JP2012067015A - Poison bait for pest control - Google Patents
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- JP2012067015A JP2012067015A JP2010210747A JP2010210747A JP2012067015A JP 2012067015 A JP2012067015 A JP 2012067015A JP 2010210747 A JP2010210747 A JP 2010210747A JP 2010210747 A JP2010210747 A JP 2010210747A JP 2012067015 A JP2012067015 A JP 2012067015A
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Abstract
Description
本発明は、アリやゴキブリなどの害虫に対して駆除効果のある害虫駆除用毒餌剤に関する。 The present invention relates to a pest-control poison bait which has a control effect against pests such as ants and cockroaches.
一般に、害虫を餌料で誘引すると共に殺虫成分を体内に取り込ませて駆除するために使用される毒餌剤として、害虫の摂食可能な粉や粒状の餌料を主成分とし、液状または粉末状の殺虫成分を添加し、これらを均一に混合した組成物からなる毒餌剤が知られている。 In general, as a poisonous bait used to attract insect pests with feed and to take in and control insecticides into the body, it is mainly composed of pest-feedable powder or granular feed, and is liquid or powdery insecticide. A poison bait composed of a composition in which components are added and these are uniformly mixed is known.
しかし、従来の組成物からなる毒餌剤は、駆除対象害虫用の餌料と殺虫成分が混在しているものであり、殺虫成分が駆除対象害虫に対して忌避効果を及ぼす場合があり、確実に誘引できる毒餌剤に調製することは困難であった。また、従来の組成物からなる毒餌剤は、これを調製するときに、餌料の誘引効果を妨げないようにするために殺虫成分の種類と添加濃度を制限する必要があるので、殺虫成分本来の効果を充分に発揮する殺虫性に優れた毒餌剤を得ることは困難であった。 However, the poison bait consisting of the conventional composition is a mixture of the feed for the insect pest to be controlled and the insecticidal component, and the insecticidal component may exert a repellent effect on the insect to be controlled, and is surely attracted. It was difficult to prepare a viable bait. In addition, when preparing a poisonous bait comprising a conventional composition, it is necessary to limit the type and concentration of the insecticidal component so as not to interfere with the attracting effect of the feed. It has been difficult to obtain a poison bait excellent in insecticidal properties that exerts its effect sufficiently.
本発明は、殺虫成分が駆除対象害虫に対する忌避効果を及ぼさない毒餌剤とし、誘引性が非常に高く、殺虫成分本来の効果を充分に発揮する殺虫性に優れた害虫駆除用毒餌剤を提供することである。 The present invention provides a poison bait for insecticides that does not exert repellent effects on insect pests to be controlled, has a very high attractiveness, and exhibits the insecticidal component's original effects sufficiently. That is.
上記の課題を解決するため、駆除対象害虫用の餌料を含有する固形状基材の外側に、殺虫剤層を設け、この殺虫剤層の外側には駆除対象害虫に対して誘引性のある誘引性被覆層を設けてなる害虫駆除用毒餌剤としたのである。 In order to solve the above-mentioned problems, an insecticide layer is provided on the outside of the solid base material containing the feed for the insect pest to be controlled, and the insecticide layer has an attracting property to the insect to be controlled on the outside. This is a pest control poison bait provided with a protective coating layer.
本発明の害虫駆除用毒餌剤は、駆除対象害虫の虫体の大きさ、習性、成長段階に応じて種々の態様で施用できるものであり、実施に際して駆除効果の最も高い最適の形態に形成できるものである。 The poison bait for pest control according to the present invention can be applied in various modes according to the size, habit, and growth stage of the pest to be controlled, and can be formed into an optimum form with the highest control effect in practice. Is.
本発明の害虫駆除用毒餌剤の実施形態と一例としては、図１に示すものが挙げられる。すなわち、駆除対象害虫用の餌料を含有する固形状基材１の外側に、液状の殺虫剤を塗布硬化させて殺虫剤層２を設け、この殺虫剤層２の外側には駆除対象害虫に対する誘引性物質を含有する液状の成膜性材料を塗布し硬化させた誘引性被覆層３を設けた錠剤状の害虫駆除用毒餌剤である。
As an embodiment and an example of the pest control poison bait of the present invention, the one shown in FIG. 1 may be mentioned. That is, a liquid insecticide is applied and cured on the outside of the solid substrate 1 containing the feed for the insect pest to be controlled, and an
本発明における駆除対象害虫は、固形状の毒餌剤によって駆除可能な害虫であればよく、虫のライフステージに合わせて効率よく作用させればよく、特に虫の種類は限定されない。しかしながら、駆除が可能な害虫の代表例を挙げれば、ゴキブリ類、アリ類、ハエ類、シロアリ類、ダンゴムシ類、ワラジムシ類などの昆虫の他、ナメクジ類などが挙げられる。 The pest to be controlled in the present invention may be a pest that can be controlled by a solid poison bait, and may be allowed to act efficiently according to the life stage of the insect, and the type of the insect is not particularly limited. However, representative examples of pests that can be controlled include cockroaches, ants, flies, termites, bugs, rotifers, and slugs.
本発明において餌料を含有する固形状基材は、毒餌剤の核（芯材）になるものであり、穀物などの植物種子その他の天然の植物質類もしくは木粉、油粕、故紙などの再生物や産業上の副産物として得られる植物質類、または乾燥肉類、ミールワームのような動物質類などの虫の餌料として周知の物質を含有するものである。そして、餌料以外の成分としては、タルク、珪藻土、結晶セルロース、カオリン、ベントナイト、ゼオライトなどの鉱物質類などが挙げられる。これらを含有する固形状基材は、一括混合して成形することができ、またこの発明の効果を妨げない程度であれば、殺虫成分を含有させることもできる。 In the present invention, the solid base material containing a feed is a core (core material) of poisonous feed, and is a plant seed such as cereal or other natural plant matter or a regenerated material such as wood flour, oil cake or waste paper. Or a plant material obtained as an industrial by-product, or a well-known substance as a food for insects such as dried meats and animals such as mealworms. Examples of components other than feed include mineral substances such as talc, diatomaceous earth, crystalline cellulose, kaolin, bentonite, and zeolite. The solid substrate containing these can be molded by batch mixing and can contain an insecticidal component as long as the effects of the present invention are not hindered.
本発明における殺虫剤層は、クロチアニジンを主成分とし、上記の固形状基材の表面などに対してコーティング可能なものであり、成膜性を有する塗料状の液体または粉体を含む流動物状に調整された殺虫剤を、浸漬、吹き付けなどの方法で塗布して形成される層である。このような成膜性を有する殺虫剤の態様としては、マイクロカプセル化されたクロチアニジンを塗膜形成成分に分散させた殺虫剤を採用することもできる。 The insecticide layer in the present invention has clothianidin as a main component and can be coated on the surface of the solid substrate, etc., and is in the form of a fluid containing a paint-like liquid or powder having film-forming properties. It is a layer formed by applying an insecticide adjusted to 1 by a method such as dipping or spraying. As an aspect of the insecticide having such a film-forming property, an insecticide obtained by dispersing micro-encapsulated clothianidin in a film-forming component can also be used.
クロチアニジンからなる殺虫剤層は、上記した一種以上の殺虫剤を含む層を積み重ねた複数層からなるものであってもよい。また、各層に異なる殺虫成分を含有させて駆除対象の害虫に最適の殺虫剤層とすることが好ましい。このような殺虫剤層の厚さは、対象害虫の性質に応じて設計するものであるが、特に１０μｍ〜２ｍｍの厚みが好ましい。 The insecticide layer made of clothianidin may be composed of a plurality of layers in which layers containing one or more insecticides as described above are stacked. Moreover, it is preferable that each layer contains a different insecticidal component to provide an optimum insecticidal layer for the pest to be controlled. The thickness of such an insecticide layer is designed according to the nature of the target pest, but a thickness of 10 μm to 2 mm is particularly preferable.
本発明に用いる誘引性被覆層は、塗膜（成膜）材料に誘引性物質を配合した組成物からなる層、または誘引性および成膜性を有する材料からなる層のいずれであってもよい。前記の塗膜材料としては、害虫に忌避性のない適度な硬さの成膜性材料であれば良いが、後述する成膜性および誘引性を有する材料を用いることも好ましく、特に害虫が好んでかじりとったり喫食したりするような材料を採用することが好ましい。誘引性被覆層の厚さは、対象害虫の性質に応じて設計するものであるが、特に１０μｍ〜２ｍｍの厚みが好ましい。 The attractive coating layer used in the present invention may be either a layer made of a composition in which an attractive substance is blended with a coating film (film formation) material, or a layer made of a material having attractiveness and film-forming properties. . The coating material may be a film-forming material having an appropriate hardness that does not repel pests, but it is also preferable to use a material having film-forming properties and attracting properties described below, and pests are particularly preferred. It is preferable to employ a material that can be galling or eating. The thickness of the attractive coating layer is designed according to the nature of the target pest, but a thickness of 10 μm to 2 mm is particularly preferable.
本発明の誘引性物質は、駆除対象となる害虫に応じて適宜に区別して採用されるものであり、害虫（ａ）〜（ｆ）と誘引性物質との好適な対応例は、以下の通りである。 The attracting substance of the present invention is appropriately selected according to the pest to be controlled, and suitable examples of correspondence between the pests (a) to (f) and the attracting substance are as follows. It is.
（ａ）ゴキブリ類またはアリ類に対する誘引物質例・グルコース、マルトース、ガラクトースなどの多糖類・魚類、甲殻類（エビなど）、昆虫類などの粉砕物またはそれらの抽出物・植物油、動物油などの油脂類・粉乳、チーズなどの乳製品・各種のゴキブリ類やアリ類の誘引性フェロモン、糞またはその抽出物。 （ｂ）ハエ類に対する誘引物質例・上記（ａ）に加えて、腐敗もしくは腐熟した動植物質またはその抽出物。 （ｃ）シロアリ類に対する誘引物質例・木粉またはその抽出物・虫体、巣またはそれらの抽出物・不飽和ジテルペン系炭化水素。（ｄ）ダンゴ虫類またはワラジムシ類に対する誘引物質例・腐敗もしくは腐熟した植物質またはその抽出物・植物粉またはその抽出物。 （ｅ）
ナメクジ類に対する誘引物質例・澱粉、グルコースなどの多糖類・腐敗もしくは腐熟した植物質またはその抽出物・ビールまたはビール酵母。
(A) Examples of attractants for cockroaches or ants ・ Polysaccharides such as glucose, maltose, and galactose ・ Pulverized products such as fish, crustaceans (such as shrimp), insects, etc., or extracts and oils such as vegetable oil and animal oil Dairy products such as milk, milk powder, cheese, various cockroaches and ants, attracting pheromones, feces or their extracts. (B) Examples of attractants for flies: In addition to the above (a), spoiled or ripened animal or plant material or extract thereof. (C) Examples of attractants for termites: wood flour or extracts thereof, insect bodies, nests or extracts thereof, unsaturated diterpene hydrocarbons. (D) Examples of attractants for Dango insects or rotifers: rotted or matured plant matter or extracts thereof, plant powders or extracts thereof. (E)
Examples of attractants for slugs: polysaccharides such as starch and glucose, spoiled or ripened plant materials or extracts thereof, beer or brewer's yeast.
また、誘引性および成膜性を有する材料としては、以下の材料を例示できる。(1) 二糖類または多糖類：グァーガム、ローカストビーンガム、カラギーナン、アルギン酸ソーダ、寒天、ペクチン、デンプン、ショ糖、還元糖など、(2) 天然粘質物：ザンサンガム、ゼラチン、カゼイン、シェラックなど、(3) セルロース誘導体：カルボキシメチルセルロース、ヒドロキシプロピルセルロースなど、(4) 油脂類（油脂成分を含む）：牛脂硬化油、魚硬化油、ステアリン酸など。 Moreover, the following materials can be illustrated as a material which has attractive property and film-forming property. (1) Disaccharides or polysaccharides: guar gum, locust bean gum, carrageenan, sodium alginate, agar, pectin, starch, sucrose, reducing sugar, etc. (2) natural mucilage: xanthan gum, gelatin, casein, shellac, etc. 3) Cellulose derivatives: carboxymethyl cellulose, hydroxypropyl cellulose, etc. (4) Fats and oils (including fat and oil components): beef tallow hardened oil, fish hardened oil, stearic acid, etc.
以上のような材料から形成される毒餌剤の形状は、固形状基材の形状によってほぼ決定されるが、例えば粒状、棒状または繊維状その他の周知形状を採用することもできる。また、本発明において製造できる毒餌剤の大きさは、駆除対象害虫の大きさや摂食量に応じて調整するため、特に限定されないが、直径１ｍｍ〜５００ｍｍで、重量２０ｇ以下のものが特に好ましい。 Although the shape of the poison bait formed from the above materials is substantially determined by the shape of the solid substrate, for example, a well-known shape such as a granular shape, a rod shape, a fiber shape, or the like can be adopted. In addition, the size of the poisonous bait that can be produced in the present invention is not particularly limited because it is adjusted according to the size of the insect pest to be controlled and the amount of food intake.
（実施例１、顆粒剤の製造例）
蛹粉３０部（部は重量部、以下同じ）と粉糖５０部、カルボキシメチルセルロースナトリウム１．３部、チアベンダゾール０．２部、コーンスターチ８部、水適量を混合した後、直径１ｍｍで湿式造粒して顆粒を得た。これを乾燥の後、クロチアニジン０．１部、粉糖１部、コーンスターチ１．５部、米糠油３部を混合した粘性液を、ブレンダーを用いてコーティングし、さらに粉糖０．８部とコーンスターチ１．７部、水２．４部を混合した粘性液をブレンダーにてコーティングし、直径約１．２ｍｍのアリ用毒餌剤を得た。
(Example 1, granule production example)
After mixing 30 parts of starch powder (parts are parts by weight, the same applies hereinafter), 50 parts of powdered sugar, 1.3 parts of sodium carboxymethylcellulose, 0.2 parts of thiabendazole, 8 parts of corn starch and an appropriate amount of water, wet granulation with a diameter of 1 mm To obtain granules. After drying this, a viscous liquid prepared by mixing 0.1 part of clothianidin, 1 part of powdered sugar, 1.5 parts of corn starch and 3 parts of rice bran oil was coated using a blender, and further 0.8 parts of powdered sugar and corn starch A viscous liquid in which 1.7 parts and 2.4 parts of water were mixed was coated with a blender to obtain an ant poison bait having a diameter of about 1.2 mm.
（実施例２、ゴキブリ用錠剤の製造例）
デンプン４５部と蛹粉１５部、カルボキシメチルセルロースナトリウム１部、クロチアニジン０．５部、エタノール５部、水５部を混合し、押し出し成形機により加圧成形して直径１．５ｃｍの錠剤を得た。ここにエタノール５部に溶解したシフェノトリン２部とペクチン１部、温水５部の混合物を糖衣機を用いてコーティングし、乾燥の後、麦芽還元糖１５部と硼砂５．５部、水５部を溶解して糖衣機を用いてさらにコーティングし、１錠約０．８ｇのゴキブリ用毒餌剤を得た。
(Example 2, Example of manufacturing a cockroach tablet)
45 parts of starch, 15 parts of starch powder, 1 part of sodium carboxymethylcellulose, 0.5 part of clothianidin, 5 parts of ethanol and 5 parts of water were mixed and pressure-molded with an extruder to obtain a tablet having a diameter of 1.5 cm. . Here, a mixture of 2 parts of siphenothrin dissolved in 5 parts of ethanol, 1 part of pectin and 5 parts of warm water was coated using a sugar coating machine, and after drying, 15 parts of malt reducing sugar, 5.5 parts of borax, 5 parts of water Was dissolved and further coated using a sugar coating machine to obtain about 0.8 g of a cockroach bait for a cockroach.
（実施例３、アリ用毒餌剤の製造例）
粟種子７０部に、加温溶解したクロチアニジン０．５部と牛脂硬化油２部の混合物を糖衣機を用いてコーティングし、これにピリプロキシフェン０．１部とショ糖グリセリンエステル０．２部、ショ糖２０部、水７．２部の溶解液をさらにコーティングし、乾燥後さらに粉糖０．８部とコーンスターチ１．７部、水２．４部を混合した粘性液をブレンダーにてコーティングし、直径約２ｍｍのアリ用毒餌剤を得た。
(Example 3, production example of poison bait for ants)
70 parts of persimmon seeds are coated with a mixture of 0.5 parts of clothianidin dissolved by heating and 2 parts of beef tallow oil using a sugar coating machine, and 0.1 parts of pyriproxyfen and 0.2 parts of sucrose glycerin ester are coated on this. Further, a solution of 20 parts of sucrose and 7.2 parts of water was further coated, and after drying, a viscous liquid obtained by mixing 0.8 part of powdered sugar, 1.7 parts of corn starch, and 2.4 parts of water was coated with a blender. An ant poison bait having a diameter of about 2 mm was obtained.
（実施例4、シロアリ用毒餌剤の製造例）
約５ｍｍのセルロースファイバー５０部に、クロチアニジンマイクロカプセル１０部とカルボキシメチルセルロースナトリウム０．２部を混合した粘稠液を糖衣機でコーティングし、木粉と加温溶解したゼラチンの混合物をさらにコーティングして粒状の剤を塊化し、１片約５ｃｍのシロアリ用毒餌剤を得た。
(Example 4, production example of termite poison bait)
A viscous liquid prepared by mixing 10 parts of clothianidin microcapsules and 0.2 part of sodium carboxymethylcellulose is coated with a sugar coating machine on 50 parts of about 5 mm cellulose fiber, and further coated with a mixture of wood flour and gelatin dissolved by heating. The granular agent was agglomerated to obtain a termite poison bait of about 5 cm.
（比較例１、アリ用毒餌剤の製造例）
蛹粉３０部と粉糖５０部、カルボキシメチルセルロースナトリウム１．３部、チアベンダゾール０．２部、コーンスターチ８部、水適量を混合した後、直径１ｍｍで湿式造粒して顆粒を得た。これを乾燥後、クロチアニジン０．１部と粉糖２部、コーンスターチ３部、米糠油５．４部を混合した粘性液を、ブレンダーを用いてコーティングし直径約１．２ｍｍのアリ用毒餌剤を得た。
(Comparative example 1, production example of poison bait for ants)
After mixing 30 parts of koji powder and 50 parts of powdered sugar, 1.3 parts of sodium carboxymethylcellulose, 0.2 part of thiabendazole, 8 parts of corn starch and an appropriate amount of water, wet granulation was performed with a diameter of 1 mm to obtain granules. After drying this, a viscous liquid in which 0.1 part of clothianidin, 2 parts of powdered sugar, 3 parts of corn starch and 5.4 parts of rice bran oil were mixed was coated with a blender to prepare a poisonous bait for ants having a diameter of about 1.2 mm. Obtained.
（比較例２、ゴキブリ用錠剤の製造例）
デンプン４５部と蛹粉１５部、カルボキシメチルセルロースナトリウム１部、クロチアニジン０．５部、シフェノトリン２部、麦芽還元糖１５部と硼砂５．５部、エタノール５部、水５部を混合し、押し出し成形機により加圧成形して１錠約０．８ｇのゴキブリ用毒餌剤を得た。
(Comparative Example 2, production example of cockroach tablet)
Mix 45 parts starch, 15 parts starch, 1 part sodium carboxymethylcellulose, 0.5 parts clothianidin, 2 parts ciphenothrin, 15 parts malt reducing sugar, 5.5 parts borax, 5 parts ethanol, 5 parts water and extrude. It was pressure-molded with a molding machine to obtain about 0.8 g of a cockroach poison bait.
（駆除効果試験１）
図２に示す飼育容器４の一側に水を含ませた砂山６を配置すると共に、このような２つの容器４内に、予めトビイロシワアリ３０匹をそれぞれ放して自然な行動状態になるまで所定期間飼育した。そして、１つの容器４内にペトリ皿に入れた実施例１を置くと共に他の容器内に比較例１の毒餌剤５を置き、これらのアリが１０分間に毒餌剤を運搬した延べ虫数および５時間〜２４時間経過後に致死したアリの固体数を計測し、これらの係数値を表１に示した。
(Extermination effect test 1)
A sand pile 6 filled with water is arranged on one side of the breeding container 4 shown in FIG. 2 and a predetermined period of time is set until a natural behavioral state is reached by releasing 30 large white whales in each of these two containers 4 in advance. Raised. Then, Example 1 placed in a Petri dish is placed in one container 4 and the poison bait 5 of Comparative Example 1 is placed in another container, and these ants carry the poison bait for 10 minutes and The number of solids of ants killed after the lapse of 5 to 24 hours was measured, and these coefficient values are shown in Table 1.
（駆除効果試験２）
２つの飼育容器内に、予めチャバネゴキブリ５０匹をそれぞれ放して自然な行動状態になるまで所定期間飼育した。そして、２つの容器４内にそれぞれペトリ皿に入れた実施例２または比較例２の毒餌剤を置き、チャバネゴキブリが１０分間にペトリ皿に進入した延べ虫数および５時間〜２４時間経過後に致死した固体数を計測し、これらの係数値を表２に示した。
(Extermination effect test 2)
In the two rearing containers, 50 German cockroaches were released in advance and reared for a predetermined period until they were in a natural behavioral state. Then, the poison bait of Example 2 or Comparative Example 2 placed in the Petri dish was placed in the two containers 4, respectively, and the number of total insects that the German cockroach entered the Petri dish in 10 minutes and died after 5-24 hours. The number of solids was measured, and these coefficient values are shown in Table 2.
本発明により、殺虫成分が駆除対象害虫に対する忌避効果を及ぼさない毒餌剤とし、誘引性が高く、殺虫成分本来の効果を充分に発揮する殺虫性に優れた害虫駆除用毒餌剤を提供することができる。 According to the present invention, it is possible to provide a poison bait for insect pest control, which has a high attractability and exhibits the original effect of the insecticide component, as a poison bait that does not exert repellent effect on the insect pest to be controlled. it can.
１ 固形状基材
２ 殺虫剤層
３ 誘引性被覆層
４ 飼育容器
５ 毒餌剤
６ 砂山
DESCRIPTION OF SYMBOLS 1
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015163599A (en) * | 2014-01-28 | 2015-09-10 | ソマール株式会社 | External preparation for skin or cosmetic additive |
| US9375001B1 (en) * | 2012-04-23 | 2016-06-28 | Wellmark International | Granular fly bait |
| JP2020158442A (en) * | 2019-03-27 | 2020-10-01 | フマキラー株式会社 | Fire ant poison bait |
| JP2023178353A (en) * | 2019-02-25 | 2023-12-14 | 住化エンバイロメンタルサイエンス株式会社 | Ant attractant and ant poison bait |
-
2010
- 2010-09-21 JP JP2010210747A patent/JP2012067015A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9375001B1 (en) * | 2012-04-23 | 2016-06-28 | Wellmark International | Granular fly bait |
| JP2015163599A (en) * | 2014-01-28 | 2015-09-10 | ソマール株式会社 | External preparation for skin or cosmetic additive |
| JP2023178353A (en) * | 2019-02-25 | 2023-12-14 | 住化エンバイロメンタルサイエンス株式会社 | Ant attractant and ant poison bait |
| JP2020158442A (en) * | 2019-03-27 | 2020-10-01 | フマキラー株式会社 | Fire ant poison bait |
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