JP2012162019A - Thermochromic writing utensil - Google Patents

Thermochromic writing utensil Download PDF

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JP2012162019A
JP2012162019A JP2011024844A JP2011024844A JP2012162019A JP 2012162019 A JP2012162019 A JP 2012162019A JP 2011024844 A JP2011024844 A JP 2011024844A JP 2011024844 A JP2011024844 A JP 2011024844A JP 2012162019 A JP2012162019 A JP 2012162019A
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thermochromic
writing instrument
rubbing member
shaft cylinder
conductive material
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Tachiharu Tsuchimoto
立春 土本
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Pilot Ink Co Ltd
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Pilot Ink Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a thermochromic writing utensil that can erase handwriting by a rubbing member, and enables input not only in a pressure-sensitive touch panel but also in a capacitance type touch panel by using the rubbing member.SOLUTION: In the writing utensil in which the reversible thermochromic ink is stored and which includes the rubbing member, conductive material is used for the rubbing member. Conductive rubber is desirably used as the conductive material. All the members used between a part held by a user and the rubbing member are made of the conductive material in a writing utensil body. Metal or conductive resin is used as the conductive material.

Description

本発明は、熱変色性筆記具に関する。詳細には静電容量方式のタッチパネルに入力することが出来る熱変色性筆記具に関する。   The present invention relates to a thermochromic writing instrument. More specifically, the present invention relates to a thermochromic writing instrument that can be input to a capacitive touch panel.

特許文献1には、筆記具本体の内部に熱変色性インキを収容し、前記筆記具本体の前端に、熱変色性インキが吐出可能なペン先を設け、前記筆記具本体の後端、或いはキャップの先端に、熱変色性インキの筆跡を摩擦しその際に生じる摩擦熱で該筆跡が熱変色可能な摩擦部を設けた熱変色性筆記具が記載されている。
また、特許文献2には軸筒内に、熱変色性インキを内蔵した筆記体を前後方向に移動可能に収容し、軸筒の外面に操作部を設け、前記操作部を操作することにより前記筆記体のペン先を軸筒の前端孔から出没可能に構成した筆記具において、前記軸筒の外面に、前記熱変色性インキの筆跡を摩擦しその際に生じる摩擦熱で該筆跡を熱変色可能な摩擦部を設けた熱変色性筆記具が記載されている。
In Patent Document 1, a thermochromic ink is accommodated inside the writing instrument body, a pen tip capable of ejecting the thermochromic ink is provided at the front end of the writing instrument body, and the rear end of the writing instrument body or the tip of the cap Describes a thermochromic writing instrument provided with a friction part that can rub the handwriting of the thermochromic ink and frictionally generate the handwriting with the frictional heat generated at that time.
Further, in Patent Document 2, a writing body containing a thermochromic ink is accommodated in a shaft cylinder so as to be movable in the front-rear direction, and an operation unit is provided on the outer surface of the shaft cylinder, and the operation unit is operated to operate the operation unit. In a writing instrument in which the pen tip of the writing body can be projected and retracted from the front end hole of the shaft tube, the handwriting of the thermochromic ink can be rubbed against the outer surface of the shaft tube, and the handwriting can be thermally discolored by frictional heat generated at that time. A thermochromic writing instrument provided with a simple friction part is described.

特開2007−223302号公報JP 2007-223302 A 国際公開WO2008−105227号公報International Publication WO2008-105227

従来から提案され、実用化されている熱変色性筆記具は擦過部材に合成ゴム等の弾性体が用いられている。これらの材料は電気絶縁材料であり、導電性は示さない。
又、前記従来の熱変色性筆記具の軸筒、キャップ、その他の部品は主に合成樹脂の成形体が用いられているが、これらの材料も電気絶縁材料であり、導電性は示さない。
The thermochromic writing instruments that have been proposed and put to practical use use an elastic body such as a synthetic rubber as a rubbing member. These materials are electrically insulating materials and do not exhibit electrical conductivity.
In addition, although the shaft tube, the cap, and other parts of the conventional thermochromic writing instrument are mainly made of synthetic resin, these materials are also electrically insulating materials and do not exhibit electrical conductivity.

一方、情報機器の分野では、タッチパネルが携帯電話、携帯情報端末(PDA)、デジタルオーディオプレーヤー、携帯ゲーム機などを中心に多方面において急速に需要が拡大している。前記タッチパネルには各種方式があるが、現在主流となっているのは抵抗膜型と静電容量型である。前記抵抗膜型は感圧入力方式のため、指のほか木製、樹脂製或いは無機材料等で構成された入力ペンで入力することが出来る。
それに対し静電容量型は指或いは導電性の入力ペン等で入力することが出来るが、電気絶縁性の材料では入力することが出来ない。本発明は静電容量型のタッチパネルに入力することが出来る熱変色性筆記具を提供しようとするものである。
On the other hand, in the field of information equipment, demand for touch panels is rapidly expanding in various fields, mainly mobile phones, personal digital assistants (PDAs), digital audio players, and portable game machines. There are various types of touch panels, but the mainstream at present is the resistance film type and the capacitance type. Since the resistance film type is a pressure-sensitive input method, it can be input with an input pen made of wood, resin or inorganic material in addition to fingers.
On the other hand, the capacitance type can be input with a finger or a conductive input pen, but cannot be input with an electrically insulating material. The present invention is intended to provide a thermochromic writing instrument that can be input to a capacitive touch panel.

本発明は、内部に熱変色性インキを収容し且つ一端に前記熱変色インキが吐出可能なペン先を備えた軸筒と、前記軸筒のペン先側に装着可能に一端が開口されたキャップとからなる熱変色性筆記具であって、前記熱変色性筆記具外面に装着され、熱変色性の筆跡を摩擦しその際に生じる摩擦熱で該筆跡を熱変色可能な擦過部材を備えた熱変色性筆記具において、前記擦過部材が導電性材料からなり、前記軸筒及び/又はキャップが導電性材料で形成され、前記擦過部材と前記軸筒及び/又はキャップが電気的に導通されていることを要件とする。
又、筆記体の内部に熱変色性インキを収容し、前記筆記体の前端に前記熱変色性インキが吐出可能なペン先を設け、前記筆記体を前後方向に移動可能に軸筒内に収容し、前記筆記体のペン先を軸筒の前端孔から出没可能に構成した熱変色性筆記具であって、前記熱変色性筆記具外面に装着され、熱変色性の筆跡を摩擦しその際に生じる摩擦熱で該筆跡を熱変色可能な擦過部材を備えた熱変色性筆記具において、前記擦過部材及び軸筒が導電性材料で形成され、前記擦過部材と前記軸筒が電気的に導通されていることを要件とする。
The present invention includes a shaft cylinder that contains a thermochromic ink inside and a pen tip that can discharge the thermochromic ink at one end, and a cap that is open at one end so as to be attachable to the pen tip side of the shaft cylinder A thermochromic writing instrument comprising: a thermal discoloration comprising a rubbing member attached to the outer surface of the thermochromic writing instrument and capable of rubbing the thermochromic handwriting and heat-discoloring the handwriting with frictional heat generated at that time In the writing instrument, the rubbing member is made of a conductive material, the shaft tube and / or the cap is formed of a conductive material, and the rubbing member and the shaft tube and / or the cap are electrically connected. As a requirement.
Also, thermochromic ink is accommodated inside the cursive body, a pen tip capable of ejecting the thermochromic ink is provided at the front end of the cursive body, and the cursive body is accommodated in the shaft cylinder so as to be movable in the front-rear direction. And a thermochromic writing instrument configured such that the pen tip of the writing body can be projected and retracted from a front end hole of the shaft cylinder, and is attached to the outer surface of the thermochromic writing instrument and rubs the thermochromic handwriting to be generated at that time In a thermochromic writing instrument provided with a rubbing member capable of thermally discoloring the handwriting by frictional heat, the rubbing member and the shaft tube are formed of a conductive material, and the rubbing member and the shaft tube are electrically connected. Is a requirement.

本発明の熱変色性筆記具は上記構成にすることにより前記擦過部材で静電容量型のタッチパネルに入力することが出来る。即ち、前記擦過部材は、前記軸筒及び/又はキャップを介して使用者の手と電気的に導通される。従って、前記擦過部材が前記軸筒及び/又はキャップを把持する使用者の手と同電位に維持されると共に、静電容量型座標タッチパネルと前記擦過部材の接触状態で静電容量が形成される。   The thermochromic writing instrument of the present invention can be input to a capacitive touch panel with the rubbing member with the above-described configuration. That is, the rubbing member is electrically connected to the user's hand through the shaft tube and / or cap. Accordingly, the rubbing member is maintained at the same potential as the user's hand holding the shaft cylinder and / or cap, and a capacitance is formed in a contact state between the capacitive coordinate touch panel and the rubbing member. .

本発明の第1の実施の形態の縦断面図である。It is a longitudinal cross-sectional view of the 1st Embodiment of this invention. 本発明の第2の実施の形態の縦断面図である。It is a longitudinal cross-sectional view of the 2nd Embodiment of this invention. 本発明の第3の実施の形態の縦断面図である。It is a longitudinal cross-sectional view of the 3rd Embodiment of this invention. 本発明の第4の実施の形態の縦断面図である。It is a longitudinal cross-sectional view of the 4th Embodiment of this invention. 本発明の第5の実施の形態の縦断面図である。It is a longitudinal cross-sectional view of the 5th Embodiment of this invention.

本発明の熱変色性筆記具に用いられる擦過部材は、導電性材料で形成される。前記擦過部材は熱変色性インキにより形成された筆跡を擦過による摩擦熱で変色させるものであり、
材料は限定されるものではないが、好適にはゴム等の弾性体が用いられる。本発明においては導電性ゴムの適用が好ましい。
前記擦過部材は、天然ゴム、又はニトリルゴム、シリコーンゴム、SBS、SEBS等の合成ゴム中に導電性カーボン或いは金属等の導電剤を混合した導電性ゴムを成形することにより得られる。
前記擦過部材は市販の導電性ゴム材料を成形することによっても得ることが出来る。市販の導電性ゴム材料としては、信越化学工業(株)製のECシリーズ・シリコーンゴム、ライオン(株)製のレオパウンドシリーズ、JFEテクノリサーチ(株)製のサステックシリーズ等が例示できる。
The rubbing member used in the thermochromic writing instrument of the present invention is formed of a conductive material. The rubbing member discolors the handwriting formed with the thermochromic ink by frictional heat due to rubbing,
The material is not limited, but an elastic body such as rubber is preferably used. In the present invention, application of conductive rubber is preferred.
The rubbing member can be obtained by molding a conductive rubber in which a conductive agent such as conductive carbon or metal is mixed in natural rubber, or synthetic rubber such as nitrile rubber, silicone rubber, SBS, or SEBS.
The scraping member can also be obtained by molding a commercially available conductive rubber material. Examples of commercially available conductive rubber materials include EC series silicone rubber manufactured by Shin-Etsu Chemical Co., Ltd., Leo Pound series manufactured by Lion Corporation, and Sustech series manufactured by JFE Techno-Research Corporation.

本発明の熱変色性筆記具に用いられる筆記具軸筒及びキャップにおいても、樹脂と導電性フィラーとを含有する成形材料、或いは金属材料等の導電性材料により形成されるが、コストや成形により所望の形状の部品が容易に得られる点で導電性樹脂が好適である。
導電性樹脂も導電性ゴム同様樹脂中に導電性カーボン或いは金属等の導電剤を混合することにより得られるが、市販の導電性樹脂を用いることも出来る。市販の導電性樹脂としては、大日精化工業(株)製のネオコンシリーズ、東京インキ(株)製のパピオスタットシリーズ、大塚化学(株)製のウイスタットシリーズ、JFEテクノリサーチ(株)製のサステックシリーズ等が例示できる。
The writing tool barrel and cap used in the thermochromic writing instrument of the present invention are also formed of a molding material containing a resin and a conductive filler, or a conductive material such as a metal material. A conductive resin is preferable in that a shaped part can be easily obtained.
The conductive resin can also be obtained by mixing a conductive agent such as conductive carbon or metal in the resin as in the case of the conductive rubber, but a commercially available conductive resin can also be used. Commercially available conductive resins include Neocon series manufactured by Dainichi Seika Kogyo Co., Ltd., Papiostat series manufactured by Tokyo Ink Co., Ltd., Wistat series manufactured by Otsuka Chemical Co., Ltd., and JFE Techno Research Co., Ltd. Examples include the Sustech series.

前記熱変色性インキは、可逆熱変色性インキが好ましい。前記可逆熱変色性インキは、発色状態から加熱により消色する加熱消色型、発色状態または消色状態を互変的に特定温度域で記憶保持する色彩記憶保持型、または、消色状態から加熱により発色し、発色状態からの冷却により消色状態に復する加熱発色型等、種々のタイプを単独または併用して構成することができる。   The thermochromic ink is preferably a reversible thermochromic ink. The reversible thermochromic ink is a heat decoloring type that decolors by heating from a colored state, a color memory retaining type that reversibly stores and retains a colored state or a decolored state in a specific temperature range, or from a decolored state Various types such as a heating coloring type that develops color by heating and returns to a decolored state by cooling from the colored state can be used alone or in combination.

また、前記可逆熱変色性インキに含有される色材は、従来より公知の(イ)電子供与性呈色性有機化合物、(ロ)電子受容性化合物、及び(ハ)前記両者の呈色反応の生起温度を決める反応媒体、の必須三成分を少なくとも含む可逆熱変色性組成物をマイクロカプセル中に内包させた可逆熱変色性顔料が好適に用いられる。   The coloring material contained in the reversible thermochromic ink includes conventionally known (a) electron donating color-forming organic compounds, (b) electron-accepting compounds, and (c) color reactions of both. A reversible thermochromic pigment in which a reversible thermochromic composition containing at least the essential three components of a reaction medium for determining the occurrence temperature of the polymer is encapsulated in a microcapsule is preferably used.

本発明の第1の実施の形態を図1に示す。本実施の形態の熱変色性筆記具1は、ポリプロピレン製のインキ収容管21に剪断減粘性可逆熱変色性インキ4を充填し一端にボールペンチップ3を嵌着し、前記剪断減粘性可逆熱変色性インキ4後端にインキ逆流防止体5を配置したレフィル2を、前軸61と後軸63を螺合した軸筒6内に収容したボールペンであって軸筒6の後端に擦過部材8を固着したものである。ここで、少なくとも後軸63が導電性樹脂からなり、擦過部材8が導電性ゴムからなる。   A first embodiment of the present invention is shown in FIG. The thermochromic writing instrument 1 of the present embodiment has a polypropylene ink containing tube 21 filled with a shear thinning viscosity reversible thermochromic ink 4 and a ballpoint pen tip 3 fitted on one end thereof, and the shear thinning viscosity reversible thermochromic property. The refill 2 in which the ink backflow prevention body 5 is arranged at the rear end of the ink 4 is a ballpoint pen that is housed in a shaft cylinder 6 in which the front shaft 61 and the rear shaft 63 are screwed. It is fixed. Here, at least the rear shaft 63 is made of a conductive resin, and the rubbing member 8 is made of a conductive rubber.

本発明の第2の実施の形態を図2に示す。本実施の形態の熱変色性筆記具1は、ポリプロピレン製のインキ収容管21に剪断減粘性可逆熱変色性インキ4を充填し一端にボールペンチップ3を嵌着し、前記剪断減粘性可逆熱変色性インキ4後端にインキ逆流防止体5を配置したレフィル2を、前軸61と後軸63を螺合した軸筒6内に収容し、前軸61に着脱自在にキャップ7を取付けたボールペンであってキャップ7の先端に擦過部材8を固着したものである。ここで、少なくともキャップ7が導電性樹脂からなり、擦過部材8が導電性ゴムからなる。   A second embodiment of the present invention is shown in FIG. The thermochromic writing instrument 1 of the present embodiment has a polypropylene ink containing tube 21 filled with a shear thinning viscosity reversible thermochromic ink 4 and a ballpoint pen tip 3 fitted on one end thereof, and the shear thinning viscosity reversible thermochromic property. The refill 2 in which the ink backflow prevention body 5 is arranged at the rear end of the ink 4 is accommodated in a shaft cylinder 6 in which the front shaft 61 and the rear shaft 63 are screwed together, and a ballpoint pen in which the cap 7 is detachably attached to the front shaft 61. In this case, the rubbing member 8 is fixed to the tip of the cap 7. Here, at least the cap 7 is made of a conductive resin, and the rubbing member 8 is made of a conductive rubber.

本発明の第3の実施の形態を図3に示す。本実施の形態の熱変色性筆記具1は、可逆熱変色性インキを、ポリエステル繊維からなる中綿をフィルム状の外皮で被覆したインキ吸蔵体10に収容し、毛細間隙が形成された繊維加工体からなるチップ3を軸筒6に装着してなり、前記インキ吸蔵体10とチップ3が連結されたマーキングペンにおいて、軸筒6後端に擦過部材8を固着したものである。ここで少なくとも軸筒6が導電性樹脂からなり、擦過部材8が導電性ゴムからなる。   A third embodiment of the present invention is shown in FIG. The thermochromic writing instrument 1 according to the present embodiment accommodates reversible thermochromic ink in an ink occlusion body 10 in which a batting made of polyester fiber is covered with a film-like outer skin, and from a fiber processed body in which a capillary gap is formed. In the marking pen in which the tip 3 is mounted on the shaft cylinder 6 and the ink occluding body 10 and the chip 3 are connected, a rubbing member 8 is fixed to the rear end of the shaft cylinder 6. Here, at least the shaft cylinder 6 is made of a conductive resin, and the rubbing member 8 is made of a conductive rubber.

本発明の第4の実施の形態を図4に示す。本実施の形態の熱変色性筆記具1は、軸筒6内に複数の熱変色性インキを内蔵したボールペンレフィル2を前後方向に移動可能に収容し、前記レフィル2に直結したスライドレバー10を操作することにより前記レフィル2先端のチップ3を出没させる構造の熱変色性筆記具1において、軸筒6後端部に設けたレフィル交換用の開閉可能な蓋11に擦過部材8を固着したものである。ここで少なくとも軸筒6及び蓋12が導電性樹脂からなり、擦過部材8が導電性ゴムからなる。   A fourth embodiment of the present invention is shown in FIG. The thermochromic writing instrument 1 of the present embodiment accommodates a ballpoint pen refill 2 containing a plurality of thermochromic inks in a shaft cylinder 6 so as to be movable in the front-rear direction, and operates a slide lever 10 directly connected to the refill 2. Thus, in the thermochromic writing instrument 1 having a structure in which the tip 3 at the tip of the refill 2 is projected and retracted, a rubbing member 8 is fixed to a refill exchangeable lid 11 provided at the rear end of the shaft tube 6. . Here, at least the shaft cylinder 6 and the lid 12 are made of conductive resin, and the rubbing member 8 is made of conductive rubber.

本発明の第5の実施の形態を図5に示す。本実施の形態の熱変色性筆記具1は、軸筒6内に熱変色性インキを内蔵したボールペンレフィル2を前後方向に移動可能に収容し、クリップを兼ねたスライドレバー10を操作することにより前記レフィル2先端のチップ3を出没させる構造の熱変色性筆記具1において、軸筒6の後端部に擦過部材8を固着したものである。ここで少なくとも中間軸62及び後軸63が導電性樹脂からなり、擦過部材8が導電性ゴムからなる。   A fifth embodiment of the present invention is shown in FIG. The thermochromic writing instrument 1 of the present embodiment accommodates a ballpoint pen refill 2 containing a thermochromic ink in a shaft cylinder 6 so as to be movable in the front-rear direction, and operates the slide lever 10 also serving as a clip. In the thermochromic writing instrument 1 having a structure in which the tip 3 at the tip of the refill 2 is projected and retracted, a rubbing member 8 is fixed to the rear end portion of the shaft tube 6. Here, at least the intermediate shaft 62 and the rear shaft 63 are made of conductive resin, and the rubbing member 8 is made of conductive rubber.

本発明の熱変色性筆記具は該熱変色性筆記具で筆記した筆跡の消去したい部分を、該筆記具に固着された擦過部材で摩擦することにより消去することができ、当該消去した部分に再度筆記することもできる。
更に前記擦過部材で抵抗膜型タッチパネル及び静電容量型のいずれにおいても入力することができた。
The thermochromic writing instrument of the present invention can be erased by rubbing a portion of the handwriting written with the thermochromic writing instrument by rubbing with a scraping member fixed to the writing instrument, and writing again on the erased part. You can also.
Furthermore, it was possible to input the resistance member type touch panel and the electrostatic capacity type with the rubbing member.

それに対し、市販の熱変色筆記具(パイロットコーポレーション社製・フリクションボール)では筆跡の消去及び抵抗膜型タッチパネルの入力は問題なく行うことができたが、静電容量型タッチパネルには入力することができなかった。   In contrast, a commercially available thermochromic writing instrument (Pilot Corporation's friction ball) was able to erase the handwriting and input the resistive touch panel without any problems, but it could be input to the capacitive touch panel. There wasn't.

1 熱変色性筆記具
2 レフィル
21 インキ収容管
22 ホルダー
3 チップ
4 剪断減粘性可逆熱変色性インキ
5 インキ逆流防止体
6 軸筒
61 前軸
62 中間軸
63 後軸
7 キャップ
8 擦過部材
9 インキ吸蔵体
10 スライドレバー
11 蓋
DESCRIPTION OF SYMBOLS 1 Thermochromic writing instrument 2 Refill 21 Ink receiving tube 22 Holder 3 Tip 4 Shear thinning viscosity reversible thermochromic ink 5 Ink backflow prevention body 6 Shaft cylinder 61 Front shaft 62 Intermediate shaft 63 Rear shaft 7 Cap 8 Scraping member 9 Ink occlusion body 10 Slide lever 11 Lid

Claims (7)

内部に熱変色性インキを収容し且つ一端に前記熱変色インキが吐出可能なペン先を備えた軸筒と、前記軸筒のペン先側に装着可能に一端が開口されたキャップとからなり、外面に前記熱変色性インキによる熱変色性の筆跡を摩擦しその際に生じる摩擦熱で該筆跡を熱変色可能な擦過部材を備えた熱変色性筆記具であって、前記擦過部材が導電性材料からなり、前記軸筒及び/又は前記キャップが導電性材料で形成され、前記擦過部材と前記軸筒及び/又は前記キャップとが電気的に導通されていることを特徴とする熱変色性筆記具。   It is composed of a shaft cylinder that contains a thermochromic ink inside and a pen tip that can discharge the thermochromic ink at one end, and a cap that is open at one end so that it can be attached to the pen tip side of the shaft cylinder, A thermochromic writing instrument provided with a rubbing member capable of thermally discoloring the handwriting with frictional heat generated by rubbing the thermochromic handwriting with the thermochromic ink on the outer surface, wherein the rubbing member is a conductive material The thermochromic writing instrument, wherein the shaft cylinder and / or the cap is made of a conductive material, and the rubbing member and the shaft cylinder and / or the cap are electrically connected. 前記擦過部材がキャップ頂部に装着されていることを特徴とする請求項1に記載の熱変色性筆記具。   The thermochromic writing instrument according to claim 1, wherein the rubbing member is attached to the top of the cap. 前記擦過部材が軸筒後端に装着されていることを特徴とする請求項1に記載の熱変色性筆記具。   The thermochromic writing instrument according to claim 1, wherein the rubbing member is attached to the rear end of the shaft cylinder. 筆記体の内部に熱変色性インキを収容し、前記筆記体の前端に前記熱変色性インキが吐出可能なペン先を設け、前記筆記体を前後方向に移動可能に軸筒内に収容し、前記筆記体のペン先を軸筒の前端孔から出没可能に構成し、前記軸筒外面に前記熱変色性インキによる熱変色性の筆跡を摩擦し、その際に生じる摩擦熱で該筆跡を熱変色可能な擦過部材を備えた熱変色性筆記具であって、前記擦過部材及び前記軸筒が導電性材料で形成され、前記擦過部材と前記軸筒とが電気的に導通されていることを特徴とする熱変色性筆記具。   A thermochromic ink is contained inside the cursive body, a pen tip capable of ejecting the thermochromic ink is provided at a front end of the cursive body, and the cursive body is accommodated in a shaft cylinder so as to be movable in the front-rear direction. The pen tip of the cursive body is configured to be able to protrude and retract from the front end hole of the shaft cylinder, and the thermochromic handwriting by the thermochromic ink is rubbed against the outer surface of the shaft cylinder, and the handwriting is heated by friction heat generated at that time A thermochromic writing instrument provided with a discolorable rubbing member, wherein the rubbing member and the shaft tube are formed of a conductive material, and the rubbing member and the shaft tube are electrically connected to each other. A thermochromic writing instrument. 前記擦過部材に用いられる導電性材料が導電性ゴムであることを特徴とする請求項1乃至4のいずれかに記載の熱変色性筆記具。   The thermochromic writing instrument according to any one of claims 1 to 4, wherein the conductive material used for the rubbing member is a conductive rubber. 前記軸筒に用いられる導電性材料が金属又は導電性樹脂であることを特徴とする請求項1乃至5のいずれかに記載の熱変色性筆記具。   6. The thermochromic writing instrument according to claim 1, wherein the conductive material used for the shaft tube is a metal or a conductive resin. 前記キャップに用いられる導電性材料が金属又は導電性樹脂であることを特徴とする請求項1、2、3、5又は6に記載の熱変色性筆記具。   The electrochromic writing instrument according to claim 1, 2, 3, 5, or 6, wherein the conductive material used for the cap is a metal or a conductive resin.
JP2011024844A 2011-02-08 2011-02-08 Thermochromic writing utensil Pending JP2012162019A (en)

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JP2015009457A (en) * 2013-06-28 2015-01-19 株式会社パイロットコーポレーション Thermochromic writing utensil
JP2015009458A (en) * 2013-06-28 2015-01-19 株式会社パイロットコーポレーション Feeding thermochromic writing utensil
JP2015009456A (en) * 2013-06-28 2015-01-19 株式会社パイロットコーポレーション Thermochromic writing utensil
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JP2021182409A (en) * 2015-05-29 2021-11-25 三菱鉛筆株式会社 Writing instrument with touch pen
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