JP2012041610A - Steel sheet for hot pressing, manufacturing method therefor and method for manufacturing hot press member - Google Patents

Steel sheet for hot pressing, manufacturing method therefor and method for manufacturing hot press member Download PDF

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JP2012041610A
JP2012041610A JP2010184840A JP2010184840A JP2012041610A JP 2012041610 A JP2012041610 A JP 2012041610A JP 2010184840 A JP2010184840 A JP 2010184840A JP 2010184840 A JP2010184840 A JP 2010184840A JP 2012041610 A JP2012041610 A JP 2012041610A
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steel sheet
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plating layer
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JP5672849B2 (en
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Seiji Nakajima
清次 中島
Hiroki Nakamaru
裕樹 中丸
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JFE Steel Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a steel sheet for hot pressing, manufacturing method therefor and method for manufacturing hot press member, which can stably obtain the hot press member having excellent adhesiveness and corrosion resistance after coating even when temperature raising speed is increased or holding time is shortened during heating before hot pressing.SOLUTION: There is provided the steel sheet for hot pressing containing: Al-Fe alloy plated layer containing, by mass, Fe, 25-90% and Si, less than 3%, the balance Al with inevitable impurities, a total content of Fe and Al of 97% or more, on a surface of the steel sheet, and deposition amount per one side of the steel sheet of 10-200g/m; and an Al layer having the deposition amount per one side of the steel sheet of 5g/mor less on the Al-Fe alloy plated layer.

Description

本発明は、自動車の足廻り部材や車体構造部材などを熱間プレスで製造するのに適した熱間プレス用鋼板、その製造方法およびそれを用いた熱間プレス部材の製造方法に関する。   The present invention relates to a steel sheet for hot pressing suitable for manufacturing an automobile underbody member, a vehicle body structural member, and the like by hot pressing, a manufacturing method thereof, and a manufacturing method of a hot pressing member using the same.

従来から、自動車の足廻り部材や車体構造部材などの多くは、所定の強度を有する鋼板をプレス加工して製造されている。近年、地球環境の保全という観点から、自動車車体の軽量化が熱望され、使用する鋼板を高強度化して、その板厚を低減する努力が続けられている。しかし、鋼板の高強度化に伴ってそのプレス加工性が低下するため、鋼板を所望の部材形状に加工することが困難になる場合が多くなっている。   2. Description of the Related Art Conventionally, many undercarriage members and body structure members of automobiles are manufactured by pressing a steel plate having a predetermined strength. In recent years, from the viewpoint of the preservation of the global environment, there has been a strong desire to reduce the weight of automobile bodies, and efforts have been made to increase the strength of steel sheets to be used and to reduce their thickness. However, as the strength of the steel plate increases, the press workability decreases, and it is often difficult to process the steel plate into a desired member shape.

そのため、特許文献1には、ダイとパンチからなる金型を用いて加熱された鋼板を加工すると同時に急冷することにより加工の容易化と高強度化の両立を可能にした熱間プレスと呼ばれる加工技術が提案されている。しかし、この熱間プレスでは、熱間プレス前に鋼板を950℃前後の高い温度に加熱するため、鋼板表面にはスケール(鉄酸化物)が生成し、そのスケールが熱間プレス時に剥離して、金型を損傷させる、または熱間プレス後の部材表面を損傷させるという問題がある。また、部材表面に残ったスケールは、外観不良や、塗装密着性の低下、塗装後耐食性の低下の原因にもなる。このため、通常は酸洗やショットブラストなどの処理を行って部材表面のスケールは除去されるが、これは製造工程を複雑にし、生産性の低下を招く。   Therefore, Patent Document 1 describes a process called a hot press that enables both easy processing and high strength by simultaneously processing a heated steel sheet using a die and punch die and simultaneously cooling it. Technology has been proposed. However, in this hot press, the steel plate is heated to a high temperature of around 950 ° C before hot pressing, so scale (iron oxide) is generated on the surface of the steel plate and the scale peels off during hot pressing. There is a problem that the mold is damaged or the surface of the member after hot pressing is damaged. In addition, the scale remaining on the surface of the member may cause poor appearance, poor paint adhesion, and poor corrosion resistance after painting. For this reason, the scale on the surface of the member is usually removed by processing such as pickling or shot blasting, but this complicates the manufacturing process and causes a decrease in productivity.

このようなことから、熱間プレス前の加熱時にスケールの生成を抑制するとともに、熱間プレス後の部材の塗装密着性や塗装後耐食性を向上させることが可能な熱間プレス技術が要望され、表面にめっき層などの皮膜を設けた鋼板やそれを用いた熱間プレス方法が提案されている。例えば、特許文献2には、熱間プレス後に高い強度と優れた耐食性の得られるAlまたはAl合金を被覆した熱間プレス用鋼板(熱延鋼板および冷延鋼板)が開示されている。また、特許文献3には、Alを主体とした金属のめっき鋼板を熱間プレス前に加熱するに際し、(Tm-200)〜Tm℃(ただし、Tmはめっき金属の融点)の温度領域で5秒以上加熱することにより、熱間プレス後に美麗な外観と優れた耐食性の得られる熱間プレス(加熱成形)用鋼板の加熱方法が開示されている。   Therefore, there is a demand for hot press technology that can suppress the generation of scale during heating before hot pressing, and can improve the coating adhesion and post-coating corrosion resistance of members after hot pressing, A steel sheet having a coating such as a plating layer on the surface and a hot pressing method using the steel sheet have been proposed. For example, Patent Document 2 discloses a steel sheet for hot pressing (hot-rolled steel sheet and cold-rolled steel sheet) coated with Al or an Al alloy that provides high strength and excellent corrosion resistance after hot pressing. Further, in Patent Document 3, when heating a plated steel sheet of metal mainly composed of Al before hot pressing, the temperature ranges from (Tm-200) to Tm ° C (where Tm is the melting point of the plated metal). A method of heating a steel sheet for hot pressing (heat forming) is disclosed in which a beautiful appearance and excellent corrosion resistance are obtained after heating for 2 seconds or more.

一方、昨今の熱間プレス部材の製造方法においては、生産性の向上、特に熱間プレス前の加熱時における昇温速度の上昇や保持時間の短縮に対する要望が高まっている。   On the other hand, in recent methods for producing a hot press member, there is an increasing demand for improvement in productivity, in particular, an increase in temperature rise rate and a reduction in holding time during heating before hot pressing.

英国特許第1490535号公報GB 1490535 特許第3931251号公報Japanese Patent No. 3931251 特開2003-27203号公報Japanese Patent Laid-Open No. 2003-27203

しかしながら、特許文献2に記載のAlまたはAl合金を被覆した熱間プレス用鋼板を用い、昇温速度の上昇や保持時間の短縮を図ると、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材を得ることが困難になる。また、特許文献3に記載の熱間プレス用鋼板の加熱方法においても、昇温速度を上昇すると、融点から融点より200℃以下の温度範囲における昇温速度制御を精度よく行えず、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材を安定して得ることが困難になる。   However, when using a hot-press steel sheet coated with Al or Al alloy described in Patent Document 2 and increasing the heating rate and shortening the holding time, it is possible to achieve hot coating with excellent coating adhesion and corrosion resistance after coating. It becomes difficult to obtain a press member. Also, in the heating method of the steel sheet for hot press described in Patent Document 3, when the temperature increase rate is increased, the temperature increase rate control in the temperature range from the melting point to 200 ° C. below the melting point cannot be performed accurately, and excellent coating is achieved. It becomes difficult to stably obtain a hot press member having adhesion and post-coating corrosion resistance.

本発明は、熱間プレス前の加熱時に昇温速度の上昇や保持時間の短縮を図っても、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られる熱間プレス用鋼板、その製造方法およびそれを用いた熱間プレス部材の製造方法を提供することを目的とする。   The present invention is a hot press capable of stably obtaining a hot press member having excellent coating adhesion and post-coating corrosion resistance even if the temperature rising rate is increased or the holding time is shortened during heating before hot pressing. It aims at providing the manufacturing method of the hot-pressing member using the steel plate for steel, its manufacturing method, and it.

本発明者らは、上記の目的とする熱間プレス用鋼板について鋭意検討を行った結果、予め、質量%で、Fe:25〜90%およびSi:3%以下を、またはさらにCr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含み、残部がAlおよび不可避的不純物からなり、かつFeとAlの合計含有率が97%以上のAl-Fe合金めっき層と5g/m2以下のAl層を有する熱間プレス用鋼板を用いることにより、熱間プレス前の加熱時に昇温速度の上昇や保持時間の短縮を図っても、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られることを見出した。 As a result of intensive studies on the steel sheet for hot pressing for the above-mentioned purpose, the present inventors have previously made mass%, Fe: 25 to 90% and Si: 3% or less, or further Cr: 3% Hereinafter, Al: Fe containing at least one selected from Mg: 3% or less and Zn: 3% or less, the balance being Al and inevitable impurities, and the total content of Fe and Al being 97% or more By using a steel sheet for hot pressing with an alloy plating layer and an Al layer of 5 g / m 2 or less, excellent coating adhesion is achieved even when the heating rate is increased and the holding time is shortened during heating before hot pressing. It was found that a hot-pressed member having good properties and corrosion resistance after coating can be obtained stably.

本発明は、このような知見に基づきなされたもので、鋼板表面に、質量%で、Fe:25〜90%およびSi:3%以下を含み、残部がAlおよび不可避的不純物からなり、かつFeとAlの合計含有率が97%以上であり、鋼板片面当たりの付着量が10〜200g/m2のAl-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を有することを特徴とする熱間プレス用鋼板を提供する。このAl-Fe合金めっき層が、さらに、質量%で、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含むことが好ましい。 The present invention has been made on the basis of such knowledge, and the steel sheet surface contains, in mass%, Fe: 25 to 90% and Si: 3% or less, the balance is made of Al and inevitable impurities, and Fe. Al-Fe alloy plating layer with a total content of 97% or more of Al and Al, and the adhesion amount per one side of the steel sheet of 10 to 200 g / m 2 , and the adhesion amount per one side of the steel sheet on the Al-Fe alloy plating layer The present invention provides a steel sheet for hot pressing characterized by having an Al layer of 5 g / m 2 or less. The Al—Fe alloy plating layer preferably further contains at least one selected from Cr: 3% or less, Mg: 3% or less, and Zn: 3% or less by mass%.

本発明の熱間プレス用鋼板におけるめっき層の下地鋼板としては、質量%で、C:0.15〜0.5%、Si:0.05〜2.0%、Mn:0.5〜3%、P:0.1%以下、S:0.05%以下、Al:0.1%以下、N:0.01%以下を含有し、残部がFeおよび不可避的不純物からなる成分組成を有する鋼板を用いることができる。この下地鋼板には、さらに、質量%で、Cr:0.01〜1%、Ti:0.2%以下、B:0.0005〜0.08%のうちから選ばれた少なくとも一種やSb:0.003〜0.03%が、個別にあるいは同時に含有されることが好ましい。   As the base steel sheet of the plating layer in the hot-press steel sheet of the present invention, in mass%, C: 0.15-0.5%, Si: 0.05-2.0%, Mn: 0.5-3%, P: 0.1% or less, S: A steel plate containing 0.05% or less, Al: 0.1% or less, and N: 0.01% or less, with the balance being composed of Fe and inevitable impurities can be used. In this base steel sheet, in addition, by mass%, Cr: 0.01 to 1%, Ti: 0.2% or less, B: 0.0005 to 0.08% or Sb: 0.003 to 0.03% individually Or it is preferable to contain simultaneously.

本発明の熱間プレス用鋼板は、鋼板を、質量%で、Al:80%以上およびSi:3%以下を含有するAl系めっき浴に浸漬後、ガスワイピングして、鋼板片面当たりの付着量が10〜200g/m2のAl-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を形成する方法により製造できる。このAl系めっき浴に、さらに、質量%で、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種が含有されることが好ましい。このとき、鋼板としては、上記の成分組成を有する鋼板を用いることができる。 The steel sheet for hot pressing of the present invention is a steel sheet immersed in an Al-based plating bath containing, by mass%, Al: 80% or more and Si: 3% or less, then gas wiping, and the adhesion amount per one side of the steel sheet There can be produced the Al-Fe alloy plating layer 10 to 200 g / m 2, by the method the amount of deposition per steel sheet one surface to the Al-Fe alloy plating layer to form a 5 g / m 2 or less of Al layer. This Al-based plating bath preferably further contains at least one selected from Cr: 3% or less, Mg: 3% or less, and Zn: 3% or less in mass%. At this time, a steel plate having the above component composition can be used as the steel plate.

本発明は、また、上記のような熱間プレス用鋼板を、Ac3変態点〜1000℃の温度範囲に加熱後、熱間プレスすることを特徴とする熱間プレス部材の製造方法を提供する。 The present invention also provides a method for producing a hot press member, characterized in that the hot press steel plate as described above is hot pressed after being heated to a temperature range of Ac 3 transformation point to 1000 ° C. .

本発明により、熱間プレス前の加熱時に昇温速度の上昇や保持時間の短縮を行っても、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られる熱間プレス用鋼板を提供できるようになった。本発明の熱間プレス用鋼板を用い、本発明の熱間プレス部材の製造方法で製造した熱間プレス部材は、自動車の足廻り部材や車体構造部材に好適である。   According to the present invention, a hot press capable of stably obtaining a hot press member having excellent coating adhesion and post-coating corrosion resistance even when the temperature rising rate is increased or the holding time is shortened during heating before hot pressing. Steel plate can be provided. The hot press member manufactured by the method for manufacturing a hot press member of the present invention using the hot press steel plate of the present invention is suitable for an automobile undercarriage member or a vehicle body structure member.

本発明において、成分の含有率を表す「%」は、特に断らない限り「質量%」を意味する。   In the present invention, “%” representing the component content means “% by mass” unless otherwise specified.

1) 熱間プレス用鋼板
1-1) Al-Fe合金めっき層
特許文献3に記載されているように、Alを主体とした金属のめっき鋼板を用いて美麗な外観と優れた耐食性を有する熱間プレス部材を製造するには、熱間プレス前にめっき層をその表面まで融点の高いAl-Fe合金にすることが効果的である。しかし、上述したように、熱間プレス前の加熱時にめっき層のAl-Fe合金化を図る場合は、生産性の向上を目的に昇温速度の上昇や保持時間の短縮を行うと、めっき層のAl-Fe合金化が十分に図れず、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材を安定して得ることが困難になる。
1) Hot press steel sheet
1-1) Al-Fe alloy plating layer As described in Patent Document 3, a hot-pressed member with a beautiful appearance and excellent corrosion resistance is produced using a plated steel sheet made mainly of Al. It is effective to make the plating layer an Al—Fe alloy having a high melting point up to the surface before hot pressing. However, as mentioned above, when the plating layer is made into an Al-Fe alloy during heating before hot pressing, if the temperature rise rate is increased or the holding time is shortened for the purpose of improving productivity, the plating layer As a result, it is difficult to obtain a hot press member having excellent coating adhesion and post-coating corrosion resistance.

そこで、本発明では、素材である熱間プレス用鋼板において、表面までAl-Fe合金化されためっき層を形成し、熱間プレス前の加熱時の昇温速度や保持時間に依存することなくAl-Fe合金めっき層の形成された状態で熱間プレスが行えるようにしている。それゆえ、加熱時に昇温速度の上昇や保持時間の短縮を行っても、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られることになる。   Therefore, in the present invention, in the hot-press steel plate that is the material, a plating layer that is alloyed to Al-Fe is formed up to the surface, and it does not depend on the temperature rising rate or holding time during heating before hot pressing. Hot pressing can be performed with the Al-Fe alloy plating layer formed. Therefore, even if the heating rate is increased or the holding time is shortened during heating, a hot press member having excellent coating adhesion and corrosion resistance after coating can be obtained stably.

本発明におけるAl-Fe合金めっき層では、Al-Fe合金めっき層の組成が、Fe:25〜90%およびSi:3%以下を含み、残部がAlおよび不可避的不純物からなり、かつFeとAlの合計含有率が97%以上であり、その鋼板片面当たりの付着量が10〜200g/m2である必要がある。Al-Fe合金めっき層のFe含有率が25%未満では、Al-Fe合金めっき層表面にFeが存在せず、表面が平滑化するため塗装密着性が劣化するのみならず、化成処理皮膜も十分に形成しないため塗装後耐食性が劣化し、90%を超えると、Alによる耐食性向上効果が著しく減少するため、塗装後耐食性が不良となる。したがって、Al-Fe合金めっき層のFe含有率は25〜90%とする。また、Al-Fe合金めっき層のSi含有率が3%を超えると、AlとFeの合金化反応が抑制されることにより、付着量が10g/m2以上のAl-Fe合金めっき層が形成せず、塗装後耐食性が不良となるため、Al-Fe合金めっき層のSi含有率は3%以下とする。さらに、FeとAlの合計含有率が97%未満では、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られないため、FeとAlの合計含有率は97%以上とする。また、Al-Fe合金めっき層の鋼板片面当たりの付着量が10g/m2未満では、塗装後耐食性が劣化し、200g/m2を超えると、効果が飽和し、コスト高を招く。したがって、めっき層の付着量は10〜200g/m2とする。 In the Al-Fe alloy plating layer in the present invention, the composition of the Al-Fe alloy plating layer includes Fe: 25 to 90% and Si: 3% or less, the balance is made of Al and inevitable impurities, and Fe and Al The total content of is not less than 97%, and the amount of adhesion per one surface of the steel sheet needs to be 10 to 200 g / m 2 . When the Fe content of the Al-Fe alloy plating layer is less than 25%, there is no Fe on the surface of the Al-Fe alloy plating layer, and the surface is smoothed. If it is not formed sufficiently, the corrosion resistance after coating deteriorates. If it exceeds 90%, the effect of improving the corrosion resistance by Al is remarkably reduced, so that the corrosion resistance after coating becomes poor. Therefore, the Fe content of the Al—Fe alloy plating layer is 25 to 90%. In addition, when the Si content of the Al-Fe alloy plating layer exceeds 3%, the Al-Fe alloy plating layer with an adhesion amount of 10 g / m 2 or more is formed by suppressing the alloying reaction between Al and Fe. Therefore, the corrosion resistance after coating becomes poor, so the Si content of the Al-Fe alloy plating layer is 3% or less. Furthermore, if the total content of Fe and Al is less than 97%, a hot press member having excellent coating adhesion and corrosion resistance after coating cannot be stably obtained, so the total content of Fe and Al is 97% or more. And Moreover, if the adhesion amount per one side of the steel sheet of the Al—Fe alloy plating layer is less than 10 g / m 2 , the corrosion resistance after coating deteriorates, and if it exceeds 200 g / m 2 , the effect is saturated and the cost increases. Therefore, the adhesion amount of the plating layer is 10 to 200 g / m 2 .

また、本発明におけるAl-Fe合金めっき層が、さらに、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含むことが好ましい。この理由は、Al-Fe合金めっき層が、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含むことにより、塗装後耐食性がより一層向上するからである。   Moreover, it is preferable that the Al—Fe alloy plating layer in the present invention further contains at least one selected from Cr: 3% or less, Mg: 3% or less, and Zn: 3% or less. The reason for this is that the Al-Fe alloy plating layer contains at least one selected from Cr: 3% or less, Mg: 3% or less, Zn: 3% or less, thereby further improving post-coating corrosion resistance. Because.

1-2) Al層
本発明では、上記したAl-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を有する。Al層の付着量が5g/m2超では、優れた塗装密着性や塗装後耐食性を有する熱間プレス部材が安定して得られないため、Al層の付着量は5g/m2以下とする。このAl層には上記したAl-Fe合金めっき層のAl以外の成分が固溶していてもよい。
1-2) Al layer In the present invention, an Al layer having an adhesion amount per one surface of a steel sheet of 5 g / m 2 or less is formed on the above-described Al—Fe alloy plating layer. If the adhesion amount of the Al layer exceeds 5 g / m 2 , a hot press member having excellent coating adhesion and post-coating corrosion resistance cannot be stably obtained. Therefore, the adhesion amount of the Al layer should be 5 g / m 2 or less. . Components other than Al of the Al—Fe alloy plating layer described above may be dissolved in the Al layer.

1-3) 下地鋼板
980MPa以上の強度を有する熱間プレス部材を得るには、めっき層の下地鋼板として、例えば、C:0.15〜0.5%、Si:0.05〜2.0%、Mn:0.5〜3%、P:0.1%以下、S:0.05%以下、Al:0.1%以下、N:0.01%以下を含有し、残部がFeおよび不可避的不純物からなる成分組成を有する鋼板を用いることができる。各成分元素の限定理由を、以下に説明する。
1-3) Base steel plate
In order to obtain a hot pressed member having a strength of 980 MPa or more, for example, C: 0.15-0.5%, Si: 0.05-2.0%, Mn: 0.5-3%, P: 0.1% or less as the base steel plate of the plating layer , S: 0.05% or less, Al: 0.1% or less, N: 0.01% or less, and the steel sheet having a composition composed of Fe and inevitable impurities as the balance can be used. The reason for limitation of each component element is demonstrated below.

C:0.15〜0.5%
Cは、鋼の強度を向上させる元素であり、熱間プレス部材のTSを980MPa以上にするには、その量を0.15%以上とする必要がある。一方、C量が0.5%を超えると、素材の鋼板のブランキング加工性が著しく低下する。したがって、C量は0.15〜0.5%とする。
C: 0.15-0.5%
C is an element that improves the strength of steel. In order to increase the TS of a hot-pressed member to 980 MPa or more, the amount needs to be 0.15% or more. On the other hand, if the amount of C exceeds 0.5%, the blanking workability of the steel plate as the material will be significantly reduced. Therefore, the C content is 0.15 to 0.5%.

Si:0.05〜2.0%
Siは、C同様、鋼の強度を向上させる元素であり、熱間プレス部材のTSを980MPa以上にするには、その量を0.05%以上とする必要がある。一方、Si量が2.0%を超えると、熱間圧延時に赤スケールと呼ばれる表面欠陥の発生が著しく増大するとともに、圧延荷重が増大したり、熱延鋼板の延性の劣化を招く。さらに、Si量が2.0%を超えると、Alを主体としためっき層を鋼板表面に形成するめっき処理を施す際に、めっき処理性に悪影響を及ぼす場合がある。したがって、Si量は0.05〜2.0%とする。
Si: 0.05-2.0%
Si, like C, is an element that improves the strength of steel. In order to increase the TS of a hot-pressed member to 980 MPa or more, the amount needs to be 0.05% or more. On the other hand, when the Si content exceeds 2.0%, the occurrence of surface defects called red scale during hot rolling is remarkably increased, the rolling load is increased, and the ductility of the hot-rolled steel sheet is deteriorated. Furthermore, if the Si content exceeds 2.0%, the plating processability may be adversely affected when a plating process for forming a plating layer mainly composed of Al on the steel sheet surface is performed. Therefore, the Si content is 0.05 to 2.0%.

Mn:0.5〜3%
Mnは、フェライト変態を抑制して焼入れ性を向上させるのに効果的な元素であり、また、Ac3変態点を低下させるので、熱間プレス前の加熱温度を低下するにも有効な元素である。このような効果の発現のためには、その量を0.5%以上とする必要がある。一方、Mn量が3%を超えると、偏析して素材の鋼板および熱間プレス部材の特性の均一性が低下する。したがって、Mn量は0.5〜3%とする。
Mn: 0.5-3%
Mn is an effective element for improving the hardenability by suppressing the ferrite transformation, and also an element effective for lowering the heating temperature before hot pressing because it lowers the Ac 3 transformation point. is there. In order to exhibit such an effect, the amount needs to be 0.5% or more. On the other hand, when the amount of Mn exceeds 3%, segregation occurs and the uniformity of the characteristics of the raw steel plate and the hot press member decreases. Therefore, the amount of Mn is 0.5 to 3%.

P:0.1%以下
P量が0.1%を超えると、偏析して素材の鋼板および熱間プレス部材の特性の均一性が低下するとともに、靭性も著しく低下する。したがって、P量は0.1%以下とする。
P: 0.1% or less
When the amount of P exceeds 0.1%, segregation occurs and the uniformity of the characteristics of the raw steel plate and hot-pressed member decreases, and the toughness also decreases significantly. Therefore, the P content is 0.1% or less.

S:0.05%以下
S量が0.05%を超えると、熱間プレス部材の靭性が低下する。したがって、S量は0.05%以下とする。
S: 0.05% or less
When the amount of S exceeds 0.05%, the toughness of the hot pressed member decreases. Therefore, the S content is 0.05% or less.

Al:0.1%以下
Al量が0.1%を超えると、素材の鋼板のブランキング加工性や焼入れ性を低下させる。したがって、Al量は0.1%以下とする。
Al: 0.1% or less
If the Al content exceeds 0.1%, blanking workability and hardenability of the steel sheet will be reduced. Therefore, the Al content is 0.1% or less.

N:0.01%以下
N量が0.01%を超えると、熱間圧延時や熱間プレス前の加熱時にAlNの窒化物を形成し、素材の鋼板のブランキング加工性や焼入れ性を低下させる。したがって、N量は0.01%以下とする。
N: 0.01% or less
If the N content exceeds 0.01%, an AlN nitride is formed during hot rolling or heating before hot pressing, and the blanking workability and hardenability of the raw steel sheet are reduced. Therefore, the N content is 0.01% or less.

残部はFeおよび不可避的不純物であるが、以下の理由により、Cr:0.01〜1%、Ti:0.2%以下、B:0.0005〜0.08%のうちから選ばれた少なくとも一種や、Sb:0.003〜0.03%が、個別にあるいは同時に含有されることが好ましい。   The balance is Fe and inevitable impurities, but for the following reasons, at least one selected from Cr: 0.01 to 1%, Ti: 0.2% or less, B: 0.0005 to 0.08%, Sb: 0.003 to 0.03 % Are preferably contained individually or simultaneously.

Cr:0.01〜1%
Crは、鋼を強化するとともに、焼入れ性を向上させるのに有効な元素である。こうした効果の発現のためには、Cr量を0.01%以上とすることが好ましい。一方、Cr量が1%を超えると、著しいコスト高を招くため、その上限は1%とすることが好ましい。
Cr: 0.01-1%
Cr is an element effective for strengthening steel and improving hardenability. In order to exhibit such an effect, the Cr content is preferably 0.01% or more. On the other hand, if the Cr content exceeds 1%, the cost is significantly increased, so the upper limit is preferably 1%.

Ti:0.2%以下
Tiは、鋼を強化するとともに、細粒化により靭性を向上させるのに有効な元素である。また、次に述べるBよりも優先して窒化物を形成して、固溶Bによる焼入れ性の向上効果を発揮させるのに有効な元素でもある。しかし、Ti量が0.2%を超えると、熱間圧延時の圧延荷重が極端に増大し、また、熱間プレス部材の靭性が低下するので、その上限は0.2%以下とすることが好ましい。
Ti: 0.2% or less
Ti is an element effective for strengthening steel and improving toughness by refining. It is also an element effective for forming a nitride in preference to B, which will be described next, and exhibiting the effect of improving hardenability by solid solution B. However, if the amount of Ti exceeds 0.2%, the rolling load during hot rolling is extremely increased, and the toughness of the hot pressed member is lowered, so the upper limit is preferably 0.2% or less.

B:0.0005〜0.08%
Bは、熱間プレス時の焼入れ性や熱間プレス後の靭性向上に有効な元素である。こうした効果の発現のためには、B量を0.0005%以上とすることが好ましい。一方、B量が0.08%を超えると、熱間圧延時の圧延荷重が極端に増大し、また、熱間圧延後にマルテンサイト相やベイナイト相が生じて鋼板の割れなどが生じるので、その上限は0.08%とすることが好ましい。
B: 0.0005-0.08%
B is an element effective for improving the hardenability during hot pressing and toughness after hot pressing. In order to exhibit such an effect, the B content is preferably 0.0005% or more. On the other hand, if the amount of B exceeds 0.08%, the rolling load during hot rolling is extremely increased, and the martensite phase and bainite phase occur after hot rolling, resulting in cracks in the steel sheet, so the upper limit is It is preferable to set it to 0.08%.

Sb:0.003〜0.03%
Sbは、熱間プレス前に鋼板を加熱してから熱間プレスの一連の処理によって鋼板を冷却するまでの間に鋼板表層部に生じる脱炭層を抑制する効果を有する。このような効果の発現のためにはその量を0.003%以上とする必要がある。一方、Sb量が0.03%を超えると、圧延荷重の増大を招き、生産性を低下させる。したがって、Sb量は0.003〜0.03%とする。
Sb: 0.003-0.03%
Sb has an effect of suppressing a decarburized layer generated in the steel sheet surface layer portion between the time when the steel plate is heated before hot pressing and the time when the steel plate is cooled by a series of processes of hot pressing. In order to exhibit such an effect, the amount needs to be 0.003% or more. On the other hand, if the Sb content exceeds 0.03%, the rolling load increases and the productivity decreases. Therefore, the Sb amount is set to 0.003 to 0.03%.

2) 熱間プレス用鋼板の製造方法
本発明の熱間プレス用鋼板は、上記のような成分組成を有する下地鋼板を、Al濃度が80%以上およびSi濃度が3%以下のAl系めっき浴に浸漬後、ガスワイピングして、鋼板片面当たりの付着量が10〜200g/m2のAl-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を形成する方法により製造できる。この方法によれば、鋼板をAl系めっき浴に浸漬中およびめっき浴から引き上げた直後には鋼板表面にAl-Fe合金めっき層が形成されている。そして、鋼板をめっき浴から引き上げた直後、ガスワイピング前にはAl-Fe合金めっき層とその上層に溶融Alが存在している。この表面に存在する溶融Alをガスワイピングして、Al-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を形成する。
2) Method for producing hot-pressed steel sheet The hot-pressed steel sheet of the present invention is a base steel sheet having the above component composition, an Al plating bath having an Al concentration of 80% or more and an Si concentration of 3% or less. After immersing in the gas-wiping, the amount of adhesion per side of the steel sheet is 10 to 200 g / m 2 and the amount of adhesion per side of the steel sheet on the Al-Fe alloy plating layer is 5 g / m. It can be produced by a method of forming an Al layer of 2 or less. According to this method, the Al—Fe alloy plating layer is formed on the surface of the steel sheet while the steel sheet is immersed in the Al-based plating bath and immediately after it is pulled up from the plating bath. Immediately after the steel plate is lifted from the plating bath, before the gas wiping, Al-Fe alloy plating layer and molten Al are present in the upper layer. The molten Al present on the surface is gas-wiped to form an Al—Fe alloy plating layer and an Al layer having an adhesion amount of 5 g / m 2 or less per one surface of the steel sheet on the Al—Fe alloy plating layer.

Al系めっき浴は、Al濃度が80%以上およびSi濃度が3%以下とする必要があるが、これは25〜90%のFeおよび3%以下のSiを含み、残部がAlおよび不可避的不純物からなり、かつFeとAlの合計含有率が97%以上であるAl-Fe合金めっき層を形成するためである。特にSiはめっき浴のAlと鋼板のFeとの合金化反応を抑制するため、Al-Fe合金めっき層を10g/m2以上形成させるには、Al系めっき浴中のSi濃度は3%以下とする必要がある。また、このめっき浴には、通常、鋼板から溶出するFeを不可避的に5%以下含有している場合があるが、本発明においてはこれを許容する。さらに、このAl系めっき浴に、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種が含有されることが好ましい。Al系めっき浴に、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種が含有されることにより、上記したCr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含むAl-Fe合金めっき層が形成されるためである。 Al-based plating baths must have an Al concentration of 80% or more and an Si concentration of 3% or less, which contains 25 to 90% Fe and 3% or less of Si, with the balance being Al and inevitable impurities This is because an Al—Fe alloy plating layer having a total content of Fe and Al of 97% or more is formed. In particular, since Si suppresses the alloying reaction between Al in the plating bath and Fe in the steel sheet, the Si concentration in the Al plating bath is 3% or less in order to form an Al-Fe alloy plating layer of 10 g / m 2 or more. It is necessary to. In addition, this plating bath usually unavoidably contains 5% or less of Fe eluted from the steel sheet, but this is allowed in the present invention. Furthermore, it is preferable that this Al-based plating bath contains at least one selected from Cr: 3% or less, Mg: 3% or less, and Zn: 3% or less. By containing at least one selected from Cr: 3% or less, Mg: 3% or less, Zn: 3% or less in the Al-based plating bath, the above Cr: 3% or less, Mg: 3% This is because an Al—Fe alloy plating layer containing at least one selected from Zn: 3% or less is formed.

Al-Fe合金めっき層のFe含有率を25〜90%とし、鋼板片面当たりの付着を10〜200g/m2とするためにはAl系めっき浴の温度を高温にし、鋼板のAl系めっき浴への浸漬時間を長くすることが好ましい。Al系めっき浴の温度は、670℃以上とすることが好ましい。より好ましくは680℃以上、さらに好ましくは690℃以上とする。鋼板のAl系めっき浴への浸漬時間は、0.1秒以上とすることが好ましい。より好ましくは0.2秒以上、さらに好ましくは0.3秒以上とする。なお、Al-Fe合金めっき層を構成する金属間化合物としては、FeAl3、Fe2Al5、FeAl2、FeAl、Fe3Alなどが例示される。 In order to set the Fe content of the Al-Fe alloy plating layer to 25 to 90% and the adhesion per one side of the steel sheet to 10 to 200 g / m 2 , the temperature of the Al-based plating bath should be increased, and the Al-based plating bath for the steel sheet. It is preferable to increase the immersion time. The temperature of the Al plating bath is preferably 670 ° C. or higher. More preferably, it is 680 ° C. or higher, and further preferably 690 ° C. or higher. The immersion time of the steel sheet in the Al plating bath is preferably 0.1 seconds or longer. More preferably, it is 0.2 second or more, and further preferably 0.3 second or more. Examples of intermetallic compounds constituting the Al—Fe alloy plating layer include FeAl 3 , Fe 2 Al 5 , FeAl 2 , FeAl, and Fe 3 Al.

Al層の鋼板片面当たりの付着量を5 g/m2以下とするためには、ワイピングガスの流量を増大させることが好ましい。好ましくは300L(リットル)/分以上、より好ましくは400L/分以上、さらに好ましくは500L/分以上、さらには1000L/分以上とする。なお、ワイピングに使用するガスとしては、N2ガスなどの不活性ガスを用いることが好ましい。また、その他の条件、例えばガスワイピングのガス圧、ノズル形状、ノズルと鋼板との距離、めっき浴面とワイピング装置との距離、ライン速度等によってもAl層の付着量は調整可能であり、目標とする付着量となるように適宜条件を決定することが好ましい。 In order to make the adhesion amount of the Al layer per one side of the steel sheet 5 g / m 2 or less, it is preferable to increase the flow rate of the wiping gas. Preferably, it is 300 L (liter) / min or more, more preferably 400 L / min or more, further preferably 500 L / min or more, and further 1000 L / min or more. As the gas used for wiping, it is preferable to use an inert gas such as N 2 gas. Also, the amount of Al layer deposited can be adjusted by other conditions such as gas wiping gas pressure, nozzle shape, distance between nozzle and steel plate, distance between plating bath surface and wiping device, line speed, etc. It is preferable to appropriately determine the conditions so that the adhesion amount is as follows.

3) 熱間プレス部材の製造方法
上記した本発明の熱間プレス用鋼板は、Ac3変態点〜1000℃の温度範囲に加熱後、熱間プレスされて熱間プレス部材となる。熱間プレス前にAc3変態点以上に加熱するのは、鋼板の組織をオーステナイト化し、熱間プレス時の急冷でマルテンサイト相などの硬質相を形成し、部材の高強度化を図るためである。また、加熱温度の上限を1000℃としたのは、1000℃を超えるとオーステナイト組織が粗大化し、熱間プレス部材の靱性が劣化するためである。なお、ここでいう加熱温度とは鋼板の最高到達温度のことをいう。
3) Manufacturing method of hot-pressed member The above-described hot-pressed steel sheet of the present invention is heated to a temperature range of Ac 3 transformation point to 1000 ° C and then hot-pressed to become a hot-pressed member. The reason for heating above the Ac 3 transformation point before hot pressing is to make the steel structure austenitic, to form a hard phase such as martensite phase by rapid cooling during hot pressing, and to increase the strength of the member. is there. The upper limit of the heating temperature is set to 1000 ° C. because when the temperature exceeds 1000 ° C., the austenite structure becomes coarse and the toughness of the hot pressed member deteriorates. In addition, the heating temperature here means the highest temperature reached of the steel sheet.

本発明の熱間プレス用鋼板には予めAl-Fe合金めっき層が形成されているので、熱間プレス前の加熱時において、下地鋼板をオーステナイト化できる範囲内で昇温速度の上昇や保持時間の短縮を図ることができることになる。なお、下地鋼板のオーステナイト化に必要な最低限の昇温速度や保持時間は鋼板の成分組成や組織に依存するが、上記の成分組成の鋼板では、昇温速度を150℃/秒、保持時間0秒でもオーステナイト化が可能であり、生産性を著しく向上できる。   Since the steel sheet for hot pressing of the present invention has an Al-Fe alloy plating layer formed in advance, the heating rate is increased and the holding time is within the range in which the base steel sheet can be austenitized during heating before hot pressing. Can be shortened. The minimum heating rate and holding time required for the austenitization of the base steel sheet depend on the composition and structure of the steel sheet, but for steel sheets with the above composition, the heating rate is 150 ° C / second and the holding time. Even at 0 seconds, austenite can be formed, and productivity can be remarkably improved.

熱間プレス前の加熱方法としては、電気炉やガス炉などによる加熱、火炎加熱、通電加熱、高周波加熱、誘導加熱などを例示できる。特に、昇温速度を上げるには、通電加熱、高周波加熱、誘導加熱などが好適である。   Examples of the heating method before hot pressing include heating by an electric furnace or a gas furnace, flame heating, energization heating, high frequency heating, induction heating, and the like. In particular, energization heating, high frequency heating, induction heating, and the like are suitable for increasing the rate of temperature increase.

下地鋼板として、質量%で、C:0.23%、Si:0.25%、Mn:1.2%、P:0.01%、S:0.01%、Al:0.03%、N:0.005%、Cr:0.2%、Ti:0.02%、B:0.0022%、Sb:0.008%を含有し、残部がFeおよび不可避的不純物からなる成分組成を有し、Ac3変態点が820℃で、板厚1.6mmの冷延鋼板を用いた。この冷延鋼板の表面に、1%のFeと表1に示す濃度のAlおよびSiと、Cr、MgまたはZnが含有される温度680〜720℃の溶融Al系めっき浴に0.5〜30秒浸漬し、めっき浴から引き上げ直後に流量1600L(リットル)/分でN2ガスワイピングを行って熱間プレス用鋼板No.1〜16を作製した。また、従来例として、めっき浴から引き上げ直後に、流量200L/分でN2ガスワイピングを行った熱間プレス用鋼板No.17〜19を作製した。 As a base steel sheet, in mass%, C: 0.23%, Si: 0.25%, Mn: 1.2%, P: 0.01%, S: 0.01%, Al: 0.03%, N: 0.005%, Cr: 0.2%, Ti: A cold-rolled steel sheet containing 0.02%, B: 0.0022%, Sb: 0.008%, the balance being composed of Fe and inevitable impurities, an Ac 3 transformation point of 820 ° C, and a thickness of 1.6 mm is used. It was. The surface of this cold-rolled steel sheet is immersed for 0.5 to 30 seconds in a molten Al-based plating bath at a temperature of 680 to 720 ° C containing 1% Fe, the concentrations of Al and Si shown in Table 1, and Cr, Mg or Zn. Then, immediately after pulling up from the plating bath, N 2 gas wiping was performed at a flow rate of 1600 L (liter) / min to produce hot-press steel plates No. 1-16. In addition, as conventional examples, steel plates No. 17 to 19 for hot pressing in which N 2 gas wiping was performed at a flow rate of 200 L / min immediately after pulling up from the plating bath were produced.

このようにして作製した熱間プレス用鋼板を、直接通電法により表1に示す平均昇温速度で、表1に示す最高到達温度まで加熱し、表1に示す保持時間保持した後、Al製金型で挟み込んで50℃/秒の冷却速度で冷却し、次に示す塗装密着性と塗装後耐食性の評価を行った。
塗装密着性:作製した熱間プレス用鋼板から試料を採取し、日本パーカライジング株式会社製PB-L3020を使用して標準条件で化成処理を施した後、関西ペイント株式会社製電着塗料GT-10を電着塗装し焼付けを行い、膜厚が20μmの電着塗膜を形成した塗装試験片を作製した。そして、この試験片の塗膜に対してカッターナイフで碁盤目(10×10個、1mm間隔)の鋼素地まで到達するカットを入れ、接着テープにより貼着・剥離する碁盤目テープ剥離試験を行った。以下の基準で評価し、○であれば本発明の目的を満足しているとした。
○:塗膜剥離なし
×:塗膜剥離あり
塗装後耐食性:上記塗装密着性の場合と同様な方法で作製した塗装試験片に、カッターナイフで塗膜にクロスカットを入れた後、JIS Z 2371-2000に準拠した塩水噴霧試験を行い、480時間後に接着テープにより貼着・剥離するテープ剥離試験を行い、カット傷の片側最大剥離幅を測定し、以下の基準で評価し、○、△であれば本発明の目的を満足しているとした。
○:最大剥離幅≦3mm
△:3mm<最大剥離幅≦5mm
×:5mm<最大剥離幅
結果を表1に示す。本発明である熱間プレス用鋼板No.1〜16では、平均昇温速度を10〜150℃/秒の範囲で変え、保持時間0秒で加熱しても、または平均昇温速度を10℃/秒とし、保持時間300秒で加熱しても、いずれも優れた塗装密着性や塗装後耐食性が得られており、熱間プレス前の加熱時に昇温速度の上昇や保持時間の短縮が可能であることがわかる。一方、Al-Fe合金めっき層のFe含有率や付着量が本発明の範囲外の比較例である熱間プレス用鋼板No.17〜19では、平均昇温速度50℃/秒とし、保持時間0秒で加熱すると、塗装密着性または塗装後耐食性のいずれかに劣るため、昇温速度の上昇や保持時間の短縮が困難であることがわかる。また、従来から熱間プレス用鋼板として使用されているAl-Fe合金層の上層に5g/m2を超えるAl層が存在しているAl-10%Siめっき鋼板(No.20〜24)では、これを平均昇温速度が10℃/秒とし、保持時間300秒とした場合には優れた塗装密着性や塗装後耐食性が得られるが、保持時間を0秒としたり、保持時間300秒でも平均昇温速度を50℃/秒以上とした場合には塗装密着性または塗装後耐食性のいずれかに劣るため、昇温速度の上昇や保持時間の短縮が困難であることがわかる。
The steel sheet for hot pressing produced in this way was heated to the maximum temperature shown in Table 1 at the average heating rate shown in Table 1 by the direct current method, and held for the holding time shown in Table 1. It was sandwiched between molds and cooled at a cooling rate of 50 ° C./second, and the following coating adhesion and post-coating corrosion resistance were evaluated.
Paint adhesion: A sample was taken from the steel sheet for hot press produced, and after chemical conversion treatment was performed under standard conditions using PB-L3020 made by Nihon Parkerizing Co., Ltd., electrodeposition paint GT-10 made by Kansai Paint Co., Ltd. The electrodeposition was applied and baked to prepare a coating specimen having an electrodeposition coating film with a thickness of 20 μm. Then, a cut that reaches the cross section (10 x 10 pieces, 1 mm interval) of the steel substrate with a cutter knife is applied to the coating film of this test piece, and a cross section tape peeling test is performed in which the adhesive tape is used to attach and peel. It was. Evaluation was made according to the following criteria, and if it was ○, the object of the present invention was satisfied.
○: No peeling of coating film ×: No peeling of coating film Corrosion resistance after painting: After applying a cross cut to the coating film with a cutter knife on a coating test piece prepared in the same manner as in the case of the above coating adhesion, JIS Z 2371 -2000 salt water spray test, tape peel test to stick and peel with adhesive tape after 480 hours, measure the maximum peel width on one side of cut wound, and evaluate according to the following criteria, ○, △ If so, the object of the present invention was satisfied.
○: Maximum peel width ≤ 3mm
Δ: 3 mm <maximum peeling width ≦ 5 mm
×: 5 mm <maximum peel width The results are shown in Table 1. In the steel plate for hot pressing No. 1 to 16 of the present invention, the average temperature rising rate is changed in the range of 10 to 150 ° C./second, and heating is performed with a holding time of 0 seconds, or the average temperature rising rate is 10 ° C. Even when heated at a holding time of 300 seconds, excellent coating adhesion and post-coating corrosion resistance are obtained, and it is possible to increase the heating rate and shorten the holding time during heating before hot pressing. It can be seen that it is. On the other hand, in the steel sheet No.17-19 for hot pressing, which is a comparative example in which the Fe content and adhesion amount of the Al-Fe alloy plating layer are out of the scope of the present invention, the average heating rate is 50 ° C./second, It can be seen that heating at 0 seconds is inferior to either coating adhesion or post-coating corrosion resistance, making it difficult to increase the heating rate and shorten the holding time. In addition, Al-10% Si plated steel sheets (No. 20-24) in which an Al layer exceeding 5 g / m 2 is present in the upper layer of the Al-Fe alloy layer that has been used as a steel sheet for hot pressing in the past When the average heating rate is 10 ° C / second and the holding time is 300 seconds, excellent coating adhesion and post-coating corrosion resistance can be obtained, but even with a holding time of 0 seconds or a holding time of 300 seconds When the average heating rate is 50 ° C./second or more, it is found that it is difficult to increase the heating rate or shorten the holding time because it is inferior to coating adhesion or post-coating corrosion resistance.

なお、本実施例では実際に熱間プレスによる加工を行っていないが、上述したように、塗装密着性や塗装後耐食性は熱間プレス前のめっき層の状態に左右されるので、本実施例の結果で熱間プレス部材の塗装密着性や塗装後耐食性を評価できることになる。   In this example, processing by hot pressing is not actually performed. However, as described above, coating adhesion and corrosion resistance after coating depend on the state of the plating layer before hot pressing. As a result, it is possible to evaluate the coating adhesion and the post-coating corrosion resistance of the hot press member.

Figure 2012041610
Figure 2012041610

Claims (9)

鋼板表面に、質量%で、Fe:25〜90%およびSi:3%以下を含み、残部がAlおよび不可避的不純物からなり、かつFeとAlの合計含有率が97%以上であり、鋼板片面当たりの付着量が10〜200g/m2のAl-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を有することを特徴とする熱間プレス用鋼板。 On the surface of the steel sheet, by mass%, Fe: 25 to 90% and Si: 3% or less, the balance is made of Al and inevitable impurities, and the total content of Fe and Al is 97% or more, and Al-Fe alloy plating layer adhesion amount of 10 to 200 g / m 2 per a feature that the amount deposited per steel sheet one surface to the Al-Fe alloy plated layer has a 5 g / m 2 or less of Al layer Steel sheet for hot pressing. Al-Fe合金めっき層が、さらに、質量%で、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種を含むことを特徴とする請求項1に記載の熱間プレス用鋼板。   The Al-Fe alloy plating layer further includes at least one selected from Cr: 3% or less, Mg: 3% or less, or Zn: 3% or less by mass%. The steel plate for hot press as described. Al-Fe合金めっき層の下地鋼板が、質量%で、C:0.15〜0.5%、Si:0.05〜2.0%、Mn:0.5〜3%、P:0.1%以下、S:0.05%以下、Al:0.1%以下、N:0.01%以下を含有し、残部がFeおよび不可避的不純物からなる成分組成を有することを特徴とする請求項1または2に記載の熱間プレス用鋼板。   The base steel plate of the Al-Fe alloy plating layer is in mass%, C: 0.15-0.5%, Si: 0.05-2.0%, Mn: 0.5-3%, P: 0.1% or less, S: 0.05% or less, Al: 3. The hot-press steel sheet according to claim 1, wherein the hot-press steel sheet contains 0.1% or less and N: 0.01% or less, and the balance has a composition composed of Fe and inevitable impurities. Al-Fe合金めっき層の下地鋼板が、さらに、質量%で、Cr:0.01〜1%、Ti:0.2%以下、B:0.0005〜0.08%のうちから選ばれた少なくとも一種を含有することを特徴とする請求項3に記載の熱間プレス用鋼板。   The base steel plate of the Al-Fe alloy plating layer further contains at least one selected from Cr: 0.01 to 1%, Ti: 0.2% or less, B: 0.0005 to 0.08% by mass%. 4. A steel sheet for hot pressing according to claim 3. Al-Fe合金めっき層の下地鋼板が、さらに、質量%で、Sb:0.003〜0.03%を含有することを特徴とする請求項3または4に記載の熱間プレス用鋼板。   5. The hot-press steel sheet according to claim 3, wherein the base steel sheet of the Al—Fe alloy plating layer further contains Sb: 0.003 to 0.03% by mass%. 鋼板を、質量%で、Al:80%以上およびSi:3%以下を含有するAl系めっき浴に浸漬後、ガスワイピングして、鋼板片面当たりの付着量が10〜200g/m2のAl-Fe合金めっき層と、該Al-Fe合金めっき層上に鋼板片面当たりの付着量が5g/m2以下のAl層を形成することを特徴とする熱間プレス用鋼板の製造方法。 After immersing the steel sheet in an Al-based plating bath containing Al: 80% or more and Si: 3% or less in mass%, gas wiping is performed, and the amount of adhesion per one side of the steel sheet is 10 to 200 g / m 2 . A method for producing a steel sheet for hot pressing, comprising forming an Fe alloy plating layer and an Al layer having an adhesion amount per one surface of the steel sheet of 5 g / m 2 or less on the Al-Fe alloy plating layer. Al系めっき浴に、さらに、質量%で、Cr:3%以下、Mg:3%以下、Zn:3%以下のうちから選ばれた少なくとも一種が含有されることを特徴とする請求項6に記載の熱間プレス用鋼板の製造方法。   The Al-based plating bath further comprises at least one selected from Cr: 3% or less, Mg: 3% or less, Zn: 3% or less by mass%. The manufacturing method of the steel plate for hot press of description. 鋼板として、請求項3から5のいずれか一項に記載の成分組成を有する鋼板を用いることを特徴とする請求項6または7に記載の熱間プレス用鋼板の製造方法。   8. The method for producing a steel sheet for hot pressing according to claim 6 or 7, wherein a steel sheet having the component composition according to any one of claims 3 to 5 is used as the steel sheet. 請求項1から5のいずれか一項に記載の熱間プレス用鋼板を、Ac3変態点〜1000℃の温度範囲に加熱後、熱間プレスすることを特徴とする熱間プレス部材の製造方法。 A method for producing a hot press member, comprising: hot pressing the steel sheet for hot pressing according to any one of claims 1 to 5 to a temperature range of Ac 3 transformation point to 1000 ° C. .
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180030563A1 (en) * 2015-01-27 2018-02-01 Jfe Steel Corporation Case hardening steel
JP6439906B1 (en) * 2018-03-20 2018-12-19 新日鐵住金株式会社 Hot stamping body
JP6443596B1 (en) * 2018-03-20 2018-12-26 新日鐵住金株式会社 Hot stamping body
JP2020084224A (en) * 2018-11-16 2020-06-04 日鉄日新製鋼株式会社 Hot-dip Al-plated steel sheet
JP2020084223A (en) * 2018-11-16 2020-06-04 日鉄日新製鋼株式会社 HOT-DIP Al-BASED STEEL SHEET, AND MANUFACTURING METHOD OF HOT-DIP Al-BASED STEEL SHEET
JP2020122202A (en) * 2019-01-31 2020-08-13 Jfeスチール株式会社 Al-Fe-BASED PLATED SHEET STEEL FOR HOT PRESSING AND MANUFACTURING METHOD OF HOT PRESS MEMBER
WO2020162513A1 (en) * 2019-02-05 2020-08-13 日本製鉄株式会社 Coated steel member, coated steel sheet, and methods for producing same
WO2021210114A1 (en) * 2020-04-16 2021-10-21 日本製鉄株式会社 Hot-dip al-based-material-coated steel plate, and method for manufacturing hot-dip al-based-material-coated steel plate
KR20210149777A (en) * 2019-04-09 2021-12-09 아르셀러미탈 Assembly of aluminum parts and press-hardened steel parts having an alloyed coating comprising silicon, iron, zinc and magnesium, the balance being aluminum
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10219415A (en) * 1997-01-31 1998-08-18 Nisshin Steel Co Ltd Hot dip aluminized steel sheet excellent in plating peeling resistance at the time of press working and its production
JP2003041343A (en) * 2001-07-27 2003-02-13 Nippon Steel Corp Aluminized steel sheet for high-strength automotive member and member for automobile with the use of the same
JP2003183802A (en) * 2001-12-18 2003-07-03 Nippon Steel Corp High-strength aluminum-plated steel sheet excellent in heat resistance and after-coating corrosion resistance, and high-strength automotive part
JP2004002933A (en) * 2002-05-31 2004-01-08 Nippon Steel Corp Aluminum plated steel sheet having excellent resistance weldability and worked parts obtained by using the aluminum plated steel sheet
JP2004244704A (en) * 2003-02-17 2004-09-02 Nippon Steel Corp HIGH STRENGTH Al BASED PLATED STEEL SHEET HAVING EXCELLENT CORROSION RESISTANCE AFTER COATING, HIGH STRENGTH AUTOMOBILE COMPONENT, AND PRODUCTION METHOD THEREFOR
JP2005238286A (en) * 2004-02-26 2005-09-08 Nippon Steel Corp Hot press method of high-strength automobile member using al-based plated steel plate
JP2010018860A (en) * 2008-07-11 2010-01-28 Nippon Steel Corp Plated steel sheet for hot press and production method therefor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10219415A (en) * 1997-01-31 1998-08-18 Nisshin Steel Co Ltd Hot dip aluminized steel sheet excellent in plating peeling resistance at the time of press working and its production
JP2003041343A (en) * 2001-07-27 2003-02-13 Nippon Steel Corp Aluminized steel sheet for high-strength automotive member and member for automobile with the use of the same
JP2003183802A (en) * 2001-12-18 2003-07-03 Nippon Steel Corp High-strength aluminum-plated steel sheet excellent in heat resistance and after-coating corrosion resistance, and high-strength automotive part
JP2004002933A (en) * 2002-05-31 2004-01-08 Nippon Steel Corp Aluminum plated steel sheet having excellent resistance weldability and worked parts obtained by using the aluminum plated steel sheet
JP2004244704A (en) * 2003-02-17 2004-09-02 Nippon Steel Corp HIGH STRENGTH Al BASED PLATED STEEL SHEET HAVING EXCELLENT CORROSION RESISTANCE AFTER COATING, HIGH STRENGTH AUTOMOBILE COMPONENT, AND PRODUCTION METHOD THEREFOR
JP2005238286A (en) * 2004-02-26 2005-09-08 Nippon Steel Corp Hot press method of high-strength automobile member using al-based plated steel plate
JP2010018860A (en) * 2008-07-11 2010-01-28 Nippon Steel Corp Plated steel sheet for hot press and production method therefor

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WO2019180852A1 (en) * 2018-03-20 2019-09-26 日本製鉄株式会社 Hot stamp molded article
WO2019180853A1 (en) * 2018-03-20 2019-09-26 日本製鉄株式会社 Hot stamp molded body
CN111868290B (en) * 2018-03-20 2022-05-31 日本制铁株式会社 Hot stamp-molded body
US11338550B2 (en) 2018-03-20 2022-05-24 Nippon Steel Corporation Hot-stamped body
JP2020084224A (en) * 2018-11-16 2020-06-04 日鉄日新製鋼株式会社 Hot-dip Al-plated steel sheet
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JP7230448B2 (en) 2018-11-16 2023-03-01 日本製鉄株式会社 Hot-dip Al-plated steel sheet
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