JP2012157370A - Gelling agent for person having difficulty in mastication and/or swallowing - Google Patents

Gelling agent for person having difficulty in mastication and/or swallowing Download PDF

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JP2012157370A
JP2012157370A JP2012121337A JP2012121337A JP2012157370A JP 2012157370 A JP2012157370 A JP 2012157370A JP 2012121337 A JP2012121337 A JP 2012121337A JP 2012121337 A JP2012121337 A JP 2012121337A JP 2012157370 A JP2012157370 A JP 2012157370A
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food
gelling agent
gel
swallowing
difficulty
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Miyoshi Hiroe
美佳 廣江
Takahiro Funemi
孝博 船見
Kunichika Yoshihira
邦周 義平
Takeshi Hatakeyama
健 畠山
Yumiko Takahashi
由美子 高橋
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San Ei Gen FFI Inc
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Abstract

PROBLEM TO BE SOLVED: To provide a gelling agent which is favorably dispersed or dissolved in a liquid food at 50-60°C which is relatively low temperature as a temperature for dissolving the gelling agent to gelatinize the liquid food, keeps a good shape retention without dissolving the gelled food even when reheated, is highly versatile so that addition of the gelling agent makes the gelled food become suitable for being taken by persons having difficulty in mastication and/or swallowing even when being added to fruit juice, milk, or liquid food richly containing minerals and/or fat content such as miso soup (soup), a concentrated fluid food or milk, and disperses without forming lumps even under a mild agitating condition such as hand agitation so as to be excellent in handling property.SOLUTION: The gelling agent includes easily dissolvable agar and guar gum having a weight-average molecular weight of 1.5×10g/mol or more, includes the guar gum at 60-700 mass% based on the amount of easily dissolvable agar, and further includes xanthan gum and/or native-type gellan gum.

Description

本発明は、咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤に関する。詳細には、50〜60℃といった比較的低温の液状の食品組成物(液状食品)に良好に分散、溶解して液状食品をゲル化させることができ、再加温を行った場合であってもゲル状食品が溶解することなく良好な保形性を保つことのできるゲル化剤に関する。液状食品は水やお茶だけでなく、果汁飲料、味噌汁(スープ)、牛乳、濃厚流動食など、ミネラル、脂肪、及びタンパク質の含有量が高い液状食品を含み、更には、手攪拌のような緩い攪拌条件でもダマになることなく良好に分散し、咀嚼・嚥下用に適したゲル状食品を提供することができるゲル化剤に関する。   The present invention relates to a gelling agent for preparing a gel food for persons with difficulty in chewing / swallowing. Specifically, it is a case where the liquid food can be well dispersed and dissolved in a relatively low temperature liquid food composition (liquid food) such as 50 to 60 ° C. to gel the liquid food, and reheated. The present invention also relates to a gelling agent capable of maintaining good shape retention without dissolving the gel food. Liquid foods include not only water and tea but also liquid foods with high contents of minerals, fats, and proteins, such as fruit juice, miso soup, milk, and concentrated liquid foods. The present invention relates to a gelling agent that can be dispersed well without being damped even under stirring conditions and can provide a gel-like food suitable for chewing / swallowing.

近年、高齢者の増加に伴い、食物を噛み砕き飲み込むという一連の動作に障害をもつ、いわゆる咀嚼・嚥下困難者が増加する傾向がある。咀嚼・嚥下困難者向けに種々のゲル化剤が開発されており、近年では、嗜好性(味・外観に与える影響が少ない)や機能性(少ない添加量で効果を発揮する)の面から、増粘多糖類を主剤にしたゲル化剤が好んで使用される。咀嚼・嚥下障害者に適した食品として、1)適度なかたさを有すること、2)食塊形成性(口中での食品のまとまりやすさ)に優れること、3)口腔及び咽頭への付着性が小さいこと、及び4)保水性が高いこと(離水が少ないこと)などが挙げられ、このようなテクスチャー条件を満たす食品、あるいは既存食品にかかる性質を付与するためのゲル化剤の開発が種々検討されている。   In recent years, with the increase in the number of elderly people, there is a tendency for so-called mastication and swallowing difficult persons who have a disorder in a series of actions of chewing and swallowing food. Various gelling agents have been developed for those who have difficulty chewing and swallowing. In recent years, from the aspect of taste (less impact on taste and appearance) and functionality (activate with a small amount added), A gelling agent based on thickening polysaccharides is preferably used. As food suitable for mastication and dysphagia, it has 1) moderate hardness, 2) excellent bolus formation (easiness to collect food in the mouth), and 3) adherence to the oral cavity and pharynx. 4) High water retention (low water separation), etc., and various studies are being made on the development of gelling agents to give foods that satisfy these texture conditions or to impart properties to existing foods. Has been.

例えば、特許文献1には、ゲル化剤及び増粘剤を含むゲル状組成物であって、予め別個に加熱された溶液を混合し、冷却してなることを特徴とするゲル状組成物が記載されている。そして、ゲル化剤として寒天、カラギナン、ファーセルラン、ジェランガム、ゼラチン等が、増粘剤としてグァーガム、キサンタンガム、ネイティブ型ジェランガム等が開示されている。また、特許文献2にはキサンタンガム、グァーガム、アルギン酸塩、カルボキシルメチルセルロース塩及びα化澱粉から選ばれた増粘剤(A)と寒天、カラギナン、ローカストビーンガム、ゼラチン、ペクチン及びカードランから選ばれたゲル化剤(B)を含有してなる食用増粘・ゲル化組成物が記載されている。同様にして特許文献3には寒天、グァーガムを始めとした1種以上の糊料と葛澱粉を含有する咀嚼・嚥下困難者用食品が、特許文献4には嚥下補助飲料に用いる糊料として、寒天、グァーガム等の糊料が開示されている。   For example, Patent Document 1 discloses a gel composition containing a gelling agent and a thickening agent, wherein the gel composition is prepared by mixing and cooling a separately heated solution. Are listed. Further, agar, carrageenan, farsellan, gellan gum, gelatin and the like are disclosed as gelling agents, and guar gum, xanthan gum, native gellan gum and the like are disclosed as thickeners. In Patent Document 2, a thickener (A) selected from xanthan gum, guar gum, alginate, carboxyl methylcellulose salt and pregelatinized starch and agar, carrageenan, locust bean gum, gelatin, pectin and curdlan were selected. An edible thickening / gelling composition containing a gelling agent (B) is described. Similarly, Patent Document 3 discloses a food for persons with difficulty in chewing / swallowing containing one or more kinds of pastes such as agar and guar gum and kuzu starch, and Patent Document 4 discloses a paste used for swallowing auxiliary drinks. Pastes such as agar and guar gum are disclosed.

一方、特許文献5、6には溶解温度が通常の寒天よりも低い易溶性寒天を用いた組成物として、インスタントゼリーミックスや、嚥下困難者用ゼリーが開示されているが、特許文献5、6には易溶性寒天に対して特定の配合量、特定の分子特性のグァーガムを用いることについて一切記載されていない。   On the other hand, Patent Documents 5 and 6 disclose instant jelly mix and jelly for persons with difficulty in swallowing as compositions using easily soluble agar whose dissolution temperature is lower than that of normal agar. Does not describe any use of guar gum having a specific blending amount and specific molecular characteristics for easily soluble agar.

以上のように、咀嚼・嚥下困難者用ゲル状食品を調製する目的で、従来からゲル化剤として寒天が用いられている。しかし、寒天を用いてゲル状食品を調製する場合は、寒天を液状食品に溶解するために通常90℃以上といった高温での加熱が必要であり、更には、プロペラ撹拌機等による機械的な混合を必要とする。しかし、咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤は、患者やその看護者が障害の程度や患者のその日の体調に合わせてベットサイドや家庭の台所で用いられる場合がある。ポットのお湯のような比較的低温の温度条件、更には、手撹拌のような緩い撹拌条件でも良好に溶解するという性質が求められるため、寒天が必ずしも万能なわけではない。更に、寒天は脆い食感のゲルを形成し、一度破砕したゲルは再結着しにくいといった問題を有し、一方で、脆さを低減するために低濃度で使用すると離水が多くなるという問題があるなど、寒天単独では咀嚼・嚥下困難者の喫食に適した物性を付与することは難しい。   As described above, agar has been conventionally used as a gelling agent for the purpose of preparing a gel food for persons with difficulty in chewing / swallowing. However, when preparing gelatinous foods using agar, heating at a high temperature of 90 ° C or higher is usually required to dissolve the agar into liquid foods. Furthermore, mechanical mixing with a propeller stirrer or the like is required. Need. However, gelling agents for preparing gel foods for those who have difficulty chewing or swallowing may be used by patients and their nurses at the bedside or in the home kitchen depending on the degree of disability and the patient's physical condition. is there. Agar is not always versatile because it is required to dissolve well even under relatively low temperature conditions such as hot water in a pot, and even under gentle stirring conditions such as hand stirring. Furthermore, agar forms a gel with a brittle texture, and once crushed gel is difficult to reattach, on the other hand, if it is used at a low concentration in order to reduce brittleness, there is a problem that water separation increases. For example, it is difficult to give physical properties suitable for eating by those who have difficulty chewing or swallowing alone.

また、寒天として易溶性寒天を用いた場合、通常の寒天に比べて溶解性は改善できるが、食感や離水はほとんど変わらず、単独では咀嚼・嚥下困難者の喫食に適した物性を付与することは難しい。易溶性寒天に、例えばローカストビーンガムやゼラチンを併用することにより、食感や離水をある程度改善することができる。しかし、ローカストビーンガムを併用する場合は、ローカストビーンガムを溶解させるために80〜90℃以上といった高温での加熱が必要であり、また、ゼラチンを併用する場合は、再加温したときにゲル状食品の食感や力学的特性が大きく変化するという問題がある。   In addition, when easily soluble agar is used as agar, solubility can be improved compared to normal agar, but the texture and water release are almost unchanged, and it alone provides physical properties suitable for eating by those who have difficulty chewing or swallowing It ’s difficult. The texture and water separation can be improved to some extent by using, for example, locust bean gum or gelatin together with easily soluble agar. However, when locust bean gum is used in combination, heating at a high temperature of 80 to 90 ° C. or more is necessary to dissolve locust bean gum, and when gelatin is used together, the gel is reheated. There is a problem that the texture and mechanical properties of the food are greatly changed.

更に、従来の咀嚼・嚥下困難者用のゲル化剤組成物は水やお茶等の液状食品をゲル化させて食することを主としており、果汁飲料、味噌汁(スープ)、牛乳、濃厚流動食など、低pHの液状食品、ミネラル、脂肪、及びタンパク質の含有量が高い液状食品まで含めた汎用性の改善が求められている。また、例えば味噌汁など、本来温かい状態で喫食される食品では、再加温しても咀嚼・嚥下困難者の喫食に適した物性を維持することができるゲル化剤が求められている。   Furthermore, the conventional gelling agent composition for those with difficulty in chewing / swallowing mainly eats liquid foods such as water and tea that are gelled, such as fruit juice drinks, miso soup, milk, concentrated liquid foods, etc. There is a need for improved versatility including liquid foods with low pH, liquid foods with high mineral, fat, and protein contents. In addition, for foods that are eaten in an originally warm state, such as miso soup, for example, there is a need for a gelling agent that can maintain physical properties suitable for eating by those who have difficulty chewing or swallowing even when reheated.

特開2002−300854号公報JP 2002-300854 A 特開2001−346527号公報JP 2001-346527 A 特開2005−253347号公報JP 2005-253347 A 特開平11−124342号公報JP-A-11-124342 特開平03−262446号公報Japanese Patent Laid-Open No. 03-262446 特開2005−245308号公報JP 2005-245308 A

そこで、本発明は、50〜60℃といったゲル化剤の溶解温度としては比較的低温の液状食品に良好に分散、溶解して液状食品をゲル化させることができ、再加温を行った場合であってもゲル状食品が溶解することなく良好な保形性を保つことのできるゲル化剤を提供することを目的とする。そして、水やお茶だけでなく、果汁飲料、味噌汁(スープ)、牛乳、濃厚流動食など、低pHの液状食品やミネラル、脂肪、及びタンパク質の含有量が高い液状食品にも適応可能なゲル化剤であって、更には、手攪拌のような緩い攪拌条件でもダマになることなく良好に分散し、咀嚼・嚥下困難者の喫食に適したゲル状食品を提供することができるゲル化剤を提供することを目的とする。更には、咀嚼・嚥下困難者自身だけでなく、その看護者の利便性も改善することを目的とする。   Therefore, in the present invention, the dissolution temperature of the gelling agent such as 50 to 60 ° C. can be well dispersed and dissolved in a relatively low temperature liquid food product to gel the liquid food product, and reheating is performed. Even so, an object of the present invention is to provide a gelling agent capable of maintaining good shape retention without dissolving the gel food. Gelation can be applied not only to water and tea, but also to liquid foods with low pH, such as fruit juice, miso soup, milk, and concentrated liquid food, and liquid foods with high mineral, fat, and protein contents. Furthermore, a gelling agent that can provide a gel-like food that is well-dispersed even under gentle stirring conditions such as hand stirring without being lumped and suitable for eating by persons with difficulty in chewing / swallowing. The purpose is to provide. Furthermore, it aims at improving not only a chewing / swallowing difficult person itself but the convenience of the nurse.

本発明者らは、上記従来技術の問題点に鑑み、鋭意研究を重ねていたところ、ゲル化剤として易溶性寒天及び重量平均分子量が1.5×10g/mol以上のグァーガムを含み、前記易溶性寒天に対して、前記グァーガムの含有量を60〜700質量%とすることにより、50〜60℃といったゲル化剤の溶解温度としては比較的低温の液状食品でも良好に分散、溶解して液状食品をゲル化させることができ、再加温を行った場合であってもゲル状食品が溶解することなく良好な保形性を保つことができることを見出して本発明に至った。更に、本発明者らは、上記寒天及びグァーガムに加え、キサンタンガムを含有することにより、寒天に由来する食感的な脆さが解消され、より適度な弾力性が付与されること、及びネイティブ型ジェランガムを含有することによりゲル化時間が短縮され、より短時間で咀嚼・嚥下困難者の喫食に適したゲル状食品を提供できることを見出して本発明を完成した。 In light of the above-mentioned problems of the prior art, the present inventors have conducted extensive research, and include a readily soluble agar as a gelling agent and guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more, By setting the content of the guar gum to 60 to 700% by mass with respect to the readily soluble agar, even a liquid food having a relatively low temperature as a dissolution temperature of the gelling agent such as 50 to 60 ° C. can be well dispersed and dissolved. Thus, the present inventors have found that the liquid food can be gelled and that even when reheating is performed, the gel food can be kept in good shape without dissolving, and the present invention has been achieved. Furthermore, the present inventors include xanthan gum in addition to the above agar and guar gum, thereby eliminating the textured brittleness derived from agar and imparting more appropriate elasticity, and the native type The gelation time was shortened by containing gellan gum, and it discovered that the gel-like food suitable for a chewing / swallowing person's eating can be provided in a shorter time, and completed this invention.

本発明は、以下の態様を有する咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤に関する;
項1.咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤であって、易溶性寒天及び重量平均分子量が1.5×10g/mol以上のグァーガムを含み、前記易溶性寒天に対して、前記グァーガムの含有量が60〜700質量%であることを特徴とするゲル化剤。
項2.更に、キサンタンガム及び/又はネイティブ型ジェランガムを含む、項1に記載のゲル化剤。
項3.更に、デキストリン、澱粉及び糖類から選択される少なくとも1種のバインダーを含む項1又は2に記載のゲル化剤。
項4.造粒されていることを特徴とする項1〜3のいずれかに記載のゲル化剤。
The present invention relates to a gelling agent for preparing a gel-like food for persons with difficulty in chewing / swallowing having the following aspects;
Item 1. A gelling agent for preparing a gel food for persons with difficulty in chewing / swallowing, comprising a readily soluble agar and a guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more. The gelling agent is characterized in that the content of the guar gum is 60 to 700% by mass.
Item 2. Item 2. The gelling agent according to Item 1, further comprising xanthan gum and / or native gellan gum.
Item 3. Item 3. The gelling agent according to Item 1 or 2, further comprising at least one binder selected from dextrin, starch and saccharide.
Item 4. Item 4. The gelling agent according to any one of Items 1 to 3, which is granulated.

更に、本発明は以下の態様を有する咀嚼・嚥下困難者用ゲル状食品に関する;
項5.液状食品に、項1〜4のいずれかに記載のゲル化剤を添加することにより調製された、咀嚼・嚥下困難者用ゲル状食品。
項6.液状食品が、下記(1)〜(4)のうち少なくとも1種の条件を満たすものである、項5に記載の咀嚼・嚥下困難者用ゲル状食品;
(1)pHが2〜5の範囲である。
(2)ミネラル分の含有量が液状食品全量に対して0.01〜10質量%である。
(3)脂肪分の含有量が液状食品全量に対して0.1〜50質量%である。
(4)タンパク質の含有量が液状食品全量に対して0.1〜20質量%である。
Furthermore, the present invention relates to a gel food for persons with difficulty in chewing / swallowing having the following embodiment;
Item 5. Item 5. A gel food for persons with difficulty in chewing / swallowing prepared by adding the gelling agent according to any one of Items 1 to 4 to a liquid food.
Item 6. Item 6. The gelled food for people with difficulty in chewing / swallowing according to Item 5, wherein the liquid food satisfies at least one of the following conditions (1) to (4):
(1) The pH is in the range of 2-5.
(2) Mineral content is 0.01-10 mass% with respect to liquid food whole quantity.
(3) The fat content is 0.1 to 50% by mass with respect to the total amount of liquid food.
(4) Protein content is 0.1-20 mass% with respect to liquid food whole quantity.

本発明のゲル化剤を使用することにより、ゲル化剤の溶解温度としては比較的低温である50〜60℃の液状食品でも良好に分散・溶解し、室温で静置して冷却するのみで、咀嚼・嚥下困難者の喫食に適したゲル状食品を調製できる。更に、本発明により、再加温した場合であっても、ゲル状食品が溶解することなく良好な保形性を保つことができるため、味噌汁(スープ)など温かい状態のままで提供できる。また本発明のゲル化剤は、一般的に増粘させたり、咀嚼・嚥下困難者の喫食に適した物性に調整することが難しいとされる低pHの液状食品や、食塩などのミネラル、脂肪、及びタンパク質の含有量が高い液状食品にも適応できる。   By using the gelling agent of the present invention, the dissolution temperature of the gelling agent is well dispersed and dissolved even in a liquid food of 50 to 60 ° C., which is relatively low temperature, and is allowed to stand and cool at room temperature. It is possible to prepare a gel food suitable for eating by those who have difficulty chewing or swallowing. Furthermore, according to the present invention, even when re-warmed, good shape retention can be maintained without dissolving the gel-like food, so that it can be provided in a warm state such as miso soup (soup). In addition, the gelling agent of the present invention is generally a low pH liquid food, which is difficult to adjust to physical properties suitable for eating by persons with difficulty in chewing or swallowing, minerals such as salt, fat And liquid foods with a high protein content.

また、本発明のゲル化剤は、手撹拌のような緩い撹拌でもダマになることなく、液状食品に良好に分散、溶解させることができ、品質が安定したゲル状食品を調製できる。更に、ゲル化時間を短縮することができるため、ベットサイドや家庭で、咀嚼・嚥下困難者の喫食に適したゲル状食品を短時間で簡単に調製できる。しかも本発明のゲル化剤は添加量を調節することにより、障害の程度や体調に合わせてゲルの物性を調整できる。係る点からしても本発明のゲル化剤は、いわゆる即席ゲル化剤として有用である。   Further, the gelling agent of the present invention can be well dispersed and dissolved in a liquid food without causing any fouling even by gentle stirring such as manual stirring, and a gel-like food with stable quality can be prepared. Furthermore, since the gelling time can be shortened, a gel-like food suitable for eating by persons with difficulty in chewing / swallowing can be easily prepared in a short time at the bedside or at home. Moreover, the gelling agent of the present invention can adjust the physical properties of the gel in accordance with the degree of injury and physical condition by adjusting the amount of addition. Even from this point, the gelling agent of the present invention is useful as a so-called instant gelling agent.

本発明のゲル化剤は、咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤であって、易溶性寒天及び重量平均分子量が1.5×10g/mol以上のグァーガムを含み、前記易溶性寒天に対して、前記グァーガムの含有量が60〜700質量%であることを特徴とする。 The gelling agent of the present invention is a gelling agent for preparing a gel food for persons with difficulty in chewing / swallowing, and comprises a readily soluble agar and a guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more. In addition, the content of the guar gum is 60 to 700% by mass with respect to the readily soluble agar.

本発明でいう咀嚼・嚥下困難者用ゲル状食品とは、食物を噛み砕き飲み込むという一連の動作に障害をもつ、いわゆる咀嚼・嚥下困難者向けに調製されるゲル状食品をいう。なお、咀嚼・嚥下困難者用ゲル状食品に適した物性として、1)適度なかたさを有すること、2)食塊形成性(口中での食品のまとまりやすさ)に優れること、3)口腔及び咽頭への付着性が小さいこと、及び4)保水性が高いこと(離水が少ないこと)などが挙げられる。そして、本発明のゲル化剤を用いることにより、上記の要件を満たす咀嚼・嚥下困難者の喫食に適したゲル状食品を調製することが可能となった。また、本発明のゲル化剤は、高温での加熱溶解を必要とせず、50〜60℃といったゲル化剤の溶解温度としては比較的低温の液状食品に添加しても分散・溶解し、室温で静置して冷却するのみゲル化させることができるため、咀嚼・嚥下困難者用ゲル状食品を簡便、なおかつ短時間で調製することが可能となった。係る点において、本発明のゲル化剤はいわゆる即席ゲル化剤として有用性が高い。   The gel food for people with difficulty in chewing / swallowing as used in the present invention refers to a gel food prepared for those who have difficulty in chewing / swallowing, which has an obstacle in a series of operations of chewing and crushing food. In addition, as physical properties suitable for gel-like foods for persons with difficulty in chewing / swallowing, 1) having an appropriate hardness, 2) excellent bolus formation (easiness of collecting food in the mouth), 3) oral cavity and Examples include low adhesion to the pharynx and 4) high water retention (low water separation). And by using the gelling agent of this invention, it became possible to prepare the gel-like food suitable for the eating of the chewing / swallowing person who satisfy | fills said requirements. Further, the gelling agent of the present invention does not require heating and dissolution at a high temperature, and the gelling agent dissolves and dissolves even when added to a liquid food at a relatively low temperature, such as 50 to 60 ° C. Therefore, it is possible to prepare a gel food for persons with difficulty in chewing / swallowing easily and in a short time. In this respect, the gelling agent of the present invention is highly useful as a so-called instant gelling agent.

本発明のゲル化剤で用いる易溶性寒天とは、次に掲げる性質をもつ寒天をいう。
(A)溶解率が60〜100%、好ましくは70〜100%、より好ましくは80〜100%である。なお、本発明における溶解率とは、寒天1%を90℃の水に溶解してゲルを調製したときのゲル強度に対し、寒天1%を50℃の水に溶解してゲルを調製したときのゲル強度の相対値を示し、溶解率(%)=ゲル強度(50℃溶解)/ゲル強度(90℃溶解)×100によって求められる(以下、本発明では、本計算式によって求められる数値を「溶解率」という)。また、本発明で用いる易溶性寒天は、通常の寒天と同じくガラクトースを主成分とする海藻由来の中性多糖類で、D−ガラクトースと3,6−アンヒドロ−L−ガラクトースの繰り返し単位をもつ。
The readily soluble agar used in the gelling agent of the present invention refers to agar having the following properties.
(A) The dissolution rate is 60 to 100%, preferably 70 to 100%, more preferably 80 to 100%. The dissolution rate in the present invention refers to the gel strength obtained when 1% agar is dissolved in 90 ° C. water and the gel strength is prepared, and when the gel is prepared by dissolving 1% agar in 50 ° C. water. Relative value of gel strength is calculated by the following formula: dissolution rate (%) = gel strength (50 ° C. dissolution) / gel strength (90 ° C. dissolution) × 100 "Dissolution rate"). Further, the readily soluble agar used in the present invention is a neutral polysaccharide derived from seaweed containing galactose as the main component as in normal agar, and has repeating units of D-galactose and 3,6-anhydro-L-galactose.

一方、従来の寒天は50℃における溶解率は0%であり、係る寒天を用いてゲル状食品を調製する場合は、90〜100℃といった高温での加熱溶解を必要とするため、調製時にお湯で火傷する恐れがあるなど、特に高齢者等にとって使用しづらいという問題点があった。更に、寒天は脆い食感のゲルを形成し、一度破砕したゲルは再結着しにくいという性質を有し、一方で脆さを低減するために低濃度で使用すると離水が多くなるという問題があり、寒天単独では咀嚼・嚥下困難者の喫食に適した物性を付与することは困難であった。   On the other hand, the conventional agar has a dissolution rate of 0% at 50 ° C., and when a gel food is prepared using such agar, it requires hot dissolution at a high temperature of 90 to 100 ° C. There is a problem that it is difficult to use especially for elderly people. Furthermore, agar forms a brittle textured gel, and once crushed gel has the property that it is difficult to reattach, while on the other hand, when used at a low concentration to reduce brittleness, there is a problem that water separation increases. In addition, it was difficult for agar alone to impart physical properties suitable for eating by persons with difficulty in chewing or swallowing.

本発明では、易溶性寒天と併用して、重量平均分子量が1.5×10g/mol以上、好ましくは1.5×10〜3.5×10g/molであるグァーガムを用いることを特徴とする。ここで、グァーガムは、β−1,4−D−マンナンの主鎖骨格に側鎖としてα−D−ガラクトースが1,6結合した、マメ科植物由来の中性多糖類であり、食品産業界では増粘剤として、ソース類、麺類、アイスクリーム類等に使用されている。グァーガム中のマンノースとガラクトースの比率は約2:1で、工業的に生産されている他のガラクトマンナン類(タラガム、ローカストビーンガム)に比べて側鎖基含量が高く、水への溶解性も高い。なお、グァーガムには精製タイプ、未精製タイプのいずれもが適応可能である。 In the present invention, guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more, preferably 1.5 × 10 6 to 3.5 × 10 6 g / mol is used in combination with easily soluble agar. It is characterized by that. Here, guar gum is a legume-derived neutral polysaccharide in which α-D-galactose is linked to the main chain skeleton of β-1,4-D-mannan as a side chain in 1,6, and is used in the food industry. Is used as a thickener in sauces, noodles, ice creams and the like. The ratio of mannose and galactose in guar gum is about 2: 1, and the side chain group content is higher than other industrially produced galactomannans (tara gum, locust bean gum), and the solubility in water is also high. high. For the guar gum, both purified and unpurified types can be applied.

そして本発明は、グァーガムの中でも特に、重量平均分子量が1.5×10g/mol以上といった、上記特定分子量を有するグァーガムと易溶性寒天を併用することにより、下記効果を奏することを見出して至った発明である。そして本発明のゲル化剤において、グァーガムは寒天のゲル構造を補強(分子的な相互作用を含む)し、寒天に由来する食感的なもろさを解消して、適度な粘弾性を付与し、更に保水性を高めるという効果がある。また、寒天のゲル化温度を上昇させるという効果があり、ゲル形成に要する時間を短縮する。寒天及びグァーガムとも酸性あるいは塩基性の官能基を含まず、従って、ミネラル、脂肪、タンパク質などの共存物質によらず、安定して、同等の食感及び力学的性質を有するゲル状食品を調製することができる。なお、本発明において上記重量平均分子量は、サイズ排除クロマトグラフィー−多角度光散乱法にて求めた。上述の特定重量平均分子量を有するグァーガムは商業的に入手可能であり、例えば三栄源エフ・エフ・アイ株式会社製のビストップ[商標]D−2029を挙げることができる。 And this invention discovered that the following effect was show | played by using together the guar gum which has the said specific molecular weights, such as a weight average molecular weight of 1.5 * 10 < 6 > g / mol or more, and easily soluble agar, especially among guar gums. It is a perfect invention. And in the gelling agent of the present invention, guar gum reinforces the gel structure of agar (including molecular interaction), eliminates the fragile texture derived from agar, and imparts appropriate viscoelasticity, Furthermore, there is an effect of increasing water retention. In addition, there is an effect of increasing the gelation temperature of the agar, and the time required for gel formation is shortened. Neither agar nor guar gum contains acidic or basic functional groups, and therefore, a gel-like food having the same texture and mechanical properties is stably prepared regardless of coexisting substances such as minerals, fats and proteins. be able to. In the present invention, the weight average molecular weight was determined by size exclusion chromatography-multi-angle light scattering method. Guar gum having the specific weight average molecular weight described above is commercially available, and examples thereof include Bistop [trademark] D-2029 manufactured by San-Ei Gen FFI Co., Ltd.

なお、本発明のゲル化剤は、易溶性寒天に対し、重量平均分子量が1.5×10g/mol以上であるグァーガムを60〜700質量%、より好ましくは80〜500質量%、更に好ましくは100〜300質量%含有することを特徴とする。易溶性寒天とグァーガムを上記特定量で配合することにより、50〜60℃といった飲食に適した温度に直接溶解することが可能であり、その後、特別な冷却工程を経ることなく、室温で静置して冷却するのみで、咀嚼・嚥下困難者の喫食に適したゲル状食品を簡便に調製することができる。更に、本発明のゲル化剤は、いったんゲル状食品を調製した後に、60℃程度まで再加温してもゲル状食品が溶解することなく良好な保形性を有し、更には咀嚼・嚥下困難者用ゲル状組成物として適した物性を維持することができるため、例えばゲル状味噌汁など、温かい状態で喫食することのできる咀嚼・嚥下困難者用ゲル状食品を提供できる。また、事前にゲル状食品を調製しておき、喫食する際に加熱して即座に温かい咀嚼・嚥下困難者用ゲル状食品を提供することもできる。 The gelling agent of the present invention is 60 to 700% by mass, more preferably 80 to 500% by mass, and more preferably 80 to 500% by mass of guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more with respect to readily soluble agar. Preferably it contains 100-300 mass%, It is characterized by the above-mentioned. By blending easily soluble agar and guar gum in the above specific amounts, it can be dissolved directly at a temperature suitable for food and drink such as 50-60 ° C., and then left at room temperature without passing through a special cooling step. Then, by simply cooling, a gel food suitable for eating by persons with difficulty in chewing / swallowing can be easily prepared. Furthermore, the gelling agent of the present invention has a good shape retaining property without dissolving the gel food even after re-heating to about 60 ° C. once the gel food is prepared. Since the physical properties suitable as a gel-like composition for persons with difficulty in swallowing can be maintained, a gel-like food for persons with difficulty in chewing / swallowing that can be eaten in a warm state such as gel-like miso soup can be provided. It is also possible to prepare a gel-like food in advance and heat it when eating and immediately provide a gel-like food for those who have difficulty in chewing / swallowing.

本発明のゲル化剤は、更に、キサンタンガム及び/又はネイティブ型ジェランガムを含むことが好ましい。ここで、キサンタンガムとは、Xanthomonas campesrtisが産生する発酵多糖類である。キサンタンガムは、β−1,4−D−グルカンを主鎖骨格とし、主鎖中のグルコース1分子おきにα−D−マンノース、β−D−グルクロン酸、β−D−マンノースからなる側鎖が結合した酸性多糖類であり、主鎖に結合したマンノースはC6位がアセチル化され、末端のマンノースはピルビン酸とアセタール結合している場合がある。本発明では、アセチル基含量が通常よりも低いあるいはアセチル基を含まないキサンタンガム、及びピルビン酸含量が通常よりも低いあるいはピルビン酸を含まないキサンタンガムも使用することができる。易溶性寒天とグァーガムに加え、キサンタンガムを含有することにより、ゲル化剤を用いて調製したゲル状食品の食感及び力学的性質を改良することができる。具体的には、寒天に由来する食感的な脆さを解消し、適度な粘弾性を付与する。寒天のゲル構造を補強する効果は小さく、むしろグァーガムとの分子的相互作用により、粘性を増加させる効果がある。なお、上述のキサンタンガムは商業的に入手可能であり、例えば三栄源エフ・エフ・アイ株式会社製のビストップ[商標]D−3000−C(キサンタンガム標準タイプ)を挙げることができる。 The gelling agent of the present invention preferably further contains xanthan gum and / or native gellan gum. Here, xanthan gum is a fermentation polysaccharide produced by Xanthomonas campesrtis . Xanthan gum has β-1,4-D-glucan as the main chain skeleton, and side chains consisting of α-D-mannose, β-D-glucuronic acid, and β-D-mannose every other glucose molecule in the main chain. In some cases, the mannose bound to the main chain is acetylated at the C6 position, and the terminal mannose is acetal-bonded to pyruvic acid. In the present invention, xanthan gum having an acetyl group content lower than usual or containing no acetyl group, and xanthan gum having a lower pyruvic acid content than usual or containing no pyruvic acid can also be used. By containing xanthan gum in addition to readily soluble agar and guar gum, the texture and mechanical properties of the gel food prepared using the gelling agent can be improved. Specifically, the textured brittleness derived from agar is eliminated and moderate viscoelasticity is imparted. The effect of reinforcing the gel structure of the agar is small, but it has the effect of increasing the viscosity due to molecular interaction with guar gum. In addition, the above-mentioned xanthan gum is commercially available. For example, Bistop [trademark] D-3000-C (xanthan gum standard type) manufactured by San-Ei Gen FFI Co., Ltd. can be mentioned.

本発明のゲル化剤におけるキサンタンガムの添加量は、適用する液状食品や必要とされる物性によって適宜調節することが可能であるが、具体的には、前記易溶性寒天とグァーガムの合計量に対して1〜200質量%、好ましくは5〜100質量%、更に好ましくは20〜80質量%含むことが好ましい。   The amount of xanthan gum added to the gelling agent of the present invention can be appropriately adjusted depending on the liquid food to be applied and the required physical properties. Specifically, the amount of xanthan gum is based on the total amount of the readily soluble agar and guar gum. 1 to 200% by mass, preferably 5 to 100% by mass, more preferably 20 to 80% by mass.

一方、ネイティブ型ジェランガム(高アシル型ジェランガム)とは、Sphingomonas elodeaが産生する発酵多糖類である。1−3結合したグルコース、1−4結合したグルクロン酸、1−4結合したグルコース及び1−4結合したラムノースの4分子を構成単位とする直鎖状の酸性多糖類であり、1−3結合したグルコースに1構成単位当たりグリセリル基1残基とアセチル基が平均1/2残基結合している。ネイティブ型ジェランガムを含有させることにより、本発明のゲル化剤を用いてゲル状食品を調製した際のゲル化時間を短縮することができる。具体的には、1−3結合したグルコース残基に結合したグリセリル基がヘリックス構造の形成に寄与するため、高い温度でゲル化する効果がある。なお、上述のネイティブ型ジェランガムは商業的に入手可能であり、例えば三栄源エフ・エフ・アイ株式会社製のケルコゲルHTを挙げることができる。 On the other hand, native gellan gum (high acyl gellan gum) is a fermented polysaccharide produced by Sphingomonas elodea . It is a linear acidic polysaccharide composed of four molecules of 1-3-bonded glucose, 1-4-bonded glucuronic acid, 1-4-bonded glucose, and 1-4-bonded rhamnose, and has 1-3 bonds 1 glucose glyceryl group and acetyl group are bonded to 1/2 glucose on average per one constituent unit. By including native gellan gum, it is possible to shorten the gelation time when a gelled food is prepared using the gelling agent of the present invention. Specifically, since the glyceryl group bonded to the 1-3 bonded glucose residue contributes to the formation of the helix structure, there is an effect of gelation at a high temperature. The above-mentioned native gellan gum is commercially available, and examples thereof include Kelcogel HT manufactured by San-Ei Gen FFI Co., Ltd.

ネイティブ型ジェランガムの添加量は、適用する液状食品や必要とされる物性によって適宜調節することが可能であるが、具体的には、前記易溶性寒天とグァーガムの合計量に対して1〜200質量%、好ましくは5〜100質量%、更に好ましくは10〜50質量%含むことが好ましい。   The amount of the native gellan gum can be adjusted as appropriate according to the liquid food to be applied and the required physical properties. Specifically, the amount of native gellan gum is 1 to 200 mass based on the total amount of the readily soluble agar and guar gum. %, Preferably 5 to 100% by mass, more preferably 10 to 50% by mass.

上記易溶性寒天と特定重量平均分子量のグァーガムを含有したゲル化剤の調製方法としては、最終的にゲル化剤に易溶性寒天とグァーガムが含有されていれば特に限定されず各種方法を用いることができ、またゲル化剤の形態も特に限定されず、液状、半固体状、固体状、粉末状など各種形態をとることができる。なお、ゲル化剤の調製方法の具体例としては、(1)リボンミキサーやVブレンダーを用いて粉体で混合する方法、(2)水中で加熱することによって溶解、均一分散させ液状とする方法、(3)別々に溶液を調製し、使用時に混合する方法、(4)混合溶液にアルコールなどの貧溶媒を加えて、寒天とグァーガムを共沈処理(コプロセス処理)する方法、(5)混合溶液をスプレードライ等により分散粉末化する方法、(6)粉体で混合し、プレス機で圧縮することにより打錠し、錠剤状にする方法、及び(7)粉体で混合し、造粒、顆粒化して使用する方法等などが挙げられ、中でも(7)に係る方法を用いて調製することが好ましい。   The preparation method of the gelling agent containing the above-mentioned readily soluble agar and guar gum having a specific weight average molecular weight is not particularly limited as long as the gelling agent finally contains easily soluble agar and guar gum. The form of the gelling agent is not particularly limited, and various forms such as liquid, semi-solid, solid, and powder can be used. Specific examples of the preparation method of the gelling agent include (1) a method of mixing with powder using a ribbon mixer or a V blender, and (2) a method of dissolving and uniformly dispersing into liquid by heating in water. (3) A method of preparing solutions separately and mixing them at the time of use, (4) A method of adding a poor solvent such as alcohol to the mixed solution, and coprecipitation treatment (co-process treatment) of agar and guar gum, (5) (6) Mixing with a powder by spray drying, etc., (6) Mixing with powder, compressing with a press and compressing into tablets, (7) Mixing with powder and making Examples of the method include granulating and granulating methods, and it is preferable to use the method according to (7).

なお、前記ゲル化剤は、バインダー(倍散剤)を含むことにより、液状食品への分散性、溶解性を向上させることができ、このようなバインダーとして、デキストリン、澱粉及び糖類から選択される少なくとも1種以上のバインダーを添加することができる。具体的には、デキストリン類として、デキストリン、アミロデキストリン、エリトロデキストリン、アクロデキストリン、マルトデキストリン、シクロデキストリン、澱粉類として、トウモロコシ、モチトウモロコシ、馬鈴薯、甘藷、小麦、米、餅米、タピオカ、サゴヤシ等由来の生澱粉や、当該澱粉に物理的又は、化学的処理を施した加工澱粉(酸分解澱粉、酸化澱粉、α化澱粉、グラフト化澱粉、カルボキシメチル基、ヒドロキシアルキル基等を導入したエーテル化澱粉、アセチル基等を導入したエステル化澱粉、澱粉の2カ所以上の水酸基を官能基を介して結合させた架橋澱粉、オクテニルコハク酸基のような疎水基を導入した乳化性澱粉、湿熱・乾熱処理澱粉等)が挙げられる。糖類としては、ショ糖、果糖、ぶどう糖、麦芽糖、澱粉糖化物、還元澱粉水飴、トレハロース等が挙げられる。中でも、DEが1〜50程度のデキストリンを好適に使用することができる。そして、前述のバインダーを、粉体混合等の混合によってゲル化剤に含有させることにより、ゲル化剤の液状食品への分散性、溶解性を向上させることができる。   In addition, the said gelatinizer can improve the dispersibility to a liquid food, and a solubility by including a binder (double powder), As such a binder, at least selected from dextrin, starch, and saccharides. One or more binders can be added. Specifically, as dextrins, dextrin, amylodextrin, erythrodextrin, acrodextrin, maltodextrin, cyclodextrin, starch as corn, waxy corn, potato, sweet potato, wheat, rice, sticky rice, tapioca, sago palm Raw starch or modified starch obtained by subjecting the starch to physical or chemical treatment (acid-degraded starch, oxidized starch, pregelatinized starch, grafted starch, ether introduced with carboxymethyl group, hydroxyalkyl group, etc.) Starch, esterified starch introduced with acetyl groups, cross-linked starch in which two or more hydroxyl groups of starch are bonded via functional groups, emulsified starch introduced with hydrophobic groups such as octenyl succinic acid groups, wet heat / dry Heat-treated starch, etc.). Examples of the saccharide include sucrose, fructose, glucose, maltose, saccharified starch, reduced starch syrup, and trehalose. Among these, dextrin having a DE of about 1 to 50 can be preferably used. And the dispersibility and solubility to the liquid foodstuff of a gelatinizer can be improved by making the above-mentioned binder contain in a gelatinizer by mixing, such as powder mixing.

なお、バインダーの配合割合については用いるゲル化剤の種類や形態によって適宜調節することが可能であるが、易溶性寒天及びグァーガム、必要に応じてキサンタンガム及び/又はネイティブ型ジェランガムの合計量に対して、10〜1000質量%、好ましくは50〜900質量%、更に好ましくは100〜400質量%添加することができる。   The blending ratio of the binder can be appropriately adjusted depending on the type and form of the gelling agent to be used, but with respect to the total amount of easily soluble agar and guar gum, and if necessary, xanthan gum and / or native gellan gum. 10 to 1000% by mass, preferably 50 to 900% by mass, more preferably 100 to 400% by mass.

なお、粉末の形態にて本発明のゲル化剤を用いる場合は、液状食品への分散性、溶解性の観点より、ゲル化剤は造粒(顆粒化)されていることが好ましい。造粒することにより、液状食品への分散性、溶解性が一段と向上し、例えば手攪拌のような緩い攪拌条件でもダマを生じることなくゲル化剤を溶解させることができる。つまり、高齢者や介護者が簡便に取り扱うことができるようになり、また該ゲル化剤を用いて調製されたゲル状食品の物性も安定したものとなる。造粒は常法にて行うことができ、例えば、回転式滴下型造粒装置、流動層造粒装置、転動造粒装置等の公知の装置によって造粒する方法などが挙げられる。中でも、流動層造粒装置によって造粒する方法が好ましい。なお、造粒する際のバインダー(倍散剤)としては特に限定されず、前述のバインダーを用いることができる。   In addition, when using the gelatinizer of this invention in the form of a powder, it is preferable that the gelatinizer is granulated (granulated) from the viewpoint of the dispersibility to a liquid food, and a solubility. By granulating, the dispersibility and solubility in liquid foods are further improved, and the gelling agent can be dissolved without causing lumps even under loose stirring conditions such as manual stirring. That is, elderly people and caregivers can easily handle it, and the physical properties of the gel-like food prepared using the gelling agent are also stabilized. Granulation can be performed by a conventional method, and examples thereof include a granulation method using a known apparatus such as a rotary dropping granulator, a fluidized bed granulator, and a rolling granulator. Among them, a method of granulating with a fluidized bed granulator is preferable. In addition, it does not specifically limit as a binder (granulating agent) at the time of granulation, The above-mentioned binder can be used.

本発明のゲル化剤を液状食品に添加することにより、咀嚼・嚥下困難者の喫食に適した物性を持つゲル状食品を調製することができるが、ゲル化させる液状食品としては特に限定されず、水分を有し、流動性のある各種液状食品を用いることができる。液状食品の具体例として、水、牛乳、乳飲料、乳酸菌飲料、ドリンクヨーグルト、果汁入り清涼飲料、オレンジジュース等の果汁飲料、菜汁飲料、茶飲料、コーヒー飲料、ココア飲料、スポーツ飲料、機能性飲料、イオン飲料、ビタミン補給飲料、栄養補給バランス飲料、赤ワイン等の果実酒、コンソメスープ、ポタージュスープ、クリームスープ、中華スープ等の各種スープ、味噌汁、清汁、シチュウ、カレー、グラタンなどの液状の最終食品や、蛋白質・リン・カリウム調整食品、塩分調整食品、油脂調整食品、整腸作用食品、カルシウム・鉄・ビタミン強化食品、低アレルギー食品、濃厚流動食、ミキサー食、及びキザミ食等の特殊食品や治療食の液状食品(ペースト状食品も含む)、醤油、ソース、ドレッシング等の液状調味料等を挙げることができ、これらの液状食品に直接、本発明のゲル化剤を添加してゲル状食品を調製することができる。あるいは、本発明のゲル化剤に粉末状の調味料や色素、香料を混合し、更にそれを造粒(顆粒化)して用いることもできる。この場合、一定量のお湯に上記粉末混合物あるいは顆粒を添加して、分散・溶解後、冷却してゲル状食品を調製することができる。   By adding the gelling agent of the present invention to a liquid food, a gel-like food having physical properties suitable for eating by persons with difficulty in chewing / swallowing can be prepared, but the liquid food to be gelled is not particularly limited. In addition, various liquid foods having moisture and fluidity can be used. Specific examples of liquid food include water, milk, milk drinks, lactic acid bacteria drinks, drink yogurt, soft drinks with fruit juice, fruit juice drinks such as orange juice, vegetable juice drinks, tea drinks, coffee drinks, cocoa drinks, sports drinks, functionality Beverages, ionic beverages, vitamin supplements, nutritional balanced beverages, fruit wines such as red wine, consommé soup, potage soup, cream soup, Chinese soup and other soups, miso soup, fresh soup, stew, curry, gratin, etc. Special foods such as foods, protein / phosphorus / potassium-adjusted foods, salt-adjusted foods, oil-and-fat-adjusted foods, intestinal foods, calcium / iron / vitamin-enriched foods, hypoallergenic foods, concentrated liquid foods, blended foods, and chopped foods Liquid foods (including pasty foods), liquid seasonings such as soy sauce, sauces and dressings It can gel directly to these liquid foods, it can be added to the gelling agent of the present invention for preparing a gelled food product. Alternatively, the gelling agent of the present invention can be mixed with a powdery seasoning, pigment, and fragrance, and further granulated (granulated). In this case, the above-mentioned powder mixture or granule is added to a certain amount of hot water, and after dispersion / dissolution, it is cooled to prepare a gel food.

本発明のゲル化剤は、上述のとおり、種々の液状食品に適用することが可能であるが、特に低pHの液状食品や、ミネラル、脂肪、及びタンパク質を含有量が高い液状食品など、安定的にゲルを形成しにくい液状食品に用いた場合であっても、他のゲル化剤に比べて優れた適性を示す。安定的にゲルを形成しにくい液状食品としては、下記(1)〜(4)のうち少なくとも1種の条件を満たす液状食品を挙げることができる。   As described above, the gelling agent of the present invention can be applied to various liquid foods, but particularly stable, such as low pH liquid foods and liquid foods having a high content of minerals, fats, and proteins. Even when it is used for liquid foods that are difficult to form gels, it shows superior suitability compared to other gelling agents. Examples of the liquid food that hardly forms a gel stably include liquid foods that satisfy at least one of the following conditions (1) to (4).

(1)pHが2〜5の範囲である液状食品
これら液状食品(ペースト状食品を含む)の一例として、オレンジジュース等の果汁飲料、清涼飲料、酸性乳飲料、ドリンクヨーグルト、酸性濃厚流動食などを挙げることができる。
(1) Liquid foods having a pH in the range of 2 to 5 As examples of these liquid foods (including pasty foods), fruit juice drinks such as orange juice, soft drinks, acidic milk drinks, drink yogurt, acidic concentrated liquid foods, etc. Can be mentioned.

(2)ミネラルの含有量が0.01〜10質量%である液状食品
ミネラルとしては、ナトリウム、カルシウム、カリウム、マグネシウム、鉄、銅、クロム、モリブデン、マンガン、亜鉛、リン、セレニウム、リチウム、パナジウム、コバルト、ニッケル、ホウ素、ゲルマニウム、臭素、ヨウ素などが含まれる。これら一定量のミネラルを含有する液状食品(ペースト状食品を含む)の一例として、食塩水、味噌汁、スープ、醤油、ソース、ドレッシング、イオン飲料、ビタミン補給飲料、栄養補給バランス飲料、濃厚流動食などを挙げることができる。
(2) Liquid food minerals having a mineral content of 0.01 to 10% by mass include sodium, calcium, potassium, magnesium, iron, copper, chromium, molybdenum, manganese, zinc, phosphorus, selenium, lithium, and panadium. , Cobalt, nickel, boron, germanium, bromine, iodine and the like. Examples of liquid foods (including pasty foods) containing a certain amount of minerals include saline, miso soup, soup, soy sauce, sauces, dressings, ionic beverages, vitamin supplements, balanced nutrition beverages, concentrated liquid foods, etc. Can be mentioned.

(3)脂肪の含有量が0.1〜50質量%である液状食品
これら液状食品(ペースト状食品を含む)の一例として、牛乳等の乳飲料、乳酸菌飲料、ミルク入りコーヒー、ミルク入り茶類、ミルクココア、ミルクセーキ、酸乳入り飲料、フルーツ牛乳、濃厚流動食などを挙げることができる。
(3) Liquid foods with a fat content of 0.1 to 50% by weight Examples of these liquid foods (including pasty foods) include milk drinks such as milk, lactic acid bacteria drinks, coffee with milk, tea with milk , Milk cocoa, milk shake, sour milk beverage, fruit milk, concentrated liquid food, and the like.

(4)タンパク質の含有量が0.1〜20質量%である液状食品
これら液状食品(ペースト状食品を含む)の一例として、濃厚流動食や豆乳等の植物性タンパク含有飲料、プロテイン飲料等の栄養ドリンクなどを挙げることができる。
(4) Liquid foods with a protein content of 0.1 to 20% by weight Examples of these liquid foods (including pasty foods) include concentrated liquid foods and vegetable protein-containing beverages such as soy milk, protein beverages, etc. The energy drink can be mentioned.

更に、本発明のゲル化剤は、前記(1)〜(4)の条件を複合的に満たす液状食品(ペースト状食品を含む)にも好適に使用できる。このような液状食品の一例として、ドリンクヨーグルト、スープ、濃厚流動食などを挙げることができる。   Furthermore, the gelling agent of the present invention can also be suitably used for liquid foods (including pasty foods) that satisfy the above conditions (1) to (4) in combination. Examples of such liquid foods include drink yogurt, soup, and concentrated liquid food.

また、本発明のゲル化剤を用いて調製したゲル状の濃厚流動食は、液状の濃厚流動食を経管的に経胃・経腸投与する場合に比べ、胃食道逆流が少ない、瘻孔からの液漏れが少ない、投与時間を短縮することができるなどの特長がある。また、付着性が低いため、チューブ内での流動性がよく、チューブ内残渣が少ないため、物性及び衛生性の両面から経腸・経管投与用の濃厚流動食として優れている。   In addition, the gel-like concentrated liquid food prepared using the gelling agent of the present invention has less gastroesophageal reflux, compared to the case where a liquid thick liquid food is administered through the stomach and enterally, from the fistula. There are features such as less liquid leakage and shortened administration time. Moreover, since the adhesiveness is low, the fluidity in the tube is good, and the residue in the tube is small, so that it is excellent as a concentrated liquid food for enteral / tube administration from both physical properties and hygiene.

ここで濃厚流動食とは、カロリー値が1 kcal/mL以上であり、栄養成分は少なくとも、タンパク質、脂質、炭水化物、ミネラル、ビタミンなどを含み、下痢などの副作用を最小限に抑え、ヒトの生体浸透圧よりも高く、細いチューブでも通過する流動性を有し、風味が良好で、数ヶ月常温で保存可能な乳化安定性を有するものを挙げることができる。   Here, the concentrated liquid food has a caloric value of 1 kcal / mL or more and contains at least protein, lipid, carbohydrates, minerals, vitamins, etc., and minimizes side effects such as diarrhea. It is higher than the osmotic pressure, has fluidity to pass even in a thin tube, has a good flavor, and has emulsion stability that can be stored at room temperature for several months.

本発明のゲル化剤を用いることにより、上記のような安定的にゲルを形成しにくいような液状食品であっても、咀嚼・嚥下困難者の喫食に適したゲル状食品を簡便に調製することができる。ゲル状食品に対するゲル化剤の添加量としては、ゲル状の対象とする液状食品の種類や、必要とされるゲル強度(かたさ)等によっても適宜調節することが可能であるが、具体的には、易溶性寒天とグァーガムが前述の配合割合であって、ゲル状食品に対し易溶性寒天が0.05〜0.9質量%、好ましくは0.05〜0.8質量%、更に好ましくは0.05〜0.7質量%、ゲル状食品に対しグァーガムが0.03〜3.0質量%、好ましくは0.035〜2.0質量%、更に好ましくは0.04〜1.5質量%となるように添加することができる。   By using the gelling agent of the present invention, a gel food suitable for eating by persons with difficulty in chewing / swallowing can be easily prepared even for liquid foods that are difficult to stably form a gel as described above. be able to. The amount of the gelling agent added to the gel food can be appropriately adjusted depending on the type of liquid food to be gelled, the required gel strength (hardness), and the like. Is easily mixed agar and guar gum in the above-mentioned mixing ratio, and 0.05 to 0.9% by mass, preferably 0.05 to 0.8% by mass, more preferably 0.05% to 0.8% by mass with respect to gelled food. 0.05-0.7 mass%, Guar gum is 0.03-3.0 mass%, preferably 0.035-2.0 mass%, more preferably 0.04-1.5 mass%, based on gel food % Can be added.

なお、本発明に係るゲル化剤を用いることで、50〜60℃といったゲル化剤の溶解温度としては比較的低温でゲル状食品を調製することが可能であるが、ゲル状食品を調製する際の温度は特にこれに限定されず、必要に応じて60℃より高い温度での加熱溶解工程を経て咀嚼・嚥下困難者の喫食に適したゲル状食品を調製することもできる。また、本発明では特に冷却装置を用いることなく、室温静置で冷却することによりゲル状食品を調製することができるため、ベットサイドや家庭の台所で簡便に咀嚼・嚥下困難者用ゲル状食品を調製することができる。   In addition, by using the gelling agent according to the present invention, it is possible to prepare a gelled food at a relatively low temperature as the gelling agent dissolution temperature such as 50 to 60 ° C., but the gelled food is prepared. The temperature at the time is not particularly limited to this, and a gel-like food suitable for eating by persons with difficulty in chewing / swallowing can be prepared through a heating and dissolving step at a temperature higher than 60 ° C., if necessary. Further, in the present invention, since a gel food can be prepared by cooling at room temperature without using a cooling device in particular, the gel food for those who have difficulty chewing / swallowing easily at the bedside or in the home kitchen. Can be prepared.

咀嚼・嚥下困難者用ゲル状食品に適した物性として、前述のとおり、1)適度なかたさを有すること、2)食塊形成性(口中での食品のまとまりやすさ)に優れること、3)口腔及び咽頭への付着性が小さいこと、及び4)保水性が高いこと(離水が少ないこと)などが挙げられる。また、ゲル状食品のゲル強度としては、20℃におけるゲル強度が5×10〜5×10N/m、好ましくは5×10〜5×10N/m、更に好ましくは5×10〜1×10N/mであることが挙げられる。この場合、ゲル強度とは、厚生労働省特別用途食品「高齢者用食品」のかたさの測定方法で測定したときの圧縮応力をいう。なお、本発明においてゲル強度の測定は、テクスチャーアナライザー(TA−XT2i,Stable Micro Systems社)を用い、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。本発明のゲル化剤は、低pHの液状食品や、ミネラル、脂肪、及びタンパク質の含有量が高い液状食品など、安定的にゲルを形成しにくい液状食品においても良好に分散、溶解し、ゲル化を形成するため、品質の安定化が図れる。 As described above, the physical properties suitable for gel foods for persons with difficulty in chewing and swallowing are as follows: 1) having moderate hardness, 2) excellent mass formation (easiness of collecting food in the mouth), 3) Examples include low adhesion to the oral cavity and pharynx, and 4) high water retention (low water separation). The gel strength of the gel food is 5 × 10 2 to 5 × 10 5 N / m 2 , preferably 5 × 10 2 to 5 × 10 4 N / m 2 , more preferably 20 ° C. 5 and the like to be a × 10 2 ~1 × 10 4 N / m 2. In this case, the gel strength refers to the compressive stress when measured by the hardness measurement method of the special-purpose food “food for the elderly” of the Ministry of Health, Labor and Welfare. In the present invention, the gel strength was measured using a texture analyzer (TA-XT2i, Stable Micro Systems) at a plunger of 20 mm in diameter, compression rate: 10 mm / sec, and clearance: 5 mm. The gelling agent of the present invention is well dispersed and dissolved in liquid foods that are difficult to form a gel stably, such as liquid foods with low pH and liquid foods with a high content of minerals, fats, and proteins. As a result, the quality can be stabilized.

本発明のゲル化剤には、本発明の効果に悪影響を及ぼさない限度で、カラギナン(カッパ、イオタ、ラムダ、あるいはそれらのハイブリッド型など共重合物)、アルギン酸類(アルギン酸、アルギン酸塩)、ガラクトマンナン(フェヌグリークガム、ローカストビーンガム、タラガム等)、タマリンドシードガム(ガラクトース側鎖を除去したものも含む)、カシアガム、グルコマンナン、サイリウムシードガム、大豆多糖類、ペクチン(ローメトキシル型、ハイメトキシル型、ローメトキシアミド型、シュガービード由来のペクチンなど)、アラビアガム、ガティガム、トラガントガム、カラヤガム、脱アシル型ジェランガム、プルラン、カードラン、マクロホモプシスガム、ゼラチン、メチルセルロース(MC)、ヒドロキシプロピルメチルセルロース(HPMC)、カルボキシメチルセルロース(CMC)ナトリウム、ヒドロキシプロピルセルロース(HPC)、ヒドロキシエチルセルロース(HEC)等のセルロース誘導体、水溶性ヘミセルロース、加工・化工でん粉、未加工でん粉(生でん粉)、デキストリンなどから選ばれる1種又は2種以上のゲル化剤、増粘剤等を併用することができる。   The gelling agent of the present invention includes carrageenan (a copolymer such as kappa, iota, lambda, or a hybrid type thereof), alginic acids (alginic acid, alginates), galacto as long as the effects of the present invention are not adversely affected. Mannan (fenugreek gum, locust bean gum, tara gum, etc.), tamarind seed gum (including galactose side chain removed), cassia gum, glucomannan, psyllium seed gum, soybean polysaccharide, pectin (low methoxyl type, high methoxyl type) , Low methoxyamide type, sugar bead-derived pectin), gum arabic, gati gum, gum tragacanth, karaya gum, deacylated gellan gum, pullulan, curdlan, macrohomopsis gum, gelatin, methylcellulose (MC), hydroxypropylme Cellulose derivatives such as cellulose cellulose (HPMC), sodium carboxymethyl cellulose (CMC), hydroxypropyl cellulose (HPC), hydroxyethyl cellulose (HEC), water-soluble hemicellulose, processed / modified starch, raw starch (raw starch), dextrin, etc. One or two or more selected gelling agents, thickeners, and the like can be used in combination.

また、本発明のゲル化剤には、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル(モノグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル、有機酸モノグリセライド、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル)、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル(ポリソルベート)、レシチン、ステアロイル乳酸塩(ナトリウムもしくはカルシウム)、ユッカ抽出物等の乳化剤、クエン酸、クエン酸ナトリウム、クエン酸カリウム、コハク酸、コハク酸ナトリウム、酒石酸、酒石酸ナトリウム、酒石酸水素カリウム、乳酸、乳酸ナトリウム、アスコルビン酸、アスコルビン酸ナトリウム、グルコン酸、グルコン酸ナトリウム、グルコン酸カリウム、エリソルビン酸ナトリウム、炭酸ナトリウム、炭酸カリウム、フィチン酸等の有機酸、無機酸やその塩類を添加することができる。更には、ソルビトール、エリスリトール、キシリトール、マンニトール等の糖アルコール類、スクラロース、アスパルテーム、ステビア、アセスルファムカリウム、ソーマチン、サッカリン等の高甘味度甘味料類、カテキン、カルニチン、グルコサミン、コンドロイチン、イソフラボン、リグナン、プロポリス、コラーゲン等の機能性素材等を添加することができる。更に、天然香料、合成香料等の香料類、カラメル色素等の着色料、調味料を添加することができる。   The gelling agent of the present invention includes sucrose fatty acid ester, glycerin fatty acid ester (monoglycerin fatty acid ester, diglycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester), sorbitan fatty acid ester. , Propylene glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester (polysorbate), lecithin, stearoyl lactate (sodium or calcium), emulsifier such as yucca extract, citric acid, sodium citrate, potassium citrate, succinic acid, succinic acid Sodium, tartaric acid, sodium tartrate, potassium hydrogen tartrate, lactic acid, sodium lactate, ascorbic acid, sodium ascorbate, gluconic acid, sodium gluconate, Potassium Con acids, may be added sodium erythorbate, sodium carbonate, potassium carbonate, organic acids such as phytic acid, inorganic acids and salts thereof. Furthermore, sugar alcohols such as sorbitol, erythritol, xylitol, mannitol, high sweetness sweeteners such as sucralose, aspartame, stevia, acesulfame potassium, thaumatin, saccharin, catechin, carnitine, glucosamine, chondroitin, isoflavone, lignan, propolis Functional materials such as collagen can be added. Furthermore, fragrance | flavors, such as a natural fragrance | flavor and a synthetic fragrance | flavor, coloring agents, such as a caramel pigment | dye, and a seasoning can be added.

以下、本発明の内容を以下の実施例、比較例を用いて具体的に説明するが、本発明はこれらに何ら限定されるものではない。また、特に記載のない限り「部」とは「質量部」、「%」は「質量%」を意味するものとする。   Hereinafter, the content of the present invention will be specifically described with reference to the following examples and comparative examples, but the present invention is not limited thereto. Unless otherwise specified, “parts” means “parts by mass” and “%” means “% by mass”.

実験例1 ゲル化剤の調製
表1に示す処方に従って実施例1〜3及び比較例1〜5のゲル化剤を調製した。詳細には、表1に示す各種粉末原料を混合し、流動層造粒機を用い、粉体混合物500gに対してバインダー液として脱イオン水250gを噴霧して造粒し、各種ゲル化剤(顆粒品)を調製した。また、比較例6として、キサンタンガムとローカストビーンガムを含有した市販品を用いた。
Experimental Example 1 Preparation of Gelling Agents Gelling agents of Examples 1 to 3 and Comparative Examples 1 to 5 were prepared according to the formulation shown in Table 1. Specifically, various powder raw materials shown in Table 1 are mixed, and using a fluidized bed granulator, granulated by spraying 250 g of deionized water as a binder liquid onto 500 g of the powder mixture, and various gelling agents ( Granule product) was prepared. Moreover, as Comparative Example 6, a commercial product containing xanthan gum and locust bean gum was used.

Figure 2012157370
Figure 2012157370

注1)50℃における溶解率が98%である寒天を用いた。
注2)50℃における溶解率が0%である寒天を用いた。
注3)サイズ排除クロマトグラフィー−多角度光散乱法から求めた重量平均分子量注5)が約2.0×10g/molであるグァーガムを用いた。
注4)サイズ排除クロマトグラフィー−多角度光散乱法から求めた重量平均分子量が約0.5×10g/molであるグァーガムを用いた。
Note 1) Agar with a dissolution rate of 98% at 50 ° C was used.
Note 2) Agar with a dissolution rate at 50 ° C. of 0% was used.
Note 3) Guar gum having a weight average molecular weight Note 5) of about 2.0 × 10 6 g / mol obtained from size exclusion chromatography-multi-angle light scattering method was used.
Note 4) Guar gum having a weight average molecular weight of about 0.5 × 10 6 g / mol obtained from size exclusion chromatography-multi-angle light scattering method was used.

注5)グァーガムの重量平均分子量は、サイズ排除クロマトグラフィーと連結した多角度光散乱法(SEC−MALLS)により決定した。詳細には、サイズ排除クロマトグラフィー用カラムとして排除体積2,000万DaのOHpak SB−806M HQを、移動相として0.05M 硝酸ナトリウム/0.02% アジ化ナトリウムを使用し、流速0.5mL/minで分画を行った。次に、静的光散乱測定装置DAWN−DSPにより、分画した試料の散乱強度(散乱角26−132度)を、温度25℃、波長633nmで測定した。また、RI検出器(Shodex RI−101)により、各画分のグァーガム濃度を測定した。測定試料のグァーガム濃度は0.01%(w/v)とし、ポアサイズ0.45μmのメンブランフィルターでろ過した後、測定に供した。各画分において、散乱強度と散乱角の関係をZimm Plotし、重量平均分子量を算出した。 Note 5) The weight average molecular weight of guar gum was determined by a multi-angle light scattering method (SEC-MALLS) coupled with size exclusion chromatography. Specifically, OHpak SB-806M HQ with an exclusion volume of 20 million Da was used as the column for size exclusion chromatography, 0.05M sodium nitrate / 0.02% sodium azide was used as the mobile phase, and the flow rate was 0.5 mL. Fractionation was performed at / min. Next, the scattering intensity (scattering angle: 26 to 132 degrees) of the fractionated sample was measured at a temperature of 25 ° C. and a wavelength of 633 nm with a static light scattering measurement device DAWN-DSP. Moreover, the guar gum density | concentration of each fraction was measured with RI detector (Shodex RI-101). The guar gum concentration of the measurement sample was set to 0.01% (w / v), filtered through a membrane filter having a pore size of 0.45 μm, and then subjected to measurement. In each fraction, the relationship between the scattering intensity and the scattering angle was Zimmmlotted, and the weight average molecular weight was calculated.

実験例2 ゲル状食品の調製1
実験例1の各ゲル化剤(顆粒品)(実施例1〜3、及び比較例1〜5)を用いてゲル状食品を調製し、食感及び物性を検討した。詳細には、60℃に調整したイオン交換水を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、各ゲル化剤(実施例1〜3、及び比較例1〜5)を2.5g添加した。ただし、キサンタンガム及びローカストビーンガムを含有した市販品である比較例6のゲル化剤は、実施例1〜3と同程度のゲル強度を示すゲル状食品とするため、その添加量を1.2gとした。スパーテルで30秒間撹拌(約4回転/秒)した後、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、20℃で2時間冷却してゲル状食品(実施例1−a〜3−a、及び比較例1−a〜6−a)を調製した。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。
Experimental Example 2 Preparation of gelled food 1
Gelled foods were prepared using each gelling agent (granular product) (Examples 1 to 3 and Comparative Examples 1 to 5) of Experimental Example 1, and the texture and physical properties were examined. Specifically, 100 ml of ion exchange water adjusted to 60 ° C. was weighed into a 200 ml beaker, and 2.5 g of each gelling agent (Examples 1 to 3 and Comparative Examples 1 to 5) was added while stirring with a spatula. . However, the gelling agent of Comparative Example 6, which is a commercial product containing xanthan gum and locust bean gum, is a gel-like food having the same degree of gel strength as in Examples 1 to 3, so the amount added is 1.2 g. It was. After stirring for 30 seconds with a spatula (about 4 rotations / second), the container (pudding cup, diameter of about 6 cm, height of about 4 cm, capacity of 90 ml) is filled and cooled at 20 ° C. for 2 hours to form a gel food (Example) 1-a to 3-a and Comparative Examples 1-a to 6-a) were prepared. 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare. Performed at 5 mm.

結果を表2に示す。各項目の評価基準は以下の通りである。
1)かたさ(ゲル強度の実測値)
2)食塊形成性(5:非常に良い、4:良い、3:やや良い、2:やや悪い、1:悪い)
3)付着性(5:非常に良い(付着性が非常に小さい)、4:良い(小さい)、3:やや良い(やや小さい)、2:やや悪い(やや大きい)、1:悪い(大きい))
4)保水性(5:離水が非常に少ない、4:少ない、3:やや少ない、2:やや多い、1:多い)
5)ダマの発生(5:非常に少ない、4:少ない、3:やや少ない、2:やや多い、1:多い)
6)溶解性(5:非常に良い、4:良い、3:やや良い、2:やや悪い、1:悪い)
The results are shown in Table 2. The evaluation criteria for each item are as follows.
1) Hardness (measured value of gel strength)
2) Bolus formation (5: very good, 4: good, 3: slightly good, 2: slightly bad, 1: bad)
3) Adhesion (5: very good (adhesion is very small), 4: good (small), 3: slightly good (somewhat small), 2: slightly bad (somewhat large), 1: bad (large) )
4) Water retention (5: very little water separation, 4: low, 3: slightly low, 2: slightly high, 1: high)
5) Occurrence of lumps (5: very low, 4: low, 3: low, 2: low, 1: high)
6) Solubility (5: very good, 4: good, 3: slightly good, 2: slightly bad, 1: bad)

Figure 2012157370
Figure 2012157370

実施例1のゲル化剤(易溶性寒天及びグァーガム:重量平均分子量約2×10g/molを含有)を用いて調製したゲル状食品(実施例1−a)は、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。易溶性寒天、重量平均分子量が約2.0×10g/molのグァーガムに加え、キサンタンガムを含有した実施例2のゲル化剤を用いて調製したゲル状食品(実施例2−a)は、実施例1−aと同様の食感、物性であったが、実施例1−aよりも粘弾性があり、更に食塊形成性に優れていた。一方、易溶性寒天、重量平均分子量が約2.0×10g/molのグァーガムに加え、ネイティブ型ジェランガムを含有した実施例3のゲル化剤を用いて調製したゲル状食品(実施例3−a)は、実施例1−aと同様の食感、物性であったが、実施例1−aよりもわずかに付着性が強かった。しかし、全体としては咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、実施例1−aより高温でゲルが形成されるため、ゲル調製に要する時間を短縮することができた。なお、実施例1−a〜3−aのいずれのゲル状食品も、かたさ(ゲル強度)は、「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準(上記「高齢者用食品」の測定法による測定値が10,000N/m以下)を満足した。 The gelled food (Example 1-a) prepared using the gelling agent of Example 1 (easily soluble agar and guar gum: containing a weight average molecular weight of about 2 × 10 6 g / mol) has an appropriate hardness and bolus. It has formability, low adhesion, and little water separation, and has a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing. Gel food (Example 2-a) prepared using the gelling agent of Example 2 containing xanthan gum in addition to easily soluble agar and guar gum having a weight average molecular weight of about 2.0 × 10 6 g / mol. The texture and physical properties were the same as those of Example 1-a, but they were more viscoelastic than Example 1-a and more excellent in the formation of bolus. On the other hand, a gel food prepared using the gelling agent of Example 3 containing native gellan gum in addition to easily soluble agar and a guar gum having a weight average molecular weight of about 2.0 × 10 6 g / mol (Example 3) -A) had the same texture and physical properties as Example 1-a, but was slightly more adherent than Example 1-a. However, as a whole, the texture and physical properties were suitable for eating by persons with difficulty in chewing and swallowing. Moreover, since the gel was formed at a higher temperature than Example 1-a, the time required for gel preparation could be shortened. In any of the gel foods of Examples 1-a to 3-a, the hardness (gel strength) is determined according to the standard of “Food for people with difficulty in swallowing” in “Food for the elderly” The value measured by the measuring method of “food for consumers” was 10,000 N / m 2 or less).

一方、通常の寒天を用いて調製した比較例1のゲル化剤(通常の寒天及びグァーガム:重量平均分子量約2.0×10g/molを含有)は、60℃では溶解せず、ゲルを形成せず、咀嚼・嚥下困難者用ゲル状食品自体を調製することができなかった(比較例1−a)。また、易溶性寒天を用いたものの、重量平均分子量が約0.5×10g/molである、低分子量のグァーガムを含有した比較例2のゲル化剤を用いて調製したゲル状食品(比較例2−a)は、凝集物を含む、不均一で弱いゲルであり、離水も多く、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。更には、比較例3のゲル化剤(易溶性寒天及びグァーガム:重量平均分子量約2.0×10g/molを含有)を用いて調製したゲル状食品(比較例3−a)は、易溶性寒天及び重量平均分子量が1.5×10g/molであるグァーガムを用いたものの、グァーガムの添加量が寒天に対して60質量%より少なく、もろい食感で、食塊形成性が悪く、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。更には、比較例3−aのゲル状食品のかたさ(ゲル強度)は、「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足しなかった。同様にして、易溶性寒天及び重量平均分子量が1.5×10g/molであるグァーガムを用いたものの、グァーガムの添加量が寒天に対して700質量%より多い比較例4のゲル化剤を用いて調製したゲル状食品(比較例4−a)は、付着性が大きく、重い食感であり、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。 On the other hand, the gelling agent of Comparative Example 1 prepared using ordinary agar (ordinary agar and guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol) does not dissolve at 60 ° C. It was not possible to prepare a gel-like food product for persons with difficulty in chewing / swallowing (Comparative Example 1-a). In addition, a gel-like food prepared using the gelling agent of Comparative Example 2 containing a low molecular weight guar gum having a weight average molecular weight of about 0.5 × 10 6 g / mol, although using readily soluble agar ( Comparative Example 2-a) was a non-uniform and weak gel containing aggregates, had a lot of water separation, and had a texture and physical properties that were not suitable for eating by persons with difficulty in chewing / swallowing. Furthermore, the gel food (Comparative Example 3-a) prepared using the gelling agent of Comparative Example 3 (easily soluble agar and guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol) Although easily soluble agar and guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol were used, the addition amount of guar gum was less than 60% by mass with respect to agar, and it had a brittle texture and formed a bolus. The texture and physical properties were unsuitable for eating by those who had difficulty chewing or swallowing. Further, the hardness (gel strength) of the gel food of Comparative Example 3-a did not satisfy the standard of “Food for people with difficulty in swallowing” of “Food for the elderly”. Similarly, although the easily soluble agar and the guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol were used, the amount of the guar gum added was more than 700% by mass with respect to the agar. The gel-like food (Comparative Example 4-a) prepared by using a large stickiness, heavy texture, and texture and physical properties that are not suitable for eating by persons with difficulty in chewing / swallowing.

一方、嚥下・介護食の基材として従来から用いられてきたゼラチンを含有した比較例5のゲル化剤を用いて調製したゲル状食品(比較例5−a)は、20℃、2時間の冷却では十分にゲルを形成せず、かたさの測定で明確な破断点がみられず、ゲルを形成させるためには更に低温(例えば5℃)で長時間(例えば、24時間)の静置が必要であった。同様にして、キサンタンガムとローカストビーンガムを含有する、従来の市販の介護食用ゲル化剤である比較例6のゲル化剤を用いて調製したゲル状食品(比較例6−a)は、60℃で完全に溶解せず、溶け残りを生じ、付着性が大きく、離水もみられ、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。   On the other hand, a gel-like food (Comparative Example 5-a) prepared using the gelling agent of Comparative Example 5 containing gelatin that has been conventionally used as a base material for swallowing and nursing foods is 20 ° C. for 2 hours. Cooling does not form a gel sufficiently, and there is no clear break point in the hardness measurement. To form a gel, it is necessary to stand still for a long time (for example, 24 hours) at a lower temperature (for example, 5 ° C.). It was necessary. Similarly, the gelatinous food (Comparative Example 6-a) prepared using the gelling agent of Comparative Example 6 which is a conventional commercially available nursing food gelling agent containing xanthan gum and locust bean gum is 60 ° C. However, it did not dissolve completely, resulting in undissolved residue, high adhesion, water separation, and a texture and physical properties that were not suitable for eating by persons with difficulty in chewing / swallowing.

以上より、50〜60℃といったゲル化剤の溶解温度としては比較的低温の液状食品に良好に分散、溶解し、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ない、咀嚼・嚥下困難者用の喫食に適したゲル状食品を調製するためには、易溶性寒天(50℃における溶解率が60〜100%)及び重量平均分子量が1.5×10g/mol以上のグァーガムの併用が必須であることが分かった。上記易溶性寒天及び特定分子量のグァーガムに加え、更にキサンタンガムを添加することにより、食塊形成性及び温度安定性(再加温したときの食感及び物性の変化を抑制する作用:後記実験例8)を改善することができ、また、ネイティブ型ジェランガムを添加することにより、ゲル状食品がゲル形成に要する時間を短縮することが可能となった。ただし、上記易溶性寒天と特定分子量のグァーガムを用いた場合であっても、易溶性寒天が過剰になるとゲル状食品の食感が脆くなり、食塊形成性が低下してしまった。また、グァーガムが過剰になった場合も、調製されたゲル状食品は食感が重く、付着性が大きくなり、いずれも咀嚼・嚥下困難者の喫食には適さないゲル状食品となってしまった。一方、50℃における溶解率が60%未満の通常の寒天をゲル化剤として用いた場合は、重量平均分子量が1.5×10g/mol以上のグァーガムと併用した場合であっても、60℃程度の溶解ではゲルの形成が不十分となってしまった。また、易溶性寒天とグァーガムを用いた場合であっても、グァーガムの重量平均分子量が1.5×10g/mol未満のグァーガムを用いた場合は、均一なゲルとならず、いずれも本発明のゲル化剤の基材として適さなかった。 As described above, the dissolution temperature of the gelling agent such as 50 to 60 ° C. is well dispersed and dissolved in a relatively low temperature liquid food, has an appropriate hardness and a bolus forming property, has low adhesion, and has little water separation. In order to prepare a gel-like food suitable for eating for persons with difficulty in chewing / swallowing, a readily soluble agar (dissolution rate at 50 ° C. is 60 to 100%) and a weight average molecular weight of 1.5 × 10 6 g / It turned out that the combined use of more than mol guar gum is essential. In addition to the above-mentioned easily soluble agar and guar gum having a specific molecular weight, addition of xanthan gum further improves the food mass formation and temperature stability (action of suppressing changes in texture and physical properties when reheated: Experimental Example 8 described later) In addition, by adding native gellan gum, it was possible to shorten the time required for the gel food to form a gel. However, even when the above-mentioned easily soluble agar and guar gum having a specific molecular weight were used, when the easily soluble agar was excessive, the texture of the gel food became brittle, and the formation of the bolus was reduced. In addition, when the guar gum is excessive, the prepared gel food has a heavy texture and increased adhesion, and both of them become gel food that is not suitable for eating by those who have difficulty chewing or swallowing. . On the other hand, when ordinary agar having a dissolution rate at 50 ° C. of less than 60% is used as a gelling agent, even when used in combination with guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more, Melting at about 60 ° C. resulted in insufficient gel formation. Moreover, even when easily soluble agar and guar gum are used, when guar gum having a weight average molecular weight of less than 1.5 × 10 6 g / mol is used, a uniform gel is not formed. It was not suitable as a base material for the gelling agent of the invention.

また、現在、嚥下・介護食の基材としてゼラチンが汎用されているが、ゼラチンを用いて咀嚼・嚥下困難者用ゲル状食品を調製する場合は、ゲルを形成させるために長時間(例えば24時間)の冷蔵保存(静置)が必要である。また、市販の介護食用ゲル化剤はキサンタンガムとローカストビーンガムを主剤とする場合が多いが、ゲルの調製には80〜90℃以上の高温加熱が必要である。しかし、咀嚼・嚥下困難者に供する食品を調製するためのゲル化剤は、設備の整った調理施設だけでなく、患者やその介護者がベットサイドや家庭の台所で用いることがある。従って、60℃程度の温度で溶解し、室温でゲルを調製できる本発明のゲル化剤は、咀嚼・嚥下困難者のQOLの向上に貢献するだけでなく、食事を調製する介護者にとっての利便性にも優れる。   At present, gelatin is widely used as a base material for swallowing and nursing foods, but when a gelatinous food for persons with difficulty in chewing or swallowing is prepared using gelatin, it takes a long time (for example, 24 hours) to form a gel. Refrigerated storage (stationary) is required. In addition, commercially available nursing food gelling agents often contain xanthan gum and locust bean gum as main ingredients, but high-temperature heating at 80 to 90 ° C. or higher is required for gel preparation. However, gelling agents for preparing foods for those who have difficulty chewing or swallowing are sometimes used not only in well-equipped cooking facilities, but also by patients and their caregivers at the bedside or in the home kitchen. Therefore, the gelling agent of the present invention which can be dissolved at a temperature of about 60 ° C. and can prepare a gel at room temperature not only contributes to the improvement of QOL of those with difficulty in chewing / swallowing, but is also convenient for caregivers who prepare meals. Excellent in properties.

実験例3 ゲル状食品の調製2
溶解温度がゲル状食品の食感及び物性に及ぼす影響について検討するため、実験例1の各ゲル化剤(顆粒品)(実施例1及び比較例1、2、6)を用いてゲル状食品を調製した。詳細には、60℃あるいは80℃に調整したイオン交換水を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、実験例1で調製した各ゲル化剤(実施例1及び比較例1、2)を2.5gずつ添加した。ただし、比較例6のゲル化剤のみ添加量は1.2gとした。スパーテルで30秒間撹拌(約4回転/秒)したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、20℃で2時間冷却し、ゲル状食品(実施例1−b〜c及び比較例1−b〜c、比較例2−b〜c、及び比較例6−b〜c)を調製した。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表3に示す。各項目の評価基準は実験例2に準じた。
Experimental Example 3 Preparation of gel food 2
In order to examine the influence of the dissolution temperature on the texture and physical properties of the gel food, the gel food using each gelling agent (granular product) of Example 1 (Example 1 and Comparative Examples 1, 2 and 6). Was prepared. Specifically, 100 ml of ion-exchanged water adjusted to 60 ° C. or 80 ° C. was weighed into a 200 ml beaker and stirred with a spatula, and each gelling agent prepared in Experimental Example 1 (Example 1 and Comparative Examples 1 and 2). Of 2.5 g was added. However, only the gelling agent of Comparative Example 6 was added in an amount of 1.2 g. After stirring for 30 seconds with a spatula (about 4 revolutions / second), the container (pudding cup, diameter about 6 cm, height about 4 cm, capacity 90 ml) is filled, cooled at 20 ° C. for 2 hours, and gelled food (Example) 1-b-c and Comparative Examples 1-b-c, Comparative Examples 2-b-c, and Comparative Examples 6-b-c) were prepared. 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 3. The evaluation criteria for each item were in accordance with Experimental Example 2.

Figure 2012157370
Figure 2012157370

実施例1のゲル化剤(易溶性寒天及びグァーガム:重量平均分子量約2.0×10g/molを含有)を用いて調製したゲル状食品(実施例1−b及び1−c)は、溶解温度によらず、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、かたさ(ゲル強度)は溶解温度の影響を受けにくく、いずれの溶解温度でも「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足した。 Gelled foods (Examples 1-b and 1-c) prepared using the gelling agent of Example 1 (easily soluble agar and guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol) Regardless of the dissolution temperature, it has moderate hardness and food mass formation, has low adhesion, and has little water separation, and has a texture and physical properties suitable for eating by those who have difficulty chewing or swallowing. Hardness (gel strength) is not easily affected by the dissolution temperature, and at any dissolution temperature, it satisfies the standard of “Food for the elderly and those who have difficulty swallowing”.

一方、比較例1のゲル化剤(通常の寒天及びグァーガム:重量平均分子量約2.0×10g/molを含有)は、60℃溶解ではゲルを形成せず(比較例1−b)、80℃溶解では弱いゲル(ゲル強度が測定できる程度の明確な破断点をもたない)を形成した(比較例1−c)が、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。比較例2のゲル化剤(易溶性寒天及び低分子グァーガム:重量平均分子量約0.5×10g/molを含有)を用いて調製したゲル状食品(比較例2−b、c)は、60℃、80℃のいずれの溶解温度でも、凝集物を含む、不均一で弱いゲルであり、離水も多く、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。一方、キサンタンガム及びローカストビーンガムを含有する市販の介護食用ゲル化剤(比較例6)を用いて調製されたゲル状食品は、80℃で溶解して調製することにより、若干かたいものの、適度な食塊形成性を有し、付着性が小さく、離水の少ないゲル状食品を調製できた(比較例6−c)。しかし、60℃の溶解温度では、ゲル化剤が完全に溶解せず、溶け残りを生じてしまい、また調製されたゲル状食品(比較例6−b)は付着性が大きく、離水もみられ、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。このように、比較例6のゲル化剤を用いた場合は、溶解温度が変化することによって調製されるゲル状食品の物性や食感が大きく変化してしまい、溶解温度に関わらず一定して咀嚼・嚥下困難者の喫食に適したゲル状食品を提供することができなかった。 On the other hand, the gelling agent of Comparative Example 1 (ordinary agar and guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol) does not form a gel when dissolved at 60 ° C. (Comparative Example 1-b) In the case of melting at 80 ° C., a weak gel (without a clear breaking point at which gel strength can be measured) was formed (Comparative Example 1-c). It was a physical property. Gel foods (Comparative Examples 2-b and c) prepared using the gelling agent of Comparative Example 2 (easily soluble agar and low-molecular guar gum: containing a weight average molecular weight of about 0.5 × 10 6 g / mol) At any dissolution temperature of 60 ° C. and 80 ° C., the gel was a non-uniform and weak gel containing aggregates, had a lot of water separation, and had a texture and physical properties that were not suitable for eating by persons with difficulty in chewing / swallowing. On the other hand, a gel food prepared using a commercially available nursing food gelling agent (Comparative Example 6) containing xanthan gum and locust bean gum is slightly hard by dissolving at 80 ° C. A gel-like food product having a good bolus forming property, low adhesion, and little water separation could be prepared (Comparative Example 6-c). However, at a melting temperature of 60 ° C., the gelling agent is not completely dissolved, resulting in undissolved residue, and the prepared gel food (Comparative Example 6-b) has high adhesion and water separation is also observed. The texture and physical properties were not suitable for eating by those with difficulty in chewing or swallowing. Thus, when the gelling agent of Comparative Example 6 is used, the physical properties and texture of the gelled food prepared by changing the dissolution temperature are greatly changed, and are constant regardless of the dissolution temperature. A gel-like food suitable for eating by those who have difficulty chewing or swallowing could not be provided.

一方、易溶性寒天と、重量平均分子量が1.5×10g/mol以上のグァーガムを
特定割合にて含有した本発明のゲル化剤は、60℃以上の加熱温度が確保されていれば、
溶解温度によらず咀嚼・嚥下困難者の喫食に適した食感と物性を有するゲル状食品を調製
することができ、更に溶解温度によってゲル状食品の食感や物性がほとんど変化しない。
従って、咀嚼・嚥下困難者が摂食しやすいというだけでなく、食事を調製する介護者にと
っての利便性にも優れる。
On the other hand, the gelling agent of the present invention containing a readily soluble agar and a guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more in a specific ratio, as long as a heating temperature of 60 ° C. or more is secured. ,
A gel-like food having a texture and physical properties suitable for eating by persons with difficulty in chewing and swallowing can be prepared regardless of the dissolution temperature, and the texture and physical properties of the gel-like food hardly change depending on the dissolution temperature.
Therefore, it is not only easy for a person with difficulty in chewing / swallowing but also convenience for a caregiver who prepares a meal.

実験例4 ゲル状食品の調製3
液状食品の違いによるゲル状食品の食感、物性の変化から、ゲル化剤の汎用性を評価した。実験例1のゲル化剤(顆粒品)(実施例1、比較例3、6)を用いてゲル状食品を調製した。詳細には、80℃に調整した液状食品(イオン交換水、牛乳、味噌汁)を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、実験例1で調製した各ゲル化剤(実施例1、比較例3)を2.5gずつ添加した。ただし、比較例6のみ添加量は1.2gとした。スパーテルで30秒間撹拌(約4回転/秒)したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、5℃で2時間冷却し、ゲル状食品を調製した(実施例1−d〜f、及び比較例3−d〜f、比較例6−d〜f)。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表4に示す。各項目の評価基準は実験例2に準じた。
Experimental Example 4 Preparation of gel food 3
The versatility of the gelling agent was evaluated from the change in the texture and physical properties of the gel food due to the difference in the liquid food. A gelled food was prepared using the gelling agent (granular product) of Example 1 (Example 1, Comparative Examples 3 and 6). Specifically, 100 ml of liquid food (ion-exchanged water, milk, miso soup) adjusted to 80 ° C. was weighed in a 200 ml beaker and stirred with a spatula to prepare each gelling agent prepared in Experimental Example 1 (Example 1, comparison). Example 3) was added in 2.5 g portions. However, only the comparative example 6 added amount was 1.2g. After stirring for 30 seconds with a spatula (about 4 revolutions / second), the container (pudding cup, diameter about 6 cm, height about 4 cm, capacity 90 ml) was filled and cooled at 5 ° C. for 2 hours to prepare a gel food. (Examples 1-df and Comparative Examples 3-df, Comparative Examples 6-df). 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 4. The evaluation criteria for each item were in accordance with Experimental Example 2.

Figure 2012157370
Figure 2012157370

実施例1のゲル化剤(易溶性寒天及びグァーガム:重量平均分子量約2.0×10g/molを含有)を用いて調製したゲル状食品は、イオン交換水(実施例1−d)、牛乳(実施例1−e)、及び味噌汁(実施例1−f)等、ゲル化の対象とする液状食品によらず、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、かたさ(ゲル強度)は液状食品の違いによってほとんど変化せず、いずれの液状食品でも「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足した。 Gelled food prepared using the gelling agent of Example 1 (easily soluble agar and guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol) is ion-exchanged water (Example 1-d). , Milk (Example 1-e), miso soup (Example 1-f), etc., liquid foods to be gelled, have moderate hardness and bolus formation, low adhesion, The water release was low, and the texture and physical properties were suitable for eating by people with difficulty in chewing or swallowing. Hardness (gel strength) hardly changed depending on the difference in liquid foods, and all liquid foods satisfied the standards for “food for the elderly and those with difficulty in swallowing” of “food for the elderly”.

一方、易溶性寒天及び重量平均分子量が1.5×10g/molを含有した場合であっても、易溶性寒天に対するグァーガムの添加量が60質量%より少ない比較例3のゲル化剤を用いて調製したゲル状食品は、イオン交換水(比較例3−d)、牛乳(比較例3−e)、味噌汁(比較例3−f)のいずれの液状食品に用いた場合であっても、もろい食感で、食塊形成性が悪く、咀嚼・嚥下困難者の喫食には適さない食感と物性であった。また、かたさ(ゲル強度)は、「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足せず、ゲル化の対象とする液状食品によってゲル状食品のかたさは大きく変化した。一方、市販の介護食用ゲル化剤(比較例6、キサンタンガムとローカストビーンガムを含有)は、イオン交換水に溶解した場合(比較例6−d)は、若干かたいものの、適度な食塊形成性を有し、付着性が小さく、離水の少ないゲルであり、咀嚼・嚥下困難者の喫食に適した食感と物性となり、またそのかたさ(ゲル強度)も「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足したが、牛乳や味噌汁といった脂肪やミネラルを含有する液状食品に用いた場合は、咀嚼・嚥下困難者用ゲル状食品として適切な物性を付与することができなかった。詳細には、牛乳(比較例6−e)に溶解した場合は凝集物が形成され、不均一で弱いゲルとなり、また、味噌汁(比較例6−f)に溶解したときには完全に溶解せず、不均一なゲルとなり、いずれも咀嚼・嚥下困難者の喫食には適さない食感と物性であった。 On the other hand, even when the readily soluble agar and the weight average molecular weight contained 1.5 × 10 6 g / mol, the gelling agent of Comparative Example 3 in which the addition amount of guar gum to the easily soluble agar was less than 60% by mass was used. The gel food prepared by use may be any liquid food such as ion-exchanged water (Comparative Example 3-d), milk (Comparative Example 3-e), and miso soup (Comparative Example 3-f). It had a fragile texture, poor mass formation, and a texture and physical properties that were not suitable for eating by persons with difficulty in chewing / swallowing. In addition, the hardness (gel strength) does not satisfy the standard of “food for elderly people” and “food for people with difficulty in swallowing”, and the hardness of the gel food is large depending on the liquid food to be gelled. changed. On the other hand, when a commercially available nursing food gelling agent (Comparative Example 6, containing xanthan gum and locust bean gum) is dissolved in ion-exchanged water (Comparative Example 6-d), it is a little hard, but moderate bolus formation It is a gel with low adhesiveness, low water release, and has a texture and physical properties suitable for eating by people with difficulty in chewing / swallowing.・ Satisfied with the standards of “food for people with difficulty swallowing”, but when used in liquid foods containing fats and minerals such as milk and miso soup, it gives appropriate physical properties as a gel food for people with difficulty in chewing and swallowing I couldn't. Specifically, aggregates are formed when dissolved in milk (Comparative Example 6-e), resulting in a non-uniform and weak gel, and not completely dissolved when dissolved in miso soup (Comparative Example 6-f), The gels were non-uniform, and both had a texture and physical properties that were not suitable for eating by those who had difficulty chewing or swallowing.

一方、本発明のゲル化剤は、ゲル化の対象とする液状食品によらず、安定して咀嚼・嚥下困難者の喫食に適した食感と物性を有するゲル状食品を調製することができる。つまり、ゲル化の対象とする液状食品の種類を選ばないため汎用性が高く、食事を調製する介護者にとっての利便性に優れる。   On the other hand, the gelling agent of the present invention can stably prepare a gel-like food having a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing, regardless of the liquid food to be gelled. . In other words, since the type of liquid food to be gelled is not selected, the versatility is high, and the convenience for caregivers preparing meals is excellent.

実験例5 ゲル状食品の調製4
液状食品の違いによるゲル状食品の食感、物性の変化からゲル化剤の汎用性を検討した。実験例1のゲル化剤(顆粒品)(実施例2)を用いてゲル状食品を調製した。詳細には、80℃に調整した液状食品(イオン交換水、緑茶、牛乳、味噌汁、オレンジジュース)を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、実験例1で調製したゲル化剤(実施例2)を2.5gずつ添加した。スパーテルで30秒間撹拌(約4回転/秒)したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、5℃で2時間冷却し、ゲル状食品を調製した(実施例2−b〜f)。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表5に示す。各項目の評価基準は実験例2に準じた。
Experimental Example 5 Preparation of gel food 4
We examined the versatility of gelling agents based on changes in the texture and physical properties of gel foods due to differences in liquid foods. A gelled food was prepared using the gelling agent (granular product) of Example 1 (Example 2). Specifically, 100 ml of liquid food (ion-exchanged water, green tea, milk, miso soup, orange juice) adjusted to 80 ° C. was weighed in a 200 ml beaker and stirred with a spatula to prepare the gelling agent prepared in Experimental Example 1 Example 2) was added in 2.5 g portions. After stirring for 30 seconds with a spatula (about 4 revolutions / second), the container (pudding cup, diameter about 6 cm, height about 4 cm, capacity 90 ml) was filled and cooled at 5 ° C. for 2 hours to prepare a gel food. (Examples 2-b to f). 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 5. The evaluation criteria for each item were in accordance with Experimental Example 2.

Figure 2012157370
Figure 2012157370

実施例2のゲル化剤(易溶性寒天、グァーガム:重量平均分子量約2.0×10g/mol、及びキサンタンガムを含有)を用いて調製したゲル状食品は、ゲル化の対象とする液状食品(イオン交換水(実施例2−b)、緑茶(実施例2−c)、牛乳(実施例2−d)、味噌汁(実施例2−e)、オレンジジュース(実施例2−f)によらず、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、かたさ(ゲル強度)は液状食品の違いによってほとんど変化せず、いずれの液状食品でも「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足した。 The gel food prepared using the gelling agent of Example 2 (easily soluble agar, guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol and xanthan gum) is a liquid to be gelled. Food (ion-exchanged water (Example 2-b), green tea (Example 2-c), milk (Example 2-d), miso soup (Example 2-e), orange juice (Example 2-f) Regardless, it has moderate hardness and bolus formation, low adhesion, and little water separation, and has a texture and physical properties suitable for eating by those who have difficulty chewing or swallowing. (Strength) hardly changed depending on the difference in liquid foods, and all liquid foods satisfied the standard of “Food for people with difficulty in swallowing” in “Food for the elderly”.

本発明のゲル化剤は、ゲル化の対象とする液状食品によらず、安定して咀嚼・嚥下困難者の喫食に適した食感と物性を付与することができる。つまり、ゲル化の対象とする液状食品の種類を選ばないため汎用性が高く、食事を調製する介護者にとっての利便性に優れることが示された。   The gelling agent of the present invention can stably give a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing, regardless of the liquid food to be gelled. That is, since the kind of liquid food to be gelled is not selected, the versatility is high, and it is shown that the liquid food is excellent in convenience for a caregiver who prepares a meal.

実験例6 ゲル状食品の調製5(濃厚流動食)
本発明のゲル化剤について、濃厚流動食への適用性を検討した。実験例1のゲル化剤(顆粒品)(実施例2)を用いてゲル状の濃厚流動食を調製した。詳細には、60℃に調整した市販の濃厚流動食A(1.6kcal/mL、タンパク質含量1.6g/100mL、脂肪含量4.5g/100mL、ミネラル含有量180mg/100mL)濃厚流動食B(1kcal/mL、タンパク質含量4.0g/100mL、脂肪含量2.8g/100mL、ミネラル含有量410mg/100mL)を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、実験例1で調製したゲル化剤(実施例2)を2.5gずつ添加した。スパーテルで30秒間撹拌(約4回転/秒)したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、5℃で2時間冷却し、ゲル状の濃厚流動食品を調製した(実施例2−g〜h)。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表6に示す。各項目の評価基準は実験例2に準じた。
Experimental Example 6 Preparation of gelled food 5 (concentrated liquid food)
About the gelatinizer of this invention, the applicability to a thick liquid food was examined. A gel-like concentrated liquid food was prepared using the gelling agent (granular product) of Example 1 (Example 2). Specifically, commercially available concentrated liquid food A adjusted to 60 ° C. (1.6 kcal / mL, protein content 1.6 g / 100 mL, fat content 4.5 g / 100 mL, mineral content 180 mg / 100 mL) concentrated liquid food B ( 1 kcal / mL, protein content 4.0 g / 100 mL, fat content 2.8 g / 100 mL, mineral content 410 mg / 100 mL) was weighed 100 ml in a 200 ml beaker and stirred with a spatula, and the gelling agent prepared in Experimental Example 1 (Example 2) was added in an amount of 2.5 g. After stirring for 30 seconds with a spatula (approx. 4 revolutions / second), the container (purine cup, diameter 6 cm, height 4 cm, capacity 90 ml) is filled and cooled at 5 ° C. for 2 hours to give a gel-like concentrated liquid food (Example 2-g to h). 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 6. The evaluation criteria for each item were in accordance with Experimental Example 2.

Figure 2012157370
Figure 2012157370

実施例2のゲル化剤(易溶性寒天、グァーガム:重量平均分子量約2.0×10g/mol、及びキサンタンガムを含有)を用いて調製したゲル状の濃厚流動食(実施例2−g、h)は、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、かたさ(ゲル強度)は濃厚流動食の種類によってほとんど変化せず、いずれの濃厚流動食でも「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足した。 Gel-like concentrated liquid food prepared using the gelling agent of Example 2 (easily soluble agar, guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol and xanthan gum) (Example 2-g H) has a moderate hardness and a bolus-forming property, has low adhesion, and has little water separation, and has a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing. Also, the hardness (gel strength) hardly changed depending on the type of concentrated liquid food, and any of the concentrated liquid foods satisfied the standard of “Food for the elderly and those with difficulty in swallowing”.

本発明のゲル化剤は、ゲル化が困難とされている濃厚流動食においても、安定して咀嚼・嚥下困難者の喫食に適した食感と物性を付与することができる。   The gelling agent of the present invention can stably provide a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing even in a concentrated liquid food that is difficult to gel.

実験例7 ゲル状食品の調製6(濃厚流動食)
本発明のゲル化剤について、濃厚流動食への適用性を検討した。実験例1のゲル化剤(顆粒品)(実施例2)を用いてゲル状の濃厚流動食を調製した。詳細には、80℃に調整したイオン交換水50mlを200mlビーカーに量り取り、プロペラ攪拌機を用いて1000rpmで攪拌しながら実験例1で調製したゲル化剤(実施例2)を2.5g添加した。このゲル化剤溶液に、市販の濃厚流動食C(2kcal/ml、タンパク質含量7.2g/100ml、脂肪含量7.5g/100ml、ミネラル含有量380mg/100ml)、濃厚流動食D(2kcal/ml、タンパク質含量8.0g/100ml、脂肪含量7.5g/100ml、ミネラル含有量230mg/100ml)、あるいは濃厚流動食E(2kcal/ml、タンパク質含量7.3g/100ml、脂肪含量5.6g/100ml、ミネラル含有量410mg/100ml)を80℃に調整した後、それぞれ50mL加え、プロペラ攪拌機を用いて1000rpmで3分間撹拌したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、5℃で2時間冷却してから、レトルト殺菌(121℃、20分間)してゲル状の濃厚流動食を調製した(実施例2−i〜k)。調製したゲル状食品について、1)かたさ(ゲル強度)を測定し、2)食塊形成性(口中での食品のまとまりやすさ)、3)口腔及び咽頭への付着性、及び4)保水性を評価した。また、ゲル化剤(顆粒品)を溶解した際の5)ダマの発生、6)溶解性について評価した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表7に示す。各項目の評価基準は実験例2に準じた。
Experimental Example 7 Preparation of gelled food 6 (concentrated liquid food)
About the gelatinizer of this invention, the applicability to a thick liquid food was examined. A gel-like concentrated liquid food was prepared using the gelling agent (granular product) of Example 1 (Example 2). Specifically, 50 ml of ion-exchanged water adjusted to 80 ° C. was weighed into a 200 ml beaker, and 2.5 g of the gelling agent prepared in Experimental Example 1 (Example 2) was added while stirring at 1000 rpm using a propeller stirrer. . In this gelling agent solution, commercially available concentrated liquid food C (2 kcal / ml, protein content 7.2 g / 100 ml, fat content 7.5 g / 100 ml, mineral content 380 mg / 100 ml), concentrated liquid food D (2 kcal / ml , Protein content 8.0 g / 100 ml, fat content 7.5 g / 100 ml, mineral content 230 mg / 100 ml), or concentrated liquid food E (2 kcal / ml, protein content 7.3 g / 100 ml, fat content 5.6 g / 100 ml) After adjusting the mineral content (410 mg / 100 ml) to 80 ° C., add 50 mL each and stir at 1000 rpm for 3 minutes using a propeller stirrer, then container (pudding cup, diameter 6 cm, height 4 cm, capacity 90 ml) And cooled at 5 ° C. for 2 hours, and then retort sterilized (121 , 20 min) and the gel-like concentrated liquid diet was prepared (Example 2-I to K). 1) Measure the hardness (gel strength) of the prepared gel-like food, 2) forming a bolus (easiness of collecting food in the mouth), 3) adhering to the oral cavity and pharynx, and 4) water retention Evaluated. Further, 5) generation of lumps when the gelling agent (granular product) was dissolved, and 6) solubility were evaluated. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 7. The evaluation criteria for each item were in accordance with Experimental Example 2.

Figure 2012157370
Figure 2012157370

実施例2のゲル化剤(易溶性寒天、グァーガム:重量平均分子量約2.0×10g/mol、及びキサンタンガムを含有)を用いて調製したゲル状の濃厚流動食(実施例2−i〜k)は、適度なかたさと食塊形成性を有し、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、かたさ(ゲル強度)は濃厚流動食の種類によってほとんど変化せず、いずれの濃厚流動食でも「高齢者用食品」の「そしゃく・えん下困難者用食品」の規格基準を満足した。 Gel-like concentrated liquid food prepared using the gelling agent of Example 2 (easily soluble agar, guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol and xanthan gum) (Example 2-i -K) had moderate hardness and food mass formation, low adhesion, and little water separation, and had a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing. Also, the hardness (gel strength) hardly changed depending on the type of concentrated liquid food, and any of the concentrated liquid foods satisfied the standard of “Food for the elderly and those with difficulty in swallowing”.

本発明のゲル化剤は、ゲル化が困難とされている濃厚流動食においても、安定して咀嚼・嚥下困難者の喫食に適した食感と物性を付与することができる。また、本発明のゲル化剤を使用したゲル状の濃厚流動食においては、通常、濃厚流動食をレトルト殺菌する際に生じる、タンパク質の凝集に起因するあれがみられず、外観上の嗜好性も高い。   The gelling agent of the present invention can stably provide a texture and physical properties suitable for eating by persons with difficulty in chewing / swallowing even in a concentrated liquid food that is difficult to gel. In addition, in the gel-like concentrated liquid food using the gelling agent of the present invention, there is usually no appearance due to protein aggregation, which occurs when the concentrated liquid food is sterilized by retort. Is also expensive.

実験例8 ゲル状食品の再加温
再加温がゲル状食品の食感及び物性に及ぼす影響について検討するため、実験例1で調製したゲル化剤(顆粒品)(実施例2及び比較例5、6)を用いてゲル状食品を調製した。詳細には、60℃に調整したイオン交換水を200mlビーカーに100ml量りとり、スパーテルで撹拌しながら、実験例1で調製したゲル化剤(実施例2及び比較例5)を2.5gずつ添加した。ただし、比較例6のみ添加量は1.2gとした。スパーテルで30秒間撹拌(約4回転/秒)したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に充填し、5℃で24時間冷却し、ゲル状食品を調製した(実施例2−l及び比較例5−b、比較例6−g)。調製したゲル状食品を60℃の恒温器中にて30分間加温し、再加温前後でかたさ(ゲル強度)を測定した。かたさ(ゲル強度)の測定は、厚生労働省特別用途食品「高齢者用食品」の測定法に準じ、テクスチャーアナライザーを用いて、プランジャー:直径20mmの円柱形、圧縮速度:10mm/秒、クリアランス:5mmで行った。結果を表8に示す。
Experimental Example 8 Reheating of Gelled Food In order to examine the effect of reheating on the texture and physical properties of gelled food, the gelling agent (granular product) prepared in Experimental Example 1 (Example 2 and Comparative Example) A gel food was prepared using 5, 6). Specifically, 100 ml of ion-exchanged water adjusted to 60 ° C. is weighed in a 200 ml beaker, and 2.5 g of the gelling agent prepared in Experimental Example 1 (Example 2 and Comparative Example 5) is added while stirring with a spatula. did. However, only the comparative example 6 added amount was 1.2g. After stirring for 30 seconds with a spatula (approximately 4 revolutions / second), the container (pudding cup, diameter 6 cm, height 4 cm, volume 90 ml) was filled and cooled at 5 ° C. for 24 hours to prepare a gel food. (Example 2-1 and Comparative Example 5-b, Comparative Example 6-g). The prepared gel-like food was heated in a 60 ° C. incubator for 30 minutes, and the hardness (gel strength) was measured before and after reheating. Hardness (gel strength) is measured using a texture analyzer according to the method for measuring foods for special use "food for the elderly" by the Ministry of Health, Labor and Welfare, plunger: 20 mm diameter cylinder, compression speed: 10 mm / second, clearance: Performed at 5 mm. The results are shown in Table 8.

Figure 2012157370
Figure 2012157370

実施例2のゲル化剤(易溶性寒天、グァーガム:重量平均分子量約2.0×10g/mol、及びキサンタンガムを含有)を用いて調製したゲル状食品(実施例2−l)は、再加温によってゲルが融解せず、咀嚼・嚥下困難の喫食に適した食感(適度なかたさと食塊形成性)を維持した。また、再加温によるかたさ(ゲル強度)の低下は約25%であり、優れた温度安定性を示した。 A gelled food (Example 2-1) prepared using the gelling agent of Example 2 (easily soluble agar, guar gum: containing a weight average molecular weight of about 2.0 × 10 6 g / mol and xanthan gum) The gel did not melt by reheating, and the texture (appropriate hardness and bolus formation) suitable for eating with difficulty in chewing and swallowing was maintained. The decrease in hardness (gel strength) due to reheating was about 25%, indicating excellent temperature stability.

一方、ゼラチンを含有する比較例5のゲル化剤を用いて調製したゲル状食品(比較例5−b)は、再加温によってゲルが融解し、液状となってしまった。また、キサンタンガムとローカストビーンガムを含有する市販の介護食用ゲル化剤(比較例6)を用いて調製したゲル状食品(比較例6−g)は、実施例2−lと同様に、再加温によってゲルは融解しなかったが、再加温によるかたさ(ゲル強度)の低下は約60%であり、実施例2−lに比べて温度安定性に劣っていた。   On the other hand, the gel food (Comparative Example 5-b) prepared using the gelling agent of Comparative Example 5 containing gelatin was melted by reheating and became liquid. Moreover, the gelatinous food (Comparative Example 6-g) prepared using the commercially available nursing food gelling agent (Comparative Example 6) containing xanthan gum and locust bean gum was re-added in the same manner as in Example 2-l. Although the gel did not melt due to the temperature, the decrease in hardness (gel strength) due to reheating was about 60%, which was inferior in temperature stability compared to Example 2-1.

本発明のゲル化剤を用いることにより、再加温による食感及び物性の変化が小さいゲル状食品を調製することができ、再加温しても咀嚼・嚥下困難者に適した食感と物性を維持することができる。本来温かい状態で喫食すべき食品を温かい状態のままで提供することができるため、咀嚼・嚥下困難者が摂食しやすい食品のバリエーション化とQOLの向上に貢献する。   By using the gelling agent of the present invention, it is possible to prepare a gel-like food with little change in texture and physical properties due to reheating, and a texture suitable for those who have difficulty chewing and swallowing even after reheating Physical properties can be maintained. Since foods that should be eaten in a warm state can be provided in a warm state, it contributes to the variation of foods that are difficult for mastication and swallowing people to eat and the improvement of QOL.

実験例9 ゲル状食品の調製7(緑茶ゼリー)
実験例1で調製したゲル化剤(実施例2)を緑茶パウダー及びL−アスコルビン酸ナトリウムと粉体混合して粉末ゼリーミックスを調製した。スパーテルで攪拌(約4回転/秒)しながら、60℃のお湯に上記粉末ゼリーミックスを添加した。更に30秒間撹拌したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に入れて充填し、5℃で2時間冷却して緑茶ゼリーを調製した。得られた緑茶ゼリーは、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、調製した際に、ダマ等を生じることがなく、食した際もざらつき等を感じることがなかった。
Experimental Example 9 Preparation of gelled food 7 (green tea jelly)
The gelling agent prepared in Experimental Example 1 (Example 2) was mixed with green tea powder and sodium L-ascorbate to prepare a powder jelly mix. While stirring with a spatula (about 4 rotations / second), the powder jelly mix was added to hot water at 60 ° C. The mixture was further stirred for 30 seconds, filled in a container (pudding cup, diameter of about 6 cm, height of about 4 cm, capacity of 90 ml), and cooled at 5 ° C. for 2 hours to prepare a green tea jelly. The obtained green tea jelly has low adhesiveness and low water separation, and has a texture and physical properties suitable for eating by those who have difficulty chewing or swallowing. Moreover, when it was prepared, no lumps or the like were produced, and no roughness or the like was felt when eating.

処方 部
実施例2のゲル化剤 1.80
緑茶パウダー(SD緑茶エキスパウダーNo.17141*) 0.18
L―アスコルビン酸ナトリウム 0.02
お湯(60℃)にて全量を100とする。
Gelling agent of prescription part example 2 1.80
Green tea powder (SD green tea extract powder No.17141 *) 0.18
L-sodium ascorbate 0.02
The total amount is 100 with hot water (60 ° C.).

実施例10 ゲル状食品の調製8(チョコレート風味プリン)
実施例1で調製したゲル化剤(実施例2)をグラニュー糖、乳タンパク濃縮物、粉末油脂、ココアパウダー、デキストリン及びチョコレート香料と粉体混合して粉末ゼリーミックスを調製した。スパーテルで攪拌(約4回転/秒)しながら、60℃の牛乳に上記粉末ゼリーミックスを添加した。更に30秒間撹拌したのち、容器(プリンカップ、直径約6cm、高さ約4cm、容量90ml)に入れて充填し、5℃で2時間冷却してチョコレート風味プリンを調製した。得られたチョコレート風味プリンは、付着性が小さく、更に離水の少ないものであり、咀嚼・嚥下困難者の喫食に適した食感と物性であった。また、調製した際に、ダマ等を生じることがなく、食した際もざらつき等を感じることがなかった。
Example 10 Preparation of gelled food 8 (chocolate flavored pudding)
The gelling agent (Example 2) prepared in Example 1 was powder-mixed with granulated sugar, milk protein concentrate, powdered oil and fat, cocoa powder, dextrin and chocolate flavor to prepare a powder jelly mix. While stirring with a spatula (about 4 rotations / second), the powder jelly mix was added to milk at 60 ° C. The mixture was further stirred for 30 seconds, filled in a container (pudding cup, diameter of about 6 cm, height of about 4 cm, capacity of 90 ml), and cooled at 5 ° C. for 2 hours to prepare a chocolate-flavored pudding. The obtained chocolate-flavored pudding has low adhesion and further water separation, and has a texture and physical properties suitable for eating by those who have difficulty chewing or swallowing. Moreover, when it was prepared, no lumps or the like were produced, and no roughness or the like was felt when eating.

処方 部
実施例2のゲル化剤 2.0
グラニュー糖 10.0
乳タンパク濃縮物(シンプレス100*) 5.7
粉末油脂(Nネオパウダー) 5.0
ココアパウダー(ココアパウダーF−23−T) 1.5
デキストリン 0.7
チョコレート香料 0.1
(サンフィックス※チョコレートNO.2027F*)
牛乳(60℃)にて全量を100とする。
Gelling agent of prescription part Example 2 2.0
Granulated sugar 10.0
Milk protein concentrate (Simpless 100 *) 5.7
Powdered oil (N Neo powder) 5.0
Cocoa Powder (Cocoa Powder F-23-T) 1.5
Dextrin 0.7
Chocolate flavor 0.1
(Sunfix * chocolate NO.2027F *)
The total amount is set to 100 with milk (60 ° C.).

実施例11 チューブ流動性の評価
経管投与の際のチューブ流動性及び付着性について、本発明のゲル化剤を用いて調製し
たゲル状濃厚流動食(実施例2−i)と市販のゾル状濃厚流動食(1.5kcal/g、
タンパク質含量6.0/100g、脂肪含量3.3g/100g、ミネラル含有量660
mg/100ml)を比較した。詳細には、実施例2−iと市販品をシリコンチューブ(
口径8mm)に注入し、水平状態にチューブをセットし、5mlのイオン交換水で試料を
押し出し、チューブ内の残存状態を評価した。結果を図1(実施例2−i)及び図2(市
販品)に示す。
Example 11 Evaluation of Tube Fluidity Regarding tube fluidity and adhesion during tube administration, a gel-like concentrated liquid food (Example 2-i) prepared using the gelling agent of the present invention and a commercially available sol-like form Rich liquid food (1.5 kcal / g,
Protein content 6.0 / 100g, fat content 3.3g / 100g, mineral content 660
mg / 100 ml). Specifically, Example 2-i and a commercially available product were combined with a silicon tube (
The tube was set in a horizontal state, the sample was pushed out with 5 ml of ion exchange water, and the remaining state in the tube was evaluated. The results are shown in FIG. 1 (Example 2-i) and FIG. 2 (commercially available product).

図1及び図2より、本発明のゲル化剤を用いて調製したゲル状濃厚流動食(図1)は、市販のゾル状濃厚流動食(図2)に比べて残存物が少なく、チューブ流動性及び付着性(付着防止)に優れていた。本発明のゲル化剤を用いることにより、操作性(注入しやすい)及び衛生性に優れた経管投与用の濃厚流動食を調製することができる。   From FIG. 1 and FIG. 2, the gel-like concentrated liquid food prepared using the gelling agent of the present invention (FIG. 1) has less residue than the commercially available sol-like concentrated liquid food (FIG. 2), and the tube flow Excellent in adhesion and adhesion (adhesion prevention). By using the gelling agent of the present invention, a concentrated liquid food for tube administration excellent in operability (easy to be injected) and hygiene can be prepared.

本発明のゲル化剤を用いることにより、50〜60℃といったゲル化剤の溶解温度としては比較的低温であるが、直接飲食することができる温度で溶解可能であり、その後、特別な冷却工程を経ることなく、室温で静置して冷却するのみで、簡便に咀嚼・嚥下困難者の喫食に適した食感と物性をもつゲル状食品を調製することができる。更に造粒(顆粒化)することで、手撹拌のような緩い撹拌でも容易に分散、溶解することができる。調製されたゲル状食品は、60℃程度まで再加温しても溶解することなく良好な保形性を有するため、温かい状態で食すことのできる咀嚼・嚥下困難者用ゲル状食品を提供できる。また、種々の液状食品に適応可能であり、汎用性が高い。   By using the gelling agent of the present invention, the melting temperature of the gelling agent such as 50 to 60 ° C. is relatively low, but it can be dissolved at a temperature at which it can be directly eaten and eaten, and then a special cooling step. A gel-like food having a texture and physical properties suitable for eating by those who have difficulty chewing / swallowing can be prepared simply by leaving it to stand at room temperature and cooling without going through. Furthermore, by granulating (granulating), it can be easily dispersed and dissolved even by gentle stirring such as manual stirring. The prepared gel-like food has good shape retention without dissolving even when re-heated to about 60 ° C., so that it can provide a gel-like food for those with difficulty in chewing / swallowing that can be eaten in a warm state . Moreover, it can be applied to various liquid foods and is highly versatile.

実施例2−iのゲル化剤を用いて調製したゲル状濃厚流動食を、シリコンチューブ(口径8mm)に注入し、水平状態にチューブをセットし、5mlのイオン交換水で試料を押し出した後のチューブの様子である。After injecting the gel-like concentrated liquid food prepared using the gelling agent of Example 2-i into a silicon tube (caliber 8 mm), setting the tube in a horizontal state, and extruding the sample with 5 ml of ion-exchanged water It is a state of the tube. 市販のゾル状濃厚流動食を、シリコンチューブ(口径8mm)に注入し、水平状態にチューブをセットし、5mlのイオン交換水で試料を押し出した後のチューブの様子である。A commercially available sol-like concentrated liquid food is injected into a silicon tube (caliber 8 mm), the tube is set in a horizontal state, and the sample is extruded with 5 ml of ion exchange water.

Claims (6)

咀嚼・嚥下困難者用ゲル状食品を調製するためのゲル化剤であって、易溶性寒天及び重量平均分子量が1.5×10g/mol以上のグァーガムを含み、前記易溶性寒天に対して、前記グァーガムの含有量が60〜700質量%であることを特徴とするゲル化剤。 A gelling agent for preparing a gel food for persons with difficulty in chewing / swallowing, comprising a readily soluble agar and a guar gum having a weight average molecular weight of 1.5 × 10 6 g / mol or more. The gelling agent is characterized in that the content of the guar gum is 60 to 700% by mass. 更に、キサンタンガム及び/又はネイティブ型ジェランガムを含む、請求項1に記載のゲル化剤。   The gelling agent according to claim 1, further comprising xanthan gum and / or native gellan gum. 更に、デキストリン、澱粉及び糖類から選択される少なくとも1種のバインダーを含む請求項1又は2に記載のゲル化剤。   The gelling agent according to claim 1 or 2, further comprising at least one binder selected from dextrin, starch and saccharide. 造粒されていることを特徴とする請求項1〜3のいずれかに記載のゲル化剤。   The gelling agent according to any one of claims 1 to 3, wherein the gelling agent is granulated. 液状食品に、請求項1〜4のいずれかに記載のゲル化剤を添加することにより調製された、咀嚼・嚥下困難者用ゲル状食品。   A gel food for persons with difficulty in chewing / swallowing prepared by adding the gelling agent according to any one of claims 1 to 4 to a liquid food. 液状食品が、下記(1)〜(4)のうち少なくとも1種の条件を満たすものである、請求項5に記載の咀嚼・嚥下困難者用ゲル状食品;
(1)pHが2〜5の範囲である。
(2)ミネラル分の含有量が液状食品全量に対して0.01〜10質量%である。
(3)脂肪分の含有量が液状食品全量に対して0.1〜50質量%である。
(4)タンパク質の含有量が液状食品全量に対して0.1〜20質量%である。
The liquid food is a gel-like food for a chewable / swallowing person according to claim 5, wherein the liquid food satisfies at least one of the following conditions (1) to (4):
(1) The pH is in the range of 2-5.
(2) Mineral content is 0.01-10 mass% with respect to liquid food whole quantity.
(3) The fat content is 0.1 to 50% by mass with respect to the total amount of liquid food.
(4) Protein content is 0.1-20 mass% with respect to liquid food whole quantity.
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