JP2012096188A - 光触媒塗装体および光触媒コーティング液 - Google Patents
光触媒塗装体および光触媒コーティング液 Download PDFInfo
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- JP2012096188A JP2012096188A JP2010247435A JP2010247435A JP2012096188A JP 2012096188 A JP2012096188 A JP 2012096188A JP 2010247435 A JP2010247435 A JP 2010247435A JP 2010247435 A JP2010247435 A JP 2010247435A JP 2012096188 A JP2012096188 A JP 2012096188A
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- Prior art keywords
- photocatalyst
- particles
- coating liquid
- photocatalytic
- resin emulsion
- Prior art date
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 162
- 238000000576 coating method Methods 0.000 title claims abstract description 102
- 239000011248 coating agent Substances 0.000 title claims abstract description 100
- 239000007788 liquid Substances 0.000 title claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 126
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 83
- 230000001699 photocatalysis Effects 0.000 claims abstract description 55
- 239000000839 emulsion Substances 0.000 claims abstract description 51
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 35
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 35
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 31
- 239000000126 substance Substances 0.000 claims abstract description 29
- 239000000758 substrate Substances 0.000 claims abstract description 25
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 15
- -1 perfluoro group Chemical group 0.000 claims description 108
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 34
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 28
- 229920001296 polysiloxane Polymers 0.000 claims description 25
- 239000007787 solid Substances 0.000 claims description 22
- 239000000049 pigment Substances 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 11
- 229910000077 silane Inorganic materials 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 5
- 125000001165 hydrophobic group Chemical group 0.000 abstract 1
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 5
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
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- 239000003973 paint Substances 0.000 description 4
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- 229910052697 platinum Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 4
- 239000005361 soda-lime glass Substances 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- 229910001887 tin oxide Inorganic materials 0.000 description 4
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- 239000003429 antifungal agent Substances 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 3
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- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 2
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- 230000007062 hydrolysis Effects 0.000 description 2
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- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 2
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- HLWCOIUDOLYBGD-UHFFFAOYSA-N trichloro(decyl)silane Chemical compound CCCCCCCCCC[Si](Cl)(Cl)Cl HLWCOIUDOLYBGD-UHFFFAOYSA-N 0.000 description 1
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- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- UDUKMRHNZZLJRB-UHFFFAOYSA-N triethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OCC)(OCC)OCC)CCC2OC21 UDUKMRHNZZLJRB-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- JIOBRIJHDZBWDE-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]-(3,3,3-trifluoropropyl)silane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)CCC(F)(F)F JIOBRIJHDZBWDE-UHFFFAOYSA-N 0.000 description 1
- WUSDGIZCXCUHAI-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)CCCOCC1CO1 WUSDGIZCXCUHAI-UHFFFAOYSA-N 0.000 description 1
- KGOOITCIBGXHJO-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]-phenylsilane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)C1=CC=CC=C1 KGOOITCIBGXHJO-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010247435A JP2012096188A (ja) | 2010-11-04 | 2010-11-04 | 光触媒塗装体および光触媒コーティング液 |
| TW100139946A TWI457386B (zh) | 2010-11-04 | 2011-11-02 | Photocatalyst-coated body and a photocatalyst coating liquid |
| CN2011104621426A CN102604465A (zh) | 2010-11-04 | 2011-11-04 | 光催化剂涂装体及光催化剂涂布液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010247435A JP2012096188A (ja) | 2010-11-04 | 2010-11-04 | 光触媒塗装体および光触媒コーティング液 |
Publications (1)
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|---|---|
| JP2012096188A true JP2012096188A (ja) | 2012-05-24 |
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| JP2010247435A Pending JP2012096188A (ja) | 2010-11-04 | 2010-11-04 | 光触媒塗装体および光触媒コーティング液 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2012096188A (zh) |
| CN (1) | CN102604465A (zh) |
| TW (1) | TWI457386B (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014057712A1 (ja) * | 2012-10-13 | 2014-04-17 | 東洋アルミニウム株式会社 | 撥水・撥油性塗膜及びその塗膜を含む物品 |
| WO2014141812A1 (ja) * | 2013-03-15 | 2014-09-18 | 昭和電工株式会社 | 抗菌抗ウイルス性光触媒酸化チタン、及び中性領域で分散した抗菌抗ウイルス性光触媒酸化チタンスラリー並びにそれらの製造方法 |
| JP2016093786A (ja) * | 2014-11-14 | 2016-05-26 | 昭和電工株式会社 | 光触媒コーティング組成物 |
| JP2016193423A (ja) * | 2015-03-31 | 2016-11-17 | Toto株式会社 | 光触媒塗装体 |
| JP2017515675A (ja) * | 2014-03-26 | 2017-06-15 | エーエム テクノロジー リミテッドＡｍ Ｔｅｃｈｎｏｌｏｇｙ Ｌｉｍｉｔｅｄ | セメント系光触媒組成物、及び、水性塗料を得るための、特には屋外用途のためのその使用 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254705A (zh) * | 2013-05-21 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | 一种水性负离子墙面装饰涂料 |
| KR20180105154A (ko) * | 2016-02-05 | 2018-09-27 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 플루오로중합체 코팅 형성용 플루오로중합체 용액 |
| CN107033708A (zh) * | 2017-04-25 | 2017-08-11 | 安徽博硕科技有限公司 | 一种凹凸棒土/纳米钛酸锶/纳米氧化锡光催化硅丙涂料的制备方法 |
| CN111363445B (zh) * | 2020-04-15 | 2022-06-07 | 浙江大学中原研究院 | 一种高含氟量水性混凝土防护涂料 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997000134A1 (en) * | 1995-06-19 | 1997-01-03 | Nippon Soda Co., Ltd. | Photocatalyst-carrying structure and photocatalyst coating material |
| DE69835139T2 (de) * | 1997-03-14 | 2007-05-31 | Matsushita Electric Works, Ltd., Kadoma | Fäulnisverhindernde emulsionsbeschichtungszusammensetzung, verfahren zur herstellung und mit dieser fäulnisverhindernden zusammensetzung beschichteter gegenstand |
| JP3791549B1 (ja) * | 2005-09-02 | 2006-06-28 | 東陶機器株式会社 | 複合材、コーティング液および複合材の製造方法 |
-
2010
- 2010-11-04 JP JP2010247435A patent/JP2012096188A/ja active Pending
-
2011
- 2011-11-02 TW TW100139946A patent/TWI457386B/zh not_active IP Right Cessation
- 2011-11-04 CN CN2011104621426A patent/CN102604465A/zh active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014057712A1 (ja) * | 2012-10-13 | 2014-04-17 | 東洋アルミニウム株式会社 | 撥水・撥油性塗膜及びその塗膜を含む物品 |
| US10494554B2 (en) | 2012-10-13 | 2019-12-03 | Toyo Aluminium Kabushiki Kaisha | Water- and oil-repellent coating film and articles having this coating film |
| WO2014141812A1 (ja) * | 2013-03-15 | 2014-09-18 | 昭和電工株式会社 | 抗菌抗ウイルス性光触媒酸化チタン、及び中性領域で分散した抗菌抗ウイルス性光触媒酸化チタンスラリー並びにそれらの製造方法 |
| JPWO2014141812A1 (ja) * | 2013-03-15 | 2017-02-16 | 昭和電工株式会社 | 抗菌抗ウイルス性光触媒酸化チタン、及び中性領域で分散した抗菌抗ウイルス性光触媒酸化チタンスラリー並びにそれらの製造方法 |
| JP2017515675A (ja) * | 2014-03-26 | 2017-06-15 | エーエム テクノロジー リミテッドＡｍ Ｔｅｃｈｎｏｌｏｇｙ Ｌｉｍｉｔｅｄ | セメント系光触媒組成物、及び、水性塗料を得るための、特には屋外用途のためのその使用 |
| JP2016093786A (ja) * | 2014-11-14 | 2016-05-26 | 昭和電工株式会社 | 光触媒コーティング組成物 |
| JP2016193423A (ja) * | 2015-03-31 | 2016-11-17 | Toto株式会社 | 光触媒塗装体 |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI457386B (zh) | 2014-10-21 |
| CN102604465A (zh) | 2012-07-25 |
| TW201231533A (en) | 2012-08-01 |
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