JP2012076997A - Glass article - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a glass article which has one or a plurality of recessed parts, in which the variation in the thickness is suppressed as much as possible and which has appropriate surface characteristics.SOLUTION: The glass article 1 has a recessed part 1a formed therein, wherein at least one surface in at least the recessed part 1a is formed by the solidification of a free surface of a softened glass base material G, and further, the variation in the thickness of the side wall portion 1x in the recessed part 1a from a target thickness is within ±5%, and the variation in the thickness of the bottom wall portion 1y in the recessed part 1a from a target thickness is within ±5%.

Description

  The present invention relates to a uniform thickness and an appropriate surface property of a glass article having one or more recesses.

  In recent years, as a method for producing a glass article having one or a plurality of recesses such as a glass container or a cover glass for an image sensor or a glass for a liquid crystal backlight, a glass material made of a flat glass plate is heated. Thus, a method of softening and deforming and solidifying while conforming to a molding concave portion of a mold by a negative pressure has been adopted.

  As an example, according to Patent Document 1 below, for example, a molding die having a molding surface with an uneven upper surface and a large number of through holes (ventilation holes) is fixed to the bottom of a heating furnace (electric furnace chamber). In addition, a technique is disclosed in which a plate glass is placed on the mold and heated, and a negative pressure is applied to the molding surface through a through hole to form the plate glass into a shape that follows the irregularities of the molding surface.

  In this case, the large number of through holes formed in the mold are joined at the counterbore formed at the bottom of the mold and on the bottom wall of the heating furnace, and the counterbore is connected to the rotary pump. It is connected to a connected suction tube. Accordingly, when the rotary pump is operated, a negative pressure is generated in the counterbore portion through the suction pipe, and this negative pressure acts on the molding surface of the mold through a large number of through holes.

  According to FIG. 6 of Patent Document 2, a plate glass heated to a softening point or higher is placed on a mold having a recess formed on the contact surface with the plate glass, and the space surrounded by the plate glass and the recess is evacuated. It is disclosed that immediately after forming a glass sheet by drawing and sucking the glass sheet into a recess of the mold, an attachment hole for attaching an electrode is provided, and this glass sheet is placed in a furnace and gradually cooled.

  In this case, a plurality of through holes that lead to the plurality of recesses are formed in the mold, and these through holes merge in the internal space of the cover that covers the back surface of the mold, and the internal space of the cover is It is connected to a rotary pump through piping and valves. Therefore, the plate glass is evacuated to the shape of the molding surface of the mold by sucking the air in the inner space of the cover through a valve and piping by a rotary pump and drawing the inside of the mold recess through a through hole. Molded.

JP-A-4-275930 JP-A-11-204035 (FIG. 6)

  By the way, according to the sheet glass forming apparatus disclosed in the above-mentioned Patent Document 1, the mold and the sheet glass are heated inside the heating furnace, except for the special glass having a heat ray absorbing effect. For example, glass generally has a property of transmitting heat rays. Therefore, in the heating furnace, first, the mold is heated by the heat rays transmitted through the plate glass, and the plate glass is softened by receiving heat supply from the mold. To the state. For this reason, the plate glass has a relatively high temperature at the contact portion with the mold and a relatively low temperature at the non-contact portion. Thus, the temperature distribution is uneven and the degree of softening is not uniform. This leads to a situation where suction by negative pressure is performed.

  Further, according to the molding method disclosed in Patent Document 2, a plate glass heated to a temperature higher than the softening point (approximately 900 ° C.) is placed on a mold heated to about 500 ° C. In order to evacuate the inside of the recess, when the plate glass is placed on the mold, the contact portion with the plate glass mold is deprived of heat and the temperature is lowered, whereas the non-contact portion is It still tends to be maintained at a high temperature. Therefore, also in this case, suction by negative pressure is performed in a state where the temperature distribution (degree of softening) of the plate glass is not uniform.

  In the above-described aspect, when the suction force due to the negative pressure acts on the plate glass, the plate glass starts to deform from the most softened portion. The deformation starts from the contact portion with the molding die, and the state in which the deformation of the contact portion is relatively large as described above tends to continue until the molding is completed. On the other hand, in the molding method disclosed in Patent Document 2 above, judging from the shape of the mold shown in FIG. 6, the boundary portion between the contact portion and the non-contact portion of the plate glass mold is most easily deformed, Therefore, after completion of molding, the glass thickness at the boundary portion is the thinnest.

  The reason why such a problem becomes prominent is that the temperature distribution of the glass sheet is not uniform as described above, and a molding process in which a negative pressure is applied to the glass sheet to cause deformation by a suction force is performed once. It comes largely from the fact that it can only be completed with a suction process. That is, including the techniques disclosed in Patent Documents 1 and 2 above, in the past, during the period from the start of deformation of the glass sheet to the end of the deformation, a negative pressure is continuously applied to transform it into the final shape all at once. This has been a major factor, and the above problems have become prominent.

  Specifically, as shown in FIG. 8A, the glass sheet G in a softened state placed on the mold 15 starts to deform and ends as shown in FIGS. When the molding process up to this is performed by a single negative pressure suction process, the unevenness of the softening degree of the glass sheet G causes variations in the glass thickness as shown in FIG. Even when negative pressure suction is started after waiting until the entire plate glass G is sufficiently softened, the softened glass flows into the center of the molding recess 15a as shown in FIG. In any case, uneven thickness was generated in the glass sheet G after completion of the molding.

  Also, if the negative pressure when deforming the sheet glass is excessively increased for the purpose of shortening the molding time, etc., the sheet glass cannot follow the shape of the molding recess and cannot be deformed, and the degree of softening of the sheet glass Combined with the uneven alignment of the deformation progression due to non-uniformity, an air pocket remains between the molding recess and the glass after the molding is completed, and the defective glass article having an irregular shape is forced to occur frequently.

  In view of the above circumstances, the present invention provides a glass article having an appropriate surface property as a glass article having one or a plurality of recesses, while suppressing variations in thickness as much as possible. To do.

  Prior to the description of the glass article according to the present invention, the glass article forming method and the first to third means relating to the forming apparatus, which are the main factors that led to the completion of the present invention, will be described. Keep it.

  The first means places a glass material on a mold having one or more molding recesses formed on the upper surface, and is surrounded by the softened back surface of the glass material and the molding recesses. In a method of forming a glass article in which one or a plurality of recesses are formed by applying a negative pressure to a forming space, the glass material is changed from the start of deformation to the target shape of the glass material by the action of the negative pressure. It is characterized in that the action of the negative pressure is temporarily interrupted at least once before the deformation is completed. Here, the above-mentioned target shape means a shape to be finally obtained in the molding process (hereinafter the same). Further, temporarily suspending the action of the negative pressure is not only when the negative pressure is temporarily not applied at all, but also when compared with the negative pressure that deforms the glass material. This also includes the case where a negative pressure (a negative pressure that is difficult to deform the glass material) is temporarily applied (hereinafter the same).

  According to such a configuration, the glass material in a softened state placed on the mold is not completed by being deformed all at once by the continuous action of negative pressure, but at least once. Since the action of the negative pressure is temporarily interrupted, the progress of the deformation can be abruptly reduced or the progress can be stopped halfway until the deformation of the glass material is completed. In this case, at the start of the deformation of the glass material, the glass material is affected by heat from the mold by coming into contact with parts other than the molding recess of the mold, so that the negative pressure is sucked into the molding recess and deformed. The softened state of the glass material in the non-contact portion should be the periphery of the contact portion that is easily affected by heat from the mold, and the portion that is far from the contact portion rather than the periphery that is hardly affected by such heat. Is different. From this state, when the glass material is deformed by the action of negative pressure, the periphery of the contact part actually comes into contact with the molding recess and is appropriately adapted to the recess. At the time when the temperature suddenly drops or stops, the area around the contact portion with the molding recess at that time moves from the mold to a part that is easily affected by heat, and the deformation of the glass material proceeds again due to negative pressure. The part which is easily affected by the heat actually comes into contact with the concave part of the molding and is appropriately adapted to the concave part. In this way, if the action of the negative pressure is temporarily interrupted at least once between the start of deformation of the glass material and the completion of the deformation, the glass material is affected by heat from the molding die (molding recess). Because there are parts that are susceptible to heat and parts that are hardly affected by heat, even if the softened state is not uniform, the part that actually contacts and conforms to the molding recess is affected by heat. It becomes possible to make only the easy part. As a result, in the process in which the glass material is deformed by the negative pressure, it becomes possible for the portions having approximately the same softened state to come into contact with the forming recesses in order and become familiar with each other properly. And air accumulation cannot occur. As a result, the variation in thickness is reduced as much as possible, the elongation due to deformation is made uniform, and furthermore, the surface properties of the surface of the glass material in which the inner surface is in a softened state before starting deformation are effectively maintained. A glass article having one or more recesses can be obtained. In the above molding process, even if the glass material is not completely in close contact with the bottom surface of the molding recess after completion of molding, if the non-contact state is the final shape (the shape of the glass article), the above and Glass articles having similar advantages can be obtained. It is also possible to deform the glass material without bringing it into contact with the molding recess.In this case, the periphery of the contact portion with the mold that is susceptible to heat in the glass material at the start of deformation is negatively affected. In addition to the same advantages as above, if the suction is deformed by temporarily interrupting at least once with pressure, both the inner and outer surfaces of the recess are softened before the deformation starts. It is possible to obtain a glass article having the advantage of maintaining the surface properties.

  Further, the second means places a glass material on a mold having one or more molding recesses formed on the upper surface, and is surrounded by the softened back surface of the glass material and the molding recesses. In a method of forming a glass article in which one or a plurality of recesses are formed by applying a negative pressure to a forming space, the glass material is changed from the start of deformation to the target shape of the glass material by the action of the negative pressure. It is characterized in that the negative pressure is adjusted so that the progress of the deformation of the glass material is temporarily interrupted at least once before the deformation is completed.

  Even with such a configuration, when applying a negative pressure to deform a glass material in a softened state, the deformation is completed from the beginning of the deformation, rather than applying a negative pressure so that the deformation proceeds continuously. In the meantime, since the negative pressure is adjusted so that the progress of the deformation of the glass material is temporarily interrupted at least once, the same effect as the first means described above can be enjoyed. can do. In this case, the progress of the deformation of the glass material is temporarily interrupted, not only when the progress of the deformation is completely stopped, but also within a range where the above-described effects can be obtained. In this case, the case where the deformation progresses slightly or the case where the deformed portion returns slightly is included.

  In the above configuration, it is preferable to temporarily interrupt the negative pressure action at least once during the period from the completion of the deformation of the glass material to the target shape to the completion of the solidification of the glass.

  In this way, it becomes possible to solidify the shape after completion of the deformation of the glass material in a manner that closely follows the shape of the molding recess of the mold, and the glass in the softened state leads to the molding recess. The formation of extra protrusions by flowing into the negative pressure suction vent and solidifying is prevented. In other words, when the glass material is in close contact with the molding recess of the mold due to the completion of deformation, the glass is still in a softened state. In such a state, suction by the negative pressure is completely stopped. Due to the positive pressure from the air vents or the shrinkage of the glass during the cooling process, the glass is unduly deformed, resulting in a problem that the state following the shape of the molding recess cannot be maintained and solidifies. On the other hand, even after the glass material is brought into close contact with the molding recess of the mold due to the completion of the deformation, if the suction by the negative pressure is continuously performed, the glass in the softened state has a negative pressure suction vent. This causes a problem that an excessive convex portion is formed. However, if the negative pressure action is adjusted as described above, such a problem can be appropriately avoided.

  In the above configuration, the glass material is heated in a state of being placed on the mold and becomes softened, and in the process until the glass material is softened, the surface side of the glass material It is possible to cause the space and the molding space to have substantially the same temperature or substantially the same atmospheric pressure, and start to apply a negative pressure to the molding space from that state.

  In this way, in the process of heating the glass material placed on the mold (the process until the suction by the negative pressure is started), the surface side space of the glass material and the back side thereof Since the molding space is at substantially the same temperature, there is almost no pressure difference between the two spaces, and therefore, the glass material is less likely to be unduely deformed due to such a pressure difference. In other words, it is difficult for unjust dent deformation to occur until the softened state of the glass material is appropriately uniformed over the entire area. Such an advantage is more accurate when the glass material is heated in the process where the front side space of the glass material and the molding space on the back side thereof have substantially the same pressure difference. Obtainable. And, when the softened state of the glass material is appropriately uniformed over the entire area and the glass material is sufficiently softened to be appropriately deformed, if negative pressure is applied to the molding space, one or As a glass article having a plurality of recesses, it is extremely advantageous in obtaining a glass article that is close to the final ideal shape and has a uniform thickness distribution. Even if the softened state of the glass material is not sufficiently and surely uniform over the entire area in the previous stage of applying the negative pressure, according to such means, the previous stage of the negative pressure suction. Thus, since no additional dent deformation that adversely affects the final shape or thickness distribution occurs, it does not greatly impede obtaining a glass article that is close to the ideal shape and has a uniform thickness distribution.

  Further, in the above configuration, the glass material is heated in a state of being placed on the mold and becomes softened, and in the process until the glass material is softened, It is also possible to increase the temperature or pressure of the molding space as compared with the temperature or pressure of the surface side space, and to start applying a negative pressure to the molding space from that state.

  In this way, in the process of heating the glass material placed on the mold (the process until the suction by the negative pressure is started), the back surface of the glass material rather than the front side space. Since the molding space on the side is heated to a higher temperature, the thickness of the glass material and the molding recess (non-contact area) may be increased until the softened state of the glass material is uniformly uniform over the entire area. Due to the area of the glass material located at the surface or the composition of the glass material itself, even if an undesired dent deformation occurs due to its own weight, the molding space on the back side has a higher atmospheric pressure than the surface side space. Since it can be, the force which raises a glass raw material moderately from the back side may generate | occur | produce. For this reason, in the process of heating the glass material, it becomes difficult for the glass material to be distorted due to its own weight. Such an advantage can be obtained more accurately when the molding space on the back side of the glass material is more actively pressurized than the surface space of the glass material in the heating process of the glass material. it can. After this, the glass article having the ideal ideal shape and the uniform thickness distribution is finally obtained by the action of the negative pressure, which is the same as already described.

  In the above configuration, it is preferable that the glass material has a flat plate-shaped portion where one or a plurality of recesses are formed.

  According to such a configuration, it is possible to obtain an image sensor cover glass, a liquid crystal backlight glass (for example, a fluorescent lamp glass) and the like having excellent quality.

  Further, the third means places a glass material on a mold having one or more molding recesses formed on the upper surface, and is surrounded by the softened back surface of the glass material and the molding recesses. In an apparatus configured to mold a glass article in which one or a plurality of recesses are formed by applying a negative pressure to the molding space, the glass material from the start of deformation of the glass material by the action of the negative pressure It is characterized in that the negative pressure is temporarily interrupted or the magnitude of the negative pressure is temporarily reduced at least once before the deformation to the target shape is completed. It is done.

  The third means has substantially the same configuration as the first means, and the operation and effect thereof is also substantially the same, so the description thereof is omitted here for convenience.

  The present invention made to solve the above technical problem is a glass article in which a recess is formed, and at least one surface of the recess is softened and the free surface of the glass material is solidified. The variation of the thickness of the side wall portion in the recess from the target thickness is within 5%, and the variation from the target thickness of the bottom wall in the recess is within ± 5%. It is done. Here, the basic significance of the above target wall thickness will be explained. For example, when the thickness is designed to be uniform over the entire area of the concave portion, the constant thickness becomes the target wall thickness. However, in the case where a thick part and a thin part are clearly present in the recess, the design thicknesses corresponding to the thick part and the thin part respectively become the target thickness. In this case, there is a target wall thickness that is a designed wall thickness for each of the side wall portion and the bottom wall portion in the recess.

  According to such a configuration, it is possible to provide a glass article that could not be produced by a conventional molding method. That is, if a glass article having one or a plurality of recesses is produced by press molding, at least the variation in thickness with respect to the target thickness of the recesses can be reduced, but on the other hand, both front and back surfaces are molded by contact with the mold. As a result, the surface property of the glass material is not maintained on any surface. On the other hand, as already described in the section of “Background Art”, if a glass article having one or a plurality of recesses is produced by a method of forming a recess using a suction action by negative pressure, at least one of the recesses Because the surface is solidified on the free surface of the glass material in the softened state (such as a mirror surface or a surface close to the mirror surface, a surface on which regular irregularities are regularly arranged, or a surface treated by sandblasting) Although it is possible to obtain a surface property close to the surface of the material, on the other hand, as already described in the section of [Problems to be solved by the invention], at least the target thickness of the concave portion Unjust variation in thickness occurs. On the other hand, according to the glass article according to the present invention, both of the advantages described above are combined and further improved. That is, surface treatment such as sandblasting is performed on at least one surface of the glass material so as to meet the requirements, and the surface property is more appropriately maintained even after the recess is formed. Therefore, it is possible to avoid the problem that it is practically impossible to perform such surface treatment after the formation of the concave portion, and to keep the variation in the thickness of the concave portion within ± 5% of the target thickness. By keeping the thicknesses of the side wall portion and the bottom wall portion in the recess within ± 5% of the respective target thicknesses, the strength and the quality can be improved. In addition, by setting both surfaces of the glass material to have a surface property as required, for example, a mirror surface or a surface close to the mirror surface, and maintaining the surface property more appropriately even after the recess is formed , It is possible to avoid the problem that it is practically impossible to make both sides of the mirror surface or the surface close to the mirror surface after forming the recess, and to keep the variation in the thickness of the recess within ± 5% of the target thickness. Can do. Such an advantage is obtained because the present inventors have devised a molding method according to the first means or the second means. However, the molding method for the glass article according to the present invention is not limited to such a molding method.

  Further, the present invention made to solve the above technical problem is a glass article comprising a concave portion and a flat plate portion connected to the outer peripheral side on the opening side of the concave portion, and at least one of the concave portions. The free surface of the glass material in the softened state is solidified, and the variation of the thickness of the concave portion from the target thickness is within 5%, from the target thickness of the thickness of the flat plate portion Is characterized by a variation of 5% or less. In addition, considering the above description of the basic significance of the target wall thickness, here, since the design is a uniform thickness over the entire area of the recess, the constant thickness is the target thickness. Therefore, there is a target wall thickness that is a designed wall thickness for each of the concave portion and the flat plate-like portion.

  Furthermore, the present invention made to solve the above technical problem is a glass article comprising a concave portion and a flat plate-like portion connected to the outer peripheral side on the opening side of the concave portion, and at least one of the concave portions. The free surface of the glass material in the softened state is solidified, and the variation from the target thickness of the side wall portion in the recess is within 5%, and the thickness of the bottom wall portion in the recess The variation from the target thickness is within ± 5%, and the variation from the target thickness of the flat plate portion is within 5%. Here, there is a target wall thickness that is a designed wall thickness for the side wall portion, the bottom wall portion, and the flat plate portion of the recess.

  Further, the present invention made to solve the above technical problem is a glass article in which a recess is formed, and at least one surface of the recess is softened and the free surface of the glass material is solidified. And the variation from the average wall thickness of the side wall in the recess is within 5%, and the variation from the wall thickness of the bottom wall in the recess is within ± 5%. Characterized. Here, the average thickness is a single value when the thickness is uniform in design over the entire area of the recess, but the side wall portion and the bottom wall portion of the recess can be clearly distinguished. If the thickness of the side wall and the thickness of the bottom wall are different enough to be clearly distinguished (if they are different in design), the average thickness of the side wall of the recess The thickness and the average wall thickness of the bottom wall of the recess are different values. Here, there is an average wall thickness that is a uniform wall thickness in terms of design for the side wall portion and the bottom wall portion of the recess.

  Even with such a configuration, it is possible to provide a glass article that could not be produced by a conventional molding method. That is, for the same reason as the case where the target thickness is set as a constituent requirement, one or both surfaces of the glass material are set as surface properties according to requirements, and the surface properties are maintained even after the recesses are formed. By maintaining as appropriate as possible, it is possible to avoid the problem that it is virtually impossible to make such a surface property after the formation of the recess, and the variation in thickness of the recess is within ± 5% of the average thickness In detail, the thickness of each of the side wall portion and the bottom wall portion of the concave portion is within ± 5% of the average thickness of each concave portion, so that the glass article is excellent in strength and quality. be able to.

  Furthermore, the present invention made to solve the above technical problem is a glass article comprising a concave portion and a flat plate-like portion connected to the outer peripheral side on the opening side of the concave portion, and at least one of the concave portions. The free surface of the glass material in the softened state is solidified, and the variation from the average thickness of the concave portion is within 5%, from the average thickness of the flat portion Is characterized by a variation of 5% or less. Here, since the above average thickness is a uniform thickness over the entire area of the recess, it becomes a single value. Accordingly, the recess and the flat portion have a uniform thickness for each design. There is an average wall thickness.

  Further, the present invention made to solve the above technical problem is a glass article comprising a concave portion and a flat plate portion connected to the outer peripheral side on the opening side of the concave portion, and at least one of the concave portions. The free surface of the glass material in the softened state is solidified, and the variation from the average thickness of the side wall in the recess is within 5%, and the thickness of the bottom wall in the recess The variation from the average thickness of the flat plate portion is within ± 5%, and the variation from the average thickness of the flat plate portion is within 5%. Here, there is an average wall thickness that is a uniform wall thickness by design for the side wall portion, the bottom wall portion, and the flat plate-like portion of the recess.

  The glass article having the above-described configuration may have only one recess, and a flat plate portion may be connected to the entire outer peripheral side on the opening side of the recess. These recesses are connected to each other on the side of each opening via a flat plate-like portion, and the entire outer peripheral side of each opening portion in the region where the plurality of recesses are formed may be a flat plate-like portion.

  By doing so, the cover glass for an image sensor and the glass for a liquid crystal backlight (for example, flat fluorescent light) that have no undue variation in thickness and whose surface property is as required and whose rigidity is effectively enhanced by a flat plate portion (for example, flat fluorescent light). Lamp glass) and the like.

  Furthermore, in these glass articles, a peripheral wall portion that rises in a direction opposite to the recess direction of the concave portion may be formed on the outer peripheral edge of the flat plate portion in the entire outer peripheral side.

  In this way, it is possible to provide an image sensor cover glass and a liquid crystal backlight glass (for example, a flat fluorescent lamp glass) having the same advantages as those described above having other forms.

  According to the glass article according to the present invention, the surface property according to the request is obtained, the thickness distribution is appropriate, and the strength and quality are excellent.

It is a schematic perspective view which shows the glass article which concerns on 1st Embodiment of this invention. It is a schematic perspective view which shows the glass article which concerns on 2nd Embodiment of this invention. It is a schematic perspective view which shows the glass article which concerns on 3rd Embodiment of this invention. It is a vertical front view which shows schematic structure of the shaping | molding apparatus for shape | molding the glass article which concerns on 1st Embodiment of this invention. FIGS. 5A to 5E are longitudinal sectional front views for explaining the molding process of molding the glass article according to the first embodiment of the present invention in order with time. It is a vertical front view which shows schematic structure of the shaping | molding apparatus for shape | molding the glass article which concerns on 2nd Embodiment of this invention. FIGS. 7A to 7D are longitudinal sectional front views for explaining the forming process of forming the glass article according to the second embodiment of the present invention in order with time. FIGS. 8A to 8D are longitudinal sectional front views for explaining a forming process for forming a conventional glass article step by step with time.

  Embodiments of the present invention will be described below with reference to the accompanying drawings.

  First, based on FIG. 1, the glass article which concerns on 1st Embodiment of this invention is demonstrated. As shown in the figure, a glass article (for example, an image sensor cover glass or a display tube glass) 1 has a single recess 1a, and a rectangular outline is formed in the entire outer peripheral side of the recess 1a on the opening side. The flat plate portion 1b is continuous. And as for the inner surface in the recessed part 1a of this glass article 1, while the free surface (for example, surface near a mirror surface) in the softened state of a glass-made raw material (glass plate) solidifies, the outer surface is a shaping | molding die. It is formed by contact with. In this case, the free surface in the softened state of the glass material may be solidified on both the inner surface and the outer surface of the recess 1a of the glass article 1. In this embodiment, the flat plate-like portion 1b of the glass article 1 is formed by contacting the inner and outer surfaces (front and back surfaces) with a mold, but the surface is free in the softened state of the glass plate. It is also possible to solidify the surface.

  Further, the thickness of the concave portion 1a of the glass article 1 is within ± 5% of variation from the target thickness (designed thickness). That is, when the design thickness of the entire recess 1a is, for example, 1 mm, the actual thickness of the entire recess 1a is within the range of 0.95 mm to 1.05 mm. Further, when the designed wall thickness of the side wall 1x of the recess 1a is, for example, 1.2 mm and the designed wall thickness of the bottom wall 1y is, for example, 0.8 mm, the actual side wall 1x The wall thickness is within the range of 1.14 mm to 1.26 mm, and the actual thickness of the bottom wall portion 1y is within the range of 0.76 mm to 0.84 mm. In this embodiment, the thickness of the flat plate portion 1b is within ± 5% of variation from the entire thickness of the recess 1a or the same target thickness (designed thickness) as the side wall portion 1x or the bottom wall portion 1y. It is.

  From another viewpoint, the thickness of the concave portion 1a of the glass article 1 has a variation from the average thickness within ± 5%. That is, when the average thickness of the entire recess 1a is, for example, 1 mm, the thickness of the entire recess 1a is within the range of 0.95 mm to 1.05 mm. When the average thickness of the side wall 1x of the recess 1a is, for example, 1.2 mm and the average thickness of the bottom wall 1y is, for example, 0.8 mm, the thickness of the side wall 1x is 1.14 mm. The thickness of the bottom wall 1y is within a range of 0.76 mm to 0.84 mm. In addition, the thickness of the flat plate-like portion 1b is within ± 5% from the average thickness (designed thickness) of the entire concave portion 1a or the side wall portion 1x or the bottom wall portion 1y thereof.

  FIG. 2 illustrates a glass article 2 according to the second embodiment of the present invention. As shown in the figure, this glass article 2 has a plurality of groove-like recesses 2a having a substantially semicircular cross section arranged in parallel, and the plurality of groove-like recesses 2a are respectively flat plate-like parts 2b on the respective opening side. In addition, the entire outer peripheral side of each opening portion in the region where the plurality of groove-like recesses 2a are formed is a flat plate-like portion 2c having a rectangular outline. And the inner surface in each groove-shaped recessed part 2a of this glass article 2 and the surface of each flat plate-like part 2b connected to these inner surfaces are free surfaces in the softened state of the glass material (glass plate). While solidifying, their outer surfaces are formed by contact with a mold. In this embodiment, the flat plate-like portion 2c in the entire outer peripheral side of the glass article 2 is formed by contact with the forming die on both the inner and outer surfaces (front and back surfaces). It is also possible that the free surface of the glass plate is solidified.

  Further, the thickness of each groove-like recess 2a of the glass article 2 is within ± 5% of variation from the target thickness (designed thickness). From another viewpoint, the thickness of the concave portion of the glass article 2 has a variation from the average thickness within ± 5%. The meaning of these variations in thickness is the same as that described in the first embodiment. In this embodiment, the thickness of the flat plate-like portion 2b between each groove-like recess 2a is within ± 5% of variation from the same target thickness and the same average thickness as each groove-like recess 2a. In addition, the thickness of the flat plate-like portion 2c in the entire outer peripheral side is within ± 5% of variation from the same target thickness and average thickness as each groove-like recess 2a.

  FIG. 3 illustrates a glass article according to the third embodiment of the present invention. The glass article 2 ′ according to the third embodiment is different from the glass article 2 according to the second embodiment described above in that the outer peripheral edge of the flat plate-like portion 2c in the entire outer peripheral side is opposite to the depression direction of the recess 2a. The peripheral wall 2d rising in the direction is formed. The wall thickness of the peripheral wall 2d may be within ± 5% of variation from the same target thickness and the same average thickness as each groove-like recess 2a, or other target thickness and other averages. The variation from the wall thickness may be within ± 5% or may not have such a wall thickness relationship. Since other configurations are the same as those of the glass article 2 according to the second embodiment described above, common components are denoted by the same reference numerals, and description thereof is omitted.

  The glass article 1 according to the first embodiment described above is produced using a molding apparatus 3 as shown in FIG. In this molding apparatus 3, a molding recess 5a having a substantially hemispherical shape is formed on the upper surface of the internal space 4a of the heating furnace 4, and a single vent hole 5b is formed that communicates with the center of the bottom inside the molding recess 5a. The formed mold 5 is provided. A chamber 6 is fixed to the bottom of the mold 5 and is entirely located in the internal space 4 a of the heating furnace 4. The entire area of the side wall 6 c and the bottom wall 6 d of the chamber 6 is the internal space of the heating furnace 4. It is exposed to the high temperature atmosphere (hot air) in 4a. The internal space 6 a of the chamber 6 communicates with the inside of the molding recess 5 a through the vent hole 5 b of the molding die 5.

  Further, an exhaust pipe (communication passage) 8 communicating with an exhaust device 7 disposed outside the heating furnace 4 is connected to the bottom wall portion 6 d of the chamber 6, and the internal space 6 a of the chamber 6 is operated by the operation of the exhaust device 7. Negative pressure is generated in the. The exhaust device 7 may be of any mechanism, but has a venturi mechanism that is particularly excellent in suction action, that is, on / off response of vacuum operation. Further, an open / close valve 9 for opening and closing the communication passage in the exhaust pipe 8 is attached to the outside of the heating furnace 4 of the exhaust pipe 8. And in this 1st Embodiment, the heating source 10 is installed only in the inner surface side of the side wall part 4c of the heating furnace 4. As shown in FIG. The heating method of the heating source 10 may be based on heating wire or based on combustion gas. A press plate 11 is provided above the mold 5 to hold and hold the peripheral edge of the glass plate G as a glass material placed on the upper surface of the mold 5. The molding apparatus 3 may have a heating source 10 installed not only on the inner surface side of the entire circumference of the side wall 4c of the heating furnace 4 but also on the inner surface side of the bottom wall portion 4d of the heating furnace 4, or An auxiliary heating source as auxiliary heating means may be installed on the outer surface of 6.

  Next, a method for forming the glass article 1 described above using the forming apparatus 3 having such a configuration will be described. First, when the glass plate G is placed on the upper surface of the mold 5, the molding space 5x surrounded by the molding recess 5a and the back surface of the glass plate G and the internal space 6a of the chamber 6 are connected via the vent hole 5b. In addition, the exhaust pipe 8 is closed by the open / close valve 9. Since the chamber 6 is entirely located in the internal space 4a of the heating furnace 4, the internal space 6a of the chamber 6 is heated and heated by the hot air in the internal space 4a of the heating furnace 4. Hot air does not escape from the internal space 6 a of the chamber 6 to the outside. In this case, the above heating is performed so that the air pressure in the internal space 6a of the chamber 6 is substantially equal to the air pressure in the internal space 4a of the heating furnace 4, specifically, the air pressure in the surface side space 4x of the glass plate G. It has been broken. Thereby, the pressure difference between the molding space 5x on the back side of the glass plate G communicating with the internal space 6a of the chamber 6 and the surface side space 4x of the glass plate G is substantially zero or extremely small. As a result, in the process of heating the glass plate G placed on the mold 5 so as to cover the molding recess 5a in the internal space 4a of the heating furnace 4, that is, in the process until the suction by the negative pressure is started. The glass plate G is unlikely to be unduely deformed due to the pressure difference. Therefore, it is possible to make it difficult to cause an inappropriate depression deformation until the softened state of the glass plate G is appropriately uniformed over the entire region. Thereafter, the exhaust pipe 8 is opened by the opening / closing valve 9 and a negative pressure starts to act on the molding space 5x from the internal space 6a of the chamber 6 through the vent hole 5b.

  In this case, the detailed temperature distribution of the glass plate G will be described based on FIG. 5A. The supply of heat to the glass plate G in the heating furnace 4 is brought into contact with the glass plate G from the mold 5. In the non-contact portion Gb of the glass plate G with the forming die 5, the temperature (viscosity) is the same as that of the contact portion Ga in the ¼ end region Gx from the end edge, and the remainder 2/4 of the central region Gy is not affected by heat from the contact portion Ga and exhibits a relatively high viscosity. If negative pressure suction is started from such a state, the end region Gx of the non-contact portion Gb of the glass plate G is immediately deformed and tries to fit into the molding concave portion 5a, but the central region Gy is hardly deformed. Therefore, the planar shape is maintained.

  Therefore, after starting the negative pressure suction, as shown in FIG. 5B, when the end region Gx of the glass plate G is deformed until it closely contacts the molding recess 5a, the exhaust pipe 8 is closed by the opening / closing valve 9. The molding space 5x is immediately returned to the original pressure so that the deformation does not proceed, and the negative pressure suction is temporarily stopped. Thereby, the progress of the deformation of the glass plate G is temporarily stopped, and during this time, heat is supplied to the central region of the glass plate G from the mold 5, and the glass plate G is not in contact with the mold 5 at this time. A new end region Gx that is ¼ from the end edge of the portion Gb is regarded as a region equivalent to the temperature of the contact portion Ga. Then, by performing the second negative pressure suction after a predetermined time has elapsed, as shown in FIG. 5C, when the new end region Gx is deformed until it comes into close contact with the molding recess 5a, again, Negative pressure suction is temporarily stopped. By repeating the operation of applying such a negative pressure intermittently, as shown in FIG. 5D, the adhesion of the glass plate G to the molding recess 5a is completed.

  Thus, since the glass plate G is still in a softened state when the adhesion of the glass plate G to the molding recess 5a is completed, the same applies to the case where the heating is stopped and the cooling process is performed after the completion of the adhesion. The negative pressure suction and its temporary stop are continuously repeated, and the operation is continued until the glass plate G is solidified. The operation in this case is performed at the same timing as the last operation before the glass plate G is closely attached to the molding recess 5a. As a result, a glass article 1 having a concave portion 1a having a shape that closely follows the shape of the molded concave portion 5a is obtained. The inner surface of the concave portion 1a maintains the surface properties of the surface of the glass plate G before the start of deformation. As described above, the variation in the thickness with respect to the target thickness or the average thickness becomes extremely small.

  In this case, in the above molding process, even if the glass plate G is not completely in close contact with the bottom surface of the forming recess 5a after the completion of the forming, if the close contact state is the final shape (the shape of the glass article 1). The glass article 1 having the same advantages as described above can be obtained by the same method as described above. It is also possible to deform the glass plate G without bringing it into contact with the molding recess 5a. That is, as shown in FIG. 5 (e), the periphery of the contact portion Ga of the glass plate G with the mold 5 at the start of deformation can be sucked and deformed at least once with a negative pressure while being temporarily interrupted. Thus, it is possible to obtain a glass article 1 (suitable when the recess 1a is shallow) having the same advantages as described above. In this case, both the inner and outer surfaces of the recess 1a maintain the surface properties of the front and back surfaces of the glass plate G before the start of deformation.

  FIG. 6 illustrates a molding apparatus 3 used for producing the glass article 2 according to the second embodiment (and the third embodiment) described above. The molding apparatus 3 is different from the molding apparatus 3 shown in FIG. 4 described above in that a plurality of groove-shaped recesses (groove-shaped recesses extending in a direction perpendicular to the paper surface) having a substantially semicircular cross section are formed on the upper surface of the mold 5. ) Are formed, and the bottom of each molding recess 5a and the internal space 6a of the chamber 6 are communicated with each other through a vent hole 5b. Other configurations are the same as those of the molding apparatus 3 shown in FIG. 5 and the matters described based on the molding device 3.

  Also in the case of the molding apparatus 3 shown in FIG. 6, the pressure in the internal space 6 a of the chamber 6 is substantially equal to the pressure in the surface side space 4 x of the glass plate G with the glass plate G placed on the upper surface of the mold 5. Then, the exhaust pipe 8 is opened by the opening / closing valve 9, and negative pressure is started to act on the molding space 5x from the internal space 6a of the chamber 6 through the vent hole 5b. Then, as shown in FIGS. 7A to 7B, the glass plate G is deformed until the end region Gx of ¼ from the end edge in the non-contact portion Gb with the forming die 5 of the glass plate G comes into close contact with the forming recess 5a. At that time, the negative pressure suction is temporarily stopped so that the molding space 5x returns to the original pressure. Thereafter, a new end region Gx that is ¼ from the end edge of the non-contact portion Gb with the mold 5 of the glass plate G at this point is regarded as a region equivalent to the temperature of the contact portion Ga. By performing the second negative pressure suction, as shown in FIG. 7C, when the new end region Gx is deformed until it comes into close contact with the molding recess 5a, the negative pressure suction is again temporarily performed. To stop. By repeating the operation of applying such a negative pressure intermittently, as shown in FIG. 7D, the adhesion of the glass plate G to the forming recess 5a is completed. In the cooling step after the close contact is completed, the negative pressure suction and the temporary stop are continuously performed in the same manner as described above, and the operation is continued until the glass plate G is solidified, thereby forming the shape of the molding recess 5a. Thus, a glass article 2 having a recess 2a having a shape accurately following the above is obtained.

  In this case, even when the surface of the glass plate G placed on the mold 5 and softened before the start of the negative pressure suction is subjected to surface treatment by sandblasting, the negative pressure suction is as described above. If it is intermittent, non-uniform elongation will not occur on the front surface (and back surface) of the glass plate G, and the uniformity of blasting will not be lost. Therefore, when the glass article 2 after completion of molding is, for example, flat fluorescent lamp glass, the inner surface of the recess 2a of the glass article 2 maintains the surface properties of the surface of the glass plate G before the start of deformation. Therefore, the light diffusion function as a flat fluorescent lamp does not deteriorate. And as already stated, the glass article 2 with the very small variation in thickness with respect to target thickness or average thickness can be obtained.

  As Example 1 of the present invention, a glass article G (display tube glass) 1 shown in FIG. 1 of A4 size is used, using a glass plate G made of 0.82 mm thick soda glass whose front and back surfaces are mirror finished. It was produced in the molding mode shown in 5 (e). In this case, the depth of the concave portion 1a of the glass article 1 is 2.2 mm, the width of the bottom wall portion 1y of the concave portion 1a is 330 mm, and the depth is less than ¼ of the width. Between the start of deformation of G and the completion of deformation, the action of negative pressure was temporarily interrupted once, and the deformation to the target shape was completed by negative pressure suction twice at a depth of 1.1 mm.

  More specifically, after heating the internal space 4a of the heating furnace 4 to the softening temperature (about 700 ° C.) of the glass plate G, the process proceeds to a molding process using negative pressure, and the suction time by a total of two negative pressures is 10 times each. With each second, a one minute break was interposed between each negative pressure draw. In this case, since the bottom of the glass plate G and the mold 5 (molding recess 5a) are not in contact, when the deformation of the glass plate G reaches the target depth, cooling in the heating furnace 4 is started, The glass plate G (glass article 1) was solidified. During this cooling, negative pressure suction for 10 seconds and interruption for 1 minute were continued, and the negative pressure suction process was performed up to about 600 ° C. at which softening deformation of the glass article 1 hardly occurs. In this glass article 1, the bottom surface of the concave portion 1a is not formed by contact with the molding concave portion 5a, but before the deformation starts, the periphery of the contact portion Ga with the molding die 5 of the glass plate G is supplied with heat, Since the other central region is not easily affected by heat, the flatness of the bottom surface of the glass plate G is maintained as it is even during deformation, and as a result, the bottom wall of the recess 1a of the glass article 1 after the completion of molding. 1y reflected the flatness of the glass plate G before deformation.

  In the glass article 1 thus obtained, the inner and outer surfaces of the concave portion 1a maintain smooth mirror surfaces on both the front and back surfaces of the plate glass G before deformation, and the necessary light transmission as a display portion of the display tube glass. I was able to secure the sex. And especially about the site | part corresponded to the inner surface of a display part, the local unevenness | corrugation which becomes an application | coating nonuniformity when a fluorescent substance is apply | coated does not exist. Further, the thickness distribution of the recess 1a of the glass article 1 is within a range of 0.77 mm (minimum value) to 0.81 mm (maximum value) with respect to the target value of 0.80 mm (average value 0.79 mm). In addition, by keeping the variation within ± 5%, it was possible to sufficiently secure the mechanical strength as the glass for the display tube.

  As Example 2 of the present invention, using a glass plate G made of soda glass having a thickness of 1.1 mm that has been subjected to sandblasting with a uniform surface (upper surface), the glass article shown in FIG. (Glass for flat fluorescent lamp) 2 was produced in the molding mode shown in FIGS. In this case, since the width of the non-contact portion Gb with the mold 5 in the plate glass G before the start of deformation is 10 mm, 2.5 mm which is the width of the ¼ end region Gx is set to the first negative pressure. It was made to adhere to forming crevice 5a by suction. And, since the width of the non-contact portion Gb at the time of starting the second negative pressure suction after the temporary interruption is 8.77 mm, in the second negative pressure suction, the quarter width of 2.2 mm is reduced. It was made to adhere to forming crevice 5a. Similarly, the negative pressure suction was repeated, and the adhesion to the molding recess 5a was completed by a total of five negative pressure suction processes. The negative pressure suction conditions in this case were the same as in Example 1, the negative pressure suction time was 10 seconds, the interruption time was 1 minute, and the operation was continued up to about 600 ° C. after completion of the close contact. The thus obtained glass article (flat fluorescent lamp glass) 1 has a uniform light diffusing function because the inner surface of the recess 2a maintains a uniform sandblast surface.

DESCRIPTION OF SYMBOLS 1 Glass article 1a Recessed part 1b Flat plate part 2 Glass article 2a Recessed part (groove-shaped recessed part)
2b Flat plate portion 2c Flat plate portion (flat plate portion in outer peripheral region)
2d peripheral wall 2 'glass article 3 molding device 4 heating furnace 4a heating furnace internal space 4x surface side space 5 molding die 5a molding recess 5x molding space 6 chamber 6a chamber internal space 7 vacuum exhaust device 8 exhaust pipe 9 opening and closing valve G Glass plate (glass material)

Claims (9)

  A glass article in which a recess is formed, wherein at least one surface of the recess is softened, and the free surface of the glass material is solidified, and the thickness of the side wall in the recess from the target thickness A glass article, wherein the variation is within 5%, and the variation from the target wall thickness of the bottom wall portion in the recess is within ± 5%.   A glass article having a recess and a flat plate portion connected to the outer peripheral side on the opening side of the recess, wherein at least one surface of the recess is softened and the free surface of the glass material is solidified. The glass article is characterized in that the variation of the thickness of the concave portion from the target thickness is within 5%, and the variation of the thickness of the flat plate portion from the target thickness is within 5%.   A glass article having a recess and a flat plate portion connected to the outer peripheral side on the opening side of the recess, wherein at least one surface of the recess is softened and the free surface of the glass material is solidified. And the variation of the thickness of the side wall portion in the concave portion from the target thickness is within 5%, the variation of the thickness of the bottom wall portion in the concave portion from the target thickness is within ± 5%, and the flat plate The glass article is characterized in that the variation of the thickness of the shape portion from the target thickness is within 5%.   A glass article in which a recess is formed, wherein at least one surface of the recess is softened, and the free surface of the glass material is solidified, and the thickness of the side wall in the recess is from the average thickness A glass article, wherein the variation is within 5%, and the variation from the average thickness of the thickness of the bottom wall portion in the recess is within ± 5%.   A glass article having a recess and a flat plate portion connected to the outer peripheral side on the opening side of the recess, wherein at least one surface of the recess is softened and the free surface of the glass material is solidified. The glass article is characterized in that the variation from the average thickness of the concave portion is within 5% and the variation from the average thickness of the flat plate portion is within 5%.   A glass article having a recess and a flat plate portion connected to the outer peripheral side on the opening side of the recess, wherein at least one surface of the recess is softened and the free surface of the glass material is solidified. And the variation from the average thickness of the side wall in the recess is within 5%, the variation from the average thickness of the bottom wall in the recess is within ± 5%, and the flat plate The glass article is characterized in that the variation from the average thickness of the thickness of the shaped portion is within 5%.   The glass article according to any one of claims 1 to 6, wherein only one of the recesses is provided, and a flat plate-like portion is connected to the entire outer peripheral side of the recess on the opening side.   A plurality of the concave portions are provided, and the plurality of concave portions are connected to each opening portion via a flat plate-like portion, and the entire outer peripheral side of each opening portion in the region where the plurality of concave portions are formed is a flat plate-like portion. The glass article according to claim 1, wherein the glass article is a glass article.   The glass article according to claim 7 or 8, wherein a peripheral wall portion that rises in a direction opposite to the direction of depression of the concave portion is formed on an outer peripheral edge of the flat plate-like portion in the entire outer peripheral side region.

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