結果が得られ、「乳化状態の安定性」については優れた結果が得られた。一方、表５の比較例８の「乳化状態の安定性」については、大部分に分離が見られ、良好な結果は得られなかった。 As can be seen from Example 23 to Example 24 in Table 5, good results were obtained for “dyeing power”, “color retention”, “feel (flexibility)”, and “feel (slidability)”. As for “emulsification stability”, excellent results were obtained. On the other hand, with regard to “stability of emulsified state” of Comparative Example 8 in Table 5, most of the separation was observed, and good results were not obtained.
これより、高級アルコールは、上記染毛料が乳化物の場合、乳化状態の安定化に効果があることが分かった。 From this, it was found that the higher alcohol is effective in stabilizing the emulsified state when the hair dye is an emulsion.
（実施例２５〜実施例２９、比較例９）
表６に記載した組成に従い、実施例２５〜実施例２９および比較例９にそれぞれに係る染毛料を調整し、上述の試験例１〜４に従って各染毛料を評価した。具体的には、実施例２５〜実施例２９および比較例９にそれぞれに係る染毛料は、主に当該各染毛料に含有されている、カチオン界面活性剤がそれぞれ異なる。
(Example 25 to Example 29, Comparative Example 9)
According to the composition described in Table 6, hair dyes according to each of Examples 25 to 29 and Comparative Example 9 were prepared, and each hair dye was evaluated according to Test Examples 1 to 4 described above. Specifically, the hair dyes according to Example 25 to Example 29 and Comparative Example 9 are different from each other in the cationic surfactant contained mainly in each hair dye.
表６の実施例２５〜実施例２９にみられるように、「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」、「乳化状態の安定性」についてそれぞれ良好な効果が得られた。一方、表６の比較例９にみられるように、「感触（柔軟性）」、「感触（滑り性）」ともに劣り、特に、「感触（柔軟性）」について劣る結果が得られた。 As seen in Examples 25 to 29 in Table 6, “dyeing power”, “color retention”, “feel (flexibility)”, “feel (slidability)”, and “stability in emulsified state” Good effects were obtained in each case. On the other hand, as seen in Comparative Example 9 in Table 6, both “feel (flexibility)” and “feel (slidability)” were inferior, and in particular, “feel (flexibility)” was inferior.
これにより、カチオン界面活性剤は、施術後（染毛料を塗布し洗い流した後）の毛髪に対するごわつき、軋みを解消する効果、言い換えると、毛髪に柔軟性を特に付与できるといった効果があることが分かった。 As a result, it is found that the cationic surfactant has an effect of eliminating stiffness and itchiness on the hair after the treatment (after applying the hair dye and washing away), in other words, an effect of particularly imparting flexibility to the hair. It was.
（実施例３０〜実施例３４、比較例１０）
表７に記載した組成に従い、実施例３０〜実施例３４および比較例１０にそれぞれに係る染毛料を調整し、上述の試験例１〜４に従って各染毛料を評価した。具体的には、実施例３０〜実施例３４および比較例１０にそれぞれに係る染毛料は、主に当該各染毛料に含有されている、芳香族アルコール（濃度の違いを含む）がそれぞれ異なる。
(Example 30 to Example 34, Comparative Example 10)
According to the composition described in Table 7, hair dyes according to each of Examples 30 to 34 and Comparative Example 10 were prepared, and each hair dye was evaluated according to Test Examples 1 to 4 described above. Specifically, the hair dyes according to each of Examples 30 to 34 and Comparative Example 10 are different from each other in aromatic alcohol (including a difference in concentration) contained in each hair dye.
表７の実施例３０〜実施例３４にみられるように、「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」、「乳化状態の安定性」についてそれぞれ良好な結果が得られた。一方、比較例１０にみられるように、「染色力」、「色持ち」ともに劣る結果が得られた。 As seen in Example 30 to Example 34 of Table 7, “dyeing power”, “color retention”, “feel (flexibility)”, “feel (slidability)”, and “stability in emulsified state” Good results were obtained for each. On the other hand, as seen in Comparative Example 10, both “dyeing power” and “color retention” were inferior.
なお、実施例３０〜実施例３４にみられるように、上記染毛料に配合する芳香族アルコールの濃度は、０．１重量％以上、好ましくは０．５重量％〜６重量％、より好ましくは２重量％〜５重量％である場合、染料の浸透を促進し、染色性を高めるといった効果について優れた結果が得られた。また、上記染毛料に配合する芳香族アルコールの濃度が高いほど、染料の浸透を促進し、染色性を高めることができるが、「感触（柔軟性）」、「感触（滑り性）」、「乳化状態の安定性」についてそれぞれ良好な結果は得られなくなる。 In addition, as seen in Example 30 to Example 34, the concentration of the aromatic alcohol blended in the hair dye is 0.1% by weight or more, preferably 0.5% by weight to 6% by weight, more preferably When the content was 2% by weight to 5% by weight, excellent results were obtained with respect to the effect of promoting dye penetration and enhancing dyeability. In addition, as the concentration of the aromatic alcohol blended in the hair dye increases, the penetration of the dye can be promoted and the dyeability can be increased. However, “feel (flexibility)”, “feel (slipperiness)”, “ Good results cannot be obtained for the stability of the emulsified state.
（実施例３５〜実施例３６、比較例１１〜１２）
まず、第２剤として、表８に示した組成に従い、実施例３５〜実施例３６および比較例１１にそれぞれに係る染毛料の第２剤を調整した。そして、上述した実施例１の染毛料を第１剤とし、当該第１剤を毛髪に塗布した後、シャンプー後プレーンリンスをし、表８に示した第２剤を毛髪に塗布した。なお、比較例１２については、第２剤を使用していない、つまり、上述した実施例１の染毛料を第１剤とし、当該第１剤を毛髪に塗布した後、シャンプー後プレーンリンスをしたのみである。
(Example 35-Example 36, Comparative Examples 11-12)
First, according to the composition shown in Table 8 as the second agent, the second agent of the hair dye according to each of Examples 35 to 36 and Comparative Example 11 was prepared. And the hair dye of Example 1 mentioned above was made into the 1st agent, and after applying the 1st agent to hair, plain rinse was carried out after shampooing and the 2nd agent shown in Table 8 was applied to hair. In Comparative Example 12, the second agent was not used, that is, the hair dye of Example 1 described above was used as the first agent, and after applying the first agent to the hair, plain rinse after shampooing was performed. Only.
また、評価項目としては、上述してきた試験例１〜４に加え、試験例５を行い評価した。 As evaluation items, in addition to Test Examples 1 to 4 described above, Test Example 5 was performed for evaluation.
表８の実施例３５〜実施例３６にみられるように、「染色力」、「色持ち」、「感触（柔軟性）」、「感触（滑り性）」、「乳化状態の安定性」についてそれぞれ良好な結果が得られた。また、第１剤を毛髪に塗布した後、第２剤を毛髪に塗布することにより、「感触（持続性）」について優れた結果が得られ、施術直後の感触（柔軟性、滑り性）が持続することが分かった。 As seen in Examples 35 to 36 of Table 8, “dyeing power”, “color retention”, “feel (flexibility)”, “feel (slidability)”, and “stability of emulsified state” Good results were obtained for each. In addition, by applying the first agent to the hair and then applying the second agent to the hair, an excellent result of “feel (sustainability)” is obtained, and the feel (flexibility, slipperiness) immediately after the treatment is obtained. I found it to last.
一方、表８の比較例１１にみられるように、第１剤を毛髪に塗布した後、第２剤を毛髪に塗布したものの、「感触（持続性）」について良好な効果は得られず、施術直後の感触があまり持続していないことが分かった。これより、第２剤には特にアミノ変性シリコーンが配合されていることが好ましいことが分かった。 On the other hand, as seen in Comparative Example 11 in Table 8, after the first agent was applied to the hair, the second agent was applied to the hair, but a good effect on “feel (sustainability)” was not obtained, It was found that the feeling immediately after the treatment was not so long. From this, it was found that it is particularly preferable that the second agent contains amino-modified silicone.
さらに、表７の比較例１２にみられるように、第２剤を塗布しない場合、「感触（持続性）」について良好な効果は得られず、施術直後の感触が持続していないことが分かった。 Furthermore, as seen in Comparative Example 12 in Table 7, when the second agent was not applied, it was found that a good effect on “feel (sustainability)” was not obtained and the feel immediately after the treatment was not sustained. It was.
本発明に係る染毛料は、染毛力を維持しつつ、かつ、施術後においても、毛髪に柔軟性や指通りの良さ（毛髪の滑り性）を与えるといったトリートメント効果を有する、いわゆるヘアマニキュア等、特に、ヘアサロンなどで用いる業務用としてのヘアマニキュア等として有用である。 The hair dye according to the present invention has so-called hair manicure or the like that has a treatment effect such as imparting flexibility and good fingering (sliding property of hair) to the hair even after the treatment while maintaining the hair coloring power. In particular, it is useful as a hair manicure for business use used in a hair salon or the like.
Claims (7)
（Ａ）成分：塩基性染料
（Ｂ）成分：芳香族アルコール
（Ｃ）成分：カチオン界面活性剤
（Ｄ）成分：ノニオン界面活性剤
（Ｅ）成分：ジメチコンもしくはジメチコノール A hair dye characterized by being an emulsion containing the following component (A), component (B), component (C), component (D), and component (E).
(A) component: basic dye (B) component: aromatic alcohol (C) component: cationic surfactant (D) component: nonionic surfactant (E) component: dimethicone or dimethiconol
（Ｆ）成分：アミノ変性シリコーン The hair dye according to claim 1, further comprising the following component (F):
Component (F): amino-modified silicone
（Ｇ）成分：ＨＬＢ（Hydrophile-Lipophile Balance）の値が７未満のポリエーテル変性シリコーン A hair dye characterized by further containing the following component (G) in the hair dye according to any one of claims 1 to 3.
(G) Component: Polyether-modified silicone having an HLB (Hydrophile-Lipophile Balance) value of less than 7
前記第１剤は請求項１、２、４の何れか１に記載の乳化物であることを特徴とする染毛料であり、
前記第２剤は下記の（Ｃ）成分、（Ｅ）成分、および（Ｆ）成分を含有する処理剤であり、
前記第１剤を毛髪に塗布した後に第２剤を毛髪に塗布することを特徴とする染毛料。
（Ｃ）成分：カチオン界面活性剤
（Ｅ）成分：ジメチコンもしくはジメチコノール
（Ｆ）成分：アミノ変性シリコーン A hair dye comprising a first agent and a second agent,
The first agent is a hair dye characterized in that it is an emulsion according to any one of claims 1, 2, and 4.
The second agent is a treatment agent containing the following component (C), component (E), and component (F):
A hair dye, wherein the second agent is applied to the hair after the first agent is applied to the hair.
(C) Component: Cationic surfactant (E) Component: Dimethicone or dimethiconol (F) Component: Amino-modified silicone
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| JP2011022164A JP4815626B1 (en) | 2011-02-03 | 2011-02-03 | Hair dye |
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| JP2011022164A JP4815626B1 (en) | 2011-02-03 | 2011-02-03 | Hair dye |
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| JP4815626B1 JP4815626B1 (en) | 2011-11-16 |
| JP2012162466A true JP2012162466A (en) | 2012-08-30 |
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| JP2011022164A Active JP4815626B1 (en) | 2011-02-03 | 2011-02-03 | Hair dye |
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| JP (1) | JP4815626B1 (en) |
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| JP2016017031A (en) * | 2014-07-04 | 2016-02-01 | ロレアル | Method of preparing cosmetic composition for keratin fiber |
| JP2016088879A (en) * | 2014-11-04 | 2016-05-23 | 株式会社ミルボン | Multiagent-type hair treatment agent |
| JP6095751B1 (en) * | 2015-11-19 | 2017-03-15 | 株式会社ヘアテック・ジャパン | Post-foaming hair dye composition |
| JP2018104371A (en) * | 2016-12-27 | 2018-07-05 | ホーユー株式会社 | Hair treatment agent composition |
| KR102164724B1 (en) * | 2020-04-20 | 2020-10-13 | 한국콜마주식회사 | Foam type semi-permanent hair dyeing composition |
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| DE102019208905A1 (en) | 2019-06-19 | 2020-12-24 | Henkel Ag & Co. Kgaa | Agent for coloring keratinic material with amino silicone, coloring compound, preservative and ethoxylated fatty alcohol |
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|---|---|---|---|---|
| JP2004107247A (en) * | 2002-09-18 | 2004-04-08 | Nikko Chemical Co Ltd | Hair conditioning agent which can simultaneously dye and condition hair |
| JP4865987B2 (en) * | 2003-10-06 | 2012-02-01 | 花王株式会社 | Hair dye composition |
| JP4934406B2 (en) * | 2006-11-02 | 2012-05-16 | 花王株式会社 | Hair treatment agent |
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| JP2016088879A (en) * | 2014-11-04 | 2016-05-23 | 株式会社ミルボン | Multiagent-type hair treatment agent |
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